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TW201439348A - PVD processing device and PVD processing method - Google Patents

PVD processing device and PVD processing method Download PDF

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Publication number
TW201439348A
TW201439348A TW103109645A TW103109645A TW201439348A TW 201439348 A TW201439348 A TW 201439348A TW 103109645 A TW103109645 A TW 103109645A TW 103109645 A TW103109645 A TW 103109645A TW 201439348 A TW201439348 A TW 201439348A
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stage
revolution
rotation
substrate
film
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TWI522486B (en
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藤井博文
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神戶製鋼所股份有限公司
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/50Substrate holders
    • C23C14/505Substrate holders for rotation of the substrates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/24Vacuum evaporation
    • C23C14/32Vacuum evaporation by explosion; by evaporation and subsequent ionisation of the vapours, e.g. ion-plating
    • C23C14/325Electric arc evaporation
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physical Vapour Deposition (AREA)
  • Coating Apparatus (AREA)

Abstract

提供一種藉由基材之自轉及公轉,而能夠在基材之外周面形成具有圓周方向均一性優異之膜厚的複合皮膜的PVD處理裝置(1)及方法。PVD處理裝置(1)係具備:真空腔室;及公轉載台,用以在真空腔室內使複數個基材(W)繞公轉軸(7)而公轉;及自轉載台(4),用以使各基材(W)在公轉載台上繞與公轉軸(7)呈平行之自轉軸(8)而自轉;及複數種靶材(5),設置於在公轉載台之徑向外側且在圓周方向相互地分離的位置;以及載台旋轉機構(6),在基材(W)通過從各靶材(5)之中央對包絡各自轉載台(4)之圓弧所拉出的二條切線(L1、L2)之間的期間使自轉載台(4)以180°以上之角度進行自轉。Provided is a PVD processing apparatus (1) and a method capable of forming a composite film having a film thickness excellent in circumferential uniformity on a peripheral surface of a substrate by the rotation and revolution of the substrate. The PVD processing apparatus (1) includes: a vacuum chamber; and a revolving stage for revolving a plurality of substrates (W) around the revolving shaft (7) in the vacuum chamber; and the self-rotating stage (4) The substrate (W) is rotated on the revolution stage by a rotation axis (8) parallel to the revolution axis (7); and the plurality of targets (5) are disposed on the radially outer side of the revolution stage. And a position at which the circumferential direction is separated from each other; and the stage rotating mechanism (6) is pulled out from the arc of each of the targets (4) by the center of each of the targets (5) The period between the two tangent lines (L1, L2) causes the self-rotating stage (4) to rotate at an angle of 180 or more.

Description

PVD處理裝置以及PVD處理方法 PVD processing device and PVD processing method

本發明係關於一種PVD處理裝置以及PVD處理方法。 The present invention relates to a PVD processing apparatus and a PVD processing method.

以提高切削工具之耐磨損性、或提高機械零件之滑動面的滑動特性為目的,來對切削工具及作為機械零件的基材(成膜對象物),進行物理蒸鍍(PVD)法之成膜、具體而言為TiN、TiAlN、CrN等的皮膜之形成。作為用於如此之成膜的裝置,已知的有電弧離子鍍膜(arc ion plating)(AIP)裝置或濺鍍(sputtering)裝置等的PVD處理裝置。 For the purpose of improving the wear resistance of the cutting tool or improving the sliding characteristics of the sliding surface of the mechanical component, the cutting tool and the substrate (the object to be film-formed) as the mechanical component are subjected to physical vapor deposition (PVD). The film formation, specifically, the formation of a film of TiN, TiAlN, CrN or the like. As a device for such film formation, a PVD treatment device such as an arc ion plating (AIP) device or a sputtering device is known.

作為如此的PVD處理裝置,已知的有組合複數個PVD方法來形成複合皮膜者。例如,以電弧離子鍍膜方法在基材(工件)之表面形成硬質皮膜,接著以濺鍍裝置在硬質皮膜之上方形成潤滑皮膜。可以藉由如此地交互使用複數種PVD方法而在基材之表面形成複合皮膜。 As such a PVD processing apparatus, it is known to combine a plurality of PVD methods to form a composite film. For example, a hard film is formed on the surface of a substrate (workpiece) by an arc ion plating method, and then a lubricating film is formed on the hard film by a sputtering apparatus. A composite film can be formed on the surface of the substrate by using a plurality of PVD methods in this way.

例如,在專利文獻1中有揭示以下的PVD處理裝置,其具備:容納濺鍍蒸發源及真空電弧蒸發源之雙 方的腔室(chamber);及基板保持具(holder);以及使用前述兩蒸發源中之一方時用以閉鎖另一方之蒸發源的開閉器(shutter),且能夠藉由依序限制兩蒸發源之使用、或是同時使用兩蒸發源,來將複數種皮膜形成於基材。在該PVD處理裝置中,係以各自的蒸發源之靶材轉向相同之方向的方式使此等的蒸發源並排。前述基板保持具,係在前述基板從各自的蒸發源之靶材僅離開一定距離的位置保持該基板,且使其旋轉。前述基板係藉由該旋轉而從正對於一方之靶材的位置移動至正對於另一方之靶材的位置,藉此,能夠在雙方之靶材的正面交互地進行成膜以形成複合皮膜。 For example, Patent Document 1 discloses a PVD processing apparatus having a double chamber containing a sputtering evaporation source and a vacuum arc evaporation source. a chamber; and a substrate holder; and a shutter for blocking the evaporation source of the other side when one of the two evaporation sources is used, and capable of sequentially limiting the two evaporation sources by sequentially A plurality of types of films are formed on the substrate by using or simultaneously using two evaporation sources. In the PVD processing apparatus, the evaporation sources are arranged side by side in such a manner that the targets of the respective evaporation sources are turned in the same direction. In the substrate holder, the substrate is held and rotated while the substrate is separated from the target of the respective evaporation source by a predetermined distance. The substrate is moved from the position of one of the targets to the position of the other target by the rotation, whereby the film can be formed alternately on the front surface of both targets to form a composite film.

又,在專利文獻2有揭示一種PVD處理裝置,其具備:容納濺鍍蒸發源及真空電弧蒸發源的真空腔室;以及設置於前述真空腔室之內部的圓筒狀之夾具,且在該夾具之外周面安裝有基材。在該裝置中,係能夠藉由使前述夾具公轉(旋轉)而依序使用兩蒸發源,藉此可以將複數種薄膜形成於基材之表面。 Further, Patent Document 2 discloses a PVD processing apparatus including: a vacuum chamber that houses a sputtering evaporation source and a vacuum arc evaporation source; and a cylindrical jig provided inside the vacuum chamber, and A substrate is mounted on the outer surface of the jig. In this apparatus, two evaporation sources can be sequentially used by revolving (rotating) the jig, whereby a plurality of films can be formed on the surface of the substrate.

在上述之專利文獻1或專利文獻2的PVD處理裝置中,只要在成膜對象是形成平板狀的基板之情況就能夠形成具有均等膜厚的皮膜,但是很難對如鑽頭(drill)或刀具(chip)等般之圓筒狀構件的外周面進行成膜。因為在圓筒狀之構件的外周面進行成膜時必須使該構件即基材自轉,但是在專利文獻1或專利文獻2之PVD處理裝置上並未設置有使基材自轉的機構。故而,在專利文獻1或 專利文獻2之PVD處理裝置中,並無法對如前述之構件進行成膜。 In the PVD processing apparatus of the above-described Patent Document 1 or Patent Document 2, it is possible to form a film having a uniform film thickness in the case where a film formation target is a flat substrate, but it is difficult to apply to a drill or a cutter. The outer peripheral surface of the cylindrical member such as (chip) is formed into a film. When the film is formed on the outer peripheral surface of the cylindrical member, it is necessary to rotate the substrate, that is, the substrate is not provided with a mechanism for rotating the substrate in the PVD processing apparatus of Patent Document 1 or Patent Document 2. Therefore, in Patent Document 1 or In the PVD processing apparatus of Patent Document 2, it is not possible to form a film as described above.

