TW201900026A - 含有平速爛（ｐｅｎｏｘｓｕｌａｍ）及丁基拉草（ｂｕｔａｃｈｌｏｒ）之加乘性除草組成物 - Google Patents
含有平速爛（ｐｅｎｏｘｓｕｌａｍ）及丁基拉草（ｂｕｔａｃｈｌｏｒ）之加乘性除草組成物 Download PDFInfo
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- TW201900026A TW201900026A TW107113858A TW107113858A TW201900026A TW 201900026 A TW201900026 A TW 201900026A TW 107113858 A TW107113858 A TW 107113858A TW 107113858 A TW107113858 A TW 107113858A TW 201900026 A TW201900026 A TW 201900026A
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- butyl
- oil
- herbicidal
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
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Abstract
本發明係有關於可加乘性防治經選別的雜草之含(a)平速爛及(b)丁基拉草的除草組成物。
Description
發明領域
保護農作物免於受到會抑制農作物成長之雜草及其它植物的危害在農業中為一時常一再出現的問題。為了有助於與該問題搏鬥，合成化學領域的研究者已製成能有效防治此種非所欲草木的多方面化學品及化學調配物。許多類型的化學除草劑業經揭示在該文獻內且多數被商業使用。
發明背景
就某些情況而言，已證明一起施撒的除草活性成份比個別施撒之該等成份更有效，因此其被稱為“加乘作用(synergism)”。如the Herbicide Handbook of the Weed Science Society of America，第8版，2002年，第462頁中所述，“‘加乘作用’[為]2或多項因素之交互作用，因此當這些因素合併時，其效用大於基於對於各別施撒之各因素之反應的預定效用”。本發明係基於以下發現：丁基拉 草及平速爛(其等之除草效力係已為吾人所知)當一起施撒時，顯示加乘性效用。
發明概要
本發明係有關於含除草有效量之(a)平速爛及(b)丁基拉草的加乘性除草混合物。該等組成物亦可含有一農業上可接受的佐劑或載劑。
本發明亦係有關於尤其在稻中防治非所欲植物的成長之方法、及本加乘性組成物的用途。
平速爛為(2-(2,2-二氟乙氧基)-N-(5,8-二甲氧基-[1,2,4]三唑并[1,5-c]嘧啶-2-基)-6-(三氟甲基)苯磺醯胺的俗名。其除草活性描述在The Pesticide Manual,Fourteenth Edition,2006中。平速爛可防治稗草(barnyard grass)、以及稻中之許多濶葉莎草及水草。
丁基拉草為N-丁氧甲基-2-氯-2’,6’-二乙基乙醯胺苯的俗名。其除草活性描述在The Pesticide Manual,Fourteenth Edition,2006中。丁基拉草可防治一年生的禾草及某些濶葉雜草。
文中使用之該名詞除草劑意指一可殺死、防治或不利地限制植物之成長的活性成份。除草上有效或植物防治量為可導致不利地限制效用且其包括違反自然發育、致死、調整、乾燥、遲延等的數量。該等名詞“植物”及“草木”包括發芽的種子、出土的幼苗及外來植物。
可以在植物成長的任何階段或在種植或萌 前，藉直接施撒該加乘性混合物之化合物至該植物所在地而呈現除草活性。所觀測之效用取決於欲防治的植物物種、該植物的成長階段、稀釋及噴灑滴液大小的施撒參數、固體組份的粒度、使用時的環境條件、所使用的特定化合物、所使用的特定佐劑及載劑、土壤類型等、以及所施撒化學品的數量。可如本項技藝所知調整這些及其它因素以促進非選擇性或選擇性除草作用。一般而言，較佳自萌前階段至相當未成熟的非所欲植物成長階段施撒本發明該組成物以獲得雜草的最大防治性。
在本發明該組成物中，除草效用具加乘性的丁基拉草對平速爛之活性成份比(wt：wt)在介於10：1與300：1間之圍內、較佳為20：1至100：1、且最佳為40：1。
該加乘性組成物之施用效率可取決於欲防治的特定雜草類型、需要控制的程序、及施撒的時機與方法。一般而言，以該組成物內之活性成份總數量計，可以以介於153克活性成份/公頃(gai/ha)與1850gai/ha間之施撒率施撒本發明該組成物。較佳為介於310gai/ha與1250gai/ha間之施撒率。在本發明之一尤佳實施例中，係以介於400gai/ha與1200gai/ha間之速率施撒丁基拉草，且以介於10gai/ha與50gai/ha間之速率施撒平速爛。
