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TW201815479A - Nozzle device capable of ejecting carbon dioxide particles and lubricant - Google Patents

Nozzle device capable of ejecting carbon dioxide particles and lubricant Download PDF

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Publication number
TW201815479A
TW201815479A TW105134516A TW105134516A TW201815479A TW 201815479 A TW201815479 A TW 201815479A TW 105134516 A TW105134516 A TW 105134516A TW 105134516 A TW105134516 A TW 105134516A TW 201815479 A TW201815479 A TW 201815479A
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Taiwan
Prior art keywords
pipe
tube
outlet
outer tube
nozzle device
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TW105134516A
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Chinese (zh)
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TWI605875B (en
Inventor
許文憲
劉奇泳
林達閔
曹凱傑
林明哲
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哈伯精密股份有限公司
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Priority to TW105134516A priority Critical patent/TWI605875B/en
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Publication of TWI605875B publication Critical patent/TWI605875B/en
Publication of TW201815479A publication Critical patent/TW201815479A/en

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Abstract

A nozzle device includes an outer tube for delivering compressed gas, a sleeve tube disposed in the outer tube for delivering compressed gas, a lubricating tube disposed in the outer tube for delivering lubricant, and a cooling tube disposed in the sleeve tube for delivering carbon dioxide. The length of the cooling tube is smaller than the length of the sleeve tube, so that the carbon dioxide entering the sleeve tube can generate particles due to phase change, and is ejected together with the compressed gas of the sleeve tube to the outside. The length of the lubricating tube is less than the length of the outer tube so as to allow the lubricant entering the outer tube to be ejected from the outlet to the outside with the compressed gas in the outer tube. In this way, in the cutting process, not only can carbon dioxide particles and lubricants be ejected to achieve the effects of cooling, cleaning and lubrication, but also a sleeve type design can be used to converge the tubes to increase space efficiency and strengthen the structural stability, and then increase the ejection speed.

Description

噴嘴裝置Nozzle device

本發明是有關於一種噴嘴裝置,特別是指一種能夠噴灑二氧化碳顆粒與潤滑劑的噴嘴裝置。The invention relates to a nozzle device, in particular to a nozzle device capable of spraying carbon dioxide particles and a lubricant.

參閱圖1,以中華民國專利第I377987號案的雪花形成裝置1為例,主要包含用於形成二氧化碳雪花的一個雪花形成腔室11,及連接該雪花形成腔室11且管徑小於該雪花形成腔室11的一個套管12。藉此,依據流量=截面積Ï速度,在相同的流量下,截面積小、速度提升,而利用截面積漸縮的設計,提升二氧化碳雪花噴射至外界的速度,及利用該套管12可替換的設計,控制二氧化碳雪花之粒徑大小。Referring to FIG. 1, taking the snowflake forming device 1 of the Republic of China Patent No. I377987 as an example, it mainly includes a snowflake forming chamber 11 for forming a carbon dioxide snowflake, and a snowflake forming chamber 11 connected to the snowflake forming chamber 11 and having a smaller pipe diameter than the snowflake forming. A sleeve 12 of the chamber 11. Based on this, according to the flow rate = cross-sectional area Ï speed, the cross-sectional area is small and the speed is increased at the same flow rate, and the design of the cross-sectional area is gradually reduced to increase the speed of the carbon dioxide snowflake spray to the outside, and the sleeve 12 is used to replace Design to control the particle size of carbon dioxide snowflakes.

惟,由於前述套管12是另外設置的元件,在二氧化碳雪花速度提升的情形下,必須考慮連接時的穩固性,才不會有鬆脫的危險。因此,若該套管12與該雪花形成腔室11固接,則要控制顆粒大小時,就要整組替換,若該套管12與該雪花形成腔室11套接,則雪花速度會受限於前述套接的方式(就專利而言,固接或套接技術手段太多種,僅會以固接或套接涵蓋所有可能的實施方式,因此,前案說明書也沒限制是那一種,但不管是那一種,前已提及固接或套接二種方式的缺點),而不能太快,否則有容易脫落的缺點。However, since the sleeve 12 is a separate component, when the speed of the carbon dioxide snowflake is increased, the stability during connection must be considered so that there is no danger of loosening. Therefore, if the sleeve 12 is fixedly connected to the snowflake-forming cavity 11, the entire group is replaced when the particle size is to be controlled. If the sleeve 12 is sleeved with the snowflake-forming cavity 11, the speed of the snowflake will be affected. Limited to the aforementioned socketing method (in terms of patents, there are too many technical methods of fixing or socketing, and only possible methods are covered by fixing or socketing. Therefore, the description of the previous case is not limited to which one, But no matter which one, the disadvantages of the two methods of fixing or socketing have been mentioned before), but not too fast, otherwise it has the disadvantage of being easy to fall off.

