TW201631706A - Memory device and method of fabricating the same - Google Patents
Memory device and method of fabricating the same Download PDFInfo
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- TW201631706A TW201631706A TW104105858A TW104105858A TW201631706A TW 201631706 A TW201631706 A TW 201631706A TW 104105858 A TW104105858 A TW 104105858A TW 104105858 A TW104105858 A TW 104105858A TW 201631706 A TW201631706 A TW 201631706A
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- 238000004519 manufacturing process Methods 0.000 title claims description 17
- 239000000758 substrate Substances 0.000 claims abstract description 103
- 229910052751 metal Inorganic materials 0.000 claims abstract description 74
- 239000002184 metal Substances 0.000 claims abstract description 74
- 239000003990 capacitor Substances 0.000 claims abstract description 34
- 239000000463 material Substances 0.000 claims abstract description 34
- XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 claims description 35
- 239000004020 conductor Substances 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 27
- 238000005496 tempering Methods 0.000 claims description 7
- SCCCLDWUZODEKG-UHFFFAOYSA-N germanide Chemical compound [GeH3-] SCCCLDWUZODEKG-UHFFFAOYSA-N 0.000 claims description 4
- 230000002093 peripheral effect Effects 0.000 claims description 4
- 238000000059 patterning Methods 0.000 claims description 3
- 230000001131 transforming effect Effects 0.000 claims 1
- 239000010410 layer Substances 0.000 description 192
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
- 230000004888 barrier function Effects 0.000 description 8
- 229910052732 germanium Inorganic materials 0.000 description 8
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 8
- 238000002955 isolation Methods 0.000 description 7
- 238000003860 storage Methods 0.000 description 7
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 7
- 229910052721 tungsten Inorganic materials 0.000 description 7
- 239000010937 tungsten Substances 0.000 description 7
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 229910017052 cobalt Inorganic materials 0.000 description 6
- 239000010941 cobalt Substances 0.000 description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- 125000006850 spacer group Chemical group 0.000 description 6
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 6
- 239000011241 protective layer Substances 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 238000005530 etching Methods 0.000 description 4
- 229910001507 metal halide Inorganic materials 0.000 description 4
- 150000005309 metal halides Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
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- 229910052719 titanium Inorganic materials 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910000449 hafnium oxide Inorganic materials 0.000 description 3
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 3
- 229910052715 tantalum Inorganic materials 0.000 description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 3
- NZIHMSYSZRFUQJ-UHFFFAOYSA-N 6-chloro-1h-benzimidazole-2-carboxylic acid Chemical compound C1=C(Cl)C=C2NC(C(=O)O)=NC2=C1 NZIHMSYSZRFUQJ-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- IAOQICOCWPKKMH-UHFFFAOYSA-N dithieno[3,2-a:3',2'-d]thiophene Chemical compound C1=CSC2=C1C(C=CS1)=C1S2 IAOQICOCWPKKMH-UHFFFAOYSA-N 0.000 description 2
- 238000001465 metallisation Methods 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- 239000010955 niobium Substances 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000007517 polishing process Methods 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 229920005591 polysilicon Polymers 0.000 description 2
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 2
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 2
- CXXKWLMXEDWEJW-UHFFFAOYSA-N tellanylidenecobalt Chemical compound [Te]=[Co] CXXKWLMXEDWEJW-UHFFFAOYSA-N 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical group Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- -1 for example Substances 0.000 description 1
- GPMBECJIPQBCKI-UHFFFAOYSA-N germanium telluride Chemical compound [Te]=[Ge]=[Te] GPMBECJIPQBCKI-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 238000005240 physical vapour deposition Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 150000004772 tellurides Chemical class 0.000 description 1
- MAKDTFFYCIMFQP-UHFFFAOYSA-N titanium tungsten Chemical compound [Ti].[W] MAKDTFFYCIMFQP-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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- Semiconductor Memories (AREA)
Abstract
Description
本發明關於一種記憶元件及其製造方法,特別是有關於一種具有淺接面(Shallow Junction)的記憶元件及其製造方法。 The present invention relates to a memory element and a method of fabricating the same, and more particularly to a memory element having a shallow junction and a method of fabricating the same.
在記憶元件的積集度提高與元件尺寸縮小的情況下,元件中的線寬亦逐漸縮小,導致元件中的儲存節點接觸窗(Storage Node Contact)與源極/汲極區之間的接觸電阻增加,產生較慢的電阻-電容延遲(RC Delay),進而影響元件的操作速度。 In the case where the accumulation of memory elements is increased and the size of the components is reduced, the line width in the components is gradually reduced, resulting in contact resistance between the storage node contact and the source/drain regions in the device. The increase, resulting in a slower resistance-capacitance delay (RC Delay), which in turn affects the operating speed of the component.
為了解決此問題,通常會利用金屬矽化物來降低儲存節點接觸窗與源極/汲極區之間的電阻值。但形成金屬矽化物的製程中會使得耗損矽基底中的矽,導致記憶元件的源極/汲極區產生接面漏電(Junction Leakage)的問題,進而影響元件效能。因此,如何降低儲存節點接觸窗與源極/汲極區之間的電阻值,且同時避免接面漏電的問題將變成相當重要的一門課題。 In order to solve this problem, metal telluride is usually used to reduce the resistance between the storage node contact window and the source/drain region. However, in the process of forming a metal telluride, the germanium in the substrate is depleted, causing a problem of junction leakage (Junction Leakage) in the source/drain region of the memory element, thereby affecting the device performance. Therefore, how to reduce the resistance value between the storage node contact window and the source/drain region, and at the same time avoid the problem of junction leakage will become a very important issue.
本發明提供一種具有淺接面的記憶元件及其製造方法,其可降低儲存節點接觸窗的電阻值。 The present invention provides a memory element having a shallow junction and a method of fabricating the same that reduces the resistance value of the storage node contact window.
本發明一種記憶元件包括:位於基底中的多個字元線組、多個位元線、多個電容器及多個接觸插塞。每一字元線組具有兩埋入式字元線。位元線位於基底上且橫越字元線組。電容器位於位元線之間的基底上且位於字元線組的兩側的基底上。接觸插塞位於電容器與基底之間。接觸插塞的材料包括金屬。 A memory element of the present invention includes a plurality of word line sets, a plurality of bit lines, a plurality of capacitors, and a plurality of contact plugs in the substrate. Each word line group has two buried word lines. The bit lines are on the substrate and traverse the group of word lines. Capacitors are located on the substrate between the bit lines and on the substrate on either side of the word line set. The contact plug is located between the capacitor and the substrate. The material of the contact plug includes metal.
