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TW201333947A - Magnetoresistive random access memories - Google Patents

Magnetoresistive random access memories Download PDF

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TW201333947A
TW201333947A TW101122595A TW101122595A TW201333947A TW 201333947 A TW201333947 A TW 201333947A TW 101122595 A TW101122595 A TW 101122595A TW 101122595 A TW101122595 A TW 101122595A TW 201333947 A TW201333947 A TW 201333947A
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magnetic layer
magnetic
random access
mram
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TW101122595A
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TWI511131B (en
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Tien-Wei Chiang
Chwen Yu
Ya-Chen Kao
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Taiwan Semiconductor Mfg
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    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/02Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
    • G11C11/16Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect
    • G11C11/161Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect details concerning the memory cell structure, e.g. the layers of the ferromagnetic memory cell
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/02Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
    • G11C11/16Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect
    • G11C11/165Auxiliary circuits
    • G11C11/1653Address circuits or decoders
    • G11C11/1655Bit-line or column circuits
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/02Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
    • G11C11/16Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect
    • G11C11/165Auxiliary circuits
    • G11C11/1659Cell access
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F10/00Thin magnetic films, e.g. of one-domain structure
    • H01F10/32Spin-exchange-coupled multilayers, e.g. nanostructured superlattices
    • H01F10/324Exchange coupling of magnetic film pairs via a very thin non-magnetic spacer, e.g. by exchange with conduction electrons of the spacer
    • H01F10/3268Exchange coupling of magnetic film pairs via a very thin non-magnetic spacer, e.g. by exchange with conduction electrons of the spacer the exchange coupling being asymmetric, e.g. by use of additional pinning, by using antiferromagnetic or ferromagnetic coupling interface, i.e. so-called spin-valve [SV] structure, e.g. NiFe/Cu/NiFe/FeMn
    • H01F10/3272Exchange coupling of magnetic film pairs via a very thin non-magnetic spacer, e.g. by exchange with conduction electrons of the spacer the exchange coupling being asymmetric, e.g. by use of additional pinning, by using antiferromagnetic or ferromagnetic coupling interface, i.e. so-called spin-valve [SV] structure, e.g. NiFe/Cu/NiFe/FeMn by use of anti-parallel coupled [APC] ferromagnetic layers, e.g. artificial ferrimagnets [AFI], artificial [AAF] or synthetic [SAF] anti-ferromagnets
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B61/00Magnetic memory devices, e.g. magnetoresistive RAM [MRAM] devices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N50/00Galvanomagnetic devices
    • H10N50/10Magnetoresistive devices
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/02Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
    • G11C11/16Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/02Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
    • G11C11/16Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect
    • G11C11/165Auxiliary circuits
    • G11C11/1673Reading or sensing circuits or methods
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/02Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
    • G11C11/16Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect
    • G11C11/165Auxiliary circuits
    • G11C11/1675Writing or programming circuits or methods
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F10/00Thin magnetic films, e.g. of one-domain structure
    • H01F10/32Spin-exchange-coupled multilayers, e.g. nanostructured superlattices
    • H01F10/324Exchange coupling of magnetic film pairs via a very thin non-magnetic spacer, e.g. by exchange with conduction electrons of the spacer
    • H01F10/3254Exchange coupling of magnetic film pairs via a very thin non-magnetic spacer, e.g. by exchange with conduction electrons of the spacer the spacer being semiconducting or insulating, e.g. for spin tunnel junction [STJ]

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  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Power Engineering (AREA)
  • Hall/Mr Elements (AREA)
  • Mram Or Spin Memory Techniques (AREA)

Abstract

A magnetoresistive random access memory (MRAM) device and a method of manufacture are provided. The MRAM device comprises a magnetic pinned layer, a compound GMR structure acting as a free layer, and a non-magnetic barrier layer separating the pinned and GMR layers. The barrier layer is provided to reduce the magnetic coupling of the free layer and GMR structure, as well as provide a resistive state (high or low) for retaining binary data (0 or 1) in the device. The GMR structure provides physical electrode connectivity for set/clear memory functionality which is separated from the physical electrode connectivity for the read functionality for the memory device.

Description

磁阻式隨機存取記憶體 Magnetoresistive random access memory

本發明係有關於一種記憶體,特別是有關於一種磁阻式隨機存取記憶體(MRAM)。 The present invention relates to a memory, and more particularly to a magnetoresistive random access memory (MRAM).

