TW201924658A - Water-washable water-repellent cosmetic composition capable of removing cosmetic by simply rubbing with water without using special organic cleansing oil - Google Patents

Abstract

The present invention provides a water-washing water-repellent makeup composition comprising: at least one emulsifier having an HLB value of 13 or less, wherein the weight percentage of the emulsifier having an HLB value of 13 or less is 0.1 to 13%; at least one solid fat Wherein the solid fat is 1% to 18% by weight; at least one thickener, wherein the thickener is 0% to 18% by weight; at least one powder, wherein the powder is 0.5% to 15% by weight; And at least one liquid fat, wherein the liquid fat is from 2 to 80% by weight. The color cosmetic composition of the present invention has water repellency, and the effect of removing the makeup can be achieved by simply using a water sputum without a special organic cleansing oil.

Description

Water-washing and water-repellent makeup composition

The present invention relates to a water-washable water-repellent makeup composition, and more particularly to a makeup composition for an emulsifier having an HLB value of 13 or less.

In recent years, with the improvement of the quality of life, women's concept of using cosmetics has become more and more popular. For most women, using cosmetics can make them look healthier and younger. For example: through the use of the foundation, it can cover up the spots and color blocks of the concealer, and make the skin show the smooth, flawless ideal state that the girl has. The use of eye shadows, eyeliners, mascaras and eyebrows can make your eyes look bigger, younger and more pure. Blush is the effect of making the face appear violent when young people are excited.

In order to avoid the makeup removal caused by sweat and tears caused by the heat of summer, female consumers can choose waterproof cosmetics for the purchase of cosmetic products; however, these waterproof cosmetics with waterproof effect are sold on the market. There is a problem that it is difficult to remove, and it is necessary to use a special cleansing oil such as oily or organic solvent as a remover for the waterproof cosmetic to achieve the removal effect, and such cosmetic remover may have eyes on the use. Causes irritation, or a layer of grease on the skin around the eyes, and such cosmetic removers will also increase microbial contamination.

Therefore, there is a need to provide a water-repellent and water-repellent makeup composition which is water-repellent and can be easily removed without relying on special oils such as oil or organic solvents. It can solve the aforementioned problems.

An object of the present invention is to provide a water-washing water-repellent makeup composition comprising: at least one emulsifier having an HLB value of 13 or less, wherein the weight percentage of the emulsifier having an HLB value of 13 or less is 0.1 to 13%; At least one solid fat, wherein the solid fat is 1% to 18% by weight; at least one thickener, wherein the thickener is 0% to 18% by weight; at least one powder, wherein the powder is 0.5% by weight ~15%; and at least one liquid fat, wherein the liquid fat is from 2 to 80% by weight.

Another object of the present invention is to provide a method for preparing a water-washing anti-splashing watercolor makeup composition, which comprises the following steps: Step 1: emulsifier, solid oil, thickener and liquid oil with an HLB value of 13 or less Adding to the stirring pot, stirring and mixing to form an intermediate product A, and heating to melt at a high temperature of 75-85 ° C, wherein the ratio is 0.1 to 13% by weight of the emulsifier having an HLB value of 13 or less, and 1 to 18% by weight of the solid fat. , thickener 0~18%wt and liquid fat 2~80%wt; Step 2: After the intermediate product A is completely melted, add powder, pigment and preservative to form another intermediate product B; Step 3: Stir well To the pigment dispersion; and step 4: the intermediate product B in which the pigment is uniformly dispersed is subjected to a mold.

A further object of the present invention is to provide a water-washable water-repellent makeup composition comprising: an emulsifier having an HLB value of 13 or less, wherein the emulsifier having an HLB value of 13 or less is 0.1 to 13% by weight of the laurel Laureth-4; at least one solid fat comprising Candellila wax, Ceresin wax, Bees wax and Vaseline. Wherein the weight percentage of the candelabra wax is 2 to 18%, the weight percentage of the wax is 1 to 9%, the weight percentage of the wax is 1 to 11%, and the weight of the vaseline is The percentage is from 1 to 5%; at least one thickener comprising Stearic alcohol and Aluminum Stearate, wherein the weight percentage of stearyl alcohol is 2-18% and the hard fat The acid aluminum has a weight percentage of 0 to 6%; at least one powder comprising polymethysilsesquioxane, quaternary ammonium salt 18 (quaternium-18 Hectorite), and a talc powder (Talc Powder). And a titanium dioxide (Titanium Dioxide), wherein the polymethyl sesquioxane is 2% to 8% by weight, the quaternary ammonium salt 18 has a weight percentage of 0.5 to 1.5%, and the weight percentage of the talc is 2 to 8% and the weight percentage of the titanium dioxide is 2 to 8%; at least one liquid fat containing Cyclopentasiloxane and Mineral Oil, wherein the weight percentage of the cyclopentaoxane is 2 to 18% and the mineral oil is 20% to 80% by weight; at least one pigment, wherein the pigment is 5 to 15% by weight; and at least one flavor, wherein the fragrance is 0.5 to 3.5% by weight; A preservative with a weight percentage of 0.1 to 1.9%.