本發明提供一種記憶元件的製造方法,其步驟如下。提供基底。上述基底具有第一區與第二區。於第一區的基底上形成多個閘極結構。於第二區的基底上形成多個位元線。進行選擇性磊晶成長製程,以於閘極結構之間的基底上以及位元線之間的基底上形成多個磊晶層。於基底上形成金屬層,以覆蓋磊晶層。進行回火製程,以於閘極結構之間的基底上以及位元線之間的基底上形成多個金屬矽化物層。於閘極結構之間的金屬矽化物層上形成多個第一接觸插塞,且同時於位元線之間的金屬矽化物層上形成多個第二接觸插塞。於第二區的第二接觸插塞上形成多個電容器。 The present invention provides a method of manufacturing a memory element, the steps of which are as follows. A substrate is provided. The substrate has a first zone and a second zone. A plurality of gate structures are formed on the substrate of the first region. A plurality of bit lines are formed on the substrate of the second region. A selective epitaxial growth process is performed to form a plurality of epitaxial layers on the substrate between the gate structures and on the substrate between the bit lines. A metal layer is formed on the substrate to cover the epitaxial layer. A tempering process is performed to form a plurality of metal telluride layers on the substrate between the gate structures and on the substrate between the bit lines. A plurality of first contact plugs are formed on the metal telluride layer between the gate structures, and a plurality of second contact plugs are simultaneously formed on the metal germanide layer between the bit lines. A plurality of capacitors are formed on the second contact plug of the second region.
本發明另一種記憶元件的製造方法,包括:提供基底。基底具有第一區與第二區。於第一區的基底上形成多個閘極結構。於第二區的基底上形成多個位元線。於第一區及第二區的基底上共形形成襯層。於基底上形成金屬層,以覆蓋襯層。進行回火製程,使得襯層轉變成金屬矽化物層。於金屬矽化物層上形成 導體層。圖案化導體層與金屬矽化物層,以於閘極結構之間形成多個第一接觸插塞,且同時於位元線之間形成多個第二接觸插塞。於第二區的第二接觸插塞上形成多個電容器。 Another method of fabricating a memory element of the present invention comprises: providing a substrate. The substrate has a first zone and a second zone. A plurality of gate structures are formed on the substrate of the first region. A plurality of bit lines are formed on the substrate of the second region. A liner is conformally formed on the substrates of the first zone and the second zone. A metal layer is formed on the substrate to cover the liner. A tempering process is performed to convert the liner into a metal halide layer. Formed on the metal telluride layer Conductor layer. The conductor layer and the metallization layer are patterned to form a plurality of first contact plugs between the gate structures, and at the same time a plurality of second contact plugs are formed between the bit lines. A plurality of capacitors are formed on the second contact plug of the second region.
本發明一種記憶元件包括:位於基底中的多個字元線、多個位元線、多個電容器、多個接觸插塞以及多個金屬矽化物層。位元線位於基底上且橫越字元線。電容器位於位元線之間的基底上且位於字元線的兩側的基底上。接觸插塞位於電容器與基底之間。接觸插塞的材料包括金屬。金屬矽化物層位於接觸插塞與基底之間。 A memory element of the present invention includes a plurality of word lines, a plurality of bit lines, a plurality of capacitors, a plurality of contact plugs, and a plurality of metal germanide layers in the substrate. The bit line is on the substrate and traverses the word line. Capacitors are located on the substrate between the bit lines and on the substrate on either side of the word line. The contact plug is located between the capacitor and the substrate. The material of the contact plug includes metal. A metal telluride layer is between the contact plug and the substrate.
基此,本發明可降低儲存節點接觸窗與源極/汲極區之間的電阻值,還可避免耗損矽基底中的矽。為讓本發明上述特徵和優點能更明顯易懂,下文舉實施例並配合圖式詳細說明如下。 Accordingly, the present invention can reduce the resistance value between the storage node contact window and the source/drain region, and can also avoid consuming defects in the substrate. The above described features and advantages of the present invention will be more apparent from the following description.
10、20、30、40、70‧‧‧開口 10, 20, 30, 40, 70‧‧‧ openings
50、60‧‧‧摻雜區 50, 60‧‧‧ doped area
100‧‧‧基底 100‧‧‧Base
101‧‧‧隔離結構 101‧‧‧Isolation structure
102‧‧‧閘極結構 102‧‧‧ gate structure
104、204‧‧‧閘介電層 104, 204‧‧‧ gate dielectric layer
106、110、206、210‧‧‧導體層 106, 110, 206, 210‧‧‧ conductor layers
108、208‧‧‧阻障層 108, 208‧‧‧ barrier layer
112、212‧‧‧頂蓋層 112, 212‧‧‧ top cover
114、214‧‧‧間隙壁 114, 214‧‧ ‧ spacer
116、118、118a、118b、 118c、136、136a‧‧‧介電層 116, 118, 118a, 118b, 118c, 136, 136a‧‧‧ dielectric layer
120‧‧‧硬罩幕層 120‧‧‧hard mask layer
122‧‧‧圖案化的罩幕層 122‧‧‧ patterned mask layer
124、224‧‧‧磊晶層 124, 224‧‧ ‧ epitaxial layer
126、226、126a、226a‧‧‧金屬層 126, 226, 126a, 226a‧‧‧ metal layers
128、228、328、328a、328b‧‧‧金屬矽化物層 128, 228, 328, 328a, 328b‧‧‧ metal telluride layers
130‧‧‧第一接觸插塞 130‧‧‧First contact plug
132‧‧‧導線層 132‧‧‧Wire layer
134、134a‧‧‧保護層 134, 134a‧‧ ‧ protective layer
202‧‧‧位元線 202‧‧‧ bit line
203‧‧‧字元線組 203‧‧‧ character line group
203a、203b‧‧‧埋入式字元線 203a, 203b‧‧‧ Buried word line
230‧‧‧第二接觸插塞 230‧‧‧second contact plug
234‧‧‧電容器 234‧‧‧ capacitor
234a‧‧‧下電極 234a‧‧‧ lower electrode
234b‧‧‧介電層 234b‧‧‧ dielectric layer
234c‧‧‧上電極 234c‧‧‧Upper electrode
240‧‧‧位元線接觸窗 240‧‧‧ bit line contact window
324‧‧‧襯層 324‧‧‧ lining
330‧‧‧導體層 330‧‧‧Conductor layer
232‧‧‧導體墊 232‧‧‧Conductor pad
AA‧‧‧主動區 AA‧‧‧Active Area
D1‧‧‧第一方向 D1‧‧‧ first direction
D2‧‧‧第二方向 D2‧‧‧ second direction
L1‧‧‧長邊 L1‧‧‧ long side
L2‧‧‧短邊 L2‧‧‧ Short side
θ‧‧‧角度 Θ‧‧‧ angle
R1‧‧‧第一區 R1‧‧‧ first district
R2‧‧‧第二區 R2‧‧‧Second District
圖1是本發明之一實施例的記憶元件的上視示意圖。 BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a top plan view of a memory device in accordance with one embodiment of the present invention.
圖2A至圖2G是沿著圖1之A-A線與B-B線之一實施例的記憶元件之製造流程的剖面示意圖。 2A to 2G are schematic cross-sectional views showing a manufacturing flow of the memory element of the embodiment taken along line A-A and line B-B of Fig. 1.
