TW201739444A - Hair cosmetic - Google Patents

Abstract

The present invention comprises components (A) through (C). The content of component (A) is 0.1 to 10 mass%, the total content of component (B) and component (C) is 30 mass% or greater, and the mass ratio (B)/(C) of component (B) and component (C) is 0.8 to 99. (A) is a polymer for a hair cosmetic that is soluble or dispersible in water or ethanol, (B) is a C1-4 monohydric alcohol, and (C) is a silicone oil having a number-average molecular weight of 100 to 1500.

Description

Hair cosmetic

The present invention relates to a hair cosmetic.

In recent years, the hairstyles that consumers expect are changing. Therefore, the performance required for the hair styling agent is also free from the use of the adhesive polymer or the film-forming polymer to fix the hair to maintain a natural tidy feeling and the touch of the hair after the care is soft and natural. In particular, women have recently demanded a hair styling agent that has no sticky touch, a natural appearance without a bundle, and a comb that is well combed and keeps the hair tidy. In response to such a demand, there is a non-aqueous hair cosmetic, particularly a product generally called a hair oil, but there is a problem in that oil is present in the product due to oil contained in the product, and is applied to the hair during application and after application. The sliding sensation lasts for a while, and there is an unnatural hair sensation left. After the smear, the appearance or feel of the hair is heavier and feels sticky. In order to eliminate the above problems of the hair oil, for example, Patent Document 1 discloses a hair oil which is used by combining a polyether modified anthrone of a specific structure with a volatile oil and ethanol. This document discloses that the hair oil removes greasy feeling shortly after application, and has good hair wettability and improves dryness over time. On the other hand, non-aqueous hair cosmetics have various uses in addition to hair care products. Patent Document 2 discloses a bifurcated hair spreader comprising an organic solvent, a volatile oil, and a specific dimethyl polyoxyalkylene derivative. This document discloses that the bifurcated hair spreader can cover the split hair without stickiness and is easy to rinse. (Patent Document 1) Japanese Patent Laid-Open Publication No. 2011-195471 (Patent Document 2) Japanese Patent Laid-Open No. Hei 8-40839

The present invention provides a hair cosmetic comprising the following components (A) to (C), wherein the content of the component (A) is 0.1% by mass or more and 10% by mass or less, and the total of the component (B) and the component (C) The content is 30% by mass or more, and the mass ratio (B)/(C) of the component (B) to the component (C) is 0.8 or more and 99 or less. (A): a polymer for hair cosmetic having solubility or dispersibility in water or ethanol (B): a monohydric alcohol having 1 to 4 carbon atoms (C): an anthrone having a number average molecular weight of 100 or more and 1,500 or less oil

When the hair oil of Patent Document 1 is applied to the wet hair after shampooing, it can impart a tidy feeling or a conditioning effect after drying, but when applied to dry hair, uneven application is still caused, so that after drying The problem of insufficient uniformity or poor touch. Further, if a sufficient amount is applied to uniformly coat the entire hair, there is also a problem that the hair feels heavy or the hair bundle feels after drying. Further, it is considered that the bifurcated hair styling agent of Patent Document 2 preferably contains 10 to 50% by weight, particularly 20 to 40% by weight, of the dimethyl polyoxane derivative in the entire composition in order to coat the bifurcated hair. Therefore, after drying, a large amount of the dimethyl polysiloxane derivative remaining on the hair causes the hair to feel heavy or hairy, and it is difficult to obtain a dry touch. Accordingly, the present invention relates to a hair cosmetic which has good wet spreadability when applied to dry hair and which dries immediately after application without causing dryness or moist feeling of the hair, and does not form a tuft after drying. The hair can be kept in a natural uniformity. The inventors of the present invention considered that the problem of the above nonaqueous hair cosmetic is mainly due to insufficient wet spreadability on dry hair and time consuming for volatilization of volatile oil after application. As a result, it has been found that when a specific ketone oil and a lower alcohol are set to a specific ratio, the surface tension of the solvent is remarkably increased, and the hair cosmetic applied to the hair spontaneously moves on the surface of the hair, and at the same time, the polymerization is