TW303380B - - Google Patents

Description

V. Description of the invention (ί) A7 B7 The present invention relates to ** novel silyl-containing piperidine triazine compounds 9 which are used as organic materials for photothermal and oxidative stability, especially synthetic polymers * and Stable organic materials 0 Silicon-based 2 2 • 6 »6 ― Tetramethylpiperidine compound as described in US-A ― 4 1 7 7 1 8 6» US ― A ― 4 8 5 9 7 5 9 »US ― A ― 4 8 9 5 8 8 5 > US ― A ― 4 9 4 6 8 8 0 * US ― A ― 4 9 4 8 8 8 8 9 US ― A ― 5 1 3 4 2 3 3 * US ― A ― 5 2 1 9 9 0 5 »US ― A ― 5 3 2 1 0 6 6 9 EP ― A ― 1 6 2 5 2 4 1 EP ― A ― 1 8 2 4 1 5 9 EP ― A ― 2 4 4 0 2 6 t EP ― A ― 3 4 3 7 1 7 t E ― A ― 3 8 8 3 2 1 9 EP ― A ― 4 8 0 4 6 6 1 DD-A ― 2 3 4 6 8 2 and DD A ― 2 3 4 6 8 3 The application as a stabilizer for synthetic polymers is well known. The present invention is based on ― a compound of formula (I) CH ^ I .0 — Si-CHq

CH3 I Ο ——Si— I A

-------- < 'installation ------ order ----- i line (please read the precautions on the back before filling this page)

I

In its

2 — R

To 1Χ is η% o The total number of 9 to o η + Ε is η ο ο The standard of the paper method is applicable to the Chinese National Standard (CNS) A4 specifications (210/297 mm) A7 B7 V. Invention description (on) X is One ◦ one or one NH-;

RiSM, (〇1 _ (: 18) alkyl, (C2-C4) alkyl substituted with (Ci-C8) alkoxy or di (Ci_C4) alkylamine at the position of 2,3 or 4; not (CS -Ct 2) cycloalkyl substituted or substituted with 1, 2 or 3 (Ci — C4) alkyl groups; unsubstituted or phenyl substituted with 1, 2, or 3 (Ci — C4) alkyl groups (C7-C9) phenylalkyl; or formula (II) group (please read the precautions on the back before filling this page).

.IT R 2 is hydrogen 9 (CX-C 8), P 0 • 0 Η, Ν C Η 2 C Ν »(C-C i 8) alkoxy 9 (C 5 -C) cycloalkyloxy (C 7-C 9) phenylalkenyl »or (CC 8) unsubstituted or phenyl substituted with 1> 2 or 3 (C 1 C 4) alkyl groups 1 A is (C 6 — C 1 8) alkyl 〇

Examples of alkyl groups containing up to 18 carbon atoms are methyl, ethyl, propyl, isopropyl, butyl, 2-butyl, isobutyl, tertiary butyl, pentyl, 2-pentyl , Hexyl, heptyl, octyl, 2-ethylhexyl, tertiary octyl, nonyl, decyl, undecyl, dodecyl · tridecyl * tetradecyl, hexadecyl and octadecyl. Substituted by (c! —C8) alkoxy, preferably by (c1 -c4) haloxy • Especially substituted by methoxy and ethoxy (c2 _c4 -6-This paper scale applies the Chinese national standard ( CNS) A4 specification (210/297 mm) A7 303380_B2_ V. Description of the invention (3) (please read the precautions on the back before filling in this page)) Example of alkyl is 2-methoxyethyl * 2-ethoxy Ethyl, 3-methoxypropyl, 3-ethoxypropyl, 3-butoxypropyl, 3-octyloxypropyl and 4-methoxymethoxy. Examples of (C2-C4) alkyl substituted by di (Ci_C4) alkylamino, preferably dimethylamino or diethylamino are 2-methylaminoethyl, 2-diethyl Aminoethyl * 3-dimethylaminopropyl, 3-diethylaminopropyl * 3-dibutylaminopropyl and 4-diethylaminobutyl. (Ci —C! 8) Examples of alkoxy groups are methoxy, ethoxy, propoxy * isopropoxy, butoxy, isobutoxy, pentoxy, isopentoxy, hexoxy Group, heptyloxy, octyloxy, decyloxy, dodecyloxy, tetradecyloxy | hexadecyloxy and octadecyloxy. Preferred examples are (C6-Ci 2) alkoxy, especially heptoxy and octoxy. Examples of (Cs — Ci 2) cycloalkyl groups that are unsubstituted or substituted with 1, 2, or 3 (Ci -C4) alkyl groups are cyclopentyl • methylcyclopentyl, dimethylcyclopentyl · cyclohexyl | Methylcyclohexyl, dimethylcyclohexyl, trimethylcyclohexyl * tertiary butylcyclohexyl, cyclooctyl, cyclodecyl and odenyl. Preferred is a cyclohexyl group which is unsubstituted or substituted with (Ci _C4) alkyl group. (C7-C9) phenylalkyl group which is unsubstituted or phenyl group is substituted with 1, 2, or 3 (Ci —C4) alkyl groups Examples are benzyl, methylbenzyl, dimethylbenzyl, trimethylbenzyl, tertiary butylbenzyl and 2-phenylethyl | M benzyl. -7- The paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (210> 29, mm) A7 B7 V. Description of the invention (±) (C5 — C: 2) The example of cycloalkoxy is cyclopentyloxy • Cyclohexyloxy * cycloheptyloxy, cyclooctyloxy> cyclodecyloxy and cyclododecyloxy, M cyclopentyloxy and cyclohexyloxy are preferred. Examples of (Ci _C8) acyl groups are aliphatic or aromatic systems are methylamyl, ethylamyl | triosyl, triamyl * isobutylamyl, pentamyl, hexyl, heptamyl, octyl and phenacyl. (Ci-108) Alkyl and phenylacryl groups are preferred, and ethylacryl is particularly preferred. These compounds of formula (I) are particularly regarded as those in which m + n is from 1 to 100. η is, for example, 0 or 1 to 50 *, which can be varied from 0 to 50% of m + n. The number of m + η wraps can be, for example, 2 to 1 0 0 · 4 to 1 0 0 * 8 to 100, 2 to 70, 4 to 70 or 8 to 70. The variable η is preferably 10 to 50% of the total number of m + n, for example 20 to 50¾ or 30 to 50%. Furthermore, the variable m is, for example, 10 to 50, and the variable η is, for example, 0 to 50, 5 to 50, or 10 to 40. Α may be, for example, (C9-Ct8) alkyl, (Ct 〇-Ci 8) alkyl or (Cl2-Cl8) alkyl.

Preferred Rz is hydrogen > (C1-C4) alkyl, OH, (Cs-Ciz) alkoxy, (Cs-C8) cycloalkoxy, benzyl or ethyl glycosyl • especially ra or methyl. The preferred compound of formula (I) is where m + n is 1 to 90, and η is 0 to 90% of the total number of m + n; X is a 0 — or a NH —; the scale of this paper is applicable to the Chinese National Standard (CNS) A4 specification (210 ;. 29, mm) -------- * Pack ------ ordered ----- i line (please read the precautions on the back before filling in this If) A7 B7 5. Description of the invention (丄)

Ri is hydrogen, (Ci-Cl2) alkyl, (Cs-C7) cycloalkyl, (C7-C9) phenylalkyl or group of formula (III); and A is (Cs-Ci 2) alkyl. A particularly preferred compound of formula (I) is where m + n is 1 to 80, η is 0 to 90% of the total number of m + n; X is a 0 — or a NH —;

Ri is hydrogen * (Ci-C8) alkyl * cyclohexyl * benzyl or formula (I I); and A is (C8-Ci 2) alkyl. Particularly important compounds of formula (I) are where m + n is 1 to 70, η is 0 to 90% of the total number of m + n; X is a 0 — or a NH — ·;

Ri is hydrogen * (Ci-C *) alkyl group (II); and A is (C8- 匚! 2) alkyl. The compound of formula (I) that is particularly valued is where m + n is 1 to 60 * η is 0 to 90% of the total number of m + n; X is —0 — or a NH —;

Ri is hydrogen, (Ci-C4) alkyl group (I I) group; and A is (C8-Ci 2) alkyl group. The example of the compound of formula (I) is based on paper music standards, and it is applicable to the Chinese National Standard (CNS) A4 specification (210> 29, mm) (please read the precautions on the back before filling this page). Description of invention (

CH—si-—CH

ch3 〇 一 Si— I (ch2). 〇 / n \ A7 B7 h9c4-n n-c4h9

π

C—SIC Η Η c Γ -.3—H '-' u.t!-

-------- f Shimin ----- Ding ----- "Form 0¾-έ (Please read the precautions on the back before filling in this 1) This paper is applicable to China National Standards (CNS) Α4 specification (210> 2Pmm) 5. Description of invention (η A7 B7 H3C-

〇

Π3 I hc 丨 SIC 〇 27 3 Η 3-c3 Η.1Ηc Is —c

CH, H3C- Si-CH 3

CH O-Si- I c8h17 3

CH I 3 • Ο-Si- CH,

I CH 3 (Please note the precautions on the back of Mlt before filling this page)-Pack. 27 Orders

n-c4h9 h9c4

H

J7 2 > —12H —siIc Η I CIS oo 27 H c 3 j 3 o —, so The size of the paper is applicable to the Chinese National Standard (CNS) A4 specification (210 > 29-mm) V. Description of the invention (8) ch3 H〇C-Si- ch3

ch3 ch3? h3 H ^ C— Si- I ch3 A7 B7

-12- This paper scale is applicable to Chinese National Standard (CNS) A4 specification (210> 29? Mm) CH,

• Si- I Ci2H2S CH. I · 〇 — Si- c3h 17? H3 -0 —Si-

CaH, -Ο-Si—CH ^ CH, 27

CH ^ I -0 — * Si-— CH «I CH, 14 CH, • 0 — Si— CH- CHn (please read the precautions on the back before filling this page)

, 1T line 14 A7 B7 V. Description of invention (

(Please read the notes on the back before filling in this!).

