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TW201406670A - Intelligent conditioning system for deep dewatering of sludge - Google Patents

Intelligent conditioning system for deep dewatering of sludge Download PDF

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Publication number
TW201406670A
TW201406670A TW102122884A TW102122884A TW201406670A TW 201406670 A TW201406670 A TW 201406670A TW 102122884 A TW102122884 A TW 102122884A TW 102122884 A TW102122884 A TW 102122884A TW 201406670 A TW201406670 A TW 201406670A
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Taiwan
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sludge
dosing
conditioning system
conditioning
chloride
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TW102122884A
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Chinese (zh)
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Heng-Rui Sui
wei-xin Yao
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Jiangsu Greenway Environmental Prot Technology Co Ltd
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Abstract

The invention discloses an intelligent conditioning system for deep dewatering of sludge, which comprises a high-efficiency mixing module, wherein the high-efficiency mixing module comprises a pipeline mixer and a stirring reactor. According to the invention, an intelligent diagnosis system diagnoses each part in the reaction process of a sludge treatment device, and transmits the diagnosis result to a control unit; the control unit analyzes the diagnosis result, and controls a dosing system to perform dosing operation according to a control result; and through the treatment of the invention, the sludge moisture content is reduced from the originally 80-98% to 35-60%, the final sludge output mass is reduced by at least 50%, the sludge can still keep 70% or above (about 600-3000 kilocalories per kilogram) of the original organic caloric value after the sludge moisture content is reduced, and the sludge can be further treated by incineration and drying.

Description

污泥深度脫水智慧調理系統 Sludge deep dewatering intelligent conditioning system

本發明涉及一種污泥調理系統,更確切地說是具有一種智慧化診測,並通過該智慧化診測模組的結果及時調整加藥的時間、加藥的種類和加藥的順序的污泥深度脫水智慧調理系統。 The invention relates to a sludge conditioning system, and more particularly to an intelligent diagnosis and diagnosis, and timely adjusts the time of dosing, the type of dosing and the order of dosing through the result of the intelligent diagnosis and testing module. Mud deep dehydration intelligent conditioning system.

現有技術的污泥處理流程為將含水率為80%的外來原泥加入到調理池,然後加水混合攪拌10-15分鐘,然後加入第一藥劑,並將加過藥的污泥加入到第二調理池並且混合攪拌10-15分鐘;然後加入第二藥劑,並將加過藥的污泥加入到第二調理池並且混合攪拌10-15分鐘;然後加入第五藥劑,並將加過藥的污泥加入到第二調理池並且混合攪拌10-15分鐘;處理完成後的污泥加入到壓濾機內保壓30鐘,經過該處理完成後得到含水率55%的乾泥,然後送入到乾泥棚。 The prior art sludge treatment process is to add external raw mud with a water content of 80% to the conditioning tank, then mix and stir with water for 10-15 minutes, then add the first agent, and add the added sludge to the second. Conditioning the tank and mixing for 10-15 minutes; then adding the second agent, adding the added sludge to the second conditioning tank and mixing and stirring for 10-15 minutes; then adding the fifth agent and adding the drug The sludge is added to the second conditioning tank and mixed for 10-15 minutes; the sludge after the treatment is added to the filter press for 30 hours, and after the treatment is completed, the dry mud having a moisture content of 55% is obtained, and then sent. Go to the dry mud shed.

現有技術的藥劑加入的方法是不管污泥的成份如何,僅加入相同的試劑,因此會造成污泥處理不完全,也不能根據污泥的組分和用途進行個性化的處理。 The prior art method of adding the medicament is to add only the same reagent regardless of the composition of the sludge, so that the sludge treatment is incomplete, and the individual treatment of the composition and use of the sludge cannot be performed.

現有技術的污泥處理流程的工藝簡單,結構多樣化,但是不可連續作業工作,且污泥來源難分類調理,且攪拌不充分,混合時間長,臭味重,調理時間長,藥劑使用人為因素大。 The prior art sludge treatment process is simple in process and diversified in structure, but it is not workable continuously, and the source of sludge is difficult to be classified and conditioned, and the stirring is insufficient, the mixing time is long, the odor is heavy, the conditioning time is long, and the human factor of the medicament is used. Big.

本發明的目的是提供一種污泥深度脫水智慧調理系統,其可以解決現有技術中的攪拌不充分,且臭味重,且不能混合均勻以致處理不完全的缺點。 It is an object of the present invention to provide a sludge deep dewatering intelligent conditioning system which can solve the disadvantages of insufficient agitation in the prior art, heavy odor, and inability to mix uniformly so that the treatment is incomplete.

本發明採用以下技術方案:一種污泥深度脫水智慧調理系統,包括一智慧診斷模組,其包括:污泥參數診測傳感單元,其對污泥的各項參數進行診測;電腦控制單元,其接收所述污泥參數診測傳感單元診測的參數資料,並對該參數資料進行處理後輸出一加藥控制信號;以及加藥裝置,其接收所述加藥控制信號並根據所述加藥控制信號進行加藥。 The invention adopts the following technical solutions: a sludge deep dehydration intelligent conditioning system, comprising a smart diagnosis module, comprising: a sludge parameter diagnosis and sensing unit, which diagnoses and measures various parameters of the sludge; the computer control unit Receiving the parameter data of the diagnosis of the sludge parameter diagnosis and sensing unit, and processing the parameter data to output a dosing control signal; and the dosing device receiving the dosing control signal and according to the The dosing control signal is used for dosing.

污泥深度脫水智慧調理系統還包括一用於儲存未處理污泥的污泥存儲罐,所述污泥參數診測單元還包括一與所述污泥存儲罐相連且檢測污泥存儲罐內的污泥參數並將所述檢測到的污泥參數資料傳輸至所述電腦控制單元的污泥檢測裝置。 The sludge deep dewatering intelligent conditioning system further comprises a sludge storage tank for storing untreated sludge, the sludge parameter diagnostic unit further comprising a sludge storage tank connected to the sludge storage tank The sludge parameter and the detected sludge parameter data are transmitted to the sludge detecting device of the computer control unit.

