TW201716465A - Imaging lens - Google Patents
Imaging lens Download PDFInfo
- Publication number
- TW201716465A TW201716465A TW105121772A TW105121772A TW201716465A TW 201716465 A TW201716465 A TW 201716465A TW 105121772 A TW105121772 A TW 105121772A TW 105121772 A TW105121772 A TW 105121772A TW 201716465 A TW201716465 A TW 201716465A
- Authority
- TW
- Taiwan
- Prior art keywords
- polycarbonate resin
- image pickup
- mol
- pickup lens
- lens
- Prior art date
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- 238000003384 imaging method Methods 0.000 title claims abstract description 18
- 238000010521 absorption reaction Methods 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 4
- 239000004417 polycarbonate Substances 0.000 claims abstract description 4
- 239000004431 polycarbonate resin Substances 0.000 claims description 48
- 229920005668 polycarbonate resin Polymers 0.000 claims description 48
- 239000008188 pellet Substances 0.000 description 23
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- -1 bisphenol oxime Chemical class 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 238000005259 measurement Methods 0.000 description 9
- 230000003287 optical effect Effects 0.000 description 9
- NQXNYVAALXGLQT-UHFFFAOYSA-N 2-[4-[9-[4-(2-hydroxyethoxy)phenyl]fluoren-9-yl]phenoxy]ethanol Chemical compound C1=CC(OCCO)=CC=C1C1(C=2C=CC(OCCO)=CC=2)C2=CC=CC=C2C2=CC=CC=C21 NQXNYVAALXGLQT-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000001746 injection moulding Methods 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 150000002009 diols Chemical class 0.000 description 5
- 239000010408 film Substances 0.000 description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 150000004650 carbonic acid diesters Chemical class 0.000 description 4
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 4
- 239000002685 polymerization catalyst Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000001339 alkali metal compounds Chemical class 0.000 description 3
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- ITHZDDVSAWDQPZ-UHFFFAOYSA-L barium acetate Chemical compound [Ba+2].CC([O-])=O.CC([O-])=O ITHZDDVSAWDQPZ-UHFFFAOYSA-L 0.000 description 3
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 3
- 229910001863 barium hydroxide Inorganic materials 0.000 description 3
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 150000004714 phosphonium salts Chemical class 0.000 description 3
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000005809 transesterification reaction Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000004075 alteration Effects 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 159000000009 barium salts Chemical class 0.000 description 2
- UCVMQZHZWWEPRC-UHFFFAOYSA-L barium(2+);hydrogen carbonate Chemical compound [Ba+2].OC([O-])=O.OC([O-])=O UCVMQZHZWWEPRC-UHFFFAOYSA-L 0.000 description 2
- 235000010216 calcium carbonate Nutrition 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- VBVCYAZECWLFHP-UHFFFAOYSA-N dodecyl benzenesulfonate;tetrabutylphosphanium Chemical compound CCCC[P+](CCCC)(CCCC)CCCC.CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 VBVCYAZECWLFHP-UHFFFAOYSA-N 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 239000012760 heat stabilizer Substances 0.000 description 2
- 239000004611 light stabiliser Substances 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 239000006078 metal deactivator Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 150000003304 ruthenium compounds Chemical class 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- VLCQYXZALXDPEV-UHFFFAOYSA-N (2,3,4-triethylphenyl)boron Chemical compound [B]C1=CC=C(CC)C(CC)=C1CC VLCQYXZALXDPEV-UHFFFAOYSA-N 0.000 description 1
- PJAWEFMLSSLAIM-UHFFFAOYSA-N (2,3,4-trimethylphenyl)boron Chemical compound [B]C1=CC=C(C)C(C)=C1C PJAWEFMLSSLAIM-UHFFFAOYSA-N 0.000 description 1
- IHPFDBSMYWRYHQ-UHFFFAOYSA-N (2-benzylphenyl)-diphenylborane Chemical compound C=1C=CC=C(B(C=2C=CC=CC=2)C=2C=CC=CC=2)C=1CC1=CC=CC=C1 IHPFDBSMYWRYHQ-UHFFFAOYSA-N 0.000 description 1
- GCLVVFYKIZYIIL-UHFFFAOYSA-N (2-butylphenyl)-diphenylborane Chemical compound CCCCC1=CC=CC=C1B(C=1C=CC=CC=1)C1=CC=CC=C1 GCLVVFYKIZYIIL-UHFFFAOYSA-N 0.000 description 1
- GPFJHNSSBHPYJK-UHFFFAOYSA-N (3-methylphenyl) hydrogen carbonate Chemical compound CC1=CC=CC(OC(O)=O)=C1 GPFJHNSSBHPYJK-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- XGVZPMZEBYEFAD-UHFFFAOYSA-N 2,2-dimethylpropylboron Chemical compound [B]CC(C)(C)C XGVZPMZEBYEFAD-UHFFFAOYSA-N 0.000 description 1
- BGCSUUSPRCDKBQ-UHFFFAOYSA-N 2,4,8,10-tetraoxaspiro[5.5]undecane Chemical compound C1OCOCC21COCOC2 BGCSUUSPRCDKBQ-UHFFFAOYSA-N 0.000 description 1
- QUMMIJOYXPIWKT-UHFFFAOYSA-N 2-(2-methylphenyl)propan-2-ylboron Chemical compound [B]C(C)(C)C1=CC=CC=C1C QUMMIJOYXPIWKT-UHFFFAOYSA-N 0.000 description 1
- BPZIYBJCZRUDEG-UHFFFAOYSA-N 2-[3-(1-hydroxy-2-methylpropan-2-yl)-2,4,8,10-tetraoxaspiro[5.5]undecan-9-yl]-2-methylpropan-1-ol Chemical compound C1OC(C(C)(CO)C)OCC21COC(C(C)(C)CO)OC2 BPZIYBJCZRUDEG-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 1
- HWUGMDUGNYFQTA-UHFFFAOYSA-N 2-methyl-2-(2,4,8,10-tetraoxaspiro[5.5]undecan-5-yl)propan-1-ol Chemical compound OCC(C)(C)C1OCOCC11COCOC1 HWUGMDUGNYFQTA-UHFFFAOYSA-N 0.000 description 1
- ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 2-phenyl-1h-imidazole Chemical compound C1=CNC(C=2C=CC=CC=2)=N1 ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 0.000 description 1
- YMTYZTXUZLQUSF-UHFFFAOYSA-N 3,3'-Dimethylbisphenol A Chemical compound C1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=CC=2)=C1 YMTYZTXUZLQUSF-UHFFFAOYSA-N 0.000 description 1
- CCZFANLSRKSNMX-UHFFFAOYSA-N 3-(2-ethylphenyl)pentan-3-ylboron Chemical compound CCC([B])(CC)C1=CC=CC=C1CC CCZFANLSRKSNMX-UHFFFAOYSA-N 0.000 description 1
- VWGKEVWFBOUAND-UHFFFAOYSA-N 4,4'-thiodiphenol Chemical compound C1=CC(O)=CC=C1SC1=CC=C(O)C=C1 VWGKEVWFBOUAND-UHFFFAOYSA-N 0.000 description 1
- BATCUENAARTUKW-UHFFFAOYSA-N 4-[(4-hydroxyphenyl)-diphenylmethyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 BATCUENAARTUKW-UHFFFAOYSA-N 0.000 description 1
- UMPGNGRIGSEMTC-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexyl]phenol Chemical compound C1C(C)CC(C)(C)CC1(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 UMPGNGRIGSEMTC-UHFFFAOYSA-N 0.000 description 1
- LNNIPFBETXOKIA-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)-9h-fluoren-2-yl]phenol Chemical compound C1=CC(O)=CC=C1C1=CC=C(C=2C(=CC=CC=2)C2)C2=C1C1=CC=C(O)C=C1 LNNIPFBETXOKIA-UHFFFAOYSA-N 0.000 description 1
- PVFQHGDIOXNKIC-UHFFFAOYSA-N 4-[2-[3-[2-(4-hydroxyphenyl)propan-2-yl]phenyl]propan-2-yl]phenol Chemical compound C=1C=CC(C(C)(C)C=2C=CC(O)=CC=2)=CC=1C(C)(C)C1=CC=C(O)C=C1 PVFQHGDIOXNKIC-UHFFFAOYSA-N 0.000 description 1
- REAVCZWUMGIGSW-UHFFFAOYSA-M 4-methylbenzenesulfonate;tetrabutylazanium Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1.CCCC[N+](CCCC)(CCCC)CCCC REAVCZWUMGIGSW-UHFFFAOYSA-M 0.000 description 1
- ZYUVGYBAPZYKSA-UHFFFAOYSA-N 5-(3-hydroxybutan-2-yl)-4-methylbenzene-1,3-diol Chemical compound CC(O)C(C)C1=CC(O)=CC(O)=C1C ZYUVGYBAPZYKSA-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- VOWWYDCFAISREI-UHFFFAOYSA-N Bisphenol AP Chemical compound C=1C=C(O)C=CC=1C(C=1C=CC(O)=CC=1)(C)C1=CC=CC=C1 VOWWYDCFAISREI-UHFFFAOYSA-N 0.000 description 1
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- 239000004420 Iupilon Substances 0.000 description 1
- JMMSLMMJRMCXPW-UHFFFAOYSA-N OC.OC.C1CC2CCC1C2 Chemical compound OC.OC.C1CC2CCC1C2 JMMSLMMJRMCXPW-UHFFFAOYSA-N 0.000 description 1
