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TW202136526A - Resourcezation method for stabilized reducing slag including mixing stabilized reducing slag, a powder material, an alkaline reagent and water into a mixture - Google Patents

Resourcezation method for stabilized reducing slag including mixing stabilized reducing slag, a powder material, an alkaline reagent and water into a mixture Download PDF

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TW202136526A
TW202136526A TW109110676A TW109110676A TW202136526A TW 202136526 A TW202136526 A TW 202136526A TW 109110676 A TW109110676 A TW 109110676A TW 109110676 A TW109110676 A TW 109110676A TW 202136526 A TW202136526 A TW 202136526A
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ballast
stabilized
water
powder
mixture
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TW109110676A
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TWI708849B (en
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李銘智
賴鴻毅
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金瑲水泥製品股份有限公司
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies

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Abstract

This invention provides a method for converting stabilized reducing slag from an electric arc furnace into renewable resource, which includes the following steps: (A) material preparing step: preparing stabilized reducing slag, a powder material, an alkaline reagent, and water; (B) mixing step: mixing the stabilized reducing slag, the powder material, the alkaline reagent and the water into a mixture; and (C) curing step: subjecting the mixture to a curing reaction under normal pressure and at the temperature of 35 DEG C to 100 DEG C to accelerate a Pozzolanic reaction to form a calcium-silicon compound, a calcium-aluminum compound, and/or tobermorite. By using the method, the stabilized reducing slag which is originally difficult to stabilize can be converted into a material with an economic value within a short period of time, the elimination degree and use approach of the stabilized reducing slag are improved, thereby reducing the steel making cost.

Description

安定化之還原碴的資源化方法Recycling method of stabilized ballast

本發明係關於一種電弧爐爐碴處理方法。具體而言,本發明係關於一種電弧爐爐碴的資源化處理方法。The invention relates to an electric arc furnace ballast treatment method. Specifically, the present invention relates to a resource treatment method of electric arc furnace slag.

鋼鐵工業為我國極重要之基礎工業,其關聯產業十分廣泛,各鋼鐵廠每年產生之爐碴高達一百多萬噸,若不加以合理利用,僅將爐碴儲存會造成儲置空間的問題,也會造成環境污染。The iron and steel industry is a very important basic industry in China, and its related industries are very extensive. The iron and steel plants produce more than one million tons of slag each year. If they are not used rationally, simply storing the slag will cause storage space problems. It will also cause environmental pollution.

電弧爐煉鋼的冶煉過程依其化學反應分成三個階段,分別為熔解期、氧化期及還原期。電弧爐煉鋼爐碴即是由此煉鋼過程所排出的熔碴,依照出碴時期不同,可分為氧化碴及還原碴。氧化碴含鐡量高、質地堅硬比重大,為物理化學性質安定的黑褐色塊狀物。未安定化之還原碴中的鐵含量少但氧化鈣及氧化鎂含量多,呈灰褐色的粉狀或塊狀。由於還原碴含游離石灰(f-CaO),其遇水膨脹易崩解,故還原碴除了用於水泥製程中的原料之外,因體積穩定性不佳的緣故並無有效的去化途徑,必須使還原碴安定化後才能安全地使用。而安定化後的還原碴呈粉末狀且含水量高難以有效使用,大量的堆存將降低還原碴安定化製程產能並間接影響煉鋼廠的產能及成本。The smelting process of electric arc furnace steelmaking is divided into three stages according to its chemical reaction, namely the melting period, the oxidation period and the reduction period. The electric arc furnace steelmaking ballast is the molten ballast discharged from the steelmaking process. According to the time of the ballast production, it can be divided into oxidation ballast and reduction ballast. The oxidation ballast has a high content of iron, a hard texture and a high specific gravity. It is a dark brown block with stable physical and chemical properties. The unstabilized reduced ballast contains less iron but more calcium oxide and magnesium oxide, which is gray-brown powder or lump. Since the reduced ballast contains free lime (f-CaO), it swells and disintegrates easily when exposed to water. Therefore, apart from being used as a raw material in the cement process, the reduced ballast has no effective way to remove it due to poor volume stability. The reduction ballast must be stabilized before it can be used safely. The stabilized reduced ballast is in powder form and has a high water content, which is difficult to use effectively. A large amount of storage will reduce the production capacity of the stabilized reducing ballast process and indirectly affect the production capacity and cost of the steel plant.

國內公共工程及營建業每年對混凝土粒料有十分龐大的需求,其中的溝管工程如污水下水道、自來水管、天然氣管線等工程需大量的控制性低強度材料(Controlled Low-Strength Material,簡稱CLSM)。CLSM中的粒料可採用再生粒料及工業副產物替代天然粒料,由於各電弧爐煉鋼廠每年煉鋼產生的還原碴數量龐大,在臺灣天然資源十分有限的情況下,若能將上述還原碴利用以替代珍貴的天然資源,將能確保資源的永續存在。安定化的還原碴內含豐富的氫氧化鈣,氫氧化鈣與含矽材料或含鋁材料產生卜作嵐反應,但在常溫下需至少一至兩個月才有比較明顯的反應成果,若以此作法來製作人工粒料或預鑄製品,在工業製程上並不具經濟效益。因此,極需發展一種能加速卜作嵐反應、並在短時間內將大量安定化的還原碴轉化為具使用價值的再生資源之方法。Domestic public works and construction industries have a huge demand for concrete pellets every year. Among them, trench pipe projects such as sewage sewers, water pipes, natural gas pipelines and other projects require a large amount of Controlled Low-Strength Material (CLSM for short) ). The pellets in CLSM can be recycled pellets and industrial by-products instead of natural pellets. Due to the huge amount of reduced ballast produced by each electric arc furnace steelmaking plant every year, Taiwan’s natural resources are very limited. The use of ballast to replace precious natural resources will ensure the sustainable existence of resources. The stabilized reducing ballast is rich in calcium hydroxide. Calcium hydroxide reacts with silicon-containing materials or aluminum-containing materials. However, it takes at least one to two months at room temperature to have a more obvious reaction result. If this is done It is not economical to produce artificial pellets or 預鑄 products in the industrial process. Therefore, there is a great need to develop a method that can accelerate the reaction of Bu Zuolan and convert a large amount of stabilized reducing ballast into a renewable resource with use value in a short time.