污泥深度脫水智慧調理系統還包括一用於檢測經所述調理裝置處理後的污泥進行脫水的脫水裝置,所述污泥參數診測單元還包括一與所述脫水裝置相連且檢測經脫水裝置脫水後的污泥參數的污泥檢測裝置;所述電腦控制單元接收所述脫水後的污泥參數資料並根據脫水後的污泥參數資料控制脫水裝置。 The sludge deep dewatering intelligent conditioning system further comprises a dewatering device for detecting dewatering by the sludge treated by the conditioning device, the sludge parameter diagnostic unit further comprising a dehydration device connected to the dehydration device and detecting dehydration a sludge detecting device for sludge parameters after dewatering; the computer control unit receives the dewatered sludge parameter data and controls the dewatering device according to the dewatered sludge parameter data.

污泥深度脫水智慧調理系統還包括一用於檢測加藥裝置藥劑參數的藥劑檢測裝置,所述藥劑檢測裝置與所述加藥裝置連接,且所述藥劑檢測裝置將檢測到的藥劑參數資料傳輸到所述電腦控制單元;所述電腦控制單元接收所述藥劑參數資料並根據藥劑參數資料控制加藥裝置。 The sludge deep dehydration intelligent conditioning system further comprises a medicament detecting device for detecting a medicament parameter of the dosing device, the medicament detecting device is connected to the dosing device, and the medicament detecting device transmits the detected drug parameter data Go to the computer control unit; the computer control unit receives the drug parameter data and controls the dosing device according to the drug parameter data.

所述污泥參數診測單元包括一與所述調理裝置相連且檢測 調理裝置調理後的污泥參數的調理檢測裝置,所述電腦控制單元接收所述調理後的污泥參數資料並根據調理後的污泥參數資料控制調理裝置的調理。 The sludge parameter diagnosis unit includes a detection and connection with the conditioning device The conditioning detection device for the sludge parameter after conditioning by the conditioning device, the computer control unit receives the conditioned sludge parameter data and controls the conditioning of the conditioning device according to the conditioned sludge parameter data.

所述調理裝置包括管道混合器和攪拌混合器,所述管道混合器包括一外殼,外殼內部設有若干依次連接的攪拌翼片,外殼的污泥進口處設有一藥劑加入管。 The conditioning device comprises a pipe mixer and a stirring mixer, the pipe mixer comprises a casing, the casing is internally provided with a plurality of agitating fins connected in series, and a sludge inlet is provided at the sludge inlet of the casing.

所述攪拌翼片由矩形的翼片主體螺旋180度或270度形成,且相鄰攪拌翼片的螺旋方向相反。 The agitating fins are formed by a rectangular fin body 180 degrees or 270 degrees, and the spiral directions of adjacent agitating fins are opposite.

所述污泥參數診測傳感單元包括污泥含水率分析儀、污泥pH檢測儀、泥污溫度感測器、污泥zeta電位電泳儀、電動污泥隔膜泵、超聲波液位元計或PLC模組。 The sludge parameter diagnosis and sensing unit comprises a sludge moisture content analyzer, a sludge pH detector, a mud temperature sensor, a sludge zeta potential electrophoresis instrument, an electric sludge diaphragm pump, an ultrasonic liquid level meter or PLC module.

所述加藥裝置包括一用於控制藥劑配製的自動配藥系統、用於投放藥劑的加藥系統及用於暫時儲存各已配製好藥劑的儲存投加系統組成。 The dosing device comprises an automatic dispensing system for controlling the formulation of the medicament, a dosing system for administering the medicament, and a storage dosing system for temporarily storing the prepared medicaments.

所述藥劑包括pH值調整劑、絮凝劑、表面活性劑、混凝劑、複合骨料。 The medicament includes a pH adjuster, a flocculant, a surfactant, a coagulant, and a composite aggregate.

所述pH值調整劑可為CaO、Ca(OH)2、MgO,Mg(OH)2、Na2C03、NaHC03、CaC03、矽酸鈉、氯化鉀、醋酸、硝酸或硫酸,且其添加量為絕乾量0.1%~1000%,且添加條件為-10~60℃,壓力為1~10公斤。所述絮凝劑可為二甲基二烯丙基氯化銨、吡啶季銨鹽型聚丙烯醯胺、聚丙烯醯胺、幾丁聚糖、脫乙醯幾丁聚糖、木質素、木素季銨鹽、二氧化矽、活化矽酸、骨膠或海藻酸鈉,且其添加量為絕乾量0.001%~100%,且添加 條件為溫度-10~60℃,壓力:1~10公斤。所述表面活性劑可為十六烷基三甲基溴化銨、三聚磷酸鈉、乙二胺四乙酸二鈉、十二烷基磺酸鈉、羥甲基纖維素鈉、甲基丙烯醯氧乙基二甲基十二烷基溴化銨、乙氧基改性聚三矽氧烷或溴化-1,2-雙(十二烷基二甲基)乙二銨,且其添加量為0.001%~50%,且添加條件為溫度-10~60℃,壓力:1~10公斤。所述氧化還原劑可為氯氣、NaClO、漂白粉、高錳酸鉀、氯化鉀、氧化鎂、一氯甲烷、臭氧、過氧化氫或三氧化氯,且其添加量為絕乾量0.1%~100%;且添加條件為溫度-10~200℃,壓力:1~100公斤。所述混凝劑可為三氯化鐵、氯化亞鐵、硝酸鐵、碳酸鐵、氧化鎂、氯化鎂、硫酸亞鐵、硫酸鎂、聚合硫酸鋁、聚合硫酸鐵、聚合氯化鋁、聚合硫酸鋁鐵或硫酸鐵,且其添加量為絕乾量0.1%~1000%,且添加條件為溫度-10~300℃;壓力:1~150公斤。所述複合骨料可為粉煤灰、爐灰或有熱值煤矸石粉中的一種,且其添加量為0.1%~1000%,添加條件為10~300℃,壓力:1~150公斤。 Said pH adjusting agent may be CaO, Ca (OH) 2, MgO, Mg (OH) 2, Na 2 C0 3, NaHC0 3, CaC0 3, silica, sodium, chloride, acetic acid, nitric acid or sulfuric acid, and The addition amount is 0.1% to 1000% of absolute dryness, and the addition condition is -10 to 60 ° C, and the pressure is 1 to 10 kg. The flocculating agent may be dimethyl diallyl ammonium chloride, pyridine quaternary ammonium polyacrylamide, polypropylene decylamine, chitosan, acetaminophen, lignin, lignin Quaternary ammonium salt, cerium oxide, activated citric acid, bone glue or sodium alginate, and the amount thereof is 0.001% to 100% of absolute dryness, and the addition condition is temperature -10 to 60 ° C, pressure: 1 to 10 kg. The surfactant may be cetyltrimethylammonium bromide, sodium tripolyphosphate, disodium edetate, sodium dodecyl sulfate, sodium carboxymethylcellulose, methacryl Oxyethyl dimethyl lauryl ammonium bromide, ethoxy modified polytrioxane or brominated-1,2-bis(dodecyldimethyl)ethylene diammonium, and its addition amount It is 0.001%~50%, and the addition condition is temperature -10~60 °C, pressure: 1~10 kg. The redox agent may be chlorine gas, NaClO, bleaching powder, potassium permanganate, potassium chloride, magnesium oxide, methyl chloride, ozone, hydrogen peroxide or chlorine trioxide, and the amount thereof is 0.1% of dry weight. 100%; and the addition conditions are temperature -10 ~ 200 ° C, pressure: 1 ~ 100 kg. The coagulant may be ferric chloride, ferrous chloride, iron nitrate, iron carbonate, magnesium oxide, magnesium chloride, ferrous sulfate, magnesium sulfate, polyaluminum sulfate, polyferric sulfate, polyaluminum chloride, polysulfate. Aluminium iron or ferric sulphate, and its addition amount is 0.1%~1000% of absolute dryness, and the addition condition is temperature -10~300 °C; pressure: 1~150 kg. The composite aggregate may be one of fly ash, furnace ash or calcined coal gangue powder, and the addition amount is 0.1% to 1000%, the addition condition is 10 to 300 ° C, and the pressure is 1 to 150 kg.