contained. The object covers the surface of the hair. Further, it has been found that the polymer component contained can be quickly and evenly applied to the surface of the hair, thereby drying extremely quickly, so that the feeling of the hair cosmetic on the hair disappears shortly after application, and the hair after drying is kept neat. , thus completing the invention. The hair cosmetic of the present invention spontaneously moves on the surface of the hair of dry hair and dries quickly. Therefore, the polymer in the hair cosmetic material spreads quickly and evenly on the surface of the hair, and the feeling of the hair cosmetic material disappears rapidly after application, and there is no unnatural hairiness, the hand feel is not sticky, and the natural tidyness is imparted. degree. Further, there is no dry feeling or sticky feeling when applied, and there is no wet feeling of hair. [Component (A): Polymer for hair cosmetic having solubility or dispersibility in water or ethanol] Component (A) is a polymer which is dissolved or stably dispersed in water or ethanol even without using a surfactant. And it can be stably present in a component such as the component (B) having a polar solvent. This component (A) is a component which is uniformly applied to the surface of the hair by the constitution of the present invention, thereby imparting a natural sense of neatness or a natural touch to the hair without feeling the presence of the polymer. As such a polymer for hair cosmetic which has solubility or dispersibility in water or ethanol, a film-forming polymer or a polyether-modified anthrone is preferable. From the viewpoint of further enhancing the feeling of uniformity, it is preferred to use a film-forming polymer as the component (A). The film-forming polymer which can be used as the component (A) is not particularly limited as long as it has solubility or dispersibility in water or ethanol, and can be used in a case where the fixing force is generally higher for the hair styling agent. Any of the relatively low setting forces. Examples of such a film-forming polymer include an anthrone-based graft polymer, an urethane-based polymer compound, a polyvinylpyrrolidone-based polymer compound, an anionic vinyl ether-based polymer compound, and an anion. Polyvinyl acetate polymer compound, anionic (meth)acrylic polymer compound, amphoteric (meth)acrylic polymer compound, nonionic (meth)acrylic polymer compound, cationic (A An acrylic polymer compound or a maleimide polymer compound. Examples of the anthrone-based graft polymer include poly(N-methyl decylethylidene) organopolyoxyalkylene, poly(N-ethyl fluorenylethylenimine) organopolyoxy siloxane, and poly( N-propionyl extended ethyl imine) polyoxafluorone-9 such as organopolyoxyalkylene; organopolyoxyalkylene graft polymer described in International Publication No. 2014/002707; KP-545 (Shin-Etsu Chemical Industry Co., Ltd.) and other alkyl acrylate copolymers such as methyl polyoxyalkylene ester; Silsoft Spread TT (Momentive) and other polyketone-17; Luviflex Silk (BASF) and other alkyl acrylates and methacrylic acid・Anthrone copolymers, etc. Among these, in terms of stereotype, no stickiness when dry, softness after application, and combability after application, it is more preferable to be a poly(N-methylstilbeneethylenimine) organic polyfluorene. Polyoxanone, poly(N-ethyl fluorenylethylenimine), organopolyoxyalkylene, poly(N-propionylethylidene), organopolyoxyalkylene, polyketone-9, polyfluorenone-28 An alkyl polyoxyalkylene acrylate copolymer such as an organopolyoxane graft polymer described in International Publication No. 2014/002707 or KP-545 (Shin-Etsu Chemical Co., Ltd.). Examples of the urethane-based polymer compound include polyurethanes such as Luviset PUR (BASF Japan) and polyurethane-14 AMP-acrylate copolymers such as DynamX (AkzoNobel Co., Ltd.). . Examples of the polyvinylpyrrolidone-based polymer compound include Luviskol K12, Luviskol K17, Luviskol K30, Luviskol L60, Luviskol K80, Luviskol K90 (BASF); PVP K15, PVP K17, PVP K30, PVP K60, PVP. Polyvinylpyrrolidone such as K90, PVP K120 (above Ashland); Luviskol VA28, Luviskol VA37, Luviskol VA55, Luviskol VA64P, Luviskol VA73 (above BASF); Luviskol Plus (BASF) and other polyethylene Indoleamine; PVP/VA E-735, PVP/VA E-635, PVP/VA E-535, PVP/VA E-335, PVP/VA S-630, PVP/VA W-735 (above is Ashland (Vinyl pyrrolidone/vinyl acetate) copolymer; polyvinylpyrrolidone/vinyl acetate/vinyl propionate terpolymer such as Luviskol VAP343 (BASF); Luviflex (BASF); Copolymer 845, Copolymer 937, Copolymer 958 (above Ashland) and other polyvinylpyrrolidone / dimethylaminomethyl / acrylic copolymer; Copolymer VC-713 (Ashland) and other polyvinylpyrrolidone / A Dimethylaminoethyl acrylate/vinyl caprolactam copolymer; Lu Viset Clear (BASF) and other (VP/methacrylamide/vinylimidazole) copolymer; Luviquat HM552 (BASF) and other vinyl imidazolium methyl chloride/vinyl pyrrolidone copolymer. Among these, it is more preferably (vinylpyrrolidone/vinyl acetate) copolymerization from the viewpoint of smoothness, setting property, no stickiness when dry, and softness after application just after application. , polyvinylpyrrolidone. Examples of the anionic vinyl ether-based polymer compound include a (vinyl vinyl ether/maleic acid ethyl ester) copolymer such as Gantrez ES-225 (Ashland Corporation), and Gantrez ES-425 (Ashland Corporation) (ethylene). Methyl ether / butyl maleate copolymer, and the like. Among these, a (vinyl methyl ether/butyl methacrylate) copolymer is preferred from the viewpoints of stereotype, no stickiness upon drying, and softness after application. Examples of the anionic polyvinyl acetate-based polymer compound include vinyl acetate/butenoic acid copolymers such as Resin 28-1310 (AkzoNobel Co., Ltd.) and Luviset CA66 (BASF Co., Ltd.); and Resin 28-2930 (Akzo Nobel Co., Ltd.). (vinyl acetate/crotonic acid/vinyl neodecanoate) copolymer; vinyl acetate/butenoic acid/vinyl propionate copolymer such as Luviset CAP (BASF). Examples of the anionic (meth)acrylic polymer compound include acrylic resin alkanolamine liquids such as Plas-size L-53P and Plas-size L-9540B (above, Mutual Chemical Industry Co., Ltd.); Diahold (Mitsubishi) Acrylic acid/acrylic acid ester copolymer; such as acrylic acid/acrylate copolymer; Ultrahold 8, Ultrahold strong (above BASF), or AMPHOMER V-42, DEMACRYL 79 (above AkzoNobel); Aniset NF-1000, Aniset HS-3000 (above, Osaka Organic Chemical Industry Co., Ltd.) and other alkyl acrylate copolymers. Examples of the amphoteric (meth)acrylic polymer compound include Yukaformer M-75, Yukaformer R205, Yukaformer 301, Yukaformer SM (above, Mitsubishi Chemical Corporation), and RAM Resin (Osaka Organic Chemical Co., Ltd.). Oxyethylcarboxybetaine/alkyl methacrylate copolymer; AMPHOMER 28-4910, AMPHOMER LV-71 (above AkzoNobel), etc. (octyl acrylamide/hydroxypropyl acrylate/methacrylic acid butyl Aminoethyl ester) copolymer; AMPHOMER HC (AkzoNobel), etc. (alkyl acrylate/octyl acrylamide) copolymer; DIAFORMER Z-651 (Mitsubishi Chemical Co., Ltd.), etc. (acrylate/lauryl acrylate/ Stearic acid acrylate / ethyl oxyalkyl methacrylate copolymer, and the like. Among these, in terms of stereotype, no stickiness upon drying, and softness after application, (methacryloxyethyl carboxybetaine/alkyl methacrylate) copolymerization is preferred. Things. Examples of the nonionic (meth)acrylic polymer compound include Plas-size L-2700 and Plas-size L-2714 (above, Mutual Chemical Industry Co., Ltd.) (dimethacrylamide/acrylic acid hydroxyl group). Ethyl ester / methoxyethyl acrylate copolymer and the like. Examples of the cationic (meth)acrylic polymer compound include an alkyl acrylamide/acrylate/alkylaminoalkyl acrylamide/polyethylene glycol described in JP-A-2-180911. A methacrylate copolymer; an alkyl acrylamide/alkylaminoalkyl acrylamide/polyethylene glycol methacrylate copolymer described in Japanese Patent Laid-Open No. Hei 8-291206; Plas-size L- 515 (Mujia Chemical Industry Co., Ltd.) and other poly-quaternary ammonium salt-99; Aquaflex SF-40 (Ashland) and other (PVP / vinyl caprolactam / acrylic acid DMAPA) copolymer; STYLEZE CC-10 (Ashland) (vinylpyrrolidone/acrylic acid DMAPA) copolymer; Luviquat PQ11 (BASF), GAFQUAT 734, GAFQUAT 755 (above Ashland) vinylpyrrolidone/dimethylamino methacrylate copolymer The quaternary compound (poly quaternary ammonium salt-11). Among them, an alkyl acrylamide/acrylate/alkylaminoalkyl acrylamide/polyethylene glycol methacrylate copolymer described in Japanese Laid-Open Patent Publication No. Hei No. 2-180911, Japanese Patent Laid-Open An alkyl acrylamide/alkylaminoalkyl decylamine/polyethylene glycol methacrylate copolymer or a polytetra-ammonium salt-11 described in 8-291206. Examples of the maleimide-based polymer compound include copolymerization of isobutylene/ethyl maleimide/hydroxyethyl maleimide, such as Aquaflex FX-64 (ISP Japan). Things. Among these film-forming polymers, an anthrone-based graft polymer or a polyvinylpyrrolidone-based polymer is preferable in terms of setting property, no stickiness during drying, and softness after application. A compound, an anionic polyvinyl acetate-based polymer compound, an amphoteric (meth)acrylic polymer compound, a nonionic (meth)acrylic polymer, and a cationic (meth)acrylic compound. On the other hand, from the viewpoint of having no dry feeling immediately after application and further improving the uniformity after drying, it is preferred to use a polyether-modified anthrone as the component (A). The polyether-modified fluorenone which can be used as the component (A) is not particularly limited