TW201817802A - 丙烯酸橡膠之製造方法、丙烯酸橡膠組成物之製造方法以及橡膠交聯物之製造方法 - Google Patents

丙烯酸橡膠之製造方法、丙烯酸橡膠組成物之製造方法以及橡膠交聯物之製造方法 Download PDF

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Publication number: TW201817802A
Authority: TW; Taiwan
Prior art keywords: acrylic rubber; weight; ethylene oxide; parts; polymerization
Prior art date: 2016-10-31

Application number

TW106137448A

Other languages

English (en)

Chinese (zh)

Inventor

佐藤獎

山之上智士

增田浩文

Original Assignee

日商日本瑞翁股份有限公司

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2016-10-31

Filing date

2017-10-30

Publication date

2018-05-16

2017-10-30 Application filed by 日商日本瑞翁股份有限公司 filed Critical 日商日本瑞翁股份有限公司

2018-05-16 Publication of TW201817802A publication Critical patent/TW201817802A/zh

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229920000800 acrylic rubber Polymers 0.000 title claims abstract description 189
229920000058 polyacrylate Polymers 0.000 title claims abstract description 189
238000004519 manufacturing process Methods 0.000 title claims abstract description 130
239000000178 monomer Substances 0.000 claims abstract description 125
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 121
229920000642 polymer Polymers 0.000 claims abstract description 81
238000007720 emulsion polymerization reaction Methods 0.000 claims abstract description 74
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 62
229920001971 elastomer Polymers 0.000 claims abstract description 57
238000000034 method Methods 0.000 claims abstract description 52
239000005060 rubber Substances 0.000 claims abstract description 48
239000000701 coagulant Substances 0.000 claims abstract description 37
238000005345 coagulation Methods 0.000 claims abstract description 30
230000015271 coagulation Effects 0.000 claims abstract description 30
238000006116 polymerization reaction Methods 0.000 claims description 108
230000002776 aggregation Effects 0.000 claims description 44
239000008188 pellet Substances 0.000 claims description 40
239000000203 mixture Substances 0.000 claims description 35
239000000839 emulsion Substances 0.000 claims description 33
239000003995 emulsifying agent Substances 0.000 claims description 30
238000004220 aggregation Methods 0.000 claims description 26
238000004945 emulsification Methods 0.000 claims description 23
238000002156 mixing Methods 0.000 claims description 23
238000004132 cross linking Methods 0.000 claims description 22
239000007788 liquid Substances 0.000 claims description 16
239000012875 nonionic emulsifier Substances 0.000 claims description 16
239000012874 anionic emulsifier Substances 0.000 claims description 15
239000003638 chemical reducing agent Substances 0.000 claims description 15
239000003431 cross linking reagent Substances 0.000 claims description 13
238000002360 preparation method Methods 0.000 claims description 5
229920001519 homopolymer Polymers 0.000 claims description 3
239000003999 initiator Substances 0.000 claims 1
229920002209 Crumb rubber Polymers 0.000 abstract 1
-1 2-ethylhexyl Chemical group 0.000 description 83
239000000243 solution Substances 0.000 description 69
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 52
239000003795 chemical substances by application Substances 0.000 description 43
239000000047 product Substances 0.000 description 36
239000002253 acid Substances 0.000 description 27
230000003712 anti-aging effect Effects 0.000 description 27
238000005406 washing Methods 0.000 description 22
239000005977 Ethylene Substances 0.000 description 19
235000002639 sodium chloride Nutrition 0.000 description 19
229920003171 Poly (ethylene oxide) Polymers 0.000 description 18
238000005054 agglomeration Methods 0.000 description 18
238000001035 drying Methods 0.000 description 18
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125000001931 aliphatic group Chemical group 0.000 description 14
239000011259 mixed solution Substances 0.000 description 14
239000003505 polymerization initiator Substances 0.000 description 14
150000003839 salts Chemical class 0.000 description 14
239000007787 solid Substances 0.000 description 14
230000004931 aggregating effect Effects 0.000 description 13
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 12
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125000004432 carbon atom Chemical group C* 0.000 description 11
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235000011152 sodium sulphate Nutrition 0.000 description 11
238000012360 testing method Methods 0.000 description 11
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238000006243 chemical reaction Methods 0.000 description 10
238000010438 heat treatment Methods 0.000 description 10
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230000000694 effects Effects 0.000 description 9
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239000000463 material Substances 0.000 description 6
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
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UTOVMEACOLCUCK-SNAWJCMRSA-N (e)-4-butoxy-4-oxobut-2-enoic acid Chemical compound CCCCOC(=O)\C=C\C(O)=O UTOVMEACOLCUCK-SNAWJCMRSA-N 0.000 description 5
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125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 5
239000000126 substance Substances 0.000 description 5
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
CIWBSHSKHKDKBQ-DUZGATOHSA-N D-araboascorbic acid Natural products OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 4
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
125000005907 alkyl ester group Chemical group 0.000 description 4
238000005354 coacervation Methods 0.000 description 4
DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 4
235000010350 erythorbic acid Nutrition 0.000 description 4
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125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 4
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229910052757 nitrogen Inorganic materials 0.000 description 4
150000001451 organic peroxides Chemical class 0.000 description 4
IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 4
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HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 3
XSQHUYDRSDBCHN-UHFFFAOYSA-N 2,3-dimethyl-2-propan-2-ylbutanenitrile Chemical compound CC(C)C(C)(C#N)C(C)C XSQHUYDRSDBCHN-UHFFFAOYSA-N 0.000 description 3
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UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
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GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 3