圖3A至圖3F是沿著圖1之A-A線與B-B線之另一實施例的記憶元件之製造流程的剖面示意圖。 3A to 3F are schematic cross-sectional views showing a manufacturing flow of a memory element along another embodiment of the A-A line and the B-B line of Fig. 1.
請參照圖1,本發明提供一種記憶元件包括:基底100、多個閘極結構102、多個第一接觸插塞130、多個字元線組203、多個位元線202、多個主動區AA、多個電容器234以及多個第二接觸插塞230。基底100具有第一區R1與第二區R2。本實施例中,第一區R1例如是周邊電路區,第二區R2例如是記憶胞陣列區。 Referring to FIG. 1, the present invention provides a memory device including: a substrate 100, a plurality of gate structures 102, a plurality of first contact plugs 130, a plurality of word line groups 203, a plurality of bit lines 202, and a plurality of active devices. AA, a plurality of capacitors 234, and a plurality of second contact plugs 230. The substrate 100 has a first region R1 and a second region R2. In this embodiment, the first region R1 is, for example, a peripheral circuit region, and the second region R2 is, for example, a memory cell array region.
閘極結構102位於第一區R1的基底100上。閘極結構102沿第一方向D1延伸,且沿第二方向D2相互排列。第一接觸插塞130位於閘極結構102之間的基底100上。因此本實施例可利用第一接觸插塞130電性連接導線層132及閘極結構102之間的摻雜區50。字元線組203位於第二區R2的基底100中。字元線組203沿著第二方向D2延伸,且沿著第一方向D1相互排列。每一字元線組203具有兩個埋入式字元線203a、203b。但本發明不限制字元線的數量;舉例而言,每一字元線組也可以只有一個字元線,為避免混淆,此種結構便不稱之為字元線組,而只稱之為字元線。位元線202位於第二區R2的基底100上,且橫越字元線組203(或字元線,圖未示)。位元線202沿著第一方向D1延伸,且沿著第二方向D2相互排列。上述字元線組203(或字元線)與上述位元線202實質上互相垂直。 The gate structure 102 is located on the substrate 100 of the first region R1. The gate structures 102 extend in the first direction D1 and are arranged in the second direction D2. The first contact plug 130 is located on the substrate 100 between the gate structures 102. Therefore, the first contact plug 130 can electrically connect the doped region 50 between the wire layer 132 and the gate structure 102. The word line group 203 is located in the substrate 100 of the second region R2. The word line group 203 extends along the second direction D2 and is arranged to each other along the first direction D1. Each word line group 203 has two buried word lines 203a, 203b. However, the present invention does not limit the number of word lines; for example, each word line group can also have only one word line. To avoid confusion, this structure is not called a word line group, but only Is the word line. The bit line 202 is located on the substrate 100 of the second region R2 and traverses the word line group 203 (or word line, not shown). The bit lines 202 extend along the first direction D1 and are arranged along the second direction D2. The above-described word line group 203 (or word line) and the above-described bit line 202 are substantially perpendicular to each other.
主動區AA位於第二區R2的基底100上。每一主動區AA具有長邊L1與短邊L2,且長邊L1橫越對應的字元線組203。每一主動區AA與對應的位元線202的重疊處具有位元線接觸窗240。因此,每一位元線202在橫越對應的字元線組203時,可利 用位元線接觸窗240來電性連接對應的摻雜區(未繪示),所述摻雜區位於兩個埋入式字元線203a、203b之間。 The active area AA is located on the substrate 100 of the second area R2. Each active area AA has a long side L1 and a short side L2, and the long side L1 traverses the corresponding word line group 203. A bit line contact window 240 is present at the overlap of each active area AA and the corresponding bit line 202. Therefore, each bit line 202 is traversable when traversing the corresponding word line group 203 A corresponding doped region (not shown) is electrically connected by a bit line contact window 240, and the doped region is located between the two buried word lines 203a, 203b.
此外,本實施例之記憶元件更包括多個隔離結構101(例如是淺溝渠隔離結構)位於主動區AA之外的第二區R2的基底100中,以電性隔離主動區AA。主動區AA的長邊方向與位元線202的延伸方向呈一角度θ,例如介於10度至40度之間。 In addition, the memory element of the embodiment further includes a plurality of isolation structures 101 (eg, shallow trench isolation structures) located in the substrate 100 of the second region R2 outside the active region AA to electrically isolate the active regions AA. The longitudinal direction of the active area AA is at an angle θ to the direction in which the bit line 202 extends, for example, between 10 and 40 degrees.
電容器234位於位元線202之間的基底100上。電容器234排列成多數列與多數行。電容器234配置於字元線組203的兩側的基底100上,換言之,每兩行的電容器234與具有兩個埋入式字元線203a、203b的字元線組203沿著第一方向D1相互交替。第二接觸插塞230位於電容器234與基底100之間。接觸插塞230的材料包括金屬。本實施例所述金屬包括鎢、氮化鈦(TiN)、鈷、鎳、鋁或其組合。請參照圖2A,本發明提供一種記憶元件的製造方法。首先,提供基底100。基底100具有第一區R1(如周邊電路區)與第二區R2(如記憶胞陣列區)。接著,於第一區R1的基底100上形成多個閘極結構102。閘極結構102由閘介電層104、導體層106、阻障層108、導體層110及頂蓋層112依序堆疊而成。本實施例之閘介電層104的材料例如是氧化矽。導體層106的材料例如是摻雜多晶矽、非摻雜多晶矽或其組合。阻障層108的材料例如是鈦、氮化鈦或其組合。導體層110的材料例如鎢。頂蓋層112的材料例如是氮化矽。閘極結構102的兩側具有間隙壁114。間隙壁114的材料例如是氧化矽、氮化矽或其組合。上述各層的形成 方法為本領域通常知識者所習知,於此不再詳述。然後,於相鄰閘極結構102之間的基底100上形成介電層116。本實施例之介電層的材料例如是氧化矽、氮化矽、硼磷矽玻璃等。之後,進行化學機械研磨製程,以暴露出閘極結構102的頂面。另一方面,於第二區R2的基底100上形成多個位元線202。位元線202由閘介電層204、導體層206、阻障層208、導體層210及頂蓋層212依序堆疊而成。本實施例中位元線202的閘介電層204、導體層206、阻障層208、導體層210及頂蓋層212分別與閘極結構102的閘介電層104、導體層106、阻障層108、導體層110及頂蓋層112的材料和形成方法相同,於此不再贅述。位元線202與閘極結構102不同之處在於其厚度、關鍵尺寸以及線距,此為本領域通常知識者所習知,於此不再詳述。位元線202的兩側具有間隙壁214。間隙壁214的材料例如是氮化矽。然後,於相鄰位元線202之間的基底100上形成介電層216。本實施例之介電層的材料及例如同上述。之後,進行化學機械研磨製程,以暴露出位元線202的頂面。由於介電層116與介電層216是分開形成,因此所述兩者的厚度可以不相同。接著,於第一區R1與第二區R2的基底100上依序形成介電層118、硬罩幕層120及圖案化的罩幕層122。具體地,圖案化罩幕層122具有開口10以及多個開口20。開口10配置於第一區R1中的相鄰閘極結構102之間的基底100上。開口20配置於第二區R2中的相鄰位元線202之間的基底100上。本實施例中,介電層118的材料例如是氧化矽。硬罩幕層120的材料例如 是矽材料、金屬材料或碳材料等。圖案化罩幕層122的材料例如是光阻。此外,本實施例更包括於第二區R2的位元線202下方的基底100中形成隔離結構101(如淺溝渠隔離結構)。隔離結構101的材料例如是摻雜或未摻雜的氧化矽、高密度電漿氧化物、氮氧化矽、旋塗式氧化矽(Spin-on silicon oxide)、低介電常數介電材料或其組合。請參照圖2A、2B,以圖案化罩幕層122為罩幕進行蝕刻製程,以暴露部分基底100的表面。詳細地,先以圖案化罩幕層122為罩幕,移除開口10及開口20下方的硬罩幕層120及介電層118。然後再以圖案化的硬罩幕層120及圖案化的介電層118(未繪示)為罩幕,移除開口10下方的介電層116及開口20下方的介電層216,以於相鄰閘極結構102之間形成開口30,且於相鄰位元線202之間形成多個開口40。開口30暴露第一區R1中的部分基底100的表面;開口40暴露第二區R2中的部分基底100的表面。