為解決上述問題,本發明之目的在於開發一種能在短時間內將大量安定化的還原碴轉化為再生資源的方法。In order to solve the above-mentioned problems, the purpose of the present invention is to develop a method that can convert a large amount of stabilized reducing ballast into renewable resources in a short time.

為達成前述目的,本發明提供一種安定化之還原碴的資源化方法,其包含下列步驟:(A)備料步驟:齊備安定化之還原碴、粉體材料、鹼性試劑、及水,其中該安定化之還原碴包含10重量百分比至60重量百分比的氫氧化鈣、3重量百分比至10重量百分比的氫氧化鎂,且該粉體材料包含矽氧化物粉、鋁氧化物粉或其組合;(B)混合步驟:將該安定化之還原碴、該粉體材料、該鹼性試劑、及該水混合成一混合物,其中該鹼性試劑在水中的體積莫耳濃度為0.5 M至6 M;及(C)固化步驟:先將該混合物形成至少一試體,再使該至少一試體於常壓下、35°C至100°C下進行固化反應,以得到至少一固化物;以1立方公尺的固化物為基準,步驟(A)中安定化之還原碴的用量為500公斤(kg)至2000 kg,粉體材料的用量為100 kg至1000 kg,鹼性試劑的用量為5 kg至50 kg。In order to achieve the foregoing objective, the present invention provides a stabilized reducing ballast resource recycling method, which includes the following steps: (A) a material preparation step: complete stabilized reducing ballast, powder materials, alkaline reagents, and water, wherein the The stabilized reducing ballast contains calcium hydroxide of 10 weight percent to 60 weight percent, magnesium hydroxide of 3 weight percent to 10 weight percent, and the powder material contains silicon oxide powder, aluminum oxide powder or a combination thereof; ( B) Mixing step: mixing the stabilized reducing ballast, the powder material, the alkaline reagent, and the water into a mixture, wherein the volume molar concentration of the alkaline reagent in the water is 0.5 M to 6 M; and (C) Curing step: first form the mixture into at least one test body, and then make the at least one test body undergo a curing reaction under normal pressure at 35°C to 100°C to obtain at least one cured product; The solidified product of meters is the benchmark, the amount of stabilized reducing ballast in step (A) is 500 kg (kg) to 2000 kg, the amount of powder material is 100 kg to 1000 kg, and the amount of alkaline reagent is 5 kg To 50 kg.

藉由利用上述方法,可在短時間內大量消耗安定化之還原碴,藉由將原本難以利用的安定化之還原碴轉化為具使用性的固化物,可增加安定化之還原碴的使用途徑及減少安定化之還原碴的處理成本。By using the above method, a large amount of stabilized reduced ballast can be consumed in a short time. By converting the originally difficult-to-use stabilized reduced ballast into a usable cured product, the use of stabilized reduced ballast can be increased And to reduce the processing cost of stabilized reduction ballast.

依據本發明,所使用的安定化之還原碴係由未安定化之還原碴經由安定化處理而得,該未安定化之還原碴包含30重量百分比至60重量百分比的氧化鈣、3重量百分比至10重量百分比的氧化鎂、及34重量百分比至60重量百分比之氧化鐵、氧化錳等其餘物質。其中,安定化的處理包含但不限於熱潑法、淺盤潑法、熱燜法、蒸汽熟成法、及高壓蒸汽熟成法。其中,為使未安定化之還原碴能充分地進行安定化,未安定化的還原碴在進行安定化的處理之前需先經過破碎及篩分以使粒度小於或等於4750微米(μm)。According to the present invention, the stabilized reducing ballast used is obtained from the unstabilized reducing ballast through a stabilized treatment. The unstabilized reducing ballast contains 30 to 60 weight percent calcium oxide and 3 weight percent to 10 weight percent of magnesium oxide, and 34 weight percent to 60 weight percent of iron oxide, manganese oxide and other substances. Among them, the stabilization treatment includes, but is not limited to, hot splashing, shallow pan splashing, hot braising, steam aging, and high-pressure steam aging. Among them, in order to fully stabilize the unstabilized reducing ballast, the unstabilized reducing ballast must be crushed and sieved to make the particle size less than or equal to 4750 microns (μm) before being stabilized.

依據本發明,安定化之還原碴除包含氫氧化鈣及氫氧化鎂外,還包含氧化鐵、氧化錳等其餘物質,所述其餘物質的含量佔安定化之還原碴的34重量百分比至80重量百分比。According to the present invention, in addition to calcium hydroxide and magnesium hydroxide, the stabilized reducing ballast also contains iron oxide, manganese oxide and other substances. The content of the remaining substances accounts for 34 to 80 weight percent of the stabilized reducing ballast. percentage.

依據本發明,以1立方公尺的固化物為基準,步驟(A)中安定化之還原碴的用量亦可控制在1000 kg至2000 kg的範圍內,粉體材料的用量亦可控制在50 kg至500 kg的範圍內,鹼性試劑的用量亦可控制在5 kg至30 kg的範圍內。According to the present invention, based on the solidified product of 1 cubic meter, the amount of stabilized reducing ballast in step (A) can also be controlled within the range of 1000 kg to 2000 kg, and the amount of powder material can also be controlled within 50 Within the range of kg to 500 kg, the amount of alkaline reagents can also be controlled within the range of 5 kg to 30 kg.

於一實施態樣中,混合步驟包含:(b1)先將粉體材料、鹼性試劑及水混合形成一預混物,及(b2)再令該預混物與安定化之還原碴混合以形成混合物,其中於上述混合物中,鹼性試劑在水中的體積莫耳濃度為0.5 M至6 M。In one embodiment, the mixing step includes: (b1) first mixing the powder material, alkaline reagent and water to form a premix, and (b2) mixing the premix with stabilized reducing ballast to A mixture is formed, wherein in the above mixture, the volume molar concentration of the alkaline reagent in water is 0.5 M to 6 M.