- QYFACSDTKGXDDM-UHFFFAOYSA-N OC.OC.C1CCCCCCCCCCCCCC1.C1CCCCCCCCCCCCCC1.C1CCCCCCCCCCCCCC1.C1CCCCCCCCCCCCCC1.C1CCCCCCCCCCCCCC1 Chemical compound OC.OC.C1CCCCCCCCCCCCCC1.C1CCCCCCCCCCCCCC1.C1CCCCCCCCCCCCCC1.C1CCCCCCCCCCCCCC1.C1CCCCCCCCCCCCCC1 QYFACSDTKGXDDM-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 description 1
- AYVGBNGTBQLJBG-UHFFFAOYSA-N [3-(hydroxymethyl)cyclopentyl]methanol Chemical compound OCC1CCC(CO)C1 AYVGBNGTBQLJBG-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- KBWLBXSZWRTHKM-UHFFFAOYSA-N [6-(hydroxymethyl)-1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalen-2-yl]methanol Chemical compound C1C(CO)CCC2CC(CO)CCC21 KBWLBXSZWRTHKM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- NDKBVBUGCNGSJJ-UHFFFAOYSA-M benzyltrimethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)CC1=CC=CC=C1 NDKBVBUGCNGSJJ-UHFFFAOYSA-M 0.000 description 1
- MUCRFDZUHPMASM-UHFFFAOYSA-N bis(2-chlorophenyl) carbonate Chemical compound ClC1=CC=CC=C1OC(=O)OC1=CC=CC=C1Cl MUCRFDZUHPMASM-UHFFFAOYSA-N 0.000 description 1
- POZGCGJFBOZPCM-UHFFFAOYSA-N bis(2-methylphenyl) carbonate Chemical compound CC1=CC=CC=C1OC(=O)OC1=CC=CC=C1C POZGCGJFBOZPCM-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- FLLNLJJKHKZKMB-UHFFFAOYSA-N boron;tetramethylazanium Chemical compound [B].C[N+](C)(C)C FLLNLJJKHKZKMB-UHFFFAOYSA-N 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- QYJXDIUNDMRLAO-UHFFFAOYSA-N butyl 4-methylbenzenesulfonate Chemical compound CCCCOS(=O)(=O)C1=CC=C(C)C=C1 QYJXDIUNDMRLAO-UHFFFAOYSA-N 0.000 description 1
- NIKBCKTWWPVAIC-UHFFFAOYSA-N butyl benzenesulfonate Chemical compound CCCCOS(=O)(=O)C1=CC=CC=C1 NIKBCKTWWPVAIC-UHFFFAOYSA-N 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- INSRQEMEVAMETL-UHFFFAOYSA-N decane-1,1-diol Chemical compound CCCCCCCCCC(O)O INSRQEMEVAMETL-UHFFFAOYSA-N 0.000 description 1
- NHADDZMCASKINP-HTRCEHHLSA-N decarboxydihydrocitrinin Natural products C1=C(O)C(C)=C2[C@H](C)[C@@H](C)OCC2=C1O NHADDZMCASKINP-HTRCEHHLSA-N 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- IZRTVYMPRPTBAI-UHFFFAOYSA-K dibenzoyloxybismuthanyl benzoate Chemical compound [Bi+3].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 IZRTVYMPRPTBAI-UHFFFAOYSA-K 0.000 description 1
- SMBQBQBNOXIFSF-UHFFFAOYSA-N dilithium Chemical class [Li][Li] SMBQBQBNOXIFSF-UHFFFAOYSA-N 0.000 description 1
- REKWWOFUJAJBCL-UHFFFAOYSA-L dilithium;hydrogen phosphate Chemical compound [Li+].[Li+].OP([O-])([O-])=O REKWWOFUJAJBCL-UHFFFAOYSA-L 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- KCIDZIIHRGYJAE-YGFYJFDDSA-L dipotassium;[(2r,3r,4s,5r,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] phosphate Chemical class [K+].[K+].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@H]1O KCIDZIIHRGYJAE-YGFYJFDDSA-L 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- TYJOJLOWRIQYQM-UHFFFAOYSA-L disodium;phenyl phosphate Chemical compound [Na+].[Na+].[O-]P([O-])(=O)OC1=CC=CC=C1 TYJOJLOWRIQYQM-UHFFFAOYSA-L 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 229930004069 diterpene Natural products 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- VRZVPALEJCLXPR-UHFFFAOYSA-N ethyl 4-methylbenzenesulfonate Chemical compound CCOS(=O)(=O)C1=CC=C(C)C=C1 VRZVPALEJCLXPR-UHFFFAOYSA-N 0.000 description 1
- XDRMBCMMABGNMM-UHFFFAOYSA-N ethyl benzenesulfonate Chemical compound CCOS(=O)(=O)C1=CC=CC=C1 XDRMBCMMABGNMM-UHFFFAOYSA-N 0.000 description 1
- SZWSLRODZDGCBJ-UHFFFAOYSA-N ethyl(methyl)boron Chemical compound C[B]CC SZWSLRODZDGCBJ-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- MHIBEGOZTWERHF-UHFFFAOYSA-N heptane-1,1-diol Chemical compound CCCCCCC(O)O MHIBEGOZTWERHF-UHFFFAOYSA-N 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 description 1
- 229940031993 lithium benzoate Drugs 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 description 1
- LDJNSLOKTFFLSL-UHFFFAOYSA-M lithium;benzoate Chemical compound [Li+].[O-]C(=O)C1=CC=CC=C1 LDJNSLOKTFFLSL-UHFFFAOYSA-M 0.000 description 1
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
- QWDJLDTYWNBUKE-UHFFFAOYSA-L magnesium bicarbonate Chemical compound [Mg+2].OC([O-])=O.OC([O-])=O QWDJLDTYWNBUKE-UHFFFAOYSA-L 0.000 description 1
- 229910000022 magnesium bicarbonate Inorganic materials 0.000 description 1
- 239000002370 magnesium bicarbonate Substances 0.000 description 1
- 235000014824 magnesium bicarbonate Nutrition 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 150000002697 manganese compounds Chemical class 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- LFETXMWECUPHJA-UHFFFAOYSA-N methanamine;hydrate Chemical compound O.NC LFETXMWECUPHJA-UHFFFAOYSA-N 0.000 description 1
- VUQUOGPMUUJORT-UHFFFAOYSA-N methyl 4-methylbenzenesulfonate Chemical compound COS(=O)(=O)C1=CC=C(C)C=C1 VUQUOGPMUUJORT-UHFFFAOYSA-N 0.000 description 1
- CZXGXYBOQYQXQD-UHFFFAOYSA-N methyl benzenesulfonate Chemical compound COS(=O)(=O)C1=CC=CC=C1 CZXGXYBOQYQXQD-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- LYQJBZLAANNIER-UHFFFAOYSA-N octyl 4-methylbenzenesulfonate Chemical compound CCCCCCCCOS(=O)(=O)C1=CC=C(C)C=C1 LYQJBZLAANNIER-UHFFFAOYSA-N 0.000 description 1
- GVMDZMPQYYHMSV-UHFFFAOYSA-N octyl benzenesulfonate Chemical compound CCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVMDZMPQYYHMSV-UHFFFAOYSA-N 0.000 description 1
- 239000012788 optical film Substances 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- KZQFPRKQBWRRHQ-UHFFFAOYSA-N phenyl 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)OC1=CC=CC=C1 KZQFPRKQBWRRHQ-UHFFFAOYSA-N 0.000 description 1
- CGEXUOTXYSGBLV-UHFFFAOYSA-N phenyl benzenesulfonate Chemical compound C=1C=CC=CC=1S(=O)(=O)OC1=CC=CC=C1 CGEXUOTXYSGBLV-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 235000010235 potassium benzoate Nutrition 0.000 description 1
- 239000004300 potassium benzoate Substances 0.000 description 1
- 229940103091 potassium benzoate Drugs 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- NBPUSGBJDWCHKC-UHFFFAOYSA-M sodium 3-hydroxybutyrate Chemical compound [Na+].CC(O)CC([O-])=O NBPUSGBJDWCHKC-UHFFFAOYSA-M 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 description 1
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 description 1
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical class CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- RXJKFRMDXUJTEX-UHFFFAOYSA-N triethylphosphine Chemical compound CCP(CC)CC RXJKFRMDXUJTEX-UHFFFAOYSA-N 0.000 description 1
- IGNTWNVBGLNYDV-UHFFFAOYSA-N triisopropylphosphine Chemical compound CC(C)P(C(C)C)C(C)C IGNTWNVBGLNYDV-UHFFFAOYSA-N 0.000 description 1
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 description 1
- KCTAHLRCZMOTKM-UHFFFAOYSA-N tripropylphosphane Chemical compound CCCP(CCC)CCC KCTAHLRCZMOTKM-UHFFFAOYSA-N 0.000 description 1
- 150000003755 zirconium compounds Chemical class 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/16—Aliphatic-aromatic or araliphatic polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/30—General preparatory processes using carbonates
- C08G64/302—General preparatory processes using carbonates and cyclic ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/30—General preparatory processes using carbonates
- C08G64/307—General preparatory processes using carbonates and phenols
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B13/00—Optical objectives specially designed for the purposes specified below
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Description
本發明關於一種由特定聚碳酸酯樹脂所構成的攝像透鏡。 The present invention relates to an image pickup lens composed of a specific polycarbonate resin.
