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TW201831745A - Moisture absorbing cool cloth and method for making the same with which there are a plurality of protrusions and a plurality of passages defined by the protrusions formed on the surface of cloth when hydrogel particles interposed between yarns of cloth body absorb moisture or sweat - Google Patents

Moisture absorbing cool cloth and method for making the same with which there are a plurality of protrusions and a plurality of passages defined by the protrusions formed on the surface of cloth when hydrogel particles interposed between yarns of cloth body absorb moisture or sweat Download PDF

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Publication number
TW201831745A
TW201831745A TW106106268A TW106106268A TW201831745A TW 201831745 A TW201831745 A TW 201831745A TW 106106268 A TW106106268 A TW 106106268A TW 106106268 A TW106106268 A TW 106106268A TW 201831745 A TW201831745 A TW 201831745A
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TW
Taiwan
Prior art keywords
cloth
moisture
absorbing
hydrogel
sensation
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Application number
TW106106268A
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Chinese (zh)
Inventor
黃晉男
李俊誼
廖亞蓉
洪維澤
Original Assignee
遠東新世紀股份有限公司
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Application filed by 遠東新世紀股份有限公司 filed Critical 遠東新世紀股份有限公司
Priority to TW106106268A priority Critical patent/TW201831745A/en
Priority to CN201710217358.3A priority patent/CN108505340A/en
Priority to US15/663,147 priority patent/US20180245250A1/en
Publication of TW201831745A publication Critical patent/TW201831745A/en

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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/16Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507Polyesters
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/395Isocyanates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/572Reaction products of isocyanates with polyesters or polyesteramides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/59Polyamides; Polyimides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/16Processes for the non-uniform application of treating agents, e.g. one-sided treatment; Differential treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34Polyamides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/06Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyethers
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/04Heat-responsive characteristics

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

A moisture absorbing cool cloth comprises a cloth body including a plurality of interwoven yarns, and a plurality of hydrogel particles interposed between the yarns of the cloth body. Based on the hydrogel particles interposed between the yarns of the cloth body, the user does not feel uncomfortable caused by existence of foreign objects when wearing the moisture absorbing cool cloth. When the hydrogel particles absorb moisture or sweat of the user, there are a plurality of protrusions spaced from each other and a plurality of passages defined by the protrusions formed on the surface of the moisture absorbing cool cloth. With the protrusions, the uncomfortable wet adhesion feeing caused by moisture or sweat is alleviated. In addition, with the passage and the hydrogel particles to absorb moisture or sweat, it is able to achieve the dry and cool effects.

Description

吸濕涼感布及製備吸濕涼感布的方法Moisture absorbing cool cloth and method for preparing moisture absorbing and cooling sensation cloth

本發明是有關於一種布,特別是指一種吸濕涼感布及製備該吸濕涼感布的方法。The present invention relates to a cloth, and more particularly to a moisture absorbing cool cloth and a method of preparing the moisture absorbing sensation cloth.

隨著人們對於衣服的舒適性的要求越來越高,針對衣服的吸濕性、快乾性且不黏肌膚等特性成為廣泛研究的議題,尤其是,當衣服吸收一穿著者所產生的濕氣或汗水時,由於衣服會吸附在該穿著者的肌膚上,而使得肌膚會產生濕黏的不適感。As people's demands for the comfort of clothes are getting higher and higher, the characteristics of hygroscopicity, quick-drying and non-sticking of the clothes have become the subject of extensive research, especially when the clothes absorb the moisture generated by a wearer. Or when sweat, the clothes will adhere to the wearer's skin, causing the skin to have a wet sticky discomfort.

為改善該不適感,台灣專利公開第201326491號揭示一種單向性吸濕排汗布料的結構,包含一表面吸浸有吸濕劑的第一人造纖維及一表面吸浸或塗佈有撥水劑的第二人造纖維,其中,該第一人造纖維與該第二人造纖維交錯而形成一第一表面及一第二表面,該第二人造纖維於接觸皮膚的該第二表面形成複數個微凸起結構。該專利案利用該等凸起結構將皮膚與已吸收汗水的第二表面隔開,以達到乾爽不黏滯的效果。In order to improve the discomfort, Taiwan Patent Publication No. 201326491 discloses a structure of a unidirectional moisture wicking fabric comprising a first rayon having a surface immersed in a moisture absorbing agent and a surface immersed or coated with water. a second rayon fiber, wherein the first rayon fiber and the second rayon fiber are interlaced to form a first surface and a second surface, and the second rayon fiber forms a plurality of micro on the second surface contacting the skin Raised structure. The patent utilizes the raised structures to separate the skin from the second surface that has absorbed sweat to achieve a dry, non-sticky effect.

雖該專利案可改善濕黏的不適感,然而,該凸起結構會使得該穿著者的皮膚一直產生有異物存在的不適感,且該凸起結構是由吸浸或塗佈有撥水劑的第二纖維所構成,所以該凸起結構並不具有吸濕效果,使得該布料整體的吸濕效果不佳,而存在有涼爽效果不足的問題。Although the patent can improve the discomfort of wet adhesion, the convex structure causes the wearer's skin to always have the uncomfortable feeling of foreign matter, and the convex structure is absorbed or coated with a water repellent. Since the second fiber is formed, the convex structure does not have a moisture absorbing effect, so that the overall moisture absorption effect of the cloth is not good, and there is a problem that the cooling effect is insufficient.

此外,為改善該不適感,中國大陸專利公開第101370978A號揭示一種形態變化纖維布帛,包含一纖維布帛層,及在該纖維布帛層的至少一面上設置有突起的圖案化的水溶脹性層。該水溶脹性層是由水不溶性水溶脹性樹脂所形成。該纖維布帛為織物、編織物或不織布。該纖維布帛的原材料為合成纖維、再生纖維、天然纖維,或上述任意的組合。該水不溶性水溶脹性樹脂指的是在使用環境下實質上水不溶性的,而在濕分或水的存在下吸水而溶脹的性質的樹脂,例如,澱粉-丙烯酸接枝系樹脂、聚丙烯酸氯系樹脂、聚乙烯醇系樹脂、聚醚系胺基甲酸酯樹脂、聚酯系胺基甲酸酯樹脂,或聚酯-聚醚系胺基甲酸酯樹脂等。該形態變化纖維布帛中的水溶脹性層吸收由運動等產生的汗或結露而溶脹,因而產生一應力,透過該應力帶動該纖維布帛層,使該纖維布帛層產生形態變化,而於乾燥時,該水溶脹性層中的水不溶性水溶脹性樹脂收縮,使得該應力消失,而使該纖維布帛層恢復到原先狀態。該專利案利用該水溶脹性層將皮膚與已吸收汗水的纖維布帛層隔開,以達到乾爽不黏滯的效果,同時,利用使該纖維布帛層產生形態變化,進一步使皮膚與已吸收汗水的纖維布帛層的接觸面積減少,更提升乾爽不黏滯的效果。In addition, in order to improve the feeling of discomfort, Chinese Patent Publication No. 101370978A discloses a morphologically varying fiber cloth comprising a fiber cloth layer and a patterned water-swellable layer provided with protrusions on at least one side of the fiber cloth layer. The water-swellable layer is formed of a water-insoluble water-swellable resin. The fiber cloth is a woven fabric, a woven fabric or a non-woven fabric. The raw material of the fiber cloth is synthetic fiber, recycled fiber, natural fiber, or any combination thereof. The water-insoluble water-swellable resin refers to a resin which is substantially water-insoluble in a use environment and which absorbs water and swells in the presence of moisture or water, for example, a starch-acrylic graft-based resin, polyacrylic acid chloride A resin, a polyvinyl alcohol-based resin, a polyether urethane resin, a polyester urethane resin, or a polyester-polyether urethane resin. The water-swellable layer in the morphological change fiber cloth swells by sweat or condensation generated by exercise or the like, thereby generating a stress, and the fiber cloth layer is driven by the stress to cause a morphological change of the fiber cloth layer, and when drying, The water-insoluble water-swellable resin in the water-swellable layer shrinks, so that the stress disappears, and the fiber cloth layer is restored to the original state. The patent utilizes the water-swellable layer to separate the skin from the sweat-absorbent fiber cloth layer to achieve a dry and non-sticky effect, and at the same time, the skin is absorbed and the sweat is absorbed by utilizing the morphological change of the fiber cloth layer. The contact area of the fiber cloth layer is reduced, and the effect of dryness and non-stickiness is enhanced.

