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TW202006891A - Semiconductor substrate and manufacturing method thereof can obtain expected shape even if in condition of performing film formation or high-temperature heating - Google Patents

Semiconductor substrate and manufacturing method thereof can obtain expected shape even if in condition of performing film formation or high-temperature heating Download PDF

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TW202006891A
TW202006891A TW107124011A TW107124011A TW202006891A TW 202006891 A TW202006891 A TW 202006891A TW 107124011 A TW107124011 A TW 107124011A TW 107124011 A TW107124011 A TW 107124011A TW 202006891 A TW202006891 A TW 202006891A
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substrate
transfer
sori
shape
polishing
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TWI744539B (en
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上田修平
竹內正樹
岡藤大雄
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日商信越化學工業股份有限公司
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Abstract

An issue of the disclosure is to provide a semiconductor substrate that does not deform or hardly deforms even if in condition of performing film formation or high-temperature heating. A semiconductor substrate is provided with a surface having one side of a convex SORI and a surface having the other side of a concave SORI equivalent to the degree as the SORI, and having a thickness deviation that is below 3[mu]m.

Description

半導體用基板及其製造方法Semiconductor substrate and manufacturing method thereof

本發明係關於半導體用基板及其製造方法。The present invention relates to a semiconductor substrate and a method of manufacturing the same.

在半導體積體電路(LSI:Large Scale Integration)或TFT-LCD(Thin Film Transistor-Liquid Crystal Display)中,微細化、高速動作之要求正在增加,被製作在半導體基板上之膜變得更緻密。In semiconductor integrated circuits (LSI: Large Scale Integration) or TFT-LCD (Thin Film Transistor-Liquid Crystal Display), requirements for miniaturization and high-speed operation are increasing, and the films formed on semiconductor substrates become denser.

若多晶矽TFT用之基板的平坦性受損時,則在於液晶顯示裝置製造工程中,挾持玻璃晶圓之情況,或機械人搬運之情況,產生不吸附或無法把持等的不妥當,或在形成多晶矽TFT之過程的施予微細圖案的光微影工程中,產生圖案之重疊變差等的不妥當。   再者,在液晶面板中,若兩片透明玻璃體彼此之平坦度不匹配時,則被夾於其中之液晶的膜厚也難以成為均勻,產生顏色不均等而產生品質上的不妥當。   並且,在使用多晶矽薄膜而製造TFT-LCD之情況,因處理溫度到達1000℃以上,基板引起黏性變形而產生翹曲變形。If the flatness of the substrate for the polysilicon TFT is damaged, the glass wafer is held in the manufacturing process of the liquid crystal display device, or the robot is transported, which causes improper adsorption or inability to hold, or is forming In the process of photolithography applied to fine patterns in the process of polysilicon TFT, improper overlapping of patterns and the like are generated.   Furthermore, in the liquid crystal panel, if the flatness of the two transparent glass bodies does not match each other, the film thickness of the liquid crystal sandwiched therebetween is also difficult to be uniform, resulting in color unevenness, resulting in improper quality.   Furthermore, in the case of manufacturing a TFT-LCD using a polycrystalline silicon thin film, the substrate is caused to undergo viscous deformation and warpage due to the processing temperature reaching 1000°C or higher.

為了解決該些問題,例如,在專利文獻1中,提案有藉由抑制羥基濃度和氯濃度之含有量,提供耐熱性優良,並且由高純度之石英玻璃材料所構成的主動元件基板。   再者,在專利文獻2中,提案有藉由在基板之表背面形成氮化矽膜,使其應力在基板之表背面相抵,使基板之翹曲不產生的方法。   並且,在專利文獻3中,揭示有藉由將氟濃度設在一定範圍內,並且使用實質上不含有鹼性金屬氧化物之石英玻璃,縮小根據假想溫度所致的密度變化,獲得高溫處理前後之尺寸安定性優良的多晶矽TFT式LCD用石英玻璃基板的方法。 [先前技術文獻] [專利文獻]In order to solve these problems, for example, Patent Document 1 proposes to provide an active device substrate made of high-purity quartz glass material by suppressing the content of hydroxyl group concentration and chlorine concentration to provide excellent heat resistance.   Furthermore, Patent Document 2 proposes a method of forming a silicon nitride film on the front and back surfaces of a substrate so that the stress is offset on the front and back surfaces of the substrate to prevent warpage of the substrate. In addition, Patent Document 3 discloses that by setting the fluorine concentration within a certain range and using quartz glass that does not substantially contain an alkali metal oxide, the density change due to the hypothetical temperature is reduced, and before and after high-temperature treatment is obtained It is a method of quartz glass substrate for polycrystalline silicon TFT LCD with excellent size stability. [Prior Technical Literature] [Patent Literature]

[專利文獻1]日本特開平6-11705號公報   [專利文獻2]日本特開平11-121760號公報   [專利文獻3]日本特開2005-215319號公報[Patent Document 1] Japanese Patent Laid-Open No. 6-11705    [Patent Document 2] Japanese Patent Laid-Open No. 11-121760    [Patent Document 3] Japanese Patent Laid-Open No. 2005-215319

[發明所欲解決之課題][Problems to be solved by the invention]

但是,在專利文獻1之方法中,即使提升石英玻璃材料之平坦性,亦無法抑制之後之多晶矽薄膜之膜應力所致的變形。   再者,在專利文獻2之方法中,雖除非在基板之表背面構成相同的膜,否則無法排除翹曲的產生,但是因以相同的膜構成TFT側及彩色濾光器側之雙面並非一般性,故即使為該方法亦難抑制變形。   並且,即使為專利文獻3之方法,雖然高溫處理前後之尺寸安定性優良,但是並非可以抑制膜應力所致的變形者。However, in the method of Patent Document 1, even if the flatness of the quartz glass material is improved, the deformation due to the film stress of the polycrystalline silicon thin film afterward cannot be suppressed. In addition, in the method of Patent Document 2, unless the same film is formed on the front and back surfaces of the substrate, the occurrence of warpage cannot be ruled out, but because the same film is used to configure the double sides of the TFT side and the color filter side, it is not In general, it is difficult to suppress deformation even with this method. Also, even with the method of Patent Document 3, although the dimensional stability before and after the high-temperature treatment is excellent, it is not possible to suppress deformation due to film stress.

本發明係鑑於上述情形而創作出,其目的在於提供即使為進行成膜或高溫加熱處理之情況,亦不變形或變形少之半導體用基板及其製造方法。 [用以解決課題之手段]The present invention was created in view of the above circumstances, and its object is to provide a semiconductor substrate and a method for manufacturing the same that are not deformed or less deformed even when film formation or high-temperature heat treatment is performed. [Means to solve the problem]

本發明者為了達成上述目的精心研究結果,發現使用在半導體用基板之製造中通常使用的雙面拋光裝置、單面拋光裝置、雙面研磨裝置或單面研磨裝置般之製造裝置,可以低成本且再現性佳地製造SORI或BOW任意被控制,並且厚度偏差少之半導體用基板,更具體而言,藉由上述裝置,以半導體用基板藉由膜應力或高溫加熱處理而變形之情形為前提,事先考慮該些變形量而計畫性地製作朝與該些變形相反的方向翹曲之形狀的基板,藉此即使為進行成膜或高溫加熱處理之情況,亦可以獲得無變形或變形少的半導體用基板,而完成本發明。In order to achieve the above object, the present inventors have carefully studied the results and found that using a manufacturing device like a double-sided polishing device, a single-sided polishing device, a double-sided polishing device, or a single-sided polishing device, which are generally used in the manufacture of semiconductor substrates, can be cost-effective The SORI or BOW is arbitrarily controlled with good reproducibility, and the thickness of the semiconductor substrate is small, more specifically, the above device is premised on the case where the semiconductor substrate is deformed by film stress or high temperature heat treatment , Considering the amount of deformation in advance, plan to fabricate a substrate that is warped in the opposite direction to the deformation, so that even if the film is formed or high-temperature heat treatment, no deformation or less deformation can be obtained The semiconductor substrate of the present invention is completed.

即是,本發明係提供以下者:   1.一種半導體用基板,其特徵在於,具備具有凸狀之SORI之一方的面,和具有與上述SORI相同程度之凹狀之SORI的另一方之面,並且厚度偏差為3μm以下。   2.如1之半導體用基板,其中,上述各面之SORI為50~600μm。   3.如1或2之半導體用基板,其中,具有上述凸狀之SORI之一方之面的BOW為+25~+300。   4.如1至3中之任一之半導體用基板,其中,具有上述凹狀之SORI之另一方之面的BOW為-25~-300。   5.如1至4中之任一之半導體用基板,其中,厚度為0.5~3mm。   6.如1至5中之任一之半導體用基板,其中,上述半導體用基板之形狀在俯視下為直徑100~450mm之圓形狀或對角長度100~450mm之矩形狀。   7.如1至6中之任一之半導體用基板,其中,為合成石英玻璃製。   8.如1至7中之任一之半導體用基板,其中,為多晶矽TFT用基板。   9.一種半導體用基板之製造方法,其特徵在於,具備:   準備工程,其係準備轉印用母盤,且該轉印用母盤具有表面及背面,具有相對於通過連結該些表背面之中心點的中心線上之中間點,與上述中心線正交之面,上述表面及背面對稱地相向的SORI和厚度偏差;   轉印工程,其係以挾入上述轉印用母盤之方式,在雙面拋光裝置設置兩片原料基板,對上述各原料基板中之不與上述轉印用母盤相接之面進行加工而製作上述轉印用母盤之形狀被轉印至各個單面的兩片轉印基板;   拋光工程,其係藉由拋光上述轉印基板之雙面,或藉由僅拋光上述轉印基板中之在上述轉印工程沒有轉印上述轉印用母盤之形狀的面而製作拋光加工基板;及   對上述拋光加工基板之雙面或單面進行研磨。   10.一種半導體用基板之製造方法,其特徵在於,具備:   準備工程,其係準備轉印用母盤,且該轉印用母盤具有表面及背面,相對於通過連結該些表背面之中心點的中心線上之中間點,與上述中心線正交之面,上述表背面之中的任一方之面為平行,並且上述表背面之中與原料基板相接之另一方之面正交於上述中心線,同時相對於上述中心線為對稱; 轉印工程,其係以與上述轉印用母盤之上述另一方之面相接之方式在單面拋光裝置設置原料基板,對上述原料基板中之不與上述轉印用母盤相接之面進行加工而製作上述轉印用母盤之形狀被轉印至單面之轉印基板;   拋光工程,其係藉由拋光上述轉印基板之雙面,或藉由僅拋光上述轉印基板中之在上述轉印工程沒有被轉印上述轉印用母盤之形狀的面而製作拋光加工基板;及   對上述拋光加工基板之雙面或單面進行研磨。 [發明之效果]That is, the present invention provides the following:    1. A semiconductor substrate, characterized in that it has a surface having one side of a convex SORI and another surface having a concave SORI of the same degree as the above SORI, And the thickness deviation is 3 μm or less.   2. The semiconductor substrate according to 1, wherein the SORI of the above-mentioned surfaces is 50 to 600 μm.   3. The semiconductor substrate according to 1 or 2, wherein the BOW of one of the surfaces of the convex SORI is +25 to +300.   4. The semiconductor substrate according to any one of 1 to 3, wherein the BOW of the other surface of the concave SORI is -25 to -300.   5. The semiconductor substrate according to any one of 1 to 4, wherein the thickness is 0.5 to 3 mm.   6. The semiconductor substrate according to any one of 1 to 5, wherein the shape of the semiconductor substrate is a circular shape with a diameter of 100 to 450 mm or a rectangular shape with a diagonal length of 100 to 450 mm in plan view.   7. The semiconductor substrate according to any one of 1 to 6, which is made of synthetic quartz glass.   8. The substrate for semiconductor according to any one of 1 to 7, which is a substrate for polysilicon TFT. 9. A method for manufacturing a substrate for semiconductors, comprising: a    preparation process, which prepares a transfer master, and the transfer master has a front surface and a back surface, and has a surface opposite to the back surface by connecting the front surfaces The middle point on the center line of the center point, the surface orthogonal to the center line, the SORI and thickness deviation of the above surface and the back surface symmetrically facing each other; The double-sided polishing device is provided with two raw material substrates, and the surface of each raw material substrate that is not in contact with the transfer master is processed to produce the shape of the transfer master, which is transferred to two single-sided surfaces. Sheet transfer substrate;    polishing process, by polishing both sides of the transfer substrate, or by polishing only the surface of the transfer substrate in the transfer process does not transfer the shape of the transfer master And manufacture a polished substrate; and grind both sides or one side of the polished substrate. 10. A method for manufacturing a substrate for semiconductors, characterized by comprising:    preparation process, which prepares a transfer master, and the transfer master has a front surface and a back surface, with respect to the center of the front and back surfaces connected by the The middle point on the center line of the point is the plane orthogonal to the center line, either side of the front and back sides is parallel, and the other side of the front and back sides that is in contact with the raw substrate is orthogonal to the above The center line is also symmetrical with respect to the center line; transfer process, which is to set the raw material substrate on the single-side polishing device in such a way as to be in contact with the other surface of the transfer master, and to the raw material substrate The surface that is not in contact with the transfer master is processed to produce the transfer substrate whose shape is transferred to a single-sided transfer substrate;    polishing process, which is by polishing the double transfer substrate Surface, or by polishing only the surface of the transfer substrate that is not transferred to the shape of the transfer master in the transfer process, and a polished substrate; and a double-sided or single-sided surface of the polished substrate Perform grinding. [Effect of invention]