近年來,行動電話幾乎都搭載了相機功能,最近出現了搭載與數位靜態相機匹敵的高解像度相機功能的行動電話。攝像元件的畫素大小經過微細化,畫素節距低於1.4微米。另一方面,因應於行動電話的小型或薄型化,攝像透鏡也會需要小型化。所以隨著攝像元件的高解像度化與攝像透鏡的小型化,正迫切需要使攝像透鏡低複折射化或提升像差修正能力。以往,行動電話、智慧型手機等的攜帶型機器用攝像透鏡是以非球面塑膠來製造,像差修正可藉由不同光學特性(折射率、阿貝數)的透鏡的組合與透鏡形狀的組合來進行。 In recent years, almost all mobile phones have been equipped with camera functions, and recently there have been mobile phones equipped with a high-resolution camera function comparable to digital still cameras. The pixel size of the imaging element is miniaturized, and the pixel pitch is less than 1.4 μm. On the other hand, in view of the small size or thinness of the mobile phone, the imaging lens also needs to be miniaturized. Therefore, with the high resolution of the imaging element and the miniaturization of the imaging lens, it is urgent to reduce the birefringence of the imaging lens or to improve the aberration correction capability. In the past, an imaging lens for a portable device such as a mobile phone or a smart phone was manufactured by aspherical plastic, and the aberration correction can be combined with a lens shape by a lens having different optical characteristics (refractive index, Abbe number). Come on.
在透鏡用途實用化的光學用透明樹脂之中,高折射率、低阿貝數的樹脂一直以來廣泛採用以雙酚A作為原料的聚碳酸酯樹脂(nd=1.584)。然而,以雙酚A作為原料的聚碳酸酯樹脂會有複折射顯著的缺點,因此無法 使用於近年來的高解像度相機。 Among the optical transparent resins that have been put to practical use in the lens, polycarbonate resins (nd=1.584) using bisphenol A as a raw material have been widely used as resins having a high refractive index and a low Abbe number. However, polycarbonate resin using bisphenol A as a raw material has a significant disadvantage of birefringence and therefore cannot be Used in high resolution cameras in recent years.
關於減少複折射的方法,有文獻揭示了含有芴基或氧螺十一烷基的聚碳酸酯共聚物(專利文獻1、2)。專利文獻1揭示了光碟等的資訊記錄媒體,專利文獻2揭示了光碟、光學薄膜、光學稜鏡、讀取透鏡(僅識別光學訊號的0或1),然而並未設想到攝像透鏡,因此折射率、阿貝數、配向複折射、吸水率等攝像透鏡所需的特性不明。另外還有文獻揭示了一種由聚碳酸酯樹脂與具有特定構造的苯乙烯樹脂所構成的相機透鏡(專利文獻3)。然而,該專利文獻的樹脂含有聚苯乙烯成分,甚至非相溶成分會彼此混合,因此會有樹脂的質地脆、耐熱性也很低這樣的課題。 As a method for reducing the birefringence, a polycarbonate copolymer containing a mercapto group or an oxetane undecyl group has been disclosed (Patent Documents 1 and 2). Patent Document 1 discloses an information recording medium such as an optical disc, and Patent Document 2 discloses an optical disc, an optical film, an optical pickup, a reading lens (only 0 or 1 of an optical signal is recognized), but an imaging lens is not assumed, and thus refraction is The characteristics required for the imaging lens such as rate, Abbe number, alignment birefringence, and water absorption rate are unknown. Further, the literature discloses a camera lens composed of a polycarbonate resin and a styrene resin having a specific structure (Patent Document 3). However, since the resin of this patent document contains a polystyrene component and even an incompatible component mixes with each other, there exists a subject that the resin of the resin is brittle and heat resistance is low.
專利文獻1:日本特開平9-268225號公報 Patent Document 1: Japanese Patent Laid-Open No. Hei 9-268225
專利文獻2:日本特開2004-67990號公報 Patent Document 2: Japanese Laid-Open Patent Publication No. 2004-67990
專利文獻3:日本特開2009-93146號公報 Patent Document 3: Japanese Laid-Open Patent Publication No. 2009-93146
於是,本發明之目的在於提供一種攝像透鏡,藉由使用特定聚碳酸酯樹脂,具有特定折射率、阿貝數,而且具有低複折射及低吸水率。 Accordingly, an object of the present invention is to provide an image pickup lens which has a specific refractive index, an Abbe number, and a low birefringence and a low water absorption rate by using a specific polycarbonate resin.
本發明人為了解決上述課題,針對新的攝像透鏡用樹脂反覆鑽研,結果發現,藉由使9,9-雙[4-(2-羥基乙氧基)苯基]芴與3,9-雙(1,1-二甲基-2-羥乙基)2,4,8,10-四氧螺[5.5]十一烷以特定組成比共聚合,得到攝像透鏡用聚碳酸酯樹脂,藉由使用該樹脂,可成為具有特定折射率、阿貝數而且具有低複折射及低吸水率的攝像透鏡。 In order to solve the above problems, the inventors of the present invention have repeatedly studied the resin for a new image pickup lens, and as a result, found that 9,9-bis[4-(2-hydroxyethoxy)phenyl]fluorene and 3,9-double are (1,1-Dimethyl-2-hydroxyethyl)2,4,8,10-tetraoxaspiro[5.5]undecane is copolymerized at a specific composition ratio to obtain a polycarbonate resin for an image pickup lens, The resin can be used as an image pickup lens having a specific refractive index and an Abbe number and having low birefringence and low water absorption.
亦即,依據本發明,提供以下所示之由聚碳酸酯樹脂所構成的攝像透鏡。 That is, according to the present invention, an image pickup lens composed of a polycarbonate resin shown below is provided.
1.一種攝像透鏡,其係以下述式的比例含有式(1)及式(2)的由聚碳酸酯所構成。 An imaging lens comprising a polycarbonate comprising the formulas (1) and (2) in a ratio of the following formula.