本發明的優點是:本發明通過智慧化診斷系統對污泥處理裝置的反應過程中的各個部分進行診測,並將該診測結果傳輸至一控制單元,該控制單元對診測結果進行分析並根據控制結果控制加藥系統加藥,且通過本發明處理過的污泥含水量由原污含水率80~98%之間降低至污泥含水率為35-60%之間,終泥產出品質同時降低至少50%,同時降低污泥含水率後仍可保有污泥原有機熱值70%以上,約600~3000大卡/千克,供進一步焚燒乾化處理。 The invention has the advantages that the invention diagnoses various parts in the reaction process of the sludge treatment device through the intelligent diagnosis system, and transmits the diagnosis result to a control unit, and the control unit analyzes the diagnosis result And according to the control result, the dosing system is controlled to add medicine, and the moisture content of the sludge treated by the invention is reduced from 80 to 98% of the original sewage moisture content to 35-60% of the sludge moisture content, and the final sludge is produced. At the same time, the quality is reduced by at least 50%, and at the same time, the original organic heat value of the sludge can be maintained at 70% or more, about 600~3000 kcal/kg, for further incineration and drying.

1‧‧‧智慧診斷模組 1‧‧‧Smart Diagnostic Module

11‧‧‧污泥參數診測傳感單元 11‧‧‧Sludge parameter diagnosis and sensing unit

111‧‧‧污泥檢測裝置 111‧‧‧Sludge detector

112‧‧‧調理檢測裝置 112‧‧‧Measurement detection device

113‧‧‧脫水檢測裝置 113‧‧‧Dehydration detection device

12‧‧‧電腦控制單元 12‧‧‧Computer Control Unit

2‧‧‧加藥裝置 2‧‧‧Dosing device

20‧‧‧藥劑檢測裝置 20‧‧‧Drug detection device

21‧‧‧第一藥劑加入裝置 21‧‧‧First drug addition device

22‧‧‧第二藥劑加入裝置 22‧‧‧Second agent addition device

3‧‧‧調理裝置 3‧‧‧ conditioning device

31‧‧‧第一藥劑混合器 31‧‧‧First drug mixer

32‧‧‧第二藥劑混合器 32‧‧‧Second drug mixer

33‧‧‧第五藥劑混合器 33‧‧‧ fifth medicament mixer

34‧‧‧反應槽 34‧‧‧Reaction tank

4‧‧‧污泥儲存罐 4‧‧‧Sludge storage tank

41‧‧‧二沉池 41‧‧‧Secondary pool

42‧‧‧帶式濃縮機 42‧‧‧belt concentrator

43‧‧‧第一調理槽 43‧‧‧First conditioning slot

44‧‧‧第二調理池 44‧‧‧Second conditioning pool

45‧‧‧板框壓濾機 45‧‧‧Shelf frame filter press

46‧‧‧乾泥棚 46‧‧‧ dry mud shed

5‧‧‧脫水裝置 5‧‧‧Dehydration device

第1圖是本發明的結構示意圖。 Fig. 1 is a schematic view showing the structure of the present invention.

第2圖是本發明的第一實施例的結構示意圖。 Fig. 2 is a schematic structural view of a first embodiment of the present invention.

如第1圖所示,一種污泥深度脫水智慧調理系統,包括智慧診斷模組1、加藥裝置2及調理裝置3,通過智慧診斷模組1可以對要處理的污泥先進行檢測,以確定要加藥的時間和加藥的量,且加藥裝置2的加藥過程中智慧診斷模組1會對該過程中進行時時的檢測回饋,以便及時調整加藥的種類、用量和時間,通過本發明的三個模組,可以將現有技術中的污泥脫水工藝的效率大幅提升,使傳統處理過的污泥含水量由70-99%降低至60%以下,終泥產出重量降低50%以上,同時仍可保有原有機熱值70%以上,即約600-3000千卡/千克,供進一步焚燒乾化處理。 As shown in Fig. 1, a sludge deep dehydration intelligent conditioning system includes a smart diagnostic module 1, a dosing device 2, and a conditioning device 3. The smart diagnostic module 1 can first detect the sludge to be treated, Determining the time of dosing and the amount of dosing, and the smart diagnostic module 1 during the dosing process of the dosing device 2 will perform feedback detection in the process for timely adjustment of the type, amount and time of dosing in time. Through the three modules of the invention, the efficiency of the sludge dewatering process in the prior art can be greatly improved, and the water content of the conventionally treated sludge is reduced from 70-99% to less than 60%, and the final sludge yield weight. Reduced by more than 50%, while still retaining the original organic heat value of more than 70%, that is, about 600-3000 kcal / kg, for further incineration and drying.