可各別或以多部份除草系統之一部份施撒本發明該加乘性混合物的各組份。
本發明該加乘性混合物可以連同一或多種 其它除草劑施撒以防治多種非所欲植物。當連同其它除草劑使用時，該組成物可經其它除草劑或除草劑群調製、經其它除草劑或除草劑群桶混、或與其它除草劑或除草劑群相繼施撒。可連同本發明加乘性組成物使用的部份該等除草劑包括：2,4-D、乙草胺(acetochlor)、亞喜芬(acifluorfen)、苯草芬(aclonifen)、拉草(alachlor)、醯嘧磺隆(amidosulfuron)、環丙嘧啶酸(aminocyclopyraclor)、氯氨基吡啶酸(aminopyralid)、胺基三唑、硫氰酸銨、莎稗磷(anilifos)、四唑嘧磺隆(azimsulfuron)、吠草黃(benfuresate)、甲基免速隆(bensulfuron-methyl)、本達隆(bentazone)、殺萘丹(benthiocarb)、苯并雙環酮(benzobicyclon)、吡草酮(benzofenap)、必芬諾(bifenox)、雙草醚鈉(bispyribac-sodium)、克草(bromacil)、溴芬諾(bromobutide)、溴苯腈(bromoxynil)、氟丙嘧草酯(butafenacil)、比達寧(butralin)、苯酮唑(cafenstrole)、卡草胺(carbetamide)、乙基克繁草(carfentrazone-ethyl)、整形素(chlorflurenol)、氯嘧磺隆(chlorimuron)、克普芬(chlorpropham)、西速隆(cinosulfuron)、剋草同(clethodim)、炔草酸酯(clodinafop-propargyl)、可滅蹤(clomazone)、克普草(clomeprop)、畢克草(clopyralid)、氯酯磺草胺(cloransulam-methyl)、苄草隆(cumyluron)、環磺隆(cyclosulfamuron)、環殺草(cycloxydim)、丁基賽伏草 (cyhalofop-butyl)、汰草龍(daimuron)、麥草畏(dicamba)、二氯苯膦(dichlobenil)、2,4-滴丙酸(dichlorprop-P)、雙氯磺草胺(diclosulam)、吡氟醯草胺(diflufenican)、二氟吡隆(diflufenzopyr)、呱草丹(dimepiperate)、愛落殺(dimethametryn)、汰草滅(dimethenamid)、p-汰草滅、敵草快(diquat)、汰硫草(dithiopyr)、達有龍(diuron)、EK2612、EPTC、戊草丹(esprocarb)、亞速隆(ethoxysulfuron)、乙氧苯草胺(etobenzanid)、芬殺草(fenoxaprop)、乙基芬殺草、乙基芬殺草+乙基雙苯唑酸(isoxidifen-ethyl)、四唑醯草胺(fentrazamide)、伏速隆(flazasulfuron)、雙氟磺草胺(florasulam)、伏寄普(fluazifop)、P-丁基伏寄普、氟吡磺隆(flucetosulfuron)、氟噻草胺(flufenacet)、氟噠草酯(flufenpyr-Ethyl)、唑嘧磺草胺(flumetsulam)、戊基氟比來(flumiclorac-pentyl)、丙炔氟草胺(flumioxazin)、可奪草(fluometuron)、氟嘧啶磺隆(flupyrsulfuron)、氟氯比(fluroxypyr)、氟磺胺草醚(fomesafen)、甲醯胺磺隆(foramsulfuron)、氟比來、固殺草(glufosinate)、固殺草銨、P-固殺草、嘉磷塞(glyphosate)、合速隆(halosulfuron)、甲基合氯氟(haloxyfop-methyl)、R-合氯氟、三氮雜戊烯(imazamethabenz)、甲氧咪草煙(imazamox)、甲咪唑菸酸(imazapic)、依滅草(imazapyr)、咪唑喹啉酸(imazaquin)、咪草煙(imazethapyr)、依速隆(imazosulfuron)、依達諾芬 (indanofan)、碘磺隆(iodosulfuron)、碘苯腈(ioxynil)、艾芬卡斑唑(ipfencarbazone)、異丙隆(isoproturon)、異草胺(isoxaben)、異唑草酮(isoxaflutole)、乳氟禾草靈(lactofen)、MCPA、MCPB、二甲四氯丙酸(mecoprop-P)、滅芬草(mefenacet)、甲基二磺隆(mesosulfuron)、硝草酮(mesotrione)、唑醯草酸(metamifop)、莫多草(metolachlor)、磺草唑胺(metosulam)、甲磺隆(metsulfuron)、福得狀(molinate)、單嘧磺隆(monosulfuron)、MSMA、滅脫落(napropamide)、煙嘧磺隆(nicosulfuron)、氟草敏(norflurazon)、OK-9701、嘧苯胺磺隆(orthosulfamuron)、歐拉靈(oryzalin)、氯炔草酮(oxadiargyl)、樂滅草(oxadiazon)、草酮(oxazichlomefone)、復祿芬(oxyfluorfen)、巴拉刈(paraquat)、施得圃(pendimethalin)、環戊草(pentoxazone)、烯草胺(pethoxamid)、畢克攔(picloram)、吡氟苯草胺(picolinafen)、哌草磷(piperophos)、普拉草(pretilachlor)、氟嘧磺隆(primisulfuron)、環苯草酮(profoxydim)、雷蒙得(propachlor)、除草靈(propanil)、異丙草胺(propisochlor)、戊炔草胺(propyzamide)、苄草丹(prosulfocarb)、氟磺隆(prosulfuron)、雙唑草腈(pyraclonil)、乙基哌芬草(pyraflufen-ethyl)、吡唑吉(pyrazogyl)、苄草唑(pyrazolynate)、乙基百速隆 (pyrazosulfuron-ethyl)、普芬草(pyrazoxyfen)、嘧啶肟草醚(pyribenzoxim)、稗草畏(pyrabuticarb)、環酯草醚(pyriftalid)、甲基嘧草醚(pyriminobac-methyl)、嘧啶硫蕃(pyrimidsulfan)、甲氧磺草胺(pyroxsulam)、快克草(quinclorac)、莫克草(quinoclamine)、乙基-D-快伏草(quizalofop-ethyl-D)、S-3252、嘧啶肟草醚(saflufenacil)、稀禾定(sethoxydim)、草滅淨(simazine)、丙草淨(simetryne)、SL-0401、SL-0402、s-莫多草、硫三酮(sulcotrione)、甲磺草胺(sulfentrazone)甲硫膦(sulfosate)、特護摧(tefuryltrione)、帖普(tembotrione)、特莫定(terbacil)、欣克草(thenylchlor)、噻草定(thiazopyr)、殺丹(thiobencarb)、三氟比(triclopyr)、氟樂靈(trifluralin)、乙基抗倒酯(trinexapac-ethyl)及三氟甲磺隆(tritosulfuron)。
較佳實施例之詳細說明
本發明該加乘性組成物可使用在對乙醯乳酸酯合成酶抑制劑具耐受性的作物上。本發明該加乘性組成物可進一步連同2,4-D、嘉磷塞、固殺草、麥草畏或咪唑啉酮使用在對嘉磷塞、固殺草、麥草畏或咪唑啉酮具耐受性的作物上。
通常較佳與用於欲處置之作物且於所使用施撒速率下可補助藉這些化合物而防治之雜草範圍的除草劑一起使用本發明該加乘性組成物。進一步通常較佳同時或以組合調配物或槽混合物形式施撒本發明該加乘性組成物及其它互補性除草劑。
通常可以與已知除草劑解毒劑一起使用本發明該加乘性組成物以增強其等之選擇性，該等已知除草劑解毒劑為，例如解草酮(benoxacor)、殺萘丹、油菜素內酯(brassinolide)、解毒喹(cloquintocet(mexyl))、解草胺腈(cyometrinil)、賽硫醯胺(cyprosulfamate)、汰草龍、二氯丙烯胺(dichlormid)、敵環酮(dicyclonon)、二依索酸酯(dietholate)、呱草丹、二硫松(disulfoton)、解草唑(fenchlorazole-ethyl)、解草啶(fenclorim)、解草胺(flurazole)、氟草肟(fluxofenim)、解草唑(furilazole)、雙苯唑酸、唑解草酯(mefenpyr-diethyl)、美芬特(mephenate)、MG 191、MON 4660、萘酸酐(NA)、解草腈(oxabetrinil)、R29148及N-苯基-磺醯基苯甲酸醯胺。
實務上，較佳使用呈含一除草有效量該等除草組份及至少一農業上可接受佐劑或載劑的混合物形式之本發明該加乘性組成物。尤其在作物存在下，於施加用於選擇性雜草防治之該等組成物時所使用的濃度下，合適的佐劑或載劑對貴重的作物不應具毒性，且不應與除草組份或其它組合物成份起化學反應。此等混合物預計可用於直 接施撒至雜草或其等之所在地或可以是在施撒前通常可經另外載劑或佐劑稀釋的濃縮物或調配物。其等可以是固體，諸如粉末、顆粒、水可分散顆粒或可濕性散劑；或液體，諸如，可乳化濃縮物、溶液、乳液或懸浮液。