磁阻式隨機存取記憶體(Magnetoresistive Random Access Memory,MRAM)為一種可儲存數位資訊(二進位0或1)位元的非揮發性(non-volatile)電腦記憶體類型。磁阻式隨機存取記憶體(MRAM)數位資料並非如傳統隨機存取記憶體(RAM)元件以電荷儲存,而是位元狀態(0或1)藉由磁性儲存元件中的電阻狀態(高電阻或低電阻)儲存,毋須固定電力以維持其狀態。舉例來說,磁性儲存元件可包括一固定磁性層、一自由(可變)磁性層與一非磁性導電阻障層,其中非磁性導電阻障層插入於固定磁性層與自由磁性層之間。固定層與自由層其磁場的相對排列決定了插入於固定磁性層與自由磁性層之間的阻障層的電阻狀態(高電阻或低電阻)。 Magnetoresistive Random Access Memory (MRAM) is a non-volatile computer memory type that can store digital information (binary 0 or 1) bits. Magnetoresistive random access memory (MRAM) digital data is not stored as a charge in a conventional random access memory (RAM) component, but in a bit state (0 or 1) by a resistive state in a magnetic storage element (high Resistor or low resistance) storage, no need to fix power to maintain its state. For example, the magnetic storage element may include a fixed magnetic layer, a free (variable) magnetic layer and a non-magnetic conductive resistance barrier layer, wherein the non-magnetic conductive resistance barrier layer is interposed between the fixed magnetic layer and the free magnetic layer. The relative arrangement of the magnetic fields of the fixed layer and the free layer determines the resistance state (high resistance or low resistance) of the barrier layer interposed between the fixed magnetic layer and the free magnetic layer.

藉由改變自由層的磁性狀態以符合固定磁性層的磁性狀態或使其相反於固定磁性層的磁性狀態可控制磁阻式隨機存取記憶體(MRAM)元件電阻狀態的變化。若使自由層的磁性方向符合固定層的磁性方向可於阻障層中創造一低電阻狀態,其儲存的記憶位元資訊等於例如1的二進位值。若磁性自由層與磁性固定層之間具有相反的磁性方向(自由層的磁性方向與固定層的磁性方向相反),則可於阻障層中創造一高電阻狀態,其儲存的記憶位元資訊等於例 如0的二進位值。一般來說,磁阻式隨機存取記憶體(MRAM)元件係於一半導體元件中的兩電極之間設置固定層、阻障層與自由層而形成。 The change in the resistance state of the magnetoresistive random access memory (MRAM) device can be controlled by changing the magnetic state of the free layer to conform to the magnetic state of the fixed magnetic layer or to the magnetic state opposite to the fixed magnetic layer. If the magnetic direction of the free layer conforms to the magnetic direction of the fixed layer, a low resistance state can be created in the barrier layer, and the stored memory bit information is equal to a binary value of, for example, 1. If the magnetic free layer and the magnetic fixed layer have opposite magnetic directions (the magnetic direction of the free layer is opposite to the magnetic direction of the fixed layer), a high resistance state can be created in the barrier layer, and the stored memory bit information is stored. Equal to A binary value such as 0. Generally, a magnetoresistive random access memory (MRAM) device is formed by providing a pinned layer, a barrier layer, and a free layer between two electrodes in a semiconductor device.

磁阻式隨機存取記憶體(MRAM)元件可操作設定及擷取資料,例如讀取、寫入1(設定數值為1)與寫入0(清除設定數值為0)。寫入操作,亦稱為程式化操作,其對電極施予電脈衝,以使電流於元件的固定層與自由層之間流動。根據電流流動方向,自由層的磁性方向將改變使其符合或相反於固定層的磁性方向。讀取操作亦藉由量測磁阻式隨機存取記憶體(MRAM)元件固定層與自由層之間的電阻而實施橫跨電極。 Magnetoresistive random access memory (MRAM) components can be manipulated to set and retrieve data such as read, write 1 (set value is 1) and write 0 (clear set value to 0). A write operation, also known as a stylized operation, applies an electrical pulse to the electrodes to cause current to flow between the fixed and free layers of the element. Depending on the direction of current flow, the magnetic direction of the free layer will change to conform to or opposite the magnetic direction of the fixed layer. The read operation is also performed across the electrodes by measuring the resistance between the fixed layer and the free layer of the magnetoresistive random access memory (MRAM) device.

本發明之一實施例,提供一種磁阻式隨機存取記憶體(magnetoresistive random access memory,MRAM)。該磁阻式隨機存取記憶體(MRAM)包括一固定磁性層,一阻障層,鄰近該固定磁性層,以及一巨磁阻(giant magnetoresistance,GMR)結構,鄰近該阻障層。該巨磁阻(GMR)結構包括一第一磁性層、一第二磁性層與一導電層,該導電層插入於該第一磁性層與該第二磁性層之間,以平面圖來看,該第一磁性層之尺寸不同於該第二磁性層之尺寸。 One embodiment of the present invention provides a magnetoresistive random access memory (MRAM). The magnetoresistive random access memory (MRAM) includes a fixed magnetic layer, a barrier layer adjacent to the fixed magnetic layer, and a giant magnetoresistance (GMR) structure adjacent to the barrier layer. The giant magnetoresistance (GMR) structure includes a first magnetic layer, a second magnetic layer and a conductive layer. The conductive layer is interposed between the first magnetic layer and the second magnetic layer. The size of the first magnetic layer is different from the size of the second magnetic layer.