本發明的智慧診斷模組1包括:污泥參數診測傳感單元11,其對污泥的各項參數進行診測;電腦控制單元12,其接收所述污泥參數診測傳感單元11診測的參數資料,並對該參數資料進行處理後輸出一加藥控制信號;加藥裝置2,其接收所述加藥控制信號並根據所述加藥控制信號進行加藥。 The smart diagnostic module 1 of the present invention comprises: a sludge parameter diagnostic sensing unit 11 that diagnoses various parameters of the sludge; and a computer control unit 12 that receives the sludge parameter diagnostic sensing unit 11 The parameter data of the diagnosis is processed, and a dosing control signal is output after the parameter data is processed; the dosing device 2 receives the dosing control signal and performs dosing according to the dosing control signal.

未處理的污泥儲存於儲存容器內,所述污泥參數診測傳感單元11還包括一與所述污泥儲存容器相連且檢測污泥儲存容器內的污泥參數並將所述檢測到的污泥參數資料傳輸至所述電腦控制單元12的污泥檢測裝置111。 The untreated sludge is stored in a storage container, and the sludge parameter diagnostic sensing unit 11 further includes a sludge storage container connected to the sludge storage container and detecting the sludge parameter in the sludge storage container. The sludge parameter data is transmitted to the sludge detecting device 111 of the computer control unit 12.

所述污泥參數診測傳感單元11包括通過一PLC模組控制污 泥含水率分析儀、污泥pH檢測儀、泥污溫度感測器、污泥zeta電位電泳儀、污泥輸送泵;污泥含水率分析儀用於量測污泥含水率,其量程為80~99%,誤差±0.02;污泥pH檢測儀用於量取污泥的酸鹼度,量程為-2~14,設備精度±0.01;泥污溫度感測器用於量測污泥的溫度,其量程為-10~60,設備精度±0.01、污泥zeta電位電泳儀的誤差為±200mv。所述污泥參數偵測傳感單元11可診測污泥的顆粒料細微性、污泥的重金屬含量、污泥的相對密度、污泥的含水率、污泥的pH值、污泥的有機物含量、污泥的沉降比、污泥的熱值、污泥的體積指數,且經過處理後的污泥的重金屬含量,主要為Cr、Pb、Zn,且其含量<1000mg/kg;污泥的相對密度為1.2~2.8kg/L;污泥的含水率低於60%以下;污泥的pH值為6~9之間;污泥的有機物含量為5~60%;污泥的熱值為600~3000大卡/千克;污泥的體積指數為30~150ml/L。 The sludge parameter diagnostic sensing unit 11 includes a sewage control through a PLC module Mud moisture content analyzer, sludge pH detector, mud temperature sensor, sludge zeta potential electrophoresis instrument, sludge transfer pump; sludge moisture content analyzer is used to measure sludge moisture content, its range is 80 ~99%, error ±0.02; sludge pH detector is used to measure the pH of sludge, the range is -2~14, equipment accuracy is ±0.01; mud temperature sensor is used to measure the temperature of sludge, its range The ratio is -10~60, the accuracy of the equipment is ±0.01, and the error of the sludge zeta potential electrophoresis instrument is ±200mv. The sludge parameter detecting and sensing unit 11 can diagnose the fineness of the granular material of the sludge, the heavy metal content of the sludge, the relative density of the sludge, the moisture content of the sludge, the pH of the sludge, and the organic matter of the sludge. Content, sedimentation ratio of sludge, calorific value of sludge, volume index of sludge, and heavy metal content of treated sludge, mainly Cr, Pb, Zn, and its content <1000mg/kg; sludge The relative density is 1.2~2.8kg/L; the moisture content of the sludge is less than 60%; the pH value of the sludge is between 6 and 9; the organic matter content of the sludge is 5~60%; the calorific value of the sludge is 600~3000 kcal/kg; the volume index of sludge is 30~150ml/L.

本發明中的智慧診斷模組1包括一污泥診斷櫃,該污泥診斷櫃設有一PLC控制器,且污泥診斷櫃內部設有各種傳感元件,污泥輸送泵在PLC控制器的控制下抽取適量污泥,然後經過管道上的背壓閥將污泥在管道中的流量和壓量調成所需要的穩定值,然後污泥通過污泥診斷櫃中的各感測器單元對污泥性質分析,並把所分析的結果發送到電腦控制單元12,電腦控制單元12會自動根據系統給定的資料,計算出調理池污泥的性質結構,並把所需要的污泥加藥量及加水量自動計算出來,通過網路發送出給中央控制中心。本發明的智慧診斷模組1可以對污泥脫水前和調理後污泥的各種性能進行檢測控制,污泥檢測裝置111檢測的脫水前污泥資料包括污泥的顆粒料細微性、污泥的重金屬含量、污泥的相對密度、污泥的含水率、 污泥的pH值、污泥的有機物含量、污泥的沉降比、污泥的熱值、污泥的體積指數;調理檢測裝置112檢測的調理污泥資料包括調理污泥的PH值、調理污泥的相對密度、調理污泥的溫度、調理污泥的含水含固率、調理污泥的濁度、調理污泥的懸浮物。 The smart diagnostic module 1 of the present invention comprises a sludge diagnostic cabinet, the sludge diagnostic cabinet is provided with a PLC controller, and the sludge diagnostic cabinet is provided with various sensing elements, and the sludge delivery pump is controlled by the PLC controller. The appropriate amount of sludge is extracted, and then the flow and pressure in the pipeline are adjusted to the required stable value through a back pressure valve on the pipeline, and then the sludge is stained by each sensor unit in the sludge diagnostic cabinet. Analysis of the nature of the mud, and sending the results of the analysis to the computer control unit 12, the computer control unit 12 will automatically calculate the nature of the sludge in the conditioning tank according to the data given by the system, and add the required amount of sludge. The amount of water added is automatically calculated and sent out to the central control center via the network. The smart diagnosis module 1 of the invention can detect and control various properties of sludge before and after sludge dewatering, and the sludge data before dewatering detected by the sludge detecting device 111 includes fineness of sludge particles and sludge. Heavy metal content, relative density of sludge, moisture content of sludge, The pH value of the sludge, the organic matter content of the sludge, the sedimentation ratio of the sludge, the calorific value of the sludge, and the volume index of the sludge; the conditioning sludge data detected by the conditioning detecting device 112 includes the pH value of the conditioning sludge, and the conditioning The relative density of the mud, the temperature of the conditioning sludge, the aqueous solid content of the conditioning sludge, the turbidity of the conditioning sludge, and the suspension of the conditioning sludge.