因此,本發明之目的,即在提供一種能夠同時達到冷卻、清潔、潤滑的效果,及提升空間效益與噴出速度的噴嘴裝置。Therefore, an object of the present invention is to provide a nozzle device capable of simultaneously achieving the effects of cooling, cleaning, and lubricating, and improving space efficiency and ejection speed.

於是,本發明噴嘴裝置,包含一個外管、一個套管、一個冷卻管,及一個潤滑管。Therefore, the nozzle device of the present invention includes an outer tube, a sleeve, a cooling tube, and a lubrication tube.

該外管包括界定出一條通道的一個圍繞壁,該通道適用於輸送壓縮氣體,該圍繞壁具有形成在一端的一個出口。The outer tube includes a surrounding wall defining a passage suitable for conveying compressed gas, the surrounding wall having an outlet formed at one end.

該套管穿置在該外管內,包括界定出一條管道的一個管壁,該管道適用於輸送壓縮氣體,該管壁具有形成在一端且鄰近該出口的一個端口。The sleeve is inserted into the outer pipe and includes a pipe wall defining a pipe suitable for conveying compressed gas, the pipe wall having a port formed at one end and adjacent to the outlet.

該冷卻管穿置在該套管內,且長度小於該套管,並包括輸出二氧化碳的一個冷卻出口,使進入該套管中的二氧化碳因為相變化產生顆粒,及隨該套管中的壓縮氣體由該套管的端口經該外管的出口噴射至外界。The cooling pipe passes through the casing and is shorter than the casing, and includes a cooling outlet for outputting carbon dioxide, so that the carbon dioxide entering the casing generates particles due to phase change, and the compressed gas in the casing Sprayed from the port of the sleeve to the outside through the outlet of the outer tube.

該潤滑管穿置在該外管內,且長度小於該外管,並包括輸出潤滑劑的一個潤滑出口,使進入該外管中的潤滑劑隨該外管中的壓縮氣體由該出口噴射至外界。The lubricating tube is inserted in the outer tube, and is shorter than the outer tube, and includes a lubricating outlet for outputting lubricant, so that the lubricant entering the outer tube is sprayed from the outlet to the compressed gas in the outer tube. external.

本發明之功效在於:在切削製程中,不但可以藉由噴出的二氧化碳顆粒與潤滑劑,達到冷卻、清潔、潤滑的效果,且能夠利用穿套式設計,匯整管路而提升空間效益,並加強構造的穩固性,而提升噴出速度。The effect of the present invention is that in the cutting process, not only can the cooling, cleaning and lubricating effects be achieved by the sprayed carbon dioxide particles and lubricants, but also the sleeve-through design can be used to consolidate the pipeline to improve space efficiency, and Strengthen the structural stability and increase the ejection speed.

參閱圖2與圖3,本發明噴嘴裝置之一個實施例,包含一個閥座2、一個外管3、一個套管4、一個冷卻管5、一個潤滑管6,及一個壓縮氣體管7。Referring to FIGS. 2 and 3, an embodiment of a nozzle device according to the present invention includes a valve seat 2, an outer pipe 3, a sleeve 4, a cooling pipe 5, a lubrication pipe 6, and a compressed gas pipe 7.

該閥座2包括一個本體21,及設置在該本體21的一個附掛件22。該本體21具有二個導入口211、212,及一個接口213。該附掛件22在本實施例為一個磁性元件,可以吸附在如圖5所示的一個加工機8上。The valve seat 2 includes a body 21 and an attachment member 22 disposed on the body 21. The main body 21 has two inlets 211 and 212 and an interface 213. The attachment 22 is a magnetic element in this embodiment, and can be adsorbed on a processing machine 8 as shown in FIG. 5.