.1T line This paper scale applies the Chinese National Standard (CNS) A4 specification (210> 29, mm) A7 B7 V. Description of invention (f.

Heart. -I i--».. 士 n ^ i —ii--J'-1----1 -1 ...... I---1. US. T® affairs (please read first (Notes on the back and then fill in this page) ί «? Bl he pr ^ wr.J >--, i .cr h 3 Ί

ch3 I H3C- Si— I ch3 ch3

I 0 — Si — CH3 (ΠΙ) CH3 where m and n are as defined above, and an appropriate number * can form a reaction of the following formula 14- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210> ' 297mm)) 3S03380 V. Description of invention (A7 (strict

X

And A group, where Rl · R 2, X and Z are as defined above, platinum or grandma in the amount of catalyst (such as EP — A — 3437 1 7 and 1818 3 88321 (Chemical Abstracts 115: 160 562f, Derwent 9 0-2 8 4 4 9 9/3 8) K and Speier (J. A. C. S. 79, 9 7 4, 1 9 5 7). The compound of formula (III) has been commercialized, or may be in accordance with It is prepared by adding K according to the conventional method. It is possible to form the following radicals

X

< 1 ch3 prepared, and the alkene capable of forming a has been commercialized. The compounds of the present invention can be very effective in improving the light resistance, heat and oxidation of synthetic materials, especially synthetic polymers and copolymers, based on their increase -1 5- The size of paper and paper is laizhongguanjiaza (CNS) ~ Specifications (210> 29-mm) (Please read the precautions on the back before filling in this page) Binding line A7 _B7_ V. Description of invention (A) Strong anti-volatility and especially entangled stable polypropylene gauze Examples of organic materials that can be stabilized include: 1. Polymers of monoolefins and diolefins, such as polypropylene, polyisobutylene, polybutene-1 monoene, poly-4-methylpentane-1 monoene, polyisoene Polymers of piperylene or polybutadiene and cyclic olefins, such as polymers of urpentene or proborneol; polyethylene (crosslinked if necessary), such as high density polyethylene (HDPE), low density polymer Ethylene (LDPE), medium low density polyethylene (LLDPE) or branched low density polyethylene (BLD PE). Polyolefin, also a monoolefin polymer, as mentioned in the previous paragraph, especially polyethylene and polypropylene, can be prepared by adding M in a variety of ways, especially by the following methods: (a) free radical polymerization ( It is usually carried out under high scraping and high temperature) »(b) box rib-catalyst, which usually contains one or more IVb, vb» VI b or VIII gold lutein, these gold lutein usually have one or more Sites, such as oxides, halides, ferrates, esters, ethers, amines • alkyls, alkenyls and / or aryls • which can be π — or σ — coordinated. These complexes may be in a free state or fixed on a carrier. For example, they may be fixed on an activated magnesium chloride, titanium nitride (II), aluminum oxide or silicon dioxide. Some catalysts are soluble or insoluble in the polymerization medium. The catalyst may be active in this polymerization reaction or an active agent may be further used, for example, gold lauryl, gold hydride, gold pendant alkyl halide, metal alkyl oxide, or gold pendant-16-this paper The scales are applicable to the Chinese National Standard (CNS) Α4 specifications (210 > '297 public broadcasting) -------- ^ Packing ------- order ----- i line (please read the back of the M first (Notes to fill out this page) A7 _B7_ V. Description of the invention (Ο) The base oxane, the gold element is an element of I a, II a and / or III a. The active agent can be modified with, for example, additional ester, ether or silyl ether groups. These catalyst systems are usually Philips, Standard Oil Indiana, Ziegler (-Natta), TNZ (Dupont), Metallocene or Single Position Catalyst (SSC). 2. The mixture of polymers mentioned in the above paragraph (1), such as a mixture of polypropylene and polyisobutylene, a mixture of polypropylene and polyethylene (such as PP / HDPE, PP / LDPE) and various polyethylene mixtures (LD PE / HDPE ). 3. Copolymers formed between monoolefins and diolefins or with other ethylene monomers, such as ethylene-propylene copolymers, intermediary low-density polyethylene (LLDPE) and its low-density polyethylene (LDPE) ) Mixture, polypropylene-butadiene copolymer, propylene-isobutylene copolymer, ethylene-butene-1 monoene copolymer • ethylene-hexene copolymer, ethylene methylpentene copolymer * ethylene-heptene Olefin copolymer, ethylene-octene copolymer, propylene-butadiene copolymer, isobutylene-isoprene copolymer, ethylene-alkyl acrylate copolymer, ethylene-alkyl methacrylic acid Methyl ester copolymer, ethylene-ethyl acetate copolymer and its copolymer with carbon monoxide, or ethylene-acrylic acid copolymer and its salt (iotiomer), and tripolymer of ethylene and propylene and diene, di Enenes such as ethylene dimethacrylate, dicyclopentadiene or ethylidene norbornene; and mixtures of such copolymers with other copolymers and the polymers mentioned in (1) • for example polypropylene / ethylene / propylene Copolymer, LDPE / Ethylene acid醮 醮 共 -17- This paper scale is applicable to the Chinese national standard ((; NS) A4 specification (210 > · 29, public broadcasting :) -------- ί -installation ------ order- ----- l · --line (please read the precautions on the back before filling in this page) V. Description of the invention (A) Polymer * LDPE / ethylene ethylene-ethyl acetate co-polymer instead of Polymers such as poly A7 B7 polymer and blends with 4 · hydrocarbon resin (such as CS _ adhesive resin) and polyalkylene and polyether 5. Polystyrene • poly (p-styrene). 6. Styrene or c (Monomethylstyrene and diene or propylene polymers, such as styrene-butadiene, styrene-acrylic acid copolymer, LLDPE /, LLDPE / ethylene-acrylic acid copolymerized alkylene / carbon monoxide copolymer and its amide. C 9) Including its modified product (such as powder mixture. Methyl styrene), and poly (α-methyl-alkyl methacrylic acid • styrene-butane-alkyl methacrylate, styrene one horse Nitrile monomethyl acrylate; high impact strength blends and other polymers, such as polyacrylate * polymers; also includes styrene ethyl-two ― Maleic anhydrides include a Μ M2-~ * λφ 3S block enoic acid-derived acryloyl propane and styrene styrene compound or copolymer bio-copolymerization, styrene acetoenoic acid_ and ene-propylene copolymerization Ethylene-propylene compounds such as styrene-butadiene-butadiene-one, styrene-isoprene-styrene, styrene-butene / butene 7 Styrene or benzene or α-methyl styrene butadiene, styrene-propylene copolymer copolymer grafted on polybutadiene; benzene; styrene and maleic anhydride or polybutadiene, acrylonitrile Ethylene-ethylene vinyl graft grafted with styrene ethylene, propylmaleic anhydride maleic acridine / propylene copolymerized polybutadiene and acrylonitrile and grafted with amine grafted olefin monophenate * ene one Benzonitrile (or methyl propylene butadiene but polybutylene). For example, styrene vinyl or polymethacrylic acid formic acid; on styrene; (please read the precautions on the back and then fill in this book) -install ·, ιτ 18 This paper is determined by the Chinese National Standard (CNS) Α4 specification (2 丨 0> '297 gala) 303380 B7 V. Description of invention (σ) (please read the precautions on the back before filling in this page) Styrene and maleimide grafted on polybutadiene, Styrene and alkyl acrylic acid_ or alkyl acrylic acid methylol grafted on polybutadiene, styrene and acrylonitrile grafted on ethylene-propylene-propylene-diene tripolymer • Styrene and acrylonitrile grafted On polyalkyl acrylates or polyalkyl methacrylates; styrene and propylene are grafted onto acrylate-butadiene copolymers, and mixtures of these with copolymers mentioned in 6. * For example , So-called A BS, MBS, ASA or AES polymer. 8 Halogen-containing polymers • For example • Polybutadiene, chlorinated rubber, chlorinated or chlorosulfonated polyethylene * copolymers of ethylene and chlorinated ethylene, epichlorohydrin 'homopolymers and copolymers Polymers, especially halogen-containing vinyl compound polymers · such as polyethylene gas * polyvinyl chloride, polyvinyl cyanide or polyvinyl fluoride, and copolymers * such as vinyl chloride monochloroethylene, vinyl chloride monoacetic acid Ethyl acetate or ethyl ethylidene monoethyl ester. 9 · Polymers derived from α, / 3 -unsaturated acids and their derivatives 'such as polyacrylates and polyacrylic acid methyl esters' methyl polymethyl methacrylate and butyl propyl acrylate, polypropylene amide and Modification of polypropylene umbilical counterweight. 10. The list of (9) «Copolymers formed between each other or with other unsaturated military bodies, such as acrylonitrile-butadiene copolymers, propylene-synthetic propionic acid copolymers' propylene Pro-oxyalkyloxypropyl copolymers, acrylonitrile-vinyl halogen copolymers or acrylonitrile-methyl propionate methyl-butadiene tripolymers. 11. Polymers derived from Blum and Yeast and amines or their ®-based derivatives or B®-based polymers, such as polyethylene yeast 'polyacetate' and polyethylene stearate-19 polystyrene-19 Standard (CNS) Α4 specifications (2l〇 > '2f public «) A7 B7 V. Description of invention / ^) 1 1 I Formic acid ethyl acetate polymaleic acid ethylene polybutene ethyl m 9 Polypeptide allyl m 1 1 1 and polyallyl maleamine and its copolymer with the olefin mentioned in (1) 1 I please 1 0 first 1 read 1 1 2 homopolymers and copolymers of cyclic ethers such as polyalkane Fermented polymer back 1 I Ethylene oxide polypropylene oxide or its copolymer with diglycidyl ether 0 Note 1 | Italian I 1 3 Polyethylene sugars such as polyoxymethylene and containing co-monomers « Polyoxymethylene items 1 I Epoxy 1 1 »As ethyl quilt is thermoplastic polyurethane m Acrylic _ or Μ B filled writing S modified polyethylose 0 Page 1 1 4 Polyphenylene oxide and polyphenylene sulfide and their mixture with styrene 1 1 or polyglyceramine 0 1 1 1 5 Derivatives η Polyether polyester and polybutadiene polyurethane, one of which contains one terminal hydroxyl group and the other end contains fatty% or aromatic polyisocyanic acid 1 suitable> λ and its predecessors. 