此外,在進行蝕刻製程之後,第一區R1的基底100上還具有部分介電層118a,其中介電層118a覆蓋閘極結構102上。接著,分別於相鄰閘極結構102之間的基底100中形成摻雜區50,且於相鄰位元線202之間的基底100中形成多個摻雜區60。具體來說,進行離子植入製程,以於開口30、40所暴露的基底100中形成摻雜區50、60。本實施例之基底100具有第一導電型;摻雜區50及摻雜區60具有第二導電型。第一導電型例如是P型;第二導電型例如是N型,反之亦然。本實施例中,摻雜區50所植入的摻質例如是磷或砷,摻雜的濃度例如是1x1015/cm3至 1×1016/cm3;摻雜區60所植入的摻質例如是磷或砷,摻雜的濃度例如是1x1015/cm3至1×1016/cm3。本實施例中,摻雜區50例如是周邊電路區的源極/汲極區;摻雜區60例如是記憶胞陣列區的源極/汲極區。請參照圖2C,進行選擇性磊晶成長(Selective Epitaxial Growth,SEG)製程,以於開口30中形成磊晶層124,且於多個開口40中形成多個磊晶層224。詳細地,由於選擇性磊晶成長製程僅會在被暴露的基底100的表面上進行,因此磊晶層124僅會位於閘極結構102之間的基底100上,磊晶層224只會位於位元線202之間的基底100上。本實施例之磊晶層124及磊晶層224的材料例如是單晶矽、矽化鍺或其組合。磊晶層124的厚度可介於5nm至50nm之間;磊晶層224的厚度可介於5nm至50nm之間。本實施例之磊晶層224可增加摻雜區60(例如源極/汲極區)與後續第二接觸插塞230之間的接面區域的高度(如下圖2D所示),其可降低後續第二接觸插塞230與摻雜區60之間的電阻值,同時可避免耗損基底100中的矽,以解決記憶元件的源極/汲極區之接面漏電的問題。同樣地,磊晶層124亦可降低後續第一接觸插塞130與摻雜區50(例如源極/汲極區)之間的電阻值。請參照圖2C與圖2D,於開口30中共形地形成金屬層126,且於開口40中共形地形成金屬層226,金屬層126覆蓋磊晶層124的表面,而金屬層226覆蓋磊晶層224的表面。在本實施例中,金屬層126、226的材料可例如是鈦、鈷、鎳、鎢或其組合,其厚度可介於10nm至80nm之間。請參照圖2D、2E,進行回火製程,以於閘極結構 102之間的基底100上形成金屬矽化物層128,且同時於位元線202之間的基底100上形成多個金屬矽化物層228。詳細地,金屬層126與磊晶層124接觸的表面以及金屬層226與磊晶層224接觸的表面進行金屬矽化反應,其使得開口30中的磊晶層124轉變為金屬矽化物層128,開口40中的磊晶層224轉變為金屬矽化物層228。由於磊晶層124、224具有足夠厚度,可與其上方的金屬層126反應以分別形成金屬矽化物層128、228,因此不僅可降低後續第一接觸插塞130與摻雜區50(例如源極/汲極區)之間的電阻值,以及降低後續第二接觸插塞230與摻雜區60(例如源極/汲極區)之間的電阻值,且可避免耗損基底100中的矽。如此便可解決記憶元件的源極/汲極區接面漏電的問題。另外,開口30及開口40側壁上還分別殘留未反應的金屬層126a及金屬層226a。本實施例之金屬層126a及金屬層226a可當作第一接觸插塞130及第二接觸插塞230的阻障層。金屬矽化物層128、228的材料例如是矽化鈦、矽化鈷、矽化鎳或其組合,其厚度可介於2nm至80nm之間。接著,分別於開口30中形成第一接觸插塞130,且於多個開口40中形成多個第二接觸插塞230。詳細地,於第一區R1以及第二區R2的基底100上形成導體材料層(未繪示),導體材料層填入開口30以及開口40中,其材料可包括金屬,金屬例如是鎢、氮化鈦、鈷、鎳、鋁或其組合。之後,移除閘極結構102以位元線202表面上的導體材料層,以分別在開口30中形成第一接觸插塞130,且於多個開口40中形成多個第二接觸插塞230。由 於本實施例可同時形成第一接觸插塞130與第二接觸插塞230,因此本實施例可減少製程步驟,進而降低製程成本。另外,本實施例中每一開口40中的第二接觸插塞230及金屬層226a可視為儲存節點接觸窗,其可用以電性連接摻雜區60與後續形成的電容器234。金屬矽化物層128位於摻雜區50與第一接觸插塞130之間,因此金屬矽化物層128可降低第一接觸插塞130與摻雜區50(例如源極/汲極區)之間的電阻值。同樣地,金屬矽化物層228位於摻雜區60與第二接觸插塞230之間,因此金屬矽化物層228可降低第二接觸插塞230與摻雜區60(例如源極/汲極區)之間的電阻值。本實施例所述移除方法可利用化學機械研磨法。請參照圖2F,於第一區R1的第一接觸插塞130上形成導線層132,使導線層132可藉由第一接觸插塞130、金屬矽化物層128來與閘極結構102之間的摻雜區50電性連接。本實施例導線層132的材料例如是鎢、氮化鈦、鈷、鎳、鋁或其組合,其形成方法可以是物理氣相沈積法。接著,於導線層132上共形地形成保護層134,以覆蓋第一區R1的介電層118a及導線層132的表面,且覆蓋第二區R2的位元線202及第二接觸插塞230的表面。本實施例保護層134的材料例如是氧化矽、氮化矽或其組合,其厚度可介於3nm至80nm之間。之後,於保護層134上形成介電層136,其材料例如同介電層116。此外本實施例亦可在形成導線層132的同時,於第二區R2的第二接觸插塞230上形成著陸墊(未繪示),以電性連接後續形成的電容器234。 Capacitor 234 is located on substrate 100 between bit lines 202. The capacitors 234 are arranged in a plurality of columns and a plurality of rows. The capacitor 234 is disposed on the substrate 100 on both sides of the word line group 203, in other words, the capacitor 234 every two rows and the word line group 203 having the two buried word lines 203a, 203b along the first direction D1 Alternate. The second contact plug 230 is located between the capacitor 234 and the substrate 100. The material of the contact plug 230 includes a metal. The metal of this embodiment includes tungsten, titanium nitride (TiN), cobalt, nickel, aluminum, or a combination thereof. Referring to FIG. 2A, the present invention provides a method of fabricating a memory device. First, a substrate 100 is provided. The substrate 100 has a first region R1 (such as a peripheral circuit region) and a second region R2 (such as a memory cell array region). Next, a plurality of gate structures 102 are formed on the substrate 100 of the first region R1. The gate structure 102 is sequentially stacked by the gate dielectric layer 104, the conductor layer 106, the barrier layer 108, the conductor layer 110, and the cap layer 112. The material of the gate dielectric layer 104 of this embodiment is, for example, hafnium oxide. The material of the conductor layer 106 is, for example, doped polysilicon, undoped polysilicon or a combination thereof. The material of the barrier layer 108 is, for example, titanium, titanium nitride, or a combination thereof. The material of the conductor layer 110 is, for example, tungsten. The material of the cap layer 112 is, for example, tantalum nitride. The gate structure 102 has spacers 114 on both sides. The material of the spacers 114 is, for example, ruthenium oxide, tantalum nitride or a combination thereof. The formation of each of the above layers is well known to those of ordinary skill in the art and will not be described in detail herein. A dielectric layer 116 is then formed over the substrate 100 between adjacent gate structures 102. The material of the dielectric layer of this embodiment is, for example, hafnium oxide, tantalum nitride, borophosphonium glass or the like. Thereafter, a chemical mechanical polishing process is performed to expose the top surface of the gate structure 102. On the other hand, a plurality of bit lines 202 are formed on the substrate 100 of the second region R2. The bit line 202 is sequentially stacked by the gate dielectric layer 204, the conductor layer 206, the barrier layer 208, the conductor layer 210, and the cap layer 212. The gate dielectric layer 204, the conductor layer 206, the barrier layer 208, the conductor layer 210, and the cap layer 212 of the bit line 202 in this embodiment are respectively connected to the gate dielectric layer 104, the conductor layer 106, and the gate of the gate structure 102. The material and formation method of the barrier layer 108, the conductor layer 110 and the cap layer 112 are the same, and will not be described herein. The bit line 202 differs from the gate structure 102 in its thickness, critical dimensions, and line