若藉由本發明時,可以提供具有事先考慮到膜應力或高溫加熱處理所致的半導體用基板之變形的特定SORI及厚度偏差之半導體用基板。因此,即使為之後進行成膜或高溫加熱處理之情況,亦能獲得期待之形狀的半導體用基板。   再者,本發明之半導體用基板可以使用在半導體基板之製造中通常使用的雙面拋光裝置或單面拋光裝置,或是雙面研磨裝置或單面研磨裝置而低成本且再現性佳地製造。According to the present invention, it is possible to provide a semiconductor substrate having a specific SORI and thickness variation in consideration of the deformation of the semiconductor substrate due to film stress or high-temperature heat treatment in advance. Therefore, even in the case where film formation or high-temperature heat treatment is performed later, a semiconductor substrate in a desired shape can be obtained. Furthermore, the semiconductor substrate of the present invention can be manufactured at low cost and with good reproducibility using a double-sided polishing device or a single-sided polishing device or a double-sided polishing device or a single-sided polishing device commonly used in the manufacture of semiconductor substrates .

以下,針對本發明具體性地進行說明。   與本發明有關之半導體用基板,其特徵在於,具備具有凸狀之SORI之一方的面,和具有與SORI相同程度之凹狀之SORI的另一方之面,並且厚度偏差為3μm以下。   如此一來,藉由於成膜或高溫加熱處理前故意地製造朝與進行成膜或高溫加熱處理之後產生的變形相反方向翹曲之形狀的半導體用基板,製作裝置之階段,或組裝之階段可以獲得期待之形狀的半導體用基板。具體而言,製造事先翹曲成與藉由成膜或高溫加熱工程而變化成凸之情況同程度的凹,與變化成凹之情況相同程度的凸之形狀的半導體用基板。Hereinafter, the present invention will be specifically described. The semiconductor substrate according to the present invention is characterized by having one surface having a convex SORI and the other surface having a concave SORI having the same degree as SORI, and having a thickness deviation of 3 μm or less. In this way, by deliberately manufacturing a semiconductor substrate that warps in a direction opposite to the deformation generated after the film formation or high-temperature heat treatment before the film formation or high-temperature heat treatment, the stage of manufacturing the device or the stage of assembly can be A semiconductor substrate of the desired shape is obtained. Specifically, a semiconductor substrate is produced in which the warped shape is previously concave to the same degree as when it becomes convex by film formation or high-temperature heating process, and convex to the same degree as when it is changed into concave.

雖然本發明之半導體基板中之SORI並不特別限定,若是可以將最終獲得的半導體用基板設為期待的形狀者即可,但是從操作性之觀點來看,較佳為50~600μm,更佳為100~400μm,最佳為100~200μm。   作為本發明中之SORI之態樣,並不特別限定,例如在藉由成膜或高溫加熱工程,半導體用基板中心對稱地變形成凸狀之情況,若製造中心對稱之凹狀的半導體用基板即可(參照圖1(A)),半導體用基板變形成凸狀且頂點中心偏移至Y軸方向的凸狀之情況,若製造配合其偏移之凹狀的半導體用基板即可(參照圖1(B)),半導體用基板變形成相對於通過中心之線為線對稱的凸狀之情況,若製造線對稱之凹狀之半導體用基板即可(參照圖1(C))。Although the SORI in the semiconductor substrate of the present invention is not particularly limited, as long as the semiconductor substrate finally obtained can be formed into a desired shape, from the viewpoint of operability, it is preferably 50 to 600 μm, more preferably It is 100~400μm, the best is 100~200μm. The form of SORI in the present invention is not particularly limited. For example, when a semiconductor substrate is deformed centrally symmetrically into a convex shape by film formation or high-temperature heating process, if a concave semiconductor substrate with a centrally symmetrical shape is manufactured (Refer to FIG. 1(A)), if the semiconductor substrate is deformed into a convex shape and the center of the vertex is shifted to a convex shape in the Y-axis direction, it is sufficient if a concave semiconductor substrate matching the deviation is manufactured (refer to 1(B)), when the semiconductor substrate is deformed into a line-symmetric convex shape with respect to a line passing through the center, a line-symmetric concave semiconductor substrate may be manufactured (see FIG. 1(C)).

在此,本發明中之SORI如圖2所示般,係指最小平方平面S和半導體用基板A之表面之距離的最小值(絕對值)a,和最小值(絕對值)b之和(SORI=|a|+|b|)。   另外,基板表面充分反射光,而能獲得與裝置參考面的干涉紋之情況,可以使用光干涉式平坦式測試儀測定SORI。相反地,基板表面為粗面無法獲得干涉紋之情況,可以以挾入基板表背之方式掃描雷射位移計而求出SORI。Here, as shown in FIG. 2, SORI in the present invention refers to the sum of the minimum value (absolute value) a and the minimum value (absolute value) b of the distance between the least square plane S and the surface of the semiconductor substrate A ( SORI=|a|+|b|).   In addition, if the surface of the substrate sufficiently reflects light and the interference pattern with the reference surface of the device can be obtained, SORI can be measured using an optical interference flat tester. Conversely, if the surface of the substrate is rough and the interference pattern cannot be obtained, the SORI can be obtained by scanning the laser displacement meter so as to penetrate the front and back of the substrate.

另外,在本發明之半導體用基板中,厚度偏差(TTV)考慮容易進行曝光時之對焦,圖案粗度設為一定之情形,設為3μm以下,較佳為2μm以下,更佳為1μm以下。   在此,厚度偏差如圖4 所示般,意味著從在基板A之面內最厚之部分的厚度減去最薄之部分的厚度之值C。另外,厚度偏差與SORI相同,可以使用光干涉式平坦度測試儀或雷射位移計而測定。In addition, in the semiconductor substrate of the present invention, the thickness deviation (TTV) is considered to be easy to focus during exposure, and the pattern thickness is set to be constant, and is set to 3 μm or less, preferably 2 μm or less, and more preferably 1 μm or less.   Here, the thickness deviation as shown in FIG. 4 means the value C minus the thickness of the thinnest part in the plane of the substrate A. In addition, the thickness deviation is the same as SORI, and can be measured using an optical interference flatness tester or a laser displacement meter.

再者,本發明之半導體用基板以具有上述凸狀之SORI之一方之面的BOW為+25~+300為佳,又以具有上述凹狀之SORI之另一方之面的BOW為-25~-300為更佳。   在本發明中,BOW將以基板表面之中心和作為表面基準被獲得的最小平方平均面之高度之差予以數值化,定義成位於較基準面上側之情況標示+符號,位於下側之情況標示-符號。藉此,至少在基板中央,可以判斷基板之形狀為凸或凹。   SORI為凸狀之情況,其一方之面的BOW較佳為+25~+300,更佳為+25~+200、最佳為+25~+100,另一方之面的BOW較佳為-25~-300,更佳為-25~-200,最佳為-25 ~-100。   另外,SORI為凹狀之情況,其一方之面的BOW較佳為-25~-300,更佳為-50~-200、最佳為-50~-100,另一方之面的BOW較佳為+25~+300,更佳為+50~+200,最佳為+50~+100。   如此一來,除了上述特定之SORI外,藉由如BOW般規定基板中央之高度,可以使凸和凹作為數值而成為更明確,可以獲得期待之形狀的半導體用基板。Furthermore, the semiconductor substrate of the present invention preferably has a BOW of one side of the convex SORI of +25 to +300, and a BOW of the other side of the concave SORI of -25 to -300 is better. In the present invention, BOW digitizes the difference between the center of the substrate surface and the height of the smallest squared average surface obtained as the surface reference, and defines the case where it is located on the upper side of the reference plane, the + sign, and the case where it is on the lower side. -symbol. Thus, at least in the center of the substrate, it can be determined whether the shape of the substrate is convex or concave. When the SORI is convex, the BOW on one side is preferably +25~+300, more preferably +25~+200, most preferably +25~+100, and the BOW on the other side is preferably- 25~-300, better -25~-200, best -25~-100. In addition, when the SORI is concave, the BOW on one side is preferably -25 to -300, more preferably -50 to -200, most preferably -50 to -100, and the BOW on the other side is better It is +25~+300, more preferably +50~+200, and the best is +50~+100. In this way, in addition to the specific SORI described above, by specifying the height of the center of the substrate as BOW, the convexity and concavity can be made clear as numerical values, and a semiconductor substrate of the desired shape can be obtained.

在此,本發明中之BOW如圖3所示般,以在從表背中間面e獲得的基準面S2和與基準面S2正交之基板中心線f的交點,和表背中間面e的距離d中,若表背中間面e較基準面S2上側則標示正,若表背中間面e較基準面S2下側則標示負之方式,對絕對值d標示符號者係定義成BOW。   另外,基板表面充分反射光,而能獲得與裝置參考面的干涉紋之情況,可以使用光干涉式平坦式測試儀測定BOW。相反地,基板表面為粗面無法獲得干涉紋之情況,可以以挾入基板表背之方式掃描雷射位移計而求出BOW。Here, as shown in FIG. 3, the BOW in the present invention is based on the intersection of the reference plane S2 obtained from the front and back middle plane e and the substrate center line f orthogonal to the reference plane S2, and the front and back middle plane e In the distance d, if the front and back middle plane e is higher than the upper side of the reference plane S2, it is marked as positive, and if the front and back middle plane e is lower than the lower side of the reference plane S2, it is marked as negative, and the absolute value d is marked as BOW.   In addition, if the surface of the substrate sufficiently reflects light and the interference pattern with the reference surface of the device can be obtained, the BOW can be measured using a light interference flat tester. Conversely, if the surface of the substrate is rough and the interference pattern cannot be obtained, the BOW can be obtained by scanning the laser displacement meter so as to penetrate the front and back of the substrate.

再者,雖然半導體用基板之厚度並不特別限制,但是從基板之操作性或曝光裝置之能夠導入厚度之觀點來看,較佳為0.5~3.0mm,更佳為0.6~1.2mm。In addition, although the thickness of the semiconductor substrate is not particularly limited, from the viewpoint of the operability of the substrate or the thickness of the exposure device that can be introduced, it is preferably 0.5 to 3.0 mm, and more preferably 0.6 to 1.2 mm.

在本發明中,半導體用基板之形狀並不特別限定,可以採用俯視圓形狀或矩形狀等之一般性的形狀。再者,雖然該些之直徑或對角長度並不特別限定,但是較佳為100~450mm,更佳為200~300mm。   雖然本發明之半導體用基板之材質並不特別限制,可以採用玻璃素材、陶瓷素材等以往皆知之材質者,但是從穿透型之多晶矽TFT用之基板需要光通過之點來看,以合成石英玻璃基板為佳,在反射型之TFT之情況,以多晶矽基板為佳。In the present invention, the shape of the semiconductor substrate is not particularly limited, and a general shape such as a circular shape or a rectangular shape in plan view may be adopted. Furthermore, although the diameter or diagonal length of these is not particularly limited, it is preferably 100 to 450 mm, and more preferably 200 to 300 mm. Although the material of the substrate for semiconductors of the present invention is not particularly limited, materials known in the art such as glass materials and ceramic materials can be used, but from the point of view of the need for light to pass through the substrate for the transmissive polysilicon TFT, it is synthesized Quartz glass substrates are preferred. In the case of reflective TFTs, polycrystalline silicon substrates are preferred.