as long as it has solubility or dispersibility in water or ethanol, and examples thereof include polyoxyethylene modified fluorenone and polypropylene. The fluorenone, the polyoxyethylene/polyoxypropylene-modified fluorenone, the polyglycerin-modified fluorenone, and the like, and the modified form may, for example, be a side chain type (side chain modified type) or a linear copolymer type. As such a polyether-modified anthrone, a copolymer having a block chain of an organic siloxane chain and a polyalkyl chain is preferable, and examples thereof include Silsoft A+ (Momentive) and the like (PEG-40/PPG- 8 methylaminopropyl/hydroxypropyl dimethyl polyoxyalkylene) copolymer; polyfluorenone-13 such as FZ-2222, FZ-2233, CB2250 (Dow Corning Toray); Silwet L-8600 (Momentive) PEG-12 dimethoxane, such as PEG-12 dimethyl polyoxy siloxane, Silsoft 900 (Momentive), PEG-10 dimethyl polyoxy siloxane such as Silsoft 860 (Momentive); SILSTYLE 104 (Dow) Corning Toray Co., Ltd. (bisisobutyl PEG-14/amino dimethylpolyoxane) copolymer; SILSTYLE 401 (Dow Corning Toray), etc. (bisisobutyl PEG/PPG-20/35/amino group Dimethicone Copolymer; CE-8411 Smooth Plus Emulsion (Dow Corning Toray), etc. Bis-isopropanolamine-PG-propyldimethylpolyoxane/bisisobutyl PEG-14 copolymer A product such as DOW CORNING TORAY SS-3588 (Dow Corning Toray Co., Ltd.) or the like (bisisobutyl PEG-15/aminodimethylpolysiloxane) copolymer. Among them, a copolymer having an amine-modified organopolyoxyalkylene chain and a block chain of a polyoxyalkylene chain is preferred, and more preferably (bisisobutyl PEG-14/amino dimethylpolyoxyl) Copolymer, (bisisobutyl PEG/PPG-20/35/amino dimethylpolyoxyalkylene) copolymer, bis-isopropanolamine-PG-propyl dimethylpolyoxane/double A linear copolymerized amino group/polyether modified anthrone such as an isobutyl PEG-14 copolymer or a (bisisobutyl PEG-15/aminodimethylpolysiloxane) copolymer, and further preferably It is a (bisisobutyl PEG-15/aminodimethylpolyoxane) copolymer. The polymer for hair cosmetic materials may be used singly or in combination of two or more kinds, and it is preferred to form the polymer into the film from the viewpoint of further improving the natural sensation and the natural touch. It is used together with the polyether modified anthrone as the component (A). Further, the component (A) is preferably an amphiphilic film forming property from the viewpoint of imparting a sticky feeling during drying, leaving it thin and evenly on the hair, and further imparting a natural touch and uniformity. Polymer or polyether modified anthrone. The amphiphilic film-forming polymer is a styling polymer containing 10 to 98% of a hydrophobic portion in terms of a mass ratio. Examples of such an amphiphilic styling polymer include polyfluorenone-9 and polyfluorene. Keto-28, especially preferably polyketone-9. The content of the component (A) in the hair cosmetic of the present invention is 0.1% by mass or more, preferably 0.5% by mass or more, and more preferably 1% by mass or more from the viewpoint of imparting uniformity to the hair. In addition, it is 10 mass% or less, preferably 7% by mass or less, and more preferably 5% by mass, from the viewpoint of feeling that the hair feels heavy or does not cause a hairiness, and gives a natural touch and a sense of uniformity. the following. [Component (B): One-to-one carbon of 1 to 4 carbons] The component (B) is controlled by combining with the component (C) to control the wet spreadability of the hair cosmetic containing the component (A) and the drying on the hair. The composition of speed. As the monohydric alcohol having 1 to 4 carbon atoms of the component (B), a saturated or unsaturated aliphatic alcohol can be used. These monohydric alcohols may be used alone or in combination of two or more. The alcohol is preferably ethanol, propanol, isopropanol or tert-butanol, more preferably ethanol or isopropanol, and still more preferably ethanol. The content of the component (B) in the hair cosmetic of the present invention is preferably 45 mass% or more, more preferably 55 mass% or more, and still more preferably 60 mass, from the viewpoint of drying speed and beamlessness. In addition, it is preferably 98% by mass or less, more preferably 90% by mass or less, still more preferably 80% by mass or less, and still more preferably 75% by mass or less from the viewpoint of having no dry feeling after application. [Component (C): Anthrone having a number average molecular weight of 100 or more and 1,500 or less] The component (C) is an anthrone having a number average molecular weight of 100 or more and 1,500 or less, and is controlled by combining with the component (B). A component of the moist spreadability of a cosmetic and the drying speed of the hair cosmetic on the hair. Examples of such an anthrone