可用以製備本發明該等除草混合物之合適農業用佐劑及載為熟悉本項技藝者所熟知。這些佐劑中之一些包括，但不限於作物油濃縮物(礦物油(85%)+乳化劑(15%))；壬基酚乙氧化物；苄基椰子烷基二甲基季銨鹽；石油烴、烷基酯、有機酸、及陰離子表面活化劑的摻合物；C9-C11烷基聚糖苷；磷酸化醇乙氧化物；天然第一醇(C12-C16)乙氧化物；二-第二-丁基酚EO-PO嵌段共聚物；聚矽氧烷-甲基帽形物；壬基酚乙氧化物+硝酸脲銨；乳化甲基化種子油；十三醇(合成)乙氧化物(8EO)；牛油胺乙氧化物(15 EO)；PEG(400)二油酸酯-99。
可使用的液體載劑包括水及有機溶劑。該等有機溶劑典型上包括，但不限於：石油餾份或烴，諸如礦物油、芳香族溶劑、石蠟族油等；植物油，諸如大豆油、油菜籽油、橄欖油、蓖麻油、葵花籽油、椰子油、玉米油、棉籽油、亞麻油、棕櫚油、花生油、紅花油、芝麻油、桐油等；上述植物油之酯；單醇或二羥、三羥或其它低碳聚醇(含4至6個羥基)的酯，諸如己基硬脂酸2-乙酯、油酸正-丁酯、肉豆蔻酸異丙酯、丙二醇二油酸酯、琥珀酸二-辛酯、己二酸二-丁酯、酞酸二-辛酯等；單、二及多羧酸之酯等。特定有機溶劑包括甲苯、二甲苯、石油腦、作物油、丙酮、 甲基乙基酮、環己酮、三氯乙烯、全氯乙烯、乙酸乙酯、乙酸戊酯、乙酸丁酯、丙二醇單甲醚及二乙二醇單甲醚、甲醇、乙醇、異丙醇、戊醇、乙二醇、丙二醇、甘油、N-甲基-2-吡咯啶酮、N,N-二甲基烷基醯胺、二甲基亞碸、液體肥料等。水通常為所選用於烯釋濃縮物的載劑。
合適的固體載劑包括滑石、葉蠟石(pyro-phyllite)黏土、矽石、阿塔波格斯(attapulgus)黏土、高嶺土、漂白土(Fuller’s earth)、棉籽外殼、小麥粉、大豆粉、浮石、胡桃殼粉、木質素等。
通常較佳將一或多種活面活化劑併入本發明該等組成物內。此等表面活化劑可有利地用於固體及流體組成物內，尤其在施撒前預計經載劑稀釋之彼等組成物。該等表面活化劑可具陰離子性、陽離子性或非離子性且可作為乳化劑、濕潤劑、懸浮劑或用於其它目的。習用於調配物技藝且亦可用於本發明調配物之表面活化劑尤其描述在以下參考文獻中：McCutcheon’s Detergents and Emulsifiers Annual,”MC Publishing Corp.,Ridgewood,New Jersey,1998、及“Encyclopedia of Surfactants,”Vol.I-III,Chemical Publishing Co.,New York,1980-81。典型的表面活化劑包括烷基硫酸鹽，諸如月桂基硫酸二乙醇銨；烷基芳基磺酸鹽，諸如十二基苯磺酸鈣；烷基酚-環氧烷烴加成產物，諸如壬基酚-C18乙氧化物；醇-環氧烷烴加成產物，產如十三醇-C16乙氧化物；皂類，諸如硬脂酸鈉；烷基萘-磺酸鹽，諸如二丁基萘磺酸 鈉；磺基琥珀酸鹽之二烷基酯，諸如二(2-乙基己基)磺基琥珀酸鈉；山梨糖醇酯，諸如油酸山梨糖醇酯；第四胺，諸如月桂基氯化三甲銨；脂肪酸之聚乙二醇酯，諸如聚乙二醇硬脂酸酯；環氧乙烷及環氧丙烷之嵌段共聚物；磷酸單-及二烷酯；植物油，諸如大豆油、油菜籽油、橄欖油、蓖麻油、葵花籽油、椰子油、玉米油、棉籽油、亞麻油、棕櫚油、花生油、紅花油、芝麻油、桐油等；及上述植物油之酯。
習用於農業組成物之其它佐劑包括相容劑、消泡劑、螯合劑、中和劑及緩衝劑、抑蝕劑、染劑、氣味劑、塗佈劑、滲透輔助劑、黏著劑、分散劑、增稠劑、冰點降低劑、抗微生物劑等。該等組成物亦可含有其它可相容組份，例如其它除草劑、植物成長調節劑、殺真菌劑、殺蟲劑等且可經液體肥料或固體、微粒狀肥料載劑(諸如硝酸銨、尿素等)調製。
本發明之加乘性組成物中的該等活性成份之濃度通常為自0.001至98重量%。通常使用自0.01至90重量%之濃度。在預計作為濃縮物的組成物中，該等活性成份之存在濃度通常為自5至98重量%、較佳自10至90重量%。此等組成物在施撒前，典型上經惰性載劑(諸如水)稀釋。通常施撒至雜草或雜草所在地的該等經稀釋組成物含有0.0001至1重量%活性成份且較佳含有0.001至0.05重量%。
可藉以下方法而將本發明組成物施撒至雜 草或其等之所在地：使用習知地面或空中撒粉器、及顆粒施撒器；添加至灌溉水；及熟悉本項技藝者已知之其它習知方法。
以下實例闡明本發明。
實例
在現場情境方法(Field Conditions Methodology)下評估混合物之萌前除草活性
使用標準除草劑小試區研究方法進行稻之田間試驗。試區大小為2米2，將1.6米直徑環形物放入具有可經水淹灌之水容量的水稻土內以代表水稻栽培。每一次處置有3次複製試驗。稻為播種在稻育苗箱內以作為每一標準栽培實務的日本型粳稻，然後在水淹環形物內播種後30天，移植。使用用於施肥、播種、澆水、淹灌及維持的標準栽培實務使該稻作物成長以確保在台灣的成熟稻條件下，該作物及雜草的正常成長。移植後，使環試區水深維持於3至7厘米深度。就在處置施加前，將試區水排乾以在環試區內維持浸透的土壤。藉手工而施加處置法且在施加後24小時，使水再引導至3至7厘米深度。