作為具有上述之SORI及BOW之本發明之半導體用基板之製造方法,可考慮在切割工程、拋光工程、研磨工程中之任一工程中,設為期待之形狀的方法。   但是,在切割工程中,一般的線鋸進行切斷之情況,因一面將含有研磨材的漿料施加至被直線性地拉伸的線材,一面切割晶錠,故獲得的半導體用基板在水平方向即是線材方向,隨著線材而成為直線性。另外,在半導體用基板表面上之與線材方向正交之垂直方向,雖然採取使晶錠下降或上升之方法,但是因該方向為再現性佳地直線性使移動的機構所致者,故難以曲線性移動而任意控制SORI和BOW。   再者,因半導體用基板之厚度相對於直徑比較薄,故拋光工程或研磨工程中之成為製作期待的SORI形狀之原動力的基板之反復應力少。藉此,因即使進行拋光加工也會成為維持SORI和BOW之原樣,故難以將表面之SORI設為凸狀,即是設為BOW正,將背面之SORI設為凹狀,即是設為BOW負等,自在地控制基板形狀。As a method of manufacturing the semiconductor substrate of the present invention having the above-mentioned SORI and BOW, a method of setting a desired shape in any of the cutting process, polishing process, and polishing process can be considered. However, in the cutting process, when a general wire saw cuts, since the slurry containing the abrasive is applied to the linearly stretched wire and the ingot is cut, the semiconductor substrate obtained is horizontal The direction is the direction of the wire and becomes linear with the wire. In addition, in the vertical direction perpendicular to the wire direction on the surface of the semiconductor substrate, although the method of lowering or raising the ingot is adopted, this direction is due to the mechanism of good reproducibility and linearity to move, so it is difficult Move SORI and BOW arbitrarily.  Furthermore, since the thickness of the semiconductor substrate is relatively thinner than the diameter, the substrate that becomes the motive force for making the desired SORI shape in the polishing process or the polishing process has less repeated stress. As a result, it is difficult to set the SORI on the surface to be convex, that is, to be BOW positive, and to make the SORI on the back to be concave, that is, to be BOW because the polishing process will maintain the original SORI and BOW. Negative, freely control the shape of the substrate.

於是,在本發明中,使用轉印用母盤,在拋光工程中製造具有期待之SORI及BOW形狀的半導體基板。在本發明被使用的轉印用母盤之形狀係依在轉印工程中被使用之拋光裝置之種類或成為目的之半導體用基板的形狀而有所不同。   例如,在使用雙面拋光裝置之情況,中心對稱之SORI形狀之半導體用基板,可以藉由:準備工程,其係準備轉印用母盤,且該轉印用母盤具有表面及背面,具有相對於通過連結該些表背面之中心點的中心線上之中間點,與中心線正交之面,表面及背面對稱地相向的SORI和厚度偏差;轉印工程,以挾入準備的轉印用母盤之方式,在雙面拋光裝置設置兩片原料基板,對各原料基板中之不與轉印用母盤相接之面進行加工而製作轉印母盤之形狀被轉印至各個單面的兩片轉印基板;拋光工程,其係拋光在該轉印工程獲得之轉印基板之雙面,或僅拋光轉印基板中之轉印用母盤之形狀沒有被轉印之面而製作拋光加工基板,和對拋光加工基板之雙面或單面進行研磨而製造。Therefore, in the present invention, a transfer master is used to manufacture a semiconductor substrate having the expected SORI and BOW shapes in a polishing process. The shape of the transfer master used in the present invention differs depending on the type of polishing device used in the transfer process or the shape of the target semiconductor substrate. For example, in the case of using a double-sided polishing device, a centrally symmetric SORI-shaped semiconductor substrate can be prepared by: a preparation process, which prepares a transfer master, and the transfer master has a front surface and a back surface, having Relative to the center point on the center line that connects the center points of the front and back surfaces, the surface and back surface are symmetrically opposed to the SORI and thickness deviation by the surface orthogonal to the center line; the transfer process is used to carry the prepared transfer In the master mode, two raw material substrates are provided on the double-sided polishing device, and the surface of each raw material substrate that is not in contact with the transfer master is processed to produce the shape of the transfer master and transferred to each single side Two transfer substrates; polishing process, which is made by polishing both sides of the transfer substrate obtained in the transfer process, or only polishing the shape of the transfer master in the transfer substrate without being transferred Polishing the substrate, and grinding and polishing both sides or one side of the substrate.

再者,使用單面拋光裝置之情況,中心對稱之SORI形狀之半導體用基板,可以藉由:準備工程,其係準備轉印用母盤,該轉印用母盤具有表面及背面,相對於通過連結該些表背面之中心點的中心線上之中間點,與中心線正交之面,表背面之中的任一方之面為平行,並且表背面之中與原料基板相接之另一方之面正交於中心線,同時相對於中心線為對稱;轉印工程,以與準備的轉印用母盤之另一方之面相接之方式,在單面拋光裝置設置原料基板,對原料基板中之不與轉印用母盤相接之面進行加工而製作轉印母盤之形狀被轉印至單面的轉印基板;拋光工程,其係拋光轉印基板之雙面,或僅拋光轉印基板中之轉印用母盤之形狀沒有被轉印之面而製作拋光加工基板,和對拋光加工基板之雙面或單面進行研磨而製造。Furthermore, in the case of using a single-sided polishing device, a centrally symmetric SORI-shaped semiconductor substrate can be prepared by: preparing a transfer master, which has a surface and a back surface, with respect to By connecting the middle point on the center line of the center points of the front and back surfaces, the surface orthogonal to the center line, either side of the front and back surfaces is parallel, and the other side of the front and back surfaces that is in contact with the raw substrate The surface is orthogonal to the center line and symmetrical with respect to the center line at the same time; in the transfer process, the raw material substrate is provided on the single-side polishing device by contacting the other side of the prepared transfer master, and the raw material substrate Among them, the surface that is not in contact with the transfer master is processed to make the transfer master. The shape of the transfer master is transferred to the single-sided transfer substrate; polishing process, which is to polish both sides of the transfer substrate, or only polishing In the transfer substrate, the shape of the transfer master is not transferred, a polished substrate is produced, and both sides or one side of the polished substrate are polished and manufactured.

在本發明使用之雙面拋光裝置及單面拋光裝置並不特別限制,可以從眾知之裝置適當選擇使用。   轉印工程中之雙面拋光裝置及單面拋光裝置之旋轉數皆以5~50rpm為佳,負載以10~200g/cm2 為佳,在雙面拋光裝置中,每時間單位之取代以雙面幾乎相同為佳。The double-sided polishing device and single-sided polishing device used in the present invention are not particularly limited, and can be appropriately selected and used from known devices. Transferring the double-side polishing apparatus projects and the number of rotations of the single-side polishing apparatus preferably 5 ~ 50rpm begin with, the load at 10 ~ 200g / cm preferably, in the double-side polishing apparatus, per unit of time to the substituted 2-bis The faces are almost the same.

雖然轉印用母盤之材質並不特別限定,可以採用氧化鋁陶瓷、金屬、樹脂等,但是從變形或破損之觀點來看,以氧化鋁陶瓷為佳。   再者,作為研磨劑,除使用平均粒徑較佳為5~20μm之氧化鋁系之研磨材,使用以水分散20~60質量%者之外,亦可以碳化矽系或人工鑽石等。Although the material of the transfer master is not particularly limited, alumina ceramic, metal, resin, etc. can be used, but from the viewpoint of deformation or breakage, alumina ceramic is preferable.   Furthermore, as the abrasive, in addition to using an alumina-based abrasive having an average particle size of preferably 5 to 20 μm, and a dispersion of 20 to 60% by mass in water, silicon carbide or artificial diamond may also be used.

在轉印工程中,使用雙面拋光之情況,以如同上述般挾入轉印用母盤之方式,在載體內封兩片原料基板,且分別設置在雙面拋光裝置之下側拋光壓盤及上側拋光壓盤而進行加工。   通常,雖然雙面拋光裝置配合一片原料基板之厚度,調整載體之厚度,但是本發明之情況係以考慮原料基板兩片和轉印用母盤之厚度量,而將載體之厚度設定成較厚為佳。其他,可以與通常的拋光加工無特別不同地進行加工。   在該階段中,因變成同時加工兩片原料基板之各個單面側,故轉印用母盤之形狀僅被轉印至與下側拋光壓盤及上側拋光壓盤接觸的單面側,另外,因與轉印用母盤相接之面沒有被加工,故無變化。In the transfer process, when double-sided polishing is used, two raw material substrates are enclosed in the carrier in such a way that the transfer master is inserted as described above, and they are respectively provided under the double-sided polishing device to polish the platen And polish the platen on the upper side for processing. Generally, although the double-sided polishing device adjusts the thickness of the carrier in conjunction with the thickness of one raw material substrate, in the case of the present invention, the thickness of the carrier is set to be thick considering the thickness of the two raw material substrates and the transfer master Better. In addition, it can be processed without any special difference from ordinary polishing. At this stage, since it becomes the processing of each single-sided side of the two raw material substrates at the same time, the shape of the transfer master is only transferred to the single-sided side that is in contact with the lower polishing platen and the upper polishing platen. Since the surface in contact with the transfer master is not processed, there is no change.

因轉印用母盤之中央較外周厚,故轉印工程之初期,原料基板和拋光壓盤的加工壓集中在原料基板之中心。此時,因原料基板薄且反作用力少,故切削從原料基板之中心選擇性地進行。若切削進行,加工到達至原料基板之外周,則最終轉印用母盤之形狀被轉印至不與轉印用母盤接觸之原料基板相反側之面(即是,與拋光壓盤相接之面)。   轉印用母盤之外周部較中心部薄之情況,因應該外周部和中心部之厚度的差,在轉印工程獲得的原料基板之外周部變得較中心部厚。相反地,轉印用母盤之外周部較中心部厚之情況,因應該外周部和中心部之厚度的差,在轉印工程獲得的原料基板之外周部變得較中心部薄。如此一來,可以因應轉印用母盤之形狀,創造被轉印之形狀。Since the center of the transfer master is thicker than the outer periphery, the processing pressure of the raw substrate and polishing platen is concentrated at the center of the raw substrate at the beginning of the transfer process. At this time, since the raw material substrate is thin and there is little reaction force, cutting is selectively performed from the center of the raw material substrate. When cutting is performed and the processing reaches the outer periphery of the raw material substrate, the shape of the final transfer master is transferred to the surface of the raw material substrate that does not contact the transfer master (that is, it is in contact with the polishing platen Face). When the outer peripheral portion of the transfer master is thinner than the central portion, the outer peripheral portion of the raw material substrate obtained in the transfer process becomes thicker than the central portion due to the difference in thickness between the outer peripheral portion and the central portion. Conversely, when the outer peripheral portion of the transfer master is thicker than the central portion, the outer peripheral portion of the raw material substrate obtained in the transfer process becomes thinner than the central portion due to the difference in thickness between the outer peripheral portion and the central portion. In this way, the shape to be transferred can be created according to the shape of the transfer master.

另外,在轉印工程中,在使用單面拋光裝置之情況,在原料基板和單面拋光裝置之頂板之間,以使平坦之面朝向頂板側之方式,設置轉印用母盤,並且以原料基板和轉印用母盤不橫向脫落之方式,將載體固定在頂板之後,對原料基板進行加工。原料基板係藉由單面拋光裝置之下側拋光壓盤進行加工,隨著加工進行,轉印用母盤之形狀僅被轉印至原料基板之下側拋光壓盤側之面。In addition, in the transfer process, when a single-sided polishing device is used, between the raw material substrate and the top plate of the single-sided polishing device, a transfer master is provided so that the flat surface faces the top plate side, and the After the carrier substrate is fixed to the top plate in such a way that the raw material substrate and the transfer master do not fall off laterally, the raw material substrate is processed. The raw material substrate is processed by the polishing platen on the lower side of the single-side polishing device. As the processing proceeds, the shape of the transfer master is transferred only to the surface on the polishing platen side of the raw material substrate.