該外管3包括界定出一條通道30的一個圍繞壁31。該通道30適用於輸送壓縮氣體。該圍繞壁31在本實施例為蛇腹管,能夠任意撓動及彎曲,並具有形成在一端的一個出口311、形成在另一端且反向於該出口311的一個入口312、鄰接該入口312的一個管身段313,及鄰接該出口311的一個出口段314。該入口312與該閥座2之本體21的接口213連接。The outer tube 3 includes a surrounding wall 31 defining a channel 30. The passage 30 is suitable for conveying compressed gas. The surrounding wall 31 is a bellows tube in this embodiment, which can be flexed and bent arbitrarily, and has an outlet 311 formed at one end, an inlet 312 formed at the other end opposite to the outlet 311, and abutting the inlet 312 A pipe section 313 and an exit section 314 adjacent to the exit 311. The inlet 312 is connected to an interface 213 of the body 21 of the valve seat 2.

該套管4由該閥座2之本體的導入口211穿置在該外管3內,並包括界定出一條管道40的一個管壁41。該管道40適用於輸送壓縮氣體。該管壁41在本實施例的材質為尼龍直管225PSI ,可以承受15.8kg/cm2的壓力,並具有形成在一端且鄰近該外管3之出口311的一個端口411。The sleeve 4 passes through the inlet 211 of the body of the valve seat 2 in the outer pipe 3 and includes a pipe wall 41 defining a pipe 40. The pipe 40 is suitable for conveying compressed gas. The material of the pipe wall 41 in this embodiment is a nylon straight pipe 225 PSI, which can withstand a pressure of 15.8 kg / cm 2, and has a port 411 formed at one end and adjacent to the outlet 311 of the outer pipe 3.

該冷卻管5穿置在該套管4內,且長度小於該套管4,並包括輸出二氧化碳的一個冷卻出口51。該冷卻出口51與該套管4的端口411間形成有一個間距L。在本實施例中,該間距L界於20mm~30mm,且可以藉由穿置入該套管4內的深度變化,改變前述間距L的大小。The cooling pipe 5 passes through the sleeve 4 and is shorter than the sleeve 4 and includes a cooling outlet 51 for outputting carbon dioxide. A distance L is formed between the cooling outlet 51 and the port 411 of the sleeve 4. In this embodiment, the distance L is within a range of 20 mm to 30 mm, and the size of the foregoing distance L can be changed by changing the depth of penetration into the sleeve 4.

該潤滑管6由該閥座2之本體的導入口212穿置在該外管3內,且長度小於該外管3,並包括輸出潤滑劑的一個潤滑出口61。The lubricating tube 6 is inserted into the outer tube 3 through an inlet 212 of the main body of the valve seat 2 and is shorter than the outer tube 3 and includes a lubricating outlet 61 for outputting lubricant.

該壓縮氣體管7與該閥座2之本體的導入口212連接,且供該潤滑管6穿經,及與壓縮氣體的來源連通,使壓縮氣體進入該通道30內。The compressed gas pipe 7 is connected to the inlet 212 of the main body of the valve seat 2 and passes through the lubrication pipe 6 and communicates with the source of the compressed gas, so that the compressed gas enters the channel 30.

另外,值得說明的是,該外管3之管身段313的最小管徑大於該冷卻管5之管徑D1與該潤滑管6之管徑D2的總和,即D>D1+D2。In addition, it is worth noting that the minimum pipe diameter of the pipe section 313 of the outer pipe 3 is greater than the sum of the pipe diameter D1 of the cooling pipe 5 and the pipe diameter D2 of the lubrication pipe 6, that is, D> D1 + D2.

參閱圖4、圖5,由於一般工具機7都包含有金屬材料,因此,使用時,只需利用該閥座2的附掛件22,將本體21吸附在該加工機8上,就可以使本發明之噴嘴裝置獲得定位。Referring to FIG. 4 and FIG. 5, since the general machine tool 7 includes a metal material, when it is used, it is only necessary to use the attachment 22 of the valve seat 2 to adsorb the body 21 on the processing machine 8 to make the machine tool 8 The nozzle device of the invention is positioned.