本發明的調理裝置3是用於調理污泥的調理裝置3,所述污泥參數診測傳感單元11包括一與所述調理裝置3相連且檢測調理裝置3調理後的污泥參數的調理檢測裝置112,所述電腦控制單元12接收所述調理後的污泥參數資料並根據調理後的污泥參數資料控制調理裝置3的調理。本發明的調理裝置3包括管道混合器和攪拌反應器,通過管道混合器及攪拌反應器對污泥與藥劑進行充分的混合攪拌,以使其充分的混合反應。管道混合器包括一外殼,且所述外殼內部若干依次連接的攪拌翼片,且所述道混合器的污泥進口處設有一藥劑加入管,所述藥劑加入管的開口處設有一噴嘴,所述攪拌翼片為矩形的翼片主體螺旋一定的角度形成,且相鄰所述翼片的螺旋方向相反,因此不容易堵塞,適用於較髒的物料。本發明中的噴嘴為可清洗噴嘴,方便阻塞時拆卸下來進行清洗。本發明中的所述攪拌反應器內部設有一攪拌器,對加入到攪拌反應器內部的污泥進行攪拌混合,以便藥劑與污泥混合的更均勻,本發明中還包括一儲泥槽,對污泥進行暫時的儲備,方便後期的處理。 The conditioning device 3 of the present invention is a conditioning device 3 for conditioning sludge, and the sludge parameter diagnostic sensing unit 11 includes a conditioning associated with the conditioning device 3 and detecting the sludge parameters after conditioning by the conditioning device 3. The detecting device 112, the computer control unit 12 receives the conditioned sludge parameter data and controls the conditioning of the conditioning device 3 according to the conditioned sludge parameter data. The conditioning device 3 of the present invention comprises a pipe mixer and a stirred reactor, and the sludge and the agent are thoroughly mixed and stirred by a pipe mixer and a stirred reactor to sufficiently mix the reaction. The pipe mixer comprises a casing, and a plurality of agitating fins are sequentially connected inside the casing, and a sludge adding pipe is arranged at the sludge inlet of the pipe mixer, and a nozzle is arranged at the opening of the medicament adding pipe. The agitating fins are formed by a rectangular angle of the main body of the fins, and the spiral directions of the adjacent fins are opposite, so that they are not easily clogged and are suitable for dirty materials. The nozzle in the present invention is a washable nozzle, which is easily removed for cleaning when it is blocked. In the stirring reactor of the present invention, an agitator is arranged inside, and the sludge added to the inside of the stirred reactor is stirred and mixed, so that the medicine and the sludge are more uniformly mixed, and the present invention further comprises a sludge tank, The sludge is temporarily stored for later processing.

本發明的加藥裝置2包括一用於控制藥劑配製的自動配藥系統、用於投放藥劑的加藥系統及用於暫時儲存各已配製好藥劑的儲存投加系統組成。本發明加入的藥劑包括pH值調整劑、絮凝劑、表面活性劑、混凝劑、複合骨料。所述pH值調整劑可為CaO、Ca(OH)2、MgO,Mg(OH)2、 Na2C03、NaHC03、CaC03、矽酸鈉、氯化鉀、醋酸、硝酸或硫酸,且其添加量為絕乾量0.1%~1000%,且添加條件為-10~60℃,壓力為1~10公斤。所述絮凝劑可為二甲基二烯丙基氯化銨、吡啶季銨鹽型聚丙烯醯胺、聚丙烯醯胺、幾丁聚糖、脫乙醯幾丁聚糖、木質素、木素季銨鹽、二氧化矽、活化矽酸、骨膠或海藻酸鈉,且其添加量為絕乾量0.001%~100%,且添加條件為溫度-10~60℃,壓力:1~10公斤。所述表面活性劑可為十六烷基三甲基溴化銨、三聚磷酸鈉、乙二胺四乙酸二鈉、十二烷基磺酸鈉、羥甲基纖維素鈉、甲基丙烯醯氧乙基二甲基十二烷基溴化銨、乙氧基改性聚三矽氧烷或溴化-1,2-雙(十二烷基二甲基)乙二銨,且其添加量為0.001%~50%,且添加條件為溫度-10~60℃,壓力:1~10公斤。所述氧化還原劑可為氯氣、NaClO、漂白粉、高錳酸鉀、氯化鉀、氧化鎂、一氯甲烷、臭氧、過氧化氫或三氧化氯,且其添加量為絕乾量0.1%~100%;且添加條件為溫度-10~200℃,壓力:1~100公斤。所述混凝劑可為三氯化鐵、氯化亞鐵、硝酸鐵、碳酸鐵、氧化鎂、氯化鎂、硫酸亞鐵、硫酸鎂、聚合硫酸鋁、聚合硫酸鐵、聚合氯化鋁、聚合硫酸鋁鐵或硫酸鐵,且其添加量為絕乾量0.1%~1000%,且添加條件為溫度-10~300℃;壓力:1~150公斤。所述複合骨料可為粉煤灰、爐灰或有熱值煤矸石粉中的一種,且其添加量為0.1%~1000%,添加條件為10~300℃,壓力:1~150公斤。 The dosing device 2 of the present invention comprises an automatic dispensing system for controlling the formulation of a medicament, a dosing system for administering a medicament, and a storage dosing system for temporarily storing each formulated medicament. The agent added in the present invention includes a pH adjuster, a flocculant, a surfactant, a coagulant, and a composite aggregate. Said pH adjusting agent may be CaO, Ca (OH) 2, MgO, Mg (OH) 2, Na 2 C0 3, NaHC0 3, CaC0 3, silica, sodium, chloride, acetic acid, nitric acid or sulfuric acid, and The addition amount is 0.1% to 1000% of absolute dryness, and the addition condition is -10 to 60 ° C, and the pressure is 1 to 10 kg. The flocculating agent may be dimethyl diallyl ammonium chloride, pyridine quaternary ammonium polyacrylamide, polypropylene decylamine, chitosan, acetaminophen, lignin, lignin Quaternary ammonium salt, cerium oxide, activated citric acid, bone glue or sodium alginate, and the amount thereof is 0.001% to 100% of absolute dryness, and the addition condition is temperature -10 to 60 ° C, pressure: 1 to 10 kg. The surfactant may be cetyltrimethylammonium bromide, sodium tripolyphosphate, disodium edetate, sodium dodecyl sulfate, sodium carboxymethylcellulose, methacryl Oxyethyl dimethyl lauryl ammonium bromide, ethoxy modified polytrioxane or brominated-1,2-bis(dodecyldimethyl)ethylene diammonium, and its addition amount It is 0.001%~50%, and the addition condition is temperature -10~60 °C, pressure: 1~10 kg. The redox agent may be chlorine gas, NaClO, bleaching powder, potassium permanganate, potassium chloride, magnesium oxide, methyl chloride, ozone, hydrogen peroxide or chlorine trioxide, and the amount thereof is 0.1% of dry weight. 100%; and the addition conditions are temperature -10 ~ 200 ° C, pressure: 1 ~ 100 kg. The coagulant may be ferric chloride, ferrous chloride, iron nitrate, iron carbonate, magnesium oxide, magnesium chloride, ferrous sulfate, magnesium sulfate, polyaluminum sulfate, polyferric sulfate, polyaluminum chloride, polysulfate. Aluminium iron or ferric sulphate, and its addition amount is 0.1%~1000% of absolute dryness, and the addition condition is temperature -10~300 °C; pressure: 1~150 kg. The composite aggregate may be one of fly ash, furnace ash or calcined coal gangue powder, and the addition amount is 0.1% to 1000%, the addition condition is 10 to 300 ° C, and the pressure is 1 to 150 kg.