另外,即便是在上述的PVD處理裝置中,例如只要在成膜中不僅進行基材之公轉就連基材之自轉也進行的話,就能夠進行上述複合皮膜之形成。例如,在真空腔室內設置繞公轉軸而公轉的公轉載台、在公轉載台上設置繞與公轉軸呈平行之自轉軸而自轉的自轉載台、將基材搭載於該自轉載台並使基材自轉及公轉、以及在公轉載台之徑向外側設置不同種類之蒸發源,藉此就可以在基材之表面形成上述的複合皮膜。 Further, even in the above-described PVD processing apparatus, for example, the formation of the composite film can be performed by performing the rotation of the substrate in the film formation without performing the revolving of the substrate. For example, a revolving stage that revolves around a revolution axis is provided in a vacuum chamber, and a revolving stage that rotates around a rotation axis parallel to the revolution axis is provided on the revolving stage, and the substrate is mounted on the rotation stage. The composite film can be formed on the surface of the substrate by rotating and revolving the substrate and by providing different types of evaporation sources on the radially outer side of the revolution stage.

然而,即便是在使用具備上述自公轉功能的裝置等來使基材自轉及公轉的情況,當自轉載台對公轉載台之旋轉比(齒輪比)未被設定於適當的數值時,亦有無法獲得均質之複合皮膜的問題。例如在自轉載台與公轉載台之旋轉比被設定於適當的數值之情況,雖然能獲得圓環狀之皮膜積層成同心狀的剖面形狀之複合皮膜,但是在自轉載台與公轉載台之旋轉比未被設定於適當的數值之情況,則恐有形成具有不均質之構造的複合皮膜之虞。具體而言,恐有如圓環中之圓周方向之一部分缺損的C字狀之皮膜包含於複合皮膜中、或是發生圓環中之圓周方向之一部分重疊的皮膜之虞。 However, even when the substrate is rotated and revolved using a device having the above-described self-revolving function, when the rotation ratio (gear ratio) of the self-rotating stage to the revolution table is not set to an appropriate value, The problem of a homogeneous composite film cannot be obtained. For example, in the case where the rotation ratio of the rotation stage and the revolution stage is set to an appropriate value, a composite film in which a ring-shaped film layer is formed into a concentric shape can be obtained, but in the rotation stage and the revolution stage. When the rotation ratio is not set to an appropriate value, there is a fear that a composite film having a structure having an uneven structure is formed. Specifically, there is a fear that a C-shaped film which is partially deficient in one of the circumferential directions of the ring is contained in the composite film or a film which partially overlaps one of the circumferential directions in the ring.

[先前技術文獻] [Previous Technical Literature]

[專利文獻] [Patent Literature]

專利文獻1:日本特開平11-200042號公報 Patent Document 1: Japanese Patent Laid-Open No. Hei 11-200042

專利文獻2:日本特許第2836876號公報 Patent Document 2: Japanese Patent No. 2836876

本發明之目的係在於提供一種可以藉由使基材自轉及公轉而在該基材之外周面形成優異之複合皮膜的PVD處理裝置及PVD處理方法。 An object of the present invention is to provide a PVD processing apparatus and a PVD processing method which can form an excellent composite film on the outer peripheral surface of the substrate by rotating and revolving the substrate.

本發明所提供者是一種用以在複數個基材之表面進行成膜的PVD處理裝置,其具備:真空腔室,用以容納前述複數個基材;及公轉載台,設置於前述真空腔室內,用以一邊支撐前述複數個基材一邊使此等的基材繞公轉軸而公轉;及複數個自轉載台,一邊支撐前述複數個基材之各基材一邊使該基材在前述公轉載台上繞與前述公轉軸呈平行之自轉軸而自轉;及複數個靶材,由互為不同種類的成膜物質所形成,分別配置於在前述公轉載台之徑向外側且在圓周方向相互地分離的複數個位置;以及載台旋轉機構,伴隨前述公轉載台之旋轉而使前述各自轉載台繞前述自轉軸而旋轉。前述載台旋轉機構,係在基材通過從前述複數個靶材之各靶材之中央對包絡前述各自轉載台之圓弧所拉出的二條切線之間的期間,使搭載有該基材的前述自轉載台相對於前述公轉載台以180°以上之角度進行自轉。 The present invention provides a PVD processing apparatus for forming a film on a surface of a plurality of substrates, comprising: a vacuum chamber for accommodating the plurality of substrates; and a revolving stage disposed in the vacuum chamber Indoor to support the plurality of substrates while revolving the substrates around the axis of revolution; and a plurality of spinning stages supporting the substrates of the plurality of substrates while the substrate is in the a rotating platform is rotated around a rotation axis parallel to the revolution axis; and a plurality of targets are formed by different types of film forming materials, respectively disposed on a radially outer side of the revolution table and in a circumferential direction a plurality of positions separated from each other; and a stage rotating mechanism that rotates the respective transfer stages around the rotation axis in association with the rotation of the revolution stage. The stage rotation mechanism is configured such that a substrate is loaded between the two tangents drawn from the arcs of the respective transfer stages from the center of each of the plurality of targets. The rotation stage rotates at an angle of 180° or more with respect to the revolution table.

又,本發明所提供者是一種用以在複數個基 材之表面進行成膜的PVD處理方法,其包含:準備PVD處理裝置的步驟,該PVD處理裝置係具備:真空腔室,用以容納前述複數個基材;及公轉載台,設置於前述真空腔室內,用以一邊支撐前述複數個基材一邊使此等的基材繞公轉軸而公轉;以及複數個靶材,由互為不同種類的成膜物質所形成,分別配置於在前述公轉載台之徑向外側且在圓周方向相互地分離的複數個位置;以及進行PVD處理的步驟,在該基材通過從前述複數個靶材之各靶材之中央對包絡由前述公轉載台支撐之前述各基材之外周面的圓弧所拉出的二條切線之間的期間,一邊使該基材繞與前述公轉載台之前述公轉軸呈平行之自轉軸而相對於該公轉載台以180°以上之角度進行自轉,一邊進行PVD處理。 Moreover, the present invention provides a method for using a plurality of bases A PVD processing method for forming a film on a surface of a material, comprising: a step of preparing a PVD processing apparatus, the PVD processing apparatus comprising: a vacuum chamber for accommodating the plurality of substrates; and a revolving stage disposed on the vacuum a chamber for supporting the plurality of substrates to revolve around the common axis while supporting the plurality of substrates; and a plurality of targets formed of different types of film forming substances, respectively disposed in the aforementioned revolution a plurality of positions radially outward of the stage and separated from each other in the circumferential direction; and a step of performing a PVD process, wherein the substrate is supported by the revolution carrying stage by a center of the respective targets from the plurality of targets a period of time between the two tangent lines drawn by the circular arc of the outer circumferential surface of each of the base materials, the substrate is wound around the revolving axis parallel to the revolution axis of the revolving stage, and is 180 with respect to the revolving stage. The PVD treatment is performed while rotating at an angle of ° or higher.

1‧‧‧PVD處理裝置 1‧‧‧PVD treatment unit

2‧‧‧真空腔室 2‧‧‧vacuum chamber

3‧‧‧公轉載台 3‧‧‧Revolving stage

4‧‧‧自轉載台 4‧‧‧Rotating station

5‧‧‧靶材 5‧‧‧ Target

6、16‧‧‧載台旋轉機構 6, 16‧‧‧ stage rotating mechanism

7‧‧‧公轉軸 7‧‧‧ public axis

8‧‧‧自轉軸 8‧‧‧Rotary axis

13‧‧‧圓弧 13‧‧‧ arc

51‧‧‧電弧離子鍍膜用之靶材 51‧‧‧Target for arc ion plating

52‧‧‧濺鍍用之靶材 52‧‧‧Target for sputtering

A1‧‧‧塗黑的區域 A1‧‧‧Blackened area

A2‧‧‧鏤空的區域 A2‧‧‧ hollow area

D1、D2‧‧‧外徑 D1, D2‧‧‧ OD

DT‧‧‧距離 DT‧‧‧ distance

L1、L2‧‧‧切線 L1, L2‧‧‧ tangent

PA、PB、PC、Pa、Pb、Pc‧‧‧位置 PA, PB, PC, Pa, Pb, Pc‧‧ position

W‧‧‧基材 W‧‧‧Substrate

第1圖係本發明之實施形態的PVD處理裝置之俯視圖。 Fig. 1 is a plan view showing a PVD processing apparatus according to an embodiment of the present invention.

第2A圖係顯示前述PVD處理裝置之各自轉載台不自轉時的基材之成膜狀態的俯視圖。 Fig. 2A is a plan view showing a state of film formation of a substrate when the respective transfer stages of the PVD processing apparatus are not rotated.

第2B圖係顯示前述各自轉載台自轉時的基材之成膜狀態的俯視圖。 Fig. 2B is a plan view showing a state of film formation of the substrate when the respective transfer stages are rotated.

第3A圖係顯示用於本發明之實施例及比較例的PVD處理裝置之要部外觀的立體圖。 Fig. 3A is a perspective view showing the appearance of a main part of a PVD processing apparatus used in the examples and comparative examples of the present invention.

第3B圖係顯示第3A圖所示的裝置之要部的俯視 圖。 Figure 3B shows a top view of the main part of the device shown in Figure 3A Figure.

第4A圖係顯示前述實施例的載台旋轉機構之俯視圖。 Fig. 4A is a plan view showing the stage rotating mechanism of the foregoing embodiment.

第4B圖係顯示前述比較例的載台旋轉機構之俯視圖。 Fig. 4B is a plan view showing the stage rotating mechanism of the above comparative example.

第5A圖係顯示前述實施例的膜厚測定結果之曲線圖。 Fig. 5A is a graph showing the results of film thickness measurement of the foregoing examples.

第5B圖係顯示前述比較例的膜厚測定結果之曲線圖。 Fig. 5B is a graph showing the results of measurement of the film thickness of the above comparative example.

第6A圖係顯示在本發明之實施例中形成於基材之外周面上的複合皮膜之剖面俯視圖。 Fig. 6A is a cross-sectional plan view showing a composite film formed on the outer peripheral surface of the substrate in the embodiment of the present invention.

第6B圖係顯示在習知例中形成於基材之外周面上的複合皮膜之剖面俯視圖。 Fig. 6B is a cross-sectional plan view showing a composite film formed on the outer peripheral surface of the substrate in the conventional example.

第7圖係顯示在本發明之實施例中形成於基材之外周面上的複合皮膜且其一部分之皮膜的圓周方向之一部分彼此相互地疊合的剖面俯視圖。 Fig. 7 is a cross-sectional plan view showing a composite film formed on the outer peripheral surface of the substrate in the embodiment of the present invention, and a part of the film in the circumferential direction of the film is superposed on each other.

一邊參照圖式,一邊就本發明之實施形態的PVD處理裝置1加以說明。本實施形態之PVD處理裝置1,係交互或是同時使用二種以上之PVD法、或是在同種之PVD法中交互或是同時使用二種以上之靶材,以在基材W之表面上進行複合皮膜之成膜的裝置。在以後之實施形態的PVD處理裝置1中,例如,即便是在PVD法中 亦能使用電弧離子鍍膜法和濺鍍法之雙方來進行複合皮膜之成膜。 The PVD processing apparatus 1 according to the embodiment of the present invention will be described with reference to the drawings. In the PVD processing apparatus 1 of the present embodiment, two or more PVD methods are used alternately or in the same type of PVD method or two or more kinds of targets are used simultaneously on the surface of the substrate W. A device for forming a film of a composite film. In the PVD processing apparatus 1 of the embodiment, for example, even in the PVD method It is also possible to form a composite film by using both the arc ion plating method and the sputtering method.

第1圖係前述實施形態的PVD處理裝置1之俯視圖。該PVD處理裝置1係具備真空腔室2、公轉載台3、複數個自轉載台4、複數個靶材5及載台旋轉機構6。前述真空腔室2係包圍處理室,且該處理室係可以使用未圖示之真空泵浦等來排氣成真空或是極低壓。前述公轉載台3、前述複數個自轉載台4、前述複數個靶材5及前述載台旋轉機構6,係容納於前述真空腔室2。前述公轉載台3係一邊支撐複數個基材W一邊使前述各基材W公轉。前述自轉載台4係一邊支撐前述各基材W一邊使該基材W在前述公轉載台3上自轉。前述各靶材5係由互為不同種類的成膜物質所形成,分別配置於在前述公轉載台3之徑向外側且在圓周方向相互地分離的位置。前述載台旋轉機構6係使前述公轉載台3和前述自轉載台4以預定之齒輪比分別旋轉。 Fig. 1 is a plan view of the PVD processing apparatus 1 of the above embodiment. The PVD processing apparatus 1 includes a vacuum chamber 2, a revolution stage 3, a plurality of rotation stages 4, a plurality of targets 5, and a stage rotation mechanism 6. The vacuum chamber 2 surrounds the processing chamber, and the processing chamber can be evacuated to a vacuum or an extremely low pressure using a vacuum pump or the like (not shown). The revolution stage 3, the plurality of rotation stages 4, the plurality of targets 5, and the stage rotation mechanism 6 are housed in the vacuum chamber 2. The revolution stage 3 revolves the respective substrates W while supporting a plurality of substrates W. The rotation stage 4 rotates the base material W on the revolution stage 3 while supporting the respective base materials W. Each of the targets 5 is formed of a film-forming substance different from each other, and is disposed at a position radially apart from the outside of the revolution stage 3 and separated from each other in the circumferential direction. The stage rotation mechanism 6 rotates the revolution stage 3 and the rotation stage 4 by a predetermined gear ratio.

如第1圖所示,前述公轉載台3係可以藉由一邊支撐前述複數個基材W一邊使該公轉載台3本身繞公轉軸7而旋轉,來使前述各基材W繞該公轉軸7而公轉的圓板狀之構件,且在圖例中前述公轉軸7係設定於在前述真空腔室2內朝向上下方向延伸的軸。前述各自轉載台4,係配備於在該公轉載台3之外緣附近且在圓周方向相互地分離的複數個(圖例中為八個)位置,且各個支撐前述基材W。前述載台旋轉機構6係設置於前述公轉載台3 之下方並使該公轉載台3繞上述的公轉軸7,朝向例如第1圖之箭頭所示從上方來看為順時鐘方向迴旋,藉此使前述各基材W繞前述公轉軸7而朝向前述方向公轉。 As shown in Fig. 1, the revolution stage 3 can rotate the revolution stage 3 around the revolution shaft 7 while supporting the plurality of substrates W, and the respective substrates W can be wound around the revolution shaft. In the case of the disk-shaped member which is revolved, the aforementioned revolving shaft 7 is set to an axis extending in the vertical direction in the vacuum chamber 2. Each of the transfer stages 4 is provided at a plurality of (eight in the illustrated example) positions in the circumferential direction in the vicinity of the outer edge of the revolution stage 3, and each of the substrates W is supported. The stage rotation mechanism 6 is disposed on the revolution table 3 The revolving stage 3 is wound around the above-mentioned revolving axis 7 so as to be rotated in the clockwise direction as viewed from the upper side, for example, as indicated by an arrow in the first drawing, whereby the respective base materials W are oriented around the revolving axis 7 The above direction is revolved.

前述各自轉載台4,係具有比前述公轉載台3之外徑還小之外徑的圓板狀之構件,且具有能夠搭載前述基材W的上表面。各自轉載台4係藉由前述載台旋轉機構6,以繞與公轉軸7呈平行之自轉軸8而自轉的方式所驅動。搭載於各自轉載台4的前述基材W,係例如鑽頭或尖錐等具備沿著圓周方向而彎曲成圓弧狀之外周面的物品,且在該彎曲的外周面之上形成有皮膜。雖然本實施形態之基材W為圓筒體之物品,但是作為本發明之成膜對象的基材並未被限於圓筒體。例如前端為尖銳的圓錐狀之構件、或包含複數個圓板狀之構件的基材套件(set)且藉由此等構件相互地積層而整體形成圓筒狀之外形者,且皆涵蓋於本發明之「基材」中。 Each of the transfer stages 4 has a disk-shaped member having an outer diameter smaller than the outer diameter of the revolution stage 3, and has an upper surface on which the substrate W can be mounted. The respective transfer stages 4 are driven by the above-described stage rotation mechanism 6 so as to rotate around the rotation shaft 8 which is parallel to the revolution axis 7. The base material W to be mounted on each of the transfer tables 4 includes, for example, a drill or a tapered cone, and has an outer peripheral surface that is curved in an arc shape in the circumferential direction, and a film is formed on the curved outer peripheral surface. Although the substrate W of the present embodiment is an article of a cylindrical body, the substrate to be film-formed according to the present invention is not limited to a cylindrical body. For example, a sharp-shaped conical member at the front end or a substrate set including a plurality of disc-shaped members is integrally formed into a cylindrical shape by laminating the members with each other, and is covered by the present invention. In the "substrate" of the invention.

前述各靶材5係由所謂Ti(鈦)、Al(鋁)、Ni(鎳)、C(碳)之作為皮膜原料的物質所構成,在本實施形態係形成為板狀。在前述複數個靶材5,係包含有電弧離子鍍膜用之靶材51和濺鍍用之靶材52,且分別由互為不同種類的成膜物質所形成。此等的電弧離子鍍膜用之靶材51和濺鍍用之靶材52,係分別配置於在前述公轉載台3之徑向外側且在圓周方向相互地分離該公轉載台3的位置。圖例中,係分別在公轉載台3之側方(在第1圖之紙面為上側)配備有前述濺鍍用之靶材52,另隔著前述公轉 軸7而在前述濺鍍用之靶材52的相反側之側方(在第2圖之紙面為下側)配備有前述電弧離子鍍膜用之靶材51。 Each of the targets 5 is made of a material such as Ti (titanium), Al (aluminum), Ni (nickel), or C (carbon) as a film material, and is formed into a plate shape in the present embodiment. The plurality of targets 5 include a target 51 for an arc ion plating film and a target 52 for sputtering, and are formed of film-forming substances different from each other. The target 51 for the arc ion plating film and the target 52 for sputtering are disposed at positions radially apart from the outside of the revolution stage 3 and separated from each other in the circumferential direction. In the example, the target 52 for sputtering is provided on the side of the revolution stage 3 (the upper side of the paper surface of Fig. 1), and the above-mentioned revolution is interposed. The shaft 7 is provided with the target 51 for the arc ion plating film on the side opposite to the opposite side of the sputtering target 52 (the lower side of the paper surface in Fig. 2).

前述載台旋轉機構6係將未圖示之驅動馬達所產生的旋轉驅動力傳遞至上述的公轉載台3和自轉載台4之雙方並使其等旋轉者,且使各自的載台3、4以預定之齒輪比旋轉。 The stage rotation mechanism 6 transmits a rotational driving force generated by a drive motor (not shown) to both of the above-described revolution stage 3 and the rotation stage 4, and rotates the same, and causes each stage 3, 4 Rotate at a predetermined gear ratio.

在第1圖所示的PVD處理裝置1中,雖然在前述公轉載台3搭載有八個自轉載台9,但是第4A圖係顯示在一個公轉載台3搭載有四個自轉載台9之實施例的載台旋轉機構6,第4B圖係顯示作為其比較例的載台旋轉機構16。 In the PVD processing apparatus 1 shown in FIG. 1 , eight rotation stages 9 are mounted on the revolution stage 3, but FIG. 4A shows that four rotation stages 9 are mounted on one revolution stage 3 . In the stage rotating mechanism 6 of the embodiment, FIG. 4B shows the stage rotating mechanism 16 as a comparative example thereof.

具體而言,前述載台旋轉機構6、16皆具有:設置於前述公轉載台3之側的中心齒輪9;以及設置於各自的自轉載台4之側的複數個自轉齒輪10。前述中心齒輪9和前述各自轉齒輪10係一邊使前述各自轉齒輪10朝向圓周方向排列於該中心齒輪9之周圍一邊相互地嚙合。如第4A圖及第4B圖所示,可以藉由改變用於前述各齒輪9、10的齒輪之外徑及齒數,來使自轉載台4相對於公轉載台3以各種的齒輪比旋轉即自轉。第4A圖所示的中心齒輪9係大徑的齒輪,而與該中心齒輪9嚙合的各自轉齒輪10係具有比前述中心齒輪9之直徑還更為小之直徑的小徑之齒輪。第4B圖所示的中心齒輪9係小徑的齒輪,而與該中心齒輪9嚙合的各自轉齒輪10係具有比前述中心齒輪9之直徑還更為大之直徑的大徑之齒輪。 Specifically, the stage rotating mechanisms 6 and 16 each have a sun gear 9 provided on the side of the revolution carrier 3 and a plurality of rotation gears 10 provided on the side of each of the rotation stages 4 . The sun gear 9 and the respective rotation gears 10 mesh with each other while arranging the respective rotation gears 10 in the circumferential direction around the center gear 9. As shown in FIGS. 4A and 4B, the rotation stage can be rotated by various gear ratios with respect to the revolution stage 3 by changing the outer diameter and the number of teeth of the gears for the gears 9 and 10 described above. rotation. The sun gear 9 shown in Fig. 4A is a gear having a large diameter, and the respective rotation gear 10 meshing with the sun gear 9 is a small-diameter gear having a diameter smaller than the diameter of the sun gear 9. The sun gear 9 shown in Fig. 4B is a small-diameter gear, and the respective rotation gear 10 meshing with the sun gear 9 is a large-diameter gear having a larger diameter than the diameter of the sun gear 9.

在前述載台旋轉機構6中,係能以如下之方式來決定中心齒輪9與自轉齒輪10之齒數比,該方式係在基材W通過從第1圖所示的複數個靶材5即靶材51、52之各靶材之中央、具體而言為靶材51、52之表面當中與前述公轉載台3對向的表面之作為與前述公轉軸7呈垂直之方向的寬度方向之中央,如第2A圖及第2B圖所示對包絡各自轉載台4之圓弧、更佳為包絡該各自轉載台4所支撐的各基材W之外周面的圓弧13所拉出的二條切線L1、L2之間的期間,使搭載有基材W的各自轉載台4相對於前述公轉載台3以180°以上之角度進行自轉。換言之,能以在基材W通過前述切線L1、L2之間的期間,自轉載台4對設定於公轉載台3上的公轉座標系以180°以上之角度進行自轉的方式,來設定前述齒數比。 In the stage rotating mechanism 6, the gear ratio of the sun gear 9 and the rotation gear 10 can be determined in such a manner that the substrate W passes through a plurality of targets 5, i.e., targets, as shown in Fig. 1. The center of each of the targets 51 and 52, specifically, the center of the targets 51 and 52 facing the revolution table 3 is the center in the width direction perpendicular to the revolution axis 7. As shown in FIGS. 2A and 2B, the arcs of the respective transfer stages 4 of the envelopes, and more preferably the two tangent lines L1 drawn by the arcs 13 of the outer peripheral surfaces of the respective substrates W supported by the respective transfer stages 4 are illustrated. In the period between L2 and L5, the respective transfer stages 4 on which the substrate W is mounted are rotated at an angle of 180° or more with respect to the revolution stage 3 described above. In other words, the number of teeth can be set by the self-rotation of the revolution coordinate set on the revolution stage 3 at an angle of 180° or more while the substrate W passes between the tangent lines L1 and L2. ratio.

本實施形態之前述中心齒輪9,係配備於前述公轉載台3之下側,且可在容許該公轉載台3相對該中心齒輪9旋轉的狀態下固定於與該公轉載台3不同的載台底座(table base)。該中心齒輪9係具有繞前述公轉軸7而排列的齒列。前述各自轉齒輪10係一邊配設於前述中心齒輪9之周圍一邊嚙合於該中心齒輪9。各自轉齒輪10係以能夠與對應此的自轉載台4一體地繞前述自轉軸8而旋轉之方式由前述公轉載台3所支撐。前述公轉載台3係藉由前述驅動馬達而旋轉驅動,隨之中介前述自轉齒輪而連結於前述中心齒輪9的各自轉載台4則可繞前述自轉軸8而旋轉驅動。亦即,在前述各自轉齒輪10,係從省略圖 示的驅動馬達賦予有旋轉驅動力,且利用被賦予的旋轉驅動力一邊使自轉齒輪10沿著中心齒輪9之外周而移動,一邊使公轉載台3和自轉載台4之雙方旋轉。 The sun gear 9 of the present embodiment is provided on the lower side of the revolving stage 3, and is fixed to a different load from the revolving stage 3 while allowing the revolving stage 3 to rotate relative to the sun gear 9. Table base. The sun gear 9 has a tooth row that is arranged around the revolution shaft 7. The respective rotation gears 10 are meshed with the sun gear 9 while being disposed around the sun gear 9 . Each of the revolving gears 10 is supported by the revolving stage 3 so as to be rotatable around the rotation shaft 8 integrally with the rotation stage 4 corresponding thereto. The revolution stage 3 is rotatably driven by the drive motor, and the respective transfer stages 4 coupled to the center gear 9 by interposing the rotation gears are rotatably driven around the rotation shaft 8. That is, in the aforementioned respective rotating gears 10, the drawings are omitted. The drive motor is provided with a rotational driving force, and the rotation gear 10 is moved along the outer circumference of the sun gear 9 by the applied rotational driving force, and both the revolution stage 3 and the rotation stage 4 are rotated.

在用具備第1圖所示之構成的PVD處理裝置1對複數個基材W進行PVD處理時,首先該基材W是搭載於各自的自轉載台4。然後,利用驅動馬達所產生的旋轉驅動力,使公轉載台3繞公轉軸7而迴旋驅動。該旋轉驅動力亦經由載台旋轉機構6而傳遞至自轉載台4,且追蹤公轉載台3之迴旋而使各自的自轉載台4繞自轉軸8而自轉。結果,搭載於自轉載台4的基材W,係一邊繞前述自轉軸8而自轉一邊繞前述公轉軸7而公轉。 When PVD processing is performed on a plurality of substrates W by the PVD processing apparatus 1 having the configuration shown in FIG. 1, first, the substrates W are mounted on the respective rotation stages 4 . Then, the revolution stage 4 is rotatably driven around the revolution shaft 7 by the rotational driving force generated by the drive motor. The rotational driving force is also transmitted to the self-rotating stage 4 via the stage rotating mechanism 6, and the rotation of the revolution carrying stage 3 is tracked, and the respective rotating stages 4 are rotated around the rotating shaft 8. As a result, the base material W mounted on the rotation stage 4 revolves around the revolution shaft 7 while rotating around the rotation shaft 8 .

此時,上述的載台旋轉機構6,係在基材W通過從複數個靶材5、在此實施形態中為靶材51、52之各靶材之中央對包絡前述各自轉載台4之圓弧13所拉出的二條切線L1、L2之間的期間,使各基材W及支撐此的各自轉載台4相對於公轉載台3以180°以上之角度進行自轉。一邊參照第1圖及第2圖所示的PVD處理裝置1,一邊說明應設定如此之自轉角度的理由。 In this case, the above-described stage rotating mechanism 6 is configured such that the substrate W is encased in the circle of the respective transfer stages 4 from the center of each of the plurality of targets 5 and the targets 51 and 52 in the embodiment. During the period between the two tangent lines L1 and L2 pulled by the arc 13, the respective base materials W and the respective transfer tables 4 supported thereby are rotated at an angle of 180 or more with respect to the revolution stage 3. The reason why such a rotation angle should be set will be described with reference to the PVD processing apparatus 1 shown in Figs. 1 and 2 .

首先,成膜物質係從濺鍍用之靶材52的電極面中心朝向公轉載台3側(公轉軸7側)一邊擴展成噴霧(spray)狀一邊飛散。更具體而言,從濺鍍用之靶材52飛出的成膜物質是如第2A圖及第2B圖所示從電極面中心朝向公轉載台3側以擴展成扇狀之方式而飛散。此時,最多量的物質是飛散至濺鍍用之靶材52的正面,且飛散量 是越朝向遠離豎立於靶材52之垂線的角度就越減少。換句話說,物質從濺鍍用之靶材52飛散的範圍,係遍及靶材52之前方全方位,且藉由其中飛散至從與包絡各自轉載台4之圓弧13相對的一方之切線L1至另一方之切線L2的範圍之物質,當基材W通過該飛散的成膜物質中時可在基材W之表面形成皮膜。 First, the film-forming substance is scattered from the center of the electrode surface of the target 52 for sputtering toward the side of the revolution stage 3 (the side of the revolution axis 7) while expanding into a spray shape. More specifically, the film-forming substance flying out from the target 52 for sputtering is scattered from the center of the electrode surface toward the side of the revolution stage 3 so as to expand in a fan shape as shown in FIGS. 2A and 2B. At this time, the most amount of material is scattered to the front side of the target 52 for sputtering, and the amount of scattering The angle toward the vertical line that is erected away from the target 52 is reduced. In other words, the range in which the substance scatters from the target 52 for sputtering is in all directions before the target 52, and is scattered by the tangent L1 from the side opposite to the circular arc 13 of the respective transfer table 4 of the envelope. The substance in the range of the other tangent line L2 can form a film on the surface of the substrate W when the substrate W passes through the scattered film-forming substance.

在此,考慮如第2A圖所示自轉載台4不自轉的情況。即便在此情況,因各自轉載台4及各基材W係公轉,故而伴隨該公轉,存在於基材W之外周面上的1點(圖中圓形符號所示的點)會進入由二條切線L1、L2包夾的區域。換句話說,圖中圓形符號所示的點會來到第2A圖所示的位置Pa之位置。從濺鍍用之靶材52飛散的成膜物質能夠從此時間點到達基材W之外周面,且該成膜物質因沉積而在第2A圖中的圓弧狀之塗黑的區域A1形成皮膜。 Here, a case where the spinning stage 4 does not rotate as shown in FIG. 2A is considered. Even in this case, since each of the transfer table 4 and each of the substrates W revolves, one point (a point indicated by a circular symbol in the figure) existing on the outer peripheral surface of the substrate W enters the two by the revolution. The area where the lines L1 and L2 are sandwiched. In other words, the point indicated by the circular symbol in the figure will come to the position Pa shown in Fig. 2A. The film-forming substance scattered from the target 52 for sputtering can reach the outer peripheral surface of the substrate W from this point of time, and the film-forming substance forms a film in the arc-shaped blackened area A1 in FIG. 2A due to deposition. .

另外,即便是在二條切線L1、L2所包夾的區域,前述基材W之外周面上的特定部位到達前述位置Pa為止,由於該特定部位從濺鍍用之靶材52隱藏於基材W本身之背面,所以也無法在該部位之表面進行成膜。 Further, even in a region sandwiched by the two tangents L1 and L2, a specific portion on the outer peripheral surface of the substrate W reaches the position Pa, and the specific portion is hidden from the substrate W from the target 52 for sputtering. Since it is on the back side of itself, it is impossible to form a film on the surface of the part.

另外,當公轉載台3繼續迴旋時,從靶材5來看,基材W之位置係藉由其公轉而在水平面上相對地變化。換句話說,設置於公轉載台3上的基材W之絕對座標系之位置,係該基材W即便不自轉亦會對靶材5產生變化,因而在該基材W之外周面上成膜物質所沉積的 場所亦會在該外周面上產生變化。 Further, when the revolving stage 3 continues to rotate, the position of the substrate W is relatively changed in the horizontal plane by the revolution of the target 5 as viewed from the target 5. In other words, the position of the absolute coordinate system of the substrate W disposed on the revolution table 3 causes the substrate W to change the target 5 even if it does not rotate, and thus is formed on the outer surface of the substrate W. Membrane material deposited The site will also change on the outer perimeter.

例如,著眼於基材W之外周面上的特定點,來考慮成膜物質之沉積。第2A圖中圓形符號所示的外周面上之特定點,係當公轉載台3公轉時就依序移行至圖中之位置Pa、Pb、Pc。換句話說,前述特定點係從一方之切線L1上的位置經由靶材5之正面的位置而移動至另一方之切線L2上的位置。另一方面,如此當基材W對靶材5之相對位置產生變化而來到位置Pc時,就亦會在鄰接上述塗黑之區域A1的位置沉積成膜物質,且除了塗黑區域A1的皮膜以外亦在鏤空的區域A2形成新的皮膜。 For example, focusing on a specific point on the outer peripheral surface of the substrate W, the deposition of the film-forming substance is considered. The specific point on the outer peripheral surface indicated by the circle symbol in Fig. 2A is sequentially moved to the positions Pa, Pb, Pc in the figure when the revolution stage 3 is revolved. In other words, the specific point is moved from the position on the tangent line L1 to the position on the other tangent line L2 via the position of the front surface of the target 5. On the other hand, when the relative position of the substrate W to the target 5 changes to the position Pc, the film forming substance is deposited at a position adjacent to the blackened area A1, and the blackened area A1 is removed. A new film is formed in the hollowed out area A2 in addition to the film.

在如上述般使基材W不自轉的情況,即便將第2A圖所示塗黑的區域A1之皮膜和鏤空的區域A2之皮膜合在一起亦無法遍及全周地覆蓋基材W之外周面。故而,在第2A圖所示的情況,例如第6B圖所示,恐有如圓周方向之一部分缺損的皮膜形成於基材W之外周面之虞。 When the substrate W is not rotated as described above, even if the film of the blackened region A1 shown in FIG. 2A and the film of the hollowed region A2 are combined, it is impossible to cover the outer peripheral surface of the substrate W over the entire circumference. . Therefore, in the case shown in Fig. 2A, for example, as shown in Fig. 6B, there is a fear that a film which is partially damaged in the circumferential direction is formed on the outer peripheral surface of the substrate W.

可是,在自轉載台4如第2B圖所示伴隨公轉載台3之迴旋以充分之角度自轉的情況,則可以將塗黑的區域A1之皮膜和鏤空的區域A2之皮膜合在一起而遍及全周地覆蓋基材W之外周面,結果,例如可以如第6A圖所示在基材W之外周面形成具有均質構造的複合皮膜。具體而言,可對上述的載台旋轉機構6之公轉齒輪9及自轉齒輪10,提供如在基材W通過二條切線L1、L2之間的期間使自轉載台4相對於公轉載台3以180°以上之角度 進行自轉的齒輪比。該齒輪比之設定,係使自轉載台4以更寬角度進行自轉並能以該部分來增加上述之鏤空的區域A2之皮膜的範圍,藉此能夠遍及基材W之外周面地形成不中斷而連續的皮膜。 However, in the case where the spinning table 4 rotates at a sufficient angle as the whirling of the revolution stage 3 as shown in FIG. 2B, the film of the blackened area A1 and the film of the hollowed area A2 can be combined. The outer peripheral surface of the substrate W is covered over the entire circumference. As a result, for example, a composite film having a homogeneous structure can be formed on the outer peripheral surface of the substrate W as shown in FIG. 6A. Specifically, the revolving gear 9 and the rotation gear 10 of the above-described stage rotating mechanism 6 can be provided such that the self-rotating stage 4 is opposed to the revolving stage 3 during the period in which the substrate W passes between the two tangent lines L1 and L2. Angle of 180° or more The gear ratio for the rotation. The gear ratio is set such that the self-rotating stage 4 is rotated at a wider angle and the range of the film of the hollowed-out area A2 can be increased by the portion, whereby the outer surface of the substrate W can be formed without interruption. And continuous film.

例如,考慮在第2B圖中由圓形符號所示的點是經由圖中之位置PA及位置PB而來到位置PC的情況。在該位置PC,是在基材W之外周面遍及比第2A圖所示之鏤空的區域A2還寬180°的區域而使皮膜形成於基材W之外周面。換句話說,只要將塗黑的區域A1之皮膜和鏤空的區域A2之皮膜合在一起就能夠遍及全周地覆蓋基材W之外周面。故而,如第6A圖所示能在基材W之外周面遍及全周地形成不中斷而連續的皮膜,且可以在基材W之外周面形成具有均質構造的皮膜。 For example, consider a case where a point indicated by a circular symbol in FIG. 2B is a position PC passing through the position PA and the position PB in the drawing. In this position PC, the film is formed on the outer peripheral surface of the substrate W over a peripheral surface of the substrate W over a region 180° wider than the hollow region A2 shown in FIG. 2A. In other words, the outer peripheral surface of the substrate W can be covered over the entire circumference as long as the film of the blackened area A1 and the film of the hollowed area A2 are combined. Therefore, as shown in Fig. 6A, an uninterrupted and continuous film can be formed on the outer peripheral surface of the substrate W over the entire circumference, and a film having a homogeneous structure can be formed on the outer peripheral surface of the substrate W.

上述之例,雖然是使用濺鍍用之靶材52遍及圓周方向地形成不中斷而連續的皮膜之情況,但是對電弧離子鍍膜用之靶材51而言亦同樣只要是以滿足上述之關係的方式使載台旋轉機構6動作,就可以遍及圓周方向地形成不中斷而連續的皮膜,且可以在基材W之外周面形成具有均質構造的複合皮膜。 In the above-described example, the target material 52 for sputtering is formed in a continuous direction without being interrupted in the circumferential direction. However, the target 51 for the arc ion plating film is similarly provided to satisfy the above relationship. By operating the stage rotating mechanism 6, a continuous film that is continuous without interruption can be formed in the circumferential direction, and a composite film having a homogeneous structure can be formed on the outer peripheral surface of the substrate W.

另外,即便可以在基材W之外周面遍及全周而形成連續的皮膜,當如第7圖所示在皮膜之中最初成膜的部分和最後成膜的部分局部疊合時,亦有在皮膜之膜厚上發生不均勻,而難以形成具有均質構造的複合皮膜之可能性。 Further, even if a continuous film can be formed over the entire circumference of the substrate W over the entire circumference, when the portion which is initially formed in the film and the portion where the film is formed are partially overlapped as shown in Fig. 7, there is also The film thickness of the film is uneven, and it is difficult to form a composite film having a homogeneous structure.

如此的情況,只要以在基材W通過二條切線L1、L2之間的期間,搭載有基材W的自轉載台4相對於公轉載台3以360°以上、更佳為720°以上之角度進行自轉的方式來設定前述齒輪比即可。如此就能抑制皮膜之厚度偏差,且能夠形成具有更均質構造的複合皮膜。具體而言,在將基材W通過二條切線L1、L2之間的期間自轉載台4相對公轉載台3旋轉的角度即自轉角度設為180°的情況,雖然在皮膜之厚度上發生±50%左右之偏差,但是在前述自轉角度為360°的情況偏差可抑制在±30%左右,而在設為720°的情況偏差可抑制到±10%左右。 In such a case, the rotation stage 4 on which the substrate W is mounted during the period in which the substrate W passes between the two tangents L1 and L2 is 360° or more, and more preferably 720° or more with respect to the revolution stage 3 . It is sufficient to set the gear ratio by performing the rotation. Thus, the thickness deviation of the film can be suppressed, and a composite film having a more homogeneous structure can be formed. Specifically, when the substrate W passes between the two tangents L1 and L2, the angle at which the rotation stage 4 rotates relative to the revolution stage 3, that is, the rotation angle is 180°, although ±50 occurs in the thickness of the film. The deviation is about %, but the deviation in the case where the rotation angle is 360° can be suppressed to about ±30%, and the deviation in the case of 720° can be suppressed to about ±10%.

[實施例] [Examples]

其次,使用實施例及比較例,來更詳細地說明本發明之PVD處理方法的作用效果。 Next, the effects of the PVD processing method of the present invention will be described in more detail using examples and comparative examples.

如第3A圖及第3B圖所示,在用於實驗的PVD處理裝置1中,係採用具有400mm之外徑D1的公轉載台3、和分別具有160mm 之外徑D2的四個自轉載台4,且此等的自轉載台4是在前述公轉載台3上以等間隔配置於圓周方向。搭載於各自轉載台4的基材W係直徑為160mm 的圓筒體,且在實施例及比較例中係可在該基材W之外周面藉由電弧離子鍍膜法來形成皮膜。 As shown in FIGS. 3A and 3B, in the PVD processing apparatus 1 for experiment, a revolving stage 3 having an outer diameter D1 of 400 mm and a 160 mm each were used. The four rotation stages 4 of the outer diameter D2, and the rotation stages 4 of these are arranged on the revolution stage 3 at equal intervals in the circumferential direction. The substrate W mounted on each of the transfer stages 4 has a diameter of 160 mm. In the cylindrical body, in the examples and the comparative examples, a film can be formed by an arc ion plating method on the outer peripheral surface of the substrate W.

用於電弧離子鍍膜法的靶材51,係直徑為100mm的圓板,且配備於從公轉載台3之外周緣朝向徑向外側僅分離160mm之距離DT的位置。對該電弧用之靶材 51供應150A之電弧電流,並且對真空腔室2之處理室內供應氮氣直至該處理室內的壓力成為3Pa為止,藉此進行成膜。 The target 51 for the arc ion plating method is a circular plate having a diameter of 100 mm, and is disposed at a position separated by a distance DT of only 160 mm from the outer periphery of the revolution stage 3 toward the radially outer side. Target for the arc 51 was supplied with an arc current of 150 A, and nitrogen gas was supplied to the processing chamber of the vacuum chamber 2 until the pressure in the processing chamber became 3 Pa, whereby film formation was performed.

在實施例及比較例中,設置於公轉載台3的中心齒輪9、和設置於自轉載台4的自轉齒輪10之齒輪比係互為不同。將此等的齒輪比顯示於表1中。在第4A圖所示之實施例的載台旋轉機構6中,具有60mm 之直徑的四個自轉齒輪10,是對具有180mm 之直徑的中心齒輪9一邊嚙合一邊自轉及公轉,且對該公轉座標系的自轉角度為337.5°。在第4B圖所示之比較例的載台旋轉機構16中,具有150mm 之直徑的四個自轉齒輪,是對具有90mm 之直徑的中心齒輪9一邊嚙合一邊自轉及公轉,且對該公轉座標系的自轉角度為67.5°。 In the embodiment and the comparative example, the gear ratios of the sun gear 9 provided on the revolution stage 3 and the rotation gear 10 provided in the rotation stage 4 are different from each other. These gear ratios are shown in Table 1. In the stage rotating mechanism 6 of the embodiment shown in Fig. 4A, there is 60 mm The four self-rotating gears 10 of the diameter are paired with 180mm The center gear 9 of the diameter rotates and revolves while meshing, and the rotation angle of the revolution coordinate system is 337.5°. In the stage rotating mechanism 16 of the comparative example shown in FIG. 4B, it has 150 mm. The four self-rotating gears of the diameter are paired with 90mm The center gear 9 of the diameter rotates and revolves while meshing, and the rotation angle of the revolution coordinate system is 67.5°.

在上述之實施例及比較例中,是在使基材W以從第3B圖之位置P1至位置P2為止的180°之範圍進行公轉的情況計測成膜於基材W之表面的皮膜之膜厚。將該實施例及比較例的膜厚之計測結果分別顯示於第5A圖 及第5B圖。在此,第5A圖、第5B圖之縱軸所示的膜厚之值,係指將基材W位於靶材5之正面時所成膜的膜厚作為基準的相對值,第5A圖、第5B圖之橫軸所示的圓周方向位置,係以將基材W位於靶材5之正面時假設為0°的情況之角度來表示。 In the above-described examples and comparative examples, the film of the film formed on the surface of the substrate W was measured while the substrate W was revolved in the range of 180° from the position P1 to the position P2 in the third drawing. thick. The measurement results of the film thicknesses of the examples and the comparative examples are respectively shown in FIG. 5A. And Figure 5B. Here, the value of the film thickness shown by the vertical axis of the 5A and 5B drawings refers to the relative value of the film thickness of the film formed when the substrate W is positioned on the front surface of the target 5, and FIG. 5A. The position in the circumferential direction indicated by the horizontal axis of Fig. 5B is expressed by the angle at which the substrate W is placed at the front side of the target 5 at assuming 0°.

如第5A圖所示,在前述實施例所形成的皮膜之膜厚,係止於在圓周方向位置之-180°至+180°的範圍內以0.7至1.0之範圍來變化,且即便圓周方向位置有變化膜厚亦沒有顯著的變化。相對於此,如第5B圖所示,在前述比較例所形成的皮膜之膜厚,係在圓周方向位置之-180°至-100°、及+100°至+180°之範圍內急遽地降低,且該膜厚之變化顯著。又可明白圓周方向位置是在-180°附近或+180°附近,而膜厚變小至0附近,且幾乎不進行成膜。 As shown in Fig. 5A, the film thickness of the film formed in the foregoing embodiment is changed in the range of -180 to +180 in the circumferential direction by 0.7 to 1.0, and even in the circumferential direction. There was no significant change in the film thickness at the location. On the other hand, as shown in FIG. 5B, the film thickness of the film formed in the above comparative example is violently in the range of -180° to -100° in the circumferential direction and +100° to +180° in the circumferential direction. Decreased, and the change in film thickness is remarkable. It can be understood that the circumferential position is in the vicinity of -180° or in the vicinity of +180°, and the film thickness is reduced to around 0, and film formation is hardly performed.

從此情形可明白如下:在基材W通過上述之二條切線L1、L2之間的期間,只要使自轉載台4相對於公轉載台3以180°以上之角度進行自轉,就可以在基材W之外周面遍及全周地形成不中斷而連續的皮膜,且可以在基材W之外周面形成膜厚均一性優異的複合皮膜。 In this case, it can be understood that the substrate W can be rotated at an angle of 180° or more with respect to the revolution stage 3 while the substrate W passes between the two tangent lines L1 and L2. The outer peripheral surface is formed with an uninterrupted and continuous film over the entire circumference, and a composite film having excellent film thickness uniformity can be formed on the outer peripheral surface of the substrate W.

可是,本發明並非被限定於上述各實施形態,只要在未變更發明之本質的範圍內均能適當變更各構件之形狀、構造、材質、組合等。又,此次揭示的實施形態中未明示揭露的事項、例如運轉條件或操作條件、各種參數、構成物之尺寸、重量、體積等,並非脫離該發明所屬技術領域中具有通常知識者通常實施的範圍,而是採用 只要是一般該發明所屬技術領域中具有通常知識者均能輕易思及的事項。 However, the present invention is not limited to the above embodiments, and the shape, structure, material, combination, and the like of each member can be appropriately changed as long as the essence of the invention is not changed. Further, the matters not disclosed in the embodiments disclosed herein, such as operating conditions, operating conditions, various parameters, size, weight, volume, and the like of the components, are not generally deviated from those of ordinary skill in the art to which the invention pertains. Scope, but adoption Any matter that is generally known to those skilled in the art to which the invention pertains can be easily considered.

如上述,依據本發明,能提供一種可以藉由使基材自轉及公轉而在該基材之外周面形成優異之複合皮膜的PVD處理裝置以及PVD處理方法。 As described above, according to the present invention, it is possible to provide a PVD processing apparatus and a PVD processing method which can form an excellent composite film on the outer peripheral surface of the substrate by rotating and revolving the substrate.

本發明所提供者為一種用以在複數個基材之表面進行成膜的PVD處理裝置,其具備:真空腔室,用以容納前述複數個基材;及公轉載台,設置於前述真空腔室內,用以一邊支撐前述複數個基材一邊使此等的基材繞公轉軸而公轉;及複數個自轉載台,一邊支撐前述複數個基材之各基材一邊使該基材在前述公轉載台上繞與前述公轉軸呈平行之自轉軸而自轉;及複數個靶材,由互為不同種類的成膜物質所形成,分別配置於在前述公轉載台之徑向外側且在圓周方向相互地分離的複數個位置;以及載台旋轉機構,用以使前述各自轉載台繞前述自轉軸而旋轉。前述載台旋轉機構,係在前述基材通過從前述複數個靶材之各靶材之中央對包絡前述各自轉載台之圓弧所拉出的二條切線之間的期間,使搭載有該基材的前述自轉載台相對於前述公轉載台以180°以上之角度進行自轉。 The present invention provides a PVD processing apparatus for forming a film on a surface of a plurality of substrates, comprising: a vacuum chamber for accommodating the plurality of substrates; and a revolving stage disposed in the vacuum chamber Indoor to support the plurality of substrates while revolving the substrates around the axis of revolution; and a plurality of spinning stages supporting the substrates of the plurality of substrates while the substrate is in the a rotating platform is rotated around a rotation axis parallel to the revolution axis; and a plurality of targets are formed by different types of film forming materials, respectively disposed on a radially outer side of the revolution table and in a circumferential direction a plurality of positions separated from each other; and a stage rotating mechanism for rotating the respective transfer stages around the rotation axis. The stage rotation mechanism is configured such that the substrate is loaded between two tangent lines which are drawn from arcs of the respective transfer stages from the center of each of the plurality of targets. The aforementioned rotation stage rotates at an angle of 180° or more with respect to the aforementioned revolution stage.

又,本發明所提供者為一種用以在複數個基材之表面進行成膜的PVD處理方法,此方法係包含:準備PVD處理裝置的步驟,該PVD處理裝置係具備:真空腔室,用以容納前述複數個基材;及公轉載台,設置於前述真空腔室內,用以一邊支撐前述複數個基材一邊使此等 的基材繞公轉軸而公轉;以及複數個靶材,由互為不同種類的成膜物質所形成,分別配置於在前述公轉載台之徑向外側且在圓周方向相互地分離的複數個位置;以及進行PVD處理的步驟,在基材通過從前述複數個靶材之各靶材之中央對包絡由前述公轉載台所支撐的前述各基材之外周面的圓弧所拉出的二條切線之間的期間,一邊使該基材繞與前述公轉載台之公轉軸呈平行之自轉軸而相對於該公轉載台以180°以上之角度進行自轉,一邊進行PVD處理。 Moreover, the present invention provides a PVD processing method for forming a film on a surface of a plurality of substrates, the method comprising: a step of preparing a PVD processing apparatus, the PVD processing apparatus comprising: a vacuum chamber, Storing the plurality of substrates; and a revolution carrying stage disposed in the vacuum chamber for supporting the plurality of substrates while supporting the plurality of substrates The substrate is revolved around the revolution axis; and the plurality of targets are formed of different types of film-forming substances, and are respectively disposed at a plurality of positions radially outward of the revolution stage and separated from each other in the circumferential direction. And a step of performing a PVD process, wherein the substrate passes through two tangents drawn from an arc of an outer circumferential surface of each of the substrates supported by the revolution carrying stage from a center of each of the plurality of targets During the period of time, the substrate is rotated while rotating at an angle of 180° or more with respect to the revolution stage around the rotation axis parallel to the revolution axis of the revolution stage, and PVD processing is performed.

依據以上的PVD處理裝置以及PVD處理,則能夠藉由前述基材W通過前述二條切線之間時相對於公轉載台以180°以上之角度進行自轉,而在該基材之外周面形成均一性優異的皮膜。如此,能夠在基材之外周面形成膜厚均一性優異的複合皮膜。 According to the PVD processing apparatus and the PVD processing described above, it is possible to form a uniformity on the outer peripheral surface of the substrate by rotating the substrate W between the two tangent lines at an angle of 180° or more with respect to the revolution stage. Excellent film. In this manner, a composite film having excellent film thickness uniformity can be formed on the outer peripheral surface of the substrate.

作為前述PVD處理裝置之載台旋轉機構,較佳是例如,具有:中心齒輪,其具有繞前述公轉軸而排列的齒列,被固定成可容許前述公轉載台相對該中心齒輪旋轉的狀態;以及複數個自轉齒輪,係與前述各自轉載台一體地繞前述自轉軸而旋轉,並且以能與前述公轉載台之繞前述公轉軸的旋轉連動而使前述各自轉載台繞前述自轉軸而旋轉的方式,將前述各自轉齒輪配設於前述中心齒輪之周圍且與該中心齒輪嚙合的載台旋轉機構。在此情況,只要以能在前述基材通過前述二條切線之間的期間使搭載有該基材的前述自轉載台相對於前述公轉載台以180°以上之角度進行自轉的方式,來設定前述中心齒輪與前述各自轉 齒輪之齒輪比即可。 Preferably, the stage rotation mechanism of the PVD processing apparatus includes a center gear having a tooth row arranged around the revolution axis, and being fixed to allow the revolution stage to rotate relative to the center gear; And a plurality of rotation gears that rotate around the rotation axis integrally with the respective transfer stages, and rotate the respective transfer stages around the rotation axis in conjunction with rotation of the revolution stage around the revolution axis In one aspect, the respective rotating gears are disposed around the sun gear and a stage rotating mechanism that meshes with the sun gear. In this case, the above-described rotation stage on which the substrate is mounted can be rotated at an angle of 180° or more with respect to the revolution stage while the substrate passes between the two tangent lines. Center gear and the aforementioned respective turn The gear ratio of the gear can be.

1‧‧‧PVD處理裝置 1‧‧‧PVD treatment unit

4‧‧‧自轉載台 4‧‧‧Rotating station

5‧‧‧靶材 5‧‧‧ Target

7‧‧‧公轉軸 7‧‧‧ public axis

8‧‧‧自轉軸 8‧‧‧Rotary axis

13‧‧‧圓弧 13‧‧‧ arc

51‧‧‧電弧離子鍍膜用之靶材 51‧‧‧Target for arc ion plating

A1、A2‧‧‧區域 A1, A2‧‧‧ area

L1、L2‧‧‧切線 L1, L2‧‧‧ tangent

PA、PB、PC‧‧‧位置 PA, PB, PC‧‧‧ position

W‧‧‧基材 W‧‧‧Substrate

Claims (3)

一種PVD處理裝置,係用以在複數個基材之表面進行成膜,其具備:真空腔室,用以容納前述複數個基材;及公轉載台,設置於前述真空腔室內,用以一邊支撐前述複數個基材一邊使此等的基材繞公轉軸而公轉;及複數個自轉載台,一邊支撐前述複數個基材之各基材一邊使該基材在前述公轉載台上繞與前述公轉軸呈平行之自轉軸而自轉;及複數個靶材,由互為不同種類的成膜物質所形成,分別配置於在前述公轉載台之徑向外側且在圓周方向相互地分離的複數個位置;以及載台旋轉機構,伴隨前述公轉載台之旋轉而使前述各自轉載台繞前述自轉軸而旋轉,該載台旋轉機構,係在基材通過從前述複數個靶材之各靶材之中央對包絡前述各自轉載台之圓弧所拉出的二條切線之間的期間,使搭載有該基材的前述自轉載台相對於前述公轉載台以180°以上之角度進行自轉。 A PVD processing apparatus for forming a film on a surface of a plurality of substrates, comprising: a vacuum chamber for accommodating the plurality of substrates; and a revolving stage disposed in the vacuum chamber for one side Supporting the plurality of substrates while revolving the substrates around the revolution axis; and a plurality of rotation stages supporting the substrates on the plurality of substrates while the substrate is wound on the revolution table The revolving shaft rotates in parallel with the rotation axis; and the plurality of targets are formed of different types of film forming substances, and are respectively disposed on the outer side of the revolution carrying stage and separated from each other in the circumferential direction. And a stage rotating mechanism that rotates the respective transfer stages around the rotation axis along with rotation of the revolution stage, the stage rotation mechanism is configured to pass the substrate from each of the plurality of targets The center of the enveloping between the two tangent lines drawn by the arcs of the respective transfer stages causes the rotation stage on which the substrate is mounted to enter the angle of 180° or more with respect to the revolution stage. Rotation. 如申請專利範圍第1項所述的PVD處理裝置,其中,前述載台旋轉機構係具有:中心齒輪,其具有繞前述公轉軸而排列的齒列,被固定成可容許前述公轉載台相對該中心齒輪旋轉的狀態;以及複數個自轉齒輪,係與前述各自轉載台一體地繞前述自轉軸而旋轉,其中,以能與前述公轉載台之繞前述公轉軸的旋轉連動而使前述各自轉載 台繞前述自轉軸旋轉的方式,將前述各自轉齒輪配設於前述中心齒輪之周圍且與該中心齒輪嚙合,將前述中心齒輪與前述各自轉齒輪之齒輪比設定成在前述基材通過前述二條切線之間的期間使搭載有該基材的前述自轉載台相對於前述公轉載台以180°以上之角度進行自轉。 The PVD processing apparatus according to claim 1, wherein the stage rotating mechanism includes a center gear having a tooth row arranged around the revolution axis, and is fixed to allow the revolution carrier to face the a state in which the sun gear rotates; and a plurality of rotation gears integrally rotate around the rotation axis with the respective transfer tables, wherein the respective rotations can be performed in conjunction with the rotation of the revolution table around the revolution axis The rotation gear rotates around the rotation axis, and the respective rotation gears are disposed around the sun gear and mesh with the sun gear, and the gear ratio of the sun gear to the respective rotation gears is set to pass the foregoing two pieces on the substrate. The period between the tangential lines causes the rotation stage on which the substrate is mounted to rotate at an angle of 180° or more with respect to the revolution stage. 一種PVD處理方法,係用以在複數個基材之表面進行成膜,其包含:準備PVD處理裝置的步驟,該PVD處理裝置係具備:真空腔室,用以容納前述複數個基材;及公轉載台,設置於前述真空腔室內,用以一邊支撐前述複數個基材一邊使此等的基材繞公轉軸而公轉;以及複數個靶材,由互為不同種類的成膜物質所形成,分別配置於在前述公轉載台之徑向外側且在圓周方向相互地分離的複數個位置;以及進行PVD處理的步驟,在基材通過從前述複數個靶材之各靶材之中央對包絡前述各基材之外周面的圓弧所拉出的二條切線之間的期間,一邊使該基材繞與前述公轉載台之前述公轉軸呈平行之自轉軸而相對於該公轉載台以180°以上之角度進行自轉,一邊進行PVD處理。 A PVD processing method for forming a film on a surface of a plurality of substrates, comprising: a step of preparing a PVD processing apparatus, the PVD processing apparatus comprising: a vacuum chamber for accommodating the plurality of substrates; a revolution carrying stage disposed in the vacuum chamber for supporting the plurality of substrates while revolving the substrates around the revolution axis; and the plurality of targets formed by different types of film forming substances And a plurality of positions respectively disposed on a radially outer side of the revolution stage and separated from each other in the circumferential direction; and a step of performing a PVD process on the substrate through the center of each of the plurality of targets a period of time between the two tangent lines drawn by the circular arc of the outer circumferential surface of each of the base materials, the substrate is wound around the revolving axis parallel to the revolution axis of the revolving stage, and is 180 with respect to the revolving stage. The PVD treatment is performed while rotating at an angle of ° or higher.
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