針對經過上述轉印工程之轉印基板,使用雙面拋光裝置或單面拋光裝置而進行拋光加工。雙面拋光裝置及單面拋光裝置之旋轉數皆以5~50rpm為佳,負載以10~200g/cm2 為佳。   使用雙面拋光裝置之情況,以使平坦之面朝向雙面拋光裝置之上側拋光壓盤側之方式,設置轉印基板,設置用以防止基板脫落之載體,進行通常的拋光加工。藉此,獲得上側面被拋光加工成凸狀,下側面被拋光加工成凹狀的拋光加工基板。拋光加工基板之SORI之值成為拋光加工前之SORI之值的約一半左右,減少程度也依存於轉印基板之直徑和厚度。   製作表背面之形狀的原理係藉由在初期形狀已經存在的厚度偏差,在雙面從加工初期產生面內加工壓力差,藉此被切削之部分選擇性地並且歷時地變化。藉此,基板面內之加工分布也隨此變化而進行加工。其結果,也依存於轉印基板之反作用力,即是轉印基板之直徑和厚度,並且原來的拋光工程前之基板形狀減半,同時反應在雙面之形狀。For the transfer substrate that has undergone the above transfer process, a double-sided polishing device or a single-sided polishing device is used for polishing. The rotation speed of the double-sided polishing device and the single-sided polishing device is preferably 5-50 rpm, and the load is preferably 10-200 g/cm 2 . In the case of using a double-sided polishing device, a transfer substrate is provided so that the flat surface faces the polishing platen side of the upper side of the double-sided polishing device, and a carrier for preventing the substrate from falling off is provided to perform normal polishing. Thereby, a polished substrate in which the upper side is polished into a convex shape and the lower side is polished into a concave shape is obtained. The SORI value of the polished substrate becomes about half of the SORI value before polishing, and the degree of reduction also depends on the diameter and thickness of the transfer substrate. The principle of making the shape of the front and back of the surface is that the thickness difference existing in the initial shape causes an in-plane processing pressure difference from the initial processing on both sides, thereby selectively and chronologically changing the part to be cut. With this, the processing distribution in the substrate surface is also processed with this change. As a result, it also depends on the reaction force of the transfer substrate, that is, the diameter and thickness of the transfer substrate, and the original substrate shape before the polishing process is halved, while reflecting the shape of both sides.

在使用單面拋光裝置之情況,在其下側拋光壓盤和頂板之間,以平坦之面朝向下側拋光壓盤側之方式,設置轉印基板,以轉印基板不橫向脫落之方式設置載體而進行拋光加工。在此情況,因僅對沒有被轉印之面進行拋光加工,故原來的轉印用壓盤之轉印側表面之SORI和獲得的拋光加工基板之SORI同等。In the case of using a single-sided polishing device, between the lower polishing platen and the top plate, a transfer substrate is provided with a flat surface facing the lower polishing platen side, so that the transfer substrate does not fall off laterally The carrier is polished. In this case, since only the surface that has not been transferred is polished, the SORI of the transfer-side surface of the original transfer platen is the same as the SORI of the polished substrate obtained.

以上述拋光加工工程獲得的拋光加工基板為了鏡面化,因應所需進一步進行研磨雙面或單面的研磨工程。   在研磨工程中,可以使用雙面研磨裝置或單面研磨裝置。進行鏡面化的面可為具有凸狀之SORI及BOW正之面或具有凹狀之SORI及BOW負之面之任一面亦可。   如此一來,最終,可以製作具有如圖1所示之期待之形狀(SORI及BOW)之各種半導體用基板。In order to mirror-finish the polished substrate obtained by the above-mentioned polishing process, a double-sided or single-sided polishing process is further performed as required.   In the polishing process, a double-sided polishing device or a single-sided polishing device can be used. The mirror-finished surface may be either a positive surface with convex SORI and BOW or a negative surface with concave SORI and BOW. In this way, finally, various semiconductor substrates having the expected shapes (SORI and BOW) as shown in FIG. 1 can be produced.

以下,邊參照圖面邊針對本發明之實施型態予以說明。   圖5為表示與本發明之第1實施型態有關之使用雙面拋光裝置1之轉印工程之實施態樣。   在該實施型態中,如圖5所示般,在以兩片原料基板11、11挾入轉印用母盤10之方式被內封在載體12之狀態,分別被設置在雙面拋光裝置1之下側拋光壓盤13及上側拋光壓盤14。Hereinafter, an embodiment of the present invention will be described with reference to the drawings. FIG. 5 is an embodiment of a transfer process using the double-sided polishing apparatus 1 related to the first embodiment of the present invention. In this embodiment, as shown in FIG. 5, the two raw material substrates 11 and 11 are enclosed in the carrier 12 in such a manner that they are encased in the transfer master 10, and are respectively installed in the double-sided polishing device. 1 Lower polishing platen 13 and upper polishing platen 14.

在該實施型態使用之轉印用母盤10如圖6所示般,具有相對於通過連結轉印用母盤10之表面100之中心點100A和背面110之中心點110A之中心線L1上的各中心點100A、110A之中間點M1,並且正交於中心線L1之假想面S1,表面100及背面110對稱地相向之凸狀的SORI和厚度偏差,具有相對於中心線L1為對稱的表背面形狀。As shown in FIG. 6, the transfer master 10 used in this embodiment has a center line L1 relative to the center point 100A passing through the front surface 100 of the transfer master 10 and the center point 110A of the back surface 110. The middle point M1 of each center point 100A, 110A, and is orthogonal to the imaginary plane S1 of the center line L1, the convex SORI and thickness deviation of the surface 100 and the back surface 110 symmetrically facing each other, has a symmetrical relative to the center line L1 Table back shape.

再者,在本實施型態中使用的原料基板11係使用線材而切割合成石英玻璃製晶錠,進行倒角加工,藉由雙面拋光裝置除去表背面之鋸痕而被製作出,為直徑100mm,厚度630μm,表背面之SORI分別為6μm,及表背面之BOW分別為+3μm、-3μm,厚度偏差為1μm圓板狀。Furthermore, the raw material substrate 11 used in the present embodiment is manufactured by cutting a crystal ingot made of synthetic quartz glass using a wire, chamfering, and removing the saw marks on the front and back surfaces by a double-sided polishing device. 100mm, thickness 630μm, SORI on the front and back are 6μm, and BOW on the front and back are +3μm, -3μm, thickness deviation is 1μm disc-shaped.

如上述般,在設置有兩片原料基板11之狀態,以雙面拋光裝置1之旋轉數20rpm,負載100g/cm2 ,同時加工各原料基板11之單面側,能獲得轉印用母盤10之形狀被轉印至單面側之轉印基板。   接著,如圖7所示般,以使平坦面朝向雙面拋光裝置1之上側拋光壓盤14側之方式,將轉印用母盤10之形狀被轉印至單面側之轉印基板11A之一片內封在載體12而設置,以旋轉數20rpm、負載100g/cm2 進行雙面拋光加工,即使針對在轉印工程沒有被轉印之面,也轉印轉印用母盤10之形狀,藉此能獲得上側面被拋光加工成凸狀,下側面被拋光加工成凹狀之拋光加工基板。As described above, in a state where two raw material substrates 11 are provided, the single-sided side of each raw material substrate 11 is processed at the same time with a rotation speed of 20 rpm of the double-sided polishing device 1 and a load of 100 g/cm 2 to obtain a transfer master. The shape of 10 is transferred to the transfer substrate on one side. Next, as shown in FIG. 7, the shape of the transfer master 10 is transferred to the single-sided transfer substrate 11A so that the flat surface faces the upper polishing platen 14 side of the double-side polishing device 1. One piece is set inside the carrier 12 and is subjected to double-sided polishing at a rotation number of 20 rpm and a load of 100 g/cm 2. Even if the surface is not transferred in the transfer process, the shape of the transfer master 10 is transferred. In this way, a polished substrate in which the upper side is polished into a convex shape and the lower side is polished into a concave shape can be obtained.

針對獲得的拋光加工基板,藉由以雙面研磨裝置(省略圖示)對雙面予以鏡面化,能獲得具有如圖1(A)所示般之中心對稱的SORI之合成石英玻璃基板。具體而言,表面之SORI為50μm的凸狀,BOW為+25μm,背面之SORI為50μm的凹狀,BOW為-25μm,面內厚度偏差為1μm,並且厚度500μm之雙面為鏡面之合成石英玻璃基板。With respect to the obtained polished substrate, by mirroring both sides with a double-sided polishing device (not shown), a synthetic quartz glass substrate having SORI with center symmetry as shown in FIG. 1(A) can be obtained. Specifically, the SORI on the surface is convex at 50 μm, the BOW is +25 μm, the SORI on the back is concave at 50 μm, the BOW is -25 μm, the in-plane thickness deviation is 1 μm, and the 500 μm thick double-sided mirror is synthetic quartz Glass base board.

圖8表示與本發明之第2實施型態有關之使用單面拋光裝置2之轉印工程之實施態樣。另外,在第2實施型態中,針對與上述第1實施型態相同之構件,賦予相同符號。   在該實施型態使用的轉印用母盤20如圖9所示般,具有相對於通過連結轉印用母盤20之表面200之中心點200A和背面210之中心點210A的中心線L2上的各中心點200A、210A之中間點M2,並且正交於中心線L2之假想面S2,表面200為平行(平坦面),背面210垂直於中心線L2,並且相對於中心線L2為對稱的沿著凸狀的形狀。FIG. 8 shows an embodiment of the transfer process using the single-side polishing device 2 related to the second embodiment of the present invention. In addition, in the second embodiment, the same members as those in the first embodiment described above are given the same symbols. As shown in FIG. 9, the transfer master 20 used in this embodiment has a center line L2 that passes through the center point 200A connecting the front surface 200 of the transfer master 20 and the center point 210A of the back surface 210. The middle point M2 of each center point 200A, 210A, and orthogonal to the imaginary plane S2 of the center line L2, the surface 200 is parallel (flat surface), the back 210 is perpendicular to the center line L2, and is symmetrical with respect to the center line L2 Along the convex shape.

再者,在本實施型態中使用的原料基板21,係以與第1實施型態相同之手法而被製作,直徑200mm、厚度855μm、表背面側之SORI分別為6μm,厚度偏差為1μm之圓板狀之合成石英玻璃基板。In addition, the raw material substrate 21 used in the present embodiment is manufactured in the same manner as the first embodiment, the diameter is 200 mm, the thickness is 855 μm, the SORI on the front and back sides is 6 μm, and the thickness deviation is 1 μm. Disc-shaped synthetic quartz glass substrate.

如圖8所示般,在以使轉印用母盤20之平坦之面朝向頂板25側之方式進行配置,並且設為與在轉印用母盤20沿著凸狀之面相接來將原料基板21設置在單面拋光裝置2,將該些內封在載體12之狀態,以旋轉數20rpm、負載100g/cm2,藉由下側拋光壓盤13僅加工原料基板21中之不與轉印用母盤20相接之面,藉此獲得轉印用母盤20之形狀被轉印至單面側的轉印基板。As shown in FIG. 8, it is arranged such that the flat surface of the transfer master 20 faces the top plate 25 side, and is set to be in contact with the transfer master 20 along the convex surface. The raw material substrate 21 is set in the single-side polishing device 2, and these are enclosed in the carrier 12 at a rotation number of 20 rpm and a load of 100 g/cm2. By the lower polishing platen 13, only the raw material substrate 21 is processed. The surface on which the printing master 20 is in contact is obtained, thereby obtaining a transfer substrate whose shape is transferred to the single-sided side.

接著,如圖10所示般,在單面拋光裝置2之下側拋光壓盤13和頂板25之間,將轉印用母盤20之形狀被轉印至單面側之轉印基板21A,在使轉印用母盤20之形狀被轉印的面朝向頂板25側之狀態,內封在載體12而設置,以旋轉數20rpm、負載100g/cm2 進行單面拋光加工,即使針對在轉印工程沒有被轉印之面,也將轉印用母盤20之形狀進行轉印,藉此能獲得上側面被拋光加工成凹狀,下側面被拋光加工成凸狀之拋光加工基板。Next, as shown in FIG. 10, between the polishing platen 13 on the lower side of the single-side polishing device 2 and the top plate 25, the shape of the transfer master 20 is transferred to the transfer substrate 21A on the single-side side. In a state where the shape of the transfer master disk 20 to be transferred faces the top plate 25 side, it is installed inside the carrier 12 and is polished on one side at a rotation number of 20 rpm and a load of 100 g/cm 2 , even for In the printing process, the surface of the transfer master 20 is also transferred by transferring the shape of the transfer master plate 20, thereby obtaining a polished substrate whose upper side is polished into a concave shape and whose lower side is polished into a convex shape.