50mol%≦(1)<70mol% 50 mol% ≦ (1) < 70 mol%
30mol%<(2)≦50mol% 30 mol% < (2) ≦ 50 mol%
[化2]
2.如前述1之攝像透鏡,其中聚碳酸酯樹脂的折射率為1.57~1.60且阿貝數為27~31。 2. The image pickup lens according to the above 1, wherein the polycarbonate resin has a refractive index of 1.57 to 1.60 and an Abbe number of 27 to 31.
3.如上述1或2項之攝像透鏡,其中由聚碳酸酯樹脂所構成的薄膜的配向複折射為2×10-3以下。 3. The image pickup lens according to item 1 or 2 above, wherein the film composed of the polycarbonate resin has an alignment birefringence of 2 × 10 -3 or less.
4.如上述1~3中任一項之攝像透鏡,其中聚碳酸酯樹脂的折射率為1.58~1.59。 4. The image pickup lens according to any one of the above 1 to 3, wherein the polycarbonate resin has a refractive index of from 1.58 to 1.59.
5.如上述1~4中任一項之攝像透鏡,其中聚碳酸酯樹脂的阿貝數為27.5~29.5。 5. The image pickup lens according to any one of the above 1 to 4, wherein the polycarbonate resin has an Abbe number of 27.5 to 29.5.
6.如上述1~5中任一項之攝像透鏡,其中聚碳酸酯樹脂的比黏度為0.12~0.32。 6. The image pickup lens according to any one of the above 1 to 5, wherein the polycarbonate resin has a specific viscosity of 0.12 to 0.32.
7.如上述1~6中任一項之攝像透鏡,其中聚碳酸酯樹脂的吸水率為0.2%以下。 7. The image pickup lens according to any one of the above 1 to 6, wherein the water absorption of the polycarbonate resin is 0.2% or less.
8.如上述1~7中任一項之攝像透鏡,其係使用於行動電話、智慧型手機、平板電腦、個人電腦、數位相機、攝影機、行車紀錄器、監視攝影機之任一者。 8. The image pickup lens according to any one of the above 1 to 7, which is used in any of a mobile phone, a smart phone, a tablet computer, a personal computer, a digital camera, a video camera, a driving recorder, and a surveillance camera.
本發明之攝像透鏡所使用的樹脂,藉由使9,9-雙[4-(2-羥基乙氧基)苯基]芴與3,9-雙(1,1-二甲基-2-羥乙基)2,4,8,10-四氧螺[5.5]十一烷以特定組成比共聚合,得到攝像透鏡用聚碳酸酯樹脂,藉由使用該樹脂,可成為 具有特定折射率、阿貝數而且具有低複折射及低吸水率的攝像透鏡,因此在需要發揮這些特性的產業上,效果特別良好。 The resin used in the image pickup lens of the present invention is obtained by using 9,9-bis[4-(2-hydroxyethoxy)phenyl]fluorene and 3,9-bis(1,1-dimethyl-2-). Hydroxyethyl) 2,4,8,10-tetraoxaspiro[5.5]undecane is copolymerized at a specific composition ratio to obtain a polycarbonate resin for an image pickup lens, which can be obtained by using the resin. An imaging lens having a specific refractive index and an Abbe number and having low birefringence and low water absorption rate is particularly effective in an industry that needs to exhibit these characteristics.
以下針對本發明之攝像透鏡依序具體說明。 Hereinafter, the imaging lens of the present invention will be specifically described in order.
本發明之攝像透鏡所使用的聚碳酸酯樹脂在測定溫度:25℃、測定波長:589nm下的折射率為1.57~1.60,以1.58~1.59為較佳。 The polycarbonate resin used in the image pickup lens of the present invention has a refractive index of 1.57 to 1.60 at a measurement temperature of 25 ° C and a measurement wavelength of 589 nm, preferably 1.58 to 1.59.
本發明之攝像透鏡所使用的聚碳酸酯樹脂在測定溫度:25℃下的阿貝數,係以27.0~31.0為佳,27.5~29.5為較佳。阿貝數是由測定溫度:25℃、測定波長:486nm、589nm、656nm的折射率,使用下述式來計算。 The polycarbonate resin used in the image pickup lens of the present invention preferably has an Abbe number at a measurement temperature of 25 ° C of 27.0 to 31.0, preferably 27.5 to 29.5. The Abbe number is calculated from the measurement temperature: 25 ° C, and the measurement wavelengths: 486 nm, 589 nm, and 656 nm, using the following formula.
ν=(nD-1)/(nF-nC) ν=(nD-1)/(nF-nC)
nD:在波長589nm的折射率 nD: refractive index at a wavelength of 589 nm
nC:在波長656nm的折射率 nC: refractive index at a wavelength of 656 nm
nF:在波長486nm的折射率 nF: refractive index at a wavelength of 486 nm
本發明之攝像透鏡所使用的聚碳酸酯樹脂含有式(1)及式(2)。 The polycarbonate resin used in the image pickup lens of the present invention contains the formulas (1) and (2).
[化3]
本發明之攝像透鏡所使用的聚碳酸酯樹脂含有式(1)50mol%以上未達70mol%,55~65mol%為佳,57~64mol%為更佳。另外,含有式(2)大於30mol%且50mol%以下,35~45mol%為佳,36~43mol%為更佳。 The polycarbonate resin used in the image pickup lens of the present invention contains 50 mol% or more of the formula (1) of less than 70 mol%, more preferably 55 to 65 mol%, more preferably 57 to 64 mol%. Further, the formula (2) is contained more than 30 mol% and 50 mol% or less, preferably 35 to 45 mol%, more preferably 36 to 43 mol%.
本發明之攝像透鏡所使用的聚碳酸酯樹脂含有式(1)及式(2)所表示的重複單元,在不損害本發明之特性的程度,亦可與其他二醇成分共聚合。其他二醇成分,在全部的重複單元中宜占10mol%以下。其他二醇成分,可列舉乙二醇、丙二醇、丁二醇、戊二醇、己二醇、庚二醇、辛二醇、壬二醇、三環[5.2.1.02,6]癸烷二甲醇、環己烷-1,4-二甲醇、十氫萘-2,6-二甲醇、降冰片烷二甲醇、五環十五烷二甲醇、環戊烷-1,3-二甲醇、異山梨糖醇酐、氫醌、間苯二酚、2,2-雙(4-羥苯基)丙烷、2,2-雙(3-甲基-4-羥苯基)丙烷、1,1-雙(4-羥苯基)-1-苯基乙烷、雙(4-羥苯基) 二苯基甲烷、1,3-雙(2-(4-羥苯基)-2-丙基)苯、雙(4-羥苯基)碸、雙(4-羥苯基)硫醚、1,1-雙(4-羥苯基)-3,3,5-三甲基環己烷、1,1-雙(4-羥苯基)環己烷、聯苯酚、雙酚芴、雙甲酚芴等。 The polycarbonate resin used in the image pickup lens of the present invention contains the repeating unit represented by the formula (1) and the formula (2), and can be copolymerized with other diol components to the extent that the characteristics of the present invention are not impaired. The other diol component is preferably 10 mol% or less in all the repeating units. Examples of the other diol component include ethylene glycol, propylene glycol, butanediol, pentanediol, hexanediol, heptanediol, octanediol, decanediol, and tricyclo [5.2.1.0 2,6 ]nonane II. Methanol, cyclohexane-1,4-dimethanol, decalin-2,6-dimethanol, norbornane dimethanol, pentacyclopentadecane dimethanol, cyclopentane-1,3-dimethanol, different Sorbitol, hydroquinone, resorcinol, 2,2-bis(4-hydroxyphenyl)propane, 2,2-bis(3-methyl-4-hydroxyphenyl)propane, 1,1- Bis(4-hydroxyphenyl)-1-phenylethane, bis(4-hydroxyphenyl)diphenylmethane, 1,3-bis(2-(4-hydroxyphenyl)-2-propyl) Benzene, bis(4-hydroxyphenyl)fluorene, bis(4-hydroxyphenyl) sulfide, 1,1-bis(4-hydroxyphenyl)-3,3,5-trimethylcyclohexane, 1 , 1-bis(4-hydroxyphenyl)cyclohexane, biphenol, bisphenol oxime, biscresol oxime, and the like.