當壓縮氣體分別注入該外管3之通道30、該套管4之管道40,且液態二氧化碳注入該冷卻管5、該潤滑劑注入該潤滑管6時,進入該套管4之管道40中的二氧化碳,會因為容積變大而產生的壓差,發生相變化並產生顆粒,形成氣態-固態共存的二氧化碳,且二氧化碳顆粒會在該間距L的行程中愈滾愈大,也就是說,該間距L愈短,無法有效形成顆粒,該間距L愈長,則形成的顆粒會愈大,但太長會致使顆粒過大而堵塞該套管4的端口411,然後,前述二氧化碳顆粒會隨該套管4中的壓縮氣體快速的由該套管4的端口411經該外管3的出口311噴射至外界。When the compressed gas is injected into the channel 30 of the outer pipe 3 and the pipe 40 of the bushing 4, and the liquid carbon dioxide is injected into the cooling pipe 5, and the lubricant is injected into the lubrication pipe 6, the Carbon dioxide, due to the pressure difference caused by the larger volume, undergoes phase changes and generates particles, forming gas-solid coexisting carbon dioxide, and the carbon dioxide particles will roll larger and larger in the distance of the distance L, that is, the distance The shorter L is, the particles cannot be formed effectively. The longer the distance L is, the larger the particles are formed, but too long will cause the particles to be too large and block the port 411 of the casing 4. Then, the carbon dioxide particles will follow the casing. The compressed gas in 4 is rapidly injected from the port 411 of the sleeve 4 to the outside through the outlet 311 of the outer tube 3.

同時,該外管3中的潤滑劑,也會隨該外管3中的壓縮氣體,與前述氣態-固態二氧化碳混合後,由該出口311噴射至外界。At the same time, the lubricant in the outer tube 3 is also injected with the compressed gas in the outer tube 3 and the aforementioned gaseous-solid carbon dioxide, and then injected to the outside through the outlet 311.

由於該套管4與該外管3中的壓縮氣體,會對二氧化碳顆粒形成極大的推力,因此,在切削製程中,可以藉由噴射出的二氧化碳顆粒,將工件表面的粉屑帶走,達到冷卻、清潔的效果,且同時噴射出的潤滑劑,也可以達到潤滑效果。藉此,可以提升該加工機8之刀具壽命與工件表面的光滑度。Since the compressed gas in the sleeve 4 and the outer tube 3 will form a great thrust to the carbon dioxide particles, during the cutting process, the carbon dioxide particles can be ejected to remove the dust on the surface of the workpiece to achieve The cooling and cleaning effect, and the lubricant sprayed out at the same time, can also achieve the lubrication effect. Thereby, the tool life of the processing machine 8 and the smoothness of the workpiece surface can be improved.

經由以上的說明,可將前述實施例的優點歸納如下:Through the above description, the advantages of the foregoing embodiments can be summarized as follows:

1、該套管4兼具有兩個功能,其中一個功能是該套管4中有壓縮氣體,可以做為二氧化碳離開該冷卻管5後,加速朝該外管3之出口311前進的推力,另一個功能是可藉由管徑變大,做為使二氧化碳產生顆粒的生成空間。1. The sleeve 4 has two functions, one of which is that there is compressed gas in the sleeve 4, which can be used as carbon dioxide to leave the cooling pipe 5 and accelerate the thrust toward the outlet 311 of the outer pipe 3, Another function is that the diameter of the pipe can be enlarged as a space for generating carbon dioxide particles.

2、本發明能夠利用穿套式設計,匯整冷卻管5、潤滑管6而提升空間效益,並加強構造的穩固性,進而能夠在滿足穩固性需求的情形下,利用壓縮氣體提升二氧化碳之顆粒的噴出速度。2. The present invention can use a sleeve-through design to integrate cooling pipes 5 and lubricating pipes 6 to improve space efficiency, and strengthen the stability of the structure, and then can use compressed gas to increase the carbon dioxide particles under the situation of meeting the stability requirements. Squirting speed.

3、且只需改變該冷卻管5穿置入該套管4內的深度,就可以改變間距L的大小,進而控制二氧化碳的顆粒大小,不但組裝方便,且成本較低。3. And only by changing the depth that the cooling pipe 5 penetrates into the sleeve 4, the size of the distance L can be changed, and the particle size of carbon dioxide can be controlled, which is not only easy to assemble, but also has low cost.

4、另外,由於該外管3之通道30內的內部壓力大於外界壓力,因此,該通道30內與外界所形成的壓差,並不會造成二氧化碳顆粒,或是潤滑劑回流的問題。4. In addition, since the internal pressure in the channel 30 of the outer tube 3 is greater than the external pressure, the pressure difference between the channel 30 and the outside will not cause the problem of carbon dioxide particles or lubricant backflow.