針對獲得的拋光加工基板,與第1實施型態相同,藉由對雙面予以鏡面化,能獲得具有如圖1(A)所示般之中心對稱的SORI之合成石英玻璃基板。具體而言,表面為SORI100μm的凸狀,及BOW為+50μm,背面為SORI110μm的凹狀,及BOW為-50μm,面內厚度偏差為1μm,並且厚度725μm之雙面為鏡面的合成石英玻璃基板。With respect to the obtained polished substrate, as in the first embodiment, by mirroring both sides, a synthetic quartz glass substrate having SORI with center symmetry as shown in FIG. 1(A) can be obtained. Specifically, the surface has a convex shape of SORI100μm, BOW is +50μm, the back surface is SORI110μm concave, and BOW is -50μm, the in-plane thickness deviation is 1μm, and the thickness is 725μm. .

另外,針對本發明之半導體用基板之製造方法所使用的轉印用母盤之形狀、厚度及SORI、原料基板之形狀及材質以及各加工之具體的條件等,並不限定於上述各實施型態,在可達成本發明之目的、效果之範圍的變更或改良也包含在本發明。In addition, the shape, thickness and SORI of the transfer master used in the manufacturing method of the semiconductor substrate of the present invention, the shape and material of the raw material substrate, and the specific conditions of each process, etc. are not limited to the above-mentioned embodiments In addition, changes or improvements within the scope that can achieve the purpose and effect of the invention are also included in the present invention.

例如,在使用雙面拋光裝置製造具有非中心對稱之SORI之半導體基板之情況,若在上述第1實施型態中,使用圖11所示的轉印用母盤30即可。   該轉印用母盤30具有相對於通過連結表面300之頂點300A和背面310之頂點310A之直線L3中的上述各頂點300A、310A之中間點M3,並且與直線L3正交之假想面S3,表面300及背面310對稱地相向之凸狀的SORI。   使用該轉印用母盤30,與第1實施型態相同,藉由進行轉印加工、拋光加工、研磨加工等,可得到圖1(B)所示般之凸狀之頂點從中心偏移至Y軸方向的凸狀,可以獲得BOW正翹曲的半導體基板。For example, in the case of manufacturing a semiconductor substrate having non-centrosymmetric SORI using a double-sided polishing device, in the above-described first embodiment, the transfer master 30 shown in FIG. 11 may be used. The transfer master 30 has an imaginary plane S3 that is relative to the middle point M3 of the vertices 300A and 310A among the straight lines L3 passing through the apex 300A of the front surface 300 and the apex 310A of the back surface 310, and is orthogonal to the straight line L3. The surface 300 and the back surface 310 are symmetrically convex SORIs facing each other. Using this transfer master 30, as in the first embodiment, by performing transfer processing, polishing processing, polishing processing, etc., a convex apex as shown in FIG. 1(B) can be shifted from the center The convex shape in the Y-axis direction can obtain a semiconductor substrate with positive BOW warpage.

再者,在使用單面拋光裝置製造具有非中心對稱之SORI之半導體基板之情況,若在上述第2實施型態中,使用圖12所示的轉印用母盤40即可。   該轉印用母盤40具有相對於通過連結背面410之頂點410A,和與此相對之表面400上之部分點400A之直線L4中的上述頂點410A和部分點400之中間點M4,並且與直線L4正交之假想面S4,表面400為平行(平坦面),背面410為凸狀之SORI。   使用該轉印用母盤40,與第2實施型態相同,藉由進行轉印加工、拋光加工、研磨加工等,可得到圖1(B)所示般之凸狀之頂點從中心偏移至Y軸方向的凸狀,可以獲得BOW正翹曲的半導體基板。In addition, in the case of manufacturing a semiconductor substrate having non-centrosymmetric SORI using a single-side polishing device, in the second embodiment described above, the transfer master 40 shown in FIG. 12 may be used. The transfer master 40 has an intermediate point M4 between the vertex 410A and the intermediate point M4 in the straight line L4 passing through the vertex 410A connecting the back surface 410 and the partial point 400A on the opposite surface 400, and is in line with the straight line The imaginary plane S4 where L4 is orthogonal, the front surface 400 is parallel (flat surface), and the back surface 410 is a convex SORI. Using this transfer master 40, as in the second embodiment, by performing transfer processing, polishing processing, polishing processing, etc., a convex apex as shown in FIG. 1(B) can be shifted from the center The convex shape in the Y-axis direction can obtain a semiconductor substrate with positive BOW warpage.

並且,在上述第1實施型態中,使用在設置如圖13所示般之在轉印用母盤的表面上正交的XY軸之時,從X方向及Y方向之剖面觀看到的厚度形狀,持有相對於貫穿在X方向及Y方向從中央朝向外周傾斜為不同的轉印用母盤之表面上之中心之線(在圖13中為Y軸)為線對稱的厚度偏差之轉印用母盤之情況,能獲得圖1(C)所示之半導體用基板。另外,在圖13之基板內側之曲線表示厚度之等高線。 [實施例]In addition, in the first embodiment described above, when the XY axis orthogonal to the surface of the transfer master as shown in FIG. 13 is provided, the thickness viewed from the cross section in the X direction and the Y direction is used The shape holds a thickness deviation that is linearly symmetrical with respect to the center line (Y axis in FIG. 13) passing through the center of the surface of the transfer master which is inclined from the center to the outer circumference in the X direction and the Y direction. In the case of a printing master, the semiconductor substrate shown in FIG. 1(C) can be obtained. In addition, the curve on the inside of the substrate in FIG. 13 represents the contour of thickness. [Example]

以下,雖然舉出實施例及比較例,更具體性地說明本發明,但是本發明並不限定於下述之實施例。Hereinafter, although the examples and comparative examples are given to explain the present invention more specifically, the present invention is not limited to the following examples.

[實施例1]   作為轉印用母盤,準備如圖6所示之形狀者。具體而言,準備表背面之SORI皆相同,為凸狀的110μm,相對於通過連結表背面之中心點之中心線上的中間點,與中心線正交之面,表背面對稱地相向,並且厚度偏差為220μm之中央厚度3mm,直徑100mm之氧化鋁陶瓷製轉印用母盤。   再者,使用東洋先進工具機(股)製作的線鋸E450E-12而切割合成石英玻璃製晶錠,進行倒角加工,藉由雙面拋光裝置除去表背面之鋸痕,準備直徑100mm、厚度630μm、表背面之SORI分別為6μm,厚度偏差為1μm之原料基板。   以挾入上述轉印用母盤之方式,將原料基板兩片分別設置在雙面拋光裝置之下側拋光壓盤及上側拋光壓盤,使用以序號為#1000之氧化鋁為主成分之拋光材,以旋轉數20rpm、負載100g/cm2 ,同時加工各原料基板之單面側,獲得兩片轉印用母盤之形狀被轉印至單面側的轉印基板。獲得的轉印基板之形狀皆單面凹狀地翹曲110μm。[Example 1] As the transfer master, a shape as shown in FIG. 6 was prepared. Specifically, the SORIs prepared for the front and back surfaces are all the same, 110 μm convex, with respect to the middle point on the center line passing through the center point connecting the back and front surfaces, the surface orthogonal to the center line, the front and back surfaces are symmetrically opposed, and the thickness The deviation is 220μm with a central thickness of 3mm and a diameter of 100mm made of alumina ceramic transfer master. Furthermore, the wire saw E450E-12 made by Toyo Advanced Machine Tool Co., Ltd. was used to cut the ingot made of synthetic quartz glass, chamfering, and the saw marks on the back and back of the table were removed by a double-sided polishing device. The diameter was 100 mm and the thickness was prepared. 630μm, raw material substrate with SORI of 6μm and thickness deviation of 1μm on the front and back respectively. Using the above-mentioned transfer master, place the two raw material substrates on the lower polishing platen and upper polishing platen of the double-sided polishing device, and use aluminum oxide with the serial number #1000 as the main component for polishing The material was processed at a rotation speed of 20 rpm and a load of 100 g/cm 2 while processing the single-sided side of each raw material substrate to obtain a transfer substrate in which the shape of two transfer masters was transferred to the single-sided side. The shapes of the obtained transfer substrates were all concavely warped by 110 μm on one side.

在雙面拋光裝置設置獲得的轉印基板之一片,與上述轉印工程相同,使用拋光材,以旋轉數20rpm、負載100g/cm2 進行雙面拋光加工,即使針對在先前的轉印工程沒有被轉印之面,也轉印轉印用母盤之形狀。而且,獲得表面為SORI50μm之凸狀,及BOW為+25μm,背面為SORI50μm之凹狀,及BOW為-25μm的拋光加工基板。   並且,作為研磨獲得的拋光加工基板之雙面的工程,以雙面裝置對雙面予以鏡面化,獲得表面為SORI50μm之凸狀及BOW為+25μm,背面為SORI50μm之凹狀及BOW為+25μm,面內厚度偏差(TTV)為1μm,厚度為500μm之雙面為鏡面之合成石英玻璃基板。   接著,在獲得的合成石英玻璃基板之表面,供給矽烷氣體,形成非晶質矽膜之後,進行退火處理,形成多晶矽膜之後,成膜的面變化成SORI122μm的凸狀,另一方之面變化成SORI1222μm的凹狀。   之後,進一步進行一小時1050℃之熱處理之後,能獲得成膜的面變化成SORI4μm之凸狀,另一方之面變化成SORI4μm之凹狀,面內厚度偏差(TTV)為1μm,具有幾乎平坦的SORI之多晶矽TFT用合成石英玻璃基板。Set one of the obtained transfer substrates on the double-sided polishing device, the same as the above transfer process, using the polishing material, the number of rotations 20rpm, load 100g/cm 2 double-sided polishing process, even for the previous transfer process The transferred surface also transfers the shape of the transfer master. Furthermore, a polished substrate with a SORI surface of 50 μm convex, BOW of +25 μm, a back surface of SORI of 50 μm concave, and a BOW of -25 μm was obtained. In addition, as a process of polishing both sides of the polished substrate obtained by polishing, the two sides were mirror-finished with a double-sided device to obtain a convex shape with a surface of SORI50μm and a BOW of +25μm, and a concave surface with a surface of SORI50μm and a BOW of +25μm , In-plane thickness deviation (TTV) is 1μm, and the thickness is 500μm, the double-sided mirror quartz glass substrate. Next, on the surface of the obtained synthetic quartz glass substrate, silane gas was supplied to form an amorphous silicon film, and then annealed to form a polycrystalline silicon film. The film-forming surface changed to SORI122μm convex shape, and the other surface changed to SORI1222μm concave. Then, after further heat treatment at 1050°C for one hour, the film-forming surface can be changed to a convex shape of SORI 4 μm, and the other surface can be changed to a concave shape of SORI 4 μm. The in-plane thickness deviation (TTV) is 1 μm, and it has almost flat SORI's synthetic quartz glass substrate for polysilicon TFT.

[實施例2]   使用雙面拋光裝置,以與實施例1相同之手法進行轉印工程之後,設置獲得的轉印基板以使轉印用母盤之形狀被轉印的面朝向單面拋光裝置之頂板側的方式,以旋轉數200rpm,荷重100g/cm2 進行單面拋光加工,獲得拋光加工基板。   並且,以與實施例1相同之方法研磨獲得的拋光加工基板之雙面,獲得表面為SORI110μm之凸狀及BOW為+55μm,背面為SORI 110μm之凹狀及BOW為-55μm,面內厚度偏差(TTV)為1μm,厚度為500μm之雙面為鏡面之合成石英玻璃基板。   接著,以與實施例1相同之方法在獲得的合成石英玻璃基板形成多晶矽膜之後,成膜的面變化成SORI122μm之凸狀,另一方之面變化成SORI122μm之凹狀。   之後,進一步進行一小時1050℃之熱處理之後,能獲得成膜的面變化成SORI4μm之凸狀,另一方之面變化成SORI4μm之凹狀,面內厚度偏差(TTV)為1μm,具有幾乎平坦的SORI之多晶矽TFT用合成石英玻璃基板。[Example 2] After the transfer process was carried out in the same manner as in Example 1 using a double-sided polishing device, the obtained transfer substrate was set so that the surface to which the shape of the transfer master was transferred faced the single-sided polishing device On the top plate side, a single-side polishing process was performed at a rotation number of 200 rpm and a load of 100 g/cm 2 to obtain a polished substrate. Furthermore, the polished substrates obtained on both sides were ground in the same manner as in Example 1. The surface was convex with SORI110μm and BOW was +55μm, the back surface was SORI with 110μm concave and BOW was -55μm, and the in-plane thickness deviation (TTV) is a synthetic quartz glass substrate with a mirror surface of 1 μm and a thickness of 500 μm. Next, after forming a polycrystalline silicon film on the obtained synthetic quartz glass substrate in the same manner as in Example 1, the film-forming surface changed to a convex shape of SORI 122 μm, and the other surface changed to a concave shape of SORI 122 μm. Then, after further heat treatment at 1050°C for one hour, the film-forming surface can be changed to a convex shape of SORI 4 μm, and the other surface can be changed to a concave shape of SORI 4 μm. The in-plane thickness deviation (TTV) is 1 μm, and it has almost flat SORI's synthetic quartz glass substrate for polysilicon TFT.