spacing, as is well known to those of ordinary skill in the art and will not be described in detail herein. The bit line 202 has spacers 214 on both sides. The material of the spacer 214 is, for example, tantalum nitride. Dielectric layer 216 is then formed over substrate 100 between adjacent bit lines 202. The material of the dielectric layer of this embodiment is, for example, the same as described above. Thereafter, a chemical mechanical polishing process is performed to expose the top surface of the bit line 202. Since the dielectric layer 116 and the dielectric layer 216 are formed separately, the thickness of the two may be different. Next, a dielectric layer 118, a hard mask layer 120, and a patterned mask layer 122 are sequentially formed on the substrate 100 of the first region R1 and the second region R2. Specifically, the patterned mask layer 122 has an opening 10 and a plurality of openings 20. The opening 10 is disposed on the substrate 100 between adjacent gate structures 102 in the first region R1. The opening 20 is disposed on the substrate 100 between adjacent bit lines 202 in the second region R2. In this embodiment, the material of the dielectric layer 118 is, for example, ruthenium oxide. The material of the hard mask layer 120 is, for example, a tantalum material, a metal material, or a carbon material. The material of the patterned mask layer 122 is, for example, a photoresist. In addition, the embodiment further includes forming an isolation structure 101 (such as a shallow trench isolation structure) in the substrate 100 below the bit line 202 of the second region R2. The material of the isolation structure 101 is, for example, doped or undoped cerium oxide, high density plasma oxide, cerium oxynitride, spin-on silicon oxide, low dielectric constant dielectric material or combination. Referring to FIGS. 2A and 2B, an etching process is performed by patterning the mask layer 122 as a mask to expose a portion of the surface of the substrate 100. In detail, the patterned mask layer 122 is used as a mask to remove the hard mask layer 120 and the dielectric layer 118 under the opening 10 and the opening 20. Then, using the patterned hard mask layer 120 and the patterned dielectric layer 118 (not shown) as a mask, the dielectric layer 116 under the opening 10 and the dielectric layer 216 under the opening 20 are removed. Openings 30 are formed between adjacent gate structures 102, and a plurality of openings 40 are formed between adjacent bit lines 202. The opening 30 exposes a surface of a portion of the substrate 100 in the first region R1; the opening 40 exposes a portion of the surface of the substrate 100 in the second region R2. In addition, after performing the etching process, the substrate 100 of the first region R1 further has a portion of the dielectric layer 118a, wherein the dielectric layer 118a covers the gate structure 102. Next, doped regions 50 are formed in the substrate 100 between adjacent gate structures 102, respectively, and a plurality of doped regions 60 are formed in the substrate 100 between adjacent bit lines 202. Specifically, an ion implantation process is performed to form doped regions 50, 60 in the substrate 100 exposed by the openings 30, 40. The substrate 100 of the present embodiment has a first conductivity type; the doping region 50 and the doping region 60 have a second conductivity type. The first conductivity type is, for example, a P type; the second conductivity type is, for example, an N type, and vice versa. In this embodiment, the doping implanted in the doping region 50 is, for example, phosphorus or arsenic, and the doping concentration is, for example, 1×10 15 /cm 3 to 1×10 16 /cm 3 ; the doping of the doped region 60 is implanted. The substance is, for example, phosphorus or arsenic, and the doping concentration is, for example, 1 x 10 15 /cm 3 to 1 × 10 16 /cm 3 . In this embodiment, the doping region 50 is, for example, the source/drain region of the peripheral circuit region; the doping region 60 is, for example, the source/drain region of the memory cell array region. Referring to FIG. 2C, a Selective Epitaxial Growth (SEG) process is performed to form an epitaxial layer 124 in the opening 30 and a plurality of epitaxial layers 224 in the plurality of openings 40. In detail, since the selective epitaxial growth process is only performed on the surface of the exposed substrate 100, the epitaxial layer 124 is only located on the substrate 100 between the gate structures 102, and the epitaxial layer 224 is only in position. On the substrate 100 between the lines 202. The material of the epitaxial layer 124 and the epitaxial layer 224 of the present embodiment is, for example, single crystal germanium, germanium telluride or a combination thereof. The thickness of the epitaxial layer 124 may be between 5 nm and 50 nm; the thickness of the epitaxial layer 224 may be between 5 nm and 50 nm. The epitaxial layer 224 of the present embodiment can increase the height of the junction region between the doped region 60 (eg, the source/drain region) and the subsequent second contact plug 230 (as shown in FIG. 2D below), which can be reduced The resistance value between the second contact plug 230 and the doping region 60 is subsequently avoided, and the defect in the substrate 100 can be avoided to solve the problem of junction leakage of the source/drain region of the memory device. Similarly, epitaxial layer 124 can also reduce the