include cyclic ketones such as octamethylcyclotetraoxane, decamethylcyclopentaoxane, dodecamethylcyclohexaoxane, and methylcyclopolyoxyalkylene. ; octamethyltrioxane, tetradecyl hexaoxane, methyltrimethylpolyoxyalkylene, a dynamic viscosity at 25 ° C, for example, a methyl group of 0.5 mm ² /s or more and 10 mm ² /s or less Chain fluorenone such as polyoxyalkylene. Among them, preferred are decamethylcyclopentaoxane, methyltrimethylpolyoxyalkylene, methyl polyoxyalkylene having an kinetic viscosity at 25 ° C of 0.5 mm ² /s or more and less than 6 mm ² /s. The iso-chain fluorenone is more preferably decamethylcyclopentaoxane or methyltrimethylpolyoxyalkylene. The number average molecular weight of the component (C) is preferably 100 or more, more preferably 150 or more, and still more preferably 200 or more from the viewpoint of good smoothness after application and combability. Further, from the viewpoint of no hairiness after drying and feeling light, it is preferably 1,000 or less, more preferably 700 or less, still more preferably 500 or less. Further, the component (C) is preferably a volatile fluorenone from the viewpoint of lightness after drying or a feeling of no presence of the agent. The volatile fluorenone is a high volatile organic compound, a volatile organic compound defined by WHO (World Health Organization), and an anthrone having a boiling point of 260 ° C or lower. Further, as the volatile fluorenone, those having a boiling point of 50 ° C or higher are preferred. The content of the component (C) in the hair cosmetic of the present invention is preferably 1% by mass or more, more preferably 10% by mass or more, from the viewpoint of good smoothness and combability after application. It is preferably 20% by mass or more, more preferably 25% by mass or more, and is preferably 52% by mass or less, more preferably 45% by mass or less, from the viewpoint of a hairless feeling after drying and feeling light. It is preferably 40% by mass or less, and more preferably 35% by mass or less. Further, the mass ratio (B)/(C) of the component (B) to the component (C) in the hair cosmetic of the present invention is 0.8 or more and 99 or less. Within this range, the hair cosmetic of the present invention has a very high surface tension, so that if applied to the hair, the droplet not only spreads laterally but spontaneously moves from top to bottom on the surface of the hair. It is speculated that the polymer contained in the hair cosmetic material spontaneously and rapidly wets and spreads on the surface of the hair, and the hair cosmetic material is rapidly dried on the surface of the hair. Therefore, it is difficult to form a hair bundle after application, and the presence of the hair cosmetic material quickly disappears, the hand feel is not sticky, and the natural uniformity is imparted. Further, there is no slippery feeling or sticky feeling when applied, and there is no wet feeling of hair. From the viewpoint of further improving the effect, the mass ratio (B)/(C) of the component (B) to the component (C) is preferably 1 or more, more preferably 1.2 or more, still more preferably 1.5 or more, and further preferably It is preferably 2 or more, and is preferably 50 or less, more preferably 30 or less, still more preferably 10 or less, still more preferably 5 or less. In addition, the total content of the component (B) and the component (C) in the hair cosmetic of the present invention is 30% by mass or more, preferably 50%, from the viewpoint of the lightness after drying and the presence of the agent. % or more, preferably 70% by mass or more. Further, it is preferably 99.9% by mass or less, more preferably 99% by mass or less, and still more preferably 98% by mass or less. [Component (D): Stabilizer] The hair cosmetic of the present invention preferably contains a selected from the group consisting of a polyol, a urea, and an organic substance, even if it is stored at a high temperature without separation and can be stably stored. One or two or more kinds of the acid, the polyoxyalkylene alkyl glucoside, and the polyoxyalkylene glyceryl ether are used as the component (D). Preferred examples of the polyhydric alcohol include 1,3-butylene glycol, glycerin, and polyglycerin. Moreover, as a preferable organic acid, lactic acid, malic acid, citric acid, etc. are mentioned. Further, preferred examples of the polyoxyalkylalkyl glucoside include PPG-10 methyl glucose, PPG-20 methyl glucose, methyl glucose 10 ethylene oxide, methyl glucose 20 ethylene oxide, and the like. . Further, preferred examples of the polyoxyalkylene glycol glyceryl ether include PEG/PPG/polybutylene glycol-8/5/3 glycerin. Among them, from the viewpoint of high-temperature storage stability, urea, lactic acid, glycerin, and more preferably urea are preferred. The content