1 1 1 6 Polym amines and copolymerized amines derived diamines and dicarboxylic acids and / or 1 1 derived white amino carboxylic acids or corresponding caprolactams such as polyamines 4 polyamines 1 1 linear amines 6 Polyamine 6/6 6/1 0 6/9 6/1 2 4 1 I / 6 and 1 2/1 2 Polyamide 1 1 Polyamide 1 2 and K 1 2 1 1 Toluene diamine and 2 Preparation of white hexamethylene 1 1 di Polyglycosamines with isopeptidic acid and / or terephthalic acid, if necessary, use elastomeric properties as modifiers such as poly-2 4 4 —trimethylhexylidene 1 1 1 peptide glycosaminoglycans or poly-ammonium Monophenylene isopeptide acetamine 0 The polyglycosamines and polyenes described above! 1 Hydrocarbon 9 Olefin copolymers ti 〇no through e Γ or chemically bonded or grafted enthalpy 1 | block copolymer or with Polyether $ For example, polyethylene glycol, polypropylene malonate, or 1 I-20-1 I 1 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210> 297 mm) A7 _B7_ V. Description of invention (〇) Polybutadiene Block copolymer formed by two enzymes. Also included are polyglycosamines or copolyamides modified by ED PM or ABSS; and polyacetamides (RIM polyacetamide strips) condensed during processing. 1 7 · Polyurea, polyimide * polyacetamide-imidimide and polybenzazole. 18. Polyester, which is derived from dicarboxylic acid and diacid and / or derived from hydroxyacrylic acid or its corresponding lactone, such as polyethylene terephthalate, polybutylene terephthalate, Poly-1,4-dimethyl yeast cyclohexane terephthalate, and polyhydroxybenzoate, and block polyether-esters, which are derived from polyethers containing hydroxyl end groups; and poly Carbonate or MB S modified polyester. 1 9 · Polycarbonate and poly__carbonate. 20. Poly-roll, polyether-roll and polyether-ketone. 2 1 · Cross-linked polymers * derived from aldehydes on the one hand and phenols, ureas or melamines on the other * eg phenol-formaldehyde resins, urea-formaldehyde resins and melamine-formaldehyde Resin. 22 · Dry refined and non-dry fermented acid resin. 2 3 · Unsaturated polyester resin, which is derived from cell and copolymers of unsaturated dicarboxylic acid and polyacrylic acid, also uses vinyl compound as crosslinking agent, and its low flammability is derived from halogen-containing improvement. 24. Cross-linked acrylic resins derived from substituted acrylics, such as epoxy acrylates, urethane acrylates or polyester acrylics. 25. Fermented acid resins, polyester resins and acrylic resins, which are cross-linked with trisaminoglycan, urea resins, polyisocyanates or epoxy resins. 2 6 · Cross-linked epoxy resins, which are derived from polyepoxides, such as derived-21- This paper scale is applicable to the Chinese National Standard (CNS) A4 specifications (210 > · 29-mm) ------ -'-¾ 衣 ------ 1T ----- (Please read the precautions on the back before filling in this page) A7 B7__ _ V. Description of the invention (α) Self-dioxopropyl ether or ring Fatty diepoxide. 2 7. Naturally produced polymers such as cellulose, natural rubber 'gels, and chemically modified derivatives of their polymer homologues' such as androgens acetate • cellulose acrylate and cellulose crotonate _ • Or cellulose ethers such as methyl cellulose · M and rosin resins and their derivatives. 28. Mixtures (poly blends) of the above polymers, such as PP / Ε PDM, Polyamide / EPDM or ABS, PVC / EVA * PVC / ABS · PVC / MBS, PC / ABS 'ΡΒ TP / ABS, PC / ASA, PC / PBT, PVC / CPE, PVE / Acrylic_, POM / Thermoplastic PUR, P C / Thermoplastic PUR, POM / Acrylic, POM / MBS · PPO / HIPS, PP0 / ΡΑ6.6 and copolymers , Ρ A / HDPE, ΡΑ / ΡΡ, ΡΑ / ΡΡΟ. 2 9. Naturally produced and synthesized compounds, which are pure military compounds or mixtures of such compounds, such as mineral oil, animal or vegetable fats, oils and fats, or oils based on M synthetic esters, M flats and fats are Main (such as peptide ester * adipate, phthalate or trimellitic acid), and a mixture of synthetic ester and mineral oil in any ratio • Used as, for example, Fangsi preparation | Μ and its aqueous emulsion . 3 0 · Aqueous suspension of naturally occurring or synthetic rubber, such as natural rubber latex or carboxylated styrene-butadiene copolymer latex. The compound of formula (I) is particularly useful for improving the light, heat and oxidation resistance of polyolefins, especially polyethylene and polypropylene. -22- This paper wave scale is applicable to the Chinese National Standard (CNS) Α4 specification (210> 297mm 1 (Please read the precautions on the back before filling in this tile) '-Installed. * 1Τ A7 B7 V. Invention description (1 ) 1 1 I The compound of formula (I) can be mixed in different proportions with 榇 木 科科 M to form a mixture 1 1 1 The proportion of the compound depends on the nature of the stabilized material and its end use M and its 1 I Please 1 I additives 0 First Μ 1 | Read 1 — Generally, -dbr uses a compound of formula (back 1 II), for example, 0 0 1 to 5% by weight, which is preferably relative to the weight of the stabilized material. Note 1 | Italian I Between 0 0 5 and 1%. Matters 1 I is more general. The compound of formula (I) can be cross-linked during m or before cross-linking before polymerization of the material or cross-linking. It is added to the polymer material 0 Page 1 1 The compound of formula (I) can be added to the polymer material 1 1 by different methods such as dry mixing in the form of M powder or M mixing in the form of M solution or suspension 1 1 i or in the form of a mixture of parent materials; In this kind of operation, the polymer can be powder. 1. The final particle S. solution float or > λ emulsion form 〇1 and formula (I). The product is stabilized. The material can be used to prepare molded products. 9 1 1 Film tape monofilament relay Dimensional surface coating and U-like substances 0 1 1 Can be added to the compound of formula (I) and organic materials as needed 1 Other synthetic polymers of linear compounds Traditional additives are antioxidants UV 1 Absorber m Stabilizer pigment filler Plasticizer corrosion inhibitor and 1 1 gold deactivator 0 1 1 can be mixed with compound of formula (I) Examples of special additives are 1 I 1 Antioxidant m 1 1 1 1 Alkylated monophenols such as 2 6 One-one tertiary-butyl one 4 1 1-Methylphenol 2 One three-tertiary one butyl-4 6 one two Methylphenol 2 6 1 | — tertiary monobutyl — 4 monoethylphenol 2 6 one two one tertiary monobutyl — 1 I-23-1 1 1 The paper standard is applicable to China National Standard (CNS) A4 specifications (210 > 29-mm) A7 B7 V. Description of the invention (> < =) 4 One n-butyl phenol, 2,6-two one three-stage one butyl one 4-isobutyl phenol, 2, 6-di-cyclopentyl-4-methylphenol, 2- (α-methylcyclohexyl) -4,6-dimethylphenol, 2,6-dioctadecyl-4-methylphenol , 2,4,6-tris-cyclohexylphenol, 2,6-di-one-tertiary-butyl-4-methoxymethylphenol, 2,6-di-nonyl-4-methyl , 4-dimethyl-6 — (1 ′ monomethyl-11-in-1 group) age, 2,4-dimethyl-6 — (1 ′ monomethyl-17-decane-1 1 ’Monoyl) phenol, 2,4-dimonomethyl-6- (1’monomethyltridecane-1 * monoyl) phenol and mixtures thereof. 1 · 2 alkylthiomethylphenol, such as 2,4-di-octylthiomethyl-6-tertiary-butylphenol, 2,4-di-octylthiomethyl-6-methyl Phenol, 2, 4-di-octylthiomethyl-6-ethylphenol, 2,6-didodecylthiomethyl-4-nonylphenol. 1 · 3 hydrogen roller and alkylated hydrogen sulfonate, for example, 2,6-di-tertiary monobutyl-4 monomethoxyphenol, 2,5-di-tertiary-butyl monohydrogen, 2, 5 -Di-tertiary monopentyl-gas trace, 6-diphenyl-4-octadecyloxyphenol, 2,6_di-tertiary monobutyl-hydrogen K, 2,5-di-tri Grade-Butyl-4-hydroxyanisole, 3,5-dione-tertiary monobutyl-4-hydroxyanisole, 3,5-dione-tertiary monobutyl-4-ketophenyl hard Fatty acid, and bis (3,5-di-tertiary-butyl-4-benzylphenyl) adipate. -2 4-This paper scale applies the Chinese National Standard (CNS) Α4 specification (210> 29-mm) -------- ^-士 κ ------ 丁 ------ * 5 ^ · (Please read the precautions on the back before filling in this page) A7 B7 5. Description of the invention (> 1) For example α-tocopherol i β — tocopherol 7 — tocopherol * δ tocopherol and its mixture (Vitamin E) 0 1 • 5 hydroxylated diphenyl sulfide »for example» 2, 2 * monothiobis (6 — secondary — butyl — 4 — methylphenol) 1 2 1 2 — thio — bis (4 — octylphenol) * 4 9 4, —thio-bis (6 — tertiary — butyl — 3 — methylphenol) * 4 dream 4 t — thio — bis (6 — secondary monobutyl) — 2 — methylphenol) t 4 t 4 »— thio-bis (3 * 6 one two-two-amylphenol) and 4 1 4 9 — bis (2 * 6 — dimethyl one 4 — hydroxyl Phenyl) disulfide Ο 1 • 6 Alkylidene-bisphenol, Example 9 2 t 2 / — Methylene — Bis (6 — Secondary — Butyl — 4 — Methylphenol) * 2 t 2, — Methylene-Double (6 — Grade — Butyl — 4 Monoethylphenol) 9 2 1 2 9 — Methylene — Double C 4 — Methyl — 6 — (α Monomethylcyclohexyl) phenol] 1 2% 2 Veg — Methylene — Bis (4 — Methyl — 6 — Cyclohexylphenol) »2 9 2» — Methylene — Bis (6 — Nonyl — 4 — Methyl Phenol) »2 1 2, monomethylene — double (4» 6 —. — — Grade — butylphenol) t 2 9 2 t monoethyl fork one pair (4 t 6 one -25- (please read the back (Notes to fill out this page)