本發明之另一實施例,提供一種磁阻式隨機存取記憶體(magnetoresistive random access memory,MRAM)。該磁阻式隨機存取記憶體(MRAM)包括一固定層,一阻障層,鄰近該固定層,一巨磁阻(giant magnetoresistance,GMR)結 構,鄰近該阻障層。該巨磁阻(GMR)結構包括一第一磁性層、一第二磁性層與一導電層,該導電層插入於該第一磁性層與該第二磁性層之間。該磁阻式隨機存取記憶體(MRAM)更包括一第一寫入電極(write electrode),耦接該第一磁性層,以及一第二寫入電極(write electrode),耦接該第二磁性層。 Another embodiment of the present invention provides a magnetoresistive random access memory (MRAM). The magnetoresistive random access memory (MRAM) includes a fixed layer, a barrier layer adjacent to the fixed layer, and a giant magnetoresistance (GMR) junction. Constructed adjacent to the barrier layer. The giant magnetoresistance (GMR) structure includes a first magnetic layer, a second magnetic layer and a conductive layer, and the conductive layer is interposed between the first magnetic layer and the second magnetic layer. The magnetoresistive random access memory (MRAM) further includes a first write electrode coupled to the first magnetic layer and a second write electrode coupled to the second Magnetic layer.

本發明之另一實施例,提供一種磁阻式隨機存取記憶體(magnetoresistive random access memory,MRAM)。該磁阻式隨機存取記憶體(MRAM)包括一固定層,一阻障層,鄰近該固定層,一第一磁性層,鄰近該阻障層,一導電層,鄰近該第一磁性層,一第二磁性層,鄰近該導電層,一第一電極,直接耦接該第一磁性層,以及一第二電極,直接耦接該第二磁性層。 Another embodiment of the present invention provides a magnetoresistive random access memory (MRAM). The magnetoresistive random access memory (MRAM) includes a fixed layer, a barrier layer adjacent to the fixed layer, a first magnetic layer, adjacent to the barrier layer, and a conductive layer adjacent to the first magnetic layer. A second magnetic layer adjacent to the conductive layer, a first electrode directly coupled to the first magnetic layer, and a second electrode directly coupled to the second magnetic layer.

為讓本發明之上述目的、特徵及優點能更明顯易懂,下文特舉一較佳實施例,並配合所附圖式,作詳細說明如下: The above described objects, features and advantages of the present invention will become more apparent and understood.

根據一實施例,第1~6B圖說明一記憶體元件製程的不同中間階段。首先,請參閱第1圖,根據一實施例,顯示一晶圓100的部分結構,其具有一包含一第一電極124的介電層110。值得注意的是,第一電極124可電性耦接至形成於一下方基板(未圖示)上的電子電路(未圖示)及/或一外部連接(external connection)(未圖示)。例如,在圖1所說明的實施例中,第一電極124可藉由一接觸窗(未圖示)電性耦接至一形成於一下方基板上的電晶體的源/汲極區。依 此方式,電晶體可用來控制後續形成的記憶體元件的狀態的讀取。 According to an embodiment, Figures 1 through 6B illustrate different intermediate stages of a memory device process. First, referring to FIG. 1, a portion of a structure of a wafer 100 having a dielectric layer 110 including a first electrode 124 is shown, in accordance with an embodiment. It should be noted that the first electrode 124 can be electrically coupled to an electronic circuit (not shown) and/or an external connection (not shown) formed on a lower substrate (not shown). For example, in the embodiment illustrated in FIG. 1, the first electrode 124 can be electrically coupled to a source/drain region of a transistor formed on a lower substrate by a contact window (not shown). according to In this manner, the transistor can be used to control the reading of the state of the subsequently formed memory component.

在一實施例中,電路可進一步包括形成於基板上的電子元件,該基板具有一或多層介電層覆蓋該電子元件。金屬層可形成於介電層之間,以於電子元件之間傳遞電子訊號。電子元件亦可形成於一或多層介電層中。一般來說,層間介電層(ILD)、金屬層間介電層(IMD)與結合的金屬化層係用來內連接形成於一下方基板上的每一電子電路並提供一外部電子連接。 In an embodiment, the circuit can further include an electronic component formed on the substrate, the substrate having one or more dielectric layers covering the electronic component. A metal layer can be formed between the dielectric layers to transfer electronic signals between the electronic components. Electronic components can also be formed in one or more dielectric layers. In general, an interlayer dielectric layer (ILD), an inter-metal dielectric layer (IMD), and a bonded metallization layer are used to internally connect each electronic circuit formed on a lower substrate and provide an external electrical connection.