of the component (D) in the hair cosmetic of the present invention is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, from the viewpoint of ensuring high-temperature stability, and ensures a natural touch. From the viewpoint of the above, it is preferably 3% by mass or less, and more preferably 2% by mass or less. [Water] The hair cosmetic of the present invention preferably does not contain water. Among them, a small amount to a small amount (for example, 0.0001% by mass or more) of water may be inevitably mixed, and in this case, the amount of water is preferably less. Specifically, the content of moisture is preferably less than 5% by mass, more preferably less than 3% by mass, still more preferably less than 0.5% by mass. [Optional component] In addition to the components described above, the hair cosmetic of the present invention may contain an oil for cosmetics other than the components (A) and (C) within the limits of the effects of the present invention. The content of the oil agent for cosmetics other than the components (A) and (C) in the hair cosmetic is preferably from 0.1 to 10% by mass. Examples of the oil agent for such a cosmetic include glycerides such as castor oil, cocoa butter, eucalyptus oil, avocado oil, and olive oil; waxes such as beeswax, cetyl wax, lanolin, and carnauba wax; and myristic acid. Isopropyl ester, hexyl laurate, cetyl lactate, propylene glycol monostearate, oleic acid oil ester, cetyl 2-ethylhexanoate, ester of octyl dodecyl acid myristate ; dimethyl polysiloxane, methyl phenyl polyoxy siloxane, epoxy modified fluorenone oil, amine modified fluorenone oil, alkyl modified fluorenone oil, etc. In addition to the component (A) or (C ) an anthrone derivative other than those contained in the product. Further, the hair cosmetic of the present invention may contain a perfume or a pigment for enhancing the commercial value, a preservative or an antioxidant for preventing deterioration of the hair cosmetic over time, and further, may optionally contain a surfactant and harden. Agents, antistatic agents, defoamers, dispersants, tackifiers, UV absorbers, antioxidants, preservatives, colored dyes, dye fixatives, propellants, etc. [Formulation] The dosage form of the hair cosmetic of the present invention is not particularly limited, and may be a transparent liquid, a milky, an emulsion, a mist (a makeup spray, a styling spray), a foam (mousse), or the like. Among them, a dosage form to be applied in a mist form is preferred, and a non-aerosol type dosage form is more preferred. Further, in the case of a non-aerosol type, the component (A) is preferably an amphiphilic agent from the viewpoint of excellent dispersibility or solubility in both the component (B) and the component (C). A film-forming polymer or a polyether-modified anthrone. Furthermore, in the case where the hair cosmetic of the present invention is used in the form of an aerosol hair cosmetic containing an aerosol stock solution and a propellant, the content of each component means the overall composition of the aerosol stock solution containing no propellant. The content in the middle. [Whole Hair Method] The hair cosmetic of the present invention can be preferably used as a hair styling agent. As a method of using the hair styling agent, that is, the hair styling method, any method may be employed as long as the hair styling method of the present invention is applied to the hair and the hair styling method is used. The hair cosmetic of the present invention can be applied to wet hair, and can also be applied to dry hair, preferably to dry hair. For example, it is preferred to apply the hair cosmetic directly in a mist form, and to comb the hair shape by combing with a comb or a brush. [Examples] Hereinafter, the present invention will be more specifically described by way of examples. The invention is not limited to the embodiments. [Examples 1 to 6 and Comparative Examples 1 to 5] The hair cosmetics described in Table 1 were prepared by a conventional method, and high-temperature stability and wettability were evaluated in accordance with the following methods and criteria. "High-Temperature Stability Evaluation" Fill 40 mL of the hair cosmetic of Table 1 in a 50 mL glass bottle (Guangkou size bottle PS-N0.6; Sanshang Co., Ltd.), and cover with a lid to seal. This was allowed to stand in a thermostat at 50 ° C for 2 hours. Thereafter, it was taken out from the constant temperature bath, and the form of the hair cosmetic in the glass bottle was visually observed. The evaluation was performed based on the following criteria. A: unseparated B: white turbidity is produced, but if it returns to room temperature, it is restored to a uniform solution C: even if it is returned to room temperature and shaken, it cannot be restored to a uniform solution "wet spreadability evaluation" as a model of dry state of hair. A glass plate (glass plate 100-2a for adsorbent coating, manufactured by AS ONE Co., Ltd.) having a hydrophobic surface of 200 × 200 × 3 mm was used. The glass plate was set at an inclination of 5° (horizontal left and right). 