resistance between subsequent first contact plugs 130 and doped regions 50 (eg, source/drain regions). Referring to FIG. 2C and FIG. 2D, a metal layer 126 is conformally formed in the opening 30, and a metal layer 226 is formed conformally in the opening 40. The metal layer 126 covers the surface of the epitaxial layer 124, and the metal layer 226 covers the epitaxial layer. The surface of 224. In this embodiment, the material of the metal layers 126, 226 may be, for example, titanium, cobalt, nickel, tungsten or a combination thereof, and may have a thickness of between 10 nm and 80 nm. Referring to FIGS. 2D and 2E, a tempering process is performed to form a metal telluride layer 128 on the substrate 100 between the gate structures 102, and simultaneously form a plurality of metal tellurides on the substrate 100 between the bit lines 202. Layer 228. In detail, the surface of the metal layer 126 in contact with the epitaxial layer 124 and the surface of the metal layer 226 in contact with the epitaxial layer 224 undergo a metal deuteration reaction, which causes the epitaxial layer 124 in the opening 30 to be transformed into a metal telluride layer 128, opening The epitaxial layer 224 in 40 is converted to a metal telluride layer 228. Since the epitaxial layers 124, 224 have sufficient thickness, they can react with the metal layer 126 above them to form the metal germanide layers 128, 228, respectively, thereby not only reducing the subsequent first contact plugs 130 and doped regions 50 (eg, source) The resistance value between the /pole region) and the resistance value between the subsequent second contact plug 230 and the doped region 60 (eg, the source/drain region), and loss of germanium in the substrate 100 can be avoided. In this way, the problem of leakage of the source/drain region of the memory element can be solved. Further, the unreacted metal layer 126a and the metal layer 226a remain on the sidewalls of the opening 30 and the opening 40, respectively. The metal layer 126a and the metal layer 226a of the present embodiment can be used as a barrier layer of the first contact plug 130 and the second contact plug 230. The material of the metal telluride layers 128, 228 is, for example, titanium telluride, cobalt telluride, nickel telluride or combinations thereof, and may have a thickness between 2 nm and 80 nm. Next, a first contact plug 130 is formed in the opening 30, and a plurality of second contact plugs 230 are formed in the plurality of openings 40. In detail, a conductive material layer (not shown) is formed on the substrate 100 of the first region R1 and the second region R2, and the conductive material layer is filled in the opening 30 and the opening 40, and the material thereof may include a metal, for example, tungsten. Titanium nitride, cobalt, nickel, aluminum or a combination thereof. Thereafter, the gate structure 102 is removed from the conductor material layer on the surface of the bit line 202 to form a first contact plug 130 in the opening 30, respectively, and a plurality of second contact plugs 230 are formed in the plurality of openings 40. . Since the first contact plug 130 and the second contact plug 230 can be formed at the same time in this embodiment, the embodiment can reduce the process steps, thereby reducing the process cost. In addition, the second contact plug 230 and the metal layer 226a in each opening 40 in this embodiment can be regarded as a storage node contact window, which can be used to electrically connect the doping region 60 with the subsequently formed capacitor 234. The metal telluride layer 128 is located between the doped region 50 and the first contact plug 130, such that the metal telluride layer 128 can reduce between the first contact plug 130 and the doped region 50 (eg, the source/drain region) The resistance value. Similarly, the metal telluride layer 228 is located between the doped region 60 and the second contact plug 230, so the metal telluride layer 228 can lower the second contact plug 230 and the doped region 60 (eg, source/drain regions) The resistance value between). The removal method described in this embodiment can utilize a chemical mechanical polishing method. Referring to FIG. 2F, a wire layer 132 is formed on the first contact plug 130 of the first region R1, so that the wire layer 132 can be separated from the gate structure 102 by the first contact plug 130 and the metal telluride layer 128. The doped regions 50 are electrically connected. The material of the wire layer 132 of this embodiment is, for example, tungsten, titanium nitride, cobalt, nickel, aluminum or a combination thereof, and the formation method thereof may be physical vapor deposition. Next, a protective layer 134 is formed conformally on the wire layer 132 to cover the surface of the dielectric layer 118a and the wire layer 132 of the first region R1, and covers the bit line 202 and the second contact plug of the second region R2. The surface of 230. The material of the protective layer 134 of this embodiment is, for example, hafnium oxide, tantalum nitride or a combination thereof, and the thickness thereof may be between 3 nm and 80 nm. Thereafter, a dielectric layer 136 is formed over the protective layer 134, such as the same dielectric layer 116. In addition, in this embodiment, a landing pad (not shown) is formed on the second contact plug 230 of the second region R2 to electrically connect the subsequently formed capacitor 234.