本發明的加藥裝置2中還包括一用於檢測加藥裝置2藥劑參數的藥劑檢測裝置20,所述藥劑檢測裝置20與所述加藥裝置2連接,且所述藥劑檢測裝置20將檢測到的藥劑參數資料傳輸到所述電腦控制單元12;所述電腦控制單元12接收所述藥劑參數資料並根據藥劑參數資料控制加藥裝 置2。通過該藥劑檢測裝置20對藥劑的各項性質進行檢測,藥劑檢測裝置20檢測的藥劑指標包括藥劑的酸鹼濃度、藥劑的相對密度、藥劑的折光指數、藥劑的灰份及鉛含量、藥劑的溶解度、藥劑的分子量、藥劑的金屬離子濃度或藥劑的色度,通過該藥劑檢測裝置20對藥劑的各項性質進行檢測控制,通過該自動配藥系統可以自動完成配藥過程,然後再通過藥劑檢測裝置20對自動配藥系統的配成的藥劑進行檢測,然後通過加藥系統完成加藥。 The dosing device 2 of the present invention further includes a drug detecting device 20 for detecting the drug parameter of the dosing device 2, the drug detecting device 20 is connected to the dosing device 2, and the drug detecting device 20 will detect The obtained drug parameter data is transmitted to the computer control unit 12; the computer control unit 12 receives the drug parameter data and controls the drug loading according to the drug parameter data Set 2. The drug detecting device 20 detects various properties of the drug, and the drug index detected by the drug detecting device 20 includes the acid-base concentration of the drug, the relative density of the drug, the refractive index of the drug, the ash and lead content of the drug, and the drug. The solubility, the molecular weight of the drug, the metal ion concentration of the drug, or the chromaticity of the drug, the drug detecting device 20 detects and controls various properties of the drug, and the automatic dispensing system can automatically complete the dispensing process, and then pass the drug detecting device. 20 The medicaments of the automatic dispensing system are tested, and then the dosing is completed by the dosing system.

本發明包括一用於儲存未處理污泥的污泥儲存罐4,污泥儲存罐4連接一檢測所述污泥儲存罐4內部污泥參數的污泥檢測裝置111,污泥儲存罐4中儲存有脫水前的污泥,所述污泥參數診測傳感單元11還包括一與所述污泥儲存罐4相連且檢測污泥儲存罐4內的污泥參數並將所述檢測到的污泥參數資料傳輸至所述電腦控制單元12的污泥檢測裝置111,儲存於污泥儲存罐4內的污泥通過污泥輸送泵抽取並送入到智慧診斷模組1對其進行檢測。 The present invention comprises a sludge storage tank 4 for storing untreated sludge, and the sludge storage tank 4 is connected to a sludge detecting device 111 for detecting sludge parameters inside the sludge storage tank 4, and the sludge storage tank 4 The sludge before dewatering is stored, and the sludge parameter detecting and sensing unit 11 further includes a sludge storage tank 4 connected to the sludge storage tank 4 and detecting the detected sludge parameters in the sludge storage tank 4 The sludge parameter data is transmitted to the sludge detecting device 111 of the computer control unit 12, and the sludge stored in the sludge storage tank 4 is extracted by a sludge transfer pump and sent to the smart diagnostic module 1 for detection.

本發明還包括一用於檢測經所述調理裝置3處理後的污泥進行脫水的脫水裝置5,所述脫水裝置5還連接一用於檢測經所述脫水裝置5脫水後污泥參數的脫水檢測裝置113,所述脫水檢測裝置113將檢測到的污泥參數傳輸至所述電腦控制單元12。通過本發明的加藥裝置2,加入的pH值調節劑及活性分散劑與污泥原液中的陰陽離子充分混合發生反應,形成類似納米分散條件,由於靜電位吸引而形成類似自組裝的行為,處理後顆粒更細,形成絮狀物,更容易脫水,在進一步的污泥乾化後得到的固體結構是含孔隙度好的層狀結構。 The present invention also includes a dewatering device 5 for detecting dewatering of sludge treated by the conditioning device 3, the dewatering device 5 being further connected to a dehydration for detecting sludge parameters after dehydration by the dewatering device 5. The detecting device 113 transmits the detected sludge parameters to the computer control unit 12. Through the medicizing device 2 of the present invention, the added pH adjusting agent and the active dispersing agent are mixed with the anion and cation in the sludge stock solution to form a reaction similar to the nano-dispersion condition, and the self-assembly behavior is formed due to the electrostatic attraction. After the treatment, the particles are finer, forming flocs, and are more easily dehydrated. The solid structure obtained after further sludge drying is a layered structure with good porosity.