介電層110可由例如一低K介電材料所形成,例如磷矽玻璃(PSG)、硼磷矽玻璃(BPSG)、氟矽玻璃(FSG)、SiOxCy、旋塗玻璃、旋塗高分子、碳矽材料、其化合物、其組合物或其組合或類似物。其可藉由任意適當方法形成,例如旋轉塗佈、化學氣相沈積(CVD)及電漿輔助化學氣相沈積(PECVD)。值得注意的是,介電層110可包括複數層介電層。 The dielectric layer 110 may be formed of, for example, a low-k dielectric material such as phosphorous-glass (PSG), borophosphorus glass (BPSG), fluorocarbon glass (FSG), SiOxCy, spin-on glass, spin-on polymer, carbon An anthraquinone material, a compound thereof, a composition thereof, or a combination or analog thereof. It can be formed by any suitable method, such as spin coating, chemical vapor deposition (CVD), and plasma assisted chemical vapor deposition (PECVD). It is noted that the dielectric layer 110 can include a plurality of dielectric layers.

第一電極124可藉由包括一鑲嵌製程的任意適當製程形成於介電層110中。一般來說,鑲嵌製程包括沈積一層(例如介電層110)於一基板上,以及形成一罩幕(未圖示)於該層上。該罩幕可利用例如光微影及蝕刻技術進行圖案化,包括沈積一光阻材料、形成罩幕、曝光及顯影,以露出介電層110將移除的部分。殘留的光阻材料係於後續例如蝕刻的製程步驟中保護下層材料。在一實施例中,光阻材料用來創造一圖案化罩幕,以定義第一電極124。開口可利用一蝕刻製程製作形成,例如一非等向性或等向性蝕刻製 程,例如一非等向性乾蝕刻製程。於蝕刻製程後,移除殘留光阻,之後,於開口中,填入一導電材料。多出的導電材料可利用一平坦化製程加以移除,例如一化學機械研磨(CMP)製程。亦可使用例如電鍍、蝕刻、雙鑲嵌及其類似製程的其他製程。 The first electrode 124 can be formed in the dielectric layer 110 by any suitable process including a damascene process. Generally, the damascene process includes depositing a layer (e.g., dielectric layer 110) on a substrate and forming a mask (not shown) on the layer. The mask can be patterned using, for example, photolithography and etching techniques, including depositing a photoresist material, forming a mask, exposing and developing to expose portions of the dielectric layer 110 that will be removed. The residual photoresist material is used to protect the underlying material during subsequent processing steps such as etching. In one embodiment, the photoresist material is used to create a patterned mask to define the first electrode 124. The opening can be formed by an etching process, such as an anisotropic or isotropic etching process. Process, such as an anisotropic dry etch process. After the etching process, the residual photoresist is removed, and then, a conductive material is filled in the opening. The excess conductive material can be removed using a planarization process, such as a chemical mechanical polishing (CMP) process. Other processes such as electroplating, etching, dual damascene, and the like can also be used.

第一電極124可由任何適當導電材料所形成,例如一高導電、低電阻金屬、元素金屬、過渡金屬或其類似物,包括金屬或金屬合金,包括一或多個鋁、鋁銅、銅、鈦、氮化鈦、鎢及其類似物。此外,第一電極124可包括一阻障/黏著層,以避免擴散及提供第一電極124與周圍介電層之間較佳的黏著。第一電極124可藉由例如物理氣相沈積(PVD)、原子層沈積(ALD)、旋塗沈積(spin-on deposition)或其他適當方法形成。 The first electrode 124 can be formed of any suitable electrically conductive material, such as a highly conductive, low resistance metal, elemental metal, transition metal, or the like, including a metal or metal alloy, including one or more of aluminum, aluminum copper, copper, titanium. , titanium nitride, tungsten and the like. In addition, the first electrode 124 can include a barrier/adhesion layer to avoid diffusion and provide better adhesion between the first electrode 124 and the surrounding dielectric layer. The first electrode 124 can be formed by, for example, physical vapor deposition (PVD), atomic layer deposition (ALD), spin-on deposition, or other suitable method.

值得注意的是,此處所提供第一電極124的位置及形狀僅作為說明之用。此外,第一電極124可包括一導線及/或重分佈導線(redistribution line),以側向延伸第一電極124穿過覆蓋其上的記憶體結構。 It should be noted that the position and shape of the first electrode 124 provided herein are for illustrative purposes only. Additionally, the first electrode 124 can include a wire and/or a redistribution line to laterally extend the first electrode 124 through the memory structure overlying it.