依據本發明,可根據預期所得固化物的抗壓強度調整混合步驟中鹼性試劑在水中的體積莫耳濃度。若需製得抗壓強度高的固化物,可將鹼性試劑在水中的體積莫耳濃度調整為3 M、3.5 M、4 M、4.5 M、5 M、5.5M、或6 M。若需製造低抗壓強度的固化物,可將鹼性試劑在水中的體積莫耳濃度調整為2 M、1.5 M、1.0 M、或0.5 M,以節省製造成本。According to the present invention, the volume molar concentration of the alkaline agent in the water in the mixing step can be adjusted according to the expected compressive strength of the cured product. If it is necessary to prepare a cured product with high compressive strength, the volume molar concentration of the alkaline reagent in the water can be adjusted to 3 M, 3.5 M, 4 M, 4.5 M, 5 M, 5.5 M, or 6 M. If it is necessary to manufacture a cured product with low compressive strength, the volume molar concentration of the alkaline agent in the water can be adjusted to 2 M, 1.5 M, 1.0 M, or 0.5 M to save manufacturing costs.

依據本發明,於固化步驟中,可利用供電方式使溫度升至35°C至100°C;於另一實施態樣中,亦可利用煉鋼過程中之餘熱、或利用將未定化之還原碴進行安定化的製程中之蒸壓釜冷凝水的餘熱,使溫度升至35°C至100°C以加速固化反應。依據本發明,固化步驟中的溫度較佳地為40°C至100°C、更佳地為45°C至100°C、再更佳地為50°C至100°C、又更佳地為55°C至100°C。According to the present invention, in the solidification step, the temperature can be raised to 35°C to 100°C by means of power supply; in another embodiment, the residual heat in the steelmaking process or the reduction of indefiniteness can also be used. The residual heat of the condensed water in the autoclave in the process of stabilizing the ballast increases the temperature to 35°C to 100°C to accelerate the curing reaction. According to the present invention, the temperature in the curing step is preferably 40°C to 100°C, more preferably 45°C to 100°C, still more preferably 50°C to 100°C, and more preferably It is 55°C to 100°C.

在一實施態樣中,粉體材料可經由乾式研磨或濕式研磨。於一實施態樣中,粉體材料於濕式研磨的過程中,可使用蒸壓釜產生的冷凝水或其他來源的熱水進行濕式研磨,除重複利用水資源外,以熱水進行粉體材料研磨有助於在固化步驟期間加速固化反應。依據本發明,為使粉體材料充分反應,粉體材料的D90粒度係小於或等於96微米。在另一實施態樣中,粉體材料的中值粒度(D50)係小於或等於96微米。於一實施態樣中,粉體材料的中值粒度係大於或等於45微米且小於或等於96微米。In one embodiment, the powder material can be dry milled or wet milled. In one embodiment, in the wet grinding process of powder materials, the condensed water generated by the autoclave or hot water from other sources can be used for wet grinding. In addition to reusing water resources, hot water is used for powder grinding. Bulk material grinding helps to accelerate the curing reaction during the curing step. According to the present invention, in order to make the powder material fully react, the D90 particle size of the powder material is less than or equal to 96 microns. In another embodiment, the median particle size (D50) of the powder material is less than or equal to 96 microns. In one embodiment, the median particle size of the powder material is greater than or equal to 45 microns and less than or equal to 96 microns.

依據本發明,安定化之還原碴的D90粒度係小於或等於4750微米。依據本發明,安定化之還原碴的D90粒度係大於或等於45微米且小於或等於4750微米。於一實施態樣中,安定化之還原碴的粒度係小於或等於4750微米。依據本發明,安定化之還原碴的係大於或等於45微米且小於或等於4750微米。According to the present invention, the D90 particle size of stabilized reduced ballast is less than or equal to 4750 microns. According to the present invention, the D90 particle size of the stabilized reducing ballast is greater than or equal to 45 microns and less than or equal to 4750 microns. In one embodiment, the particle size of the stabilized reducing ballast is less than or equal to 4750 microns. According to the present invention, the stabilized reducing ballast is greater than or equal to 45 microns and less than or equal to 4750 microns.

依據本發明,以整體安定化之還原碴的總重為基準,該安定化之還原碴的水含量為0重量百分比至50重量百分比。依據本發明,以整體安定化之還原碴的總重為基準,安定化之還原碴亦可包含5重量百分比至30重量百分比的水。According to the present invention, based on the total weight of the stabilized reducing ballast, the water content of the stabilized reducing ballast is 0 wt% to 50 wt%. According to the present invention, based on the total weight of the stabilized reducing ballast, the stabilized reducing ballast may also contain 5 wt% to 30 wt% of water.

依據本發明,矽氧化物粉包含二氧化矽(SiO2 )粉,鋁氧化物粉包含三氧化二鋁(Al2 O3 )粉。According to the present invention, the silicon oxide powder contains silicon dioxide (SiO 2 ) powder, and the aluminum oxide powder contains aluminum oxide (Al 2 O 3 ) powder.

依據本發明,粉體材料可為飛灰粉、燃煤底灰粉、高爐石粉、廢玻璃粉或其組合。飛灰粉購自於台中火力發電廠的燃煤副產物,可為F級飛灰粉,亦可為N級飛灰粉或C級飛灰粉。燃煤底灰粉亦購自於台中火力發電廠的燃煤副產物。高爐石粉購自於中聯資源股份有限公司,高爐石粉係中國鋼鐵股份有限公司煉鐵製程中的副產物「水淬高爐碴」經研磨後的粉體材料,可使用80級的高爐石粉、100級的高爐石粉、或120級的高爐石粉。廢玻璃類來自於民生廢玻璃(例如啤酒瓶)或工業廢玻璃(例如面板)。其中,飛灰粉或燃煤底灰粉中的晶體礦物組成包含莫來石(3Al2 O3 •2SiO2 )、石英(SiO2 )、磁鐵礦(Fe3 O4 )、石膏(CaSO4 )、鋁酸三鈣(3CaO•Al2 O3 )、黃長石(Ca2 Al2 SiO7 )、方鎂石(MgO)、石灰(CaO)。高爐石粉可包含SiO2 、Al2 O3 、CaO、MgO鍵結在一起形成CaO•SiO2 •Al2 O3 的結構。廢玻璃粉亦包含CaO•SiO2 •Na2 O、CaO•SiO2 •K2 O等的結構。According to the present invention, the powder material can be fly ash powder, coal bottom ash powder, blast furnace stone powder, waste glass powder or a combination thereof. The fly ash powder is purchased from the coal-burning by-product of the Taichung Thermal Power Plant. It can be Class F fly ash powder, Class N fly ash powder or Class C fly ash powder. Coal-fired bottom ash powder is also purchased from the coal-fired by-products of the Taichung Thermal Power Plant. The blast furnace stone powder was purchased from China United Resources Co., Ltd. The blast furnace stone powder is a by-product of the ironmaking process of China Iron and Steel Co., Ltd. after grinding the "water quenched blast furnace ballast". It can use grade 80 blast furnace stone powder, 100 Grade blast furnace stone powder, or grade 120 blast furnace stone powder. Waste glass comes from people's livelihood waste glass (such as beer bottles) or industrial waste glass (such as panels). Among them, the crystalline mineral composition in fly ash powder or coal-fired bottom ash powder includes mullite (3Al 2 O 3 • 2SiO 2 ), quartz (SiO 2 ), magnetite (Fe 3 O 4 ), gypsum (CaSO 4) ), tricalcium aluminate (3CaO•Al 2 O 3 ), yellow feldspar (Ca 2 Al 2 SiO 7 ), periclase (MgO), lime (CaO). The blast furnace stone powder may include SiO 2 , Al 2 O 3 , CaO, and MgO bonded together to form a structure of CaO•SiO 2 •Al 2 O 3 . The waste glass powder also contains structures such as CaO•SiO 2 •Na 2 O, CaO•SiO 2 •K 2 O, etc.