It can be seen from the above that the water-washing anti-splashing and water-repellent makeup composition of the present invention is an emulsifier having an HLB value of 13 or less, which can provide a simple low-cost, good waterproof effect, and is simple and does not have to pass through a special organic Cleansing oil can achieve the effect of removing cosmetics.

S100~S300‧‧‧Steps

BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a flow chart showing the preparation method of the water-washing water-repellent makeup composition of the present invention; and Figures 2 to 6 are photographs of the test results of the water-washing water-repellent makeup composition and the general anti-splashing watercolor makeup of the present invention.

The present invention is a preferred embodiment of the technical means employed to solve the problem or The scope of the invention is not limited to the scope of the invention, and the equivalent variations and modifications made by the scope of the patent application of the invention, or the scope of the invention, are covered by the invention.

A water-washing anti-splashing watercolor makeup composition of the present invention is characterized in that it comprises: at least one emulsifier having an HLB value of 13 or less, at least one solid fat, at least one thickener, at least one powder, and at least one liquid fat. The features of the present invention are further described below.

Emulsifier with HLB value less than or equal to 13

The emulsifier having an HLB value of 13 or less used in the water-washable water-repellent makeup composition of the present invention can reduce the surface tension of water by adsorbing the polymer particles at the gas-liquid two-phase interface, or reduce the oil-water by adsorbing between the liquid interfaces. Interfacial tension is introduced into the composition, and these emulsifiers are commonly used to stabilize the surfactant of the polymer particles.

The color cosmetic composition of the present invention may comprise at least one emulsifier having an HLB value of 13 or less, wherein the emulsifier having an HLB value of 13 or less is 0.1 to 13% by weight relative to the composition, further 5 to 10%, more Further 6~8%. The emulsifier mentioned in the present invention having an HLB value of 13 or less is a nonionic surfactant, for example, PEG-30 Dipolyhydroxystearate, Glyceryl Stearate, Polyethylene B. Glycol-100 Stearate, Laureth-4, Cetyl Dimethicone Copolyol, Bi-PEG/PPG -14/14 Polydimethyloxane (Bis-PEG/PPG-14/14 Dimethicone), Lauryl Alcohol Polythylene Glycol Ether, Cetyl/Stearylether-22 (Ceteareth- 22) and tridecethene-10 (Trideceth-10).

Further, it may also be a nonionic surfactant-polyether type, for example: poly Polyglyceryl-4 Isostearate or Polyglyceryl-3 Oleate.

Further, it may be a nonionic surfactant-ester type such as sorbitan isostearate or sorbitan sesquioleate.

Solid grease

The solid fat used in the water-washing anti-splashing watercolor makeup composition of the present invention can provide soft skin, control viscosity and function as a film-forming agent, and can further adjust the solid oil for the structural properties of the water-washing anti-splashing watercolor makeup composition. Dosage.

The make-up composition of the present invention may comprise at least one solid fat, wherein the solid fat is from 1 to 18% by weight, further from 3 to 15%, and further preferably from 5 to 12% by weight of the composition. The solid fats and oils referred to in the present invention may comprise at least one of the following vegetable waxes, for example, Candellila wax, also known as candelilla wax, Carnaub wax, and Rhus verniciflua Peel Wax. Among them, Candellila wax contains 40~50% hydrocarbons, esters, acids, resins and the like.

Further, it may be Celesin wax, Bees wax or Vasline.

Thickener

The thickening agent used in the water-washing anti-splashing watercolor makeup composition of the present invention can form a three-dimensional hydration network structure by using a surfactant (emulsifier) to form a rod-shaped micelle, interact with water, or utilize its own macromolecular length. The chain structure and the like achieve the purpose of thickening the system. In addition, it can have a better effect on the final rheological morphology of the product through a variety of thickeners.

The make-up composition of the present invention may comprise at least one thickening agent, wherein the thickening agent is from 0 to 18% by weight, further from 3 to 15%, and further preferably from 6 to 13% by weight of the composition. The thickener mentioned in the present invention may comprise at least one of the following hydrophilic thickeners, for example: sodium polyacrylate, Stearic alcohol, polyethylene, polyquaternium (Polyquaternium) And sodium polyacryloyldimethyl taurate.