根據一實施例,第2圖說明一固定層120、一阻障層130與一第一鐵磁層140的形成步驟。固定層120可為一單層或多層結構。例如,在一實施例中,固定層120包括一例如鈷鐵、鈷鐵硼、鎳鐵、鈷、鐵、鎳或其類似物的磁性材料層,其厚度可大體介於40~200埃。在另一實施例中,固定層120可包括多層,例如一由適當的反鐵磁材料例如鉑錳、鎳錳、銥錳、鐵錳或其類似物所形成的底層,以及一由磁性材料例如鈷鐵、鈷鐵硼、鎳鐵、鈷、鐵、鎳 或其類似物所形成的覆蓋層。在此實施例中,底部的反鐵磁層的厚度大體介於40~200埃,而覆蓋其上的磁性層的厚度大體介於40~200埃。 According to an embodiment, FIG. 2 illustrates a step of forming a fixed layer 120, a barrier layer 130, and a first ferromagnetic layer 140. The pinned layer 120 can be a single layer or a multilayer structure. For example, in one embodiment, the pinned layer 120 includes a layer of magnetic material such as cobalt iron, cobalt iron boron, nickel iron, cobalt, iron, nickel, or the like, which may have a thickness generally between 40 and 200 angstroms. In another embodiment, the pinned layer 120 can comprise multiple layers, such as a bottom layer formed of a suitable antiferromagnetic material such as platinum manganese, nickel manganese, lanthanum manganese, iron manganese or the like, and a magnetic material such as Cobalt iron, cobalt iron boron, nickel iron, cobalt, iron, nickel a cover layer formed by or the like. In this embodiment, the thickness of the antiferromagnetic layer at the bottom is generally between 40 and 200 angstroms, and the thickness of the magnetic layer overlying it is generally between 40 and 200 angstroms.

在另一實施例中,固定層120可包括一反鐵磁層與一覆蓋其上的巨磁阻結構(giant magnetoresistance(GMR)structure)。反鐵磁層可包括一適當的反鐵磁材料,例如鉑錳、鎳錳、銥錳、鐵錳或其類似物,其厚度大體介於40~200埃。覆蓋其上的巨磁阻結構可包括具有一中間導電層的兩磁性層,例如兩磁性層可由任何磁性材料所形成,例如鈷鐵、鈷鐵硼、鎳鐵、鈷、鐵、鎳、鐵硼、鐵鉑或其類似物,其厚度大體介於10~50埃。中間導電層可由任何適當導電材料所形成,例如銅、釕、鉭或其類似物,其厚度大體介於5~20埃。然,其他實施例可使用不同材料、層數、厚度及其類似條件。 In another embodiment, the pinned layer 120 can include an antiferromagnetic layer and a giant magnetoresistance (GMR) structure overlying it. The antiferromagnetic layer may comprise a suitable antiferromagnetic material, such as platinum manganese, nickel manganese, lanthanum manganese, iron manganese or the like, having a thickness generally between 40 and 200 angstroms. The giant magnetoresistive structure covered thereon may comprise two magnetic layers having an intermediate conductive layer, for example, the two magnetic layers may be formed of any magnetic material, such as cobalt iron, cobalt iron boron, nickel iron, cobalt, iron, nickel, iron boron. , iron platinum or the like, the thickness of which is generally between 10 and 50 angstroms. The intermediate conductive layer may be formed of any suitable electrically conductive material, such as copper, tantalum, niobium or the like, having a thickness generally between 5 and 20 angstroms. However, other embodiments may use different materials, layers, thicknesses, and the like.

阻障層130可例如為一介電材料,例如氧化鎂,氧化鋁及/或其類似物。在一實施例中,阻障層130的厚度大體介於5~30埃。 The barrier layer 130 can be, for example, a dielectric material such as magnesium oxide, aluminum oxide, and/or the like. In one embodiment, the thickness of the barrier layer 130 is generally between 5 and 30 angstroms.

在一實施例中,第一鐵磁層(first ferromagnetic layer)140可由任何適當磁性材料所形成,例如鈷鐵硼、鎳鐵、鈷、鐵、鎳、鐵硼、鐵鉑及/或其類似物,其厚度大體介於15~50埃。第一鐵磁層140可利用任意適當製程例如化學氣相沈積(CVD)、物理氣相沈積(PVD)或原子層沈積(ALD)形成。 In an embodiment, the first ferromagnetic layer 140 may be formed of any suitable magnetic material, such as cobalt iron boron, nickel iron, cobalt, iron, nickel, iron boron, iron platinum, and/or the like. The thickness is generally between 15 and 50 angstroms. The first ferromagnetic layer 140 can be formed using any suitable process such as chemical vapor deposition (CVD), physical vapor deposition (PVD), or atomic layer deposition (ALD).

