TW201942066A - Filter cartridge and water purification system using the same including a carrying seat and a filter - Google Patents
Filter cartridge and water purification system using the same including a carrying seat and a filter Download PDFInfo
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- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical class Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 description 1
- 208000009304 Acute Kidney Injury Diseases 0.000 description 1
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- Separation Using Semi-Permeable Membranes (AREA)
- Water Treatment By Sorption (AREA)
Abstract
Description
本發明是有關於一種濾心,特別是指一種用於淨水並產製含有矽酸(silicic acid)與氫氣的生物用水組成(water for organism)的濾心與使用其濾心的淨水系統。The present invention relates to a filter, in particular to a filter for purifying water and producing a water for organism containing silicic acid and hydrogen, and a water purification system using the same. .
有鑑於溶氫飲用水於人體飲用後有利於與存在於體內之致病性活性氧或自由基團中和,以減緩器官損害。因此,溶氫飲用水的相關研究已成為近幾年來的熱門研究主題。In view of the fact that hydrogen-soluble drinking water is beneficial for neutralizing pathogenic reactive oxygen species or free radical groups existing in the body after drinking in order to reduce organ damage. Therefore, research on hydrogen-soluble drinking water has become a hot research topic in recent years.
訪間常見的溶氫飲用水多半是將高純度氫氣直接溶於水中,或是以鎂粉或鎂錠來與純水反應生成氫氣,並以此稱為溶氫飲用水。然而,前者之方法,存在著高純度氫氣取得不易、氫氣溶解困難以及安全性之問題。後者之方法,則因為殘留在純水中的氫氧化鎂是被歸類為藥品,其與部分心血管疾病的藥品會產生衝突,一旦含量過高時,也容易引發急性藥物中毒、急性腎衰竭或高血鎂症等問題。Most of the common hydrogen-dissolved drinking water in the interview is mostly dissolved high-purity hydrogen directly in water, or magnesium powder or magnesium ingot to react with pure water to generate hydrogen, which is called hydrogen-dissolved drinking water. However, the former method has problems such as difficulty in obtaining high-purity hydrogen, difficulty in dissolving hydrogen, and safety. The latter method is because magnesium hydroxide remaining in pure water is classified as a drug, which conflicts with some cardiovascular diseases. Once the content is too high, it can easily cause acute drug poisoning and acute renal failure. Or hypermagnesemia.
經上述說明可知,使飲用水可以溶氫並提供安全的溶氫飲用水,是本發明相關技術領域的技術人員所待突破的課題。It can be known from the above description that making drinking water soluble in hydrogen and providing safe hydrogen-dissolved drinking water is a subject to be solved by those skilled in the technical field related to the present invention.
因此,本發明的第一目的,即在提供一種用於淨水並產製含有矽酸及氫氣的生物用水組成的濾心。Therefore, a first object of the present invention is to provide a filter for purifying water and producing biological water containing silicic acid and hydrogen.
於是,本發明濾心,是用於淨水並產製含有矽酸及氫氣的生物用水組成,其包括一載座,及一濾材。該載座界定出一容置空間,並包括與該容置空間相通的一進水口及一出水口。該濾材填充於該載座的該容置空間中,且該濾材包括一載體,及複數活性矽材。該載體選自一多孔性材料、一非多孔性材料,或前述載體的一組合。該等活性矽材吸附於該載體的一表面。Therefore, the filter core of the present invention is used for purifying water and producing biological water containing silicic acid and hydrogen. The filter core includes a carrier and a filter material. The carrier defines an accommodation space, and includes a water inlet and a water outlet that communicate with the accommodation space. The filter material is filled in the accommodation space of the carrier, and the filter material includes a carrier and a plurality of active silicon materials. The support is selected from a porous material, a non-porous material, or a combination of the foregoing supports. The active silicon materials are adsorbed on a surface of the carrier.
本發明的第二目的,即在提供一種產製含有矽酸及氫氣的生物用水組成的淨水系統。A second object of the present invention is to provide a water purification system for producing biological water containing silicic acid and hydrogen.
於是,本發明淨水系統,是用於與一產製且容置有一生物用水的生物用水單元連接並產製含有矽酸及氫氣的生物用水組成,該淨水系統沿一水流方向包括至少一第一濾心。該第一濾心是使用如上所述的濾心。Therefore, the water purification system of the present invention is used to connect with a biological water unit that produces and contains a biological water and produces biological water containing silicic acid and hydrogen. The water purification system includes at least one along a water flow direction. The first filter. The first filter is a filter as described above.
本發明的功效在於:利用形成於載體表面的活性矽材與生物用水反應生成矽酸與氫氣,使生物用水內的溶氫量提升並提供安全的生物用水組成,且含有對人體有益的溶解性矽。The effect of the present invention is that the active silicon material formed on the surface of the carrier reacts with biological water to generate silicic acid and hydrogen, which increases the amount of hydrogen dissolved in biological water and provides a safe composition of biological water, and contains beneficial solubility for the human body. Silicon.
在本發明被詳細描述的前,應當注意在以下的說明內容中,類似的元件是以相同的編號來表示。Before the present invention is described in detail, it should be noted that in the following description, similar elements are represented by the same numbers.
參閱圖1與圖2,本發明濾心4之一第一實施例,是用於淨水並產製一含有矽酸及氫氣921的生物用水組成92(見圖13),其包括一載座41,及一濾材42。Referring to FIG. 1 and FIG. 2, a first embodiment of the filter 4 of the present invention is used for purifying water and producing a biological water composition 92 (see FIG. 13) containing silicic acid and hydrogen 921, which includes a carrier. 41, and a filter material 42.
該載座41界定出一容置空間40,並包括相反設置且與該容置空間40相通的一進水口401及一出水口402,且該進水口401的位置是低於該出水口402的位置。The carrier 41 defines an accommodating space 40, and includes an inlet 401 and an outlet 402 which are oppositely disposed and communicate with the accommodating space 40. The position of the inlet 401 is lower than the outlet 402. position.
該濾心4之濾材42填充於該載座41的該容置空間40中,且包括一載體421,及複數活性矽材422。該載體421選自一多孔性材料、一非多孔性材料,或前述載體421的一組合。該等活性矽材422吸附於該載體421的一表面。The filter material 42 of the filter core 4 is filled in the accommodation space 40 of the carrier 41, and includes a carrier 421 and a plurality of active silicon materials 422. The support 421 is selected from a porous material, a non-porous material, or a combination of the foregoing supports 421. The active silicon materials 422 are adsorbed on a surface of the carrier 421.
在本發明中,所謂的生物用水,是被定義為可在動物、植物等生物內服或外用後受生物所吸收的水,且矽酸與氫氣氣泡921是經如圖13所示之一生物用水9與一預定量的活性矽材422混合所反應生成。In the present invention, the so-called biological water is defined as water that can be absorbed by organisms after being taken orally or externally by organisms such as animals and plants, and silicic acid and hydrogen bubbles 921 are biological water as shown in FIG. 13. 9 is formed by mixing with a predetermined amount of active silicon material 422.
該載體421的目的主要是在於,攔截該等活性矽材422,舉凡可以攔截該等活性矽材422的材料皆適用。因此,較佳地,適用於本發明之載體421是選自由下列所構成之群組:如圖2所示的活性碳4211、如圖5所示的中空絲膜(hollow fiber membrane filter)4212、竹炭(bamboo-charcoal)、麥飯石(porphyritic andesites)、石英砂(quartz sand)、纖維(fiber)、陶瓷(ceramics),及前述載體421的一組合;該等活性矽材422是選自粒徑介於50 nm至300 nm間的奈米矽材、多孔性矽材(porous silicon)、造粒矽材(granulated silicon),或矽奈米線(Si nanowires)。舉例來說,奈米矽材可以是如矽晶圓長晶廠經矽晶錠(Si ingot)的開方(squaring)與切片(slicing)後所廢棄不用的奈米矽粉等廢料;多孔性矽材可以是如經酸蝕刻後的矽晶圓、矽粉等材料;造粒矽材例如可以是矽粉經噴霧造粒(spray granulation)所得;矽奈米線例如可以是矽材經溶液蝕刻所得。The purpose of the carrier 421 is mainly to intercept the active silicon materials 422, and any material that can intercept the active silicon materials 422 is applicable. Therefore, preferably, the carrier 421 suitable for the present invention is selected from the group consisting of activated carbon 4211 shown in FIG. 2, and hollow fiber membrane filter 4212 shown in FIG. 5. Bamboo-charcoal, porphyritic andesites, quartz sand, fibers, ceramics, and a combination of the aforementioned carriers 421; the active silicon material 422 is selected from a particle size Nano silicon, porous silicon, granulated silicon, or Si nanowires between 50 nm and 300 nm. For example, nano-silicon materials can be waste materials such as nano-silicon powder that is discarded after squaring and slicing of silicon ingots in silicon wafer growth plants; porous The silicon material can be materials such as silicon wafers, silicon powder, etc. after acid etching; the granulated silicon material can be, for example, silicon powder obtained by spray granulation; silicon nanowires can be, for example, silicon material subjected to solution etching Income.
此處須說明的是,基於經奈米化的矽材(即,奈米矽材)本質上具有高度的活性,其有利於與水分子快速地進行反應生成矽酸及氫氣。需進一步說明的是,一般奈米矽材的粒徑越小,活性越大,奈米矽材與該生物用水9兩者間的反應速率通常就越快,反應生成矽酸與氫氣的速度也就越快。為避免活性矽材422因粒徑過小而劇烈且迅速地與生物用水9反應用盡;因此,較佳地,該奈米矽材的表面具有氧化矽薄膜。What needs to be explained here is that nano-based silicon materials (ie, nano-silicon materials) are highly active in nature, which facilitates rapid reaction with water molecules to generate silicic acid and hydrogen. It needs to be further explained that, generally, the smaller the particle size of the nano-silica material, the greater the activity, the faster the reaction rate between the nano-silica material and the biological water9, and the rate of reaction to generate silicic acid and hydrogen is also faster. Faster. In order to prevent the active silicon material 422 from reacting with the biological water 9 violently and quickly due to its too small particle size, it is preferable that the surface of the nano silicon material has a silicon oxide film.
如圖2所示,本發明該第一實施例之濾心4的第一種濾材42,該載體421是表面分布有複數微孔洞4210的活性碳4211,且該等活性矽材422是粒徑介於100 nm至250 nm間的奈米矽材,該等吸附於該載體421表面的活性矽材422是部分位於活性碳4211的微孔洞4210中。As shown in FIG. 2, the first filter material 42 of the filter core 4 of the first embodiment of the present invention, the carrier 421 is activated carbon 4211 with a plurality of micropores 4210 distributed on the surface, and the active silicon materials 422 are granules. Nano-silicon materials with a diameter between 100 nm and 250 nm, and the active silicon materials 422 adsorbed on the surface of the support 421 are partially located in the micropores 4210 of the activated carbon 4211.
較佳地,以該濾材42的重量百分比計,該載體421的含量是小於等於90 wt%,該等活性矽材422的含量是大於等於10 wt%。更佳地,該等活性矽材422的含量是介於10 wt%~40wt%,再更佳地,該等活性矽材422的含量是介於15 wt%~30wt%(即,該等活性矽材422的含量是20 wt%以上,該載體421的含量是80 wt%以下),如此可令濾材42更能兼顧過濾與生物用水組成92的產製。需說明的是,活性矽材422含量越高,達到設計的溶氫量與溶矽量的所需載體421就可以越少。因此,在其他實施例中,活性矽材422亦可單獨做為該濾材42使用。換句話說,活性矽材422並非一定要搭配活性碳4211等載體421一起使用。Preferably, based on the weight percentage of the filter material 42, the content of the carrier 421 is 90% by weight or less, and the content of the active silicon materials 422 is 10% by weight or more. More preferably, the content of the active silicon material 422 is between 10 wt% and 40 wt%, and even more preferably, the content of the active silicon material 422 is between 15 wt% and 30 wt% (that is, the active silicon material The content of the silicon material 422 is more than 20 wt%, and the content of the carrier 421 is less than 80 wt%), so that the filter material 42 can be more compatible with the production of the filtration and biological water composition 92. It should be noted that the higher the content of the active silicon material 422, the less the required carrier 421 to achieve the designed hydrogen and silicon dissolving amount. Therefore, in other embodiments, the active silicon material 422 can also be used as the filter material 42 alone. In other words, the activated silicon material 422 does not have to be used with a carrier 421 such as activated carbon 4211.