雖該專利案可改善濕黏的不適感,然而,該水溶脹性層會使得該穿著者的皮膚一直產生有異物存在的不適感。再者,該形態變化纖維布帛經多次清洗後,該水溶脹性層易從該纖維布帛層上脫落,使得該形態變化纖維布帛的使用期限不符合需求。Although the patent can improve the discomfort of wet adhesion, the water-swellable layer causes the wearer's skin to always have the uncomfortable feeling of foreign matter. Moreover, after the morphological change fiber cloth is washed a plurality of times, the water swellable layer is easily detached from the fiber cloth layer, so that the service life of the morphological fiber cloth is not satisfactory.

因此,本發明的一目的,即在提供一種至少能夠解決先前技術所述的一缺點的吸濕涼感布。Accordingly, it is an object of the present invention to provide a absorbent sensation fabric that is at least capable of solving one of the disadvantages described in the prior art.

於是,本發明吸濕涼感布,包含一包括複數相互交織的紗線的布體,及複數被壓陷於該布體的該等紗線間的水凝膠微粒。Accordingly, the absorbent sensation fabric of the present invention comprises a cloth body comprising a plurality of interwoven yarns, and a plurality of hydrogel particles which are pressed between the yarns of the cloth body.

本發明的另一目的,即在提供一種製備吸濕涼感布的方法。Another object of the present invention is to provide a method of preparing a moisture absorbing sensation cloth.

於是,本發明製備吸濕涼感布的方法,包含以下步驟:步驟(a)混合一液態凝膠基質與一交聯劑而生成一乳化液,其中,該液態凝膠基質包含一前驅水凝膠及一溶劑,該乳化液包括藉由該前驅水凝膠與該交聯劑進行膠凝作用而形成的複數水凝膠微粒;步驟(b)將該乳化液印壓在一布體上,以使得該等水凝膠微粒被壓陷於該布體的數個相互交織的紗線間。Therefore, the method for preparing a moisture-absorbing and cooling sensation fabric comprises the steps of: (a) mixing a liquid gel matrix with a crosslinking agent to form an emulsion, wherein the liquid gel matrix comprises a precursor hydrogel. And a solvent comprising a plurality of hydrogel particles formed by gelation of the precursor hydrogel with the crosslinking agent; and step (b) printing the emulsion onto a cloth body, The hydrogel particles are caused to be trapped between a plurality of interwoven yarns of the cloth body.

本發明的功效在於:透過水凝膠微粒被壓陷於該布體的該等紗線間,當穿著者穿著該吸濕涼感布時,不會一直產生有異物存在的不適感,且當該等水凝膠微粒吸收該穿著者所產生的濕氣或汗水時,會導致該吸濕涼感布的表面形成有複數間隔的突起部以及複數由該等突起部相互界定出通道。透過該等突起部隔開穿著者的肌膚與吸收濕氣或汗水的吸濕涼感布,改善濕黏的不適感,再者,透過該等水凝膠微粒具有吸收濕氣或汗水的特性及該等通道產生的通風效果,使汗水快速被吸收及揮發且加速吸收汗水的吸濕涼感布的乾燥,達到乾燥涼爽的效果。The effect of the present invention is that the hydrogel particles are pressed between the yarns of the cloth body, and when the wearer wears the moisture-absorbing cool cloth, the uncomfortable feeling of foreign matter does not always occur, and when When the hydrogel particles absorb the moisture or sweat generated by the wearer, the surface of the moisture-absorbing sensation fabric is formed with a plurality of spaced-apart protrusions and a plurality of channels are defined by the protrusions. The wearer's skin and the moisture-absorbing and cooling sensation absorbing moisture or sweat are separated by the protrusions to improve the discomfort of wet adhesion, and further, the hydrogel particles have the property of absorbing moisture or sweat and The ventilation effect produced by the equal channel enables the sweat to be quickly absorbed and volatilized and accelerates the absorption of the moisture-absorbing moisture-absorbing cloth to achieve a dry and cool effect.

以下將就本發明內容進行詳細說明。The contents of the present invention will be described in detail below.

參閱圖1,本發明吸濕涼感布用於供依穿著者3穿著,且包含該布體1及該等水凝膠微粒2。Referring to Figure 1, the absorbent sensation fabric of the present invention is for wearing by the wearer 3 and comprises the cloth body 1 and the hydrogel particles 2.

<布體><cloth body>

該布體1例如但不限於具有彈性的織物。該具有彈性的織物例如但不限於針織布、平織布或不織布等。該布體1的該等紗線例如但不限於聚酯紗線、聚酯與棉混合紗線、棉紗線與尼龍紗線等。該聚酯與棉混合紗線例如但不限於CVC紗線或T/C紗線。The cloth body 1 is, for example but not limited to, a fabric having elasticity. The elastic fabric is, for example but not limited to, a knitted fabric, a plain woven fabric or a non-woven fabric. The yarns of the cloth body 1 are, for example but not limited to, polyester yarns, polyester and cotton hybrid yarns, cotton yarns, nylon yarns, and the like. The polyester-cotton blend yarn is, for example but not limited to, a CVC yarn or a T/C yarn.

<水凝膠微粒><Hydrogel particles>

該等水凝膠微粒2是由一前驅水凝膠與一交聯劑進行膠凝作用而形成。為使該吸濕涼感布吸收該穿著者3所產生的濕氣或汗水後更有效地改善濕黏的不適感並具有更佳的乾燥涼爽的效果,較佳地,該布體1具有一面積,該等水凝膠微粒2佔據該面積的40%至80%。該等水凝膠微粒2可共同建構出一設計圖案20。該設計圖案20例如但不限於網狀圖案或由數個幾何圖形塊間隔排列所構成的圖案。該網狀圖案具有複數網格,且該網格的形狀呈多邊形,而該多邊形例如六邊形。該幾何圖形塊例如但不限於多邊形塊、圓形塊、橢圓塊、環形塊,或同心圓塊等。該多邊形塊例如但不限於星形塊、方形塊、六邊形塊(參閱圖2),或菱形塊(參閱圖3)等。The hydrogel microparticles 2 are formed by gelation of a precursor hydrogel with a crosslinking agent. In order to make the moisture-absorbing and cooling cloth absorb the moisture or sweat generated by the wearer 3 to more effectively improve the discomfort of wet adhesion and have a better dry and cool effect, preferably, the cloth body 1 has an area. The hydrogel particles 2 occupy 40% to 80% of the area. The hydrogel particles 2 can be combined to form a design pattern 20. The design pattern 20 is, for example but not limited to, a mesh pattern or a pattern formed by a plurality of geometric block intervals. The mesh pattern has a complex grid, and the shape of the mesh is a polygon, and the polygon is, for example, a hexagon. The geometric block is for example but not limited to a polygonal block, a circular block, an elliptical block, a ring block, or a concentric block or the like. The polygon block is, for example but not limited to, a star block, a square block, a hexagonal block (see FIG. 2), or a diamond block (see FIG. 3), and the like.