50 μL of each of the hair cosmetic materials described in Table 1 was dropped onto the glass plate from a height of 5 mm using a micropipette (Research Plus V 3120, manufactured by Eppendorf Co., Ltd.), and the distance of liquid movement during this period was measured after one minute. In addition, the hair cosmetic preparations of Table 1 were filled in a pump spray container manufactured by Yoshino Seisakusho Co., Ltd. (a sprayer having an average particle diameter of 60 μm when the hair cosmetics of the examples and the comparative examples were sprayed in a mist form) , performance evaluation based on the following methods and benchmarks. Furthermore, in Comparative Example 4, since the viscosity of the composition was high, it could not be sprayed by means of a sprayer, and the liquid was applied to the hand and applied to the performance evaluation according to the following methods and standards. The method of hair bundles. (Evaluation of hair bundles) A wool with a length of 30 cm and a weight of 8 g was produced using the fragile irregular hair of a Japanese who had not been chemically treated. Apply 3 g of medicinal shampoo h manufactured by Kao Co., Ltd. to the hair bundle, rinse for 30 seconds, and rinse with tap water at 40 °C for 30 seconds. This shampooing operation was repeated twice. Then, 3 g of the sample conditioner shown in the following formulation was applied, and after soaking for 15 seconds, it was rinsed with tap water of 40 ° C for 30 seconds. Then, after drying with a towel, it was naturally dried under laboratory conditions for 6 hours, and the obtained one was used as a hair bundle for evaluation. (Composition of sample rinse) Composition ( % by mass ) Cetearyl alcohol 2.0 Chlorostearyl trimethyl ammonium 0.76 Distearyl dimethyl ammonium chloride 2.7 Propylene glycol 5.0 Isopropyl alcohol 0.6 P-hydroxybenzoic acid Ethyl acetate 0.1 Ion exchange water balance Total 100 (Evaluation method) "Drying speed immediately after application" 0.2 g of each hair cosmetic filled in the pump sprayer was sprayed on the evaluation hair bundle. After spraying, the hair bundle for evaluation was combed by hand 30 times. The drying speed during the carding by hand was evaluated based on the following criteria. The evaluation was performed by seven functional inspectors for which one of "drying faster" / "difficult to evaluate" / "slow drying" was performed when the respective compositions were treated by the above operation. The number of functional inspectors who answered faster/difficult to evaluate/slower drying were displayed in sequence. "The presence or absence of dryness immediately after application" was treated by the same method as "drying speed immediately after application", and the feeling of dryness was repeated for 1 to 10 times by hand, and evaluated based on the following criteria. The evaluation was carried out by seven functional inspectors for which one of the "no dry feeling" / "difficult to evaluate" / "having a dry feeling" was selectively used when the respective compositions were treated by the above operation. The number of functional inspectors who answered no dry feelings/difficult to evaluate/having a sense of dryness were displayed in sequence. "The combing of the rationality just after the application" is handled by the same method as the "drying speed immediately after the application", and the combing is performed smoothly for 1 to 10 times by hand, based on the following criteria. Evaluation. The evaluation was carried out by seven functional inspectors for which one of the "comfortable good" / "difficult to evaluate" / "poor combability" was selected when the respective compositions were treated by the above operation. The number of functional inspectors with good combability/difficulty evaluation/comparable combing is displayed in sequence. "The presence or absence of the sticky feeling when combing by hand" was treated by the same method as "drying speed immediately after application", and the presence or absence of a sticky feeling during hand combing was evaluated based on the following criteria. The evaluation was conducted by seven functional inspectors for which one of the "non-sticky feeling" / "difficult to evaluate" / "sticky feeling" was used when the respective compositions were treated by the above operation. select. The number of functional inspectors with good combability/difficulty evaluation/comparable combing is displayed in sequence. "The presence or absence of the feeling of the hair after