參閱圖3,本發明該第一實施例之濾心4之第一種濾材42的製法,是於一具有攪拌功能的容器內加入由溶劑(例如:酒精4222)與該等活性矽材(例如:奈米矽材)422所形成的一奈米矽漿料(slurry)4220,並於該奈米矽漿料4220內混入活性碳4211予以均勻攪拌,令活性矽材422得以透過該奈米矽漿料4220於攪拌時所造成的擾流嵌入活性碳4211的微孔洞4210中以吸附於活性碳4211的表面。待活性碳4211均勻攪拌至奈米矽漿料4220後進行烘乾以移除酒精4222,從而製得如圖2所示之該第一實施例的第一種濾材42。Referring to FIG. 3, the first method for manufacturing the first filter material 42 of the filter core 4 according to the first embodiment of the present invention is to add a solvent (for example, alcohol 4222) and these active silicon materials (for example, alcohol 4222) to a container having a stirring function. : Nano-silicon slurry 4220 formed by nano-silicon material) 422, and activated carbon 4211 is mixed into the nano-silicon slurry 4220 and stirred uniformly, so that the active silicon material 422 can pass through the nano-silicon. The turbulence caused by the slurry 4220 while being stirred is embedded in the micropores 4210 of the activated carbon 4211 to be adsorbed on the surface of the activated carbon 4211. After the activated carbon 4211 is uniformly stirred to the nano-silica slurry 4220 and dried to remove the alcohol 4222, the first filter material 42 of the first embodiment shown in FIG. 2 is prepared.
參閱圖4,本發明該第一實施例之濾心4的一第二種濾材42大致上是相同於該第一種濾材42,其不同處是在於,該第二種濾材42還包括一黏結材(binder)423。該黏結材423結合奈米矽材(即,活性矽材422)與活性碳4211令部分活性矽材422附著於活性碳4211上,且該黏結材423與活性碳4211共同構成一燒結活性碳(sintered activated carbon)。詳細地來說,該第二種濾材42是將活性碳4211、奈米矽材(即,活性矽材422)與黏結材423混合後,再透過一模具熱壓以形成一生胚(green body),最後燒結該生胚成該濾材42。在其他實施例中,亦可將該第一實施例的第一種濾材42與黏結材423混合後再壓合燒結。值得一提的是,燒結後的該黏結材423會形成多個孔道(圖未示)供生物用水流過。Referring to FIG. 4, a second filter medium 42 of the filter core 4 according to the first embodiment of the present invention is substantially the same as the first filter medium 42. The difference is that the second filter medium 42 further includes a bonding agent.材 (binder) 423. The bonding material 423 combines nano silicon material (ie, activated silicon material 422) and activated carbon 4211 to partially attach the activated silicon material 422 to the activated carbon 4211, and the bonding material 423 and activated carbon 4211 together form a sintered activated carbon ( sintered activated carbon). In detail, the second filter material 42 is a mixture of activated carbon 4211, nanometer silicon material (ie, active silicon material 422) and bonding material 423, and then hot-pressed through a mold to form a green body. Finally, the green embryo is sintered to form the filter material 42. In other embodiments, the first filter material 42 of the first embodiment may be mixed with the bonding material 423 and then pressed and sintered. It is worth mentioning that the sintered bonding material 423 will form a plurality of channels (not shown) for biological water to flow through.
參閱圖5,本發明該第一實施例之濾心4的一第三種濾材42,大致上是相同於該第一種濾材42,其不同處是在於,該載體421是呈一管狀結構並具有貫穿其管狀結構之微孔洞4210的中空絲膜4212,且該等微孔洞4210的孔徑是介於10 nm至100 nm間。該等活性矽材(例如:奈米矽材)422是吸附於各中空絲膜4212的表面。本發明該第一實施例之濾心4之第三種濾材42的製法,是令該等活性矽材422混於一流體(圖未示)中,以使該等活性矽材422透過該流體的一流向被引導至各中空絲膜4212的表面並吸附於各中空絲膜4212的表面,且該流體亦順著該流向流進各微孔洞4210內以朝各中空絲膜4212的一出口(圖未示)行進。當然,在其他衍生實施例中,活性矽材422也可以不透過流體的手段固定設置在中空絲膜4212上,例如:透過黏結材固定,或是在中空絲膜4212的製作過程中添加活性矽材422。Referring to FIG. 5, a third filter medium 42 of the filter core 4 according to the first embodiment of the present invention is substantially the same as the first filter medium 42 except that the carrier 421 has a tubular structure and The hollow fiber membrane 4212 has micro-holes 4210 passing through its tubular structure, and the pore diameter of the micro-holes 4210 is between 10 nm and 100 nm. The active silicon materials (for example, nano-silicon materials) 422 are adsorbed on the surface of each hollow fiber membrane 4212. The method for manufacturing the third filter medium 42 of the filter core 4 of the first embodiment of the present invention is to mix the active silicon materials 422 in a fluid (not shown) so that the active silicon materials 422 pass through the fluid. The first direction is guided to the surface of each hollow fiber membrane 4212 and adsorbed on the surface of each hollow fiber membrane 4212, and the fluid flows into the micro-holes 4210 along the flow direction to an exit of each hollow fiber membrane 4212 (Not shown) proceed. Of course, in other derivative embodiments, the active silicon material 422 can also be fixed on the hollow fiber membrane 4212 without a fluid-permeable means, for example, fixed through an adhesive material, or active silicon is added during the manufacturing process of the hollow fiber membrane 4212.材 422.
本發明該第一實施例之濾心4還包括一分散水流單元,及一阻擋單元。The filter core 4 of the first embodiment of the present invention further includes a dispersed water flow unit and a blocking unit.
該分散水流單元是位於該載座41的容置空間40中並鄰近該進水口處401,且該阻擋單元是位於該載座41的容置空間40中並鄰近該出水口處402。在本發明該第一實施例之濾心4中,該載體421是均勻分布在該載座41之容置空間40中的活性碳4211,且該等活性矽材422是奈米矽材;換句話說,該第一實施例之濾心4是使用該第一種濾材42,且是填充於該載座41的該容置空間40中。The dispersed water flow unit is located in the accommodation space 40 of the carrier 41 and is adjacent to the water inlet 401, and the blocking unit is located in the accommodation space 40 of the carrier 41 and near the water outlet 402. In the filter core 4 of the first embodiment of the present invention, the carrier 421 is activated carbon 4211 uniformly distributed in the accommodating space 40 of the carrier 41, and the active silicon materials 422 are nano silicon materials; In other words, the filter element 4 of the first embodiment uses the first filter material 42 and is filled in the accommodation space 40 of the carrier 41.
此處值得一提的是,本發明該第一實施例之濾心4內所使用的第一種濾材42,可因被嵌入於該等微孔洞4210內的活性矽材422,使生物用水(圖未示)與該等活性矽材422在反應生成氫氣(圖未示)與矽酸時,藉由微孔洞4210使溶有氫氣的生物用水組成在濾材42中流動時有更多的接觸面積,以藉此提升溶氫量。又,該進水口401的位置低於該出水口402的位置,則有助於減緩活性矽材422被生物用水沖刷而流失,亦可提升溶氫量。It is worth mentioning here that the first filter material 42 used in the filter core 4 of the first embodiment of the present invention can be used for biological water because of the active silicon material 422 embedded in the micro-holes 4210. (Not shown) When reacting with these active silicon materials 422 to generate hydrogen (not shown) and silicic acid, the bio-water dissolved hydrogen is composed of micropores 4210 and flows more in the filter material 42. Contact area to increase the amount of dissolved hydrogen. In addition, the position of the water inlet 401 is lower than the position of the water outlet 402, which helps to slow down the active silicon material 422 being washed away by biological water, and can also increase the amount of dissolved hydrogen.
又,需附帶說明的是,本發明圖1所揭示之第一實施例的濾心4,除了可以直接採用上述第一種濾材42外,在其他的衍生實施例中,也可只單獨在該載座41的容置空間40中填充活性矽材422作為濾材42,如此同樣可產製含有矽酸及氫氣的生物用水組成。In addition, it should be noted that, in addition to the filter element 4 of the first embodiment disclosed in FIG. 1 of the present invention, in addition to the first filter material 42 described above, in other derivative embodiments, it can also be used alone in this embodiment. The accommodating space 40 of the carrier 41 is filled with the active silicon material 422 as the filter material 42, so that the biological water composition containing silicic acid and hydrogen can also be produced.
本發明顯示於圖1之第一實施例的濾心4除了可以直接採用該第一種濾材42外,另外也可於使用前,於該載座41之容置空間40內自其進水口401朝其出水口402依序填入部分載體421(如,活性碳4211)、該等活性矽材422與剩餘載體421(如,活性碳4211)。於實際使用以自該載座41之進水口401引入如圖13所示之該生物用水9時,該生物用水可因鄰近進水口401處的部分活性碳421使生物用水分散,以利生物用水實質填滿該容置空間40並令該等活性矽材422隨著生物用水的流動方向移動以附著於該載體421上,而鄰近該出水口402處的剩餘活性碳4211則可降低水量衝擊並阻擋活性矽材422。因此,在本發明該第一實施例之濾心4中,是以位處於該載座41之容置空間40中並鄰近該進水口401處的載體421做為該分散水流單元,並以位處於該載座41之容置空間40中並鄰近該出水口402處的載體421做為該阻擋單元。The filter core 4 of the first embodiment of the present invention shown in FIG. 1 can use the first filter material 42 directly, and can also be used from its water inlet 401 in the accommodation space 40 of the carrier 41 before use. A part of the carrier 421 (for example, activated carbon 4211), the activated silicon materials 422, and the remaining carrier 421 (for example, activated carbon 4211) are sequentially filled toward the water outlet 402 thereof. When the biological water 9 shown in FIG. 13 is introduced from the water inlet 401 of the carrier 41 in actual use, the biological water may be dispersed by the activated carbon 421 adjacent to the water inlet 401 to facilitate the biological water Substantially fill the accommodating space 40 and make the active silicon materials 422 move with the biological water flow direction to adhere to the carrier 421, and the remaining activated carbon 4211 near the water outlet 402 can reduce the impact of water volume and Block active silicon 422. Therefore, in the filter core 4 of the first embodiment of the present invention, the carrier 421 located in the accommodating space 40 of the carrier 41 and adjacent to the water inlet 401 is used as the dispersed water flow unit. The carrier 421 in the accommodation space 40 of the carrier 41 and adjacent to the water outlet 402 serves as the blocking unit.
基於該分散水流單元的目的是避免水流方向集中在進水口401處,並使生物用水均勻分散至該載座41的容置空間40中。因此,適用於本發明之分散水流單元並不限於上述活性碳4211,舉凡具有分散水流功能的玻璃珠、帶有孔洞的隔板或不織布等,均可適用。又,基於阻擋單元的目的是在於攔下活性矽材422,以降低活性矽材422自該出水口402被生物用水的水流方向帶出該容置空間40的機率。因此,適用於本發明之阻擋單元並不限於上述活性碳4211,舉凡能攔下鄰近該出水口402處的活性矽材422的竹炭、麥飯石、中空絲膜、纖維或石英砂等,亦均可適用。The purpose of the dispersed water flow unit is to prevent the water flow direction from being concentrated at the water inlet 401 and to evenly disperse biological water into the accommodation space 40 of the carrier 41. Therefore, the dispersed water flow unit suitable for the present invention is not limited to the above-mentioned activated carbon 4211, and any glass beads, a partition with holes, or a non-woven fabric having a function of dispersing water flow can be applied. In addition, the purpose of the blocking unit is to stop the active silicon material 422 to reduce the probability that the active silicon material 422 is taken out of the accommodating space 40 from the water outlet 402 by the biological water flow direction. Therefore, the barrier unit applicable to the present invention is not limited to the above-mentioned activated carbon 4211. For example, bamboo charcoal, maifan stone, hollow silk membrane, fiber or quartz sand that can block the activated silicon material 422 adjacent to the water outlet 402 are also all applicable.