根據一實施例,第3圖說明固定層120、阻障層130與第一鐵磁層140的圖案化步驟。一般來說,該些層可利 用光微影技術進行圖案化,藉由形成一圖案化罩幕以保護固定層120、阻障層130與第一鐵磁層140欲保留的部分,接著,利用一或多種可接受技術例如利用一非等向性蝕刻(anisotropic etch)以移除露出部分,之後,形成一第二介電層115於晶圓100上。第二介電層115可包括例如一低K介電材料,例如磷矽玻璃(PSG)、硼磷矽玻璃(BPSG)、氟矽玻璃(FSG)、SiOxCy、旋塗玻璃、旋塗高分子、碳矽材料、二氧化矽、四乙基矽氧烷(TEOS)、其化合物、其組合物或其組合或類似物。其可藉由任意適當方法形成,例如旋轉塗佈、化學氣相沈積(CVD)及電漿輔助化學氣相沈積(PECVD)。值得注意的是,第二介電層115可包括複數層介電層。可實施一例如化學機械研磨(CMP)製程的平坦化製程,以露出第一鐵磁層140的上表面,其結構如第3圖所示。 According to an embodiment, FIG. 3 illustrates a patterning step of the pinned layer 120, the barrier layer 130, and the first ferromagnetic layer 140. Generally speaking, these layers are profitable. Patterning by photolithography, by forming a patterned mask to protect the portion of the pinned layer 120, the barrier layer 130 and the first ferromagnetic layer 140 to be retained, and then utilizing one or more acceptable techniques, for example, An anisotropic etch is performed to remove the exposed portions, after which a second dielectric layer 115 is formed on the wafer 100. The second dielectric layer 115 may include, for example, a low-k dielectric material such as phosphorous bismuth glass (PSG), borophosphoquinone glass (BPSG), fluorocarbon glass (FSG), SiOxCy, spin-on glass, spin-on polymer, Carbonium material, cerium oxide, tetraethyl decane (TEOS), compounds thereof, combinations thereof, or combinations or analogs thereof. It can be formed by any suitable method, such as spin coating, chemical vapor deposition (CVD), and plasma assisted chemical vapor deposition (PECVD). It should be noted that the second dielectric layer 115 may include a plurality of dielectric layers. A planarization process such as a chemical mechanical polishing (CMP) process may be performed to expose the upper surface of the first ferromagnetic layer 140, the structure of which is shown in FIG.

根據一實施例,第4圖說明一間隙層220與一第二鐵磁層230的形成步驟。間隙層220可為一導電層,其由任何適當導電材料所形成,包括金屬材料,例如銅、釕、鉭、其組合及/或其類似物。在一實施例中,間隙層220的厚度大體介於5~20埃。在一實施例中,間隙層220的厚度小於第一鐵磁層140的厚度。第二鐵磁層230可由任何適當鐵磁材料所形成,例如鈷鐵硼、鎳鐵、鈷、鐵、鎳、鐵硼、鐵鉑及/或其類似物,其厚度大體介於10~50埃。 According to an embodiment, FIG. 4 illustrates the steps of forming a gap layer 220 and a second ferromagnetic layer 230. The gap layer 220 can be a conductive layer formed of any suitable electrically conductive material, including metallic materials such as copper, tantalum, niobium, combinations thereof, and/or the like. In one embodiment, the thickness of the gap layer 220 is generally between 5 and 20 angstroms. In an embodiment, the thickness of the gap layer 220 is less than the thickness of the first ferromagnetic layer 140. The second ferromagnetic layer 230 may be formed of any suitable ferromagnetic material, such as cobalt iron boron, nickel iron, cobalt, iron, nickel, iron boron, iron platinum, and/or the like, and has a thickness generally between 10 and 50 angstroms. .

根據一實施例,第5圖說明間隙層220與第二鐵磁層230的圖案化步驟。間隙層220與第二鐵磁層230以類似第3圖所述圖案化固定層120、阻障層130與第一鐵磁層 140的方式進行圖案化。例如形成一罩幕層,並利用光微影技術圖案化該罩幕層,以露出間隙層220與第二鐵磁層230不期望保留的部分,利用一或多種蝕刻製程以移除間隙層220與第二鐵磁層230的露出部分,形成如第5圖所示的結構。利用上述第二介電層115的類似材料與製程形成一第三介電層135。 According to an embodiment, FIG. 5 illustrates a patterning step of the gap layer 220 and the second ferromagnetic layer 230. The gap layer 220 and the second ferromagnetic layer 230 pattern the fixed layer 120, the barrier layer 130 and the first ferromagnetic layer in a manner similar to that shown in FIG. The way of 140 is patterned. For example, a mask layer is formed and patterned by photolithography to expose portions of the gap layer 220 and the second ferromagnetic layer 230 that are not desired to be retained, using one or more etching processes to remove the gap layer 220. With the exposed portion of the second ferromagnetic layer 230, a structure as shown in Fig. 5 is formed. A third dielectric layer 135 is formed using a similar material and process of the second dielectric layer 115 described above.