Further, it may also be a lipophilic thickener such as stearic acid.

Further, it may be an organic clay mineral such as: Stearalkonium bentonite, Hydrogenated Tallowalkonium Bentonite or Bentalkonium Bentonite.

powder

The make-up composition of the present invention may comprise at least one powder, wherein the powder is from 0.5 to 15% by weight, further from 3 to 15%, and further preferably from 5 to 15% by weight of the composition. The powder mentioned in the present invention is selected from the group consisting of Talc Powder, Silicon Powder, Zinc Oxide, Polymethylmethacrylate (PMMA), Calcium Silicate (Calcium Silicate). , Polymethysilsesquioxane, Zinc stearate, Aluminum Starch Octenylsuccinate, Titanium Dioxide, Bentonite, Kaolinite Group of Kaolinite), Quaternium-18 Bentonite, Quaternium-90 Bentonite, and Quaternium-18 Hectorite. Among them, zinc oxide (Zinc Oxide) and titanium dioxide (Titanium Dioxide) can be used as sunscreen The agent is resistant to UVA and UVB; in addition, the silicone powder and the polymethysilsesquioxane have water resistance as a water repellent.

Further, Talc Powder, Calcium Silicate, Aluminum Starch Octenylsuccinate, Bentonite, Kaolinite can be used as an adsorbent to absorb oil and absorb water. characteristic.

Liquid grease

The color cosmetic composition of the present invention may comprise at least one liquid fat, wherein the liquid fat is from 2 to 80% by weight, further from 15 to 60%, and further preferably from 30 to 50% by weight relative to the composition. The liquid fat used in the water-washing anti-splashing watercolor makeup composition of the present invention mainly serves as an emollient for the makeup composition and provides a moisturizing effect, and may contain a volatile oil such as cyclomethoxane. (Cyclonethicone), cyclopentasiloxane and cyclopentasiloxane.

Further, it may also be a non-volatile fat, such as Dimethicone.

Further, it may be an unsaturated hydrocarbon mineral oil, Dissostearyl malate, Isopropyl myristate, octanoic acid/capric acid triglyceride (Caprylic). /Capric Triglyceride), N-butyl stearate, Squalane, Hydrogenated Polyisobutene, Isononyl Isononanoate, Cetylpyridoxane Cetyl Dimethicone) and Ethylhexyl palmitate.

Colorant

The color cosmetic composition of the present invention may further comprise a coloring agent, wherein the coloring agent The weight percentage relative to the composition is from 1 to 15%, further from 3 to 13%, and further from 9 to 12%. The type of coloring agent can be selected from a group consisting of a synthetic coloring agent and a natural coloring agent extracted from animal and plant tissues.

Still further, the color cosmetic composition of the present invention may further comprise a fragrance, an antioxidant, and a preservative.

In addition, the color cosmetic composition of the present invention may be in any of the following forms, including a paste, an emulsion, a powder or a gel, and the application product of the makeup composition may be an eye shadow, a powder cake, a liquid foundation, a vermicelli, Mascara, eyebrows, or blush.

The invention also provides a preparation method of a water-washing anti-splashing watercolor makeup composition, which is specifically as follows: Please refer to FIG. 1. FIG. 1 is a flow chart of a method for preparing a water-washing water-repellent makeup composition according to the present invention. Firstly, the emulsifier, solid oil, thickener and liquid oil with HLB value less than or equal to 13 are respectively added to the stirring pot according to a ratio, stirred and mixed to form an intermediate product A, and heated to melt at a high temperature of 75-85 ° C. The ratio is 0.1 to 13% by weight of the emulsifier having an HLB value of 13 or less, 1 to 18% by weight of the solid fat, 0 to 18% by weight of the thickener, and 2 to 80% by weight of the liquid fat (step S100). After the intermediate product A is completely melted, powder, a pigment, and a preservative are added, and the same intermediate product B is uniformly stirred to be uniformly stirred until the pigment is completely dispersed (step S200). Finally, the intermediate product B in which the pigment is uniformly dispersed is subjected to a mold filling, and is placed at a normal temperature shade to be cooled, and is used after being cooled (step S300).