依據本發明,鹼性試劑包含氫氧化鈉、氫氧化鉀或其組合。於一實施態樣中,鹼性試劑包含氫氧化鈉、氫氧化鉀、矽酸鈉或其組合。其中,氫氧化鈉可為片狀或粒狀、或為液態氫氧化鈉。According to the present invention, the alkaline agent includes sodium hydroxide, potassium hydroxide or a combination thereof. In one embodiment, the alkaline reagent includes sodium hydroxide, potassium hydroxide, sodium silicate, or a combination thereof. Among them, the sodium hydroxide may be in the form of flakes or granules, or liquid sodium hydroxide.

依據本發明,固化步驟可進一步包含將混合物先進行造粒步驟或製模步驟,再於常壓下進行固化反應形成固化物。依據本發明,造粒步驟包含將混合步驟得到的混合物經由擠壓造粒機器製得可為球狀或圓柱狀的至少一試體,再將上述至少一試體置入控溫容器內進行固化反應以增加抗壓強度,之後再將上述至少一試體自控溫容器取出,以得到至少一固化物。依據本發明,製模步驟可為先將混合步驟得到的混合物灌入至少一模具,再將上述至少一模具置入控溫容器內進行固化反應以增加抗壓強度,之後再將各模具自控溫容器取出、脫模,以得到至少一固化物。依據本發明,亦可先利用高壓成型製磚機將混合步驟得到的混合物製得至少一磚狀物,再將上述至少一磚狀物置入控溫容器內進行固化反應以增加抗壓強度,之後再將各磚狀物自控溫容器取出,以得到至少一固化物。According to the present invention, the curing step may further include a granulation step or a molding step of the mixture, and then a curing reaction under normal pressure to form a cured product. According to the present invention, the granulation step includes passing the mixture obtained in the mixing step through an extrusion granulation machine to prepare at least one sample body that can be spherical or cylindrical, and then placing the above-mentioned at least one sample body in a temperature-controlled container for curing The reaction is performed to increase the compressive strength, and then the at least one test body is taken out from the temperature-controlled container to obtain at least one cured product. According to the present invention, the molding step may include pouring the mixture obtained in the mixing step into at least one mold, then placing the at least one mold in a temperature-controlled container for curing reaction to increase the compressive strength, and then automatically controlling each mold The warm container is taken out and demoulded to obtain at least one cured product. According to the present invention, it is also possible to first use a high-pressure forming brick-making machine to prepare at least one brick from the mixture obtained in the mixing step, and then place the at least one brick in a temperature-controlled container for curing reaction to increase the compressive strength, and then Then take out each brick from the temperature control container to obtain at least one solidified product.

依據本發明,固化步驟的時間為30分鐘至3天,即可依固化物用途製得抗壓強度為10 kgf/cm2 至100 kgf/cm2 、抗壓強度為20 kgf/cm2 至70 kgf/cm2 、或抗壓強度為25 kgf/cm2 至50 kgf/cm2 的固化物。According to the present invention, the curing step takes 30 minutes to 3 days, and the compressive strength of the cured product is 10 kgf/cm 2 to 100 kgf/cm 2 and the compressive strength is 20 kgf/cm 2 to 70. kgf/cm 2 , or a cured product with a compressive strength of 25 kgf/cm 2 to 50 kgf/cm 2.

在一實施態樣中,使用0.5 M至1.0 M之鹼性試劑可得到20 kgf/cm2 至40 kgf/cm2 之抗壓強度的固化物,上述固化物可適合作為控制性低強度材料的粒料,表示不需大量的鹼性試劑即可將原先難以利用的安定化之還原碴轉化為具廣泛用途的控制性低強度材料,故本發明為具經濟性的資源化方法。In one embodiment, the use of alkaline reagents of 0.5 M to 1.0 M can obtain a cured product with a compressive strength of 20 kgf/cm 2 to 40 kgf/cm 2. The cured product can be used as a controllable low-strength material. Pellets mean that the stabilized reducing ballast, which was previously difficult to use, can be converted into a controllable low-strength material with a wide range of uses without a large amount of alkaline reagents. Therefore, the present invention is an economical resource utilization method.

依據本發明,所形成的固化物包含鈣矽化合物(calcium-silicate hydrate,C-S-H)、鈣鋁化合物(calcium-aluminum hydrate,C-A-H)、托勃莫來石(tobermorite)。該固化物可進一步視需求產出不同規格的磚、瓦、預鑄混凝土版等水泥製品、或作為控制性低強底材料的原料。According to the present invention, the formed cured product includes calcium-silicate hydrate (C-S-H), calcium-aluminum hydrate (C-A-H), and tobermorite. The cured product can further produce different specifications of cement products such as bricks, tiles, and concrete plates according to requirements, or be used as a raw material for controllable low-strength bottom materials.