又,值得一提的是,引入至該濾心4之容置空間40內的生物用水亦可與其他可釋放微量元素(例如:鉀、鍶、硒)及/或礦物質的濾材反應,以在生物用水與活性矽材422反應生成矽酸與氫氣的同時釋放微量元素到生物用水組成內。It is also worth mentioning that the biological water introduced into the containing space 40 of the filter core 4 can also react with other filter materials that can release trace elements (such as potassium, strontium, selenium) and / or minerals to When biological water reacts with active silicon 422 to generate silicic acid and hydrogen, trace elements are released into the composition of biological water.
參閱圖6,本發明濾心4之一第二實施例大致上是相同於該第一實施例,其不同處是在於,該濾材42是使用該第一實施例所述的第二種濾材42。值得一提的是,透過該濾材42之黏結材423結合活性碳4211與活性矽材422,可令活性矽材422更能有效地附著/固定於活性碳4211上,以防止該濾心4於實際使用時,活性矽材422遭生物用水沖刷並帶往該載座41的出水口402處。Referring to FIG. 6, a second embodiment of a filter element 4 of the present invention is substantially the same as the first embodiment, except that the filter material 42 is a second filter material 42 described in the first embodiment. . It is worth mentioning that combining activated carbon 4211 and activated silicon material 422 through the bonding material 423 of the filter material 42 enables the activated silicon material 422 to be more effectively attached / fixed to the activated carbon 4211 to prevent the filter core from In actual use, the active silicon material 422 is washed by biological water and taken to the water outlet 402 of the carrier 41.
參閱圖7、8,本發明濾心4之一第三實施例大致上相同於該第一實施例,不同處在於,該載體421是活性碳4211與中空絲膜4212的組合,且該等活性矽材422是奈米矽材;也就是說,本發明該第三實施例之濾心4除了使用該第一實施例之第一種濾材42外,亦使用該第一實施例之第三種濾材42。在本發明該第三實施例之濾心4中,活性碳4211是均勻分布在該載座41之容置空間40中,並相對中空絲膜4212靠近該進水口401;中空絲膜4212是分布在該載座41之容置空間40中,並相對活性碳4211靠近該出水口402。Referring to FIGS. 7 and 8, a third embodiment of the filter 4 of the present invention is substantially the same as the first embodiment, except that the carrier 421 is a combination of activated carbon 4211 and hollow fiber membrane 4212, and the activities The silicon material 422 is a nano silicon material; that is, the filter core 4 of the third embodiment of the present invention uses the third filter material of the first embodiment in addition to the third filter material of the first embodiment. Filter medium 42. In the filter 4 of the third embodiment of the present invention, the activated carbon 4211 is evenly distributed in the accommodation space 40 of the carrier 41 and is close to the water inlet 401 relative to the hollow fiber membrane 4212; the hollow fiber membrane 4212 is distributed In the accommodating space 40 of the carrier 41, the water outlet 402 is close to the activated carbon 4211.
詳細地來說,本發明該第三實施例之濾心4除了可以直接採用上述第一與第三種濾材42外,另外也可於使用前(見圖7),於該載座41之容置空間40內自其進水口401朝其出水口402依序填入部分載體421(如,活性碳4211)、該等活性矽材422、剩餘活性碳4211與該等中空絲膜4212。再參閱圖8,於實際使用以自該載座41之進水口401引入該生物用水(圖未示)時,該生物用水可因應其自身的流動方向實質填滿該容置空間40並令該等活性矽材422隨著生物用水的流動方向移動。經移動後的部分活性矽材422可嵌入該等活性碳4211的微孔洞4210內,以藉由微孔洞4210使溶出有氫氣的生物用水組成在濾材42中流動時有更多的接觸面積來藉此提升溶氫量,而未被嵌入於微孔洞4210內的活性矽材422仍可隨著生物用水的流動方向被帶往中空絲膜4212以吸附於中空絲膜4212的表面,使生物用水組成在中空絲膜4212繼續與活性矽材422反應,並於該處發生類似曝氣(aeration)的效果以藉此再進一步提升溶氫量。此外,中空絲膜4212還可以攔截可能產生的矽酸聚合或沉澱,令因過飽和所致的矽酸聚合或沉澱可再因為繼續引入至該濾心4之容置空間40內的生物用水降低其生物用水內的矽酸濃度並繼續溶解。簡單地來說,本發明該第三實施例之濾心4是一體式的濾心。In detail, in addition to the filter element 4 of the third embodiment of the present invention, in addition to the first and third filter materials 42 described above, it can also be used before the use (see FIG. 7). In the installation space 40, a part of the carrier 421 (for example, activated carbon 4211), the activated silicon materials 422, the remaining activated carbon 4211, and the hollow fiber membranes 4212 are sequentially filled from its water inlet 401 to its water outlet 402. Referring again to FIG. 8, when the biological water (not shown) is introduced from the water inlet 401 of the carrier 41 in actual use, the biological water may substantially fill the accommodating space 40 and make the biological water according to its own flow direction. The isoactive silicon material 422 moves with the flow direction of biological water. The partially moved active silicon material 422 can be embedded in the micro-holes 4210 of the activated carbon 4211, so that the micro-holes 4210 can make the biological water with hydrogen dissolved therein have more contact area when flowing in the filter material 42. In order to increase the amount of dissolved hydrogen, the active silicon material 422 that is not embedded in the micropores 4210 can still be taken to the hollow fiber membrane 4212 along with the flow direction of biological water to be adsorbed on the surface of the hollow fiber membrane 4212, so that The composition of biological water in the hollow fiber membrane 4212 continues to react with the active silicon material 422, and an aeration effect occurs there to further increase the amount of dissolved hydrogen. In addition, the hollow fiber membrane 4212 can also intercept possible silicic acid polymerization or precipitation, so that the silicic acid polymerization or precipitation due to supersaturation can be reduced by the biological water that is continuously introduced into the accommodation space 40 of the filter 4 The concentration of silicic acid in biological water continues to dissolve. In brief, the filter core 4 of the third embodiment of the present invention is an integrated filter core.
參閱圖9,本發明濾心4之一第四實施例大致上是相同於該第三實施例(亦為一體式濾心),其不同處是在於,該濾材42於本發明該濾心4之載座41之容置空間40中的配置關係。同樣地,該載體421是活性碳4211與中空絲膜4212的組合,且該等活性矽材422是奈米矽材。活性碳4211是均勻分布在該載座41之容置空間40中,並相對中空絲膜4212靠近該進水口401,中空絲膜4212是位在該載座41之容置空間40中,以圍繞活性碳4211並相對活性碳4211靠近該出水口402。Referring to FIG. 9, a fourth embodiment of the filter element 4 of the present invention is substantially the same as the third embodiment (also an integrated filter element), except that the filter material 42 is different from the filter element 4 of the present invention. The arrangement relationship in the accommodation space 40 of the carrier 41. Similarly, the carrier 421 is a combination of activated carbon 4211 and hollow fiber membrane 4212, and the activated silicon materials 422 are nano-silicon materials. Activated carbon 4211 is evenly distributed in the accommodation space 40 of the carrier 41 and is close to the water inlet 401 relative to the hollow fiber membrane 4212. The hollow fiber membrane 4212 is located in the accommodation space 40 of the carrier 41 to surround The activated carbon 4211 is close to the water outlet 402 relative to the activated carbon 4211.
詳細地來說,在本發明該第四實施例之濾心4中,該容置空間40中是填充有該第一實施例之第一種濾材42(即,活性矽材422嵌於活性碳4211之微孔洞4210中者),並令該第一實施例之第三種濾材42(即,活性矽材422吸附於該等中空絲膜4212表面者)圍繞該第一實施例之第一種濾材42。In detail, in the filter core 4 of the fourth embodiment of the present invention, the accommodation space 40 is filled with the first filter material 42 of the first embodiment (that is, the activated silicon material 422 is embedded in activated carbon). 4211), and the third filter material 42 of the first embodiment (that is, the active silicon material 422 is adsorbed on the surface of the hollow fiber membranes 4212) surrounds the first of the first embodiment Kind of filter material 42.
圖9是顯示出使用後的狀態。同樣地,當本發明該第四實施例之濾心4在使用前,其活性碳4211與活性矽材422於該容置空間40內的配置關係是雷同於該第一或第三實施例。因此,當該第四實施例之濾心4於實際使用以自該載座41之進水口401輸入該生物用水(圖未示)時,該等活性矽材422同樣能隨著生物用水的流動方向流經活性碳4211及中空絲膜4212,以提升溶氫量,細節不再加以贅述。Fig. 9 shows a state after use. Similarly, when the filter core 4 of the fourth embodiment of the present invention is used, the arrangement relationship between the activated carbon 4211 and the active silicon material 422 in the accommodating space 40 is similar to that of the first or third embodiment. Therefore, when the filter 4 of the fourth embodiment is actually used to input the biological water (not shown) from the water inlet 401 of the carrier 41, the active silicon materials 422 can also flow with the biological water. Flow through activated carbon 4211 and hollow fiber membrane 4212 to increase the amount of dissolved hydrogen. Details will not be repeated here.
參閱圖10,本發明濾心4之一第五實施例大致上是相同於該第四實施例(亦為一體式濾心),其不同處是在於,該濾材42於本發明該濾心4之載座41之容置空間40中的配置關係,以及該進水口401與該出水口402的配置關係。同樣地,該載體421是活性碳4211與中空絲膜4212的組合,且該等活性矽材422是奈米矽材。在本發明該第五實施例之濾心4中,該進水口401與該出水口402位於該載座41之同一側,中空絲膜4212是位在該載座41之容置空間40中,且相對活性碳4211靠近該出水口402;活性碳4211是位在該載座41之容置空間40中以圍繞中空絲膜4212,且相對中空絲膜4212靠近進水口401。換句話說,中空絲膜4212是配置在該容置空間40中央,活性碳4211是與活性矽材422圍繞中空絲膜4212設置。Referring to FIG. 10, a fifth embodiment of the filter element 4 of the present invention is substantially the same as the fourth embodiment (also an integrated filter element), except that the filter material 42 is different from the filter element 4 of the present invention. The arrangement relationship in the accommodation space 40 of the carrier 41 and the arrangement relationship between the water inlet 401 and the water outlet 402. Similarly, the carrier 421 is a combination of activated carbon 4211 and hollow fiber membrane 4212, and the activated silicon materials 422 are nano-silicon materials. In the filter core 4 of the fifth embodiment of the present invention, the water inlet 401 and the water outlet 402 are located on the same side of the carrier 41, and the hollow fiber membrane 4212 is located in the accommodation space 40 of the carrier 41. The relatively activated carbon 4211 is close to the water outlet 402; the activated carbon 4211 is located in the accommodation space 40 of the carrier 41 to surround the hollow fiber membrane 4212, and is relatively close to the water inlet 401 relative to the hollow fiber membrane 4212. In other words, the hollow fiber membrane 4212 is disposed in the center of the accommodating space 40, and the activated carbon 4211 and the active silicon material 422 are disposed around the hollow fiber membrane 4212.
本發明該第五實施例之濾心4於實際使用時,該生物用水(圖未示)會先由該進水口401引入且順著該生物用水的流動方向流經過吸附於活性碳4211表面的活性矽材422並與活性矽材422反應生成矽酸與氫氣,以在形成溶出有矽酸與氫氣的生物用水組成後,再順著生物用水組成的流動方向經由中空絲膜4212的微孔洞4210流入中空絲膜4212內以朝該出水口402流出;其中,活性矽材422也可隨著該生物用水的流動方向被帶往中空絲膜4212以吸附於中空絲膜4212的表面。When the filter 4 of the fifth embodiment of the present invention is actually used, the biological water (not shown) is first introduced from the water inlet 401 and flows along the flow direction of the biological water through the surface adsorbed on the activated carbon 4211. The active silicon material 422 reacts with the active silicon material 422 to generate silicic acid and hydrogen, so that after the biological water composed of silicic acid and hydrogen is formed, it is then passed through the micropores of the hollow fiber membrane 4212 along the flow direction of the biological water composition 4210 flows into the hollow fiber membrane 4212 to flow out to the water outlet 402. Among them, the active silicon material 422 can also be taken to the hollow fiber membrane 4212 along with the flow direction of the biological water to be adsorbed on the surface of the hollow fiber membrane 4212.