.1T 丨 The size of the line paper is applicable to the Chinese National Standard (CNS) A4 specification (210 > _mm) A7 B7 V. Description of the invention (1 1 I second-grade-butylphenol) 2 2 9 monoethyl fork-double (6 — one-grade 1 1 1 — butyl — 4-isobutylphenol) 2 2, monomethylene — double C 6 — (1 1 please 1 I α — methylbenzyl) — 4 nonylphenol] 2 2 t Monomethyl support — Double C 6 Read first 1 1 Read 1 1 (α α —. Monomethylbenzyl) — 4 — Nonylphenol 3 4 4 > Back 1 ιέ | — Mono support — Double (2 6 First- and second-level butylphenol) 4 4 »— Methylene / i | Italian I — bis (6 first-level monobutyl-2 — methylphenol) 1 1 — bis (5 matters 1 I again — third-level one Butyl — 4 — hydroxy — 2 monomethylphenyl) Dingyuan 2 6 Fill in the writing equipment — bis (3 — tertiary monobutyl — 5 — A Group-2-hydroxybenzyl)-4 pages 1 I monomethylphenol 1 1 3 A ginseng (5-secondary monobutyl 4-hydroxy 1 1 group-2-methyl) Dingyuan 1 1-double ( 5 — tertiary — butyl — 4 1 1 one hydroxy one 2 one methyl phenyl group) one 3 one n_ _ ten-synthetic hydrogen sulfhydryl butane burn 1 set »Glycerol double C 3 3 one double (3, — Secondary — Butyl-4, monohydroxy 1 I phenyl) crotonate) bis (3 — secondary — butyl — 4 monohydroxy — 1 1 5 monomethylphenyl) dicyclopentadiene Double C 2-(3, one tertiary-butan 1 I group-2 > —— hydroxy-5, —— methylbenzyl) 6 first-level monobutyl-4 1 line-methylphenyl] pair Phthalic acid 1 1 — bis (3 5-dimethyl 1 yl-2-hydroxyphenyl) butyrin 2 2 — bis (3 5 — bis 1 1 1 level — butyl — 4 — hydroxyphenyl) propane School 2 2 One pair (5 First and second level 1 I One butyl one 4 one hydroxy one 2-methylphenyl)-4-n-dodecyl 1 I thiothiobutane and 1 1 5 5-four (5 one tertiary-butyl-4 1 1 (1-hydroxy-2-methylphenyl) pentylamine 0 1 1 1 7 0 1-N and S-benzyl compounds Example 3 5 3 9 1 1 * 5 t one four-secondary-butyl one 4 4 > — Dihydroxydibenzyl ether t 1 I-26-1 1 1 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210> 29 ”mm) A7 B7 5. Description of invention (7)) 1 1 I Octadecyl — 4 — hydroxy — 3 5 dimethylbenzyl hydrosulfoacetate 1 1 1 1 Ginseng (3 1 5 —-a tertiary monobutyl — 4 — hydroxybenzyl) amine bis (1 1 Please 1 | 4 a tertiary-butyl-3-hydroxy-6-dimethylbenzyl) disulfide first M 1 1 read 1 terephthalate bis (3 5-two-tertiary one Butyl-4 — hydroxyl back 1 δ | benzyl) sulfide and isooctyl 3 5 — tertiary — butyl 4 — hydroxy Note 1 meaning I benzyl hydrothioacetate 0 livestock 1 | re 1 8 Hydroxybenzylated malonate such as di-octadecyl 2 »Fill 1 Pack 2 One pair (3 5 One two one three tertiary monobutyl one 2 one hydroxybenzyl) Propionate 1 | Ester two Eighteen Yuan group 2 one (3-tertiary-butyl-4-hydroxy-1 1 5 methylbenzyl) malonate behenyl hydrogenthioethyl 2 > 1 1 2 one double (3 »5 one two one — grade _ butyl _ 4 hydroxybenzyl) malonic acid 1 ordered 9 two C 4 one (1 1 3 3 — tetramethylbutyl) phenyl] 2 1 1 2 — bis ( 3 5 — di-tertiary — butyl-4-hydroxybenzyl) propane 1 1 diacid 0 1 I 1 9 Hydroxybenzyl-aromatic compounds such as 1 3 5 a reference r V line (3 1 5 one two one two secondary-butyl-4-hydroxybenzyl)-2 4 > 1 6 monodimethylbenzene 1 4 — Bis (3 5 one two — tertiary — butyl — 1 1 4 — hydroxybenzyl) — 2 3 5 6 — tetramethylbenzene »2 4 t II 6 one ginseng (3 5 — two-tertiary one butyl -4-hydroxybenzyl) phenol 〇1 I 1 * 1 0 triazine compounds such as 2 4-bis-octyl hydrogen sulfide-1 1 6 one (3 5-two-tertiary monobutyl-4-hydroxyaniline Radicals) — 1 1 1 t 3 5 monotriazine 2-octylhydrosulfanyl — 4 > 6 — bis (3 5 1 1 — di — tertiary — 4 — hydroxyanilinyl) mono 1 3 5 monotriazine 2 1 1 I-27-1 1 1 The paper size is in accordance with Chinese National Standard (CNS> A4 specification (210/297 mm) A7 B7 V. Description of the invention (Μ) _octyl hydrosulfide 1, 4, 6-double (3, 5-two one three level one butyl one 4- Hydroxyphenoxy) -1,3,5-triazine, 2,4,6-ginseng (3,5-dione-tertiary-butyl-4-hydroxyphenoxy) -1,2,3-tri Azine, 1, 3, 5-ginseng (3, 5-bis-tertiary-butyl-4-hydroxybenzyl) isocyanurate, 2, 4, 6-ginseng (4-tertiary butyl-3 —Hydroxy-2,6-dimonobenzyl) isocyanurate, 2,4,6-ginseng (3,5-dione-tertiary monobutyl-4-hydroxyphenylethyl) -1, 3,5-triazine, 1 * 3,5-ginseng (3,5-dione-tertiary-butyl-4-monohydroxyphenylpropionyl) hexahydro-1,3,5-triazine and 1, 3,5-Ginseng (3,5-Dicyclohexyl-4-hydroxybenzyl) isocyanurate. 1 · 1 1 phosphonates such as dimethyl 2, 5-dione-tertiary monobutyl mono-4-hydroxybenzyl phosphate, diethyl 3 · 5-dione-tertiary-4 monohydroxybenzyl phosphate , Dioctadecyl 3,5-di-tertiary-butyl-4-monohydroxybenzyl phosphate, dioctadecane, 5-tertiary monobutyl-4-hydroxy-3-methylbenzyl Calcium salt of phosphoric acid ester and monoethyl 3,5-bis-tertiary-4-hydroxybenzyl phosphate. 1 · 1 2 · Acrylamidophenols, such as 4-hydroxyhydroxylaurate, aniline, 4-hydroxystearic acid, aniline, and octyl N- (3,5_di-tris-monobutyl-4-1 Hydroxyphenyl) carbamate. 1.13 β-(3,5_two one three tertiary monobutyl _4 monohydroxyphenyl) propionic acid and unit or multi-ester ester, enzymes such as formic enzymes, ethyl fermentation, capryl fermentation, 18 fermentation, 1 , 6 — Adipic fermentation, 1, 9 A nona fermentation, Ethylene-28 * This paper size is applicable to China National Standard (CNS) Α4 specification (210> 297mm) (Please read the notes on the back first (Fill in this page) Packing. A7 303380__ 5. Description of the invention (Ο yeast, 1, 2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol , Ginseng (hydroxyethyl) isocyanurate, Ν, Ν '-bis (hydroxyethyl) glufosinate, 3-salicylic acid, 3-thiopentadecanase, trimethyl adipase, Trimethylpropane and 4-hydroxymethyl-1-phospho-2,6,7-trioxabicyclo [2.2.2] octane. 1-14 β-(5-tertiary monobutyl-4- Ester of hydroxy-3-methyl-phenyl) propionic acid and rice or multi-enzyme, enzymes such as formic enzyme, ethanol, caprylic enzyme, octofermentation, 1, 6-hexanediol, 1, 9 one person Second leaven, ethylene glycol, 1,2-propanediol, neopentyl glycol, Thiodiethylene fermentation, diethylene fermentation, triethylene fermentation, pentaerythritol, ginseng (hydroxyethyl) isocyanurate, Ν, Ν 'bis (hydroxyethyl) oxaldiamine, 3-thiol Undecanol, 3-thiopentadecanol, trimethyl adipase, trimethylpropane and 4-hydroxymethyl-1-phosphorus-2,6,7-trioxabicyclo [2 · 2 · 2] octane Alkanes. 1. 15 β-(3,5-Dicyclohexyl-4-hydroxyphenyl) propionic acid ester with unit or polyol> Enzymes such as methanol, ethyl fermentation, capryl fermentation, stearyl fermentation, 1 , 6 — Hexanediol, 1, 9 Azelaine, Glycerolase, 1, 2 — Malonylase, Neoglutarase, Thioglycolyl Fermentation, Diethylene Glyceryl Fermentation, Triethylene Glyceryl Fermentation, Pentaerythritol , Ginseng (hydroxyethyl) isocyanurate, N, N bis (hydroxyethyl) glufosinate, 3- blind eleven, 3-salicylate, trimethyl adipase, trimethyl Propane and 4_hydroxymethyl-1_phospho-2,6,7-trioxabicyclo [2.2.2] octane. 1.16 (3,5-di-tertiary-butyl-4- Hydroxyphenyl) -2 9- The standard of this paper is applicable to China National Standard (CNS) Α4 specification (2 0〉 _ 29, mm) -------- ί.installed ------ ordered ---- It line (please read the precautions on the back before filling in this page) A7 B7 5. Invention Description (> Μ 1 1 I esterases of acetic acid and meat or polyhydric alcohols, for example, formic acid, ethyl fermentation, caprylic fermentation 1 1 1 »octadecyl alcohol« 1 6 — adipic fermentation 1 9 »1 1 Please 1 I 1 2 — Malonyl neopentyl glycol thiodiethylene glycol diethylene glycol» First Reading 1 I Read 1 Triethylene glycol 9 Pentaerythritol Ginseng (Hydroxyethyl) Isocyanide Urate N% back 1 & | N t a bis (hydroxyethyl) oxaldiamine 3 — sleep undecanol 3 monothiol | Italian I Pentadecyl trimethyl adipate trimethyl propane And 4 monohydroxymethyl — 1 matters 1 1 then 1 1 1 phosphorus — 2 6 7 — trioxabicyclo C 2 2 2] Xinyuan 0 fill 1 pack 1 1 7 β one (3 5 one two-two-level one-4-hydroxyphenyl page 1) propionate acetamide such as NN *-bis (3 5-two one two-1 1 butyl-4-hydroxybenzene Methacrylic acid) -JL-. Methylenediamine acid amides such as 1 1 NN, one bis (3 5 one- one-grade one butyl-4 monohydroxyphenyl 1 propylene) trimethylenediamine acid Acetylamines such as NN, a pair (3 1 I 5-two ~ tertiary-butyl-4-hydroxyphenylpropanol) hydrazine 0 1 1 1 1 8 ascorbic acid (vitamin C) 1 | 1 1 9 Amine antioxidants such as NN / one two one isophenylene diamine line »NN 〆 一 — _ two-level butyl one pair phenylene diamine NN — bis (1 4 — dimethylphenyl) one pair phenylene di Amine NN / — bis (1 1 1 — ethyl — 3 — methylphenyl) — p — phenylenediamine NN / — 1 | bis (1 — methylheptyl) — pair Phenylenediamine NN / — dicyclohexyl 1 1 pair one-phenylenediamine NN / — diphenyl — p-phenylenediamine 1 1 1 N 1 N * — double (2 — m group) pair One stupid diamine N — isopropyl 1 1 — N / — phenyl — p — phenylene diamine N — (1 3 — dimethylbutyl 1 I group) one N / — phenyl — p-phenylene di Amine N- (1 -Methylheptyl 1 1 I-30-1 1 1 The paper scale is applicable to the Chinese National Standard (CNS) A4 specification (; n〇> 29, mm) A 7 B7 V. Description of the invention (4)) —N'-phenyl pair of phenylenediamines, N, Ν '_dimethyl-N, Ν'_phenyl pair of phenylenediamines, 4_ (p-toluene sulfonamide) _ Diphenylamine, N, N, dimethyl-N, N'-di-secondary butyl-p-phenylenediamine, diphenylamine, N-allyldiphenylamine, 4-one Isopropoxydiphenylamine, N-phenyl-1-naphthylamine, N- (4-tertiary octylphenyl) -1-naphthylamine, N-phenyl-2-naphthylamine, Octylated diphenylamine, for example Ρ, Ρ'—di-tertiary octylphenylamine, 4-n-butylaminophenol, 4-butenylaminophenol | 4 mono-n-nonylaminophenol, 4-dodecylaminophenol , 4 octadecylaminoaminophenol, bis (4-methoxyphenyl) amine, 2, 6-di-tertiary butyl 4-dimethylaminomethylphenol · 2,4'- Diaminodiphenylmethane, 4,4 'diaminodiphenylamine, Ν, Ν, Ν', Ν'-tetramethyl-4,4 'diaminodiphenylmethane, 1 , 2-bis [(2-methylphenyl) amino] ethane, 1,2-bis (phenylamino) propane, (o-tolyl) biguanide, bis [4- — (1 /, 3 ′ — Dimethylbutyl) phenyl] amine, tertiary-octylated N-phenyl-1 mononaphthylamine, a mixture of mono- and dialkylated tertiary butyl / tertiary octyl dianiline , Mixture of mono-alkylated and di-inyl nonyl diphenylamine • mixture of mono- and di-alkylated dodecyl diphenylamine • mono- and di-alkylated isopropyl / isohexyl A mixture of diphenylamine, a mixture of monoalkylated and dialkylated tertiary butyldiphenylamine, 2, 3_ Hydrogen-3.3-dimethyl-4H-1,4-benzothiazine, phenothiazine> mixture of monoalkylated and dialkylated tributyl / tertiary octylphenothiazine, monoalkane Arylated and dialkyl tertiary octylphenothione-3 1- This paper scale is applicable to China National Standard (CNS) Α4 specification (210/2 mm) Round ———— ι—_ιι · η I — (Please read the / i matters on the back before filling out this page)

