TW201934111A - 油中水型乳化化妝料 - Google Patents
油中水型乳化化妝料 Download PDFInfo
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- TW201934111A TW201934111A TW107130099A TW107130099A TW201934111A TW 201934111 A TW201934111 A TW 201934111A TW 107130099 A TW107130099 A TW 107130099A TW 107130099 A TW107130099 A TW 107130099A TW 201934111 A TW201934111 A TW 201934111A
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Abstract
本發明之目的在於提供一種油中水型乳化化妝料，其擁有優異之整髮效果，且對所塗抹之組織賦予滋潤之功能較高，具有與髮霜或髮蠟不同之乾爽之指感，不會使手或頭髮產生黏膩感。本發明之油中水型乳化化妝料之特徵在於：含有(A)交聯型矽氧烷彈性體、(B)固態油分、(C)液狀油分及(D)55質量%以上之水，且(B)成分相對於(C)成分之比率((B)/(C))為0.25～1.5。
Description
本發明係關於一種油中水型乳化化妝料。更詳細而言，關於一種固態或半固態之化妝料，其尤其用於毛髮等角質纖維時發揮優異之整髮效果，滋潤且不產生黏膩感。
一般而言，整髮劑中調配有蠟(wax)、蠟等油分或整髮樹脂，以實現良好之髮型之定型力或保持力。另一方面，近年來，大眾趨於喜好光亮感或光澤感較少、質感自然之髮型，又，關於使用性亦追求無黏膩感者。
例如，專利文獻1中揭示有一種整髮用化妝料，其藉由向蠟類及液體油分中調配水溶性高分子作為整髮樹脂而具有自然之整髮性，且黏膩感較少。 又，專利文獻2中揭示有一種乳化型毛髮化妝料，其藉由調配包括來源於植物之半固態油分、堪地里拉蠟、液狀油分、界面活性劑及高級脂肪酸之複合體，而易於整髮，且油膩感或黏膩感較少。
然而，調配較多蠟類或整髮樹脂雖然使整髮效果得到提高，但會產生油膩感或發硬感，無法充分滿足追求自然造型之消費者之需求。又，雖一定程度上減輕了整髮劑之黏膩感，但實際上大部分整髮劑於使用時需要消費者在使用後擦拭沖洗手上殘留之整髮劑等，業界尚未實現無黏膩感殘留之整髮劑。 [先前技術文獻] [專利文獻]
專利文獻1：日本專利特開平10-45546號公報 專利文獻2：日本專利特開2009-209103號公報
[發明所欲解決之問題]
本發明之目的在於提供一種油中水型乳化化妝料，其擁有優異之整髮效果，且滋潤所塗抹之組織之功能較高，具有與髮霜或髮蠟不同之乾爽之指感，不會使手或頭髮產生黏膩感。 [解決問題之技術手段]
本發明者等人為了解決上述課題，經過銳意研究，結果發現，藉由含有交聯型矽氧烷彈性體、固態油分、液狀油分及水，並將固態油分與液狀油分調整至特定比率，而具有整髮效果，且最大限度地抑制黏膩感，具有與髮霜或髮蠟不同之乾爽之指感，從而完成本發明。