值得一提的是,上述第一至第四實施例之濾心4的進水口401與出水口402,在其他實施例中,也可以是位於該載座41之同一側的配置關係。It is worth mentioning that the water inlet 401 and the water outlet 402 of the filter core 4 in the first to fourth embodiments described above may also be disposed on the same side of the carrier 41 in other embodiments.
參閱圖11,本發明濾心4的一第六實施例大致上是相同於該第三實施例,其不同處是在於,該第六實施例之濾心4還包括一拆卸式開關構件43,以及該載座41的細部結構及該濾材42的配置關係。Referring to FIG. 11, a sixth embodiment of the filter element 4 of the present invention is substantially the same as the third embodiment, except that the filter element 4 of the sixth embodiment further includes a detachable switch member 43, And the detailed structure of the carrier 41 and the arrangement relationship of the filter material 42.
詳細地來說,該載座41具有彼此間隔設置的一第一部件411及一第二部件412。該第一部件411與該第二部件412分別對應包括該進水口401與該出水口402,且各部件411、412具有一接口段4111、4121;其中,該等接口段4111、4121彼此相向且相通。該拆卸式開關構件43是連接於該第一部件411與該第二部件412間,且該載座41的容置空間40是由該第一部件411、該第二部件412與該拆卸式開關構件43所共同定義而成。同樣地,該載體421是活性碳4211與中空絲膜4212的組合,且該等活性矽材422是奈米矽材,活性碳4211是位在該載座41之第一部件411內,中空絲膜4212是位在該載座41的第二部件412內。換句話說,該第一實施例之第一種濾材42[即,活性矽材(如奈米矽材)422嵌於活性碳4211之微孔洞4210中者]是被填置於該第一部件411內,該第一實施例之第三種濾材42[即,活性矽材422(如奈米矽材)吸附於該等中空絲膜4212表面者]是被填置於該第二部件412內。In detail, the carrier 41 includes a first member 411 and a second member 412 disposed at intervals from each other. The first component 411 and the second component 412 respectively include the water inlet 401 and the water outlet 402, and each component 411, 412 has an interface section 4111, 4121; wherein the interface sections 4111, 4121 face each other and Communicate. The detachable switch member 43 is connected between the first member 411 and the second member 412, and the accommodation space 40 of the carrier 41 is formed by the first member 411, the second member 412, and the detachable switch. The components 43 are collectively defined. Similarly, the carrier 421 is a combination of activated carbon 4211 and hollow fiber membrane 4212, and the activated silicon materials 422 are nano-silicon materials, the activated carbon 4211 is located in the first part 411 of the carrier 41, and the hollow fiber The film 4212 is located in the second member 412 of the carrier 41. In other words, the first filter material 42 of the first embodiment [that is, the active silicon material (such as nano-silicon material) 422 embedded in the micro holes 4210 of the activated carbon 4211] is filled in the first In the component 411, the third filter material 42 of the first embodiment [that is, the active silicon material 422 (such as nanometer silicon material) is adsorbed on the surface of the hollow fiber membranes 4212] is filled in the second component 412 Inside.
在本發明該第六實施例之濾心4中,該拆卸式開關構件43是一旋轉式連接組件,且該載座41之第一部件411的接口段4111與第二部件412的接口段4121分別對應形成有一外螺紋4112、4122,及一彼此相向的環槽4113、4123。該旋轉式連接組件包括一形成有一內螺紋4310的貫孔螺帽431,及兩彈性的外止漏環432。該螺帽431具有反向凹陷的一上環槽4311與一下環槽4312,且該等外止漏環432是分別對應設置於該上環槽4311與該下環槽4312內。具體來說,本發明該第六實施例之載座41的第一部件411與第二部件412的環槽4113、4123是彼此相向設置,以透過一設置於該等環槽4113、4123內的內止漏環44來間隔設置,並透過設置有該等外止漏環432的貫孔螺帽431的內螺紋4310來螺接至該等部件411、412的外螺紋4112、4122,從而定義出該載座41的容置空間40,並密封該容置空間40以避免該容置空間40內的生物用水(圖未示)外洩。In the filter element 4 of the sixth embodiment of the present invention, the detachable switch member 43 is a rotary connection assembly, and the interface section 4111 of the first component 411 and the interface section 4121 of the second component 412 of the carrier 41 An external thread 4112, 4122 and an annular groove 4113, 4123 facing each other are formed correspondingly. The rotary connection assembly includes a through-hole nut 431 formed with an internal thread 4310, and two elastic outer leakage rings 432. The nut 431 has an upper ring groove 4311 and a lower ring groove 4312 which are recessed in opposite directions, and the outer leakage rings 432 are respectively disposed in the upper ring groove 4311 and the lower ring groove 4312. Specifically, the ring grooves 4113 and 4123 of the first member 411 and the second member 412 of the carrier 41 of the sixth embodiment of the present invention are disposed facing each other so as to pass through one of the ring grooves 4113 and 4123 provided in the ring grooves 4113 and 4123. The inner leakage rings 44 are arranged at intervals, and are screwed to the external threads 4112, 4122 of these parts 411, 412 through the internal threads 4310 of the through-hole nuts 431 provided with the external leakage rings 432, thereby defining The accommodating space 40 of the carrier 41 is sealed, and the accommodating space 40 is sealed to avoid leakage of biological water (not shown) in the accommodating space 40.
本發明該第六實施例之濾心4雖然是以該旋轉式連接組件的態樣來實施該可拆式開關構件43,但在其他實施例中,該旋轉式連接組件亦可替換為其他已知的可拆卸式開關構件,例如利用卡掣結構進行非旋轉式的卡合連接。Although the filter core 4 of the sixth embodiment of the present invention implements the detachable switch member 43 in the form of the rotary connection assembly, in other embodiments, the rotary connection assembly can also be replaced with other The known detachable switch member uses, for example, a non-rotating snap connection using a latch structure.
圖11所顯示的態樣是該生物用水尚未被輸入至該載座41的第二部件412內。一旦該第六實施例之濾心4於實際使用時,該等活性矽材422同樣能隨著該生物用水的流動方向被帶往位在該第二部件412內以吸附於該等中空絲膜4212表面。The state shown in FIG. 11 is that the biological water has not been input into the second part 412 of the carrier 41. Once the filter 4 of the sixth embodiment is actually used, the active silicon materials 422 can also be taken into the second member 412 to be adsorbed to the hollow fiber membranes along with the flow direction of the biological water. 4212 surface.
此外,值得補充說明的是,本發明該第六實施例之濾心4是一可分離式的濾心。簡單地來說,當被填置於該第一部件411中之該第一實施例之濾材42內的活性矽材422已無法再與該生物用水反應生成出矽酸與氫氣時,僅需鬆開該旋轉式連接組件的貫孔螺帽431以分離該第一部件411與該第二部件412,並更換第一部件411內部的濾材42,便可再透過該旋轉連接組件的貫孔螺帽431接合該第一部件411與該第二部件412的接口段4111、4121以重複使用該第六實施例之濾心4,從而達到節省費用的目的。In addition, it should be added that the filter element 4 of the sixth embodiment of the present invention is a separable filter element. Simply put, when the active silicon material 422 filled in the filter material 42 of the first embodiment in the first component 411 can no longer react with the biological water to generate silicic acid and hydrogen, it only needs to be loosened. Open the through-hole nut 431 of the rotary connection assembly to separate the first member 411 and the second member 412, and replace the filter material 42 inside the first member 411, and then pass through the through-hole nut of the rotary connection assembly 431 engages the interface sections 4111, 4121 of the first component 411 and the second component 412 to reuse the filter core 4 of the sixth embodiment, thereby achieving the purpose of saving costs.
參閱圖12與圖13,本發明淨水系統(或稱生物用水產製系統)的一第一實施例,是用以與一產製且容置有該生物用水9的生物用水單元2連接,並產製該含有矽酸(圖未示)及氫氣氣泡921的生物用水組成92,且該淨水系統是沿一水流方向F包括至少一第一濾心4,並選擇性地包括一具有至少一沿該水流方向F延伸的輸送管路72的管路單元7、一脫氣單元3、至少一第二濾心5,及/或一紫外光殺菌單元6;其中,該第一濾心4是使用如該第一實施例至該第六實施例中任一實施例所述的濾心4。該生物用水單元2包括一進水口201及一出水口202。適合做為該生物用水單元2的設備,可以是市售的逆滲透(reverse osmosis;以下簡稱R.O.)純水機或是其他淨水設備。當然,亦可直接取用自然水、地下水等其他未經過濾處理的生物用水。具體來說,本發明之淨水系統於適當條件下(如,以R.O.純水機作為該生物用水單元2),僅需單一個第一濾心4即可產製該生物用水組成92。12 and FIG. 13, a first embodiment of the water purification system (or biological water production system) of the present invention is used to connect to a biological water unit 2 produced and containing the biological water 9. The biological water composition 92 containing silicic acid (not shown) and hydrogen bubbles 921 is produced, and the water purification system includes at least one first filter element 4 along a water flow direction F, and optionally includes a filter element having at least one A pipeline unit 7, a degassing unit 3, at least a second filter element 5, and / or an ultraviolet light sterilization unit 6 of a conveying pipeline 72 extending along the water flow direction F; wherein the first filter element 4 The filter element 4 according to any one of the first to sixth embodiments is used. The biological water unit 2 includes a water inlet 201 and a water outlet 202. The equipment suitable as the biological water unit 2 may be a commercially available reverse osmosis (hereinafter referred to as R.O.) pure water machine or other water purification equipment. Of course, it is also possible to directly use natural water, groundwater and other biological water without filtering treatment. Specifically, the water purification system of the present invention can produce the biological water composition 92 under a suitable condition (for example, an R.O. pure water machine is used as the biological water unit 2), and only a single first filter 4 is required.
選擇性所包括的該脫氣單元3是沿該流水方向設置於該第一濾心4的一上游位置,並藉該管路單元7的輸送管路72沿該流水方向依序連接該脫氣單元的與該第一濾心4,並用以除去水中的氣體。具體來說,該脫氣單元3包括一界定出一容置空間30的載座31,及一填充於該容置空間30中的脫氣構件32。該脫氣單元3是用以使原本溶於該生物用水9內的溶解氣體,例如二氧化碳(CO2 )、氧氣(O2 )與氮氣(N2 )脫除,以藉此提升該等第一濾心4中之生物用水9內的溶氫量。適用於本發明該實施例之淨水系統的脫氣單元3可以是膜脫氣機(Filter-type Air Extractor),或是其他可吸附氣體的濾心。The degassing unit 3 included selectively is disposed at an upstream position of the first filter element 4 along the flowing water direction, and is sequentially connected to the degassing along the flowing water direction by the pipeline 72 of the pipeline unit 7 The unit is connected to the first filter element 4 and is used to remove the gas in the water. Specifically, the degassing unit 3 includes a carrier 31 defining an accommodation space 30, and a degassing member 32 filled in the accommodation space 30. The degassing unit 3 is used to remove dissolved gases, such as carbon dioxide (CO 2 ), oxygen (O 2 ), and nitrogen (N 2 ), which are originally dissolved in the biological water 9, so as to improve the first The amount of hydrogen dissolved in the biological water 9 in the filter 4. The degassing unit 3 suitable for the water purification system in this embodiment of the present invention may be a membrane-type air extractor (Filter-type Air Extractor), or other filters capable of adsorbing gas.
選擇性所包括的該第二濾心5在未包括有該脫氣單元3的實施狀態下,是沿該水流方向F設置於該第一濾心4的一下游位置,並包括一界定出一容置空間50的載座51,及複數填充於該載座51的容置空間50中的多孔性材料52。該第二濾心5的載座51具有相反設置並與其容置空間50相通的一進水口501及一出水口502。該第二濾心5內的多孔性材料52是選自活性碳521、中空絲膜522,或前述多孔性材料52的一組合。該管路單元7的輸送管路72是沿該水流方向F依序連接該第一濾心4及該第二濾心5。The second filter element 5 included in the selectivity is disposed at a downstream position of the first filter element 4 along the water flow direction F in an implementation state that does not include the degassing unit 3, and includes a boundary The accommodating space 51 of the accommodating space 50 and a plurality of porous materials 52 filled in the accommodating space 50 of the accommodating space 51. The carrier 51 of the second filter core 5 has a water inlet 501 and a water outlet 502 which are oppositely arranged and communicate with the accommodating space 50. The porous material 52 in the second filter element 5 is selected from activated carbon 521, hollow fiber membrane 522, or a combination of the foregoing porous materials 52. The conveying pipeline 72 of the pipeline unit 7 is sequentially connected to the first filter element 4 and the second filter element 5 along the water flow direction F.