<<前驅水凝膠>><<Precursor hydrogel>>

該前驅水凝膠為一聚醚系高分子。較佳地,該聚醚系高分子的重量平均分子量範圍為7,500至50,000。較佳地,該聚醚系高分子選自於具有酯基的聚醚系高分子、具有醯胺基的聚醚系高分子,或上述任意組合。該聚醚系高分子具有一重量平均分子量小於1,000的硬段重複單元及一與該硬段重複單元連接且重量平均分子量為1,000以上的軟段重複單元,且該軟段重複單元及該硬段重複單元皆由多元酸化合物或多元異氰酸酯化合物,與多元醇化合物經聚合反應所形成,其中,該軟段重複單元具有醚基。為使該前驅水凝膠具有更佳的親水性或吸濕性,較佳地,該硬段重複單元與該軟段重複單元的重量比例範圍為50:50至10:90。較佳地,該軟段重複單元的重量平均分子量範圍為2,000至8,500。該多元酸化合物可單獨一種使用或混合多種使用,且該多元酸化合物例如但不限於對苯二甲酸(terephthalic acid,簡稱TPA)、間苯二甲酸(isophthalic acid,簡稱IPA)、己二酸(adipic acid,簡稱AA)、丁二酸(succinic acid,簡稱SA),或二聚物酸(dimer acid)等。該多元異氰酸酯化合物可單獨一種使用或混合多種使用,且該多元異氰酸酯化合物例如但不限於二苯甲烷二異氰酸酯(methylene diphenyl diisocyanate,簡稱MDI)、二亞甲基苯二異氰酸酯(xylyl diisocyanate,簡稱XDI)、二異氰酸甲苯酯(toluene diisocyanate,簡稱TDI)、二異氰酸異佛爾酮(isophorone diisocyanate,簡稱IPDI),或六亞甲基二異氰酸酯(hexamethylene diisocyanate,簡稱HDI)等。該多元醇化合物可單獨一種使用或混合多種使用,且該多元醇化合物例如但不限於乙二醇(ethylene glycol,簡稱EG)、丁二醇(butylene glycol,簡稱BG)、己二醇(hexylene glycol,簡稱HG)、二乙二醇(diethylene glycol,簡稱DEG)、三乙二醇(triethylene glycol,簡稱TEG),或重量平均分子量範圍為200至11,000的聚乙二醇等。較佳地,該前驅水凝膠的體積膨脹率範圍為200%以上。The precursor hydrogel is a polyether polymer. Preferably, the polyether polymer has a weight average molecular weight ranging from 7,500 to 50,000. Preferably, the polyether polymer is selected from the group consisting of a polyether polymer having an ester group, a polyether polymer having a guanamine group, or any combination thereof. The polyether polymer has a hard segment repeating unit having a weight average molecular weight of less than 1,000 and a soft segment repeating unit connected to the hard segment repeating unit and having a weight average molecular weight of 1,000 or more, and the soft segment repeating unit and the hard segment The repeating unit is formed by a polybasic acid compound or a polyvalent isocyanate compound which is polymerized with a polyol compound, wherein the soft segment repeating unit has an ether group. In order to provide the precursor hydrogel with better hydrophilicity or hygroscopicity, preferably, the weight ratio of the hard segment repeating unit to the soft segment repeating unit ranges from 50:50 to 10:90. Preferably, the soft segment repeating unit has a weight average molecular weight ranging from 2,000 to 8,500. The polybasic acid compound may be used alone or in combination of two or more, and the polybasic acid compound is, for example but not limited to, terephthalic acid (TPA), isophthalic acid (IPA), adipic acid (abbreviated as IPEA). Adipic acid (AA), succinic acid (SA), or dimer acid. The polyisocyanate compound may be used alone or in combination of two or more, and the polyisocyanate compound is, for example but not limited to, methylene diphenyl diisocyanate (MDI), dimethylol phenyl diisocyanate (XDI). , toluene diisocyanate (TDI), isophorone diisocyanate (IPDI), or hexamethylene diisocyanate (HDI). The polyol compound may be used alone or in combination of two or more, and the polyol compound is, for example but not limited to, ethylene glycol (EG), butylene glycol (BG), hexylene glycol (hexylene glycol). , abbreviated as HG), diethylene glycol (DEG), triethylene glycol (TEG), or polyethylene glycol having a weight average molecular weight ranging from 200 to 11,000. Preferably, the precursor hydrogel has a volume expansion ratio in the range of 200% or more.

<<交聯劑>><<Crosslinker>>

該交聯劑可單獨一種使用或混合多種使用,且該交聯劑例如但不限於多元異氰酸酯化合物、環氧類交聯劑或矽烷類交聯劑等。以該液態凝膠基質的固形份的總量為100重量份計,該交聯劑的使用量範圍為3重量份至10重量份。當該交聯劑的使用量範圍大於10wt%,會使得該等水凝膠微粒2過硬,從而影響吸濕涼感布的手感變的較硬且粗糙(例如表面平滑而無粗糙顆粒感)。該多元異氰酸酯化合物可單獨一種使用或混合多種使用,且該多元異氰酸酯化合物例如但不限於二苯甲烷二異氰酸酯、二異氰酸甲苯酯或六亞甲基二異氰酸酯等。The crosslinking agent may be used singly or in combination of two or more kinds, and the crosslinking agent is, for example, but not limited to, a polyvalent isocyanate compound, an epoxy crosslinking agent or a decane crosslinking agent. The crosslinking agent is used in an amount ranging from 3 parts by weight to 10 parts by weight based on 100 parts by weight of the total of the solid parts of the liquid gel base. When the cross-linking agent is used in an amount greater than 10% by weight, the hydrogel microparticles 2 are made too hard, so that the hand feeling of the moisture-absorbing and cooling fabric is hard and rough (for example, the surface is smooth without coarse graininess). The polyvalent isocyanate compound may be used singly or in combination of plural kinds, and the polyvalent isocyanate compound is, for example, but not limited to, diphenylmethane diisocyanate, toluene diisocyanate or hexamethylene diisocyanate.