以下,將藉由數種實施例示例說明本發明的安定化之還原碴的資源化方法,熟習此技藝者可經由本說明書之內容輕易地了解本發明所能達成之優點與功效,並且於不悖離本發明之精神下進行各種修飾與變更,以施行或應用本發明之內容。In the following, several examples will be used to illustrate the stabilization and reduction ballast recycling method of the present invention. Those who are familiar with this technique can easily understand the advantages and effects of the present invention through the content of this specification. Various modifications and changes are made without departing from the spirit of the present invention to implement or apply the content of the present invention.

實施例Example 11

齊備安定化之還原碴(D90粒度小於或等於4750微米)2597 g、高爐石粉(D90粒度小於或等於96微米)67 g、飛灰(D90粒度小於或等於96微米)231 g、氫氧化鈉22 g、及水82 g。於此,安定化之還原碴的含水量的測定方法如下:先將2597 g的安定化之還原碴烘乾,得到2028.9克之乾燥後的安定化之還原碴,由此計算得到乾燥前的安定化之還原碴包含568.1 g的水,即,安定化之還原碴的含水量為22%。Completely stabilized reduced ballast (D90 particle size less than or equal to 4750 microns) 2597 g, blast furnace stone powder (D90 particle size less than or equal to 96 microns) 67 g, fly ash (D90 particle size less than or equal to 96 microns) 231 g, sodium hydroxide 22 g, and water 82 g. Here, the method for measuring the water content of stabilized reduced ballast is as follows: first dry 2597 g of stabilized reduced ballast to obtain 2028.9 g of stabilized reduced ballast after drying, and calculate the stabilized ballast before drying. The reduced ballast contains 568.1 g of water, that is, the stabilized reduced ballast has a water content of 22%.

接著,將高爐石粉、飛灰、氫氧化鈉、及水混合成一預混物後,再令該預混物與安定化之還原碴混合,形成一混合物。在該混合物中,氫氧化鈉在水中的體積莫耳濃度可由以下方法計算:混合物中的氫氧化鈉莫耳數除以混合物中的液體體積總和,即,氫氧化鈉的莫耳數除以水的總體積及氫氧化鈉溶解後的體積(氫氧化鈉(M)=莫耳數氫氧化鈉 ÷(體積 +體積氫氧化鈉 )),其中氫氧化鈉溶解後的體積可利用氫氧化鈉的質量除以其密度(2.13克/每立方公分(g/cm3 ))得知,此外,水的體積包含安定化之還原碴內含的水及外加的水。因此,混合物中氫氧化鈉的體積莫耳濃度可利用氫氧化鈉的莫耳數(0.55莫耳)除以水的體積(0.650公升)與氫氧化鈉溶解後之體積(0.01公升)的總和計算得到0.83 M。Then, the blast furnace stone powder, fly ash, sodium hydroxide, and water are mixed into a premix, and then the premix is mixed with stabilized reducing ballast to form a mixture. In this mixture, the volume molar concentration of sodium hydroxide in water can be calculated by the following method: the number of moles of sodium hydroxide in the mixture divided by the sum of the liquid volumes in the mixture, that is, the number of moles of sodium hydroxide divided by water The total volume of sodium hydroxide and the volume after dissolution of sodium hydroxide (sodium hydroxide (M) = molar number of sodium hydroxide ÷ (volume of water + volume of sodium hydroxide )), where the volume of sodium hydroxide dissolved can be used sodium hydroxide Divide the mass by its density (2.13 grams per cubic centimeter (g/cm 3 )). In addition, the volume of water includes the water contained in the stabilized reduced ballast and the added water. Therefore, the volume molar concentration of sodium hydroxide in the mixture can be calculated by dividing the molar number of sodium hydroxide (0.55 mol) by the volume of water (0.650 liters) and the volume of sodium hydroxide dissolved (0.01 liters). 0.83 M is obtained.

將該混合物攪拌均勻並灌入數個體積為50 公釐(mm)*50 mm*50 mm的模具,之後將各模具放入一控溫容器內,再將該控溫容器於常壓、60°C的養護溫度下進行固化反應,並於經過3小時、6小時、及24小時後各取出一塊模具進行脫模,以分別獲得經過不同固化時間的固化物。於此,所有模具脫膜後之固化物的總體積為1500立方公分(cm3 )。Stir the mixture evenly and pour it into several molds with a volume of 50 mm (mm) * 50 mm * 50 mm. Then put each mold in a temperature-controlled container, and then place the temperature-controlled container at normal pressure and 60 mm. The curing reaction is carried out at a curing temperature of °C, and after 3 hours, 6 hours, and 24 hours have passed, a mold is taken out and demolded to obtain cured products with different curing times. Here, the total volume of the cured product after all the molds are released is 1500 cubic centimeters (cm 3 ).

實施例Example 22

齊備安定化之還原碴(D90粒度小於或等於4750微米)2597 g、高爐石粉(D90粒度小於或等於96微米)67 g、飛灰(D90粒度小於或等於96微米)231 g、氫氧化鈉22 g、及水82 g。於此,安定化之還原碴利用上述方法測得含水量為22%,即,乾燥前的安定化之還原碴2597 g包含568.1 g的水。Completely stabilized reducing ballast (D90 particle size less than or equal to 4750 microns) 2597 g, blast furnace stone powder (D90 particle size less than or equal to 96 microns) 67 g, fly ash (D90 particle size less than or equal to 96 microns) 231 g, sodium hydroxide 22 g, and 82 g of water. Here, the stabilized reduced ballast has a water content of 22% as measured by the above method, that is, 2597 g of stabilized reduced ballast before drying contains 568.1 g of water.

接著,將高爐石粉、飛灰、氫氧化鈉、及水混合成一預混物後,再令該預混物與安定化之還原碴混合,形成一混合物。在該混合物中,利用上述方法計算得到氫氧化鈉在水中的體積莫耳濃度為0.83 M(氫氧化鈉的莫耳數為0.55莫耳;水的總體積為0.650公升;氫氧化鈉溶解後的體積為0.01公升;)。Then, the blast furnace stone powder, fly ash, sodium hydroxide, and water are mixed into a premix, and then the premix is mixed with stabilized reducing ballast to form a mixture. In this mixture, the volumetric molar concentration of sodium hydroxide in water calculated by the above method is 0.83 M (the molar number of sodium hydroxide is 0.55 molar; the total volume of water is 0.650 liters; the sodium hydroxide is dissolved The volume is 0.01 liters;).