選擇性所包括的紫外光殺菌單元6在未包括有該脫氣單元3與該第二濾心5的實施狀態下,是沿該水流方向F設置於該第一濾心4的一下游位置。該紫外光殺菌單元6是藉該管路單元7的輸送管路72沿該水流方向F依序連接該第一濾心4與該紫外光殺菌單元6,並用以對該生物用水組成92進行殺菌。具體來說,該紫外光殺菌單元6包括一界定出一容置空間60的載座61,及一紫外光燈組62。該載座61具有與其容置空間60相通且相反設置的一進水口601及一出水口602。在其他實施例中,亦可採用一紫外光燈柱(圖未示)軸向設置於該容置空間60中之結構態樣。The selective ultraviolet light sterilization unit 6 is provided at a downstream position of the first filter element 4 along the water flow direction F in the state where the deaeration unit 3 and the second filter element 5 are not included. The ultraviolet light sterilization unit 6 is used to sequentially connect the first filter element 4 and the ultraviolet light sterilization unit 6 along the water flow direction F through the transportation pipe 72 of the pipeline unit 7 and is used to sterilize the biological water composition 92 . Specifically, the ultraviolet sterilization unit 6 includes a carrier 61 defining an accommodation space 60 and an ultraviolet light group 62. The carrier 61 has a water inlet 601 and a water outlet 602 that are oppositely connected to the receiving space 60. In other embodiments, a structural state in which an ultraviolet lamp post (not shown) is axially disposed in the accommodating space 60 may also be adopted.
在本發明該第一實施例之淨水系統中,是透過一進水管路71與該生物用水單元2連接,並產製該含有矽酸(圖未示)及氫氣氣泡921的生物用水組成92,以透過一出水管路73送出該生物用水組成92;其中,該第一實施例之淨水系統沿該水流方向F依序包括該脫氣單元3、該第一濾心4、該第二濾心5,及該紫外光殺菌單元6,且該管路單元7之輸送管路72的數量是五個;該第一濾心4的數量是兩個,且是使用如該第一實施例所述的濾心4;該第二濾心5的數量是一個,且是呈直立式擺放,該第二濾心5內的多孔性材料52是中空絲膜522。In the water purification system according to the first embodiment of the present invention, a biological water composition 92 containing silicic acid (not shown) and hydrogen bubbles 921 is connected to the biological water unit 2 through a water inlet pipe 71, and a biological water composition 92 is produced. To send the biological water composition 92 through a water outlet pipe 73; wherein the water purification system of the first embodiment includes the degassing unit 3, the first filter 4, and the second along the water flow direction F in this order. The number of filter cores 5 and the ultraviolet light sterilization unit 6 and the number of transport lines 72 of the pipeline unit 7 are five; the number of the first filter cores 4 is two, and they are used as in the first embodiment The number of the filter elements 4 is one; the number of the second filter elements 5 is one, and the second filter element 5 is placed in an upright position. The porous material 52 in the second filter element 5 is a hollow fiber membrane 522.
換句話說,該進水管路71連接該生物用水單元2的進水口201;該等輸送管路72沿該水流方向F依序連接該生物用水單元2的出水口202與該脫氣單元3的進水口301、該脫氣單元3的出水口302與位於上游之該第一濾心4的進水口401、位於上游之該第一濾心4的出水口402與位於下游之該第一濾心4的進水口401、位於下游之該第一濾心4的出水口402與該第二濾心5的進水口501,及該第二濾心5的出水口502與該紫外光殺菌單元6的進水口601;而該出水管路73是連接該紫外光殺菌單元6之出水口602。In other words, the water inlet pipe 71 is connected to the water inlet 201 of the biological water unit 2; the delivery pipes 72 are sequentially connected along the water flow direction F to the water outlet 202 of the biological water unit 2 and the deaeration unit 3 Water inlet 301, water outlet 302 of the degassing unit 3, water inlet 401 of the first filter element 4 located upstream, water outlet 402 of the first filter element 4 located upstream, and the first filter element downstream The water inlet 401 of 4, the water outlet 402 of the first filter 4 and the water inlet 501 of the second filter 5 located downstream, and the water outlet 502 of the second filter 5 and the ultraviolet sterilization unit 6 The water inlet 601; and the water outlet pipe 73 is a water outlet 602 connected to the ultraviolet light sterilization unit 6.
需補充說明的是,基於該生物用水組成92本身及其沿該流水方向F移動時,本質上便會產生擾動現象。然而,此擾動現象會逐漸於該生物用水組成92內累積氣體以影響流體的流量。因此,該第二濾心5採直立擺放的用意在於,令第二濾心5之載座51容置空間50中的中空絲膜5212能在其容置空間50中呈垂直擺放,使累積在該第二濾心5之載座51容置空間50中的氣體易於自其出水口502排出流往連通該出水口502處的輸送管路72。It should be added that, based on the biological water composition 92 itself and its movement in the direction F of the flowing water, a disturbance phenomenon will be generated in essence. However, this disturbance phenomenon will gradually accumulate gas in the biological water composition 92 to affect the fluid flow. Therefore, the purpose of placing the second filter element 5 in an upright position is to allow the hollow fiber membrane 5212 in the receiving space 50 of the carrier 51 of the second filter element 5 to be placed vertically in the receiving space 50 so that The gas accumulated in the accommodating space 50 of the seat 51 of the second filter core 5 is easily discharged from its water outlet 502 and flows to the delivery pipe 72 communicating with the water outlet 502.
再參閱圖12與圖13,經使用本發明該第一實施例之淨水系統來實施該生物用水組成92的製法,其包括以下步驟:自該脫氣單元3的進水口301輸入該生物用水單元2所產製的生物用水9,以脫除該生物用水9內的CO2 、O2 與N2 ,並使經脫除前述氣體的生物用水9自該脫氣單元3的出水口302流經該管路單元7至位於上游的該第一濾心4;自位於上游的該第一濾心4的進水口401輸入該生物用水9,以令該生物用水9沿該水流方向F流經其濾材42並與其濾材42之活性矽材422反應生成矽酸與氫氣,從而在該生物用水9內溶出矽酸與氫氣氣泡921,並令該含有該生物用水9、矽酸、氫氣氣泡921與一部分活性矽材422的生物用水組成92自位於上游的該第一濾心4的出水口402流經該管路單元7的輸送管路72(見圖13)至位於下游的該第一濾心4;自位於下游的該第一濾心4的進水口401輸入該生物用水組成92,令該生物用水組成92與位於下游的該第一濾心4內的活性矽材422繼續反應生成矽酸與氫氣氣泡921,以藉此提升該生物用水組成92的溶氫量,並自位於下游的該第一濾心4的出水口402流經該管路單元7至該第二濾心5;自該第二濾心5的進水口501輸入該生物用水組成92,以令該生物用水組成92沿該水流方向F流經該第二濾心5的該等中空絲膜522並局部或全部過濾該生物用水組成92中的該部分活性矽材422,且令該經局部或全部過濾的生物用水組成92自該第二濾心5的出水口502流經該管路單元7至該紫外光殺菌單元6;及自該紫外光殺菌單元6的進水口601輸入該生物用水組成92至其容置空間60中,透過該紫外光燈組62對該生物用水組成92進行殺菌程序,以進一步地透過該出水管路73令該生物用水組成92自該紫外光殺菌單元6的出水口602輸出該生物用水組成92。Referring again to FIG. 12 and FIG. 13, the method for manufacturing the biological water composition 92 is implemented by using the water purification system of the first embodiment of the present invention, which includes the following steps: inputting the biological water from the water inlet 301 of the degassing unit 3 The biological water 9 produced by the unit 2 is used to remove the CO 2 , O 2 and N 2 in the biological water 9, and the biological water 9 from which the foregoing gas has been removed flows from the water outlet 302 of the degassing unit 3. Through the pipeline unit 7 to the first filter core 4 located upstream; the biological water 9 is input from the water inlet 401 of the first filter core 4 located upstream so that the biological water 9 flows through the water flow direction F The filter material 42 reacts with the active silicon material 422 of the filter material 42 to generate silicic acid and hydrogen, thereby dissolving silicic acid and hydrogen bubbles 921 in the biological water 9, and the biological water 9, silicic acid, hydrogen bubbles 921 and A part of the biological water composition 92 of the active silicon material 422 flows from the water outlet 402 of the first filter core 4 located upstream to the delivery pipe 72 (see FIG. 13) of the pipeline unit 7 to the first filter core located downstream. 4; input the biological water composition 9 from the water inlet 401 of the first filter 4 located downstream 2. The biological water composition 92 and the active silicon material 422 located in the first filter element 4 downstream continue to react to generate silicic acid and hydrogen bubbles 921, thereby increasing the amount of hydrogen dissolved in the biological water composition 92, and The water outlet 402 of the first filter 4 located downstream flows through the pipeline unit 7 to the second filter 5; the biological water composition 92 is input from the water inlet 501 of the second filter 5 to make the organism The water composition 92 flows through the hollow fiber membranes 522 of the second filter element 5 along the water flow direction F and partially or completely filters the part of the active silicon material 422 in the biological water composition 92, and allows the partial or total filtration The biological water composition 92 flows from the water outlet 502 of the second filter 5 through the pipeline unit 7 to the ultraviolet light sterilization unit 6; and the biological water composition 92 is input from the water inlet 601 of the ultraviolet light sterilization unit 6 In the accommodating space 60, the biological water composition 92 is sterilized through the ultraviolet light group 62 to further pass the water outlet pipe 73 to make the biological water composition 92 from the water outlet 602 of the ultraviolet light sterilization unit 6. The biological water composition 92 is output.
值得一提的是,該第一濾心4的數量可以變更,越多的第一濾心4,ORP值通常就越低。另外,若下游的第一濾心4採用圖8至圖11之具有中空絲膜4212的濾心4,就可選擇性地省去該第二濾心5。It is worth mentioning that the number of the first filter element 4 can be changed. The more the first filter element 4 is, the lower the ORP value is usually. In addition, if the downstream first filter element 4 adopts the filter element 4 with a hollow fiber membrane 4212 in FIGS. 8 to 11, the second filter element 5 can be selectively omitted.
參閱圖14與圖15,本發明淨水系統的一第二實施例大致上是相同於該第一實施例,其不同處是在於,該第二實施例之淨水系統還包括一排出單元74及兩總溶解固體量(total dissolved solids;簡稱TDS)量測單元75,且該第二實施例之淨水系統未包括該脫氣單元3,該第一濾心4的數量是一個,該第二濾心5的數量是複數個,且該等第二濾心5之容置空間50中的內容物是有別於該第一實施例之第二濾心5。在本發明該第二實施例之淨水系統中,該管路單元7之輸送管路72的數量是四個,該第二濾心5的數量是兩個,填充於該等第二濾心5之載座51的容置空間50中的多孔性材料52沿該水流方向F依序是活性碳521與中空絲膜522(也就是,位於上游位置處的第二濾心5的載座51的容置空間50內填充有活性碳521,位於下游位置處的第二濾心5的載座51的容置空間50內填充有中空絲膜522),且位於上游位置處的第二濾心5還包括填充於其容置空間50中的奈米銀53。14 and FIG. 15, a second embodiment of the water purification system of the present invention is substantially the same as the first embodiment, except that the water purification system of the second embodiment further includes a discharge unit 74 And two total dissolved solids (referred to as TDS) measurement unit 75, and the water purification system of the second embodiment does not include the degassing unit 3, the number of the first filter element 4 is one, the first The number of the two filter elements 5 is plural, and the contents in the accommodating spaces 50 of the second filter elements 5 are different from the second filter elements 5 of the first embodiment. In the water purification system according to the second embodiment of the present invention, the number of the conveying pipes 72 of the pipeline unit 7 is four, and the number of the second filters 5 is two, which are filled in the second filters. The porous material 52 in the accommodating space 50 of the carrier 51 of 5 is sequentially the activated carbon 521 and the hollow fiber membrane 522 along the water flow direction F (that is, the carrier 51 of the second filter element 5 located at the upstream position). The accommodating space 50 is filled with activated carbon 521, the accommodating space 50 of the carrier 51 of the second filter 5 located at the downstream position is filled with hollow fiber membrane 522), and the second filter is located at the upstream position 5 also includes nanosilver 53 filled in its accommodation space 50.