參閱圖1,透過該等水凝膠微粒2是被壓陷於該布體1的該等紗線間,使得該吸濕涼感布的表面實質上為平坦,故當一穿著者3穿著該吸濕涼感布且該穿著者3未產生濕氣或汗水時,穿著者3不會一直產生有異物存在的不適感。參閱圖4,當該吸濕涼感布的該等水凝膠微粒2吸收該穿著者3所產生的濕氣或汗水時,會降低溫度而有涼爽的效果,且該等水凝膠微粒2會膨脹而牽動該等紗線,使得該布體1整體產生變形,繼而導致該吸濕涼感布形成有複數間隔的突起部21以及複數由該等突起部21相互界定出通道22,透過該等突起部21,使得該穿著者3的肌膚與吸收濕氣或汗水的吸濕涼感布隔開,而改善濕黏的不適感,再者,透過該等通道22產生的通風效果,有效地帶走熱氣或濕氣而使汗水快速揮發且加速吸收汗水的吸濕涼感布的乾燥,以及透過該等水凝膠微粒2會吸收濕氣及汗水的特性,因而達到乾燥涼爽的效果。此外,當膨脹的水凝膠微粒中的汗水揮發後,該等膨脹的水凝膠微粒回復為未膨脹的狀態,而使得該等突起部21以及該等通道22消失,於此時,該穿著者3也不會產生有異物存在的不適感。Referring to FIG. 1, the hydrogel particles 2 are interposed between the yarns of the cloth body 1 such that the surface of the moisture-absorbing cool cloth is substantially flat, so when a wearer 3 wears the moisture absorption When the wearer 3 does not generate moisture or sweat, the wearer 3 does not always have an uncomfortable feeling of foreign matter. Referring to FIG. 4, when the hydrogel particles 2 of the moisture-absorbing sensation cloth absorb moisture or sweat generated by the wearer 3, the temperature is lowered and the cooling effect is obtained, and the hydrogel particles 2 are Expanding and pulling the yarns, so that the cloth body 1 is deformed as a whole, which in turn causes the moisture-absorbing and cooling fabric to form a plurality of spaced-apart protrusions 21 and a plurality of channels 22 defined by the protrusions 21, through which the protrusions are The portion 21 separates the skin of the wearer 3 from the moisture-absorbing and cooling cloth that absorbs moisture or sweat, thereby improving the discomfort of wet adhesion, and further, the ventilation effect generated by the passages 22 effectively removes the hot air. The drying of the moisture-absorbing and cooling sensation cloth which causes the sweat to rapidly evaporate and accelerates the absorption of sweat, and the characteristics of moisture and sweat absorbed by the hydrogel particles 2, thereby achieving a dry and cool effect. In addition, when the sweat in the expanded hydrogel particles volatilizes, the expanded hydrogel particles return to an unexpanded state, and the protrusions 21 and the channels 22 disappear, at which time the wearing 3 does not cause discomfort with foreign matter.

本發明吸濕涼感布可應用於服裝上。該服裝例如但不限於汗衫、貼身排汗衣、袖套,或運動服飾等。該運動服飾例如但不限於運動衣、運動褲、運動頭套,或運動腕套等。The moisture absorbing cool cloth of the present invention can be applied to clothing. The garment is, for example but not limited to, a sweatshirt, a sweatshirt, a sleeve, or a sportswear. The sportswear is for example but not limited to sportswear, sweatpants, sports headgear, or sports wristbands.

<製備吸濕涼感布的方法><Method of preparing moisture absorbing cool cloth>

步驟(a)混合一液態凝膠基質與一交聯劑而生成一乳化液,其中,該液態凝膠基質包含一前驅水凝膠及一溶劑,該乳化液包括藉由該前驅水凝膠與該交聯劑進行膠凝作用而形成的複數水凝膠微粒。該前驅水凝膠例如上述,故不再贅述。該溶劑可單獨一種使用或混合多種使用,且該溶劑例如但不限於酮類化合物、醇類化合物、酯類化合物、醯胺類化合物、苯類化合物、鹵烷類化合物,或醚類化合物等。該酮類化合物例如但不限於2-丁酮或丙酮等。該酯類化合物例如但不限於乙酸乙酯。該醇類化合物例如但不限於甲醇、乙醇,或異丙醇等。該醚類化合物例如但不限於四氫呋喃。該鹵烷類化合物例如但不限於氯仿。該苯類化合物例如但不限於甲苯或氯酚等。該醯胺類化合物例如但不限於N,N-二甲基乙醯胺、N,N-二甲基甲醯胺或N,N-二乙基乙醯胺等。該交聯劑例如上述,故不再贅述。Step (a) mixing a liquid gel matrix with a crosslinking agent to form an emulsion, wherein the liquid gel matrix comprises a precursor hydrogel and a solvent, the emulsion comprising the precursor hydrogel The cross-linking agent is subjected to gelation to form a plurality of hydrogel particles. The precursor hydrogel is, for example, the above, and therefore will not be described again. The solvent may be used alone or in combination of two or more, and the solvent is, for example but not limited to, a ketone compound, an alcohol compound, an ester compound, a guanamine compound, a benzene compound, a halogenated compound, or an ether compound. The ketone compound is, for example but not limited to, 2-butanone or acetone. The ester compound is, for example but not limited to, ethyl acetate. The alcohol compound is, for example but not limited to, methanol, ethanol, or isopropanol. The ether compound is, for example but not limited to, tetrahydrofuran. The halogenated compound is, for example but not limited to, chloroform. The benzene compound is, for example but not limited to, toluene or chlorophenol. The guanamine compound is, for example but not limited to, N,N-dimethylacetamide, N,N-dimethylformamide or N,N-diethylacetamide. The crosslinking agent is, for example, the above, and therefore will not be described again.

步驟(b)將該乳化液印壓在一布體上,以使得該等水凝膠微粒被壓陷於該布體的數個相互交織的紗線間。該布體例如上述,故不再贅述。該印壓方式例如但不限於凹版印刷(gravure printing)或凸版印刷(relief printing)等。較佳地,該印壓是利用一凹版印刷方式進行。該凹版印刷方式是利用一凹版來進行。該凹版例如但不限於雕刻凹版(intaglio)、網目凹版,或照相凹版等。為使該等水凝膠微粒更利於被壓陷於該布體的數個相互交織的紗線間,較佳地,該乳化液的黏度範圍為500 cps 至10,000 cps。更佳地,該乳化液的黏度範圍為1,500 cps 至3,500 cps。Step (b) printing the emulsion onto a cloth such that the hydrogel particles are trapped between the plurality of interwoven yarns of the body. The cloth body is as described above, and therefore will not be described again. The printing method is, for example but not limited to, gravure printing or relief printing. Preferably, the printing is performed by a gravure printing method. This gravure printing method is carried out using a gravure. The intaglio plate is, for example but not limited to, an intaglio, a gravure, or a gravure. Preferably, the emulsion has a viscosity in the range of from 500 cps to 10,000 cps in order to facilitate the incorporation of the hydrogel particles between the plurality of interwoven yarns of the body. More preferably, the emulsion has a viscosity ranging from 1,500 cps to 3,500 cps.

本發明將就以下實施例來作進一步說明,但應瞭解的是,該實施例僅為例示說明之用,而不應被解釋為本發明實施之限制。The present invention will be further illustrated by the following examples, but it should be understood that this embodiment is intended to be illustrative only and not to be construed as limiting.