將該混合物攪拌均勻並灌入數個體積為50 mm *50 mm *50 mm的模具,之後將各模具放入一控溫容器內,再將該控溫容器於常壓、90°C的養護溫度下進行固化反應,並於經過3小時、6小時、及24小時後各取出一塊模具進行脫模,以分別獲得經過不同固化時間的固化物。於此,所有模具脫膜後之固化物的總體積為1500立方公分(cm3 )。Stir the mixture evenly and pour it into several molds with a volume of 50 mm *50 mm *50 mm, then put each mold in a temperature-controlled container, and then cure the temperature-controlled container at normal pressure and 90°C The curing reaction is carried out at a temperature, and after 3 hours, 6 hours, and 24 hours have passed, a mold is taken out and demolded to obtain cured products with different curing times. Here, the total volume of the cured product after all the molds are released is 1500 cubic centimeters (cm 3 ).

實施例Example 33

齊備安定化之還原碴(D90粒度小於或等於4750微米)2505 g、高爐石粉(D90粒度小於或等於96微米)83 g、飛灰(D90粒度小於或等於96微米)300 g、氫氧化鈉29 g、及水84 g。於此,安定化之還原碴乾燥後的重量為1957 g,計算得到乾燥前的安定化之還原碴包含548 g的水,即,乾燥前的安定化之還原碴的含水量為22%。Completely stabilized reducing ballast (D90 particle size less than or equal to 4750 microns) 2505 g, blast furnace stone powder (D90 particle size less than or equal to 96 microns) 83 g, fly ash (D90 particle size less than or equal to 96 microns) 300 g, sodium hydroxide 29 g, and 84 g of water. Here, the weight of the stabilized reduced ballast after drying is 1957 g, and it is calculated that the stabilized reduced ballast before drying contains 548 g of water, that is, the water content of the stabilized reduced ballast before drying is 22%.

接著,將高爐石粉、飛灰、氫氧化鈉、及水混合成一預混物後,再令該預混物與安定化之還原碴混合,形成一混合物。在該混合物中,利用上述方法計算得到氫氧化鈉在水中的體積莫耳濃度為1.12 M(氫氧化鈉的莫耳數為0.725莫耳;水的總體積為0.632公升;氫氧化鈉溶解後的體積為0.014公升)。Then, the blast furnace stone powder, fly ash, sodium hydroxide, and water are mixed into a premix, and then the premix is mixed with stabilized reducing ballast to form a mixture. In this mixture, the volumetric molar concentration of sodium hydroxide in water calculated using the above method is 1.12 M (the molar number of sodium hydroxide is 0.725 molar; the total volume of water is 0.632 liters; the sodium hydroxide is dissolved The volume is 0.014 liters).

將該混合物攪拌均勻並灌入數個體積為50 mm*50 mm*50 mm的模具,之後將各模具放入一控溫容器內,再將該控溫容器於常壓下、60°C的養護溫度下進行固化反應,並於經過3小時、6小時、及24小時後各取出一塊模具進行脫模,以分別獲得經過不同固化時間的固化物。於此,所有模具脫膜後之固化物的總體積為1500立方公分(cm3 )。Stir the mixture evenly and pour it into several molds with a volume of 50 mm*50 mm*50 mm, then put each mold in a temperature-controlled container, and then place the temperature-controlled container under normal pressure at 60°C. The curing reaction is carried out at the curing temperature, and after 3 hours, 6 hours, and 24 hours have passed, a mold is taken out and demolded to obtain cured products with different curing times. Here, the total volume of the cured product after all the molds are released is 1500 cubic centimeters (cm 3 ).

實施例Example 44

齊備安定化之還原碴(D90粒度小於或等於4750微米)2505 g、高爐石粉(D90粒度小於或等於96微米)83 g、飛灰(D90粒度小於或等於96微米)300 g、氫氧化鈉29 g、及水84 kg。於此,安定化之還原碴利用上述方法測得含水量為22%,即,乾燥前的安定化之還原碴2505 g包含548 g的水。Completely stabilized reducing ballast (D90 particle size less than or equal to 4750 microns) 2505 g, blast furnace stone powder (D90 particle size less than or equal to 96 microns) 83 g, fly ash (D90 particle size less than or equal to 96 microns) 300 g, sodium hydroxide 29 g, and 84 kg of water. Here, the stabilized reduced ballast has a water content of 22% as measured by the above method, that is, 2505 g of stabilized reduced ballast before drying contains 548 g of water.

接著,將高爐石粉、飛灰、氫氧化鈉、及水混合成一預混物後,再令該預混物與安定化之還原碴混合,形成一混合物。在該混合物中,利用上述方法計算得到氫氧化鈉的體積莫耳濃度為1.12 M(氫氧化鈉的莫耳數為0.725莫耳;水的總體積為0.632公升;氫氧化鈉溶解後的體積為0.014公升)。Then, the blast furnace stone powder, fly ash, sodium hydroxide, and water are mixed into a premix, and then the premix is mixed with stabilized reducing ballast to form a mixture. In this mixture, the volumetric molar concentration of sodium hydroxide calculated using the above method is 1.12 M (the molar number of sodium hydroxide is 0.725 molar; the total volume of water is 0.632 liters; the volume after dissolving sodium hydroxide is 0.014 liters).

將該混合物攪拌均勻並灌入數個體積為50 mm*50 mm*50 mm的模具,之後將各模具放入一控溫容器內,再將該控溫容器於常壓下、90°C的養護溫度下進行固化反應,並於經過3小時、6小時、及24小時後各取出一塊模具進行脫模,以分別獲得經過不同固化時間的固化物。於此,所有模具脫膜後之固化物的總體積為1500立方公分(cm3 )。Stir the mixture evenly and pour it into several molds with a volume of 50 mm*50 mm*50 mm, then put each mold in a temperature-controlled container, and then place the temperature-controlled container under normal pressure at 90°C. The curing reaction is carried out at the curing temperature, and after 3 hours, 6 hours, and 24 hours have passed, a mold is taken out and demolded to obtain cured products with different curing times. Here, the total volume of the cured product after all the molds are released is 1500 cubic centimeters (cm 3 ).