即，本發明提供一種油中水型乳化化妝料，其含有： (A)交聯型矽氧烷彈性體、 (B)固態油分、 (C)液狀油分、及 (D)55質量%以上之水，且 (B)成分相對於(C)成分之比率((B)/(C))為0.25～1.5。進而，本發明之化妝料較佳為固態或半固態，不為棒狀。 [發明之效果]
本發明藉由採用上述構成，可獲得具有滋潤所塗抹之組織之功能、無黏膩感、觸感乾爽之化妝料。尤其於塗抹於毛髮等角質組織之情形時，可發揮良好地整飾髮梢或鬢角等、撫平頭髮表面之整髮效果，賦予毛髮等自然之光澤。
如上所述，本發明之油中水型乳化化妝料之特徵在於，含有(A)交聯型矽氧烷彈性體、(B)固態油分、(C)液狀油分及(D)水。以下，詳述構成本發明之化妝料之各成分。
＜(A)交聯型矽氧烷彈性體＞ 調配於本發明之油中水型乳化化妝料之(A)交聯型矽氧烷彈性體(以下，有時簡稱為「(A)成分」)係使聚二甲基矽氧烷三維交聯而成之矽氧烷彈性體(聚矽氧彈性體)，包括乳化性及非乳化性者。
作為乳化性交聯型矽氧烷彈性體，未特別限定，可列舉：交聯型聚氧乙烯甲基聚矽氧烷、含有烷基之交聯型聚氧乙烯甲基聚矽氧烷、交聯型聚甘油改性聚矽氧、含有烷基之交聯型聚甘油改性聚矽氧等。該等乳化性交聯型矽氧烷彈性體可使用以膨潤於聚矽氧油、礦物油、三異辛酸甘油酯、角鯊烷等各種油分中之膨潤物之形態市售者。作為具體例，可列舉以下者。
作為聚氧乙烯甲基聚矽氧烷交聯聚合物之膨潤物，可列舉：KSG-210(((PEG-10/15)/矽靈)交聯聚合物，於矽靈之混合物中交聯物為20～30%)(信越化學工業股份有限公司製造)、9011聚矽氧彈性體摻合物((PEG-12/矽靈)交聯聚合物、環甲矽脂之混合物)(東麗道康寧股份有限公司製造)等。
作為含有烷基之聚氧乙烯甲基聚矽氧烷交聯聚合物之膨潤物，可列舉：KSG-310((PEG-15/月桂基矽靈)交聯聚合物，於礦物油之混合物中交聯物為25～35%)、KSG-320((PEG-15/月桂基矽靈)交聯聚合物，於異十二烷之混合物中交聯物為20～30%)、KSG-330((PEG-15/月桂基矽靈)交聯聚合物，於三異辛酸甘油酯之混合物中交聯物為15～25%)、KSG-340((PEG-15/月桂基矽靈)交聯聚合物、(PEG-10/月桂基矽靈)交聯聚合物，於角鯊烷之混合物中交聯物為25～35%)(以上由信越化學工業股份有限公司製造)等。
作為聚甘油改性聚矽氧交聯聚合物之膨潤物，可列舉：KSG-710((矽靈/聚甘油-3)交聯聚合物，於矽靈之混合物中交聯物為20～30%(信越化學工業股份有限公司製造)等。
作為含有烷基之聚甘油改性聚矽氧交聯聚合物之膨潤物，可列舉：KSG-810((月桂基矽靈/聚甘油3)交聯聚合物，於礦物油之混合物中交聯物為25～35%)、KSG-820((月桂基矽靈/聚甘油3)交聯聚合物，於異十二烷之混合物中交聯物為20～30%)、KSG-830((月桂基矽靈/聚甘油3)交聯聚合物，於三異辛酸甘油酯之混合物中交聯物為15～25%)、KSG-840((月桂基矽靈/聚甘油3)交聯聚合物，於角鯊烷之混合物中交聯物為25～35%)(以上由信越化學工業股份有限公司製造)等。
作為非乳化性交聯型矽氧烷彈性體，未特別限定，可列舉：甲基聚矽氧烷交聯聚合物、甲基苯基聚矽氧烷交聯聚合物、乙烯基矽靈/月桂基矽靈交聯聚合物、月桂基聚二甲基矽烷氧基乙基矽靈/雙乙烯基矽靈交聯聚合物、烷基(C30-45)鯨蠟硬脂基矽靈交聯聚合物、鯨蠟硬脂基矽靈交聯聚合物等。該等非乳化性交聯型矽氧烷彈性體可使用以於聚矽氧油、礦物油、三異辛酸甘油酯、角鯊烷等各種油分中膨潤之膨潤物之形態市售者。作為具體例，可列舉以下者。