就在移植後的第5至7天藉手工施加入該等環試區內之前，藉混合處置法與土壤而施加該等田間試驗中的所有處置法。在水中混合平速爛及丁基拉草的市售產物並噴撒至45克土壤上，其相當於在225公斤土壤/公頃的施撒速率下經處置的面積。就各2米2試區而言，使45克土壤與該合適的經調配產物數量混合以處置2米2來獲得以施 撒單位面積(公頃)計的所欲施撒速率。與未經處置的對照試區比較，評定處置法。以0至100%之比例評定目測雜草防治，其中0相當於無損害，而100相當於完全摧毀。
評估
施加處置法後，於各時間間隔下進行該等經處置試區與對照試區之盲評定。評分係根據目測雜草防治百分率(%)，其中0相當於無損害，而100相當於完全摧毀。
收集所有試驗的數據並使用各種統計學的方法進行分析。
使用科比方程式(Colby’s equation)以測定自該等混合物所預期的除草效用(Colby,S.R.Calculation of the synergistic and antagonistic response of herbicide combinations.Weeds 1967 15,20-22)。
使用以下方程式以計算含兩活性成份(A及B)的混合物之預測活性：預測活性=A+B-(A×B/100)
A=於與用於該混合物之相同濃度下，活性成份A的觀測效力；B=於與用於該混合物之相同濃度下，活性成份B的觀測效力。
結果摘述在表1至3內。
ECHCG-稗草(稗(Ehinochloa crus-galli))
MOOVA-梭魚草(鴨舌草(Monochoria vaginalis))
ISCRU-田螺草(田間鴨嘴草(Ischaemum rugosum))
克ae/ha-每公頃之活性成份的克數
Obs-所觀測防治%
預期活性*-藉科比方程式而預期的防治%
Claims (10)
- 一種用於萌前使用以防治非所欲之植物的加乘性除草混合物，其包含一除草有效量之(a)平速爛(penoxsulam)及(b)丁基拉草(butachlor)，其中該丁基拉草對平速爛的重量比為自10：1至23：1、40：1、或自79：1至100：1。
- 如請求項1之加乘性除草混合物，其中該丁基拉草對平速爛的重量比為自10：1至23：1。
- 如請求項1之加乘性除草混合物，其中該丁基拉草對平速爛的重量比為自79：1與100：1之間。
- 如請求項1之加乘性除草混合物，其中該丁基拉草對平速爛的重量比為20：1、23：1、40：1或79：1。
- 如請求項1之加乘性除草混合物，其中該丁基拉草對平速爛的重量比為約40：1。
- 如請求項1至5中任一項之加乘性除草混合物，其中該混合物進一步包含農業上可接受之佐劑或載劑。
- 如請求項6之加乘性除草混合物，其中該農業上可接受之佐劑或載劑包括作物油濃縮物。
- 如請求項1至5中任一項之加乘性除草混合物，其進一步包含一或多種額外除草劑。
- 如請求項8之加乘性除草混合物，其中該一或多種額外除草劑是選自2,4-D、嘉磷塞、固殺草、麥 草畏或咪唑啉酮。
- 如請求項1至5中任一項之加乘性除草混合物，其進一步包含除草劑解毒劑。
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| CN104994738B (zh) * | 2012-12-12 | 2019-06-28 | 美国陶氏益农公司 | 施用五氟磺草胺和苯噻酰草胺所引起的协同杂草防治 |
| US10412964B2 (en) | 2012-12-14 | 2019-09-17 | Dow Agrosciences Llc | Synergistic weed control from applications of aminopyralid and clopyralid |
| CN104994734B (zh) | 2012-12-14 | 2018-06-29 | 美国陶氏益农公司 | 由施用氯氨基吡啶酸和二氯吡啶酸进行协同杂草防治 |
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| US9717244B2 (en) | 2013-02-25 | 2017-08-01 | Dow Agrosciences Llc | Methods of weed control in pineapple |
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| CN108707010A (zh) * | 2018-06-28 | 2018-10-26 | 达州市兴隆化工有限公司 | 一种除草、施肥、增产多功效水稻药肥 |