試驗例Test example 11 :抗壓強度測試: Compressive strength test

依據CNS 1010測試法進行,將實施例1至4之不同固化時間的固化物以萬能材料試驗機(型號:H-300,廠牌:弘達儀器股份有限公司),以每分鐘加載500公斤重(500 kgf/min)之加壓速度進行單軸載重試驗,待破壞固化物後記錄最大值,再將其除以受力面積即可得到各固化物之抗壓強度。 表1:實施例1至4之固化物於不同養護溫度下加熱3小時、6小時、及24小時後的抗壓強度(kgf/cm2 )。   養護溫度(°C) 抗壓強度3 小時 (kgf/cm2 抗壓強度6 小時 (kgf/cm2 抗壓強度24 小時 (kgf/cm2 實施例1 60 10.2 20.1 29.3 實施例2 90 15.5 23.2 31.8 實施例3 60 11.7 23.1 33.6 實施例4 90 16.3 28.4 38.9 According to the CNS 1010 test method, the cured products with different curing times of Examples 1 to 4 were used with a universal material testing machine (model: H-300, brand: Hongda Instruments Co., Ltd.), with a load of 500 kg per minute ( Perform a uniaxial load test at a pressurization speed of 500 kgf/min). After the cured product is destroyed, record the maximum value, and then divide it by the force area to obtain the compressive strength of each cured product. Table 1: The compressive strength (kgf/cm 2 ) of the cured products of Examples 1 to 4 after heating at different curing temperatures for 3 hours, 6 hours, and 24 hours. Curing temperature (°C) Compressive strength for 3 hours (kgf/cm 2 ) Compressive strength 6 hours (kgf/cm 2 ) Compressive strength for 24 hours (kgf/cm 2 ) Example 1 60 10.2 20.1 29.3 Example 2 90 15.5 23.2 31.8 Example 3 60 11.7 23.1 33.6 Example 4 90 16.3 28.4 38.9

實驗結果討論Discussion of experimental results

如上表1所示,利用本發明的安定化之還原碴的資源化方法,能在短時間內獲得抗壓強度為10 kgf/cm2 至100 kgf/cm2 的固化物。具備上述抗壓強度之固化物為具經濟價值的材料,可大量使用於CLSM材料、非結構混凝土材料,增加使用途徑、減少堆置需求進而降低煉鋼的成本。As shown in Table 1 above, the stabilized reducing ballast recycling method of the present invention can obtain a cured product with a compressive strength of 10 kgf/cm 2 to 100 kgf/cm 2 in a short time. The cured product with the above-mentioned compressive strength is a material with economic value, which can be used in large quantities in CLSM materials and non-structural concrete materials to increase the use of channels, reduce the stacking requirements and reduce the cost of steelmaking.

觀察實施例1及3,於養護溫度60°C固化反應3小時後,所得的固化物之抗壓強度分別為10.2 kgf/cm2 及11.7 kgf/cm2 ,表示本發明的方法可在3小時內即能將安定化之還原碴轉化為具使用性的固化物。再觀實施例1及3,於養護溫度60°C固化反應6小時後,所得的固化物之抗壓強度分別為20.1 kgf/cm2 及23.1 kgf/cm2 ,相較於經過3小時得到的固化物,經過6小時之固化物的抗壓強度為經過3小時之固化物的抗壓強度約兩倍,表示本發明的方法可在短時間內增加固化物的抗壓強度。Observing Examples 1 and 3, after curing and reacting at a curing temperature of 60°C for 3 hours, the compressive strengths of the resulting cured products were 10.2 kgf/cm 2 and 11.7 kgf/cm 2 , respectively, indicating that the method of the present invention can be used in 3 hours It can transform the stabilized reducing ballast into a usable solidified substance inside. Looking back at Examples 1 and 3, after curing and reacting at a curing temperature of 60°C for 6 hours, the compressive strengths of the cured products obtained are 20.1 kgf/cm 2 and 23.1 kgf/cm 2 respectively , compared with those obtained after 3 hours The compressive strength of the cured product after 6 hours is about twice the compressive strength of the cured product after 3 hours, indicating that the method of the present invention can increase the compressive strength of the cured product in a short time.

進一步地,將實施例2及4與實施例1及3相比較,得知將養護溫度提高至90°C後,於經過相同的加熱時間(3小時),實施例2及4所得的固化物之抗壓強度相較於實施例1及3的固化物之抗壓強度增加約一半,分別為15.5 kgf/cm2 及16.3 kgf/cm2 ,可知增加溫度有助於提升固化物的抗壓強度。再觀察於養護溫度90°C加熱6小時後,所得的固化物之抗壓強度分別增強為23.2 kgf/cm2 及28.4 kgf/cm2 ,表示於90°C加熱6小時後可獲得接近25 kgf/cm2 、甚至接近30 kgf/cm2 之抗壓強度的固化物。Further, comparing Examples 2 and 4 with Examples 1 and 3, it is known that after the curing temperature is increased to 90°C, after the same heating time (3 hours), the cured products obtained in Examples 2 and 4 Compared with the compressive strength of the cured product of Examples 1 and 3, the compressive strength of the composite is increased by about half, respectively, 15.5 kgf/cm 2 and 16.3 kgf/cm 2. It can be seen that increasing the temperature helps to increase the compressive strength of the cured product . Observe that after heating for 6 hours at a curing temperature of 90°C, the compressive strength of the resulting cured product is increased to 23.2 kgf/cm 2 and 28.4 kgf/cm 2 respectively , which means that approximately 25 kgf can be obtained after heating at 90°C for 6 hours. /cm 2 , even close to 30 kgf/cm 2 of the cured product with compressive strength.

再觀實施例1至4之加熱24小時的固化物,不管於60°C還是90°C的養護溫度,所得的固化物皆具有約30 kgf/cm2 的抗壓強度,於90°C加熱24小時的固化物更具有接近40 kgf/cm2 的抗壓強度,可知本發明的方法能大幅縮短將安定化之還原碴轉化為固化物的時間。Looking at the cured products heated for 24 hours in Examples 1 to 4, regardless of curing temperature of 60°C or 90°C, the cured products obtained have a compressive strength of about 30 kgf/cm 2 and heated at 90°C The cured product for 24 hours has a compressive strength close to 40 kgf/cm 2. It can be seen that the method of the present invention can greatly shorten the time to convert stabilized reduced ballast into a cured product.