在一實施例中,第一鐵磁層140、間隙層220與第二鐵磁層230形成一巨磁阻(GMR)結構,其可視為一實施例利用一巨磁阻結構以取代磁阻式隨機存取記憶體(MRAM)元件的自由層(free layer)。值得注意的是,在第5圖所說明的實施例中,第二鐵磁層230與間隙層220圖案化後的寬度與下層第一鐵磁層140的寬度不同。依此方式,極易形成對第一鐵磁層140的電性接觸,例如以下第6A與6B圖的說明。 In one embodiment, the first ferromagnetic layer 140, the gap layer 220, and the second ferromagnetic layer 230 form a giant magnetoresistance (GMR) structure, which may be considered as an embodiment using a giant magnetoresistive structure instead of a magnetoresistive type. A free layer of random access memory (MRAM) components. It should be noted that in the embodiment illustrated in FIG. 5, the width of the second ferromagnetic layer 230 and the gap layer 220 after patterning is different from the width of the lower first ferromagnetic layer 140. In this manner, electrical contact to the first ferromagnetic layer 140 is readily formed, such as the description of Figures 6A and 6B below.

固定層120亦可包括一巨磁阻(GMR)結構,在此實施例中,固定層120包括一第一巨磁阻(GMR)結構,而第一鐵磁層140、間隙層220與第二鐵磁層230形成一第二巨磁阻(GMR)結構。 The fixed layer 120 may also include a giant magnetoresistive (GMR) structure. In this embodiment, the fixed layer 120 includes a first giant magnetoresistance (GMR) structure, and the first ferromagnetic layer 140, the gap layer 220 and the second layer The ferromagnetic layer 230 forms a second giant magnetoresistance (GMR) structure.

根據一實施例,第6A與6B圖分別說明於形成一第四介電層145、一第二電極324與一第三電極224後的一剖面圖與一平面圖,其中第6A圖為沿第6B圖A-A’剖面線所得的剖面圖。第四介電層145可利用與上述第二介電層115類似的材料與製程形成。之後,第二電極324可形成穿過第四介電層145,而第三電極224可形成穿過第三介電層135與第四介電層145,藉此分別提供對第二鐵磁層230與 第一鐵磁層140的電性接觸。 6A and 6B are respectively a cross-sectional view and a plan view showing a fourth dielectric layer 145, a second electrode 324 and a third electrode 224, wherein FIG. 6A is along the sixth A cross-sectional view taken from the section line A-A'. The fourth dielectric layer 145 can be formed using a material and process similar to the second dielectric layer 115 described above. Thereafter, the second electrode 324 may be formed through the fourth dielectric layer 145, and the third electrode 224 may be formed through the third dielectric layer 135 and the fourth dielectric layer 145, thereby respectively providing the second ferromagnetic layer 230 with Electrical contact of the first ferromagnetic layer 140.

根據一實施例,第6A與6B圖更說明不同電極與層別的相對位置。例如距離D1、D2與D3說明下圖案化層(即固定層120、阻障層130與第一鐵磁層140)相對於上圖案化層(即間隙層220與第二鐵磁層230)以及相對於第三電極224的位置。第6B圖平面圖說明下圖案化層(即固定層120、阻障層130與第一鐵磁層140)橢圓圖案的尺寸,例如具有一長度B與一寬度A,以及上圖案化層(即間隙層220與第二鐵磁層230)橢圓圖案的尺寸,例如具有一長度b與一寬度a。 According to an embodiment, Figures 6A and 6B illustrate the relative positions of the different electrodes and layers. For example, the distances D1, D2, and D3 illustrate the patterned layer (ie, the fixed layer 120, the barrier layer 130, and the first ferromagnetic layer 140) with respect to the upper patterned layer (ie, the gap layer 220 and the second ferromagnetic layer 230) and Relative to the position of the third electrode 224. 6B is a plan view illustrating the size of the elliptical pattern of the lower patterned layer (ie, the fixed layer 120, the barrier layer 130, and the first ferromagnetic layer 140), for example, having a length B and a width A, and an upper patterned layer (ie, a gap) The dimensions of the elliptical pattern of layer 220 and second ferromagnetic layer 230, for example, have a length b and a width a.