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- 2011-02-01 BR BR112012019410-0A patent/BR112012019410A2/pt not_active IP Right Cessation
- 2011-02-01 KR KR1020127022920A patent/KR20120124473A/ko not_active Ceased
- 2011-02-01 TW TW105125624A patent/TWI633842B/zh active
- 2011-02-01 WO PCT/US2011/023270 patent/WO2011097187A2/en not_active Ceased
- 2011-02-01 KR KR1020187009547A patent/KR101937116B1/ko active Active
- 2011-02-01 CN CN2011800168242A patent/CN102984942A/zh active Pending
- 2011-02-01 JP JP2012552025A patent/JP2013518884A/ja active Pending
- 2011-02-02 PE PE2011000118A patent/PE20110688A1/es not_active Application Discontinuation
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2012
- 2012-07-31 IL IL221213A patent/IL221213A/en active IP Right Grant
- 2012-08-03 CO CO12131433A patent/CO6592075A2/es not_active Application Discontinuation
- 2012-09-03 EC ECSP12012135 patent/ECSP12012135A/es unknown
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2015
- 2015-12-17 JP JP2015245936A patent/JP6211047B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| TWI682719B (zh) | 2020-01-21 |
| ECSP12012135A (es) | 2012-09-28 |
| TW201717763A (zh) | 2017-06-01 |
| TWI633841B (zh) | 2018-09-01 |
| JP6211047B2 (ja) | 2017-10-11 |
| CN105075748A (zh) | 2015-11-25 |
| KR20180037331A (ko) | 2018-04-11 |
| TR201208936T1 (tr) | 2013-01-21 |
| US20110190135A1 (en) | 2011-08-04 |
| IL221213A0 (en) | 2012-10-31 |
| JP2013518884A (ja) | 2013-05-23 |
| JP2016117724A (ja) | 2016-06-30 |
| WO2011097187A2 (en) | 2011-08-11 |
| TWI633842B (zh) | 2018-09-01 |
| CN102984942A (zh) | 2013-03-20 |
| TW201136521A (en) | 2011-11-01 |
| CO6592075A2 (es) | 2013-01-02 |
| BR112012019410A2 (pt) | 2020-09-24 |
| KR101937116B1 (ko) | 2019-01-09 |
| KR20120124473A (ko) | 2012-11-13 |
| IL221213A (en) | 2016-11-30 |
| PE20110688A1 (es) | 2011-10-10 |
| PH12012501577A1 (en) | 2012-10-22 |
| WO2011097187A3 (en) | 2012-01-12 |
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