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ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
239000007983 Tris buffer Substances 0.000 description 3
125000004183 alkoxy alkyl group Chemical group 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
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SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 3
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125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 2
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241001441571 Hiodontidae Species 0.000 description 2
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125000000129 anionic group Chemical group 0.000 description 2
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150000002989 phenols Chemical class 0.000 description 1
150000003014 phosphoric acid esters Chemical class 0.000 description 1
229910000073 phosphorus hydride Inorganic materials 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
235000021110 pickles Nutrition 0.000 description 1
PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920006122 polyamide resin Polymers 0.000 description 1
229920002857 polybutadiene Polymers 0.000 description 1
229920005668 polycarbonate resin Polymers 0.000 description 1
239000004431 polycarbonate resin Substances 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920001225 polyester resin Polymers 0.000 description 1
239000004645 polyester resin Substances 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920006124 polyolefin elastomer Polymers 0.000 description 1
229920005672 polyolefin resin Polymers 0.000 description 1
229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
229920001955 polyphenylene ether Polymers 0.000 description 1
229920001451 polypropylene glycol Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
229920005990 polystyrene resin Polymers 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
235000019275 potassium ascorbate Nutrition 0.000 description 1
229940017794 potassium ascorbate Drugs 0.000 description 1
DJEHXEMURTVAOE-UHFFFAOYSA-M potassium bisulfite Chemical compound [K+].OS([O-])=O DJEHXEMURTVAOE-UHFFFAOYSA-M 0.000 description 1
229940099427 potassium bisulfite Drugs 0.000 description 1
239000001103 potassium chloride Substances 0.000 description 1
235000011164 potassium chloride Nutrition 0.000 description 1
235000010259 potassium hydrogen sulphite Nutrition 0.000 description 1
RWPGFSMJFRPDDP-UHFFFAOYSA-L potassium metabisulfite Chemical compound [K+].[K+].[O-]S(=O)S([O-])(=O)=O RWPGFSMJFRPDDP-UHFFFAOYSA-L 0.000 description 1
235000010333 potassium nitrate Nutrition 0.000 description 1
239000004323 potassium nitrate Substances 0.000 description 1
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
229910052939 potassium sulfate Inorganic materials 0.000 description 1
BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
235000011151 potassium sulphates Nutrition 0.000 description 1
235000019252 potassium sulphite Nutrition 0.000 description 1
CONVKSGEGAVTMB-RXSVEWSESA-M potassium-L-ascorbate Chemical compound [K+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] CONVKSGEGAVTMB-RXSVEWSESA-M 0.000 description 1
VMBJJCDVORDOCF-UHFFFAOYSA-N prop-2-enyl 2-chloroacetate Chemical compound ClCC(=O)OCC=C VMBJJCDVORDOCF-UHFFFAOYSA-N 0.000 description 1
PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
238000007717 redox polymerization reaction Methods 0.000 description 1
238000011160 research Methods 0.000 description 1
238000010057 rubber processing Methods 0.000 description 1
239000004945 silicone rubber Substances 0.000 description 1
229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
VYKVQJFOZDGJLN-UHFFFAOYSA-M sodium hydrogen sulfite sulfurous acid Chemical compound [Na+].OS(O)=O.OS([O-])=O VYKVQJFOZDGJLN-UHFFFAOYSA-M 0.000 description 1
235000010344 sodium nitrate Nutrition 0.000 description 1
239000004317 sodium nitrate Substances 0.000 description 1
CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
235000010265 sodium sulphite Nutrition 0.000 description 1
AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
235000019345 sodium thiosulphate Nutrition 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229920003048 styrene butadiene rubber Polymers 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
125000004434 sulfur atom Chemical group 0.000 description 1
230000008961 swelling Effects 0.000 description 1
RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 description 1
TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
KRAHLZAGPKKBSW-UHFFFAOYSA-N tetrasodium;dioxidophosphanyl phosphite Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])OP([O-])[O-] KRAHLZAGPKKBSW-UHFFFAOYSA-N 0.000 description 1
150000007970 thio esters Chemical class 0.000 description 1
150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
229910052718 tin Inorganic materials 0.000 description 1
FAKFSJNVVCGEEI-UHFFFAOYSA-J tin(4+);disulfate Chemical compound [Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O FAKFSJNVVCGEEI-UHFFFAOYSA-J 0.000 description 1
HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
229910000348 titanium sulfate Inorganic materials 0.000 description 1
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
VPYJNCGUESNPMV-UHFFFAOYSA-N triallylamine Chemical compound C=CCN(CC=C)CC=C VPYJNCGUESNPMV-UHFFFAOYSA-N 0.000 description 1
OAHWWXAJFXEIPX-UHFFFAOYSA-M tributyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](CCCC)(CCCC)CCCC OAHWWXAJFXEIPX-UHFFFAOYSA-M 0.000 description 1
IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
ABVVEAHYODGCLZ-UHFFFAOYSA-N tridecan-1-amine Chemical compound CCCCCCCCCCCCCN ABVVEAHYODGCLZ-UHFFFAOYSA-N 0.000 description 1
RKBCYCFRFCNLTO-UHFFFAOYSA-N triisopropylamine Chemical compound CC(C)N(C(C)C)C(C)C RKBCYCFRFCNLTO-UHFFFAOYSA-N 0.000 description 1
YQMWDQQWGKVOSQ-UHFFFAOYSA-N trinitrooxystannyl nitrate Chemical compound [Sn+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O YQMWDQQWGKVOSQ-UHFFFAOYSA-N 0.000 description 1
YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
WXAZIUYTQHYBFW-UHFFFAOYSA-N tris(4-methylphenyl)phosphane Chemical compound C1=CC(C)=CC=C1P(C=1C=CC(C)=CC=1)C1=CC=C(C)C=C1 WXAZIUYTQHYBFW-UHFFFAOYSA-N 0.000 description 1
NCPXQVVMIXIKTN-UHFFFAOYSA-N trisodium;phosphite Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])[O-] NCPXQVVMIXIKTN-UHFFFAOYSA-N 0.000 description 1
125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/12—Esters of monohydric alcohols or phenols
- C08F20/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F20/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
- C08F6/22—Coagulation