請參照圖2G,於第二區R2的第二接觸插塞230上形成多個電容器234。具體來說,每一電容器234包括下電極234a、上電極234c及介電層234b。每一介電層234b位於下電極234a與上電極234c之間。每一下電極234a與所對應的第二接觸插塞230電性連接。在一實施例中,介電層234b可包括高介電常數材料層,其材料例如是下述元素的氧化物,如:鉿、鋯、鋁、鈦、鑭、釔、釓或鉭,又或是氮化鋁,或是上述任意組合。下電極234a與上電極234c的材料例如是氮化鈦、氮化鉭、鎢、鈦鎢、鋁、銅或金屬矽化物。請參照圖3A與圖3B,本發明提供另一種記憶元件的製造方法,其步驟如下。由於圖3A的結構、製造流程與所述圖2A的結構、製造流程相同,於此便不再贅述。之後,如圖3B所示,以圖案化的罩幕層122為罩幕,進行蝕刻製程,以暴露部分基底100的表面。接著,分別於相鄰閘極結構102之間的基底100中形成摻雜區50,且於相鄰位元線202之間的基底100中形成多個摻雜區60。值得一提的是,圖3B與圖2B的製造流程基本上相似,但其不同之處在於:在進行所述蝕刻製程之後,圖3B之第二區R2的基底100上還具有部分介電層118a,其中介電層118a覆蓋位元線202上。接著,請參照圖3C,於第一區R1以及第二區R2的基底100上共形地形成襯層(Liner Layer)324。襯層324覆蓋第一區R1的介電層118a及開口30的表面,且覆蓋第二區R2的的介電層118a及開口40的表面。本實施例中襯層324的材料例如是多晶矽、非晶矽或其組合,其厚度可介於2nm至15nm之間。 Referring to FIG. 2G, a plurality of capacitors 234 are formed on the second contact plugs 230 of the second region R2. Specifically, each capacitor 234 includes a lower electrode 234a, an upper electrode 234c, and a dielectric layer 234b. Each dielectric layer 234b is located between the lower electrode 234a and the upper electrode 234c. Each lower electrode 234a is electrically connected to the corresponding second contact plug 230. In an embodiment, the dielectric layer 234b may include a high dielectric constant material layer, such as an oxide of the following elements, such as: yttrium, zirconium, aluminum, titanium, tantalum, niobium, tantalum or niobium, or It is aluminum nitride or any combination of the above. The material of the lower electrode 234a and the upper electrode 234c is, for example, titanium nitride, tantalum nitride, tungsten, titanium tungsten, aluminum, copper or metal halide. Referring to FIG. 3A and FIG. 3B, the present invention provides another method of manufacturing a memory element, the steps of which are as follows. The structure and manufacturing process of FIG. 3A are the same as those of the structure and manufacturing process of FIG. 2A, and thus will not be described again. Thereafter, as shown in FIG. 3B, an etching process is performed with the patterned mask layer 122 as a mask to expose a portion of the surface of the substrate 100. Next, doped regions 50 are formed in the substrate 100 between adjacent gate structures 102, respectively, and a plurality of doped regions 60 are formed in the substrate 100 between adjacent bit lines 202. It is worth mentioning that the manufacturing process of FIG. 3B is substantially similar to that of FIG. 2B, but the difference is that after performing the etching process, the substrate 100 of the second region R2 of FIG. 3B further has a partial dielectric layer. 118a, wherein dielectric layer 118a covers bit line 202. Next, referring to FIG. 3C, a liner layer 324 is conformally formed on the substrate 100 of the first region R1 and the second region R2. The liner layer 324 covers the dielectric layer 118a of the first region R1 and the surface of the opening 30, and covers the dielectric layer 118a of the second region R2 and the surface of the opening 40. The material of the liner layer 324 in this embodiment is, for example, polycrystalline germanium, amorphous germanium or a combination thereof, and the thickness thereof may be between 2 nm and 15 nm.
請參照圖3C與圖3D,然後,於襯層324上共形地形成金屬層(未繪示)。本實施例中金屬層的材料例如是鈦、鈷、鎳、鎢或其組合,其厚度可介於10nm至80nm之間。之後,進行回火製程,使得襯層324轉變成金屬矽化物層328。詳細地,所述金屬層(未繪示)與襯層324所接觸的表面進行金屬矽化反應,其使得所述襯層324轉變為金屬矽化物層328。本實施例金屬矽化物層328的材料例如是矽化鈦、矽化鈷、矽化鎳或其組合,其厚度可介於2nm至80nm之間。同上述實施例,由於襯層324具有足夠厚度,可與其上方的金屬層反應以形成金屬矽化物層328,因此,其不僅可降低後續第一接觸插塞130與摻雜區50(例如源極/汲極區)之間的電阻值,以及降低後續第二接觸插塞230與摻雜區60(例如源極/汲極區)之間的電阻值,且可避免耗損基底100中的矽。如此便可解決記憶元件的源極/汲極區之接面漏電的問題。接著,於金屬矽化物層328上形成導體層330。導體層330填入開口30與開口40,且覆蓋金屬矽化物層328上。本實施例之導體層330的材料例如是氮化鈦、鈷、鎳、鋁或其組合,其厚度可介於10nm至80nm之間。 Referring to FIG. 3C and FIG. 3D, a metal layer (not shown) is formed conformally on the liner layer 324. The material of the metal layer in this embodiment is, for example, titanium, cobalt, nickel, tungsten or a combination thereof, and the thickness thereof may be between 10 nm and 80 nm. Thereafter, a tempering process is performed to cause the liner layer 324 to be converted into a metal telluride layer 328. In detail, the surface of the metal layer (not shown) that is in contact with the liner layer 324 undergoes a metal deuteration reaction that causes the liner layer 324 to be converted into a metal telluride layer 328. The material of the metal telluride layer 328 of the present embodiment is, for example, titanium telluride, cobalt telluride, nickel telluride or a combination thereof, and the thickness thereof may be between 2 nm and 80 nm. As with the above embodiment, since the liner layer 324 has a sufficient thickness, it can react with the metal layer above it to form the metal telluride layer 328, so that it can not only lower the subsequent first contact plug 130 and the doping region 50 (eg, source) The resistance value between the /pole region) and the resistance value between the subsequent second contact plug 230 and the doped region 60 (eg, the source/drain region), and loss of germanium in the substrate 100 can be avoided. This solves the problem of junction leakage of the source/drain regions of the memory device. Next, a conductor layer 330 is formed on the metal telluride layer 328. Conductor layer 330 fills opening 30 and opening 40 and overlying metal halide layer 328. The material of the conductor layer 330 of this embodiment is, for example, titanium nitride, cobalt, nickel, aluminum or a combination thereof, and the thickness thereof may be between 10 nm and 80 nm.