惟以上所述者,僅為本發明之實施例而已,當不能以此限定本發明實施之範圍,凡是依本發明申請專利範圍及專利說明書內容所作之簡單的等效變化與修飾,皆仍屬本發明專利涵蓋之範圍內。However, the above are only examples of the present invention. When the scope of implementation of the present invention cannot be limited in this way, any simple equivalent changes and modifications made in accordance with the scope of the patent application and the content of the patent specification of the present invention are still Within the scope of the invention patent.

2‧‧‧閥座 2‧‧‧Valve seat

21‧‧‧本體 21‧‧‧ Ontology

211‧‧‧導入口 211‧‧‧Inlet

212‧‧‧導入口 212‧‧‧Inlet

213‧‧‧接口 213‧‧‧Interface

22‧‧‧附掛件 22‧‧‧ Attached

3‧‧‧外管 3‧‧‧ Outer tube

30‧‧‧通道 30‧‧‧channel

31‧‧‧圍繞壁 31‧‧‧ around the wall

311‧‧‧出口 311‧‧‧Exit

312‧‧‧入口 312‧‧‧Entrance

313‧‧‧管身段 313‧‧‧ tube body

314‧‧‧出口段 314‧‧‧Exit

4‧‧‧套管 4‧‧‧ Casing

40‧‧‧管道 40‧‧‧pipe

41‧‧‧管壁 41‧‧‧pipe wall

411‧‧‧端口 411‧‧‧Port

5‧‧‧冷卻管 5‧‧‧ cooling pipe

51‧‧‧冷卻出口 51‧‧‧cooling outlet

6‧‧‧潤滑管 6‧‧‧Lubrication tube

61‧‧‧潤滑出口 61‧‧‧Lubrication outlet

7‧‧‧壓縮氣體管 7‧‧‧ compressed gas tube

8‧‧‧工具機 8‧‧‧tool machine

L‧‧‧間距 L‧‧‧ pitch

D‧‧‧最小管徑 D‧‧‧minimum pipe diameter

D1‧‧‧管徑 D1‧‧‧ diameter

D2‧‧‧管徑 D2‧‧‧ diameter

本發明之其他的特徵及功效,將於參照圖式的實施方式中清楚地呈現,其中: 圖1是中華民國專利第I377987號案的一個剖視示意圖; 圖2是一個正視圖,說明本發明噴嘴裝置的一個實施例; 圖3是該實施例之一個不完整的剖視圖; 圖4是類似圖3之一個不完整的剖視圖,說明噴射出二氧化碳顆粒與潤滑劑的狀態;及 圖5是該實施例安裝在一個加工機的一個正視示意圖。Other features and effects of the present invention will be clearly presented in the embodiment with reference to the drawings, in which: FIG. 1 is a schematic cross-sectional view of the Republic of China Patent No. I377987; FIG. 2 is a front view illustrating the present invention An embodiment of the nozzle device; FIG. 3 is an incomplete cross-sectional view of the embodiment; FIG. 4 is an incomplete cross-sectional view similar to FIG. 3, illustrating a state in which carbon dioxide particles and a lubricant are ejected; and FIG. 5 is the implementation A schematic front view of the example installed on a processing machine.

Claims (9)