該排出單元74是設置於該管路單元7上,且沿該水流方向F位於下游位置處的該第二濾心5後。具體來說,該排出單元74是一設置在連接該下游位置處的第二濾心5的出水口502與該紫外光殺菌單元6的進水口601間的輸送管路72上的洩壓閥門(valve),以連通該管路單元7的輸送管路72並用以排出液體、氣體,或液體與氣體的一組合。需補充說明的是,礙於該生物用水9沿著該流水方向F引入至該等濾心4、5的過程中,會不斷地因自身及其所產生的擾流而累積氣體,使得該等輸送管路72內的壓力值過高從而影響液體流量。因此,該第二實施例之淨水系統內的排出單元(即,洩壓閥門)74主要用意是在於,排除流體在該等輸送管路內72因累積過多的氣體所增加的壓力值,以藉此提升液體的流量。The discharge unit 74 is disposed behind the second filter element 5 on the pipeline unit 7 and located at a downstream position along the water flow direction F. Specifically, the discharge unit 74 is a pressure relief valve on a transmission line 72 provided between the water outlet 502 of the second filter core 5 connected to the downstream position and the water inlet 601 of the ultraviolet light sterilization unit 6 ( valve) to communicate with the delivery pipe 72 of the pipe unit 7 and to discharge liquid, gas, or a combination of liquid and gas. It should be added that the process of introducing the biological water 9 into the filters 4 and 5 along the flowing water direction F will continuously accumulate gas due to itself and the turbulence generated by it, such that The pressure value in the delivery pipe 72 is too high, which affects the liquid flow. Therefore, the discharge unit (ie, the pressure relief valve) 74 in the water purification system of the second embodiment is mainly intended to exclude the pressure value of the fluid in the conveying pipes 72 due to the accumulation of excessive gas, so as to This increases the liquid flow.
該等總溶解固體量量測單元75是沿該水流方向F分別設置於該第一濾心4的一上游位置與一下游位置。具體來說,位在上游位置處的該總溶解固體量量測單元75是設置在連接該生物用水單元2的出水口202與該第一濾心4的進水口401間的輸送管路72上,且位在下游位置處的該總溶解固體量量測單元75是設置在連接該下游位置處的第二濾心5的出水口502與該紫外光殺菌單元6的進水口601間的輸送管路72上,並沿該水流方向F位在該排除單元74的下游位置。須說明的是,位在下游位置處的該總溶解固體量量測單元75所測得的總溶解固體量(以下稱Vt ),會大於位在上游位置處的該總溶解固體量量測單元75所測得的總溶解固體量(以下稱V0 ),其兩者間會有一總溶解固體量差值(∆V)。因此,本發明該第二實施例之淨水系統增設該等總溶解固體量量測單元75的目的在於,利用該等總溶解固體量量測單元75來取得該總溶解固體量差值(∆V),一旦該總溶解固體量差值(∆V)小於使用者所設定的預定數值時,代表該生物用水組成92內可溶出矽酸與氫氣氣泡921的量已逐漸下降,有更換該第一濾心4之濾材42的需求。The total dissolved solid measurement units 75 are respectively disposed at an upstream position and a downstream position of the first filter element 4 along the water flow direction F. Specifically, the total dissolved solids measuring unit 75 located at an upstream position is disposed on a conveying pipe 72 connecting the water outlet 202 of the biological water unit 2 and the water inlet 401 of the first filter 4. The total dissolved solids measuring unit 75 located at the downstream position is a conveying pipe provided between the water outlet 502 of the second filter 5 and the water inlet 601 of the ultraviolet sterilization unit 6 connected to the downstream position. It is located on the road 72 and is located downstream of the exclusion unit 74 along the water flow direction F. It should be noted that the total dissolved solids amount (hereinafter referred to as V t ) measured by the total dissolved solids measurement unit 75 at the downstream position will be greater than the total dissolved solids measurement at the upstream position. The total dissolved solids amount (hereinafter referred to as V 0 ) measured by the unit 75 will have a total dissolved solids difference (ΔV) therebetween. Therefore, the purpose of adding the total dissolved solids measurement unit 75 in the water purification system of the second embodiment of the present invention is to use the total dissolved solids measurement unit 75 to obtain the total dissolved solids difference (Δ V). Once the total dissolved solids difference (ΔV) is less than a predetermined value set by the user, it means that the amount of dissolvable silicic acid and hydrogen bubbles 921 in the biological water composition 92 has gradually decreased. The requirement of the filter material 42 of the filter core 4.
參閱圖16,本發明淨水系統之一第三實施例大致上是相同於該第二實施例,其不同處是在於,該第三實施例之淨水系統還包括一流量計76,且該排出單元74是設置於該管路單元7上且位於該第一濾心4與該等第二濾心5間。該流量計76是沿該水流方向F設置於該第一濾心4的上游位置。Referring to FIG. 16, a third embodiment of a water purification system of the present invention is substantially the same as the second embodiment, except that the water purification system of the third embodiment further includes a flow meter 76, and the The discharge unit 74 is disposed on the pipeline unit 7 and is located between the first filter element 4 and the second filter elements 5. The flow meter 76 is disposed upstream of the first filter element 4 along the water flow direction F.
具體來說,本發明該第三實施例之淨水系統的排出單元74是設置在連接位於上游位置處的第二濾心5的出水口502與位於下游位置處的第二濾心5的進水口501間的輸送管路72上,且位於上游位置處的第二濾心5的進水口501是低於其出水口502,而位於下游位置處的第二濾心5的進水口501是高於其出水口502。須說明的是,本發明該第三實施例之淨水系統將該排出單元(洩氣閥門)74設置在下游位置處之第二濾心5的進水口501前,並令其進水口501高於其出水口502的目的是在於,提升排氣效果,並令下游位置處之濾心5的容置空間50內的氣體容易因上進下出而有利於氣體的排出並減少所累積的氣體。Specifically, the drain unit 74 of the water purification system according to the third embodiment of the present invention is disposed between the water outlet 502 of the second filter element 5 located at the upstream position and the inlet of the second filter element 5 located at the downstream position. The water inlet 501 of the second filter element 5 located on the transmission line 72 between the water outlets 501 and located at the upstream position is lower than the water outlet 502 thereof, and the water inlet 501 of the second filter core 5 located at the downstream position is high于 出 出 水口 502。 In its water outlet 502. It should be noted that, in the water purification system of the third embodiment of the present invention, the discharge unit (vent valve) 74 is disposed in front of the water inlet 501 of the second filter 5 at a downstream position, and the water inlet 501 is higher than The purpose of the water outlet 502 is to improve the exhaust effect and make the gas in the accommodation space 50 of the filter core 5 at the downstream position easier to go up and down to facilitate the discharge of the gas and reduce the accumulated gas.
此外,在本發明該第三實施例之淨水系統中,該流量計76是設置在連接該生物用水單元2的出水口202與該第一濾心4的進水口401間的輸送管路72上,並沿該水流方向F位在該上游位置處的總溶解固體量量測單元75的上游位置。此處須說明的是,當下游位置處的排出單元74未適時地打開洩氣閥門以排出所累積的氣體,或是各濾心4、5有阻塞時,位於上游處的流量計76所檢測到的水流速度會由初始的0.9~2 L/min下降至0.4 L/min左右,嚴重影響產製該生物用水組成92的速度與品質(如細菌滋生、口感變化等問題)。因此,本發明該第三實施例之淨水系統增設該流量計76的目的是在於,適時地在水流速度下降時利用該排出單元74排除累積於輸送管路72內的氣體,及/或搭配總溶解固體量差值(∆V)與濾心4、5的使用時間以藉此告知使用者更換濾心4、5。In addition, in the water purification system according to the third embodiment of the present invention, the flow meter 76 is a transmission line 72 provided between the water outlet 202 of the biological water unit 2 and the water inlet 401 of the first filter 4. Up, and located upstream of the total dissolved solids measuring unit 75 at the upstream position along the water flow direction F. It should be noted here that when the discharge unit 74 at the downstream position does not open the vent valve in time to discharge the accumulated gas, or the filter elements 4 and 5 are blocked, the flow meter 76 located at the upstream detects The water flow speed will drop from the initial 0.9 ~ 2 L / min to about 0.4 L / min, which will seriously affect the speed and quality of the water composition 92 (such as bacteria growth and taste changes). Therefore, the purpose of adding the flow meter 76 to the water purification system of the third embodiment of the present invention is to use the discharge unit 74 to remove the gas accumulated in the conveying pipe 72 in a timely manner when the water flow speed decreases, and / or to match The difference between the total dissolved solids (ΔV) and the use time of the filters 4 and 5 is used to inform the user to replace the filters 4 and 5.
<生物用水組成及其製法之具體例1><Specific Example 1 of Biological Water Composition and Production Method>
本發明生物用水組成92及其製法之一具體例1是使用上述第二實施例之濾心4[也就是如圖6所示的濾心4,黏結材423結合活性矽材(如,奈米矽材)422與活性碳4211,令部分活性矽材422附著於活性碳4211上]來實施,其濾心4內的濾材42、由其濾心4所產製之生物用水組成及其生物用水組成的製法簡單說明於下。One of the specific examples 1 of the biological water composition 92 of the present invention and its preparation method is to use the filter 4 of the second embodiment described above [that is, the filter 4 shown in FIG. 6, and the bonding material 423 is combined with an active silicon material (such as nanometer). (Silicon material) 422 and activated carbon 4211, so that part of the activated silicon material 422 is attached to the activated carbon 4211], the filter material 42 in its filter core 4, the biological water produced by the filter core 4 and its biological water The composition method is briefly explained below.
再參閱圖6,自該濾心4的進水口401引入飲用水,令該飲用水與該濾材42中的活性矽材422反應生成矽酸(圖未示)與氫氣,從而製得溶有矽酸與氫氣氣泡921之生物用水組成92(見圖13),並令該具體例1之生物用水組成自該出水口402流出。在本發明該具體例1中,活性矽材422的規格與出處是純度與粒徑D50各為99.35%與約200 nm的奈米矽材,且前述奈米矽材是經研磨細化純度9N的矽晶圓所取得,活性碳4211是購自高仕達炭科技股份有限公司的椰殼活性碳,且活性碳的粒徑約介於150至380 μm間,黏結材423是購自Tinoca 型號為GUR2122的超高分子量聚乙烯(polyethylene,簡稱PE)。Referring again to FIG. 6, drinking water is introduced from the water inlet 401 of the filter 4, and the drinking water is reacted with the active silicon material 422 in the filter material 42 to generate silicic acid (not shown) and hydrogen, so that silicon is dissolved. The biological water composition 92 of the acid and hydrogen bubbles 921 (see FIG. 13), and the biological water composition of the specific example 1 is caused to flow out from the water outlet 402. In the specific example 1 of the present invention, the specifications and provenance of the active silicon material 422 are nano silicon materials each having a purity and a particle size D50 of 99.35% and about 200 nm, and the nano silicon material is ground to a purity of 9N. The activated carbon 4211 is a coconut shell activated carbon purchased from Goldstar Carbon Technology Co., Ltd., and the particle size of the activated carbon is between 150 and 380 μm. The bonding material 423 is purchased from Tinoca and the model is GUR2122. Ultra high molecular weight polyethylene (PE).
經本發明該具體例1之製法所產製的生物用水組成92的矽酸濃度與ORP值是經產自JAQUA之型號為EO221之電極與產自Horiba的氧化還原電位分析主機分析取得其氧化還原電位(ORP),並經Merck比色法藥品量測其矽酸濃度,其分析結果彙整於下列 表1.。The silicic acid concentration and ORP value of the composition 92 of biological water produced by the production method of the specific example 1 of the present invention are obtained by analyzing the redox potential of the electrode of model EO221 produced by JAQUA and the redox potential analysis produced by Horiba. (ORP), and the silicic acid concentration was measured by Merck colorimetric drugs, and the analysis results are summarized in Table 1 below.