本發明之攝像透鏡所使用的聚碳酸酯樹脂的比黏度在0.12~0.32的範圍為佳,在0.18~0.30的範圍為較佳。若比黏度為0.12~0.32,則成形性與強度的平衡性優異。 The polycarbonate resin used in the image pickup lens of the present invention preferably has a specific viscosity of from 0.12 to 0.32, more preferably from 0.18 to 0.30. When the specific viscosity is 0.12 to 0.32, the balance between formability and strength is excellent.
本發明之攝像透鏡所使用的聚碳酸酯樹脂的配向複折射(△n)的絕對值宜在0~6×10-3的範圍,較佳為0~4×10-3,更佳為0~2×10-3。配向複折射(△n),是使由該聚碳酸酯樹脂所得到的厚度100μm的澆鑄薄膜在Tg+10℃下延伸2倍,在波長589nm下進行測定。 The absolute value of the alignment birefringence (?n) of the polycarbonate resin used in the image pickup lens of the present invention is preferably in the range of 0 to 6 × 10 -3 , preferably 0 to 4 × 10 -3 , more preferably 0. ~2×10 -3 . The birefringence (Δn) of the alignment was such that the cast film having a thickness of 100 μm obtained from the polycarbonate resin was stretched twice at Tg + 10 ° C and measured at a wavelength of 589 nm.
本發明之攝像透鏡所使用的聚碳酸酯樹脂在厚度1mm時的總透光率宜為80%以上,較佳為85%以上,更佳為88%以上。 The polycarbonate resin used in the image pickup lens of the present invention preferably has a total light transmittance of 80% or more, preferably 85% or more, more preferably 88% or more at a thickness of 1 mm.
本發明之攝像透鏡所使用的聚碳酸酯樹脂,在23℃浸漬24小時後的吸水率係以0.20%以下為佳,0.17%以下為較佳。 The polycarbonate resin used in the image pickup lens of the present invention preferably has a water absorption ratio of 0.20% or less after immersion at 23 ° C for 24 hours, and preferably 0.17% or less.
本發明之攝像透鏡使用的聚碳酸酯樹脂的玻璃轉移點係以120~160℃為佳,125~150℃為較佳。 The glass transition point of the polycarbonate resin used in the image pickup lens of the present invention is preferably 120 to 160 ° C, and preferably 125 to 150 ° C.
本發明之攝像透鏡所使用的聚碳酸酯樹脂,是藉由通 常製造聚碳酸酯樹脂的周知反應手段,例如使二醇成分與碳酸二酯等的碳酸酯前驅物質反應的方法來製造。接下來針對這些製造方法,簡單說明基本的手段。 The polycarbonate resin used in the image pickup lens of the present invention is passed through Conventional reaction means for producing a polycarbonate resin, for example, a method in which a diol component is reacted with a carbonate precursor such as a carbonic acid diester. Next, the basic means will be briefly explained for these manufacturing methods.
使用碳酸二酯作為碳酸酯前驅物質的酯交換反應,是藉由在惰性氣體環境下,將既定比例的芳香族二羥基成分與碳酸二酯加熱,同時攪拌,將所產生的醇或酚類餾出的方法來進行。反應溫度會依照所產生的醇或酚類的沸點等而有所不同,通常是在120~300℃的範圍。反應是從其初期開始減壓,將所產生的醇或酚類餾出,同時使反應結束。另外還可因應必要添加末端停止劑、抗氧化劑等。 The transesterification reaction using a carbonic acid diester as a carbonate precursor is carried out by heating a predetermined ratio of an aromatic dihydroxy component and a carbonic acid diester under an inert gas atmosphere while stirring, and distilling the produced alcohol or phenol. The method is out. The reaction temperature will vary depending on the boiling point of the alcohol or phenol to be produced, etc., and is usually in the range of 120 to 300 °C. The reaction is carried out under reduced pressure from the initial stage, and the produced alcohol or phenol is distilled off, and the reaction is completed. In addition, terminal stoppers, antioxidants, and the like may be added as necessary.
前述酯交換反應所使用的碳酸二酯,可列舉可經取代的碳數6~12的芳香基、芳烷基等的酯。具體而言,可例示碳酸二苯酯、碳酸二(甲苯基)酯、雙(氯苯基)碳酸酯及碳酸間甲酚酯等。尤其以碳酸二苯酯為特佳。碳酸二苯酯的使用量,相對於二羥基化合物的合計1莫耳,宜為0.95~1.10莫耳、較佳為0.98~1.04莫耳。另外,在熔融聚合法之中,為了加快聚合速度,可使用聚合觸媒,該聚合觸媒,可列舉鹼金屬化合物、鹼土類金屬化合物、鹼性磷化合物、含氮化合物、金屬化合物等。這種化合物適合使用鹼金屬或鹼土類金屬的有機酸鹽、無機鹽、氧化物、氫氧化物、氫化物、烷氧化物、4級氫氧化銨等,這些化合物可單獨或組合使用。 The carbonic acid diester used in the transesterification reaction may, for example, be an ester of a 6- to 12-valent aromatic group or an aralkyl group which may be substituted. Specific examples thereof include diphenyl carbonate, bis(tolyl) carbonate, bis(chlorophenyl) carbonate, and m-cresol carbonate. In particular, diphenyl carbonate is particularly preferred. The amount of use of diphenyl carbonate is preferably from 0.95 to 1.10 mol, preferably from 0.98 to 1.04 mol, based on 1 mol of the total of the dihydroxy compound. Further, in the melt polymerization method, a polymerization catalyst may be used in order to accelerate the polymerization rate, and examples of the polymerization catalyst include an alkali metal compound, an alkaline earth metal compound, a basic phosphorus compound, a nitrogen-containing compound, and a metal compound. Such a compound is suitably used as an organic acid salt, an inorganic salt, an oxide, a hydroxide, a hydride, an alkoxide, a 4-grade ammonium hydroxide or the like of an alkali metal or an alkaline earth metal, and these compounds may be used singly or in combination.
鹼金屬化合物,可例示氫氧化鈉、氫氧化 鉀、氫氧化銫、氫氧化鋰、碳酸氫鈉、碳酸鈉、碳酸鉀、碳酸銫、碳酸鋰、醋酸鈉、醋酸鉀、醋酸銫、醋酸鋰、硬脂酸鈉、硬脂酸鉀、硬脂酸銫、硬脂酸鋰、氫化硼鈉、安息香酸鈉、安息香酸鉀、安息香酸銫、安息香酸鋰、磷酸氫二鈉、磷酸氫二鉀、磷酸氫二鋰、苯基磷酸二鈉、雙酚A的二鈉鹽、二鉀鹽、二銫鹽、二鋰鹽、酚的鈉鹽、鉀鹽、銫鹽、鋰鹽等。 An alkali metal compound, which can be exemplified by sodium hydroxide or hydroxide Potassium, barium hydroxide, lithium hydroxide, sodium hydrogencarbonate, sodium carbonate, potassium carbonate, barium carbonate, lithium carbonate, sodium acetate, potassium acetate, barium acetate, lithium acetate, sodium stearate, potassium stearate, stearic acid Acid bismuth, lithium stearate, sodium borohydride, sodium benzoate, potassium benzoate, bismuth benzoate, lithium benzoate, disodium hydrogen phosphate, dipotassium hydrogen phosphate, dilithium hydrogen phosphate, disodium phenyl phosphate, double The disodium salt, the dipotassium salt, the diterpene salt, the dilithium salt of the phenol A, the sodium salt, the potassium salt, the phosphonium salt, the lithium salt and the like of the phenol.