.IT line A7 B7 5. Mixture of invention description (> 8) · N-allyl phenoxypyrazine, N, N, N ', N'-tetraphenyl-1, 4-diaminobutane-2 — Alkene, Ν, Ν—bis (2,2,6,6-tetramethylmonosporidine-4-ylhexamethylenediamine, bis (2,2,6,6-tetramethyl shomine— 4-yl) sebacate, 2,2,6,6-tetramethyl succinimide 4-sin, 2,2,6,6-tetramethylbenzyl-4-enzyme. UV absorber and light stable Agent 2 • 1 2 — (2 »monohydroxyphenyl) benzotriazole» eg * 2 mono (2, monohydroxy one 5 t monomethylphenyl) benzodiazole t 2 mono (3 »» 5 t One two-two-butyl-2 t-hydroxyphenyl) benzotriazole 2-(5 body one three-butyl one 2 »-hydroxyphenyl) benzodiazole 1 2-(2 9 one Hydroxyl 5 > one (1 »1 3» 3 — tetramethylbutyl) phenyl) benzotriazole »2 one (3» one and two levels — butyl — 2 , — Hydroxy— 5 9 — methylphenyl) — 5 — atmosphere benzotriazole 2 — (3 * — secondary monobutyl-5, — secondary butyl-2 t — hydroxyphenyl) benzo Triazole 1 2 — (2, —hydroxyl 4 $ monooctyloxyphenyl) benzotriazole I 2 one (3 9 t 5 »— two secondary — pentyl — 2 9 monohydroxyphenyl) benzotri Azole, 2 — (3, $ 5 »one pair (a 9 α monomethyl benzyl) one 2 one -32- This paper scale is applicable to China National Standards (CNS) Α4 specifications (210 > 2 mm)- ------- install ------ order ----- Γ line (please read the precautions on the back before filling in this page) A7 B7 V. Description of the invention (4) Hydroxyphenyl) benzene Pyrogallazole; 2 — (3 J a tertiary monobutyl-2 ′ monohydroxy-5 ′ mono (2 octyloxycarbonylethyl) phenyl) — 5 — benzotriazole and 2 — (3 'One tertiary-butyl one 5'-[2-(2-ethylhexyloxy) carbonylethyl]-2 'one hydroxyphenyl)-5-benzotriazole Compound t 2 — (3 J — tertiary monobutyl-2′-hydroxy-5 ′-(2-methoxycarbonylethyl) phenyl) -5 chlorobenzotriazole; 2 — (3 ′ one Tertiary monobutyl-2'monohydroxy-5'mono (2-methoxycarbonylethyl) phenyl) benzotriazole; 2— (3-tertiary monobutyl-2'one quinone-5 ' — (2-octyloxycarbonylethyl) phenyl) benzotriazole; 2 — (3 —tertiary monobutyl-5 ′ — [2 — (2- ethylhexyloxy) carbonylethyl] -2 '-hydroxyphenyl) benzotriazole; 2-(3,-dodecyl-2'-hydroxy-5 '-methoxyphenyl) benzotriazole; and 2-(3,-tri Grade—Butyl-2′—Hydroxy-5 ′ — (2-Isooctyloxycarbonylethyl) phenylbenzotriazole; 2,2 ′ monomethyl bis [4-(1 · 1, 3 , 3-tetramethylbutyl) -6-benzotriazole-2-ylphenol]; 2-(3 'one tertiary one butyl one 5' one (2-methoxycarbonylethyl) one 2 '—Hydroxyphenyl] benzotriazole and polyethylene glycol 300 transesterification; -33- This paper size is applicable National Standards (CNS) A4 size (2 Shu 0 > 2W mm) (Please read the back of the Notes then fill out this tile) installed