表1.
<第一種濾材及其製法之具體例>< Specific example of the first filter material and its manufacturing method >
本發明第一種濾材及其製法之一具體例是根據該第一實施例之濾心之第一種濾材的製法來實施,其所使用的奈米矽材的出處與規格是相同於上述具體例1,且活性碳的出處與規格是Haycarb之型號為RWAP 10742的活性碳(粒徑約介於1.7 mm至0.425 mm間,下稱HB活性碳)。有關於該第一種濾材之具體例的詳細製作條件,說明於下。One specific example of the first filter material of the present invention and the manufacturing method thereof is implemented according to the method of manufacturing the first filter material of the filter core of the first embodiment. The source and specifications of the nano-silicon material used are the same as those described above. Example 1, and the source and specification of the activated carbon is Haycarb's type RWAP 10742 activated carbon (particle size is between 1.7 mm and 0.425 mm, hereinafter referred to as HB activated carbon). The detailed production conditions of the specific example of the first filter medium are described below.
首先,在一攪拌器內加入80 g的奈米矽材與純度為99.5%的酒精以均勻攪拌成一固含量為20%的奈米矽漿料。接著,於該奈米矽漿料內添加270 g的活性碳並均勻攪拌,以令該奈米矽漿料內的奈米矽材得以嵌入活性碳的微孔洞中。最後,烘乾並去除奈米矽漿料中的酒精,從而製得該具體例之第一種濾材。以該具體例之第一種濾材的重量百分比計,活性碳與奈米矽材各為77.1 wt%與22.9 wt%。First, add 80 g of nano-silicon material and 99.5% purity alcohol in a stirrer to uniformly stir into a nano-silicon slurry with a solid content of 20%. Then, 270 g of activated carbon is added to the nano-silicon slurry and uniformly stirred, so that the nano-silicon material in the nano-silicon slurry can be embedded in the micropores of the activated carbon. Finally, the alcohol in the nano-silica slurry is dried and removed, so as to obtain the first filter material of the specific example. Based on the weight percentage of the first filter material in this specific example, the activated carbon and the nano-silica material were 77.1 wt% and 22.9 wt%, respectively.
<濾心及其製法之具體例><Specific examples of the filter and its manufacturing method>
再參閱圖1,本發明濾心之一具體例是根據上述第一實施例之濾心4來實施,其所使用的奈米矽材的出處與規格是相同於上述第一種濾材及其製法的具體例。有關於該具體例之濾心的詳細製作條件,是說明於下。Referring again to FIG. 1, a specific example of the filter of the present invention is implemented according to the filter 4 of the first embodiment described above. The source and specifications of the nano-silicon material used are the same as those of the first filter material and its manufacturing method. Specific examples. The detailed manufacturing conditions of the filter of this specific example are explained below.
首先,自本發明該具體例之濾心之一載座的一出水口依序於其一容置空間中填入50 g的活性碳(底層)、100 g的奈米矽材(中段),與230 g的活性碳(上層),以作為該具體例之濾心的濾材;其中,以該具體例之濾心之濾材的重量百分比計,活性碳與奈米矽材的含量各為73.7 wt%與26.3 wt%。接著,於該載座之一進水口與該出水口分別接上一輸送管路。最後,自該載座之進水口輸入飲用水至該容置空間內令該飲用水朝向該出水口的一流動方向帶動奈米矽材四處流動,以使奈米矽材得以嵌入活性碳的微孔洞內;其中,在該飲用水被輸入至該容置空間以接觸到奈米矽材時,是同時反應生成矽酸與氫氣,且活性碳之微孔洞內所嵌入的奈米矽材有利於提升溶氫量,其有利於提升溶氫量的原因已載明於前述發明詳細說明中,於此不再多加贅述。First, a water outlet of a carrier of the filter core of this specific example of the present invention is sequentially filled with 50 g of activated carbon (bottom layer) and 100 g of nano-silicon material (middle section) in a containing space. And 230 g of activated carbon (upper layer) as the filter material of the specific example; wherein, based on the weight percentage of the filter material of the specific example, the content of the activated carbon and the nano-silica material were each 73.7 wt. % And 26.3 wt%. Then, a delivery pipe is connected to a water inlet and a water outlet of the carrier, respectively. Finally, the drinking water is input from the water inlet of the carrier into the accommodating space, so that the drinking water drives the nano-silicon material to flow around in a direction of the water outlet, so that the nano-silicon material can be embedded into the micro-particles of activated carbon. Inside the hole; when the drinking water is input into the accommodating space to contact the nano-silicon material, the nano-silicon material embedded in the micro-holes of the activated carbon is simultaneously reacted to generate silicic acid and hydrogen It is beneficial to increase the amount of dissolved hydrogen, and the reason for the increase in the amount of dissolved hydrogen has been described in the detailed description of the foregoing invention, and will not be repeated here.
<生物用水組成及其製法之具體例2><Specific Example 2 of Biological Water Composition and Production Method>
本發明生物用水組成及其製法之一具體例2是使用該第一實施例之該淨水系統來實施);換句話說,本發明具體例2之生物用水組成及其製法中所使用的兩個第一濾心,是根據上面所載之具體例之濾心的製法來實施;其中,該具體例2所使用的奈米矽材的出處與規格亦是相同於上述第一種濾材及其製法的具體例。有關於本發明具體例2之生物用水組成及其製法的詳細製作條件,是說明於下。One specific example 2 of the composition of biological water of the present invention and its preparation method is implemented using the water purification system of the first embodiment); in other words, the composition of biological water of specific example 2 of the present invention and the two methods used in its preparation method The first filter element is implemented according to the method for manufacturing the filter element of the specific example described above; among them, the source and specifications of the nanometer silicon material used in the specific example 2 are also the same as those of the first filter element and its Specific examples of manufacturing methods. The detailed production conditions of the biological water composition and the production method of the specific example 2 of the present invention are described below.
首先,自一產自ADD且型號為400P的R.O.純水機產製一飲用水,以令該飲用水自該R.O.純水機的一出水口流經一管路單元至一膜脫氣機。First, drinking water is produced from an R.O. pure water machine of 400P model produced by ADD, so that the drinking water flows from a water outlet of the R.O. pure water machine through a pipeline unit to a membrane deaerator.
接著,自該膜脫氣機的一進水口輸入該飲用水以脫除該飲用水內的CO2 、O2 與N2 ,並使經脫除前述氣體的飲用水自該膜脫氣機的一出水口流經該管路單元至位於上游位置處的該第一濾心。Next, the drinking water is input from a water inlet of the membrane degasser to remove CO 2 , O 2 and N 2 in the drinking water, and the drinking water from which the foregoing gas has been removed is removed from the membrane degasser. A water outlet flows through the pipeline unit to the first filter core at an upstream position.
接續,是自位於上游位置處的該第一濾心的一進水口輸入該飲用水以令該飲用水沿其一水流方向流經其濾材並與其濾材之奈米矽材反應生成矽酸與氫氣,從而在該飲用水內溶出矽酸與氫氣,並令一含有該飲用水、矽酸、氫氣與一部分奈米矽材的生物用水組成,且自位於上游位置處的該第一濾心的一出水口流經該管路單元的一輸送管路至位於下游位置處的一第一濾心,以進一步於下游位置處的該第一濾心的一進水口輸入該生物用水組成,令該生物用水組成與位於下游位置處的該第一濾心內的奈米矽材繼續反應生成矽酸與氫氣以藉此提升溶氫量,並自位於下游的該第一濾心的一出水口流經該管路單元至一第二濾心。Next, the drinking water is input from an inlet of the first filter element at an upstream position, so that the drinking water flows through its filter material along a direction of water flow and reacts with the nano-silicon material of the filter material to generate silicic acid and hydrogen. So that silicic acid and hydrogen are dissolved in the drinking water, and a biological water containing the drinking water, silicic acid, hydrogen and a part of nano-silicon material is composed, and a part of the first filter element located at an upstream position is formed. The water outlet flows through a conveying pipeline of the pipeline unit to a first filter element located at a downstream position, and further inputs the biological water composition into a water inlet of the first filter element at a downstream position, so that the organism The water composition and the nano-silicon material in the first filter element at the downstream position continue to react to generate silicic acid and hydrogen to thereby increase the amount of dissolved hydrogen, and flow through a water outlet of the first filter element at the downstream position. The pipeline unit is connected to a second filter element.
後續,自該第二濾心的一進水口輸入該生物用水組成以令該生物用水組成沿其水流方向流經該第二濾心的複數中空絲膜(購自SAMPO,且型號為FJ-V1203BL),並局部或全部過濾該生物用水組成中的該部分奈米矽材,且令該經局部或全部過濾的生物用水組成自該第二濾心的一出水口流經該管路單元至一紫外光殺菌機(購自KC-FLOW,且型號為16W-2GPM)。Subsequently, the biological water composition is input from a water inlet of the second filter element so that the biological water composition flows through the second filter element through a hollow fiber membrane (purchased from SAMPO, and the model number is FJ-V1203BL). ), And partially or completely filter the part of the nano-silica material in the biological water composition, and make the partially or completely filtered biological water composition flow from an outlet of the second filter core through the pipeline unit to a Ultraviolet sterilizer (purchased from KC-FLOW, and the model is 16W-2GPM).
最後,自該紫外光殺菌機的一進水口輸入該生物用水組成以進行殺菌程序,並進一步地令該生物用水組成自該紫外光殺菌機的一出水口輸出該生物用水組成。此處需補充說明的是,雖然本發明該具體例2之生物用水組成及其製法中所用之淨水系統的該兩第一濾心是如上述。然而,本發明該具體例2之生物用水組成及其製法中所使用的該兩第一濾心中的濾材,亦可以是根據上面所載該具體例之第一種濾材的製法來實施。Finally, the biological water composition is input from a water inlet of the ultraviolet sterilizer to perform a sterilization process, and the biological water composition is further output from a water outlet of the ultraviolet sterilizer to output the biological water composition. What needs to be supplemented here is that although the biological water composition of the specific example 2 of the present invention and the two first filters of the water purification system used in the preparation method thereof are as described above. However, the biological water composition of the specific example 2 of the present invention and the filter materials in the two first filters used in the manufacturing method thereof may also be implemented according to the manufacturing method of the first filter material of the specific example described above.
在本發明生物用水組成及其製法的具體例2中,自位於上游的該第一濾心之進水口輸入該飲用水至該生物用水組成流出該紫外光殺菌機之出水口為止持續生產15天所製得的生物用水組成,其氧化還原電位(ORP)與矽酸濃度,是簡單地彙整於以下 表2.。In the specific example 2 of the biological water composition and the manufacturing method thereof of the present invention, the drinking water is input from the water inlet of the first filter element located upstream to the biological water composition flowing out of the water outlet of the ultraviolet sterilizer for 15 days. The prepared biological water composition, its redox potential (ORP) and silicic acid concentration are simply summarized in Table 2 below.
表2.
值得一提的是,若使用新的第一濾心,則上述數據會更佳,ORP值可低於-670 mV。It is worth mentioning that if the new first filter is used, the above data will be better, and the ORP value can be lower than -670 mV.
此外,參閱圖17,由本發明該具體例2之生物用水組成於開瓶後測試經不同的填充率所取得的氧化還原電位(ORP)顯示可知,當瓶內的填充率僅為23%左右時,其經432分鐘的穩定性測試後的ORP值雖然是從-570 mV左右提升至-100 mV,但其經60分鐘的穩定性測試後的ORP值卻仍可維持在-500 mV左右。再者,當瓶內的填充為90%時,其經432分鐘的穩定性測試後的ORP值仍可維持在-450 mV以下;又,當瓶內的填充提升至93.48%時,其經432分鐘的穩定性測試後的ORP值則可維持在-530 mV左右。由前述穩定性分析結果顯示,本發明該具體例2之生物用水組成的氧化還原電位(ORP)穩定性佳。In addition, referring to FIG. 17, the redox potential (ORP) obtained from the biological water of the specific example 2 of the present invention after opening the bottle and tested through different filling rates shows that when the filling rate in the bottle is only about 23% Although the ORP value after the 432-minute stability test was increased from -570 mV to -100 mV, the ORP value after the 60-minute stability test was still maintained at -500 mV. In addition, when the filling in the bottle is 90%, the ORP value after the 432-minute stability test can still be maintained below -450 mV; when the filling in the bottle is increased to 93.48%, it is passed 432 The ORP value after a one-minute stability test can be maintained at -530 mV. The stability analysis results show that the oxidation-reduction potential (ORP) composition of the biological water of the specific example 2 of the present invention has good stability.