作為甲基聚矽氧烷交聯聚合物之膨潤物，可列舉：9040聚矽氧彈性體摻合物(矽靈交聯聚合物，於環五矽氧烷之混合物中交聯物為12%)、9041聚矽氧彈性體摻合物(矽靈交聯聚合物，於矽靈5 mPa・s之混合物中交聯物為16%)、9045聚矽氧彈性體摻合物(矽靈交聯聚合物，於環五矽氧烷之混合物中交聯物為12.5%)、EL-8040ID聚矽氧有機摻合物(矽靈交聯聚合物，於異十二烷之混合物中交聯物為18%)(以上由東麗道康寧股份有限公司製造)等矽靈交聯聚合物之膨潤物，或KSG-15((矽靈/乙烯基矽靈)交聯聚合物，於環五矽氧烷之混合物中交聯物為4～10%)、KSG-16((矽靈/乙烯基矽靈)交聯聚合物，於矽靈6 mPa・s之混合物中交聯物為20～30%)、KSG-1610((矽靈/乙烯基矽靈)交聯聚合物，於甲基三甲矽油之混合物中交聯物為15～20%)(以上由信越化學工業股份有限公司製造)等矽靈/乙烯基矽靈交聯聚合物之膨潤物等。
作為甲基苯基聚矽氧烷交聯聚合物之膨潤物，可列舉：KSG-18A((矽靈/苯基乙烯基矽靈)交聯聚合物，於二苯基矽烷氧基苯基三甲矽油之混合物中交聯物為10～20%)(信越化學工業股份有限公司製造)等。
作為乙烯基矽靈/月桂基矽靈交聯聚合物之膨潤物，可列舉：KSG-41A((乙烯基矽靈/月桂基矽靈)交聯聚合物，於礦物油之混合物中交聯物為20～30%)、KSG-42A((乙烯基矽靈/月桂基矽靈)交聯聚合物，於異十二烷之混合物中交聯物為15～25%)、KSG-43((乙烯基矽靈/月桂基矽靈)交聯聚合物，於三異辛酸甘油酯之混合物中交聯物為25～35%)、KSG-44((乙烯基矽靈/月桂基矽靈)交聯聚合物，於角鯊烷之混合物中交聯物為25～35%)(以上由信越化學工業股份有限公司製造)等。
作為月桂基聚二甲基矽烷氧基乙基矽靈/雙乙烯基矽靈交聯聚合物之膨潤物，可列舉：KSG-042Z((月桂基聚二甲基矽烷氧基乙基矽靈/雙乙烯基矽靈)交聯聚合物，於異十二烷之混合物中交聯物約為20%)、KSG-045Z((月桂基聚二甲基矽烷氧基乙基矽靈/雙乙烯基矽靈)交聯聚合物，於環五矽氧烷之混合物中交聯物約為20%)(以上由信越化學工業股份有限公司製造)等。
作為烷基(C30-45)鯨蠟硬脂基矽靈交聯聚合物之膨潤物，可列舉：VELVESIL 125(烷基(C30-45)鯨蠟硬脂基矽靈交聯聚合物，於環五矽氧烷之混合物中交聯物約為12.5%)、VELVESIL 034(烷基(C30-45)鯨蠟硬脂基矽靈交聯聚合物，於辛甲基聚矽氧烷之混合物中交聯物約為16%)(以上由邁圖高新材料公司製造)等。
作為鯨蠟硬脂基矽靈交聯聚合物之膨潤物，可列舉：VELVESIL DM(鯨蠟硬脂基矽靈交聯聚合物，於矽靈5 mPa・s之混合物中交聯物約為17%)(邁圖高新材料公司製造)等。
(A)成分之調配量相對於油中水型乳化化妝料總量，為0.01～10質量%，較佳為0.1～8質量%，更佳為0.4～5質量%，進而較佳為0.4～3質量%。若(A)成分之調配量未達0.01質量%則產生黏膩感，於塗抹於毛髮之情形時產生不自然之光澤，若調配超過10質量%則使用感油膩，整髮時之定型力降低，就該等方面而言欠佳。