Further, the present invention provides another water-washing water-repellent makeup composition comprising: an emulsifier having an HLB value of 13 or less, wherein the emulsifier having an HLB value of 13 or less is 0.1 to 13% by weight of the laurel Laureth-4; at least one solid oil a fat comprising a Candellila wax, a Ceresin wax, a Bees wax, and a Vaseline, wherein the candied wax is 2-18% by weight The wax is 1% to 9% by weight, the wax is 1% to 11% by weight, and the Vaseline is 1% to 5% by weight; at least one thickener comprising stearyl alcohol (Stearic) Alcohol) and aluminum stearate, wherein stearyl alcohol is 2-18% by weight and the aluminum stearate is 0-6% by weight; at least one powder comprising polymethyl hydrazine Polymethysilsesquioxane, quaternium 18 Hectorite, Talc Powder, and Titanium Dioxide, wherein the weight percentage of the polymethyl sesquioxane is 2 to 8%, the weight percentage of the quaternary ammonium salt 18 hectorite is 0.5 to 1.5%, the weight percentage of the talc powder is 2 to 8%, and the weight percentage of the titanium dioxide is 2 to 8%; at least one liquid fat, Containing cyclopentasiloxane and mineral oil, wherein the weight of the cyclopentaoxane The percentage of the amount is 2 to 18% and the weight percentage of the mineral oil is 20 to 80%; at least one pigment, wherein the pigment is 5 to 15% by weight; at least one fragrance, wherein the fragrance is 0.5 to 3.5 by weight. %; and 0.1 to 1.9% by weight of preservative.

In summary, the water-washable water-repellent makeup composition provided by the present invention relates to a color cosmetic composition having an emulsifier having an HLB value of 13 or less, which has more than half of a fat and oil component, and provides water repellent property and good oil. Phase (continuous phase) solubility to achieve an easy removal effect, wherein the oil content component is mainly determined by the ratio of solid fat to liquid fat, and in addition, the present invention uses a neutral emulsifier (nonionic surfactant) As a component of the stable emulsion, the emulsion provided by the present invention is more excellent in stability than other ionic surfactants.

Example 1 - Eyeshadow Series Makeup Composition

Please refer to FIGS. 2-6. FIG. 2-6 is a water-washing and water-repellent makeup composition of the present invention. A photograph of the test results of the general anti-splashing watercolor makeup, in the part of Fig. 2, is a schematic view of the water-washing anti-splashing watercolor makeup composition (left side) and the general anti-watercolor makeup (right side) applied to the glass sheet; then, the part of Fig. 3 is The water is poured into the glass piece of the water-repellent anti-splashing watercolor makeup composition (left side) and the general anti-watercolor makeup (right side), and it can be found that the color block on the right side of FIG. 3 is injected into the general anti-watercolor makeup. The phenomenon of color blurring appears, and the water-washing anti-splashing watercolor makeup composition on the left side of Fig. 3 has no color blurring phenomenon when water is injected.

In the parts of Fig. 4 and Fig. 5, the water-cleaning condition of the water-washing anti-splashing watercolor makeup composition (Fig. 4) and the general water-proof cleaning condition (Fig. 5) of the water-repellent water-repellent makeup composition are respectively shown in Fig. 4 The water-repellent and anti-splashing watercolor makeup composition can be easily removed by the water and the cleaning brush, while the water-repellent and cleaning brush of Figure 5 cannot easily remove the general anti-watercolor makeup.

Next, the part of Fig. 6 shows a comparison between the water-washing anti-splashing watercolor makeup composition and the general anti-watercolor makeup after the use of clear water to remove the makeup, and it can be found that the water-washing anti-splashing watercolor makeup composition can be completely removed by the water, and generally The anti-watercolor makeup can't be completely cleaned by water.

The formulation dosages of the water-washable water-repellent makeup compositions of the present invention mentioned in the above Figures 2 to 6 are listed in Table 1, and the amounts of the respective components are expressed by weight percentage.

Claims (10)