[實施例3]   作為轉印用母盤,準備如圖9所示之形狀者。具體而言,準備表背面之中一方之面為平坦,並且另一方之面正交於連結表背面之中心的中心線,並且相對於中心線為對稱地凸狀地翹曲110μm之形狀,並且面內厚度偏差(TTV)為110μm之中央之厚度2mm,直徑200mm之氧化鋁製轉印母盤。   作為原料基板,以與實施例1相同之方法,準備直徑200mm,厚度855μm,表背面側之SORI分別為6μm,厚度偏差為1μm的石英玻璃基板。   在該原料基板和單面拋光裝置之頂板之間,以使平坦之面朝向頂板側之方式,設置上述轉印用母盤,使用以序號為#1000之氧化鋁為主成分之拋光材,以旋轉數20rpm,荷重100g/cm2 ,對原料基板之單面側進行加工,獲得轉印用母盤之形狀被轉印至單面側的轉印基板。獲得的轉印基板之形狀係單面為平坦,另一方之面凹狀地翹曲110μm。[Example 3] As the transfer master, a shape as shown in FIG. 9 was prepared. Specifically, one of the front and back surfaces is flat, and the other surface is orthogonal to the center line connecting the centers of the front and back surfaces, and is symmetrically convexly warped by 110 μm with respect to the center line, and The in-plane thickness deviation (TTV) is a transfer master disk made of alumina with a thickness of 2 mm at the center of 110 μm and a diameter of 200 mm. As a raw material substrate, a quartz glass substrate having a diameter of 200 mm, a thickness of 855 μm, a SORI of 6 μm on the front and back sides, and a thickness deviation of 1 μm was prepared in the same manner as in Example 1. Between the raw material substrate and the top plate of the single-side polishing device, the above-mentioned transfer master is provided so that the flat surface faces the top plate side, and a polishing material with alumina as the main component of the serial number #1000 is used to The number of rotations was 20 rpm and the load was 100 g/cm 2. The single-sided side of the raw material substrate was processed to obtain a transfer substrate whose shape of the transfer master was transferred to the single-sided side. The shape of the obtained transfer substrate was flat on one side, and the other side was warped by 110 μm concavely.

接著,在單面拋光裝置之下側拋光壓盤和頂板之間,以使被轉印之面朝向單面拋光裝置之頂板側的方式設置轉印基板,與上述轉印工程相同使用拋光材,以旋轉數20rpm、荷重100g/cm2 ,進行單面加工,獲得拋光加工基板。獲得的加工基板係表面為SORI10μm之凸狀,背面為SORI110μm之凹狀的拋光加工基板。   並且,以單面研磨裝置對凸側之單面予以鏡面化,獲得表面為SORI110μm之凸狀及BOW為+55μm,背面為SORI為110μm之凹狀及BOW為-55μm,面內厚度偏差(TTV)為1μm,厚度為725μm之合成石英玻璃基板。   以與實施例1相同之方法,在獲得的合成石英玻璃基板形成多晶矽膜之後,成膜的面變化成SORI122μm之凸狀,另一方之面變化成SORI122μm之凹狀。   之後,進一步進行一小時1050℃之熱處理之後,能獲得成膜的面變化成SORI4μm之凸狀,另一方之面變化成SORI4μm之凹狀,面內厚度偏差(TTV)為1μm,具有幾乎平坦的SORI之多晶矽TFT用合成石英玻璃基板。Next, between the polishing platen on the lower side of the single-side polishing device and the top plate, a transfer substrate is provided so that the surface to be transferred faces the top plate side of the single-side polishing device, and the polishing material is used in the same manner as the above transfer process. One-sided processing was performed at a rotation number of 20 rpm and a load of 100 g/cm 2 to obtain a polished substrate. The obtained processed substrate was a polished processed substrate with a SORI 10 μm convex surface and a back surface SORI 110 μm concave shape. In addition, the single surface of the convex side was mirror-finished with a single-sided polishing device to obtain a convex surface with a SORI of 110 μm and a BOW of +55 μm, and a back surface with a concave of a SORI of 110 μm and a BOW of -55 μm, and the in-plane thickness deviation (TTV ) Is a synthetic quartz glass substrate of 1 μm and a thickness of 725 μm. In the same manner as in Example 1, after the polysilicon film was formed on the obtained synthetic quartz glass substrate, the film-forming surface changed to a convex shape of SORI 122 μm, and the other surface changed to a concave shape of SORI 122 μm. Then, after further heat treatment at 1050°C for one hour, the film-forming surface can be changed to a convex shape of SORI 4 μm, and the other surface can be changed to a concave shape of SORI 4 μm. The in-plane thickness deviation (TTV) is 1 μm, and it has almost flat SORI's synthetic quartz glass substrate for polysilicon TFT.

[實施例4]   以與實施例1相同之方法對以與實施例3相同之方法進行轉印工程而獲得的轉印基板進行雙面拋光加工,獲得表面為SORI50μm之凸狀,背面為SORI150μm之凹狀的拋光加工基板。   並且,以與實施例1相同之方法研磨雙面,獲得表面為SORI150μm之凸狀及BOW為+25μm,背面為SORI50μm之凹狀及BOW為-25μm,厚度偏差為1μm,厚度為725μm之雙面為鏡面之合成石英玻璃基板。   以與實施例1相同之方法,在獲得的合成石英玻璃基板形成多晶矽膜之後,成膜的面變化成SORI122μm之凸狀,另一方之面變化成SORI122μm之凹狀。   之後,進一步進行一小時1050℃之熱處理之後,能獲得成膜的面變化成SORI4μm之凸狀,另一方之面變化成SORI4μm之凹狀,厚度偏差(TTV)為1μm,具有幾乎平坦的SORI之多晶矽TFT用合成石英玻璃基板。[Example 4] In the same manner as in Example 1, the transfer substrate obtained by the transfer process in the same manner as in Example 3 was subjected to double-sided polishing to obtain a convex shape with a surface of SORI50 μm and a back surface of SORI150 μm. Concave polished substrate. In addition, the two sides were polished in the same manner as in Example 1 to obtain a convex surface with a SORI of 150 μm and a BOW of +25 μm, a reverse surface with a SORI of 50 μm and a concave shape with a BOW of -25 μm, a thickness deviation of 1 μm, and a thickness of 725 μm. It is a synthetic quartz glass substrate with mirror surface.  In the same manner as in Example 1, after forming a polycrystalline silicon film on the obtained synthetic quartz glass substrate, the film-forming surface changed to a convex shape of SORI 122 μm, and the other surface changed to a concave shape of SORI 122 μm. Then, after further heat treatment at 1050°C for one hour, the film-forming surface was changed into a convex shape of SORI 4 μm, and the other surface was changed into a concave shape of SORI 4 μm. The thickness deviation (TTV) was 1 μm. Synthetic quartz glass substrate for polysilicon TFT.

[實施例5]   作為轉印用母盤,準備如圖11所示之形狀者。具體而言,準備表背面之形狀為互相對稱的凸形狀,該些SORI為110μm,並且面內厚度偏差(TTV)為220μm,從表背面之中心點偏移30mm之處最厚,其部分之厚度為3000μm,直徑100mm的氧化鋁陶瓷製轉印用母盤。   作為原料基板,以與實施例1相同之方法,準備直徑100mm,厚度630μm,表背面側之SORI分別為6μm,面內厚度偏差(TTV)為1μm的合成石英玻璃基板。   以與實施例1相同之方法,藉由雙面拋光裝置同時加工兩片原料基板之單面側,獲得轉印用母盤之形狀被轉印至單面側之轉印基板。獲得的轉印基板之形狀皆單面凹狀地翹曲110μm。再者,凹狀之最薄之部分從中心偏移30mm。[Example 5] As a transfer master, a shape as shown in FIG. 11 was prepared. Specifically, the shapes of the front and back surfaces are prepared to be convex shapes symmetrical to each other. The SORIs are 110 μm, and the in-plane thickness deviation (TTV) is 220 μm, which is the thickest at a position offset by 30 mm from the center point of the front and back surfaces. An alumina ceramic transfer master with a thickness of 3000 μm and a diameter of 100 mm. As a raw material substrate, in the same manner as in Example 1, a synthetic quartz glass substrate having a diameter of 100 mm, a thickness of 630 μm, a SORI of 6 μm on the front and back sides, and an in-plane thickness deviation (TTV) of 1 μm was prepared. In the same manner as in Example 1, a single-sided side of two raw material substrates was simultaneously processed by a double-sided polishing device to obtain a transfer substrate whose shape of the transfer master was transferred to the single-sided side. The shapes of the obtained transfer substrates were all concavely warped by 110 μm on one side. Furthermore, the thinnest part of the concave is offset by 30 mm from the center.

在雙面拋光裝置設置獲得的轉印基板,以與實施例1相同之方法,進行雙面拋光加工,即使針對在先前轉印工程沒有被轉印之面,亦轉印轉印用母盤之形狀,獲得表面為SORI50μm之凸狀,背面為SORI50μm之凹狀的拋光加工基板。   並且,以單面研磨裝置對獲得的拋光加工基板之凸狀側之面予以鏡面化,獲得鏡面為SORI150μm之凸狀及BOW為+20μm,粗面為SORI50μm之凹狀及BOW為-20μm,面內厚度偏差(TTV)為1μm,厚度為500μm之合成石英玻璃基板。   接著,以與實施例1相同之方法在獲得的合成石英玻璃基板之表面形成多晶矽膜之後,成膜的面變化成SORI122μm之凸狀,另一方之面變化成SORI122μm之凹狀。   之後,進一步進行兩小時1100℃之熱處理之後,能獲得成膜的面變化成SORI4μm之凸狀,另一方之面變化成SORI4μm之凹狀,厚度偏差為1μm,具有幾乎平坦的SORI之多晶矽TFT用合成石英玻璃基板。Set the obtained transfer substrate on the double-sided polishing device and perform double-sided polishing in the same way as in Example 1. Even if the transfer substrate is not transferred in the previous transfer process, the transfer master is transferred. For the shape, a polished substrate with a SORI50 μm convex surface and a backside SORI50 μm concave shape was obtained. Moreover, the surface of the convex side of the polished substrate obtained was mirror-finished with a single-side polishing device to obtain a convex shape with a mirror surface of SORI150μm and a BOW of +20μm, a rough surface with a concave shape of SORI50μm and a BOW of -20μm, surface Synthetic quartz glass substrate with an internal thickness deviation (TTV) of 1 μm and a thickness of 500 μm.   Next, after forming a polysilicon film on the surface of the obtained synthetic quartz glass substrate in the same manner as in Example 1, the film-forming surface changed to a convex shape of SORI 122 μm, and the other surface changed to a concave shape of SORI 122 μm. After further heat treatment at 1100°C for two hours, the film-forming surface can be changed to a convex shape of SORI 4 μm, and the other surface can be changed to a concave shape of SORI 4 μm. The thickness deviation is 1 μm. Synthetic quartz glass substrate.