請參照圖3D、3E,圖案化導體層330與金屬矽化物層328,以於閘極結構102之間形成多個第一接觸插塞130,且同時於位元線202之間形成多個第二接觸插塞230。詳細地,在形成第一接觸插塞130的同時亦形成導線層132,導線層132位於第一接觸插塞130上,其可藉由第一接觸插塞130、金屬矽化物層328a 與閘極結構102之間的摻雜區50電性連接。金屬矽化物層328a位於第一接觸插塞130與摻雜區50之間,可降低第一接觸插塞130與摻雜區50之間的電阻值。同樣地,在形成第二接觸插塞230的同時亦形成導體墊232,導體墊232位於第一接觸插塞130上,其可藉由第二接觸插塞230、金屬矽化物層328b與位元線202之間的摻雜區60電性連接。本實施例之導體墊232可視為著陸墊。金屬矽化物層328b位於第二接觸插塞230與摻雜區60之間,可降低第二接觸插塞230與摻雜區60之間的電阻值。另外,在進行所述圖案化製程,亦移除部分介電層118a,以於第一區R1的閘極結構102上形成介電層118b,且於第二區R2的位元線202上形成介電層118c。部分金屬矽化物層328a位於介電層118b與導線層132之間;而部分金屬矽化物層328b亦位於介電層118c與導體墊232之間。 Referring to FIGS. 3D and 3E, the patterned conductor layer 330 and the metallization layer 328 are formed to form a plurality of first contact plugs 130 between the gate structures 102, and at the same time form a plurality of first lines between the bit lines 202. Two contact plugs 230. In detail, a wire layer 132 is also formed at the same time as the first contact plug 130 is formed. The wire layer 132 is located on the first contact plug 130, which can be formed by the first contact plug 130 and the metal telluride layer 328a. The doped region 50 between the gate structure 102 is electrically connected. The metal telluride layer 328a is located between the first contact plug 130 and the doped region 50 to reduce the resistance between the first contact plug 130 and the doped region 50. Similarly, a conductor pad 232 is formed at the same time as the second contact plug 230 is formed. The conductor pad 232 is located on the first contact plug 130, which can be connected to the bit by the second contact plug 230, the metal telluride layer 328b. The doped regions 60 between the lines 202 are electrically connected. The conductor pad 232 of this embodiment can be regarded as a landing pad. The metal telluride layer 328b is located between the second contact plug 230 and the doped region 60 to reduce the resistance between the second contact plug 230 and the doped region 60. In addition, during the patterning process, a portion of the dielectric layer 118a is also removed to form a dielectric layer 118b on the gate structure 102 of the first region R1, and formed on the bit line 202 of the second region R2. Dielectric layer 118c. A portion of the metal telluride layer 328a is between the dielectric layer 118b and the wire layer 132; and a portion of the metal halide layer 328b is also between the dielectric layer 118c and the conductor pad 232.
請參照圖3E、3F,於第二區R2的第二接觸插塞230上形成多個電容器234。具體地,先於基底100上形成介電層136。介電層136覆蓋第一區R1的介電層118b及導線層132的表面,且填入第二區R2的開口70中,並覆蓋第二區R2的介電層118c及導體墊232的表面。之後,在第二區R2的介電層136中形成電容器234。每一電容器234與所對應的導體墊232電性連接。 Referring to FIGS. 3E and 3F, a plurality of capacitors 234 are formed on the second contact plug 230 of the second region R2. Specifically, a dielectric layer 136 is formed on the substrate 100. The dielectric layer 136 covers the surface of the dielectric layer 118b and the wiring layer 132 of the first region R1, and fills the opening 70 of the second region R2, and covers the dielectric layer 118c of the second region R2 and the surface of the conductor pad 232. . Thereafter, a capacitor 234 is formed in the dielectric layer 136 of the second region R2. Each capacitor 234 is electrically connected to a corresponding conductor pad 232.
綜上所述,本發明之一實施例利用選擇性磊晶成長製程,在閘極結構之間的摻雜區上及位元線之間的摻雜區上形成多個磊晶層。另一方面,本發明之另一實施例是在基底上形成襯層 覆蓋摻雜區。在進行後續回火製程時,上述磊晶層以及襯層可用以參與金屬矽化反應,以形成金屬矽化物層。如此,本發明不僅可降低儲存節點接觸窗與記憶胞陣列區的源極/汲極區之間的電阻值,同時亦可避免耗損矽基底中的矽,解決記憶元件的源極/汲極區之接面漏電的問題。此外,本發明可於第一區與第二區上同時形成接觸插塞,可減少製程步驟,降低製程成本。 In summary, an embodiment of the present invention utilizes a selective epitaxial growth process to form a plurality of epitaxial layers on a doped region between gate structures and a doped region between bit lines. In another aspect, another embodiment of the invention is to form a liner on a substrate Cover the doped area. The epitaxial layer and the underlayer may be used to participate in the metal deuteration reaction to form a metal telluride layer during the subsequent tempering process. Thus, the present invention can not only reduce the resistance between the storage node contact window and the source/drain region of the memory cell array region, but also avoid the loss of germanium in the germanium substrate and solve the source/drain region of the memory device. The problem of leakage at the junction. In addition, the present invention can simultaneously form contact plugs on the first zone and the second zone, which can reduce the process steps and reduce the process cost.
50、60‧‧‧摻雜區 50, 60‧‧‧ doped area
100‧‧‧基底 100‧‧‧Base
101‧‧‧隔離結構 101‧‧‧Isolation structure
102‧‧‧閘極結構 102‧‧‧ gate structure
104、204‧‧‧閘介電層 104, 204‧‧‧ gate dielectric layer
106、110、206、210‧‧‧導體層 106, 110, 206, 210‧‧‧ conductor layers
108、208‧‧‧阻障層 108, 208‧‧‧ barrier layer
112、212‧‧‧頂蓋層 112, 212‧‧‧ top cover
114、214‧‧‧間隙壁 114, 214‧‧ ‧ spacer
116、118a、136a‧‧‧介電層 116, 118a, 136a‧‧‧ dielectric layer
126a、226a‧‧‧金屬層 126a, 226a‧‧‧ metal layer
128、228‧‧‧金屬矽化物層 128, 228‧‧‧metal telluride layer
130‧‧‧第一接觸插塞 130‧‧‧First contact plug
132‧‧‧導線層 132‧‧‧Wire layer
134a‧‧‧保護層 134a‧‧ ‧ protective layer
202‧‧‧位元線 202‧‧‧ bit line
230‧‧‧第二接觸插塞 230‧‧‧second contact plug
234‧‧‧電容器 234‧‧‧ capacitor
234a‧‧‧下電極 234a‧‧‧ lower electrode
234b‧‧‧介電層 234b‧‧‧ dielectric layer
234c‧‧‧上電極 234c‧‧‧Upper electrode
R1‧‧‧第一區 R1‧‧‧ first district
R2‧‧‧第二區 R2‧‧‧Second District
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| TWI667770B (en) * | 2017-05-25 | 2019-08-01 | 華邦電子股份有限公司 | Dynamic random access memory and method of manufacturing the same |
| CN112542458A (en) * | 2019-09-23 | 2021-03-23 | 南亚科技股份有限公司 | Semiconductor device and method for manufacturing the same |
| CN112542458B (en) * | 2019-09-23 | 2024-03-05 | 南亚科技股份有限公司 | Semiconductor components and manufacturing methods |
| TWI718806B (en) * | 2019-12-11 | 2021-02-11 | 華邦電子股份有限公司 | Memory device and method of manufacturing the same |
| TWI766609B (en) * | 2021-03-10 | 2022-06-01 | 華邦電子股份有限公司 | Semiconductor memory structure |
| CN115223995A (en) * | 2021-04-20 | 2022-10-21 | 华邦电子股份有限公司 | Semiconductor memory structure |
| CN115223995B (en) * | 2021-04-20 | 2025-05-06 | 华邦电子股份有限公司 | Semiconductor memory structure |
| TWI836976B (en) * | 2022-05-09 | 2024-03-21 | 南韓商三星電子股份有限公司 | Semiconductor memory devices |
| TWI868699B (en) * | 2023-05-19 | 2025-01-01 | 華邦電子股份有限公司 | Semiconductor structure and manufacturing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| TWI557850B (en) | 2016-11-11 |
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