製備例1 液態凝膠基質Preparation Example 1 Liquid Gel Matrix

將22.0克的對苯二甲酸、3.29克的乙二醇及180.13克的聚乙二醇混合,並於240℃進行4小時酯化反應,其中,以該多元醇化合物的總量和為100wt%計,該聚乙二醇的使用量範圍為90wt%。接著,在溫度為275℃且壓力為2torr以下進行4小時縮合聚合反應,即可獲得重量平均分子量約為40,000的前驅水凝膠,其中,該硬段重複單元由對苯二甲酸及乙二醇所形成,而該軟段重複單元由對苯二甲酸及聚乙二醇所形成,且該硬段重複單元與該軟段重複單元的重量比例為10:90,及該軟段重複單元的重量平均分子量為1,000至11,000。然後,加入2-丁酮,形成一液態凝膠基質,且以該液態凝膠基質的總量為100wt%計,固形份的含量為30wt%。22.0 g of terephthalic acid, 3.29 g of ethylene glycol, and 180.13 g of polyethylene glycol were mixed, and subjected to esterification reaction at 240 ° C for 4 hours, wherein the total amount of the polyol compound was 100 wt%. The polyethylene glycol is used in an amount ranging from 90% by weight. Next, a condensation polymerization reaction is carried out for 4 hours at a temperature of 275 ° C and a pressure of 2 torr or less to obtain a precursor hydrogel having a weight average molecular weight of about 40,000, wherein the hard segment repeating unit is composed of terephthalic acid and ethylene glycol. Formed, and the soft segment repeating unit is formed of terephthalic acid and polyethylene glycol, and the weight ratio of the hard segment repeating unit to the soft segment repeating unit is 10:90, and the weight of the soft segment repeating unit The average molecular weight is from 1,000 to 11,000. Then, 2-butanone was added to form a liquid gel matrix, and the solid content was 30% by weight based on 100% by weight of the total of the liquid gel matrix.

製備例2 液態凝膠基質Preparation 2 Liquid gel matrix

將22.0克的對苯二甲酸、3.29克的乙二醇及180.13克的聚乙二醇混合,並於240℃進行4小時酯化反應,其中,以該多元醇化合物的總量和為100wt%計,該聚乙二醇的使用量範圍為70wt%。接著,在溫度為275℃且壓力為2torr以下進行4小時縮合聚合反應,即可獲得重量平均分子量約為40,000的前驅水凝膠,其中,該硬段重複單元與該軟段重複單元的重量比例為30:70,且該軟段重複單元的重量平均分子量為1,000至11,000。然後,加入N,N-二甲基乙醯胺,形成一液態凝膠基質,且以該液態凝膠基質的總量為100wt%計,固形份的含量為20wt%。22.0 g of terephthalic acid, 3.29 g of ethylene glycol, and 180.13 g of polyethylene glycol were mixed, and subjected to esterification reaction at 240 ° C for 4 hours, wherein the total amount of the polyol compound was 100 wt%. The polyethylene glycol was used in an amount ranging from 70% by weight. Next, a condensation polymerization reaction is carried out for 4 hours at a temperature of 275 ° C and a pressure of 2 torr or less to obtain a precursor hydrogel having a weight average molecular weight of about 40,000, wherein the weight ratio of the hard segment repeating unit to the soft segment repeating unit It is 30:70, and the soft segment repeating unit has a weight average molecular weight of 1,000 to 11,000. Then, N,N-dimethylacetamide was added to form a liquid gel matrix, and the solid content was 20% by weight based on 100% by weight of the total of the liquid gel matrix.

製備例3 液態凝膠基質Preparation Example 3 Liquid Gel Matrix

將22.0克的對苯二甲酸、3.29克的乙二醇及180.13克的聚乙二醇混合,並於240℃進行4小時酯化反應,其中,以該多元醇化合物的總量和為100wt%計,該聚乙二醇的使用量範圍為50wt%。接著,在溫度為275℃且壓力為2torr以下進行4小時縮合聚合反應,即可獲得重量平均分子量約為40,000的前驅水凝膠,其中,該硬段重複單元與該軟段重複單元的重量比例為50:50,且該軟段重複單元的重量平均分子量為1,000至11,000。然後,加入氯仿及氯酚,形成一液態凝膠基質,且以該液態凝膠基質的總量為100wt%計,固形份的含量為20wt%。22.0 g of terephthalic acid, 3.29 g of ethylene glycol, and 180.13 g of polyethylene glycol were mixed, and subjected to esterification reaction at 240 ° C for 4 hours, wherein the total amount of the polyol compound was 100 wt%. The polyethylene glycol is used in an amount ranging from 50% by weight. Next, a condensation polymerization reaction is carried out for 4 hours at a temperature of 275 ° C and a pressure of 2 torr or less to obtain a precursor hydrogel having a weight average molecular weight of about 40,000, wherein the weight ratio of the hard segment repeating unit to the soft segment repeating unit It is 50:50, and the soft segment repeating unit has a weight average molecular weight of 1,000 to 11,000. Then, chloroform and chlorophenol were added to form a liquid gel matrix, and the solid content was 20% by weight based on 100% by weight of the total of the liquid gel matrix.

評價項目Evaluation project

吸水率量測:為方便描述量測過程,以製備例1做為代表進行說明,而製備例2至3皆以相同方式進行量測。將一不吸水的離型紙進行秤重,獲得一重量值為W1克。將製備例1的液態凝膠基質利用刮刀塗抹至該離型紙上,接著置於130℃的烘箱中烘烤3分鐘並秤重,獲得一重量值為W2克,然後浸泡於清水中5分鐘後取出並秤重,獲得一重量值為W3克。該吸水率=(W3-W2-W1)/(W2-W1)。評價結果參閱表1。該吸水率越大,表示該液態凝膠基質中的前驅水凝膠越具有親水性及吸水性。評價結果參閱表1。Water absorption measurement: In order to facilitate the description of the measurement process, the preparation example 1 is taken as a representative, and the preparation examples 2 to 3 are all measured in the same manner. A non-absorbent release paper was weighed to obtain a weight value of W1 gram. The liquid gel matrix of Preparation Example 1 was applied to the release paper by a doctor blade, and then baked in an oven at 130 ° C for 3 minutes and weighed to obtain a weight value of W 2 g, and then immersed in water for 5 minutes. Remove and weigh to obtain a weight value of W3 grams. The water absorption rate = (W3-W2-W1) / (W2-W1). The evaluation results are shown in Table 1. The greater the water absorption, the more hydrophilic and water-absorbent the precursor hydrogel in the liquid gel matrix. The evaluation results are shown in Table 1.

表1 Table 1

水滴接觸角量測:為方便描述量測過程,以製備例1做為代表進行說明,而製備例2至3皆以相同方式進行量測。在一針織布體(材質:聚酯紗線)的表面滴上水滴並以一水滴接觸角量測儀(廠牌:Kruss;型號:FM40)進行量測,獲得一水滴接觸角為A1。將製備例1的液態凝膠基質塗佈於一不吸水的基材上,接著進行乾燥處理,而在該不吸水的基材上形成約30μm的膜層,然後於該膜層的表面滴上水滴並以上述水滴接觸角量測儀進行量測,獲得一水滴接觸角為A2。當A2與A1的差值越大,表示該液態凝膠基質中的前驅水凝膠越具有親水性。評價結果參閱表2。Water droplet contact angle measurement: In order to facilitate the description of the measurement process, the preparation example 1 is taken as a representative, and the preparation examples 2 to 3 are all measured in the same manner. Water droplets were dropped on the surface of a knitted fabric (material: polyester yarn) and measured by a water droplet contact angle measuring instrument (label: Kruss; model: FM40) to obtain a water droplet contact angle of A1. The liquid gel matrix of Preparation Example 1 was coated on a non-absorbent substrate, followed by drying treatment, and a film layer of about 30 μm was formed on the non-absorbent substrate, and then dropped on the surface of the film layer. The water droplets were measured by the above-described water droplet contact angle measuring instrument to obtain a water droplet contact angle of A2. The greater the difference between A2 and A1, the more hydrophilic the precursor hydrogel in the liquid gel matrix. The evaluation results are shown in Table 2.