, 1T line A7 B7 5. Description of the invention (;.) [R-C Η 2 C Η 2 -COO (C Η 2) 3] 2-, where R is 3, a tertiary butyl one 4, hydroxyl A 5'-2H-benzotriazole-2-ylphenyl. 2 · 2 2 -Hydroxydibenzyl such as its 4-hydroxyl * 4-methoxy, 4-octyloxy, 4-decyloxy, 4-dodecyloxy, 4-benzyloxy , 4,2 ', 4'-trihydroxy and 2'-hydroxy-4,4'-dimethoxy derivatives. 2 · 3 Unsubstituted or substituted esters of benzoic acid, for example, 4-tertiary-butyl-phenyl salicylate, phenyl salicylate, octylphenyl salicylate, diphenyl ether Resorcinol, bis (4-tertiary monobutyl benzoquinone) resorcinol, benzoquinone resorcinol, 2,4-dione tertiary-butylphenyl 3, 5-di-tris Grade-Butyl-4-hydroxybenzoate, cetyl 3, 5-di-tertiary monobutyl-4 monohydroxybenzoate, octadecyl 3, 5-dione-tertiary Butyl mono-4-hydroxybenzoate and 2-methyl-4,6-dione-tertiary monobutylphenyl 3,5-di-tertiary-butyl-4-hydroxybenzoate. 2 · 4 acrylates, such as ethyl and isooctyl α-cyano-Θ, / 3-diphenyl acrylate, methyl α-carbon methoxycinnamate, methyl and butyl α-cyano One-to-one methyl one-to-one methoxycinnamate, * methyl-α-carbon methoxy one-to-one methoxycinnamate and N — (jS — carbon methoxy one / 9 monocyanoethylene Group) a 2 methyl indole. 2 · 5 Nickel compounds, for example, 2,2 'monothio-bis [4- (1,1,3,3-tetramethylbutyl) phenol] nickel complexes, such as 1-3-4 The paper scale is applicable to the Chinese National Standard (CNS) A4 specification (2 丨 0> · 2mm) -------- 1-(please read the precautions on the back before filling this page), 1T line V. Description of the invention (: 1 or 1 such as n-butanedithioaminobenzyl phosphate, such as 2 to 4 lauryl. 2.6 pyridyl) decuccinate, diyl-3, 1 monohydroxy And tetramethyl succinate-2,6,2,6 (2,2,4_butanebis (3 *, 2,6,6,6 ylpiperidinyl: 2 ratio of complex amine 9 triethyl Enzymatic carbamate $ 4 — Nickel ester of sodium ester »— Hydroxy — 4 — Methyl — 5 — Hydroxyl hindered amine t For example > Diester» Double (2 I Double (1, 2 9 (1 I 2 ί 2 > 5 — di—secondary — ethyl — 2 9 2, the condensation product> N 4 — shodinyl) -X-. — Diamine— 1 t 3 9 6 one tetramethyl — > 6 »6 — Tetramethane Cool > 1 3 9 5, 5 — tetra 6 — tetramethyl shovel — tetramethyl shovelidine t) — 2 —— n-butyl 9 as required or N — cyclohexyl dihydroxy — 3 9 5 — Such as methyl or ethyl ester phenyl undecylimidyl compound m complex bis (2 > 2 »6 9 2 1 6 1 6 — 2 ref 6» 6 — 五 6 > 6 — 五甲4-Butyl-4-hydroxy 6 * 6-tetramethyl 9 N 9 bis (2 methylenediamine and 4-* 5-trihydropyridine 4-pyridyl) nitrogen-4-piperidinyl > 1, —— (1 methyl sulazine) 9 pyridine »4 CB stearic acid bis (1» 2 »2 base — 2 (2 — hydroxy- 3 5 _ outside ligand, such as zymamine, nickel di Butyl di-tertiary-butyl, oxime nickel complex keto oxime and 1-phenyl, with or without additional compound, 6-tetramethyl-n-tetramethylpiperidinyl) methyl succinimide) decane Piperidinyl) n-butylbenzyl malonate, —4 monohydroxypiperidine, 2,6,6 — tertiary monooctylamine synthesis product, ginseng (2-yl triacetate • tetra ) -1-2-3 2 —ethanediyl) 4 _benzyl-2-yloxy-2,2 * 6, 6-pentamethyl-3, 5--2 (please read the notes on the back first (Fill in this page again) This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (2 丨 0> 29, mm) 303380 V. Invention description (A7 B7 SI installed (please read the precautions on the back before filling in this Page) — tertiary-benzyl) malonate, 3-n-octyl-7,7,9,9-tetramethyl-1,3,8-triazine helix [4,5] decane-one 2, 4, a di-heir, bis (1-octyloxy-2, 2.6, 6-tetramethyl linyl pyridyl) sebacate • bis (1-octyloxy-2, 2, 2 , 6, 6-tetramethylpiperidinyl) succinate, N, N 'a bis (2, 2, 6, 6, 6-tetramethyl- 4- quinolinyl) hexamethylenediamine and 4-morpholine Condensation products of 2-, 6-diamine-1,3,5-triazine, 2-chloro-4,6-bis (4-n-n-butylamino-2,2,6,6_tetramethyl Succinyl) -1,3,5-triazine and 1,2-bis (3.11-aminopropylamino) ethane condensation product, 2 -Atmosphere—4,6-di (4-n-butylamino, 2,2,6,6-tetramethyldynyl)-1,3,5-triazine and 1,2-bis (3 —Aminopropylamino) The condensation product of ethane, 8_ethanyl-3-dodecyl-7,7,9,9-tetramethyl-1,3,8-triazine spin [ 4 · 5] decane-line-2,4_ disi, 3_dodecyl-1- (2,2,6,6 —tetramethyl_4_shodinyl) pyrrolidine-2,5_dione And 3-dodecyl_1 one (1, 2, 2, 6, 6, pentamethyl-4 butane)

Ift pyrrolidine one 2,5-two heirs. 2 · 7 oxalamine, for example * 4,4'-dioctyloxyglutanilide, 2, -diethoxyglutanilide, 2,2'-dioctyloxy-5,5 * -Di-tertiary monobutyl glufosinate, 2,2'-di-dodecyloxy-5,5 'di-tertiary-butyl glufosinate, 2-ethoxy- 2 'Ethyl-pyridaniline, N, Ν'--36- The standard of this paper is applicable to China National Standard (CNS) Α4 specification (210 '/ 29, mm) A7 B7

