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TW202603071A - Heat-resistant liquid crystal polymer film - Google Patents

Heat-resistant liquid crystal polymer film

Info

Publication number
TW202603071A
TW202603071A TW113126025A TW113126025A TW202603071A TW 202603071 A TW202603071 A TW 202603071A TW 113126025 A TW113126025 A TW 113126025A TW 113126025 A TW113126025 A TW 113126025A TW 202603071 A TW202603071 A TW 202603071A
Authority
TW
Taiwan
Prior art keywords
liquid crystal
crystal polymer
heat
polymer film
resistant liquid
Prior art date
Application number
TW113126025A
Other languages
Chinese (zh)
Other versions
TWI892749B (en
Inventor
蔡承成
謝佳勳
何宜學
Original Assignee
達邁科技股份有限公司
Filing date
Publication date
Application filed by 達邁科技股份有限公司 filed Critical 達邁科技股份有限公司
Priority to TW113126025A priority Critical patent/TWI892749B/en
Priority claimed from TW113126025A external-priority patent/TWI892749B/en
Application granted granted Critical
Publication of TWI892749B publication Critical patent/TWI892749B/en
Publication of TW202603071A publication Critical patent/TW202603071A/en

Links

Abstract

本發明耐熱型液晶高分子膜,其包括有一可溶型液晶高分子,其占該耐熱型液晶高分子膜之15~75wt%;一不可溶型液晶高分子,其占該耐熱型液晶高分子膜之15~75wt%;及一聚醯亞胺,其係由二酸酐及二胺組成,其占該耐熱型液晶高分子膜10~50wt%,且該聚醯亞胺之玻璃轉化溫度(Tg)大於250℃,其中,該耐熱型液晶高分子膜之吸濕性小於0.5%、在頻率10GHz、濕度為65%RH條件下,該耐熱型液晶高分子膜之介電損耗(Df)小於0.005;又在50~200℃之條件下,該耐熱型液晶高分子膜之線性熱膨脹係數(CTE)小於20ppm/℃;在310℃條件下,該耐熱型液晶高分子膜之儲存模數(E’)大於0.2Gpa;以該耐熱型液晶高分子膜之玻璃轉化溫度(Tg)大於220℃。The present invention comprises a heat-resistant liquid crystal polymer film, comprising a soluble liquid crystal polymer comprising 15-75 wt% of the heat-resistant liquid crystal polymer film; an insoluble liquid crystal polymer comprising 15-75 wt% of the heat-resistant liquid crystal polymer film; and a polyimide composed of dianhydride and diamine comprising 10-50 wt% of the heat-resistant liquid crystal polymer film, wherein the glass transition temperature (Tg) of the polyimide is greater than 250°C, and the hygroscopicity of the heat-resistant liquid crystal polymer film is less than... The dielectric loss (Df) of the heat-resistant liquid crystal polymer film is less than 0.005 under the conditions of 10 GHz frequency and 65% RH humidity; the linear thermal expansion coefficient (CTE) of the heat-resistant liquid crystal polymer film is less than 20 ppm/℃ under the conditions of 50~200℃; the storage modulus (E’) of the heat-resistant liquid crystal polymer film is greater than 0.2 Gpa under the conditions of 310℃; and the glass transition temperature (Tg) of the heat-resistant liquid crystal polymer film is greater than 220℃.

TW113126025A 2024-07-11 2024-07-11 Heat-resistant liquid crystal polymer film TWI892749B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
TW113126025A TWI892749B (en) 2024-07-11 2024-07-11 Heat-resistant liquid crystal polymer film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
TW113126025A TWI892749B (en) 2024-07-11 2024-07-11 Heat-resistant liquid crystal polymer film

Publications (2)

Publication Number Publication Date
TWI892749B TWI892749B (en) 2025-08-01
TW202603071A true TW202603071A (en) 2026-01-16

Family

ID=97523911

Family Applications (1)

Application Number Title Priority Date Filing Date
TW113126025A TWI892749B (en) 2024-07-11 2024-07-11 Heat-resistant liquid crystal polymer film

Country Status (1)

Country Link
TW (1) TWI892749B (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI650358B (en) * 2017-09-14 2019-02-11 佳勝科技股份有限公司 Liquid crystal polymer composition and high frequency composite substrate
CN119875271A (en) * 2020-06-12 2025-04-25 日铁化学材料株式会社 Resin composition, resin film, metal-clad laminate, and printed wiring board

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