表2 Table 2

製備例4 乳化液Preparation Example 4 Emulsion

將10公斤的製備例1的液態凝膠基質與0.3公斤的交聯劑(廠牌:安鋒實業;型號:WH-2110;成分:二苯甲烷二異氰酸酯)充分混合均勻並進行膠凝作用,形成一包含複數水凝膠微粒的乳化液。該乳化液的黏度為2,000 ± 500 cps。10 kg of the liquid gel matrix of Preparation Example 1 was thoroughly mixed with 0.3 kg of a crosslinking agent (label: An Feng Industrial; model: WH-2110; component: diphenylmethane diisocyanate) and gelled. An emulsion comprising a plurality of hydrogel particles is formed. The emulsion has a viscosity of 2,000 ± 500 cps.

製備例5 乳化液Preparation Example 5 Emulsion

將10公斤的製備例2的液態凝膠基質與0.2公斤的交聯劑(廠牌:安鋒實業;型號:WH-2110;成分:二苯甲烷二異氰酸酯)充分混合均勻並進行膠凝作用,形成一包含複數水凝膠微粒的乳化液。該乳化液的黏度為2,000 ± 500 cps。10 kg of the liquid gel matrix of Preparation Example 2 was thoroughly mixed with 0.2 kg of a crosslinking agent (label: An Feng Industrial; model: WH-2110; component: diphenylmethane diisocyanate) and gelled. An emulsion comprising a plurality of hydrogel particles is formed. The emulsion has a viscosity of 2,000 ± 500 cps.

製備例6 乳化液Preparation Example 6 Emulsion

將10公斤的製備例3的液態凝膠基質與0.06公斤的交聯劑(廠牌:安鋒實業;型號:WH-2110;成分:脂肪族異氰酸酯)充分混合均勻並進行膠凝作用,形成一包含複數水凝膠微粒的乳化液。該乳化液的黏度為1,500 ± 500 cps。10 kg of the liquid gel matrix of Preparation Example 3 was thoroughly mixed with 0.06 kg of a crosslinking agent (label: Anfeng Industrial; model: WH-2110; component: aliphatic isocyanate) and gelled to form a An emulsion comprising a plurality of hydrogel particles. The emulsion has a viscosity of 1,500 ± 500 cps.

評價項目Evaluation project

吸水倍率及體積膨脹率量測:為方便描述量測過程,以製備例4做為代表進行說明,而製備例5至6皆以相同方式進行量測。將製備例4的乳化液形成一厚度為12.1μm的乾膜,並將其秤重得到一乾膜重量值,接著,將該乾膜浸泡在室溫水中5分鐘後取出,然後,將該乾膜表面的水漬去除,並經多次秤重得到一吸水後總重量平均值。該乾膜密度主要是利用塑料密度測定儀(廠牌:Mettler Toledo)量測。該吸水倍率為[(吸水後總重量平均值-乾膜重量值)/乾膜重量值]×100%。該體積膨脹率為[(乾膜體積與水分體積的總和)/乾膜體積] ×100%,其中,該乾膜體積為乾膜重量值/乾膜密度,而該水分體積為(吸水後總重量平均值-乾膜重量值)/1。評價結果參閱表3。該體積膨脹率越大,表示該液態凝膠基質中的前驅水凝膠可使該吸濕涼感布吸收該穿著者所產生的濕氣或汗水後所形成的突起部的高度更高,繼而減輕濕黏的不適感及提升乾燥涼爽的效果。Water absorption ratio and volume expansion ratio measurement: In order to facilitate the description of the measurement process, the preparation example 4 was taken as a representative, and the preparation examples 5 to 6 were all measured in the same manner. The emulsion of Preparation Example 4 was formed into a dry film having a thickness of 12.1 μm, and weighed to obtain a dry film weight value, and then the dry film was taken out in room temperature water for 5 minutes, and then taken out, and then the dry film was taken out. The water stain on the surface is removed, and the weight is averaged after being weighed several times. The dry film density is mainly measured by a plastic densitometer (label: Mettler Toledo). The water absorption ratio is [(total weight average after water absorption - dry film weight value) / dry film weight value] × 100%. The volume expansion ratio is [(sum of dry film volume to moisture volume) / dry film volume] × 100%, wherein the dry film volume is dry film weight value / dry film density, and the water volume is (total after water absorption) Weight average - dry film weight value) / 1. The evaluation results are shown in Table 3. The larger the volume expansion ratio, the higher the height of the protrusion formed by the precursor moisture gel in the liquid gel matrix after the moisture absorbent cloth absorbs the moisture or sweat generated by the wearer, thereby reducing Wet sticky discomfort and improved dryness and coolness.

表3 table 3

實施例1 吸濕涼感布Example 1 moisture absorbing cool cloth

利用一輪狀雕刻凹版(材料:不鏽鋼;凹紋深度:100μm)將製備例4的乳化液印壓在一針織布體(材質:聚酯纖維)上,以使得該乳化液中的該等水凝膠微粒被壓陷於該布體的數個相互交織的紗線間。接著置於120℃的烘箱中進行60秒的乾燥處理。The emulsion of Preparation Example 4 was printed on a knitted fabric (material: polyester fiber) using a round engraving gravure (material: stainless steel; concave depth: 100 μm) so that the water in the emulsion The gel particles are crushed between a plurality of interwoven yarns of the cloth body. It was then placed in an oven at 120 ° C for 60 seconds of drying.

實施例2至14Examples 2 to 14

實施例2至14是以與實施例1相同的步驟來製備吸濕涼感布,不同的地方在於如表3所示。Examples 2 to 14 were prepared in the same manner as in Example 1 except that they were as shown in Table 3.

比較例1Comparative example 1

採用實施例1的針織布體,但不具有水凝膠微粒。The knitted fabric of Example 1 was used, but without hydrogel particles.

評價項目Evaluation project

印刷覆蓋率(%):該等水凝膠微粒共同建構出的圖案佔據該針織布體的面積的多寡。Print coverage (%): The pattern of the hydrogel particles co-constructed occupies the area of the knitted fabric.

突起部的高度(單位:μm)量測:使實施例1至14的吸濕涼感布吸收水分1分鐘後,利用一表面3D輪廓量測儀(廠牌:KEYENCE International Belgium;型號:VR-3100)進行量測。Height (unit: μm) of the projections: After absorbing the moisture for the moisture absorbing fabrics of Examples 1 to 14 for 1 minute, a surface 3D profile measuring instrument was used (label: KEYENCE International Belgium; model: VR-3100) ) Perform measurements.