鹼土類金屬化合物,可例示氫氧化鎂、氫氧化鈣、氫氧化鍶、氫氧化鋇、碳酸鎂、碳酸鈣、碳酸鍶、碳酸鋇、碳酸氫鈣、碳酸氫鋇、碳酸氫鎂、碳酸氫鍶、二醋酸鎂、二醋酸鈣、二醋酸鍶、二醋酸鋇等。鹼性硼化合物,可列舉例如四甲基硼、四乙基硼、四丙基硼、四丁基硼、三甲基乙基硼、三甲基苄基硼、三甲基苯基硼、三乙基甲基硼、三乙基苄基硼、三乙苯基硼、三丁基苄基硼、三丁基苯基硼、四苯基硼、苄基三苯基硼、甲基三苯基硼、丁基三苯基硼等的鈉鹽、鉀鹽、鋰鹽、鈣鹽、鋇鹽、鎂鹽、或鍶鹽等。 The alkaline earth metal compound may, for example, be magnesium hydroxide, calcium hydroxide, barium hydroxide, barium hydroxide, magnesium carbonate, calcium carbonate, barium carbonate, barium carbonate, calcium hydrogencarbonate, barium hydrogencarbonate, magnesium hydrogencarbonate or barium hydrogencarbonate. , magnesium diacetate, calcium diacetate, barium diacetate, barium diacetate and the like. Examples of the basic boron compound include tetramethylboron, tetraethylboron, tetrapropylboron, tetrabutylboron, trimethylethylboron, trimethylbenzylboron, trimethylphenylboron, and trisole. Ethylmethylboron, triethylbenzylboron, triethylphenylboron, tributylbenzylboron, tributylphenylboron, tetraphenylboron, benzyltriphenylboron, methyltriphenyl A sodium salt, a potassium salt, a lithium salt, a calcium salt, a barium salt, a magnesium salt or a barium salt of boron, butyltriphenylboron or the like.
鹼性磷化合物,可列舉例如三乙基膦、三正丙基膦、三異丙基膦、三正丁基膦、三苯膦、三丁基膦、或四級鏻鹽等。 Examples of the basic phosphorus compound include triethylphosphine, tri-n-propylphosphine, triisopropylphosphine, tri-n-butylphosphine, triphenylphosphine, tributylphosphine, or a quaternary phosphonium salt.
含氮化合物,可列舉四甲基氫氧化銨、四乙基氫氧化銨、四丙基氫氧化銨、四丁基氫氧化銨、三甲基苄基氫氧化銨等的具有烷基、芳香基等的4級氫氧化銨類。另外還可列舉三乙胺、二甲基苄基胺、三苯基胺等的 3級胺類、2-甲基咪唑、2-苯基咪唑、苯并咪唑等的咪唑類。另外還可例示氨、四甲基硼氫化銨、四丁基硼氫化銨、四丁基銨四苯基硼酸鹽、四苯基銨四苯基硼酸鹽等的鹼或鹼性鹽等。 Examples of the nitrogen-containing compound include an alkyl group and an aromatic group such as tetramethylammonium hydroxide, tetraethylammonium hydroxide, tetrapropylammonium hydroxide, tetrabutylammonium hydroxide, and trimethylbenzylammonium hydroxide. Class 4 ammonium hydroxides. Further, examples thereof include triethylamine, dimethylbenzylamine, and triphenylamine. An imidazole such as a tertiary amine, 2-methylimidazole, 2-phenylimidazole or benzimidazole. Further, an alkali or a basic salt such as ammonia, tetramethylammonium borohydride, tetrabutylammonium borohydride, tetrabutylammonium tetraphenylborate or tetraphenylammonium tetraphenylborate may be exemplified.
金屬化合物,可例示鋅鋁化合物、鍺化合物、有機錫化合物、銻化合物、錳化合物、鈦化合物、鋯化合物等。這些化合物可使用1種或併用2種以上。 The metal compound may, for example, be a zinc aluminum compound, a ruthenium compound, an organotin compound, a ruthenium compound, a manganese compound, a titanium compound, a zirconium compound or the like. These compounds may be used alone or in combination of two or more.
這些聚合觸媒的使用量,可選在相對於1莫耳的二醇成分為1×10-9~1×10-2當量的範圍,宜為1×10-8~1×10-3當量,較佳為1×10-7~1×10-5當量。 The amount of the polymerization catalyst to be used may be in the range of 1 × 10 -9 to 1 × 10 -2 equivalents, preferably 1 × 10 -8 to 1 × 10 -3 equivalents per 1 mole of the diol component. Preferably, it is 1 × 10 -7 ~ 1 × 10 -5 equivalent.
另外,亦可依照必要在反應後期添加觸媒失活劑。所使用的觸媒失活劑可有效採用周知的觸媒失活劑,其中宜為磺酸的銨鹽、鏻鹽。此外,還宜為十二烷基苯磺酸四丁基鏻鹽等的十二烷基苯磺酸的鹽類、對甲苯磺酸四丁基銨鹽等的對甲苯磺酸的鹽類。 Alternatively, a catalyst deactivator may be added later in the reaction as necessary. The catalyst deactivator used can be effectively used as a known catalyst deactivating agent, and among them, an ammonium salt or a phosphonium salt of a sulfonic acid is preferable. Further, it is also preferably a salt of dodecylbenzenesulfonic acid such as tetrabutylphosphonium dodecylbenzenesulfonate or a p-toluenesulfonic acid salt such as tetrabutylammonium p-toluenesulfonate.
另外,磺酸酯適合使用苯磺酸甲酯、苯磺酸乙酯、苯磺酸丁酯、苯磺酸辛酯、苯磺酸苯酯、對甲苯磺酸甲酯、對甲苯磺酸乙酯、對甲苯磺酸丁酯、對甲苯磺酸辛酯、對甲苯磺酸苯酯等。尤其,最適合使用十二烷基苯磺酸四丁基鏻鹽。 In addition, the sulfonate is preferably methyl benzenesulfonate, ethyl benzenesulfonate, butyl benzenesulfonate, octyl benzenesulfonate, phenyl benzenesulfonate, methyl p-toluenesulfonate, ethyl p-toluenesulfonate, Butyl p-toluenesulfonate, octyl p-toluenesulfonate, phenyl p-toluenesulfonate and the like. In particular, tetrabutylphosphonium dodecylbenzenesulfonate is most suitable.
這些觸媒失活劑的使用量,在使用選自鹼金屬化合物及/或鹼土類金屬化合物的至少1種聚合觸媒的情況,宜以每1莫耳該觸媒0.5~50莫耳失活劑的比例來使用,較佳為0.5~10莫耳,更佳為0.8~5莫耳。 When the amount of the catalyst deactivator used is at least one polymerization catalyst selected from the group consisting of an alkali metal compound and/or an alkaline earth metal compound, it is preferred to inactivate 0.5 to 50 moles per 1 mole of the catalyst. The ratio of the agent is preferably 0.5 to 10 moles, more preferably 0.8 to 5 moles.
另外,本發明之聚碳酸酯樹脂可依照用途或因應必要摻合熱安定劑、可塑劑、光安定劑、聚合金屬失活劑、阻燃劑、潤滑劑、抗靜電劑、界面活性劑、抗菌劑、紫外線吸收劑、脫模劑等的添加劑。 In addition, the polycarbonate resin of the present invention may be blended with a heat stabilizer, a plasticizer, a light stabilizer, a polymeric metal deactivator, a flame retardant, a lubricant, an antistatic agent, a surfactant, and an antibacterial agent according to the use or as necessary. Additives such as agents, ultraviolet absorbers, and release agents.
此外,還可依照用途或因應必要摻合熱安定劑、可塑劑、光安定劑、聚合金屬失活劑、阻燃劑、潤滑劑、抗靜電劑、界面活性劑、抗菌劑、紫外線吸收劑、脫模劑等的添加劑。 In addition, heat stabilizers, plasticizers, light stabilizers, polymeric metal deactivators, flame retardants, lubricants, antistatic agents, surfactants, antibacterial agents, ultraviolet absorbers, etc. may be blended according to the application or as necessary. An additive such as a release agent.
本發明之攝像透鏡可藉由射出成形、壓縮成形、射出壓縮成形、熔融擠出成形、澆鑄等的任意方法來成形、加工,特別適合為射出成形。 The image pickup lens of the present invention can be formed and processed by any method such as injection molding, compression molding, injection compression molding, melt extrusion molding, casting, etc., and is particularly suitable for injection molding.
射出成形的成形條件不受特別限定,成形機的料缸溫度係以180~320℃為佳,220~300℃為較佳,240~280℃為更佳。另外,金屬模具溫度係以70~130℃為佳,80~125℃為較佳,90~120℃為更佳。射出壓力係以50~1,700kgf/cm2為佳,500~1,600kgf/cm2為較佳,1,000~1,500kgf/cm2為更佳。 The molding conditions for the injection molding are not particularly limited, and the cylinder temperature of the molding machine is preferably 180 to 320 ° C, preferably 220 to 300 ° C, and more preferably 240 to 280 ° C. Further, the temperature of the metal mold is preferably 70 to 130 ° C, preferably 80 to 125 ° C, and more preferably 90 to 120 ° C. The injection pressure is preferably 50 to 1,700 kgf/cm 2 , more preferably 500 to 1,600 kgf/cm 2 , and more preferably 1,000 to 1,500 kgf/cm 2 .