drying" was treated by the same method as "the drying speed immediately after the application", and the hand was finished for 3 minutes. Thereafter, the evaluation was carried out based on the following criteria with respect to the presence or absence of a hairiness. The evaluation was carried out by seven functional inspectors for which one of the "hairless beam feeling" / "slightly hairy feeling" / "hairy feeling" was used when the respective compositions were treated by the above operation. Alternative choice. The number of functional inspectors who answered the hairlessness/slightly hairy/hairy feeling was displayed in sequence. The "degree of uniformity after drying" was treated by the same method as "drying speed immediately after application", and after combing by hand, it was left for 3 minutes. Thereafter, the evaluation was performed based on the following criteria with respect to the uniformity. The evaluation was performed by seven functional inspectors for which one of "tidy"/"slightly neat"/"untidy" was used when processing each composition by the above operation. The number of functional inspectors who answered neatly/slightly neat/untidy was displayed in sequence. "The presence or absence of the feeling of the hair styling after drying" was treated by the same method as the "drying speed immediately after application", and after the carding was completed, it was left for 3 minutes. Thereafter, the presence or absence of a hair styling agent, particularly a polymer, on the evaluation hair bundle was evaluated based on the following criteria. The evaluation was performed by seven panelists in accordance with which of the "no sense of presence" / "difficult to evaluate" / "having a sense of presence" when using the respective compositions by the above operation. The number of functional inspectors who answered no sense of presence/difficult to evaluate/have a sense of presence was displayed in sequence. The "comfort of combing after drying" was treated by the same method as "drying speed immediately after application", and after combing by hand, it was left for 3 minutes. Thereafter, the combability of the evaluation hair bundle was evaluated based on the following criteria. The evaluation was carried out by seven functional inspectors for which one of the "comfortable good" / "difficult to evaluate" / "poor combability" was selected when the respective compositions were treated by the above operation. The number of functional inspectors with good combability/difficulty evaluation/comparable combing is displayed in sequence. The "toughness after drying" was treated by the same method as "drying speed immediately after application", and after finishing by hand, it was left for 3 minutes. Thereafter, the combability of the evaluation hair bundle was evaluated based on the following criteria. The evaluation was conducted by seven functional inspectors for which one of the "strongness", "difficult to evaluate", and "no-toughness" was used for the treatment with each composition by the above operation. select. The number of functional inspectors who responded with a strong/hard-to-evaluate/no-toughness was displayed in sequence. [Table 1]

no

Claims (10)

A hair cosmetic comprising the following components (A) to (C), wherein the content of the component (A) is 0.1% by mass or more and 10% by mass or less, and the total content of the component (B) and the component (C) is 30%. The mass ratio (B)/(C) of the component (B) to the component (C) is 0.8 or more and 99 or less, and (A): a hair cosmetic having solubility or dispersibility in water or ethanol. Polymer (B): a monohydric alcohol having 1 to 4 carbon atoms (C): an anthrone oil having a number average molecular weight of 100 or more and 1,500 or less. The hair cosmetic of claim 1, wherein the content of the component (B) is 45 mass% or more and 98 mass% or less. The hair cosmetic of claim 1 or 2, wherein the content of the component (C) is 1% by mass or more and 52% by mass or less. The hair cosmetic of claim 1 or 2, wherein the water content is less than 3% by mass. A hair cosmetic according to claim 1 or 2, wherein the component (A) is a film-forming polymer or a polyether-modified anthrone. The hair cosmetic of claim 1 or 2, wherein the total content of the component (B) and the component (C) is 50% by mass or more and 99.9% by mass or less. A hair cosmetic according to claim 1 or 2, wherein component (B) is ethanol. The hair cosmetic of claim 1 or 2, which further comprises one or more selected from the group consisting of a polyol, a urea, an organic acid, a polyoxyalkylalkyl glucoside, and a polyoxyalkylene glyceryl ether. Ingredient (D). A hair cosmetic according to claim 1 or 2, which is in the form of a mist. A hair cosmetic according to claim 9 which is a non-aerosol type user.