單向傳輸指數(one-way transport capability,簡稱OTC,單位:%)量測:依據美國紡織品染化師協會(American Association of Textile Chemists and Colorists,簡稱AATCC)公布的編號195-2010的測試方法,並使用一水分吸收測試儀(廠牌:ALTAS Moisture Management Tester)進行量測。One-way transport capability (OTC, unit: %) measurement: according to the test method number 195-2010 published by the American Association of Textile Chemists and Colorists (AATCC), The measurement was carried out using a moisture absorption tester (label: ALTAS Moisture Management Tester).

瞬間涼感度量測:依據機能性暨產業用紡織品認證與驗證評議委員會製定的「織物瞬間涼感驗證規範FTTS-FA-019」進行評估,並使用熱效應測定儀(廠牌:KES-F7 THERMO LABO II)進行織物瞬間涼感熱流量(簡稱Q-max,單位:W/cm2 )的量測。該織物瞬間涼感熱流量係使用儀器模擬試驗織物接觸人體時單位面積的最大熱量流失值(瓦特/平方公分,W/cm2 ),以作為織物涼感度的指標。Instant Cooling Measurement: Based on the “Fabric Instant Cooling Verification Specification FTTS-FA-019” developed by the Functional and Industrial Textiles Certification and Verification Review Committee, and using a thermal effect tester (label: KES-F7 THERMO LABO II The measurement of the instantaneous thermal flow rate of the fabric (Q-max for short, unit: W/cm 2 ) is performed. The instantaneous thermal flow rate of the fabric is an instrument used to simulate the maximum heat loss per unit area (Watt/cm 2 , W/cm 2 ) of the test fabric when it contacts the human body, as an indicator of the coolness of the fabric.

持續涼感溫度(單位:℃)量測:為方便描述量測過程,以實施例1做為代表進行說明,而其餘實施例及比較例皆以相同方式進行量測。將一張已吸收1.5毫升水的濾紙置於實施例1的吸濕涼感布上。接著,將一片重量為183克的玻璃板置於該濾紙上,並於該玻璃板上放置1公斤的重物。待1分鐘後,移除該玻璃板與該重物,並紀錄該吸濕涼感布的表面溫度。Continuous cooling temperature (unit: ° C) measurement: In order to facilitate the description of the measurement process, the embodiment 1 is taken as a representative, and the remaining examples and comparative examples are measured in the same manner. A piece of filter paper having absorbed 1.5 ml of water was placed on the moisture absorbing cloth of Example 1. Next, a piece of glass plate weighing 183 g was placed on the filter paper, and a weight of 1 kg was placed on the glass plate. After 1 minute, the glass plate and the weight were removed, and the surface temperature of the moisture-absorbing cool cloth was recorded.

體感溫度變化值(單位:℃)量測:為方便描述量測過程,以實施例1做為代表進行說明,而其餘實施例皆以相同方式進行量測。使一穿著有實施例1的吸濕涼感布及比較例1的針織布體的受測者以時速為10公里/時的條件跑步20分鐘,接著使用一紅外線熱顯像儀(廠牌:FLIR;型號:E60)對穿著有實施例1的吸濕涼感布的地方及穿著有比較例1的針織布體的地方量測溫度,且該等溫度分別為T2及T1。該體感溫度變化值為T2-T1。Somatosensory temperature change value (unit: ° C) measurement: In order to facilitate the description of the measurement process, the embodiment 1 is taken as a representative, and the remaining examples are measured in the same manner. A subject wearing the moisture-absorbing sensation cloth of Example 1 and the knitted fabric of Comparative Example 1 was run for 20 minutes at a speed of 10 km/h, and then an infrared thermal imaging image (label: FLIR) was used. ; Model: E60) The temperature was measured at the place where the moisture-absorbing cool cloth of Example 1 was worn and the place where the knitted fabric of Comparative Example 1 was worn, and the temperatures were T2 and T1, respectively. The somatosensory temperature change value is T2-T1.

尺寸變化率(Dimensional Change,簡稱DC;單位:%)量測:依據AATCC公布的編號135-2003的方法,量測實施例1至14的吸濕涼感布及比較例1的針織布體經正常洗滌20次前及後的尺寸。該尺寸變化率(%)=[(經正常洗滌20次後尺寸-洗滌前尺寸)/洗滌前尺寸]×100%。Measurement of Dimensional Change (DC; unit: %): The moisture-absorbing sensation cloths of Examples 1 to 14 and the knitted fabric of Comparative Example 1 were normalized according to the method of No. 135-2003 published by AATCC. Wash the size before and after 20 times. The dimensional change rate (%) = [(size after pre-washing 20 times - size before washing) / size before washing] × 100%.

水洗20次後突起部的高度(單位:μm)量測:將經正常洗滌20次後的實施例1至14的吸濕涼感布吸收水分1分鐘後,利用上述表面3D輪廓量測儀進行量測。The height (unit: μm) of the protrusions after washing 20 times: The moisture-absorbing sensation cloths of Examples 1 to 14 after the normal washing 20 times were absorbed for 1 minute, and then the amount was measured by the above-mentioned surface 3D profilometer. Measurement.

表4 Table 4

表5 table 5

由表4及表5的實驗數據可知,本發明透過該等水凝膠微粒的存在,該等吸濕涼感布的涼感度得以提升,再者,該等吸濕涼感布於吸收穿著者所產生的濕氣或汗水後,有效地可將濕氣或汗水排出。此外,由水洗前後的吸濕涼感布經吸收水1分鐘後的突起部的高度數據可知,本發明吸濕涼感布中的該等水凝膠微粒牢固地壓陷於該布體的該等紗線間,而不會脫落,表示有較佳地水洗牢度,使得該等吸濕涼感布具有較佳的使用期限。It can be seen from the experimental data of Tables 4 and 5 that the present invention enhances the coolness of the moisture-absorbing and cooling sensation cloth by the presence of the hydrogel particles, and further, the moisture-absorbing and cooling sensation cloth is produced by the absorbent wearer. After moisture or sweat, it can effectively remove moisture or sweat. Further, it can be seen from the height data of the projections obtained by absorbing the water for one minute after the water-absorbing and cooling fabric before and after the water washing, the hydrogel particles in the moisture-absorbing and cooling fabric of the present invention are firmly pressed against the yarns of the cloth body. Between, without falling off, indicating better washing fastness, so that the absorbent sensation fabric has a better life span.

綜上所述,本發明透過該等水凝膠微粒被壓陷於該布體的該等紗線間,當該穿著者穿著該吸濕涼感布時,不會一直產生有異物存在的不適感,且當該等水凝膠微粒吸收該穿著者所產生的濕氣或汗水時,形成的該等突起部隔開該穿著者的肌膚與吸收濕氣或汗水的吸濕涼感布,改善濕黏的不適感,再者,形成的該等通道產生的通風效果,使汗水快速被吸收及揮發且加速吸收汗水的吸濕涼感布的乾燥,達到乾燥涼爽的效果,故確實能達成本發明的目的。In summary, the present invention is infiltrated between the yarns of the cloth body through the hydrogel particles, and when the wearer wears the moisture-absorbing cool cloth, the uncomfortable feeling of foreign matter does not always occur. And when the hydrogel particles absorb moisture or sweat generated by the wearer, the protrusions formed separate the wearer's skin from the moisture absorbing cloth absorbing moisture or sweat to improve wet adhesion. Discomfort, furthermore, the ventilation effect produced by the passages is such that the sweat is quickly absorbed and volatilized, and the moisture-absorbing and cooling cloth which accelerates the absorption of sweat is dried to achieve a dry and cool effect, so that the object of the present invention can be achieved.