一種噴嘴裝置,包含: 一個外管,包括界定出一條通道的一個圍繞壁,該通道適用於輸送壓縮氣體,該圍繞壁具有形成在一端的一個出口; 一個套管,穿置在該外管內,包括界定出一條管道的一個管壁,該管道適用於輸送壓縮氣體,該管壁具有形成在一端且鄰近該出口的一個端口; 一個冷卻管,穿置在該套管內,且長度小於該套管,並包括輸出二氧化碳的一個冷卻出口,使進入該套管中的二氧化碳因為相變化產生顆粒,及隨該套管中的壓縮氣體由該套管的端口經該外管的出口噴射至外界;及 一個潤滑管,穿置在該外管內,且長度小於該外管,並包括輸出潤滑劑的一個潤滑出口,使進入該外管中的潤滑劑隨該外管中的壓縮氣體由該出口噴射至外界。A nozzle device includes: an outer tube including a surrounding wall defining a channel, the channel is suitable for conveying compressed gas, the surrounding wall has an outlet formed at one end; a sleeve is inserted in the outer tube Including a pipe wall defining a pipe suitable for conveying compressed gas, the pipe wall having a port formed at one end and adjacent to the outlet; a cooling pipe passing through the casing and having a length less than The casing includes a cooling outlet for outputting carbon dioxide, so that the carbon dioxide entering the casing generates particles due to phase change, and the compressed gas in the casing is injected from the port of the casing to the outside through the outlet of the outer tube And a lubricating tube inserted into the outer tube and having a length shorter than the outer tube, and including a lubricating outlet for outputting lubricant, so that the lubricant entering the outer tube is removed by the compressed gas in the outer tube from the The exit jets to the outside world. 如請求項1所述的噴嘴裝置,其中,該外管的圍繞壁還具有形成在另一端且反向於該出口的一個入口、鄰接該入口的一個管身段,及鄰接該出口的一個出口段,該外管之管身段的最小管徑大於該冷卻管之管徑與該潤滑管之管徑的總和。The nozzle device according to claim 1, wherein the surrounding wall of the outer pipe further has an inlet formed at the other end and opposite to the outlet, a tube section adjacent to the inlet, and an outlet section adjacent to the outlet The minimum pipe diameter of the pipe section of the outer pipe is greater than the sum of the pipe diameter of the cooling pipe and the pipe diameter of the lubrication pipe. 如請求項1所述的噴嘴裝置,其中,該外管為蛇腹管,可任意撓動及彎曲。The nozzle device according to claim 1, wherein the outer tube is a bellows tube and can be flexed and bent arbitrarily. 如請求項1所述的噴嘴裝置,其中,該冷卻管的冷卻出口與該套管的端口間形成有一個間距。The nozzle device according to claim 1, wherein a distance is formed between a cooling outlet of the cooling pipe and a port of the sleeve. 如請求項4所述的噴嘴裝置,其中,該間距界於20mm~40mm。The nozzle device according to claim 4, wherein the pitch is within a range of 20 mm to 40 mm. 如請求項1所述的噴嘴裝置,還包含有一個閥座,且該外管的圍繞壁還具有形成在另一端且反向於該出口的一個入口,該閥座包括一個本體,該本體具有二個導入口,及一個接口,該等導入口分別供該冷卻管、該潤滑管穿經,該接口與該外管入口連接。The nozzle device according to claim 1, further comprising a valve seat, and the surrounding wall of the outer pipe further has an inlet formed at the other end and opposite to the outlet, the valve seat including a body, the body having Two inlets and one interface are provided for the cooling pipe and the lubrication pipe to pass through respectively, and the interface is connected to the outer pipe inlet. 如請求項6所述的噴嘴裝置,其中,該閥座還包括一個附掛件,該附掛件設置在該本體,且適用將該閥座附掛在一個加工機上。The nozzle device according to claim 6, wherein the valve seat further includes an attachment member, the attachment member is disposed on the body, and is adapted to attach the valve seat to a processing machine. 如請求項7所述的噴嘴裝置,其中,該附掛件為一磁性元件,適用將該本體吸附在該加工機上。The nozzle device according to claim 7, wherein the attachment is a magnetic element, and the body is adapted to be adsorbed on the processing machine. 如請求項6所述的噴嘴裝置,還包含與該閥座之本體供該潤滑管穿經的導入口連接,且與壓縮氣體的來源連通,使壓縮氣體進入該通道內。The nozzle device according to claim 6, further comprising an inlet connected to the body of the valve seat through which the lubrication tube passes, and is in communication with the source of the compressed gas, so that the compressed gas enters the channel.
TW105134516A 2016-10-26 2016-10-26 Nozzle device TWI605875B (en)

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US5725154A (en) * 1995-08-18 1998-03-10 Jackson; David P. Dense fluid spray cleaning method and apparatus
HUE06751815T2 (en) * 2005-04-29 2017-04-28 Univ Michigan Regents Method for Lubricating Metal based on Supercritical Carbon Dioxide
US7389941B2 (en) * 2005-10-13 2008-06-24 Cool Clean Technologies, Inc. Nozzle device and method for forming cryogenic composite fluid spray
US9221067B2 (en) * 2013-06-18 2015-12-29 Cleanlogic Llc CO2 composite spray method and apparatus
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