[實施例6]   與實施例5相同,準備表背面之中一方之面為平坦,並且另一方之面為凸狀地翹曲110μm的形狀,並且面內偏差(TTV)為220μm,從表背面之中心點偏移30mm之處最厚,其部分之厚度為3000μm,直徑100mm之氧化鋁陶瓷製轉印用母盤。   作為原料基板,準備與實施例5相同者。   以與實施例3相同之方法,藉由單面拋光裝置對原料基板之單面側進行加工,獲得轉印用母盤之形狀被轉印至單面側之轉印基板。獲得的轉印基板之形狀係單面為平坦,另一方之面為凹狀地翹曲110μm。再者,凹狀之最薄之部分從中心偏移30mm。   在單面拋光裝置設置獲得的轉印基板,以與實施例2相同之方法,進行單面拋光加工,即使針對在轉印工程沒有被轉印之轉印基板之相反側之面,亦轉印轉印用母盤之形狀,獲得表面為SORI110μm之凸狀,背面為SORI110μm之凹狀的拋光加工基板。   以單面研磨裝置對獲得的拋光加工基板之凸狀側之面予以鏡面化,獲得鏡面為SORI110μm之凸狀及BOW為+50μm,粗面為SORI為110μm之凹狀及BOW為-50μm,面內厚度偏差(TTV)為1μm,厚度為500μm之合成石英玻璃基板。   接著,以與實施例1相同之方法在獲得的合成石英玻璃基板之表面形成多晶矽膜之後,成膜的面變化成SORI122μm之凸狀,另一方之面變化成SORI122μm之凹狀。   之後,進一步進行兩小時1100℃之熱處理之後,能獲得成膜的面變化成SORI4μm之凸狀,另一方之面變化成SORI4μm之凹狀,面內厚度偏差為1μm,具有幾乎平坦的SORI之多晶矽TFT用合成石英玻璃基板。[Example 6] As in Example 5, one of the front and back surfaces is flat, and the other surface is convexly warped by 110 μm, and the in-plane deviation (TTV) is 220 μm, from the front and back The center point is the thickest where the center point is offset by 30 mm, and the thickness of the part is 3000 μm, and the transfer master is made of alumina ceramic with a diameter of 100 mm. As the raw material substrate, the same as in Example 5 was prepared. In the same manner as in Example 3, the single-sided side of the raw material substrate was processed by a single-sided polishing device to obtain a transfer substrate whose shape of the transfer master was transferred to the single-sided side. The shape of the obtained transfer substrate was flat on one side and warped by 110 μm on the other side in a concave shape. Furthermore, the thinnest part of the concave is offset by 30 mm from the center. The obtained transfer substrate was set in a single-side polishing device, and the single-side polishing process was performed in the same manner as in Example 2, even for the surface on the opposite side of the transfer substrate that was not transferred in the transfer process. The shape of the master for transfer was to obtain a polished substrate with a convex surface of SORI110μm and a concave surface of SORI110μm. The convex surface of the polished substrate obtained was mirror-finished with a single-side lapping device to obtain a convex surface with a mirror surface of SORI110μm and a BOW of +50μm, a rough surface with a concave surface of SORI of 110μm and a BOW of -50μm, surface Synthetic quartz glass substrate with an internal thickness deviation (TTV) of 1 μm and a thickness of 500 μm.   Next, after forming a polysilicon film on the surface of the obtained synthetic quartz glass substrate in the same manner as in Example 1, the film-forming surface changed to a convex shape of SORI 122 μm, and the other surface changed to a concave shape of SORI 122 μm. Then, after further heat treatment at 1100°C for two hours, the film-forming surface can be changed to a convex shape of SORI 4 μm, and the other surface can be changed to a concave shape of SORI 4 μm. The in-plane thickness deviation is 1 μm. The polycrystalline silicon with almost flat SORI Synthetic quartz glass substrate for TFT.

[比較例1]   作為轉印用母盤,準備表背面之SORI為110μm,單面為凸狀,另一方之面為凹狀,厚度為2mm,厚度偏差為2μm且一定,直徑100mm之氧化鋁製轉印用母盤,作為原料基板,準備與實施例1相同者。   使用雙面拋光裝置,以與實施例1相同之手法,對原料基板進行轉印加工,獲得表背面之SORI為1μm之轉印基板。   並且,以雙面研磨裝置對獲得的轉印基板予以雙面鏡面化,獲得表背面之SORI為1μm及表面之BOW為+0.5μm背面之BOW為-0.5μm,面內厚度偏差(TTV)為1μm,厚度為500μm之雙面為鏡面的合成石英玻璃基板。   以與實施例1相同之方法,在獲得的合成石英玻璃基板形成多晶矽膜之後,成膜的面變化成SORI120μm之凸狀,另一方之面變化成SORI120μm之凹狀。   之後,進一步進行一小時1050℃之熱處理之後,面內厚度偏差(TTV)維持1μm之原樣,成膜的面變化成SORI60μm之凸狀,另一方之面變化成SORI61μm之凹狀,無法獲得期待的平坦SORI。[Comparative Example 1]    As a transfer master, prepared SORI of the front and back sides was 110 μm, one side was convex, the other side was concave, the thickness was 2 mm, the thickness deviation was 2 μm and constant, and the diameter was 100 mm alumina As the raw material substrate, a master for transfer was prepared as in Example 1.  Using a double-sided polishing device, the raw material substrate was subjected to transfer processing in the same manner as in Example 1, to obtain a transfer substrate with a SORI of 1 μm on the front and back surfaces. In addition, the transfer substrate obtained was mirrored on both sides with a double-sided polishing device to obtain a SORI of 1 μm on the front and back and a BOW of +0.5 μm on the front and a BOW of -0.5 μm on the back. The in-plane thickness deviation (TTV) was Synthetic quartz glass substrate with a mirror surface of 1 μm and a thickness of 500 μm on both sides.  In the same manner as in Example 1, after forming a polycrystalline silicon film on the obtained synthetic quartz glass substrate, the film-forming surface changed to a convex shape of SORI 120 μm, and the other surface changed to a concave shape of SORI 120 μm. After that, after further heat treatment at 1050°C for one hour, the in-plane thickness deviation (TTV) was maintained at 1 μm, the film-forming surface changed to a SORI 60 μm convex shape, and the other surface changed to a SORI 61 μm concave shape. Flat SORI.

[比較例2]   作為轉印用母盤,準備表背面之SORI為110μm,單面為凸狀,另一方之面為凹狀,面內厚度偏差(TTV)為1μm,厚度為2mm,直徑200mm之氧化鋁製轉印用母盤,作為原料基板,準備與實施例4相同者。   以與實施例4相同之手法,使用單面拋光裝置對原料基板進行轉印工程之後,以雙面拋光裝置且以旋轉數20rpm、負載100g/cm2 對獲得的轉印基板進行拋光加工,獲得表背面之SORI為1μm的拋光加工基板。   並且,進行獲得的拋光基板之雙面研磨,獲得表背面之SORI為1μm及表面之BOW為+0.5μm,背面之BOW為 -0.5μm,面內厚度偏差(TTV)為1μm,厚度為725μm的合成石英玻璃基板。   以與實施例1相同之方法,在獲得的合成石英玻璃基板形成多晶矽膜之後,面內厚度偏差(TTV)維持1μm之原樣,成膜的面變化成SORI120μm之凸狀,另一方之面變化成SORI120μm之凹狀。   之後,進一步進行一小時1050℃之熱處理之後,面內厚度偏差(TTV)以1μm之原樣,成膜的面變化成SORI60μm之凸狀,另一方之面變化成SORI61μm之凹狀,無法獲得期待的平坦SORI。[Comparative Example 2] As a master for transfer, the SORI of the front and back sides was prepared to be 110 μm, one side was convex, the other side was concave, the in-plane thickness deviation (TTV) was 1 μm, the thickness was 2 mm, and the diameter was 200 mm The aluminum oxide transfer master was prepared as the raw material substrate in the same manner as in Example 4. In the same manner as in Example 4, after the transfer process of the raw material substrate was performed using a single-sided polishing device, the transfer substrate obtained was polished using a double-sided polishing device with a rotation number of 20 rpm and a load of 100 g/cm 2 to obtain The polished substrate with SORI of 1 μm on the back of the table. Furthermore, the polished substrates obtained were polished on both sides to obtain a SORI of 1 μm on the front and back and a BOW of +0.5 μm on the front, a BOW of -0.5 μm on the back, an in-plane thickness deviation (TTV) of 1 μm, and a thickness of 725 μm. Synthetic quartz glass substrate. In the same manner as in Example 1, after the polysilicon film was formed on the obtained synthetic quartz glass substrate, the in-plane thickness deviation (TTV) was maintained at 1 μm, the film-forming surface changed to a SORI 120 μm convex shape, and the other surface changed to SORI 120μm concave. Then, after further heat treatment at 1050°C for one hour, the in-plane thickness deviation (TTV) was 1 μm as it was, and the film-forming surface changed to a SORI 60 μm convex shape, and the other surface changed to a SORI 61 μm concave shape. Flat SORI.

[比較例3]   作為轉印用母盤,準備表背面之SORI為110μm,單面為凸狀,另一方之面為凹狀,面內厚度偏差(TTV)為1μm,厚度為2mm,直徑110mm之氧化鋁製轉印用母盤,作為原料基板,準備與實施例2相同者。   以與實施例2相同之方法,使用雙面拋光裝置對原料基板進行轉印工程之後,以使轉印用母盤之形狀沒有被轉印的平坦面朝向單面拋光裝置之頂板側之方式設置轉印基板,以與實施例2相同之條件進行拋光加工,獲得表面之SORI為1μm之拋光加工基板。   並且,以單面研磨裝置對獲得的拋光基板之單面予以鏡面化,獲得表面之SORI為1μm及表面之BOW為+0.5μm,背面之BOW為-0.5μm,面內厚度偏差(TTV)為1μm,厚度為500μm的合成石英玻璃基板。   以與實施例1相同之方法,在獲得的合成石英玻璃基板形成多晶矽膜之後,成膜的面變化成SORI120μm之凸狀,另一方之面變化成SORI120 μm之凹狀。   之後,進一步進行一小時1050℃之熱處理之後,面內厚度偏差(TTV)以1μm之原樣,成膜的面變化成SORI60μm之凸狀,另一方之面變化成SORI61μm之凹狀,無法獲得期待的平坦SORI。[Comparative Example 3] As a transfer master, the SORI of the front and back surfaces was prepared to be 110 μm, one side was convex, the other side was concave, and the in-plane thickness deviation (TTV) was 1 μm, the thickness was 2 mm, and the diameter was 110 mm The aluminum oxide transfer master was prepared as the raw material substrate in the same manner as in Example 2. In the same manner as in Example 2, after the transfer process of the raw material substrate using the double-sided polishing device, the flat surface of the shape of the transfer master that has not been transferred faces the top plate side of the single-sided polishing device The transfer substrate was polished under the same conditions as in Example 2 to obtain a polished substrate with a SORI of 1 μm on the surface. In addition, the single surface of the polished substrate was mirror-finished with a single-side polishing device, the SORI of the obtained surface was 1 μm and the BOW of the surface was +0.5 μm, the BOW of the back surface was -0.5 μm, and the in-plane thickness deviation (TTV) was 1 μm, synthetic quartz glass substrate with a thickness of 500 μm.  In the same manner as in Example 1, after forming a polycrystalline silicon film on the obtained synthetic quartz glass substrate, the film-forming surface changed to a convex shape of SORI 120 μm, and the other surface changed to a concave shape of SORI 120 μm. Then, after further heat treatment at 1050°C for one hour, the in-plane thickness deviation (TTV) was 1 μm as it was, and the film-forming surface changed to a convex shape of SORI 60 μm, and the other surface changed to a concave shape of SORI 61 μm, which could not be expected. Flat SORI.