作為本發明之(A)成分，可使用選自上述乳化性交聯型矽氧烷彈性體及非乳化性交聯型矽氧烷彈性體中之一種或組合兩種以上使用。又，為了提高乾爽之使用感，較佳為將選自乳化性交聯型矽氧烷彈性體中之一種或兩種以上與選自非乳化性交聯型矽氧烷彈性體中之一種或兩種以上組合使用。
＜(B)固態油分＞ 調配於本發明之油中水型乳化化妝料之(B)固態油分(以下，有時簡稱為「(B)成分」)係通常用於化妝料之常溫(25℃)下為固態之油分，作為具體例，可列舉：天然來源及人工合成之油脂、烴油、高級脂肪酸、高級醇、酯油等。
作為油脂，可列舉：可可脂、椰子油、氫化椰子油、棕櫚油、棕櫚仁油、木蠟核油、木蠟、氫化蓖麻油等。
作為烴油，可列舉：地蠟(ozokerite)、白地蠟(ceresin)、聚乙烯蠟、微晶蠟、石蠟等。
作為高級脂肪酸，可列舉：月桂酸、肉豆蔻酸、棕櫚酸、硬脂酸、山萮酸、12-羥基硬脂酸、十一碳烯酸等。
作為高級醇，例如可列舉：直鏈醇(例如月桂醇、鯨蠟醇、硬脂醇、山萮醇、肉豆蔻醇、鯨蠟硬脂醇等)；支鏈醇(例如單硬脂甘油醚(鯊肝醇))等。
作為酯油，可列舉：肉豆蔻酸肉豆蔻酯、肉豆蔻酸鯨蠟酯、硬脂酸硬脂酯、硬脂酸鯨蠟酯、棕櫚酸鯨蠟酯、膽固醇硬脂酸酯、膽固醇油酸酯、棕櫚酸糊精、硬脂酸菊糖、氫化荷荷芭油等。
上述固態油分中，就無黏膩感或易用手延展之觀點而言，較佳為選自烴油及酯油中之一種或兩種以上。
於本發明之油中水型乳化化妝料中，可調配半固態油分作為上述固態油分。 作為用於本發明之半固態油分，未特別限定，可列舉：凡士林、三羊毛脂脂肪酸甘油、軟質羊毛脂脂肪酸、支鏈或羥基化膽固醇脂肪酸酯、二季戊四醇脂肪酸酯(二季戊四醇六羥基硬脂酸酯等)、異硬脂酸氫化蓖麻油、單羥基硬脂酸氫化蓖麻油、三(辛酸/癸酸/肉豆蔻酸/硬脂酸)甘油酯、乳酸肉豆蔻酯、二聚亞油酸氫化蓖麻油、二聚亞油酸(植物固醇酯/山萮酯)、二聚亞油酸(植物固醇酯/異硬脂酯/鯨蠟酯/硬脂酯/山萮酯)、油酸植物固醇酯、四(山萮酸/苯甲酸/乙基己酸)季戊四醇酯、六羥基硬脂酸二季戊四醇酯等。於本發明之化妝料中，就提高整髮效果之觀點而言，較佳為於固態油分中調配凡士林。
(B)成分之調配量相對於油中水型乳化化妝料總量，為20質量%以下，較佳為1.0～20質量%。若(B)成分之調配量未達1.0質量%則無法獲得作為化妝料所需之足夠之硬度，若調配超過20質量%則延展性變差，就該等方面而言欠佳。
＜(C)液狀油分＞ 調配於本發明之油中水型乳化化妝料之(C)液狀油分(以下，有時簡稱為「(C)成分」)係通常用於化妝料之常溫(25℃)下為液狀之油分，作為具體例，可列舉：天然來源及人工合成之油脂、脂肪酸、酯油、烴油、高級醇、聚矽氧油等。
作為油脂，可列舉：亞麻籽油、山茶油、澳洲胡桃油、玉米油、橄欖油、萼梨油、山茶花油、蓖麻油、紅花油、杏仁油、錫蘭肉桂油、荷荷芭油、葡萄籽油、葵花籽油、扁桃仁油、菜籽油、芝麻油、小麥胚芽油、米胚芽油、米糠油、棉籽油、大豆油、花生油、茶籽油、月見草油等。
作為脂肪酸，可列舉：庚酸、辛酸、壬酸、癸酸、十五酸、十七酸、十九酸、異硬脂酸、油酸、亞麻油酸、次亞麻油酸、花生四烯酸等。
作為酯油，可列舉：四辛酸季戊四醇酯、辛酸鯨蠟酯、月桂酸己酯、肉豆蔻酸異丙酯、肉豆蔻酸辛基十二烷基酯、棕櫚酸辛酯、異硬脂酸異丙酯、異棕櫚酸辛酯、油酸異癸酯、乙基己酸鯨蠟酯、三(2-乙基己酸)甘油酯等。