A water-washing water-repellent makeup composition comprising: at least one emulsifier having an HLB value of 13 or less, wherein the emulsifier having an HLB value of 13 or less is 0.1 to 13% by weight; at least one solid fat, wherein The solid fat is 1% to 18% by weight; at least one thickener, wherein the thickener is 0% to 18% by weight; at least one powder, wherein the powder is 0.5% to 15% by weight; and at least one Liquid fat, wherein the liquid fat is 2% to 80% by weight. The water-washing water-repellent makeup composition according to claim 1, wherein the emulsifier having an HLB value of 13 or less is selected from the group consisting of PEG-30 Dipolyhydroxystearate and glyceryl stearic acid. (Glyceryl Stearate), PEG-100 Stearate, Laureth-4, Cetyl Dimethicone Copolyol ), bis-PEG/PPG-14/14 polydimethyloxane (Bis-PEG/PPG-14/14 Dimethicone), Lauryl Alcohol Polythylene Glycol Ether, polyglycerol-4 Polyglyceryl-4 Isostearate, Polyglyceryl-3 Oleate, Stearylth-22, Sorbitan isostearate, Dehydration A group consisting of sorbitan sesquioleate and trideceth-10. The water-repellent water-repellent makeup composition according to the above aspect of the invention, wherein the solid oil is selected from the group consisting of Candellila wax, Ceresin wax, Bees wax, palm A group of Carnaub wax, Rhus verniciflua Peel Wax, and Vaseline. The water-washing water-repellent makeup composition according to the above aspect of the invention, wherein the thickener is selected from the group consisting of aluminum stearate, stearic acid, and sodium polyacrylate. ), Stearic alcohol, Polyethylene, Polyquaternium, Sodium polyacryloyldimethyl taurate, Stearalkonium bentonite , a group consisting of hydrogenated Tallowalkonium Bentonite and Benzokonium Bentonite. The water-washing water-repellent makeup composition according to claim 1, wherein the powder is selected from the group consisting of Talc Powder, Silicon Powder, Zinc Oxide, and Polymethacrylic Acid. Methyl (PMMA, Polymethylmethacrylate), Calcium Silicate, Polymethysilsesquioxane, Zinc stearate, Aluminum Starch Octenylsuccinate Titanium Dioxide, Bentonite, Kaolinite, Quaternium-18 Bentonite, Quaternium-90 Bentonite and Quaternary Ammonium 18 Quaternium -18 Hectorite) group. The water-repellent and water-repellent makeup composition according to the above aspect of the invention, wherein the liquid fat is selected from the group consisting of mineral oil, cyclomethylhicone, and polydimethyloxane. (Dimethicone), Dissostearyl malate, Isopropyl myristate, Caprylic/Capric Triglyceride, n-butyl stearate N-butyl stearate), squalane, cyclopentasiloxane, hydrogenated polyisobutylene Polyisobutene), Isononyl Isononanoate, Cetyl Dimethicone, Cyclopentasiloxane, and Ethylhexyl palmitate. The water-washable water-repellent makeup composition according to the above aspect of the invention, wherein the composition further comprises a coloring agent, a preservative, a fragrance or an antioxidant. The water-washing water-repellent makeup composition according to the above aspect of the invention, wherein the composition is in the form of a paste, an emulsion, a powder or a gel. The invention discloses a preparation method of a water-washing anti-splashing watercolor makeup composition, which comprises the following steps: Step 1: adding an emulsifier, a solid oil, a thickener and a liquid fat with an HLB value of 13 or less to a stirring pot according to a ratio, stirring and mixing An intermediate product A is formed and heated to a high temperature at a temperature of 75 to 85 ° C, wherein the ratio is 0.1 to 13% by weight of an emulsifier having an HLB value of 13 or less, 1 to 18% by weight of a solid fat, and 0 to 18% of a thickener. Wt and liquid fat 2~80%wt; Step 2: After the intermediate product A is completely melted, add powder, pigment and preservative to form another intermediate product B; Step 3: Stir evenly until the pigment is dispersed; and Step 4: The intermediate product B in which the pigment is uniformly dispersed is subjected to a mold. A water-washing water-repellent makeup composition comprising: an emulsifier having an HLB value of 13 or less, wherein the emulsifier having an HLB value of 13 or less is 0.1 to 13% by weight of laureth-4 (Laureth- 4); at least one solid fat comprising Candellila wax, Ceresin wax, Bees wax and Vaseline, wherein the weight of the candelabra wax The percentage is 2 to 18%, the weight percentage of the wax is 1 to 9%, the weight percentage of the wax is 1 to 11%, and the weight percentage of the vaseline is 1 to 5%; at least one a thickener comprising Stearic alcohol and Aluminum Stearate, wherein the weight percentage of stearyl alcohol is 2 to 18% and the weight percentage of the aluminum stearate is 0 to 6%. At least one powder comprising polymethysilsesquioxane, quaternium-18 Hectorite, Talc Powder and Titanium Dioxide, wherein The weight percentage of polymethyl sesquioxane is 2 to 8%, the weight percentage of the quaternary ammonium salt 18 hectorite is 0.5 to 1.5%, the weight percentage of the talc powder is 2 to 8%, and the weight percentage of the titanium dioxide. 2 to 8%; at least one liquid fat, comprising Cyclopentasiloxane and Mineral Oil, wherein the weight percentage of the cyclopentaoxane is 2-18% and the weight of the mineral oil The percentage is 20-80%; at least one pigment, wherein the pigment is 5-15% by weight; at least one flavor, wherein the fragrance is 0.5-3.5% by weight; and 0.1-1.9% by weight of the preservative.