<應用例>< Application example >
為了進一步證實本發明該具體例2之生物用水組成添加於物品內具有減緩氧化速度的功效,申請人是於兩個容量皆為0.2 L的玻璃瓶內填入100 c.c.的蘋果汁後,並於該兩玻璃瓶內分別填入100 c.c.的該具體例2之生物用水組成(以下稱應用例)與一般的飲用水(以下稱比較例),且封閉該兩玻璃瓶以進行氧化速度比較測試。參閱圖18同時配合參閱附件所顯示的彩色影像可知,該比較例(右側玻璃瓶)之蘋果汁經過約3小時後,其顏色已經自黃橙色轉變成暗橙色,證實該比較例之蘋果之已明顯氧化。反觀本發明該應用例(左側玻璃瓶)之蘋果汁經過約3小時後,其顏色仍維持在黃橙色的狀態,證實本發明該具體例2之生物用水組成添加於蘋果汁內可減緩其氧化的問題。In order to further confirm that the biological water composition of the specific example 2 of the present invention has the effect of slowing the oxidation rate when added to the article, the applicant filled 100 cc apple juice into two glass bottles with a capacity of 0.2 L, and The two glass bottles were filled with 100 cc of the biological water composition of the specific example 2 (hereinafter referred to as an application example) and general drinking water (hereinafter referred to as a comparative example), and the two glass bottles were closed for a comparison test of oxidation speed. Referring to Figure 18 and the color image shown in the attachment, it can be seen that the apple juice of this comparative example (right glass bottle) has changed its color from yellow orange to dark orange after about 3 hours, confirming that the apple of this comparative example has already Significantly oxidized. In contrast, after about 3 hours, the apple juice of the application example (left glass bottle) of the present invention remains in a yellow-orange state, confirming that the biological water composition of the specific example 2 of the present invention is added to the apple juice to slow down its oxidation. The problem.
綜上所述,本發明之濾心4與使用其濾心4的淨水系統,利用形成於該載體(如,活性碳4211、中空絲膜4212等多孔性材料)的表面的活性矽材422與生物用水9反應生成矽酸與氫氣氣泡921,使生物用水9內的溶氫量及溶矽量兩者均獲得提升並提供安全的生物用水組成92,故確實能達成本發明的目的。In summary, the filter core 4 and the water purification system using the filter core 4 of the present invention utilize active silicon material 422 formed on the surface of the carrier (such as porous materials such as activated carbon 4211 and hollow fiber membrane 4212). It reacts with biological water 9 to generate silicic acid and hydrogen bubbles 921, so that both the amount of dissolved hydrogen and the amount of dissolved silicon in biological water 9 are improved and a safe composition of biological water 92 is provided. Therefore, the purpose of the present invention can be achieved.
惟以上所述者,僅為本發明的實施例而已,當不能以此限定本發明實施的範圍,凡是依本發明申請專利範圍及專利說明書內容所作的簡單的等效變化與修飾,皆仍屬本發明專利涵蓋的範圍內。However, the above are only examples of the present invention. When the scope of implementation of the present invention cannot be limited by this, any simple equivalent changes and modifications made according to the scope of the patent application and the contents of the patent specification of the present invention are still Within the scope of the invention patent.
2‧‧‧生物用水單元 2‧‧‧ biological water unit
50‧‧‧容置空間 50‧‧‧ accommodation space
201‧‧‧進水口 201‧‧‧ Inlet
501‧‧‧進水口 501‧‧‧ water inlet
202‧‧‧出水口 202‧‧‧ Outlet
502‧‧‧出水口 502‧‧‧outlet
3‧‧‧脫氣單元 3‧‧‧ degassing unit
51‧‧‧載座 51‧‧‧ carrier
30‧‧‧容置空間 30‧‧‧ accommodation space
52‧‧‧多孔性材料 52‧‧‧ Porous material
301‧‧‧進水口 301‧‧‧ water inlet
521‧‧‧活性碳 521‧‧‧ activated carbon
302‧‧‧出水口 302‧‧‧outlet
522‧‧‧中空絲膜 522‧‧‧ hollow fiber membrane
31‧‧‧載座 31‧‧‧ carrier
53‧‧‧奈米銀 53‧‧‧Nano silver
32‧‧‧脫氣構件 32‧‧‧ degassing component
6‧‧‧紫外光殺菌單元 6‧‧‧UV sterilization unit
4‧‧‧濾心、第一濾心 4‧‧‧ filter, first filter
60‧‧‧容置空間 60‧‧‧accommodation space
40‧‧‧容置空間 40‧‧‧accommodation space
601‧‧‧進水口 601‧‧‧ water inlet
401‧‧‧進水口 401‧‧‧ water inlet
602‧‧‧出水口 602‧‧‧outlet
402‧‧‧出水口 402‧‧‧outlet
61‧‧‧載座 61‧‧‧ carrier
41‧‧‧載座 41‧‧‧ carrier
62‧‧‧紫外光燈組 62‧‧‧UV light set
411‧‧‧第一部件 411‧‧‧The first part
7‧‧‧管路單元 7‧‧‧Piping unit
4111‧‧‧接口段 4111‧‧‧Interface section
71‧‧‧進水管路 71‧‧‧ water inlet pipe
4112‧‧‧外螺紋 4112‧‧‧ Male thread
72‧‧‧輸送管路 72‧‧‧conveying pipeline
4113‧‧‧環槽 4113‧‧‧Ring groove
73‧‧‧出水管路 73‧‧‧outlet pipe
412‧‧‧第二部件 412‧‧‧Second Part
74‧‧‧排出單元 74‧‧‧Discharge unit
4121‧‧‧接口段 4121‧‧‧Interface section
75‧‧‧總溶解固體量量測單元 75‧‧‧Total dissolved solids measurement unit
4122‧‧‧外螺紋 4122‧‧‧External thread
76‧‧‧流量計 76‧‧‧Flowmeter
4123‧‧‧環槽 4123‧‧‧Ring groove
42‧‧‧濾材 42‧‧‧ Filter media
421‧‧‧載體 421‧‧‧ carrier
4210‧‧‧微孔洞 4210‧‧‧Micropore
4211‧‧‧活性碳 4211‧‧‧Activated carbon
4212‧‧‧中空絲膜 4212‧‧‧ hollow fiber membrane
422‧‧‧活性矽材 422‧‧‧active silicon
9‧‧‧生物用水 9‧‧‧ biological water
4220‧‧‧奈米矽漿料 4220‧‧‧Nano silicon paste
4222‧‧‧酒精 4222 ‧ ‧ alcohol
423‧‧‧黏結材 423‧‧‧bonding material
43‧‧‧拆卸式開關構件 43‧‧‧ Removable switch components
431‧‧‧貫孔螺帽 431‧‧‧Throughnut
4310‧‧‧內螺紋 4310‧‧‧Internal thread
92‧‧‧生物用水組成 Composition of 92‧‧‧ biological water
4311‧‧‧上環槽 4311‧‧‧ Upper ring groove
921‧‧‧氫氣氣泡 921‧‧‧ Hydrogen Bubble
4312‧‧‧下環槽 4312‧‧‧Lower ring groove
432‧‧‧外止漏環 432‧‧‧External leakage ring
F‧‧‧流水方向 F‧‧‧flow direction
44‧‧‧內止漏環 44‧‧‧Inner leakage ring
5‧‧‧第二濾心 5‧‧‧Second Filter
本發明的其他的特徵及功效,將於參照圖式的實施方式中清楚地呈現,其中:Other features and effects of the present invention will be clearly presented in the embodiments with reference to the drawings, wherein:
圖1是一局部剖視示意圖,說明本發明濾心的一第一實施例; 1 is a schematic partial cross-sectional view illustrating a first embodiment of the filter core of the present invention;
圖2是一正視示意圖,說明本發明該第一實施例之濾心的一第一種濾材; 2 is a schematic front view illustrating a first filter medium of the filter core of the first embodiment of the present invention;
圖3是一正視示意圖,說明本發明該第一實施例之濾心之第一種濾材的製法; 3 is a schematic front view illustrating a method for manufacturing a first filter medium of the filter core according to the first embodiment of the present invention;
圖4是一局部剖視示意圖,說明本發明該第一實施例之濾心的一第二種濾材; 4 is a schematic partial cross-sectional view illustrating a second filter medium of the filter core according to the first embodiment of the present invention;
圖5是一正視示意圖,說明本發明該第一實施例之濾心的一第三種濾材及其製法; 5 is a schematic front view illustrating a third filter material and a manufacturing method thereof for the filter core of the first embodiment of the present invention;
圖6是一局部剖視示意圖,說明本發明濾心的一第二實施例; 6 is a schematic partial cross-sectional view illustrating a second embodiment of the filter core of the present invention;
圖7是一局部剖視示意圖,說明本發明濾心的一第三實施例於使用前的狀態; 7 is a schematic partial sectional view illustrating a state of a third embodiment of the filter core of the present invention before use;
圖8是一局部剖視示意圖,說明本發明該第三實施例之濾心於使用後的狀態; 8 is a schematic partial cross-sectional view illustrating a state of the filter core after use according to the third embodiment of the present invention;
圖9是一局部剖視示意圖,說明本發明濾心的一第四實施例; 9 is a schematic partial cross-sectional view illustrating a fourth embodiment of the filter core of the present invention;
圖10是一局部剖視示意圖,說明本發明濾心的一第五實施例; 10 is a schematic partial cross-sectional view illustrating a fifth embodiment of the filter core of the present invention;
圖11是一局部剖視示意圖,說明本發明濾心的一第六實施例; 11 is a schematic partial cross-sectional view illustrating a sixth embodiment of the filter core of the present invention;
圖12是一局部剖視示意圖,說明本發明淨水系統的一第一實施例; 12 is a schematic partial cross-sectional view illustrating a first embodiment of the water purification system of the present invention;
圖13是一局部剖視圖,說明經本發明該第一實施例之淨水系統所製得的生物用水組成; 13 is a partial cross-sectional view illustrating the composition of biological water produced by the water purification system according to the first embodiment of the present invention;
圖14是一局部剖視示意圖,說明本發明淨水系統的一第二實施例; 14 is a schematic partial cross-sectional view illustrating a second embodiment of the water purification system of the present invention;
圖15是圖14的一局部放大示意圖,說明本發明該第二實施例的淨水系統的一第二濾心的細部結構; 15 is a partially enlarged schematic view of FIG. 14, illustrating a detailed structure of a second filter element of the water purification system according to the second embodiment of the present invention;
圖16是一局部剖視示意圖,說明本發明淨水系統的一第三實施例; 16 is a schematic partial cross-sectional view illustrating a third embodiment of the water purification system of the present invention;
圖17是一氧化還原電位(oxidation-reduction potential;簡稱ORP)對時間曲線圖,說明經本發明該第一實施例之淨水系統所製得之生物用水組成在不同填充率之條件下的穩定性;及 FIG. 17 is a graph of oxidation-reduction potential (ORP) versus time, illustrating the stability of the biological water composition produced by the water purification system according to the first embodiment of the present invention under different filling rates ;and
圖18是一灰階影像,說明經本發明生物用水組成之一具體例2之減緩氧化速度的測試結果。 FIG. 18 is a grayscale image illustrating the test result of slowing down the oxidation rate according to the specific example 2 of the biological water composition of the present invention.
Claims (31)
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| TW108113205A TWI720459B (en) | 2018-04-03 | 2018-04-03 | Filter and water purification system using the filter |
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| TW108113205A TWI720459B (en) | 2018-04-03 | 2018-04-03 | Filter and water purification system using the filter |
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| TW201942066A true TW201942066A (en) | 2019-11-01 |
| TWI720459B TWI720459B (en) | 2021-03-01 |
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| CN202478694U (en) * | 2011-07-20 | 2012-10-10 | 林祥利 | Installation structure of filter element and water purifier including the same |
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