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Polymerisation Methods In General (AREA)
Compositions Of Macromolecular Compounds (AREA)

TW106137448A 2016-10-31 2017-10-30 丙烯酸橡膠之製造方法、丙烯酸橡膠組成物之製造方法以及橡膠交聯物之製造方法 TW201817802A (zh)

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Application Number	Priority Date	Filing Date	Title
JP2016-213493		2016-10-31
JP2016213493		2016-10-31
JP2017-013294		2017-01-27
JP2017013294		2017-01-27

Publications (1)

Publication Number	Publication Date
TW201817802A true TW201817802A (zh)	2018-05-16

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TW106137448A TW201817802A (zh)	2016-10-31	2017-10-30	丙烯酸橡膠之製造方法、丙烯酸橡膠組成物之製造方法以及橡膠交聯物之製造方法

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JP (3)	JP6394834B1 (ja)
TW (1)	TW201817802A (ja)
WO (1)	WO2018079786A1 (ja)

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CN113412284A (zh) *	2019-03-29	2021-09-17	株式会社大阪曹達	丙烯酸酯橡胶的制造方法
TWI837378B (zh) *	2019-07-19	2024-04-01	日商日本瑞翁股份有限公司	儲存穩定性與加工性優異的丙烯酸橡膠塊體及其製造方法、橡膠混合物以及橡膠交聯物