作為烴油，可列舉：液態石蠟、角鯊烷、角鯊烯、石蠟、異構石蠟、辛烷、癸烷、十二烷、異十二烷、十六烷、異十六烷等。
作為高級醇，可列舉：辛醇、異硬脂醇、油醇等。
作為聚矽氧油，可列舉：二甲基聚矽氧烷、甲基苯基聚矽氧烷、甲基氫聚矽氧烷等鏈狀聚矽氧，八甲基環四矽氧烷、十甲基環五矽氧烷、十二甲基環六矽氧烷、二苯基矽烷氧基苯基三甲矽油等環狀聚矽氧等。
(C)成分之調配量相對於油中水型乳化化妝料總量，為1.0～40質量%，較佳為3.0～30質量%，更佳為5.0～25質量%。若(C)成分之調配量未達1.0質量%則塗抹時之延展性變差，若調配超過40質量%則產生黏膩感，於塗抹於毛髮之情形時產生不自然之光澤，就該等方面而言欠佳。
於本發明之油中水型乳化化妝料中，為了抑制黏膩感且提昇延展性，較佳為將(B)固態油分與(C)液狀油分之調配比例((B)/(C))以質量比設為0.25～1.5，進而更佳為設為0.5～1.2。增大(B)成分之調配比例則產生黏膩感，延展性變差。又，增大(C)成分之調配比例則整髮效果降低。
本發明之油中水型乳化化妝料進而以(D)水(以下，有時簡稱為「(D)成分」)為必須成分。 (D)成分之調配量相對於油中水型乳化化妝料總量，為55質量%以上。若水分含量未達55質量%，則有產生黏膩感，毛髮等之整髮效果變差之趨勢。
本發明之化妝料除上述必須成分(A)～(D)以外，亦可於無損發明之效果之範圍內含有能夠調配於化妝料之其他任意成分。作為任意成分，可列舉以下者。
藉由調配(E)界面活性劑，可提高乳化穩定性。調配於本發明之化妝料之(E)界面活性劑係通常用於製造油中水型乳化物之界面活性劑，未特別限定，可列舉：HLB(Hydrophile Lipophile Balance，親水-親油平衡值)為8以下之非離子性界面活性劑或聚矽氧系界面活性劑等。其中，就無黏膩感或黏膩感減輕之觀點而言，較佳為使用聚矽氧系界面活性劑。聚矽氧系界面活性劑係指於聚矽氧骨架導入聚氧伸烷基結構之聚醚改性聚矽氧中之非交聯型者。
作為聚矽氧系界面活性劑之具體例，可列舉：PEG-10矽靈、PEG-9聚二甲基矽烷氧基乙基矽靈、月桂基PEG-9聚二甲基矽烷氧基乙基矽靈等聚醚改性聚矽氧。可調配該等1種或混合調配2種以上。
又，聚矽氧系界面活性劑可以包含該界面活性劑與溶劑之聚矽氧凝膠之狀態進行調配，可使用市售之聚矽氧凝膠。例如可列舉：KF-6017、KF-6028、KF-6038(以上由信越化學工業股份有限公司製造)等。再者，該等聚矽氧凝膠所包含之作為溶劑之油分亦屬於上述成分(C)，其調配量當然納入成分(C)之調配量。
本發明之化妝料中之(E)界面活性劑之調配量通常為0.05～20質量%，較佳為0.1～10質量%，更佳為0.5～5質量%。
藉由調配(F)保濕劑，可提高使用後之組織(毛髮或皮膚等)之保濕力。 作為保濕劑之具體例，可列舉：丙二醇、二丙二醇、1,3-丁二醇、1,4-丁二醇、二乙二醇、三乙二醇、聚乙二醇等二醇類；甘油、雙甘油、聚甘油等甘油類；山梨糖醇、甘露醇、麥芽糖醇、木糖醇、赤蘚糖醇等糖醇類；果糖、葡萄糖、半乳糖、麥芽糖、乳糖、海藻糖等糖類。
於向本發明之化妝料調配保濕劑之情形時，其調配量通常為0.1～50質量%，較佳為1～30質量%，更佳為5～20質量%。