本發明之攝像透鏡可使用於智慧型手機、數位相機、攝影機等的攝像透鏡。 The image pickup lens of the present invention can be used for an image pickup lens of a smart phone, a digital camera, a video camera or the like.
以下列舉實施例對本發明進一步說明。 The invention is further illustrated by the following examples.
實施例1~3、比較例1~4 Examples 1 to 3 and Comparative Examples 1 to 4
評估是依照下述方法來實施。 The evaluation was carried out in accordance with the following method.
(1)比黏度:使聚合結束後所得到的聚碳酸酯樹脂充分乾燥,並使該顆粒0.7g溶於二氯甲烷100ml而形成溶液,然後測定該溶液在20℃下的比黏度(ηsp)。 (1) Specific viscosity: The polycarbonate resin obtained after completion of the polymerization was sufficiently dried, and 0.7 g of the pellet was dissolved in 100 ml of dichloromethane to form a solution, and then the specific viscosity (ηsp) of the solution at 20 ° C was measured. .
(2)共聚合比:使用日本電子公司製的JNM-AL400的質子NMR進行測定。在7.6~7.8ppm附近,由式(1)的構造產生的峰與0.8~1.1ppm附近的式(2)的構造產生的峰的積分比求得。 (2) Copolymerization ratio: Measurement was carried out by proton NMR of JNM-AL400 manufactured by JEOL Ltd. In the vicinity of 7.6 to 7.8 ppm, the integral ratio of the peak generated by the structure of the formula (1) and the peak of the formula (2) in the vicinity of 0.8 to 1.1 ppm was obtained.
(3)折射率(nD)、阿貝數(ν):使用ATAGO製DR-M2的阿貝折射計,測定藉由射出成形得到的厚度0.3mm、 5mm的圓板在25℃下的折射率。阿貝數是由測定波長=486nm、589nm、656nm的折射率,使用下述式作計算。 (3) Refractive index (nD) and Abbe number (ν): The thickness of the film obtained by injection molding was 0.3 mm using an Abbe refractometer made of ATAGO DR-M2. The refractive index of a 5 mm circular plate at 25 °C. The Abbe number is calculated from the refractive indices of the measurement wavelengths = 486 nm, 589 nm, and 656 nm using the following formula.
ν=(nD-1)/(nF-nC) ν=(nD-1)/(nF-nC)
nD:在波長589nm的折射率 nD: refractive index at a wavelength of 589 nm
nC:在波長656nm的折射率 nC: refractive index at a wavelength of 656 nm
nF:在波長486nm的折射率 nF: refractive index at a wavelength of 486 nm
(4)配向複折射(△n):使聚碳酸酯樹脂溶於二氯甲烷之後,澆鑄在玻璃淺皿上,使其充分乾燥,而製作出厚度100μm的澆鑄薄膜。使該薄膜在玻璃轉移點(Tg)+10℃下延伸2倍,使用日本分光股份有限公司製的橢圓偏光計M-220,測定589nm下的相位差(Re),依照下述式求得配向複折射(△n)。此外,玻璃轉移點是藉由島津製作所製 的DSC-60A,以昇溫速度20℃/min進行測定。 (4) Directional birefringence (?n): After dissolving the polycarbonate resin in methylene chloride, it was cast on a glass dish and sufficiently dried to prepare a cast film having a thickness of 100 μm. The film was stretched twice at a glass transition point (Tg) + 10 ° C, and an ellipsometer M-220 manufactured by JASCO Corporation was used to measure the phase difference (Re) at 589 nm, and the alignment was determined according to the following formula. Birefringence (Δn). In addition, the glass transfer point is made by Shimadzu Corporation. The DSC-60A was measured at a temperature increase rate of 20 ° C / min.
△n=Re/d △n=Re/d
△n:配向複折射 △n: alignment birefringence
Re:相位差 Re: phase difference
d:厚度 d: thickness
(5)吸水率:依據ISO62來測定藉由射出成形得到的板狀成形片。 (5) Water absorption ratio: A plate-shaped formed sheet obtained by injection molding was measured in accordance with ISO62.
(6)透鏡的光學畸變評估:在料缸溫度280℃、金屬模具溫度120℃下,使用住友重機械股份有限公司製的SE30DU射出成形機,將厚度0.2mm、凸面曲率半徑5mm、凹面曲率半徑4mm、 5mm的非球面透鏡射出成形。將非球面透鏡夾在二枚偏光板之間,依照正交偏光法,以目視觀察漏光來評估光學畸變。評估是依照以下基準來進行。 (6) Evaluation of optical distortion of the lens: At a cylinder temperature of 280 ° C and a mold temperature of 120 ° C, a SE30DU injection molding machine manufactured by Sumitomo Heavy Industries Co., Ltd. was used, which has a thickness of 0.2 mm, a convex curvature radius of 5 mm, and a concave radius of curvature. 4mm, A 5 mm aspheric lens was injection molded. The aspherical lens was sandwiched between two polarizing plates, and the optical distortion was evaluated by visually observing the light leakage according to the orthogonal polarization method. The evaluation is based on the following criteria.
◎:幾乎沒有漏光。 ◎: There is almost no light leakage.
○:稍微觀察到漏光。 ○: Light leakage was slightly observed.
×:顯著漏光。 ×: Significant light leakage.
(7)透鏡的成形性評估:藉由與(6)同樣的方法,以目視觀察所成形的非球面透鏡的填充不良、成形不良、透鏡的脆性、金屬模具附著物的有無等。評估是依照成形500枚時,產生缺陷品的機率未達1%(◎)、未達1~5%(○)、未達5~10%(△)、10%以上(×)來分類。 (7) Evaluation of Formability of Lens: By the same method as (6), the filling failure of the formed aspherical lens, the molding failure, the brittleness of the lens, the presence or absence of the deposit of the metal mold, and the like were visually observed. The evaluation is based on the case where 500 pieces are formed, and the probability of producing defective products is less than 1% (◎), less than 1 to 5% (○), less than 5 to 10% (Δ), and 10% or more (×).
將9,9-雙(4-(2-羥基乙氧基)苯基)芴(以下簡記為BPEF)110.50份、3,9-雙(1,1-二甲基-2-羥乙基)-2,4,8,10-四氧螺[5.5]十一烷(以下簡記為SPG)45.05份、碳酸二苯酯87.40份、及作為觸媒的氫氧化鈉8.00×10-5份、四甲基氫氧化銨3.65×10-3份裝入附有攪拌機及蒸餾裝置的反應釜,進行3次氮氣置換,然後將套管加熱至180℃,使原料熔融。完全熔化後,花費20分鐘減壓至20kPa,同時以60℃/hr的速度使套管昇溫至260℃,進行酯交換反應。然後,將套管保持在260℃,花費80分鐘減壓至0.13kPa,在260℃、0.13kPa以下的條件下進行聚合反應30分鐘。反應結束後,將所產生的聚碳酸酯樹脂造粒,同時取出,而得到聚碳酸酯樹脂顆粒。使用該顆粒,測定比黏度、共聚合比、配向複折射,將結果記載於表1。另外,使該顆粒在110℃下乾燥4小時後,藉由射出成形而成形為測試片,折射率(nD)、阿貝數(ν)、吸水率、透鏡的光學畸變評估、透鏡的成形性的測定將結果記載於表1。 1,9-bis(4-(2-hydroxyethoxy)phenyl)indole (hereinafter abbreviated as BPEF) 110.50 parts, 3,9-bis(1,1-dimethyl-2-hydroxyethyl) -2,4,8,10-tetraoxaspiro[5.5]undecane (hereinafter abbreviated as SPG) 45.05 parts, 87.40 parts of diphenyl carbonate, and sodium hydroxide 8.00×10 -5 parts as a catalyst, four Methylammonium hydroxide (3.65 × 10 -3 parts) was placed in a reaction vessel equipped with a stirrer and a distillation apparatus, and nitrogen substitution was performed three times, and then the jacket was heated to 180 ° C to melt the raw material. After complete melting, the pressure was reduced to 20 kPa in 20 minutes while the jacket was heated to 260 ° C at a rate of 60 ° C/hr to carry out a transesterification reaction. Then, the sleeve was kept at 260 ° C, the pressure was reduced to 0.13 kPa in 80 minutes, and the polymerization reaction was carried out for 30 minutes under conditions of 260 ° C and 0.13 kPa or less. After the completion of the reaction, the produced polycarbonate resin was granulated and taken out at the same time to obtain polycarbonate resin pellets. The specific viscosity, the copolymerization ratio, and the complex birefringence were measured using the pellets, and the results are shown in Table 1. Further, the pellet was dried at 110 ° C for 4 hours, and then formed into a test piece by injection molding, refractive index (nD), Abbe number (ν), water absorption, optical distortion evaluation of the lens, and lens formability. The results of the measurement are shown in Table 1.