V. Description of the invention 1 1 I bis (3-dimethylaminopropyl) oxanilide 2 — ethoxy — 5 1 1 1 1st and 2nd level one butyl — 2 9 — ethyl oxanilide and It is a pre-M 1 I reading mixture with 2-ethoxy 1 I, I 1-2,-ethyl mono 5 4 *-bis-tertiary-butyl oxalidine, λ, and o, p-a Oxygen — mixtures and o-, p-ethoxyl groups 1 ιέ I One-two substituted oxalose aniline mixture 0 Note | Meaning I 2 8 2 mono (2 monohydroxyphenyl) mono 1 3 5 — azine Example 1 I again | one i such as 2 4 6 — ginseng (2 — hydroxy — 4 octyloxyphenyl) one 1 fill 1 pack »3 5 — triazine 2 one (2 one hydroxy — 4 — octyloxy Phenyl) 1 | — 4 6 — double (2 4 one two Methylphenyl) mono 1 3 5 — di 1 1 azine 2 mono (2 4 monodihydroxyphenyl) — 4 6 — bis (2 4 1 1 — dimethylphenyl) mono 1 3 5 monodiazine 2 4 _ bis (2 _ 1 hydroxy-4-propyloxyphenyl)-6 (2 4-dimethylphenyl) 1-1 3 5-diazine 2-(2-hydroxy-4-octyl Oxybenzene 1 1 group) — 4 6 a bis (4-methylphenyl) — 1 3 5 monotriazine I t 2 one (2 monohydroxy one 4 one dodecyloxyphenyl) one 4 6 one Double wire (2 4 -dimethylphenyl) — 1 3 5 — triazine 9 2 — C 2 — hydroxy — 4 — (2 monohydroxy — 3 — butyloxypropylaminophenyl) 4 1 f 6 — Bis (2 4 dimethylphenyl) — 1 3 5 monotriazine 1 1 2 — C 2 — hydroxy — 4 mono (2 monohydroxy — 3 — octyloxypropoxybenzene 1 I group) — 4 6 — bis (2 4 — dimethylphenyl) — 1 t 3 5 1 1 — three And 2-C 4 — dodecyl / tridecyloxy (2-hydroxypropyl 1 1) oxy-2-hydroxyphenyl] — 4 6 a bis (2 4 dimethylbenzene 1 I group) — 1 3 5 Monodiazine 〇1 I-37-1 1 I This paper scale is applicable to China National Standard (CNS) A4 specification (210 &29; mm) A7-______B7_________ 5. Description of invention () 3 Active agent, such as N.N, diphenyl oxalate diacetamide, N-salicylic acid-n, monosalicylic acid, N, N, a double (water-sowing) hydrazine, N, N, a double ( 3,5-di-tert-butyl-4 hydroxyphenylpropionyl) hydrazine, 3-salicylic amine 1,2,4-triazine, bis (benzyl fork) oxalic acid bishydrazine, grass Acetanilide, isopeptidic acid hydrazide, sebacic acid bis-phenyl hydrazine, N, N, diethyleneglycol adipic acid hydrazide, N, N 'a pair of salicylic acid oxalate dihydrazine, and N, N, a pair of dihydrated thiopropionic acid dihydrazine. 4 · Phosphite and phosphonates, such as triphenyl phosphite, diphenyl alkyl phosphite, phenyl dialkyl phosphite, ginseng (nonylphenyl) phosphinate Lauryl phosphite, ginsyl octadecyl phosphite _, distearate pentaerythritol diphosphoric acid ester. Ginseng (2, 4_ di-t-butylphenyl) phosphinic acid _ Isodecyl pentaerythritol diphosphite, bis (2,4 one two one special one butylphenyl) pentaerythritol diphosphite _ • bis (2,6 one two-special one butyl_4 Monomethylphenyl) pentaerythritol diphosphite, bis-isodecyloxypentaerythritol diphosphite, bis (2,4 one two one special-butyl one 6-methylphenyl) Pentaerythritol diacid "acid ester, bis (2, 4, 6-ginseng-tert-butylphenyl) pentaerythritol diphosphite _, tristearate sorbitan triphosphorylase, four double ( 2,4_di-tert-butylphenyl) 4,4'_diphenylene diphosphite, 6-isooctyloxy-2, 4 · 8 * 10—tetra-tert-butyl- 12H —Diphenyl 〔d · g〕 —1, 3, 2—Phosphocin and 6—Gas—2, 4, 8, 10—Four Tert-Butyl-12 — Methyldiphenyl [d, g] 1 -3 8 _ The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 >, 29 ”mm) ----- ---- installed ------ ordered ----- line L (please read the precautions on the back before filling in this page) A7 B7 5. Description of the invention (, 3, 2-two voice phosphocin, double ( 2,4-Di-tert-butyl-6-methylphenyl) methyl phosphite and bis (2,4-di-tert-butyl monomethylphenyl) ethyl phosphite. (Please Read the precautions on the back first and then fill out this page) Binding line-39 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210 > '29? Mm) 303380 V. Invention description (") A7 B7 ---- ----- 二 衣 ---- ^ --- ΪΤ ------ ^ (Please read the precautions on the back before filling in this page) 5 · Hydroxyamine, for example, derived from hydrogenated tallamine N, N-dibenzylhydroxylamine, N, N-diethylhydroxylamine, N, N-dioctylhydroxylamine, N, N-dilaurylhydroxylamine, N, N-ditetradecylhydroxyl Amine, N, N — hexadecyl hydroxyamine, N, N — octacosyl amine, N — Hexadecyl-N-octadecyl-controlled amine * N-deca-tyl-N-octadecylhydroxylamine, N, N-dialkylhydroxylamine. 6 · Nitrate, for example N-benzyl-α —Phenyl nitrate, N — -40- The paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (210 > '29 -mm) A7 B7 V. Description of invention () 1 1 I ethyla Nitrate S »Ν — octyl-α — heptyl nitrate m N 1 1 1 — lauryl — a — decyl nitrate m 9 N — tetradecyl-α — tridecyl 1 I please 1 | Nitrate N — Ten base one α 15 base nitric acid m > N 18 base one first reading 1 I α 17 base nitric acid m N —— ten base _ α 17 base nitric acid m 9 N Read back 1 1 &; I octadecyl-α-pentadecyl nitrate S, N 17-yl-α- hexadecyl Note I meaning I 1 nitrate N octadecyl-α-decyl nitrate-derived i Proper thing Item 1 IA 1 ^ N of Nylamine • Ν—dialkylhydroxylamine nitrate. Fill in I 7 phobic synergists such as dilauryl thiopropionic acid _ or distearyl sulfide write this page 1 generation 2 Propionate 0 1 1 8 Breaking through peroxide compounds such as β-thiopropionate such as laurel 1 I lauryl stearic acid m myristyl or tridecyl m hydrogen benzimid 1 oxazole 2 Zinc salt of dihydrobenzobenzyl dibutyldithiocarbamate 1 Zinc »Di-octadecyl disulfide and pentaerythritol four bis (β-dodecane 1 1 ylthio Base) Propionate 〇I 9 ♦ Polyacetamide stabilizers such as m salt and iodide and / or m compound and t-line divalent magnesium for abdominal use 〇1 0 * Basic co-stabilizers such as melamine m amine 9 Polyethylene Itt Pyridine_ 1 1 t dicyandiacetamide 9 triallyl cyanate 9 urea derivatives > hydrazine derivatives • 1 I amine 9 polyacetamide polycarbamic acid m higher gold fatty acid m Jin Yi salt and 1 I m soil Gold salt f, such as calcium stearate 9 ΧΒΛ flx zinc stearate 9 magnesium behenate stearate 1 1 magnesium fate sodium grate 1 brown potassium potassium salt »Titanium pyrocateate or cyanide *>% Catecholic acid 1 1 Cadmium 〇1 1 1 1 • Nucleating agent »For example, non-degradable substances such as m stone powder t Jingong oxide * • 1 |-4 1 1 1 1 This paper size is applicable to China National Standard (CNS) A4 Specifications (210 y 297 mm) A7 B7 V. Description of the invention () 1 1 I For example, dioxins or magnesium oxides are preferably phosphates of carbonic acid 1 1 1 or organic compounds such as monohydrate. Carboxylic acids and polycarboxylic acids and their salts such as 4 1 I please 1 I — special monobutyl benzoate adipic acid and di Phenylester acid 9 Polymer compounds such as the first reading 1 I Ionic Ά polymer (ion single) 〇 Read back 1 | 1 2 Additives and reinforcing agents such as calcium carbonate silicate glass m Viton | 'Italian I 9 glass ball asbestos Talc powder kaolinite barium phoshate barium gold concessions 1 I reoxide and & oxygen Λ substance carbon black • Graphite wood powder or other natural products Continue to fill out this I Packing and synthesis m Dimension 0 Page 1 1 1 3 Other additives such as Plasticizer slip agent 9 emulsifier pigment 1 1 rheological additive catalyst flow control m optical brightener flame retardant t 1 1 antistatic agent and foaming agent 0 1 order 1 4 benzodiazepine and indole Siru US-A — 4 3 2 5 8 6 1 | 3 US—A — 4 3 3 8 2 4 4 > US — A — 5 1 7 5 3 1 1 1 3 US — A — 5 2 1 6 0 5 2 U S — A — 5 2 5 2 1 6 4 3 DE — A — 4 3 1 6 6 1 1, D — A — 4 3 1 6 wire 6 2 2 DE — A — 4 3 1 6 8 7 6 DE — A 0 5 8 9 I 8 3 9 or EP — A — 0 5 9 1 1 0 2 I or 3 — C 4 — (2 1 1 monoethylacetoxyethoxy) phenyl] — 5 f 7 — di— Tertiary monobutylbenzene 1 1 benzofuran 2 1 m 5 »7 — bis — tertiary — butyl mono 3 — C 4 — 1 1 (2 — stearyl ethoxy) phenyl] benzofuran One 2 one m 3 f 1 1 I 3 / — double C 5 7 one two-tertiary monobutyl-3 one (4 — C 2 — 1 1 hydroxyethoxy) phenyl 3 — 5 7 — — «- One and three grades-butyl benzofuran 1 1 one 2 one ketone 5 7 one-three grades-butyl 3-(4-ethoxy II 42-1 1 This paper wave scale is applicable to China National Standard (CNS) A4 specifications (210 >. 297 Gong Dong) A7 ___B7_ V. Description of the invention (π) Phenyl] mono 5,7-di-tertiary_butylbenzofuran-2-one 3 — (4 —Ethylamino-3,5-dimethylphenyl) -5,7-di-tertiary-butyl-benzofuran-2-lanthanum, 3- (3,5-dimethyl Yl_4 a tert-pentyloxyphenyl), 7-two one three tertiary butyl benzofuran one two-heir. The compounds of the present invention can also be used as stabilizers, especially as photo stabilizers for most of the materials used in photographic reproduction and other reproduction techniques * such as Research D isc 1 〇sure 1 9 9 0, 3 1 4 2 9 (4 7 4 to 4 8 0 pages). Many examples M of preparation and application of compounds of formula (I) are provided to illustrate the invention in more detail; these examples are intended to illustrate and are not intended to constitute any limitations. Example 1: Preparation of polysiloxane of the following formula ch3 H3C- Si- ch3

CH 3 ch3 \ CH3 O-Si-l

• Ο-Si- CH 3 26 / CH, 27 ----- 1 ------ ^ ------ 1T ------. ^ (Please read the notes on the back before filling in this page)

HgC ^ — N "

-0-Si—— (CH2) 3 0 1 N ^ N 、 n-c4h9

6 yl, pyridine 4 piper 1 -yl 4 gas monopropylene-penta 2 f of 6 \ 17 »ear 6 Mo, 0 2 8 丨. 2 7, 7 1 / V / | g f 5 N • rL 4 Bis-I 4 I aminobutanedimethionone ο 5 Yurongzhao triazine-5 3 3 4 1 _ This recording size is applicable to China National Standards (CNS) A4 specifications (2i〇 >, 29, Gongguang )

A7 B7 Fifth, invention description U. ) Base * Add 2 gram of dichlorinated platinum (styrene). This solution was heated to 1 40Ό, and with stirring, 10 g (3 mmol) of trimethylsilane-terminated polymethylhydrosiloxane (containing 53 S i — Η units) at 1 50 μl were slowly added The solution formed in xylene. The reaction was maintained at 1 40 ^ 0 for 3 hours, cooled to 70¾, and stirred at the same time. Add 15 g (133 · 9 mmol) of 1-octane, and add 2 g of PtCl2 (styrene) 2. The mixture was heated at 100 ton: stirred for 6 hours, the solvent and excess 1-octane were evaporated in vacuo (140C / 0.1 mbar). A white solid was obtained with a melting point of 75-79¾. NMR and IR analysis confirmed the expected structure. Example 2: Preparation of polymethylsiloxane

H3i H3 c-si-c 3C · H CH,

-0-Si—— (CH2) 3 NH I N ^ N 26 H9C4 — N 、 N-c4H9

ΝΙΗ N 丨 Η

Using a procedure similar to Example 1, 43 · 2g (77 · 7 奄 Mo-44- this paper music standard is applicable to the Chinese National Standard (CNS) A4 specification (2! 0 '/ 297mm) -------- i I 士 l ------ 丁 _____-__ > ^ -r (please read the precautions on the back and then fill in this page) Α7 Β7 Fifth, the description of invention (W) ear) 2-allyl Amino group 4,6—Double 〔N — (1, 2, 2 ---- 丨 -1--1--1 _ installed; ------ order ----— 1 line i (please read first Note on the back and then fill in this page), 6,6-pentamethyl-4-imidimidyl) butylamino] -1,3,5-triazine and 10 grams of trimethylsilane-terminated polymethyl Hydrogen siloxane (containing 53S i — Η units) and 15 grams (133 · 9 millimoles) of 10 octane were reacted in 4 mg of PtCl2 (styrene) 2 (in xylene). Evaporate the solvent and excess 1-octane in a vacuum (140C / 0 · 1 mbar) to obtain a solid with a viscosity of 1 10-1 15υ. NMR and IR analysis confirmed the expected structure. Example 3: Preparation of polymethylsiloxane