作為除上述以外之任意成分，例如可列舉：增黏劑、腦醯胺類、維生素類、紫外線吸收劑、螯合劑、殺菌劑、防腐劑、植物萃取液、胺基酸、各種藥劑、乙醇等低級醇類等。
本發明之化妝料可根據先前所用之方法製造。簡言之，可藉由視需要一面分別加熱油性成分與水性成分一面混合，使水相於油相中乳化，其次將所獲得之乳化物填充於容器內緩慢冷卻而製造。
本發明之化妝料含有大量之水，故而可滋潤所塗抹之組織(毛髮或皮膚等)。又，藉由將固態油分與液狀油分之調配量調整至特定比率而具有特有硬度，故而無黏膩感，塗抹於皮膚上時乳化崩解而內相之水溢出，藉此可獲得水潤之感覺。進而，藉由調配矽氧烷彈性體可獲得乾爽之感覺。
本發明之化妝料之硬度較佳為50～500，更佳為75～450，進而較佳為100～400。此處，「硬度」係使用流變計(SUN公司製造之COMPAC100-II)對於製造次日在25℃之恆溫槽中放置3小時後之化妝料以荷重200 g、感壓軸8、針入度10.0 mm、針入速度300 mm/min進行測定時之值。
本發明之化妝料例如為收容於廣口容器等中之固態或半固態之化妝料，本發明之化妝料不包括棒狀化妝料。又，本發明之化妝料較佳為取至手指等進行塗抹而使用。再者，將化妝料取至手指時，可直接用手指或使用刮片等工具自收容化妝料之容器取出化妝料。
本發明之化妝料亦稱為乳霜(balm)基劑，可用於全身護理，但由於延展性較佳，具有整髮效果，故而較佳為用於角質組織護理及整髮。又，本發明之化妝料無黏膩感，故而用作整髮用化妝料亦無需於使用後擦拭沖洗手指上殘留之化妝料。 [實施例]
以下列舉實施例對本發明進行詳述，但本發明不限定於該等實施例。再者，只要無特別記載，調配量表示質量%。
一面分別加熱各例之組成所包含之油性成分與水性成分一面混合，使水相於油相中乳化，其次將所獲得之乳化物填充於容器內緩慢冷卻，藉此製備具有下述表1所示之組成之油中水型乳化化妝料。對所調整之化妝料進行以下之試驗。
1.效果試驗 由10名專業官能檢查員進行實際使用性試驗。使用性項目包括手或頭髮有無黏膩感、用手延展之難易度、整髮力(髮型製作難易度)、定型力(髮型保持力)，對各個項目基於下述基準進行評價。結果示於表中。 ＜評價基準＞ A：9名以上官能檢查員回答優異。 B：7名或8名官能檢查員回答優異。 C：3名～6名官能檢查員回答優異。 D：2名以下官能檢查員回答優異。
[表1]
於水分之調配量未達55質量%之情形(比較例1、比較例4)時，有產生黏膩感，整髮力(髮型製作難易度)及定型力(髮型保持力)較差之趨勢。於增大固態油分之調配比例之情形((B)成分/(C)成分＝2.0，比較例2)時，定型力良好，但整髮力較差，不易延展，產生黏膩感。另一方面，於減小固態油分之調配比例之情形((B)成分/(C)成分＝0.21，比較例3)時，易於延展，無黏膩感，但整髮力及定型力均較差。
相對於上述比較例，於調配本發明之必須成分、並使固態油分與液狀油分之調配比例為0.25～1.5之情形時，均可獲得具有充分之整髮力，同時於延展難易度或黏膩感之方面亦良好之化妝料。
2.塗抹後乾燥時之黏膩感(滾動阻力) 其次，加熱(2)～(10)使之熔解成為油相，向(11)添加(12)、(13)及(15)，攪拌溶解後添加(1)並使之均勻分散成為水相，向水相添加油相並乳化後添加(14)、(16)，藉此製備含有以下所示之組成之髮蠟。以所製備之髮蠟為比較例5，與上述實施例10一同藉由下述方法測定滾動阻力，比較黏膩感之評價。