惟以上所述者,僅為本發明的實施例而已,當不能以此限定本發明實施的範圍,凡是依本發明申請專利範圍及專利說明書內容所作的簡單的等效變化與修飾,皆仍屬本發明專利涵蓋的範圍內。However, the above is only the embodiment of the present invention, and the scope of the invention is not limited thereto, and all the simple equivalent changes and modifications according to the scope of the patent application and the patent specification of the present invention are still Within the scope of the invention patent.

1‧‧‧布體
2‧‧‧水凝膠微粒
20‧‧‧圖案
21‧‧‧突起部
22‧‧‧通道
3‧‧‧穿著者
1‧‧‧ cloth body
2‧‧‧Hydrogel particles
20‧‧‧ patterns
21‧‧‧Protruding
22‧‧‧ channel
3‧‧‧wearers

本發明的其他的特徵及功效,將於參照圖式的實施方式中清楚地呈現,其中: 圖1是本發明吸濕涼感布的一不完整的剖視示意圖; 圖2是本發明吸濕涼感布的一不完整的俯視示意圖; 圖3是本發明吸濕涼感布的一不完整的俯視示意圖; 及 圖4是一不完整的剖視示意圖,說明本發明吸濕涼感布吸收一穿著者的濕氣及/或汗水的狀態。Other features and effects of the present invention will be apparent from the following description of the drawings, wherein: Figure 1 is a schematic view of an incomplete cross-sectional view of the absorbent sensation fabric of the present invention; FIG. 3 is an incomplete top view of the absorbent sensation fabric of the present invention; and FIG. 4 is an incomplete cross-sectional schematic view showing the absorbent wicking cloth of the present invention absorbing a wearer's The state of moisture and / or sweat.

Claims (11)

一種吸濕涼感布,包含: 一布體,包括複數相互交織的紗線;及 複數水凝膠微粒,被壓陷於該布體的該等紗線間。A moisture absorbing cool woven fabric comprising: a cloth body comprising a plurality of interwoven yarns; and a plurality of hydrogel particles being pressed between the yarns of the cloth body. 如請求項1所述的吸濕涼感布,其中,該等水凝膠微粒是由一前驅水凝膠與一交聯劑進行膠凝作用而形成。The moisture-absorbing sensation fabric according to claim 1, wherein the hydrogel microparticles are formed by gelation of a precursor hydrogel with a crosslinking agent. 如請求項2所述的吸濕涼感布,其中,該前驅水凝膠為一聚醚系高分子。The moisture-absorbing and cooling sensation according to claim 2, wherein the precursor hydrogel is a polyether polymer. 如請求項3所述的吸濕涼感布,其中,該聚醚系高分子選自於具有酯基的聚醚系高分子、具有醯胺基的聚醚系高分子,或上述任意組合。The moisture-absorbing and cooling fabric according to claim 3, wherein the polyether polymer is selected from the group consisting of a polyether polymer having an ester group, a polyether polymer having a mercapto group, or any combination thereof. 如請求項1所述的吸濕涼感布,其中,該布體具有一面積,該等水凝膠微粒佔據該面積的40%至80%。A moisture-absorbing sensation cloth according to claim 1, wherein the cloth body has an area, and the hydrogel particles occupy 40% to 80% of the area. 如請求項1所述的吸濕涼感布,其中,該布體為一具有彈性的織物。The absorbent sensation fabric of claim 1, wherein the cloth body is a fabric having elasticity. 如請求項6所述的吸濕涼感布,其中,該具有彈性的織物為一針織物。The absorbent sensation fabric of claim 6, wherein the elastic fabric is a knitted fabric. 一種製備吸濕涼感布的方法,包含以下步驟: 步驟(a)混合一液態凝膠基質與一交聯劑而生成一乳化液,其中,該液態凝膠基質包含一前驅水凝膠及一溶劑,該乳化液包括藉由該前驅水凝膠與該交聯劑進行膠凝作用而形成的複數水凝膠微粒; 步驟(b)將該乳化液印壓在一布體上,以使得該等水凝膠微粒被壓陷於該布體的數個相互交織的紗線間。A method for preparing a moisture-absorbing and cooling sensation cloth comprising the steps of: (a) mixing a liquid gel matrix with a crosslinking agent to form an emulsion, wherein the liquid gel matrix comprises a precursor hydrogel and a solvent The emulsion comprises a plurality of hydrogel particles formed by gelation of the precursor hydrogel with the crosslinking agent; and step (b) printing the emulsion onto a cloth body to make the same The hydrogel particles are trapped between a plurality of interwoven yarns of the cloth body. 如請求項8所述的製備吸濕涼感布的方法,其中,該印壓是利用一凹版印刷方式進行。A method of preparing a moisture absorbing sensation cloth according to claim 8, wherein the printing is performed by a gravure printing method. 如請求項8所述的製備吸濕涼感布的方法,其中,該前驅水凝膠為一聚醚系高分子。The method for preparing a moisture absorbing sensation cloth according to claim 8, wherein the precursor hydrogel is a polyether polymer. 如請求項8所述的製備吸濕涼感布的方法,其中,該乳化液的黏度範圍為500 cps 至10,000 cps。A method of preparing a moisture absorbing sensation cloth according to claim 8, wherein the emulsion has a viscosity ranging from 500 cps to 10,000 cps.
TW106106268A 2017-02-24 2017-02-24 Moisture absorbing cool cloth and method for making the same with which there are a plurality of protrusions and a plurality of passages defined by the protrusions formed on the surface of cloth when hydrogel particles interposed between yarns of cloth body absorb moisture or sweat TW201831745A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI794573B (en) * 2019-12-27 2023-03-01 南韓商可隆工業股份有限公司 Skin cooling fabric, polyethylene yarn therefor, and method for manufacturing polyethylene yarn

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109736078B (en) * 2019-01-18 2021-07-20 东华大学 A post-finishing process for hygroscopic cool sports fabrics
CN110447984A (en) * 2019-08-09 2019-11-15 李宁(中国)体育用品有限公司 Promote the clothes of heat dissipation
TWI753667B (en) * 2020-11-23 2022-01-21 財團法人紡織產業綜合研究所 Moisture-proof and heat-insulating fabric

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20080107370A (en) * 2006-01-17 2008-12-10 세이렌가부시끼가이샤 Morphological Fiber
CN101914854B (en) * 2009-07-15 2012-10-24 高鼎精细化工(昆山)有限公司 Temperature sensitive type waterproof moisture-penetrating urethane resin and preparation method thereof
US10875274B2 (en) * 2011-11-29 2020-12-29 Columbia Sportswear North America, Inc. Cooling material
TWI507581B (en) * 2011-11-29 2015-11-11 Columbia Sportswear Na Inc Cooling fabric and method of making the same
WO2015153926A1 (en) * 2014-04-02 2015-10-08 Columbia Sportswear North America, Inc. Cooling material
CN105295076B (en) * 2015-11-23 2017-12-12 安踏(中国)有限公司 A kind of cool feeling hydrogel and preparation method thereof, cool feeling fabric and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI794573B (en) * 2019-12-27 2023-03-01 南韓商可隆工業股份有限公司 Skin cooling fabric, polyethylene yarn therefor, and method for manufacturing polyethylene yarn

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