本發明的工作原理是:電腦控制單元12對脫水前污泥資料 進行分析,將分析結果傳送至加藥裝置2;加藥裝置2根據脫水前污泥檢測資料與脫水後污泥檢測資料的對比結果,綜合藥劑檢測裝置20檢測的藥劑指標優化調整藥劑的供給量、補給時間和供給順序;電腦控制單元12根據脫水前污泥的檢測資料控制調理裝置3對污泥進行調理,調理檢測裝置112檢測調理污泥資料發送給電腦控制單元12處理,從而控制調理裝置3對污泥的調理速度和污泥反應時間優化調整。本發明還包括一用於檢測經所述調理裝置3處理後的污泥進行脫水的脫水裝置5,所述污泥參數診測傳感單元11還包括一與所述脫水裝置5相連且檢測經脫水裝置5脫水後的污泥參數的污泥檢測裝置111;所述電腦控制單元12接收所述脫水後的污泥參數資料並根據脫水後的污泥參數資料控制脫水裝置5,經過調理裝置3調理後的污泥送入到脫水裝置5,污泥檢測裝置111檢測深度脫水後的污泥資料傳送給電腦控制單元12與脫水前污泥檢測資料對比為下一步的處理。 The working principle of the invention is: the computer control unit 12 analyzes the sludge data before dewatering The analysis is performed, and the analysis result is transmitted to the medicinal device 2; the medicinal device 2 optimizes the supply amount of the drug by the drug index detected by the integrated drug detecting device 20 according to the comparison result between the sludge detecting data before dehydration and the sludge detecting data after dehydration. The replenishment time and the supply sequence; the computer control unit 12 controls the conditioning device 3 to adjust the sludge according to the detection data of the sludge before dewatering, and the conditioning detection device 112 detects the conditioning sludge data and sends it to the computer control unit 12 for processing, thereby controlling the conditioning device. 3 Optimize the adjustment of sludge conditioning speed and sludge reaction time. The present invention further includes a dehydration device 5 for detecting dehydration of the sludge treated by the conditioning device 3, the sludge parameter diagnostic sensing unit 11 further comprising a dehydration device 5 connected to the dehydration device 5 a sludge detecting device 111 for sludge parameters after dehydration of the dewatering device 5; the computer control unit 12 receives the dewatered sludge parameter data and controls the dehydrating device 5 according to the dehydrated sludge parameter data, and passes through the conditioning device 3 The conditioned sludge is sent to the dewatering device 5, and the sludge detecting device 111 detects that the sludge data after the deep dehydration is transmitted to the computer control unit 12 and compares the data of the sludge before dewatering to the next step.

如第2圖所示,其為本發明的一實施例的示意圖,污泥先送入到二沉池41,在該二沉池內污泥先進行沉澱,除去一部分的水份,經過該二沉池處理後的污泥流經一帶式濃縮機42,經過該帶式濃縮機42後污泥進行進一步的濃縮,然後污泥再送入到調理裝置3,調理裝置3內部設有一第一藥劑混合器31,經過第一藥劑混合器31處理後送入到一反應槽34,在第一反應槽處理後送入到一第二藥劑混合器32,第二藥劑混合器32的出口連接一第一調理槽43的入口,且第一調理槽43的出口連接一第五藥劑混合器33,第五藥劑混合器33的出口連接一第二調理池44,第二調理池44的出口連接一板框壓濾機45,且板框壓濾機45的出口連接一乾泥棚46;還包括多個藥劑加入罐,且藥劑加入罐的出口連接一第五藥劑混合器33。智慧診 斷模組1的污泥參數診測傳感單元11對污泥的各項參數進行診測,並將診測得到的參數傳輸至一電腦控制單元12,該電腦控制單元12對該參數進行分析,且該電腦控制單元12根據該參數控制加藥裝置2的第一藥劑加入裝置21和第二藥劑加入裝置22,調整加藥裝置2的加藥時間、加藥種類和加藥順序,然後加藥裝置2將藥加入到第一藥劑混合器31,在第一藥劑混合器31加藥混合,智慧診斷模組1的污泥參數診斷傳感單元11再對從第一藥劑混合器31出來的污泥進行檢測,並將診測得到的參數傳輸至電腦控制單元12,該電腦控制單元12對該參數進行分析,且該電腦控制單元12根據該參數控制加藥裝置2,調整加藥裝置2的加藥時間、加藥種類和加藥順序,如此迴圈;然後相同的處理方法再對進入到第二藥劑混合器32內污泥進行處理。 As shown in Fig. 2, which is a schematic view of an embodiment of the present invention, the sludge is first sent to the secondary settling tank 41, and the sludge is first precipitated in the secondary settling tank to remove a part of the water. The sludge treated by the sinking tank flows through the belt concentrator 42, and the sludge is further concentrated after passing through the belt concentrator 42, and then the sludge is sent to the conditioning device 3, and the first chemical mixing device is provided inside the conditioning device 3. The device 31 is processed by the first drug mixer 31 and sent to a reaction tank 34. After being processed in the first reaction tank, it is sent to a second drug mixer 32, and the outlet of the second drug mixer 32 is connected to a first The inlet of the conditioning tank 43 is connected, and the outlet of the first conditioning tank 43 is connected to a fifth medicament mixer 33, the outlet of the fifth medicament mixer 33 is connected to a second conditioning tank 44, and the outlet of the second conditioning tank 44 is connected to a plate frame. The filter press 45, and the outlet of the plate and frame filter press 45 is connected to a dry mud shed 46; a plurality of medicaments are added to the tank, and the outlet of the medicament addition tank is connected to a fifth medicament mixer 33. Wisdom diagnosis The sludge parameter diagnosis and sensing unit 11 of the broken module 1 diagnoses the parameters of the sludge, and transmits the diagnosed parameters to a computer control unit 12, and the computer control unit 12 analyzes the parameters. And the computer control unit 12 controls the first medicine adding device 21 and the second medicine adding device 22 of the dosing device 2 according to the parameter, adjusting the dosing time, dosing type and dosing order of the dosing device 2, and then adding The medicine device 2 adds the medicine to the first medicine mixer 31, and the medicine is mixed and mixed in the first medicine mixer 31, and the sludge parameter diagnosis sensing unit 11 of the smart diagnosis module 1 again comes out from the first medicine mixer 31. The sludge is detected, and the diagnosed parameters are transmitted to the computer control unit 12, the computer control unit 12 analyzes the parameter, and the computer control unit 12 controls the dosing device 2 according to the parameter, and adjusts the dosing device 2 The dosing time, the dosing type, and the dosing sequence are thus looped; then the same treatment is used to treat the sludge entering the second medicament mixer 32.

以上所述僅為本發明的較佳實施例而已,並不用以限制本發明,凡在本發明的精神和原則之內所作的任何修改、等效替換和改進等,均應包含在本發明的保護範圍之內。 The above is only the preferred embodiment of the present invention, and is not intended to limit the present invention. Any modifications, equivalent substitutions and improvements made within the spirit and principles of the present invention should be included in the present invention. Within the scope of protection.