綜合上述實驗結果,利用本發明的方法,能在短時間內即將大量的安定化之還原碴轉化為具使用途徑的固化物,該固化物為再生資源,其可大量使用於CLSM材料、非結構混凝土材料,藉此增加安定化之還原碴的用途及減少安定化之還原碴的處理成本。Based on the above experimental results, using the method of the present invention, a large amount of stabilized reduced ballast can be converted into a cured product with a use path in a short time. The cured product is a renewable resource, which can be used in large quantities for CLSM materials and non-structural materials. Concrete materials, thereby increasing the use of stabilized reducing ballast and reducing the processing cost of stabilized reducing ballast.

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Claims (10)

一種安定化之還原碴的資源化方法,其包含下列步驟: (A)   備料步驟:齊備安定化之還原碴、粉體材料、鹼性試劑、及水,其中該安定化之還原碴包含10重量百分比至60重量百分比的氫氧化鈣、3重量百分比至10重量百分比的氫氧化鎂,且該粉體材料包含矽氧化物粉、鋁氧化物粉或其組合; (B)    混合步驟:將該安定化之還原碴、該粉體材料、該鹼性試劑、及該水混合成一混合物,其中該鹼性試劑在水中的體積莫耳濃度為0.5 M至6 M;及 (C)    固化步驟:先將該混合物形成至少一試體,再使該至少一試體於常壓下、35°C至100°C下進行固化反應,以得到至少一固化物; 以1立方公尺的固化物為基準,步驟(A)中安定化之還原碴的用量為500 kg至2000 kg,粉體材料的用量為100 kg至1000 kg,鹼性試劑的用量為5 kg至50 kg。A method for stabilizing and reducing ballast resources, which includes the following steps: (A) Material preparation step: prepare stabilized reducing ballast, powder materials, alkaline reagents, and water, where the stabilized reducing ballast contains 10 to 60 weight percent calcium hydroxide, 3 to 10 weight percent Percentage of magnesium hydroxide, and the powder material includes silicon oxide powder, aluminum oxide powder or a combination thereof; (B) Mixing step: mixing the stabilized reducing ballast, the powder material, the alkaline reagent, and the water into a mixture, wherein the volume molar concentration of the alkaline reagent in the water is 0.5 M to 6 M; and (C) Curing step: first form the mixture into at least one test body, and then subject the at least one test body to a curing reaction under normal pressure at 35°C to 100°C to obtain at least one cured product; Based on the solidified product of 1 cubic meter, the amount of stabilized reducing ballast in step (A) is 500 kg to 2000 kg, the amount of powder material is 100 kg to 1000 kg, and the amount of alkaline reagent is 5 kg To 50 kg. 如請求項1所述之安定化之還原碴的資源化方法,其中該混合步驟包含: (b1)先將該粉體材料、該鹼性試劑、及該水混合後,形成一預混物;及 (b2)再令該預混物與該安定化之還原碴混合,形成該混合物,其中於該混合物中,該鹼性試劑在水中的體積莫耳濃度為0.5 M至6 M。The method of stabilizing the recovery ballast as described in claim 1, wherein the mixing step includes: (B1) The powder material, the alkaline reagent, and the water are mixed first to form a premix; and (B2) The premix and the stabilized reducing ballast are mixed to form the mixture, wherein the volume molar concentration of the alkaline reagent in the water is 0.5 M to 6 M in the mixture. 如請求項2所述之安定化之還原碴的資源化方法,其中該粉體材料之中值粒度係小於或等於96微米。The method for recycling stabilized reduced ballast as described in claim 2, wherein the median particle size of the powder material is less than or equal to 96 microns. 如請求項2所述之安定化之還原碴的資源化方法,其中該安定化之還原碴的D90粒度係小於或等於4750微米。The method for recycling stabilized reduced ballast as described in claim 2, wherein the D90 particle size of the stabilized reduced ballast is less than or equal to 4750 microns. 如請求項1所述之安定化之還原碴的資源化方法,其中以整體該安定化之還原碴的總重為基準,該安定化之還原碴的水含量為0重量百分比至50重量百分比。The method for recycling stabilized reduced ballast according to claim 1, wherein based on the total weight of the stabilized reduced ballast as a whole, the water content of the stabilized reduced ballast is 0 wt% to 50 wt%. 如請求項3所述之安定化之還原碴的資源化方法,其中該粉體材料係飛灰粉、燃煤底灰粉、高爐石粉、廢玻璃粉或其組合。The method for recycling stabilized reduced ballast according to claim 3, wherein the powder material is fly ash powder, coal bottom ash powder, blast furnace stone powder, waste glass powder or a combination thereof. 如請求項2所述之安定化之還原碴的資源化方法,其中該鹼性試劑包含氫氧化鈉、氫氧化鉀、矽酸鈉或其組合。The resource recovery method of stabilized reducing ballast according to claim 2, wherein the alkaline reagent comprises sodium hydroxide, potassium hydroxide, sodium silicate or a combination thereof. 如請求項1至7中任一項所述之安定化之還原碴的資源化方法,其中該固化步驟的時間為30分鐘至3天。The method for recycling stabilized reduced ballast according to any one of claims 1 to 7, wherein the curing step takes 30 minutes to 3 days. 如請求項8所述之安定化之還原碴的資源化方法,其中該固化物的抗壓強度為10 kgf/cm2 至100 kgf/cm2The method for recycling stabilized reduced ballast as described in claim 8, wherein the compressive strength of the cured product is 10 kgf/cm 2 to 100 kgf/cm 2 . 如請求項1所述之安定化之還原碴的資源化方法,其中該固化步驟包含: (c1)先將該混合物填充於至少一模具中,使該混合物於該至少一模具中形成該至少一試體; (c2)將該至少一模具於常壓下、35°C至100°C下進行固化反應;及 (c3)脫模,以得到該至少一固化物。The stabilization method for resource recovery of reduced ballast as described in claim 1, wherein the solidification step includes: (C1) First fill the mixture in at least one mold, and make the mixture form the at least one test body in the at least one mold; (C2) Carry out the curing reaction of the at least one mold under normal pressure at 35°C to 100°C; and (C3) Demoulding to obtain the at least one cured product.
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