比較例5(髮蠟) 質量% (1)高嶺土 2.0 (2)苯基甲基聚矽氧烷 5.0 (3)胺端矽靈 1.0 (4)堪地里拉蠟 18.0 (5)蓖麻醇酸植物固醇酯 5.0 (6)羥基硬脂酸氫化蓖麻油 3.0 (7)油酸癸酯 5.0 (8)甲基環聚矽氧烷 5.0 (9)八甲基三矽氧烷 3.0 (10)異硬脂酸 3.0 (11)離子交換水 餘量 (12)1,3-丁二醇 5.0 (13)2-十一烷基-N,N,N-(羥乙基羧甲基)-2-咪唑啉鈉(實際量30%) 8.0 (14)三仙膠 1.0 (15)EDTA-2Na・2H2
O 0.05 (16)苯氧基乙醇 0.5
對上述實施例10及比較例5之試樣，使用日本專利第3945729號中記載之裝置，測定試樣與探針之間之滾動阻力，藉此測定乾燥時之黏膩感。測定條件為滑動速度1.2 cm/s、滑動行程20 mm、樣品量20 μL、平台溫度32℃、室溫25℃、相對濕度50%。結果示於圖1及圖2。
由圖1之結果可知，與比較例5之試樣相比，實施例10之試樣滾動阻力較低，乾燥時之黏膩感較少。再者，圖1之縱座標係滾動阻力，越往高處延伸表示滾動阻力越大。 又，由圖2之結果可知，隨著滑動循環次數之增加，比較例5之試樣黏膩感變強，但實施例10之試樣黏膩感之上升較平緩，與比較例5相比黏膩感較少。此表明實施例10之試樣不易隨著乾燥而產生黏膩感。
圖1係顯示滾動阻力測定之結果之圖表。縱座標係滾動阻力之程度，越往高處延伸表示滾動阻力越大。 圖2係將滾動阻力之程度與滑動循環次數之增加一同顯示之圖表。縱座標係滾動阻力之程度，越往高處延伸表示滾動阻力越大。
Claims (6)
- 一種油中水型乳化化妝料，其含有： (A)交聯型矽氧烷彈性體、 (B)固態油分、 (C)液狀油分、及 (D)55質量%以上之水，且 (B)成分相對於(C)成分之調配比例((B)/(C))為0.25～1.5。
- 如請求項1之油中水型乳化化妝料，其中(B)成分包括半固態油分。
- 如請求項1或2之油中水型乳化化妝料，其中(B)固態油分之調配量為20質量%以下。
- 如請求項1至3中任一項之油中水型乳化化妝料，其中(B)成分係選自烴油及酯油中之一種或兩種以上。
- 如請求項1至4中任一項之油中水型乳化化妝料，其為固態或半固態(但，棒狀除外)。
- 如請求項1至5中任一項之油中水型乳化化妝料，其用於角質組織護理製品。
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| EP0545002A1 (en) * | 1991-11-21 | 1993-06-09 | Kose Corporation | Silicone polymer, paste-like composition and water-in-oil type cosmetic composition comprising the same |
| JP3208164B2 (ja) | 1991-11-21 | 2001-09-10 | 株式会社コーセー | 油中水型メークアップ化粧料 |
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