Using a procedure similar to Example 1, 45 · 5 grams (77 · 8 millimoles) of 2-allylamino-4,6-bis [N_ (1,2,2,6,6-tetramethyl-one 4_piperidinyl) butylamino] _1,3,5-triazine and 10 g (3 mol) trimethylsilane-terminated polymethyl-45- This paper scale is applicable to the Chinese National Standard (CNS ) A4 specification (210> '297mm) ............................................. ............................... A 7 303380_B7_ V. Description of the invention (衿) Based on siloxane (containing 53Si-H units) and 15 grams (133.9 mol) of 10 octane reacted in 4¾ grams of PtCl2 (styrene) 2 (in xylene). The solvent and excess 1-octane were evaporated in vacuo (140Ό / 0 · 1mbar) to obtain a solid with a melt viscosity of 90-95t :. NMR and IR analysis confirmed the expected structure. Example 4: Preparation of polymethylsiloxane of the following formula ch3 \ ch3 O-Si-l * 0-Si-CH3 ^ 8 ^ * 17 I CH3 / 27 (please read the precautions on the back before filling this page) ch3 -O-Si- CH3 H3C- Si— ch3

(CHa) 3 NH 26

H9C4 N-c4Hg

Using a procedure similar to Example 1, 43 · 4 g (77 · 8 ammol) of 2-propoxy-4,6-bis [N-(1,2,2 1 6,6-pentamethyl one 4 monopiperidinyl) butylamino] 1,3,5 monotriazine and 10 g (3¾ mol) of trimethylsilane-terminated polymethylhydrogensiloxane (containing 53Si-Η units) and 15 grams (133 · 9 mols) of 10 octane at 4 grams of PtClz (styrene) 2 (-4 6-This paper wave scale is applicable to the Chinese National Standard (CNS) A4 specification (210X29 ”mm). Description of the invention () A7 B7-in toluene) reaction. In Xingkong (140 = / 0.1 mbar) to evaporate the solvent and excess 1-octane to obtain melting point 94-98 its solid ». NMR and IR analysis confirmed the expected structure. Example 5: Light stabilization effect on polypropylene fiber 2.5 g of each compound listed in Table 1, 1 g of ginseng (2,4-di-tertiary butylphenyl) Phosphate phosphate, 0. 5 grams of military ethyl 3 5_di-one tertiary butyl 4-hydroxybenzylphosphonate calcium ethyl ft, 1 gram of calcium stearate and 2.5 grams of dioxide in one Melting index with 1 000 g in slow mixer A polypropylene powder of 12 g / 10 min shovel (measured at 230 t: and 2.16 kg) was mixed. The mixture was extruded at 200 0-2 3 0 to obtain polymer particles * and then a pilot-type device (® Leonard- SuBirago (va) It; aly) The conditions are as follows: Fuck -------- install-- (please read the precautions on the back before filling this page)

, 1T 瘅 出 温 头 Temperature extraction rate linear density 200-230t! 255-260C 1: 3 · 5 The military position is hidden for 1 1 dte The fiber prepared is placed on the plate and exposed to 65WR Weather-O-Meter ( AS TM D25 6 5-85), its blackboard (blac1 panel) temperature is 63. The residual toughness is measured after the sample is exposed to light (constant speed langometer) several times, and the calculated exposure time to reach the initial toughness is hours (Ts 0). -47- The paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (210 > 297 public signature). Line V. Description of the invention (called A7 B7. For comparison and comparison, prepared under the same conditions as above without adding the stabilizer of the invention The fibers are also exposed. Table 1 shows the results obtained. Table 1: Stabilizer without stabilizer Example 1 Compound Example 2 Compound T 5 0 15 0 2 5 4 0 2 6 8 0 hours) -----: ----— install-- (please read the precautions on the back of this page before filling in this page) Binding line 48- The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 > '2F mm)

Claims (1)

• '" • Report 8 8 88 ABCD ° β ra 2 · 5 · QO- positive Six, patent application scope 0 to 90% of n ch3 ch3 • Ο — Si— A CH3 -O — Si-CH3 I ch3 ⑴ (Please read the precautions on the back before filling this page) Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy. X is -0—or—NH—; Ri is hydrogen, (Ci—CiS) alkyl or (II) group (Π) C i 8) alkyl. 2. For example, the compound of formula I in item 1 of the patent application park, wherein Rz is radium or (C i-C 4) alkyl. 3. A compound of formula I as described in item 1 of the patent application plaque, wherein Rz is hydrogen or methyl. 4 · For example, the compound of formula I in item 1 of the patent application park, where -1-the paper size is in accordance with the Chinese National Standard (CNS) A4 specification (· 210Χ297mm) A8 B8 C8 D8 VII. Patent application range m + n Is 1 to 90, η is 0 to 90% of the number of m + n; X is a 0 — or a NH —; Rt is hydrogen, (Ci — ClZ) alkyl or group (II); and A is ( C6-C12) alkyl. 5. A compound of formula I as claimed in item 1 of the patent scope, wherein m + n is 1 to 80, η is 0 to 90% of m tens η 缌; X is _0_ or-ΝΗ- ·; R! Is hydrogen , (Ci—Cs) alkyl, or group of formula (II); and A is (C8 — Ci 2) alkyl. 6. The compound of formula I as claimed in item 1 of the patent scope, wherein m + n is 1 to 70, η is 0 to 90% of the total number of m + n; X is a 0—or a NH—; Rt is hydrogen, ( Ci — C4) alkyl group (II) group; and A is (Ca — Ci 2) alkyl group. (Please read the matters on the back of this page before filling in this I). Printed by the Ministry of Economic Affairs, Central Bureau of Accreditation and Printing of the Consumer Industry Cooperative 7. If the compound of formula I in item 1 of the patent application contains the following formula The size of this paper is easy to use China National Standard (CNS) A4 specification (210 X 297 mm). Patent application scope 3 I 3 H .'- H c Is —c-C3 H Η3Ϊ—Η3 CS—C c · H3 H3IH3 c -S 丨 c 3C · H A8 B8 C8 D8 ch3 • O-Si-i (CH2) 3 I 〇 26 N ^ N H9C4-N n-c4h9 N1H N1H-〒η3 Bu 0-Si-CH3, 'ch3 27: *-n-II---11 ..--1 ------ ----1 :: »---I -I—., J ^ i (Please read the precautions on the back before filling in this page) CH 3 H3 .O-Si- I (CH2) 3 NH 26 l \ o H cl—silca CH〇! 3 -〇 -Si— CH3 I ch3 27 Central Bureau of Standards of the Ministry of Economic Affairs for the printing of industrial and consumer cooperation N ^ N H9C4 n-c4h9 This paper uses the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 303380 A8 B8 C8 D8 6. Patent application scope CH. I 3 • Si- CH, o clalc H 5 2 H 12 Η C 3-3 H.iHc Is 1C Iο 27 CH, H3C—Si- CH, CH, H3C— Si_ CH, CH. I -O-Si- (? h2) 3 NH \\ os 2 H 2 Q 丨 C1 CH · (please read the notes on the back before filling this page) o 27 Ηc I H3-silc N ^ N 26 -a Printed by the Industrial and Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs h9c CH, CH 3 This paper uses the Chinese National Standard (CNS) A4 format (210 X 297 mm) J o CHlaIcc 7 H1 o 4 Hc H3 I h3 ol ^ —c A8 B8 C8 D8 VI. Application for Patent Scope Central Standards Bureau of the Ministry of Economy Printed by the consumer labor cooperative -5 (Please read the precautions on the back before filling in this page). -1T J This paper size is applicable to China National Standards (CNS) A4 see grid (210X297mm) 303380 A8 B8 C8 D8 Patent scope CH, H ^ C— Si-I CH. CH3v CH3 H3C —Ν 'ch3 ch3 CH CH 3 CH. 3 I CH3 ch3 〇_Si-I (ch2) 3 〇 N < ^ N 26 CH.I · 〇— Si— I ^ 12 ^ 25 CH, -o-Lch CH. 3 ch3 ch3 N—CK CH3 CH3 27 CH ch3 CH, ChU CH, Hd〇—- Si • O — Si · I (ch2 ) 3 NH 26 — ·· — 卜-^ —— r—Subscribe (please read the notes on the back before filling in this page) Printed by the Ministry of Economic Affairs, Central Standards Bureau, Yougong Consumer Cooperatives N 丄 N Km This paper uses the Chinese National Standard (CNS) A4 specification (210Χ297mm) 303380 A8 B8 C8 D8 々, patent application scope 8 · For example, apply for the compound of formula I in item 1 of the patent park, where m + n is 1 to 60, η is 0 to 90% of the total number of m + n; X is a-or a NH-; R! Is hydrogen, (CX-C4) alkyl group (II) group; and A is (C8- Ci 2) alkyl. 9. A stabilized composition including a polymer M that is susceptible to degradation due to light, heat, or oxidation, and 0.01 to 5% by weight (relative to the weight of the polymer) of the patent application, item 1 Of formula I. 1 0. The composition as claimed in item 9 of the patent application, wherein the polymer is poly-ethylene or polypropylene. --.--, --- Bu --- 1. Installed ------ ordered -----.- 1: --- 1 (please read the notes on the back before filling this page) Economy Printed by the Consumer Labor Cooperative of the Central Standards Bureau of the Ministry of Education_This paper wave scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm)