TW201436207A - Germanium FINFET structure - Google Patents
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- TW201436207A TW201436207A TW102108915A TW102108915A TW201436207A TW 201436207 A TW201436207 A TW 201436207A TW 102108915 A TW102108915 A TW 102108915A TW 102108915 A TW102108915 A TW 102108915A TW 201436207 A TW201436207 A TW 201436207A
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- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 229910052732 germanium Inorganic materials 0.000 title claims abstract description 63
- 230000005669 field effect Effects 0.000 claims abstract description 51
- 239000000758 substrate Substances 0.000 claims abstract description 45
- 239000013078 crystal Substances 0.000 claims description 91
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 25
- 229910052707 ruthenium Inorganic materials 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 13
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 12
- 108091006149 Electron carriers Proteins 0.000 claims description 10
- 229910052715 tantalum Inorganic materials 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 7
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910001218 Gallium arsenide Inorganic materials 0.000 claims description 2
- 229910052762 osmium Inorganic materials 0.000 claims description 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 2
- 239000013598 vector Substances 0.000 abstract description 9
- 239000004065 semiconductor Substances 0.000 description 15
- 238000004519 manufacturing process Methods 0.000 description 6
- 230000007547 defect Effects 0.000 description 5
- VGRFVJMYCCLWPQ-UHFFFAOYSA-N germanium Chemical compound [Ge].[Ge] VGRFVJMYCCLWPQ-UHFFFAOYSA-N 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 229910052785 arsenic Inorganic materials 0.000 description 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- 229910000577 Silicon-germanium Inorganic materials 0.000 description 2
- KCFIHQSTJSCCBR-UHFFFAOYSA-N [C].[Ge] Chemical compound [C].[Ge] KCFIHQSTJSCCBR-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000002019 doping agent Substances 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 229910005898 GeSn Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910020750 SixGey Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000000231 atomic layer deposition Methods 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000005234 chemical deposition Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- IWTIUUVUEKAHRM-UHFFFAOYSA-N germanium tin Chemical compound [Ge].[Sn] IWTIUUVUEKAHRM-UHFFFAOYSA-N 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
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- Insulated Gate Type Field-Effect Transistor (AREA)
Abstract
Description
本發明是有關於一種半導體元件結構,且特別是有關於一種包含鍺{111}晶面的鍺半導體鰭式場效電晶體結構。 The present invention relates to a semiconductor device structure, and more particularly to a germanium semiconductor fin field effect transistor structure including a germanium {111} crystal face.
所謂「晶態材料」(crystal material)係指該材料之原子具有週期性的排列方式;所謂「單晶材料」(single crystal material)係指該原子周期性排列方式沿伸至整個材料。對於單晶材料的晶格方向及晶面方向,依據密勒指數(Miller Index,即基於直角立體座標之三維指數)之定義,其中:<hkl>晶格方向表示單晶材料中由原點(0,0,0)指向座標點(h,k,l)所形成的向量,例如:晶格方向<100>係指由原點(0,0,0)指向座標點(1,0,0)的向量;晶格方向[hkl]則是表示包含單晶材料中所有由原點(0,0,0)指向(±h,±k,±l)形成的向量集合,例如:晶格方向[100]係指包含由原點(0,0,0)指向座標點(1,0,0)及(-1,0,0)的向量集合;(hkl)晶面係指法向量為[h,k,l]的平面,例如:(100)晶面係指與向量[1,0,0]垂直的平面;{hkl}晶面則是表示包含所有與向量(±h,±k,±l)垂直的平面集合,例如:{100}晶面係指所有與向量(1,0,0)及(-1,0,0)垂直的平面集合;而晶格方向[hkl]與{hkl}晶面相垂直,例如:晶格方向[100]與{100}晶面相垂直。 By "crystal material" is meant a periodic arrangement of atoms of the material; the so-called "single crystal material" means that the atom is periodically aligned along the entire material. For the lattice direction and the crystal plane direction of the single crystal material, according to the Miller Index (the three-dimensional index based on the right-angled solid coordinates), wherein: the <hkl> lattice direction indicates the origin from the single crystal material ( 0,0,0) points to the vector formed by the coordinate point (h,k,l). For example, the lattice direction <100> means that the origin (0,0,0) points to the coordinate point (1,0,0). The vector; the lattice direction [hkl] is a vector set containing all the points (0, 0, 0) in the single crystal material formed by (±h, ±k, ±l), for example: lattice direction [100] is a set of vectors containing coordinate points (1,0,0) and (-1,0,0) from the origin (0,0,0); (hkl) crystal plane refers to the normal vector as [h] The plane of , k, l], for example: (100) crystal plane refers to the plane perpendicular to the vector [1, 0, 0]; {hkl} crystal plane means that all the vectors are included (±h, ±k, ± l) vertical plane set, for example: {100} crystal plane refers to all plane sets perpendicular to the vector (1,0,0) and (-1,0,0); and lattice direction [hkl] and {hkl The crystal plane is perpendicular, for example, the lattice direction [100] is perpendicular to the {100} crystal plane.
在次奈米世代的半導體製程中,為了達到持續縮小半導體元件尺寸之設計需求,並且進一步提升半導體元件的反應速度與減少半導體元件的消耗功率,選用高載子遷移率的半導體材料,例如:鍺(Ge),來製造 半導體元件是一種解決方案。在垂直於表面的電場下,單結晶鍺{111}表面會形成一勢阱(potential well)。勢阱內的電子因量子力學限制效應會重新分布,而重新分布後的電子占據最低能態,其在{111}面上移動具有最低有效質量,因此,以單結晶鍺結構之{111}晶面做為電子載子之傳導通道,應用於多數載子為電子之N型鍺半導體元件中,例如:N型鍺場效應電晶體(簡稱:N-type Ge FET),其能產生最高的電子載子遷移率。此外,標準型式之N型鰭式閘極鍺場效應電晶體(簡稱:N-type Ge fin-FET),其矩形截面式通道結構之垂直側壁可以貢獻很大的通道有效寬度,更能有效增加元件的驅動電流。 In the sub-nano generation semiconductor process, in order to achieve the design requirements for continuously reducing the size of semiconductor components, and further increase the reaction speed of semiconductor components and reduce the power consumption of semiconductor components, semiconductor materials with high carrier mobility are selected, for example: (Ge), to manufacture Semiconductor components are a solution. Under an electric field perpendicular to the surface, a single crystal 锗 {111} surface forms a potential well. The electrons in the potential well are redistributed due to the quantum mechanical limiting effect, and the redistributed electrons occupy the lowest energy state, which has the lowest effective mass on the {111} plane. Therefore, the {111} crystal with a single crystal 锗 structure The surface is used as a conduction channel for electron carriers, and is applied to N-type germanium semiconductor devices in which most carriers are electrons, for example, an N-type field effect transistor (abbreviation: N-type Ge FET), which can generate the highest electrons. Carrier mobility. In addition, the standard type of N-type fin gate field effect transistor (abbreviation: N-type Ge fin-FET), the vertical side wall of the rectangular section channel structure can contribute a large channel effective width, and can effectively increase The drive current of the component.
由上述兩點可知,標準型式N-type Ge fin-FET之通道結構,若其垂直側壁表面為鍺{111}晶面,則元件可具有極佳的電性表現。然而,習知技術尚無法在表面為鍺{100}晶面之鍺層上形成垂直面為鍺{111}晶面之結構,進而無法製造出標準型式具有{111}面側壁之鰭式閘極鍺場效應電晶體。因此,如何在表面為鍺{110}晶面之鍺層上形成包含垂直面為鍺{111}晶面之鍺鰭式結構,即為發展本發明之主要目的之一。 It can be seen from the above two points that the channel structure of the standard type N-type Ge fin-FET can have an excellent electrical performance if the vertical sidewall surface is a 锗{111} crystal plane. However, the conventional technique cannot form a structure in which a vertical surface is a 锗{111} crystal plane on a germanium layer having a surface of 锗{100} crystal plane, and thus it is impossible to manufacture a standard type fin gate having a {111} plane side wall.锗 field effect transistor. Therefore, how to form a skeletal structure including a vertical plane of 锗{111} crystal plane on the ruthenium layer whose surface is 锗{110} crystal plane is one of the main purposes of developing the present invention.
本發明的目的就是在提供一種鍺鰭式場效電晶體結構,其包含一基底以及一鍺層。鍺層,形成於基底上,鍺層表面為鍺{110}晶面。鍺層包含至少一鍺立體結構。鍺立體結構包含一頂面以及一側壁表面,其中頂面為鍺{110}晶面,側壁表面垂直於頂面。側壁表面與頂面交界處形成一軸線,軸線之延伸方向平行於鍺層表面之鍺[112]晶格方向,側壁表面為鍺{111}晶面。 It is an object of the present invention to provide a skeletal field effect transistor structure comprising a substrate and a layer of germanium. The ruthenium layer is formed on the substrate, and the surface of the ruthenium layer is a 锗{110} crystal plane. The layer of germanium contains at least one solid structure. The 锗 three-dimensional structure comprises a top surface and a sidewall surface, wherein the top surface is a 锗{110} crystal plane, and the sidewall surface is perpendicular to the top surface. An axis is formed at the interface between the sidewall surface and the top surface, and the axis extends in a direction parallel to the 锗[112] lattice direction of the surface of the ruthenium layer, and the sidewall surface is a 锗{111} crystal plane.
在本發明之一實施例中,上述基底為一矽、鍺或鎵砷材料之基底,上述基底表面為{110}晶面。 In an embodiment of the invention, the substrate is a substrate of a ruthenium, osmium or gallium arsenide material, and the surface of the substrate is a {110} crystal plane.
在本發明之一實施例中,上述基底包含一氧化層,氧化層形成於上述基底表面,氧化層包含至少一開口,開口平行於上述基底表面之 [112]晶格方向,上述鍺立體結構形成於開口之中。 In an embodiment of the invention, the substrate includes an oxide layer formed on the surface of the substrate, and the oxide layer includes at least one opening parallel to the surface of the substrate [112] The lattice direction, the above-described 锗 three-dimensional structure is formed in the opening.
在本發明之一實施例中,上述鍺層表面之鍺[112]晶格方向係指由鍺層表面之[110]晶格方向沿上述鍺層表面逆時針旋轉50-60度角或順時針旋轉120-130角之範圍內,亦可順時針旋轉50-60度角或逆時針旋轉120-130角之範圍得到其它等價之[112]晶格方向。 In one embodiment of the present invention, the 锗[112] lattice direction of the surface of the ruthenium layer means that the [110] lattice direction of the surface of the ruthenium layer is rotated counterclockwise by 50-60 degrees or clockwise along the surface of the ruthenium layer. Rotating the range of 120-130 angles can also be rotated clockwise by 50-60 degrees or counterclockwise by 120-130 angles to obtain other equivalent [112] lattice directions.
在本發明之一實施例中,上述鍺立體結構更包含一介電層、一導電結構以及一電子載子(N型)源/汲極掺雜區域。介電層形成於部分之上述鍺立體結構上。導電結構包覆介電層上。導電結構組合介電層構成一第一閘極。電子載子(N型)源/汲極掺雜區域形成於上述鍺立體結構中,配置於第一閘極兩側。 In an embodiment of the invention, the 锗-dimensional structure further includes a dielectric layer, a conductive structure, and an electron carrier (N-type) source/drain doping region. The dielectric layer is formed on a portion of the above-described 锗-dimensional structure. A conductive structure is coated over the dielectric layer. The conductive structure combines the dielectric layer to form a first gate. The electron carrier (N-type) source/drain-doped region is formed in the above-described 锗-dimensional structure and disposed on both sides of the first gate.
在本發明之一實施例中,上述鍺立體結構更包含一底面,底面位於頂面之下而懸浮於上述基底之上。 In an embodiment of the invention, the 锗 three-dimensional structure further includes a bottom surface, and the bottom surface is located below the top surface and suspended on the base.
在本發明之一實施例中,上述鍺立體結構更包含一第一閘極側壁以及一第一應力層。第一閘極側壁環繞於該導電結構之側壁上。第一應力層,配置於上述電子載子(N型)源/汲極掺雜區域上,其中第一應力層之晶格尺寸小於上述鍺層之晶格尺寸。 In an embodiment of the invention, the first three-dimensional structure further includes a first gate sidewall and a first stress layer. The first gate sidewall surrounds the sidewall of the conductive structure. The first stress layer is disposed on the electron carrier (N-type) source/drain doping region, wherein a lattice size of the first stress layer is smaller than a lattice size of the germanium layer.
在本發明之一實施例中,上述電子載子(N型)源/汲極掺雜區域之表面高度低於上述頂面之表面高度。 In an embodiment of the invention, the surface height of the electron carrier (N-type) source/drain doped region is lower than the surface height of the top surface.
在本發明之一實施例中,上述鍺層更包含至少一電洞載子(P型)平面式場效應電晶體結構,P型平面式場效應電晶體結構包含一第二閘極、一電洞載子(P型)源/汲極掺雜區域以及一通道。第二閘極配置於上述鍺層表面上。電洞載子(P型)源/汲極掺雜區域形成於上述鍺層配置於上述第二閘極兩側。通道配置於上述第二閘極下方之上述鍺層表面,其中通道之表面為鍺{110}晶面。 In an embodiment of the invention, the germanium layer further comprises at least one hole carrier (P-type) planar field effect transistor structure, and the P-type planar field effect transistor structure comprises a second gate and a hole carrier. Sub (P-type) source/drain doped regions and one channel. The second gate is disposed on the surface of the germanium layer. A hole carrier (P-type) source/drain-doped region is formed on the tantalum layer and disposed on both sides of the second gate. The channel is disposed on the surface of the germanium layer below the second gate, wherein the surface of the channel is a 锗{110} crystal plane.
在本發明之一實施例中,上述電洞載子(P型)平面式場效應電晶體結構更包含一第二應力層,配置於上述電洞載子(P型)源/汲極掺雜區域上,其中第二應力層之晶格尺寸大於上述鍺層之晶格尺寸。 In an embodiment of the invention, the hole carrier (P-type) planar field effect transistor structure further comprises a second stress layer disposed in the hole carrier (P type) source/drain doped region. Above, wherein the lattice size of the second stress layer is larger than the lattice size of the germanium layer.
本發明提供在平行於{110}鍺層表面之鍺[112]晶格方向形 成鍺立體結構,因此能夠在鍺{110}晶面之鍺層上製造出包含垂直側面為鍺{111}晶面之鍺鰭式場效電晶體結構。 The present invention provides a lattice [112] lattice orientation parallel to the surface of the {110} layer The three-dimensional structure is formed, so that a ruthenium field effect transistor structure including a vertical side surface of 锗{111} crystal plane can be fabricated on the 锗{110} crystal plane.
為讓本發明之上述和其他目的、特徵和優點能更明顯易懂,下文特舉較佳實施例,並配合所附圖式,作詳細說明如下。 The above and other objects, features and advantages of the present invention will become more <RTIgt;
10‧‧‧單晶鍺層 10‧‧‧ Single crystal layer
10a‧‧‧單晶鍺層平側面 10a‧‧‧Single side of the single crystal layer
11‧‧‧單晶鍺層表面 11‧‧‧Single crystal layer surface
12‧‧‧單晶鍺層切面 12‧‧‧ Single crystal layer
Θ‧‧‧鍺[110]晶格方向與[112]晶格方向之夾角 Θ‧‧‧锗[110] The angle between the lattice direction and the [112] lattice direction
⊙‧‧‧垂直於紙面之鍺層上的[112]晶格方向 ⊙‧‧‧The direction of the [112] lattice perpendicular to the layer of paper
200、300‧‧‧基底 200, 300‧‧‧ base
210‧‧‧鍺層 210‧‧‧锗
210P‧‧‧P型平面式場效應電晶體結構之通道表面 Channel surface of 210P‧‧‧P type planar field effect transistor structure
210S‧‧‧P+型源極區 210S‧‧‧P+ source region
210D‧‧‧P+型汲極區 210D‧‧‧P+ type bungee area
211‧‧‧鍺層表面 211‧‧‧锗layer surface
220、320‧‧‧鍺立體結構 220, 320‧‧‧锗 three-dimensional structure
220a、320a‧‧‧鍺立體結構之頂面 220a, 320a‧‧‧锗 top surface of the three-dimensional structure
220b、320b‧‧‧鍺立體結構之側壁表面 Side wall surface of 220b, 320b‧‧‧锗 three-dimensional structure
220S、221S‧‧‧N+型源極區 220S, 221S‧‧‧N+ source region
220D、221D‧‧‧N+型汲極區 220D, 221D‧‧‧N+ type bungee area
230‧‧‧遮罩 230‧‧‧ mask
240‧‧‧絕緣結構層 240‧‧‧Insulation structural layer
241、330‧‧‧閘極介電層 241, 330‧‧ ‧ gate dielectric layer
250、340‧‧‧導電結構 250, 340‧‧‧ conductive structure
260‧‧‧第一閘極 260‧‧‧ first gate
261‧‧‧第一閘極側壁 261‧‧‧First gate sidewall
270‧‧‧N型鰭式場效應電晶體結構 270‧‧‧N-type fin field effect transistor structure
271‧‧‧第一應力層 271‧‧‧First stress layer
280‧‧‧第二閘極 280‧‧‧second gate
290‧‧‧P型平面式場效應電晶體結構 290‧‧‧P type planar field effect transistor structure
291‧‧‧第二應力層 291‧‧‧Second stress layer
301‧‧‧基底表面 301‧‧‧Base surface
310‧‧‧絕緣層 310‧‧‧Insulation
310a‧‧‧絕緣層開口 310a‧‧‧Insulation opening
350‧‧‧閘極 350‧‧‧ gate
圖1A至圖1C繪示單晶鍺層之晶格及晶面方向座標圖。 1A to 1C are graphs showing the lattice and crystal plane orientation of a single crystal germanium layer.
圖2A至圖2E繪示本發明之一實施例部分結構示意圖。 2A to 2E are partial structural views showing an embodiment of the present invention.
圖3A至3D繪示本發明另一實施例部分結構示意圖。 3A to 3D are partial structural views showing another embodiment of the present invention.
為能便於說明本發明所提供在鍺{110}晶面之鍺層上形成包含垂直側面為鍺{111}晶面之鍺鰭式場效電晶體結構,圖1A至圖1C繪示針對具體(110)單晶鍺層在立體座標系中,其各晶面標示與晶格方向之具體關係。 In order to facilitate the description of the present invention, a ruthenium field effect transistor structure including a vertical side surface of a 111{111} crystal plane is formed on the 锗{110} crystal plane, and FIGS. 1A to 1C are for specific (110). The single crystal ruthenium layer is in the three-dimensional coordinate system, and its crystal faces are marked with a specific relationship with the lattice direction.
請參見圖1A所示x-y-z直角立體座標圖,圖1A中縱軸標示為z軸(沿<001>晶格方向),兩條水平軸標示為x軸(沿<100>晶格方向)及y軸(沿<010>晶格方向),做為說明的單晶鍺層10繪示為晶圓狀圓盤,其中心位於x-y-z立體座標之原點。單晶鍺層表面11為(110)晶面,圖中垂直記號┌標示與單晶鍺層表面11相垂直的晶格方向為<110>晶格方向,即單晶鍺層表面11的法向;單晶鍺層10的平側面10a為晶面,其法向為晶格方向。由單晶鍺層表面11上的晶格方向沿著表面做逆時針旋轉Θ角(Θ約為54.7度角)為單晶鍺層表面11上的晶格方向,或順時針旋轉π-Θ角為單晶鍺層表面11上的晶格方向。 See the xyz right-angled stereograph shown in Figure 1A. In Figure 1A, the vertical axis is labeled z-axis (along the <001> lattice direction), and the two horizontal axes are labeled x-axis (along the <100> lattice direction) and y The axis (along the <010> lattice direction), as a description of the single crystal germanium layer 10 is shown as a wafer-like disk, the center of which is located at the origin of the xyz stereo coordinates. The surface 11 of the single crystal germanium layer is a (110) crystal plane, and the vertical mark 图 in the figure indicates that the lattice direction perpendicular to the surface 11 of the single crystal germanium layer is <110> lattice direction, that is, the normal direction of the surface 11 of the single crystal germanium layer. The flat side 10a of the single crystal germanium layer 10 is Crystal face, its normal direction is Lattice direction. On the surface 11 of the single crystal germanium layer The lattice direction is rotated counterclockwise along the surface (the angle of Θ is about 54.7 degrees) on the surface 11 of the single crystal germanium layer. Lattice direction, or clockwise rotation of π-Θ angle on the surface of the single crystal germanium layer 11 Lattice direction.
請參見圖1B所示單晶鍺層(110)晶面平面座標圖,圖1B中縱軸標示為z軸。與單晶鍺層表面11上的晶格方向(反方向為晶格方向)相垂直的為晶格方向。 Please refer to the plane plane coordinate diagram of the single crystal germanium layer (110) shown in FIG. 1B, and the vertical axis in FIG. 1B is denoted as the z-axis. On the surface 11 of the single crystal germanium layer Lattice direction (reverse direction is The direction of the crystal lattice is perpendicular to Lattice direction.
再請參見圖1C所示x-y-z直角立體座標圖,圖1C中縱軸標示為z軸,兩條水平軸標示為x軸及y軸,做為說明的單晶鍺層10繪示由單晶鍺層表面11上的延伸至其反方向之晶格方向所做的垂直剖面立體圖,與單晶鍺層切面12相垂直的為單晶鍺層的晶格方向,亦即單晶鍺層之切面12為晶面。 Referring again to the xyz rectangular solid coordinate diagram shown in FIG. 1C, the vertical axis of FIG. 1C is denoted as the z-axis, and the two horizontal axes are denoted by the x-axis and the y-axis, and the single crystal germanium layer 10 is illustrated as a single crystal germanium. On the surface 11 of the layer Extend to the opposite direction A vertical sectional perspective view made in the direction of the crystal lattice, which is perpendicular to the single-crystal tantalum layer 12, is a single crystal layer The lattice direction, that is, the slice 12 of the single crystal germanium layer is Planes.
請再參見圖1B。值得一提的是,由於對稱關係,由單晶鍺層表面11上的晶格方向沿著表面做順時針旋轉Θ角(Θ約為54.7度角)為單晶鍺層表面11上的晶格方向(圖未示)或逆時針旋轉π-Θ角為其反方向晶格方向,由延伸至其反方向之晶格方向做垂直表面切割,所得到的切面為晶面。 Please refer to FIG. 1B again. It is worth mentioning that due to the symmetrical relationship, the surface of the single crystal layer is on the surface 11 The lattice direction is rotated clockwise along the surface (an angle of about 54.7 degrees) on the surface 11 of the single crystal germanium layer. Lattice direction (not shown) or counterclockwise rotation π-Θ angle is the opposite direction Lattice direction, by Extend to the opposite direction The vertical direction of the lattice direction is cut, and the obtained cut surface is Planes.
由圖1A至圖1C的說明可知,本發明利用在表面為{110}晶面的單晶鍺層上,沿著單晶鍺層表面上的[112]晶格方向垂直切割,即可形成垂直面為鍺{111}晶面之鍺立體結構。值得注意的是,本發明所指單晶鍺層表面上的[112]晶格方向,係指由單晶鍺層表面11上的[110]晶格方向沿著表面做逆時針旋轉Θ角或順時針旋轉π-Θ角,其中Θ±5度均屬本發明所定義單晶鍺層表面上的[112]晶格方向範圍內。詳細來說,即是由單晶鍺層表面11的[110]晶格方向沿著表面做逆時針旋轉50-60度角或順時針旋轉120-130角均屬本發明所定義單晶鍺層表面上的[112]晶格方向。 1A to 1C, the present invention can be vertically formed by cutting vertically along the [112] lattice direction on the surface of the single crystal germanium layer on a single crystal germanium layer having a {110} crystal plane on the surface. The surface is the three-dimensional structure of the {111} crystal plane. It should be noted that the [112] lattice direction on the surface of the single crystal germanium layer referred to in the present invention means that the [110] lattice direction on the surface 11 of the single crystal germanium layer is counterclockwise rotated along the surface or The π-turn angle is rotated clockwise, wherein Θ±5 degrees are within the range of the [112] lattice direction on the surface of the single crystal germanium layer defined by the present invention. In detail, it is a single crystal germanium layer defined by the present invention, which is rotated by a 50-60 degree angle counterclockwise from the [110] lattice direction of the surface 11 of the single crystal germanium layer surface or rotated 120-130 degrees clockwise. [112] lattice direction on the surface.
本發明可進一步利用該垂直面為鍺{111}晶面之鍺立體結構來製造具有高速電子載子遷移率的鍺鰭式場效電晶體。 The present invention can further utilize a three-dimensional structure in which the vertical plane is a 锗{111} crystal plane to fabricate a skeletal field effect transistor having high-speed electron carrier mobility.
圖2A至2E繪示本發明之一實施例部分步驟及結構示意圖。 2A to 2E are partial schematic views showing the steps and structures of an embodiment of the present invention.
請參見圖2A所示剖面示意圖,基底200上形成有鍺層210,其中基底200可為鍺基底、本體矽基底(bulk)、絕緣層上矽基底(SOI)或化合物半導體基底,例如:砷化鎵等,鍺層表面211為{110}晶面。圖中⊙標記為垂直於紙面之鍺[112]晶格方向。形成鍺層的方法可以是:在基底上磊晶生長鍺層;在基底上先形成過度層(buffer layer),例如是:矽鍺過度層(SixGey buffer layer),再生長鍺層,其中鍺層210中之過度層可用以調整鍺層與異質基底間之晶格尺寸差異和降低鍺層內之缺陷密度;又,可利用聰明切法 (smart cut):於另一基底上形成鍺層210後,在該基底與鍺層210間生長一氧化層,由該氧化層切割鍺層210,再將鍺層210貼合於基底200上等方法在基底200上形成鍺層210,本發明對此不做限制。另一方面,如利用異質基底直接形成鍺層,因鍺層與異質基底材料的晶格尺寸不同,而會在鍺層之結構中產生差排缺陷(dislocation defect)。消除上述差排缺陷之方法,可依據如台灣專利申請號101117652專利申請案說明書中所揭露之技術,對鍺層進行反覆退火製程來消除鍺層之結構中的差排缺陷。 Referring to the cross-sectional view of FIG. 2A, a substrate 210 is formed on the substrate 200. The substrate 200 may be a germanium substrate, a bulk germanium, an insulating germanium germanium (SOI) or a compound semiconductor substrate, for example, arsenic. For gallium or the like, the surface 211 of the germanium layer is a {110} crystal plane. In the figure, ⊙ is marked as perpendicular to the 锗 [112] lattice direction of the paper surface. The method for forming the ruthenium layer may be: epitaxial growth of the ruthenium layer on the substrate; forming a buffer layer on the substrate, for example: a SixGey buffer layer, a regenerated ruthenium layer, wherein the ruthenium layer The excess layer in 210 can be used to adjust the difference in lattice size between the germanium layer and the heterogeneous substrate and to reduce the defect density in the germanium layer; (smart cut): after forming the tantalum layer 210 on another substrate, an oxide layer is grown between the substrate and the tantalum layer 210, the tantalum layer 210 is cut by the oxide layer, and the tantalum layer 210 is attached to the substrate 200, etc. The method forms a layer 210 on the substrate 200, which is not limited in the present invention. On the other hand, if a germanium layer is directly formed by using a heterogeneous substrate, since the lattice size of the germanium layer and the heterogeneous base material are different, a dislocation defect may occur in the structure of the germanium layer. The method of eliminating the above-mentioned difference in the defect can be performed by performing a reverse annealing process on the tantalum layer to eliminate the defective defect in the structure of the tantalum layer, according to the technique disclosed in the specification of the patent application No. 101117652.
請參見圖2B所示剖面示意圖,於鍺層表面211上的[112]晶格方向上形成遮罩230後,去除部分之鍺層而形成鍺立體結構220。並且可進一步如上述101117652專利申請案所揭露之技術,利用鍺層與基底結合界面差排缺陷的結構較為脆弱,去除鍺立體結構220與基底接合界面之差排缺陷,使鍺立體結構懸浮於基底表面而形成一底面。在本實施例中,鍺立體結構220底部可製作至鍺層210與基底200界面處,甚至深入到基底200,鍺立體結構220包含頂面220a側壁表面220b。頂面220a同樣為鍺{110}晶面。側壁表面220b垂直於頂面220a之交界處形成一軸線(如圖3D中所示之箭頭符號),軸線之延伸方向平行於鍺層之鍺[112]晶格方向,在此架構下,側壁表面220b為鍺{111}晶面。 Referring to the cross-sectional view shown in FIG. 2B, after the mask 230 is formed in the [112] lattice direction on the surface 211 of the enamel layer, a portion of the ruthenium layer is removed to form the ruthenium structure 220. Further, as disclosed in the above-mentioned Patent Application No. 101117652, the structure in which the defect of the tantalum layer and the substrate is poorly arranged is weak, and the difference between the tantalum structure 220 and the substrate joint interface is removed, and the three-dimensional structure is suspended on the substrate. The surface forms a bottom surface. In this embodiment, the bottom of the 锗-dimensional structure 220 can be fabricated to the interface between the ruthenium layer 210 and the substrate 200, even deep into the substrate 200, and the 锗-dimensional structure 220 includes the top surface 220a sidewall surface 220b. The top surface 220a is also a 锗{110} crystal plane. The sidewall surface 220b forms an axis perpendicular to the interface of the top surface 220a (as indicated by the arrow in FIG. 3D), and the axis extends in a direction parallel to the 锗[112] lattice direction of the 锗 layer, under which the sidewall surface 220b is a 111{111} crystal plane.
請參見圖2C所示剖面示意圖,於鍺層包含鍺立體結構之表面上,以化學沉積或原子層沉積等方法形成如氧化矽等絕緣材料之絕緣結構層240。接著,去除部分絕緣結構層240而露出部分之鍺結構220。之後,於部分之鍺立體結構表面220上,以二氧化鋯或其他高介電係數絕緣材料形成閘極介電層241,再以鈦或其他金屬材料形成導電結構250包覆閘極介電層241即可構成第一閘極260。第一閘極260包覆部分之頂面220a及側壁表面220b。接著,以N型摻質,例如:磷或砷,於第一閘極260兩側之露出部分之鍺立體結構進行摻雜,而形成一電子載子(N型)源/汲極掺雜區域。如圖2C中所示之鍺立體結構進而可製造具有垂直面通道為鍺{111}晶面之標準N型鰭式場效應電晶體。 Referring to the cross-sectional view shown in FIG. 2C, an insulating structure layer 240 of an insulating material such as yttrium oxide is formed by chemical deposition or atomic layer deposition on the surface of the ruthenium layer including the 锗-dimensional structure. Next, a portion of the insulating structure layer 240 is removed to expose a portion of the germanium structure 220. Thereafter, a gate dielectric layer 241 is formed on a portion of the tantalum structure surface 220 with zirconium dioxide or other high dielectric constant insulating material, and the conductive structure 250 is coated with titanium or other metal material to cover the gate dielectric layer. The first gate 260 can be formed by 241. The first gate 260 covers a top surface 220a of the portion and a sidewall surface 220b. Then, an N-type dopant, such as phosphorus or arsenic, is doped in the exposed three-dimensional structure on both sides of the first gate 260 to form an electron carrier (N-type) source/drain-doped region. . The 锗-dimensional structure as shown in FIG. 2C can in turn produce a standard N-type fin field effect transistor having a vertical plane of 锗{111} crystal plane.
本發明所提供的技術方案,可輕易地在表面為鍺{110}晶面之鍺層上形成具有垂直面為鍺{111}晶面的鍺結構,進而製造出高載子遷移 率的N型鰭式閘極鍺場效應電晶體。此外,電洞載子在鍺{110}晶面上的遷移率最高,因此,除上述所提供製造N型鍺鰭式場效應電晶體之技術方案,本發明還可利用鍺{110}晶面之鍺層表面來形成P型鍺平面式場效應電晶體,或可進一步於場效應電晶體之源汲極區上形成應力層(stressor),能更加提升場效應電晶體元件的電性表現。 According to the technical solution provided by the present invention, a germanium structure having a vertical plane of 锗{111} crystal plane can be easily formed on a germanium layer having a surface of 锗{110} crystal plane, thereby producing high carrier migration. The rate of the N-type fin gate field effect transistor. In addition, the mobility of the hole carrier on the 锗{110} crystal plane is the highest, and therefore, in addition to the above-mentioned technical solution for manufacturing the N-type skeletal field effect transistor, the present invention can also utilize the 锗{110} crystal plane. The surface of the germanium layer is formed to form a P-type germanium planar field effect transistor, or a stressor may be further formed on the source drain region of the field effect transistor to further improve the electrical performance of the field effect transistor component.
請參見圖2D所式剖面示意圖,鍺層210除包含N型鰭式場效應電晶體結構270,更可包含P型平面式場效應電晶體結構290。製造P型平面式場效應電晶體結構290可依據一般製造平面式場效應電晶體的方法,於此不多贅述。P型平面式場效應電晶體結構290中第二閘極280下方之通道表面210P為鍺{110}晶面;N型鰭式場效應電晶體結構270中垂直通道之側壁表面220b為鍺{110}晶面。具有鍺{111}晶面通道的N型鰭式場效應電晶體結構270與具有鍺{110}晶面通道的P型平面式場效應電晶體結構290可組合形成具有極佳電性表現的互補式場效應電晶體(CMOS)。 Referring to the cross-sectional view of FIG. 2D, the germanium layer 210 includes a N-type fin field effect transistor structure 270, and may further include a P-type planar field effect transistor structure 290. The fabrication of the P-type planar field effect transistor structure 290 can be based on the general method of fabricating a planar field effect transistor, and will not be described here. The channel surface 210P under the second gate 280 in the P-type planar field effect transistor structure 290 is a 锗{110} crystal plane; the sidewall surface 220b of the vertical channel in the N-type fin field effect transistor structure 270 is 锗{110} crystal surface. An N-type fin field effect transistor structure 270 having a 锗{111} plane channel and a P-type planar field effect transistor structure 290 having a 锗{110} plane channel can be combined to form a complementary field effect with excellent electrical performance. Transistor (CMOS).
詳細來說,N型鰭式場效應電晶體結構270中,N+型源極區220S與N+型汲極區220D配置於第一閘極260兩側,且源極區220S與汲極區220D上方還配置有第一應力層271。第一應力層271可以如下述方法完成。首先,形成第一閘極側壁261環繞第一閘極260之側壁,並露出部分之鍺立體結構。接著,於露出部分之鍺立體結構中,摻雜高濃度之N型摻質形成N+型源極區220S與N+型汲極區220D。以及,於N+型源極區220S與N+型汲極區220D之表面上,磊晶生長晶格尺寸小於鍺之N+摻雜半導體材料層,例如是:矽(Si)、矽鍺(SiGe)、矽鍺-碳(SiGe:C)或矽碳(SiC)等,形成第一應力層271。第一應力層271可透過在通道區產生拉伸應變,提升電子遷移率。此外,因應電子與電洞不同的載子特性,本發明還可選用晶格尺寸大於鍺層之半導體材料,例如是:鍺錫(GeSn),於P型平面式場效應電晶體結構290之P+型源極區210S與P+型汲極區210D上,形成高濃度P型摻雜之第二應力層281。如圖2D所示,配置於N型鰭式場效應電晶體結構270中之第一應力層271與配置於P型平面式場效應電晶體結構290中之第二應力層291為提升式應力層(raised type stressor),而在其他實施方式中,亦可於形成嵌入式應力層(embedded type stressor)。 In detail, in the N-type fin field effect transistor structure 270, the N+ type source region 220S and the N+ type drain region 220D are disposed on both sides of the first gate 260, and the source region 220S and the drain region 220D are further disposed. A first stress layer 271 is disposed. The first stressor layer 271 can be completed as follows. First, the first gate sidewall 261 is formed to surround the sidewall of the first gate 260, and a portion of the dome structure is exposed. Next, in the exposed three-dimensional structure, a high concentration of N-type dopant is doped to form an N+ source region 220S and an N+ type drain region 220D. And on the surface of the N+ type source region 220S and the N+ type drain region 220D, the epitaxial growth lattice size is smaller than the N+ doped semiconductor material layer of germanium, for example: germanium (Si), germanium (SiGe), The first stress layer 271 is formed of germanium-carbon (SiGe: C) or germanium carbon (SiC). The first stress layer 271 can increase the electron mobility by generating tensile strain in the channel region. In addition, in view of the different carrier characteristics of the electron and the hole, the present invention may also select a semiconductor material having a lattice size larger than that of the germanium layer, for example, germanium tin (GeSn), P+ type of the P-type planar field effect transistor structure 290. On the source region 210S and the P+ type drain region 210D, a high concentration P-doped second stress layer 281 is formed. As shown in FIG. 2D, the first stressor layer 271 disposed in the N-type fin field effect transistor structure 270 and the second stress layer 291 disposed in the P-type planar field effect transistor structure 290 are lifted stress layers (raised) Type stressor), and in other embodiments, an embedded type stressor may also be formed.
請參見圖2E所示剖面圖,於形成第一閘極側壁261而露出部分之立體鍺結構後,去除部分露出部分之鍺立體結構,而使N+型源極區221S與N+型汲極區221D表面低於鍺立體結構頂面220a。接著,如前述之方法,於N+型源極區221S與N+型汲極區221D上形成第一應力層271,即可形成具有嵌入式應力層之N型鰭式場效應電晶體結構270。 Referring to the cross-sectional view shown in FIG. 2E, after forming the first gate sidewall 261 and exposing a portion of the three-dimensional structure, the three-dimensional structure of the partially exposed portion is removed, and the N+ source region 221S and the N+ type drain region 221D are removed. The surface is lower than the top surface 220a of the three-dimensional structure. Next, as described above, the first stressor layer 271 is formed on the N+ source region 221S and the N+ type drain region 221D to form an N-type fin field effect transistor structure 270 having an embedded stress layer.
圖3A至3D繪示本發明另一實施例之部分結構示意圖。 3A to 3D are partial structural views showing another embodiment of the present invention.
請參見圖3A所示剖面示意圖,基底300上形成有絕緣層310,其中基底300可為鍺基底、本體矽基底(bulk)、絕緣層上矽基底(SOI)或化合物半導體基底,例如:砷化鎵等,本發明對此不做限制。基底表面301為{110}晶面,圖中⊙標記[112]晶格方向垂直於紙面。沿著半導體基底表面301上的[112]晶格方向上,去除部分之絕緣層而形成至少一開口310a。 Referring to the cross-sectional view of FIG. 3A, an insulating layer 310 is formed on the substrate 300. The substrate 300 may be a germanium substrate, a bulk germanium, an insulating germanium germanium (SOI) or a compound semiconductor substrate, for example, arsenic. Gallium and the like, the present invention does not limit this. The substrate surface 301 is a {110} crystal plane, and the ⊙ mark [112] lattice direction is perpendicular to the paper surface. A portion of the insulating layer is removed along the [112] lattice direction on the surface 301 of the semiconductor substrate to form at least one opening 310a.
請參見圖3B所示剖面示意圖,利用基底表面的{110}晶面磊晶生長鍺層。鍺層包含至少一鍺立體結構320,鍺立體結構320形成於開口310a中。鍺立體結構320包含頂面320a以及側壁表面320b,其中頂面320a為鍺{110}晶面。再請參見圖3C所示剖面示意圖,回蝕去除部分絕緣層310而露出部分之側壁表面320b。 Referring to the cross-sectional view shown in FIG. 3B, the germanium layer is epitaxially grown by {110} crystal plane on the surface of the substrate. The ruthenium layer includes at least one 锗 stereostructure 320 formed in the opening 310a. The 锗 stereostructure 320 includes a top surface 320a and a sidewall surface 320b, wherein the top surface 320a is a 锗{110} crystal plane. Referring again to the cross-sectional view of FIG. 3C, a portion of the insulating layer 310 is removed by etch back to expose a portion of the sidewall surface 320b.
請參見圖3D所示鍺立體結構320之立體示意圖。鍺立體結構320之側壁表面320b與頂面320a交界處形成一軸線(圖中箭頭所示),軸線之延伸方向平行於基底之[112]晶格方向,側壁表面320b則為鍺{111}晶面。於部分之鍺結構320表面上形成鰭式場效應電晶體之閘極介電層330,再形成導電結構340包覆閘極介電層330,導電結構340組合閘極介電層330即可構成閘極350。鍺立體結構320進而可應用於製造出具有垂直通道面為鍺{111}晶面的鍺鰭式場效應電晶體。 Please refer to the perspective view of the three-dimensional structure 320 shown in FIG. 3D. An axis (shown by an arrow in the figure) is formed at a boundary between the sidewall surface 320b of the three-dimensional structure 320 and the top surface 320a. The axis extends in a direction parallel to the [112] lattice direction of the substrate, and the sidewall surface 320b is a 锗{111} crystal. surface. A gate dielectric layer 330 of the fin field effect transistor is formed on a portion of the germanium structure 320, and a conductive structure 340 is formed to cover the gate dielectric layer 330. The conductive structure 340 is combined with the gate dielectric layer 330 to form a gate. Extreme 350. The 锗 stereostructure 320 is in turn applicable to the fabrication of a skeletal field effect transistor having a vertical channel surface of 锗{111} crystal plane.
綜上所述,實施本發明之技術方案,在平行於{110}鍺層表面之鍺[112]晶格方向形成鍺立體結構,因此能輕易地在鍺{110}晶面之鍺層上形成包含垂直側面為鍺{111}晶面之鍺鰭式場效電晶體結構,從而能製造出具有極佳電性效能之半導體元件。 In summary, the technical solution of the present invention is to form a 锗-dimensional structure in a lattice direction parallel to the surface of the {110} 锗 layer, so that it can be easily formed on the 锗 layer of the 110{110} crystal plane. The ruthenium field effect transistor structure including the vertical side surface is a 111{111} crystal plane, thereby manufacturing a semiconductor element having excellent electrical performance.
雖然本發明已以較佳實施例揭露如上,然其並非用以限定本 發明,任何熟習此技藝者,在不脫離本發明之精神和範圍內,當可作些許之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。 Although the present invention has been disclosed above in the preferred embodiments, it is not intended to limit the present invention. The invention is to be understood as being limited by the scope of the appended claims.
300‧‧‧基底 300‧‧‧Base
310‧‧‧絕緣層 310‧‧‧Insulation
320‧‧‧鍺立體結構 320‧‧‧锗Three-dimensional structure
320a‧‧‧鍺立體結構之頂面 320a‧‧‧锗Top surface of the three-dimensional structure
320b‧‧‧鍺立體結構之側壁表面 320b‧‧‧锗Side structure of the side wall surface
330‧‧‧閘極介電層 330‧‧‧ gate dielectric layer
340‧‧‧導電結構 340‧‧‧Electrical structure
350‧‧‧閘極 350‧‧‧ gate
Claims (10)
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11271094B2 (en) | 2018-11-29 | 2022-03-08 | Taiwan Semiconductor Manufacturing Company Ltd. | Semiconductor structure and method of manufacturing the same |
| TWI793370B (en) * | 2018-11-29 | 2023-02-21 | 台灣積體電路製造股份有限公司 | Semiconductor structure and method of manufacturing the same |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11271094B2 (en) | 2018-11-29 | 2022-03-08 | Taiwan Semiconductor Manufacturing Company Ltd. | Semiconductor structure and method of manufacturing the same |
| TWI793370B (en) * | 2018-11-29 | 2023-02-21 | 台灣積體電路製造股份有限公司 | Semiconductor structure and method of manufacturing the same |
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