[比較例4]   作為轉印用母盤,準備表背面之SORI為110μm,單面為凸狀,另一方之面為凹狀,面內厚度偏差(TTV)為1μm,厚度為2mm,直徑200mm之氧化鋁製轉印用母盤,作為原料基板,準備與實施例4相同者。   以與實施例4相同之方法,使用單面拋光裝置進行原料基板之轉印工程之後,以使轉印用母盤之形狀沒有被轉印的平坦面朝向單面拋光裝置之頂板側之方式設置轉印基板,以與實施例2相同之條件進行拋光加工,獲得表面之SORI為1μm之拋光加工基板。   並且,以單面研磨裝置對獲得的拋光基板之單面予以鏡面化,獲得表面之SORI為1μm及表面之BOW為+0.5μm,背面之BOW為-0.5μm,面內厚度偏差(TTV)為1μm,厚度為725μm的合成石英玻璃基板。   以與實施例1相同之方法,在獲得的合成石英玻璃基板形成多晶矽膜之後,成膜的面變化成SORI120μm之凸狀,另一方之面變化成SORI120μm之凹狀。   之後,進一步進行一小時1050℃之熱處理之後,面內厚度偏差維持1μm之原樣,成膜的面變化成SORI60μm之凸狀,另一方之面變化成SORI61μm之凹狀,無法獲得期待的平坦SORI。[Comparative Example 4]    As a transfer master, the SORI of the front and back sides was prepared to be 110 μm, one side was convex, the other side was concave, the in-plane thickness deviation (TTV) was 1 μm, the thickness was 2 mm, and the diameter was 200 mm The aluminum oxide transfer master was prepared as the raw material substrate in the same manner as in Example 4. In the same manner as in Example 4, after the transfer process of the raw material substrate was performed using a single-sided polishing device, the flat surface of the transfer master whose shape was not transferred was set to face the top plate side of the single-sided polishing device The transfer substrate was polished under the same conditions as in Example 2 to obtain a polished substrate with a SORI of 1 μm on the surface. In addition, the single surface of the polished substrate was mirror-finished with a single-side polishing device, the SORI of the obtained surface was 1 μm and the BOW of the surface was +0.5 μm, the BOW of the back surface was -0.5 μm, and the in-plane thickness deviation (TTV) was 1μm, synthetic quartz glass substrate with a thickness of 725μm.  In the same manner as in Example 1, after forming a polycrystalline silicon film on the obtained synthetic quartz glass substrate, the film-forming surface changed to a convex shape of SORI 120 μm, and the other surface changed to a concave shape of SORI 120 μm. After   , after further heat treatment at 1050°C for one hour, the in-plane thickness deviation remained the same as 1 μm, the film-forming surface changed to a SORI 60 μm convex shape, and the other surface changed to a SORI 61 μm concave shape, and the expected flat SORI could not be obtained.

將上述各實施例及比較例之結論顯示於表1。The conclusions of the above examples and comparative examples are shown in Table 1.

Figure 02_image001
Figure 02_image001

Figure 02_image003
Figure 02_image003

A‧‧‧半導體用基板1‧‧‧雙面拋光裝置2 單面拋光裝置10、20、30、40‧‧‧轉印用母盤11A、21A‧‧‧轉印基板100、200、300、400‧‧‧轉印用母盤之表面110、210、310、410‧‧‧轉印用母盤之背面100A、110A、200A、210A‧‧‧中心點L1、L2‧‧‧中心點S1、S2、S3、S4‧‧‧假想面(與中心線正交之面)11、21‧‧‧原料基板A‧‧‧Semiconductor substrate 1‧‧‧Double-sided polishing device 2 Single-sided polishing device 10, 20, 30, 40 ‧‧‧ Transfer master 11A, 21A ‧‧‧ Transfer substrate 100, 200, 300, 400‧‧‧Transfer master surface 110, 210, 310, 410‧‧‧ Transfer master back 100A, 110A, 200A, 210A‧‧‧‧center point L1, L2‧‧‧center point S1 S2, S3, S4 ‧‧‧ imaginary plane (plane perpendicular to the center line) 11, 21 ‧‧‧ raw substrate

圖1表示本發明之半導體用基板之SORI之態樣,(A)表示中心對稱地翹曲成凸狀之狀態,(B)表示翹曲成凸狀之頂點從中心偏移至Y軸方向之凸狀之狀態,(C)表示翹曲成線對稱之凸狀之狀態。另外,面上內部之曲線表示顯示高度之等高線。   圖2為本發明之半導體用基板之SORI之說明圖,S表示最小平方平面,a表示面S和半導體用基板A之表面的距離之最小值,b表示面S和半導體用基板A之表面的距離之最大值。   圖3為本發明之半導體用基板之BOW之說明圖,e表示表背中間面,S2表示從e獲得的基準面,f表示基板中心線,以在與f交叉之S2和e之距離中,若e較S2上側則標示+d,若較S2下側則標示-d之方式對d標示符號者係定義成BOW。   圖4為表示本發明之半導體用基板之厚度偏差c的圖式。   圖5為表示與本發明之第1實施型態有關之使用雙面拋光裝置之轉印工程之概略圖。   圖6為表示在第1實施型態中被使用的具有中心對稱之SORI之轉印用母盤之側視圖。   圖7表示與第1實施型態有關之使用雙面拋光裝置之拋光工程之概略圖。   圖8表示與本發明之第2實施型態有關之使用單面拋光裝置之轉印工程之概略圖。   圖9為表示在第2實施型態中被使用的具有中心對稱之SORI之轉印用母盤之側視圖。   圖10表示與第2實施型態有關之使用單面拋光裝置之拋光工程之概略圖。   圖11為表示與第1實施型態之變形例有關之具有非中心對稱之SORI之轉印用母盤之側視圖。   圖12為表示與第2實施型態之變形例有關之具有非中心對稱之SORI之轉印用母盤之側視圖。   圖13為表示與第1實施型態之其他變形例有關之轉印用母盤之上視圖及側視圖。1 shows the state of SORI of the semiconductor substrate of the present invention, (A) shows a state where the center is symmetrically warped into a convex shape, and (B) shows a state where the apex of the warped and convex shape is shifted from the center to the Y-axis direction In a convex state, (C) indicates a state in which it is warped into a line-symmetric convex state. In addition, the inner curve on the surface indicates the contour line of the display height. 2 is an explanatory diagram of the SORI of the semiconductor substrate of the present invention, where S represents the least square plane, a represents the minimum distance between the surface S and the surface of the semiconductor substrate A, and b represents the surface of the surface S and the surface of the semiconductor substrate A The maximum distance. 3 is an explanatory diagram of the BOW of the semiconductor substrate of the present invention, e represents the middle surface of the front and back, S2 represents the reference plane obtained from e, and f represents the centerline of the substrate, so that in the distance between S2 and e crossing with f, If e is higher than the upper side of S2, +d is marked, and if it is lower than S2, the way of -d is marked, BO is defined as a symbol for d. FIG. 4 is a diagram showing the thickness deviation c of the semiconductor substrate of the present invention. FIG. 5 is a schematic diagram showing a transfer process using a double-sided polishing device related to the first embodiment of the present invention. FIG. 6 is a side view showing the transfer master with SORI used for center symmetry used in the first embodiment. FIG. 7 shows a schematic diagram of a polishing process using a double-sided polishing device related to the first embodiment. FIG. 8 shows a schematic diagram of a transfer process using a single-side polishing device related to the second embodiment of the present invention. FIG. 9 is a side view showing a transfer master with SORI having a center symmetry used in the second embodiment. FIG. 10 shows a schematic diagram of a polishing process using a single-side polishing device related to the second embodiment. FIG. 11 is a side view showing a transfer master with non-central symmetry SORI related to a modification of the first embodiment. FIG. 12 is a side view showing a transfer master with non-central symmetry SORI related to a modification of the second embodiment. FIG. 13 is a top view and a side view showing a transfer master related to another modification of the first embodiment.

Claims (10)

一種半導體用基板,其特徵在於:   具備具有凸狀之SORI之一方的面,和具有與上述SORI相同程度之凹狀之SORI的另一方之面,並且厚度偏差為3μm以下。A semiconductor substrate characterized by having a surface having one side of a convex SORI and another surface having a concave SORI of the same degree as the above SORI, and having a thickness deviation of 3 μm or less. 如請求項1所載之半導體用基板,其中   上述各面之SORI為50~600μm。The substrate for semiconductor as described in claim 1, wherein the SORI of the above-mentioned surfaces is 50 to 600 μm. 如請求項1或2所載之半導體用基板,其中   具有上述凸狀之SORI之一方之面的BOW為+25~ +300。The substrate for semiconductor as described in claim 1 or 2, wherein the BOW of one side of the above-mentioned convex SORI is +25~+300. 如請求項1至3中之任一項所載之半導體用基板,其中   具有上述凹狀之SORI之另一方之面的BOW為-25~ -300。The substrate for semiconductor as described in any one of claims 1 to 3, wherein the BOW of the other side of the SORI having the concave shape is -25 to -300. 如請求項1至4中之任一項所載之半導體用基板,其中   厚度為0.5~3mm。The substrate for semiconductor as described in any one of claims 1 to 4, wherein the thickness of    is 0.5~3mm. 如請求項1至5中之任一項所載之半導體用基板,其中   上述半導體用基板之形狀在俯視下為直徑100~450mm之圓形狀或對角長度100~450mm之矩形狀。The substrate for semiconductor as described in any one of claims 1 to 5, wherein the shape of the above-mentioned semiconductor substrate is a circular shape with a diameter of 100 to 450 mm or a rectangular shape with a diagonal length of 100 to 450 mm in plan view. 如請求項1至6中之任一項所載之半導體用基板,其中   為合成石英玻璃製。The substrate for semiconductor as described in any one of claims 1 to 6, wherein    is made of synthetic quartz glass. 如請求項1至7中之任一項所載之半導體用基板,其中   為多晶矽TFT用基板。The substrate for semiconductor as described in any one of claims 1 to 7, wherein    is a substrate for polysilicon TFT. 一種半導體用基板之製造方法,其特徵在於,具備:   準備工程,其係準備轉印用母盤,且該轉印用母盤具有表面及背面,具有相對於通過連結該些表背面之中心點的中心線上之中間點,與上述中心線正交之面,上述表面及背面對稱地相向的SORI和厚度偏差;   轉印工程,其係以挾入上述轉印用母盤之方式,在雙面拋光裝置設置兩片原料基板,對上述各原料基板中之不與上述轉印用母盤相接之面進行加工而製作上述轉印用母盤之形狀被轉印至至各個單面的兩片轉印基板;   拋光工程,其係藉由拋光上述轉印基板之雙面,或藉由僅拋光上述轉印基板中之在上述轉印工程沒有被轉印上述轉印用母盤之形狀的面而製作拋光加工基板;及   對上述拋光加工基板之雙面或單面進行研磨。A method for manufacturing a semiconductor substrate, characterized by comprising: a   preparation process, which prepares a transfer master, and the transfer master has a front surface and a back surface, and has a center point relative to the back surface of the front surface through the connection The middle point on the center line of the center, the surface orthogonal to the center line, the SORI and the thickness deviation of the surface and the back surface symmetrically facing each other;   transfer engineering, which is carried out by inserting the transfer master disk on both sides The polishing device is provided with two raw material substrates, and the surfaces of the raw material substrates that are not in contact with the transfer master are processed to produce two pieces of the transfer master whose shape is transferred to each single surface Transfer substrate;    polishing process, by polishing both sides of the transfer substrate, or by polishing only the surface of the transfer substrate in the transfer process is not transferred to the shape of the transfer master And manufacture a polished substrate; and grind both sides or one side of the polished substrate. 一種半導體用基板之製造方法,其特徵在於,具備:   準備工程,其係準備轉印用母盤,且該轉印用母盤具有表面及背面,相對於通過連結該些表背面之中心點的中心線上之中間點,與上述中心線正交之面,上述表背面之中的任一方之面為平行,並且上述表背面之中與原料基板相接之另一方之面正交於上述中心線,同時相對於上述中心線為對稱; 轉印工程,其係以與上述轉印用母盤之上述另一方之面相接之方式在單面拋光裝置設置原料基板,對上述原料基板中之不與上述轉印用母盤相接之面進行加工而製作上述轉印用母盤之形狀被轉印至單面之轉印基板;   拋光工程,其係藉由拋光上述轉印基板之雙面,或藉由僅拋光上述轉印基板中之在上述轉印工程沒有被轉印上述轉印用母盤之形狀的面而製作拋光加工基板;及   對上述拋光加工基板之雙面或單面進行研磨。A method for manufacturing a semiconductor substrate, characterized by comprising: a   preparation process, which prepares a transfer master, and the transfer master has a front surface and a back surface, with respect to the center point connecting the front and back surfaces The middle point on the center line is the plane orthogonal to the center line, either side of the front and back sides is parallel, and the other side of the front and back sides that is in contact with the raw substrate is orthogonal to the center line At the same time, it is symmetrical with respect to the center line; transfer process, which is to set the raw material substrate on the single-side polishing device in contact with the other surface of the transfer master plate, and the raw material substrate is not The surface in contact with the transfer master is processed to produce the transfer substrate whose shape is transferred to a single-sided transfer substrate;    polishing process, which is by polishing both sides of the transfer substrate, Or by polishing only the surface of the transfer substrate that is not transferred to the shape of the transfer master in the transfer process; and polishing the double-sided or single surface of the polished substrate .
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