將BPEF定為105.24份、SPG定為48.70份,除此之外依照與實施例1同樣的方法,得到聚碳酸酯樹脂顆粒。使用該顆粒,與實施例1同樣地進行測定,將結果記載於表1。 Polycarbonate resin pellets were obtained in the same manner as in Example 1 except that the BPEF was changed to 105.24 parts and the SPG was changed to 48.70 parts. The pellets were measured in the same manner as in Example 1 using the pellets, and the results are shown in Table 1.
將BPEF定為98.22份、SPG定為53.57份,除此之外依照與實施例1同樣的方法,得到聚碳酸酯樹脂顆粒。使用該顆粒,與實施例1同樣地進行測定,將結果記載於表1。 Polycarbonate resin pellets were obtained in the same manner as in Example 1 except that the BPEF was 98.22 parts and the SPG was 53.57 parts. The pellets were measured in the same manner as in Example 1 using the pellets, and the results are shown in Table 1.
將BPEF定為87.70份、SPG定為60.88份,除此之外依照與實施例1同樣的方法,得到聚碳酸酯樹脂顆粒。使用該顆粒,與實施例1同樣地進行測定,將結果記載於表1。 Polycarbonate resin pellets were obtained in the same manner as in Example 1 except that the BPEF was 87.70 parts and the SPG was 60.88 parts. The pellets were measured in the same manner as in Example 1 using the pellets, and the results are shown in Table 1.
依照日本特許第3160209號的實施例17所記載的方法,得到聚碳酸酯樹脂顆粒。使用該顆粒,與實施例1同樣地進行測定,將結果記載於表1。透鏡成形性評估時,發現許多透鏡破裂或澆口斷裂,成形性不良。 According to the method described in Example 17 of Japanese Patent No. 3160209, polycarbonate resin pellets were obtained. The pellets were measured in the same manner as in Example 1 using the pellets, and the results are shown in Table 1. When the lens formability was evaluated, many lenses were broken or the gate was broken, and the formability was poor.
將BPEF定為52.62份、SPG定為85.23份,除此之外依照與實施例1同樣的方法,得到聚碳酸酯樹脂顆粒。使用該顆粒,與實施例1同樣地進行測定,將結果記載於表1。 Polycarbonate resin pellets were obtained in the same manner as in Example 1 except that the BPEF was 52.62 parts and the SPG was 85.23 parts. The pellets were measured in the same manner as in Example 1 using the pellets, and the results are shown in Table 1.
使用帝人股份有限公司製的聚碳酸酯樹脂AD-5503,以與實施例1同樣地進行測定,將結果記載於表1。 The polycarbonate resin AD-5503 manufactured by Teijin Co., Ltd. was used for measurement in the same manner as in Example 1, and the results are shown in Table 1.
依照日本特許第5217644號的實施例3所記載的方法,得到聚碳酸酯樹脂顆粒。亦即,將作為聚碳酸酯樹脂的上述IUPILON H-4000(三菱Engineering Plastics股份有限公司製)50.0份與作為苯乙烯樹脂的上述DYLARK D-232(NOVA Chemicals股份有限公司製)50.0份以擠出機在255℃下混練、造粒,而得到光線學透鏡用樹脂組成物的顆粒。 According to the method described in Example 3 of Japanese Patent No. 5,217,644, polycarbonate resin pellets were obtained. In other words, 50.0 parts of the above-mentioned IUPILON H-4000 (manufactured by Mitsubishi Engineering Plastics Co., Ltd.) as a polycarbonate resin and 50.0 parts of the above-mentioned DYLARK D-232 (manufactured by NOVA Chemicals Co., Ltd.) as a styrene resin were extruded. The machine was kneaded and granulated at 255 ° C to obtain pellets of a resin composition for a light lens.
使用該顆粒,與實施例1同樣地進行測定,將結果記載於表1。 The pellets were measured in the same manner as in Example 1 using the pellets, and the results are shown in Table 1.
本發明之攝像透鏡具有特定折射率、阿貝數,而且具有低複折射及低吸水率,因此使用於行動電話、智慧型手機、平板電腦、個人電腦、數位相機、攝影機、行車紀錄器、監視攝影機等的攝像透鏡極為有效。 The image pickup lens of the present invention has a specific refractive index, an Abbe number, and has low birefringence and low water absorption, so it is used in mobile phones, smart phones, tablets, personal computers, digital cameras, cameras, driving recorders, and surveillance. An imaging lens such as a camera is extremely effective.
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| CN111655754B (en) | 2018-03-12 | 2022-08-19 | 帝人株式会社 | Polyester resin or polyester carbonate resin and optical member using the same |
| CN113439099B (en) * | 2019-02-08 | 2022-12-09 | 三菱瓦斯化学株式会社 | Polycarbonate resin composition and optical lens using same |
| US12195622B2 (en) | 2019-02-13 | 2025-01-14 | Teijin Limited | Polycarbonate resin composition or copolymer, and optical film |
| US12281198B2 (en) | 2019-02-27 | 2025-04-22 | Teijin Limited | Thermoplastic resin and optical member |
| CN115916869A (en) * | 2020-06-30 | 2023-04-04 | 帝人株式会社 | Thermoplastic resin and optical part containing the thermoplastic resin |
| JP7582837B2 (en) * | 2020-10-27 | 2024-11-13 | 帝人株式会社 | Resin composition and molded article thereof |
| JP7658759B2 (en) * | 2021-03-09 | 2025-04-08 | 帝人株式会社 | Resin composition and molded article thereof |
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| US20250199203A1 (en) | 2022-03-25 | 2025-06-19 | Teijin Limited | Thermoplastic resin and optical member containing same |
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| JP3160209B2 (en) | 1996-01-30 | 2001-04-25 | 帝人株式会社 | Polycarbonate copolymer containing oxaspiroundecan group and process for producing the same |
| US5859685A (en) * | 1996-07-18 | 1999-01-12 | Innotech, Inc. | Achromatic ophthalmic lenses |
| JP4196326B2 (en) | 2002-06-12 | 2008-12-17 | 三菱瓦斯化学株式会社 | Polycarbonate copolymer |
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| JP5217644B2 (en) | 2007-09-19 | 2013-06-19 | 三菱瓦斯化学株式会社 | Optical lens and manufacturing method thereof |
| JP5883204B2 (en) * | 2007-09-27 | 2016-03-09 | 帝人株式会社 | Method for producing surface protective film or sheet |
| EP2223951A4 (en) * | 2007-12-12 | 2013-08-21 | Mitsubishi Chem Corp | PROCESS FOR PRODUCTION OF POLYCARBONATE AND MOLDINGS IN POLYCARBONATE |
| JP2010077249A (en) * | 2008-09-25 | 2010-04-08 | Teijin Chem Ltd | Film for light transmission layer |
| EP2378320A4 (en) * | 2008-12-16 | 2017-07-19 | Teijin Chemicals, Ltd. | Optical film |
| JP2011079898A (en) * | 2009-10-05 | 2011-04-21 | Teijin Chem Ltd | Polycarbonate resin with low photoelastic constant, and optical film |
| KR101801580B1 (en) * | 2010-05-27 | 2017-11-27 | 미쯔비시 케미컬 주식회사 | Polycarbonate resin and transparent film formed from same |
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