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SG11202010602WA (en) *	2018-04-27	2020-11-27	Zeon Corp	Production of acrylic rubber and obtained acrylic rubber
KR20250165684A (ko)	2018-09-28	2025-11-26	니폰 제온 가부시키가이샤	전고체 이차 전지용 바인더 조성물, 전고체 이차 전지용 슬러리 조성물, 고체 전해질 함유층 및 전고체 이차 전지
US12057583B2 (en)	2018-09-28	2024-08-06	Zeon Corporation	Binder composition for all-solid-state secondary battery, slurry composition for all-solid-state secondary battery, solid electrolyte-containing layer, and all-solid-state secondary battery
JP7459668B2 (ja) *	2019-07-19	2024-04-02	日本ゼオン株式会社	保存安定性と加工性に優れるアクリルゴムシート
WO2021014791A1 (ja) *	2019-07-19	2021-01-28	日本ゼオン株式会社	保存安定性と加工性に優れるアクリルゴムシート
JP7293997B2 (ja) *	2019-08-30	2023-06-20	日本ゼオン株式会社	合成ゴムの製造方法
JP2021036007A (ja) *	2019-08-30	2021-03-04	日本ゼオン株式会社	合成ゴムの製造方法
KR20220063149A (ko) *	2019-09-12	2022-05-17	가부시키가이샤 오사카소다	아크릴 고무의 제조 방법
KR20220161550A (ko) *	2020-03-31	2022-12-06	가부시키가이샤 오사카소다	아크릴 공중합체, 아크릴 공중합체 함유 조성물 및 그 가교물
CN116034116B (zh) *	2020-06-05	2024-03-26	日本瑞翁株式会社	辊加工性、强度特性以及耐水性优异的丙烯酸橡胶
KR20230019825A (ko) *	2020-06-05	2023-02-09	니폰 제온 가부시키가이샤	롤 가공성, 강도 특성 및 내압축영구변형 특성이 우수한 아크릴 고무
CN116057085A (zh) *	2020-06-05	2023-05-02	日本瑞翁株式会社	辊加工性、班伯里加工性、耐水性、强度特性以及耐压缩永久变形性优异的丙烯酸橡胶
JPWO2021261214A1 (ja) *	2020-06-23	2021-12-30
WO2022070902A1 (ja) *	2020-09-30	2022-04-07	株式会社大阪ソーダ	アクリルゴム組成物およびゴム架橋物

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JPS5947698B2 (ja) *	1975-06-17	1984-11-21	鐘淵化学工業株式会社	合成樹脂粉末の粉体特性改良法
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JP2008274084A (ja) *	2007-04-27	2008-11-13	Dic Corp	樹脂水性分散体
JP5163390B2 (ja) *	2008-09-22	2013-03-13	日本ゼオン株式会社	アクリルゴム

2017
- 2017-10-30 JP JP2018506446A patent/JP6394834B1/ja active Active
- 2017-10-30 WO PCT/JP2017/039180 patent/WO2018079786A1/ja not_active Ceased
- 2017-10-30 TW TW106137448A patent/TW201817802A/zh unknown
2018
- 2018-08-29 JP JP2018160497A patent/JP6930952B2/ja active Active
2020
- 2020-02-19 JP JP2020026292A patent/JP7010318B2/ja active Active

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CN113412284A (zh) *	2019-03-29	2021-09-17	株式会社大阪曹達	丙烯酸酯橡胶的制造方法
TWI837378B (zh) *	2019-07-19	2024-04-01	日商日本瑞翁股份有限公司	儲存穩定性與加工性優異的丙烯酸橡膠塊體及其製造方法、橡膠混合物以及橡膠交聯物

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Publication number	Publication date
JP6930952B2 (ja)	2021-09-01
JP2020097754A (ja)	2020-06-25
JPWO2018079786A1 (ja)	2018-10-25
JP6394834B1 (ja)	2018-09-26
WO2018079786A1 (ja)	2018-05-03
JP7010318B2 (ja)	2022-01-26
JP2019031672A (ja)	2019-02-28

Publication	Publication Date	Title
TW201817802A (zh)	2018-05-16	丙烯酸橡膠之製造方法、丙烯酸橡膠組成物之製造方法以及橡膠交聯物之製造方法
CN111989347B (zh)	2024-03-08	丙烯酸橡胶的制造方法以及通过该制造方法得到的丙烯酸橡胶
KR102524865B1 (ko)	2023-04-21	아크릴 고무의 제조 방법
JP6696583B2 (ja)	2020-05-20	アクリルゴムおよびゴム架橋物
TW201817748A (zh)	2018-05-16	丙烯酸橡膠之製造方法、丙烯酸橡膠組成物之製造方法以及橡膠交聯物之製造方法
TW201817801A (zh)	2018-05-16	丙烯酸橡膠及其製造方法、丙烯酸橡膠組成物以及橡膠交聯物
TWI810288B (zh)	2023-08-01	丙烯酸橡膠的製造方法、丙烯酸橡膠、橡膠組成物、橡膠交聯物
JP6753429B2 (ja)	2020-09-09	アクリルゴムの製造方法、および、その製造方法により得られるアクリルゴム
JP6696584B2 (ja)	2020-05-20	アクリルゴムおよびその製造方法
JP6753431B2 (ja)	2020-09-09	アクリルゴムの製造方法、ならびに、その製造方法により得られるアクリルゴム、ゴム組成物、及びゴム架橋物
JP2019194326A (ja)	2019-11-07	耐水性に優れるアクリルゴムの製造
JP6753430B2 (ja)	2020-09-09	アクリルゴムの製造方法
JP7155594B2 (ja)	2022-10-19	アクリルゴムの製造方法

TW201817802A - 丙烯酸橡膠之製造方法、丙烯酸橡膠組成物之製造方法以及橡膠交聯物之製造方法 - Google Patents

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