11‧‧‧污泥參數診測傳感單元 11‧‧‧Sludge parameter diagnosis and sensing unit

111‧‧‧污泥檢測裝置 111‧‧‧Sludge detector

112‧‧‧調理檢測裝置 112‧‧‧Measurement detection device

113‧‧‧脫水檢測裝置 113‧‧‧Dehydration detection device

12‧‧‧電腦控制單元 12‧‧‧Computer Control Unit

2‧‧‧加藥裝置 2‧‧‧Dosing device

20‧‧‧藥劑檢測裝置 20‧‧‧Drug detection device

3‧‧‧調理裝置 3‧‧‧ conditioning device

4‧‧‧污泥儲存罐 4‧‧‧Sludge storage tank

5‧‧‧脫水裝置 5‧‧‧Dehydration device

Claims (7)

一種污泥深度脫水智慧調理系統,包括一加藥模組,該加藥模組包括一自動配藥系統、加藥系統及各藥劑儲存投加系統組成。 A sludge deep dehydration intelligent conditioning system comprises a dosing module, which comprises an automatic dispensing system, a dosing system and a drug storage and dosing system. 根據申請專利範圍第1項之污泥深度脫水智慧調理系統,其中,該污泥調理助劑包括pH值調整劑、絮凝劑、表面活性劑、混凝劑、複合骨料。 The sludge deep dewatering intelligent conditioning system according to the first aspect of the patent application, wherein the sludge conditioning auxiliary comprises a pH adjusting agent, a flocculating agent, a surfactant, a coagulant, and a composite aggregate. 根據申請專利範圍第2項之污泥深度脫水智慧調理系統,其中,該pH值調整劑為CaO、Ca(OH)2、MgO,Mg(OH)2、Na2C03、NaHC03、CaC03、矽酸鈉、氯化鉀、醋酸、硝酸或硫酸,且其添加量為絕乾量0.1%~1000%,且添加條件為-10~60℃,壓力為1~10公斤。 The scope of the patent sludge deep dehydration wisdom conditioning system of Item 2, wherein the pH adjusting agent is the CaO, Ca (OH) 2, MgO, Mg (OH) 2, Na 2 C0 3, NaHC0 3, CaC0 3 , sodium citrate, potassium chloride, acetic acid, nitric acid or sulfuric acid, and the amount of addition is 0.1% to 1000% of absolute dryness, and the addition condition is -10 to 60 ° C, and the pressure is 1 to 10 kg. 根據申請專利範圍第2項之污泥深度脫水智慧調理系統,其中,該絮凝劑為二甲基二烯丙基氯化銨、吡啶季銨鹽型聚丙烯醯胺、聚丙烯醯胺、幾丁聚糖、脫乙醯幾丁聚糖、木質素、木素季銨鹽、二氧化矽、活化矽酸、骨膠或海藻酸鈉,且其添加量為絕乾量0.001%~100%,且添加條件為溫度-10~60℃,壓力:1~10公斤。 The sludge deep dewatering intelligent conditioning system according to the second application of the patent scope, wherein the flocculating agent is dimethyl diallyl ammonium chloride, pyridine quaternary ammonium salt type polyamide, polypropylene decylamine, chitin Glycan, deacetylated chitosan, lignin, lignin quaternary ammonium salt, cerium oxide, activated citric acid, bone glue or sodium alginate, and the amount thereof is 0.001% to 100% absolute dry amount, and added The condition is temperature -10~60 °C, pressure: 1~10 kg. 根據申請專利範圍第2項之污泥深度脫水智慧調理系統,其中,該表面活性劑為十六烷基三甲基溴化銨、三聚磷酸鈉、乙二胺四乙酸二鈉、十二烷基磺酸鈉、羥甲基纖維素鈉、甲基丙烯醯氧乙基二甲基十二烷基溴化銨、乙氧基改性聚三矽氧烷或溴化-1,2-雙(十二烷基二甲基)乙二銨,且其添加量為0.001%~50%,且添加條件為溫度-10~60℃,壓力:1~10公斤。 The sludge deep dehydration intelligent conditioning system according to item 2 of the patent application scope, wherein the surfactant is cetyltrimethylammonium bromide, sodium tripolyphosphate, disodium edetate, dodecane Sodium sulfonate, sodium carboxymethylcellulose, methacryloyloxyethyl dimethyldodecylammonium bromide, ethoxylated polytrioxane or brominated-1,2-dual ( Dodecyldimethyl)ethylene diammonium, and its addition amount is 0.001% to 50%, and the addition conditions are temperature -10 to 60 ° C, pressure: 1 to 10 kg. 根據申請專利範圍第2項之污泥深度脫水智慧調理系統,其中,該氧化還原劑為氯氣、NaClO、漂白粉、高錳酸鉀、氯化鉀、氧化鎂、一氯甲烷、臭氧、過氧化氫或三氧化氯,且其添加量為絕乾量0.1%~100%;且添加條件為溫度-10~200℃;壓力:1~100公斤。 According to the scope of patent application No. 2, the sludge deep dehydration intelligent conditioning system, wherein the redox agent is chlorine gas, NaClO, bleaching powder, potassium permanganate, potassium chloride, magnesium oxide, methyl chloride, ozone, hydrogen peroxide Or chlorine trioxide, and its addition amount is 0.1%~100% of absolute dryness; and the addition condition is temperature -10~200 °C; pressure: 1~100 kg. 根據申請專利範圍第2項之污泥深度脫水智慧調理系統,其中,該混凝劑為三氯化鐵、氯化亞鐵、硝酸鐵、碳酸鐵、氧化鎂、氯化鎂、硫酸亞鐵、硫酸鎂、聚合硫酸鋁、聚合硫酸鐵、聚合氯化鋁、聚合硫酸鋁鐵或硫酸鐵,且其添加量為絕乾量0.1%~1000%,且添加條件為溫度-10~300℃;壓力:1~150公斤。 According to the patent scope of the second item of the sludge deep dehydration intelligent conditioning system, wherein the coagulant is ferric chloride, ferrous chloride, ferric nitrate, iron carbonate, magnesium oxide, magnesium chloride, ferrous sulfate, magnesium sulfate , polyaluminum sulphate, polyferric sulphate, polyaluminum sulphate, polyaluminum sulphate or ferric sulphate, and the amount of addition is 0.1%~1000%, and the addition condition is temperature -10~300 °C; pressure: 1 ~150 kg.
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