在一實施例中,距離D1(自下圖案化層邊緣至上圖案化層側向邊緣的一側向距離)的數值大體介於0~(B-b)/4nm。距離D2(上圖案化層與第三電極224之間的一側向距離)的範圍大體介於10~(B-b)/4nm。距離D3(自第三電極224至下圖案化層側向邊緣的一側向距離)的數值大體介於0~(B-b)/4nm。在一實施例中,第一電極124、第二電極324與第三電極224可沿橢圓形狀的中心線設置,例如沿中心線A/2。在一實施例中,長寬比(aspect ratio)b/a與B/A的範圍可介於1~3.5。在一實施例中,a可介於10~100nm。 In one embodiment, the value of distance D1 (the distance from the edge of the lower patterned layer to the lateral edge of the upper patterned layer) is generally between 0 and (B-b) / 4 nm. The range of distance D2 (the lateral distance between the upper patterned layer and the third electrode 224) is generally in the range of 10 to (B-b) / 4 nm. The value of the distance D3 (the distance from the third electrode 224 to the lateral side of the lateral edge of the lower patterned layer) is generally between 0 and (B-b) / 4 nm. In an embodiment, the first electrode 124, the second electrode 324, and the third electrode 224 may be disposed along a centerline of the elliptical shape, such as along the centerline A/2. In an embodiment, the aspect ratios b/a and B/A may range from 1 to 3.5. In an embodiment, a may be between 10 and 100 nm.

值得注意的是,上述提供的形狀、尺寸、距離、相對位置及比例僅作為說明之用。其他實施例可使用不同形狀(例如環形、方形、矩形等)、尺寸、相對位置、比例及其類似條件。 It should be noted that the shapes, dimensions, distances, relative positions, and ratios provided above are for illustrative purposes only. Other embodiments may use different shapes (e.g., circular, square, rectangular, etc.), dimensions, relative positions, ratios, and the like.

根據另一實施例,第7A與7B圖分別說明一剖面圖與 一平面圖,其中第7A圖為沿第7B圖B-B’剖面線所得的剖面圖。在此實施例中,固定層120、阻障層130、第一鐵磁層140、間隙層220與第二鐵磁層230於成層製程中的方位順序恰好相反。此實施例可利用如上述類似的製程與材料。 According to another embodiment, the 7A and 7B drawings respectively illustrate a cross-sectional view and A plan view in which Fig. 7A is a cross-sectional view taken along line B-B' of Fig. 7B. In this embodiment, the orientation order of the pinned layer 120, the barrier layer 130, the first ferromagnetic layer 140, the gap layer 220, and the second ferromagnetic layer 230 in the layering process is reversed. This embodiment can utilize processes and materials similar to those described above.

根據一實施例,第7A與7B圖亦說明相對距離D1、D2、D3及相對尺寸A、B、a、b。在一實施例中,該些距離與尺寸的數值可與上述第6A與6B圖所述數值類似,其中,在此實施例中,下圖案化層包括第一鐵磁層140、間隙層220與第二鐵磁層230,而上圖案化層包括固定層120與阻障層130。 According to an embodiment, Figures 7A and 7B also illustrate relative distances D1, D2, D3 and relative dimensions A, B, a, b. In an embodiment, the values of the distances and dimensions may be similar to the values described in the above FIGS. 6A and 6B, wherein in this embodiment, the lower patterned layer includes the first ferromagnetic layer 140, the gap layer 220, and The second ferromagnetic layer 230, and the upper patterned layer includes the fixed layer 120 and the barrier layer 130.

根據一實施例,第8A~8D圖說明記憶體單元的操作過程。值得注意的是,該操作過程係相對於第6A與6B圖所說明的實施例作描述。在此實施例中,第一電極124作為一讀取位元線(read bit-line(BL)),第二電極324作為一寫入源極線(write source line(SL)),第三電極224作為一寫入位元線(write bit-line(BL))。 According to an embodiment, Figures 8A-8D illustrate the operation of the memory unit. It should be noted that this operational procedure is described with respect to the embodiments illustrated in Figures 6A and 6B. In this embodiment, the first electrode 124 serves as a read bit line (BL), and the second electrode 324 serves as a write source line (SL). 224 is written as a bit line (write bit-line (BL)).

請參閱第8A圖,說明一”寫入0(write to 0)”的過程,其電流流動方向自第三電極224(電性耦接第一鐵磁層140)流向第二電極324(電性耦接第二鐵磁層230),使得巨磁阻(GMR)結構的磁性方向自一反平行排列(anti-parallel alignment)改變為一與固定層120磁性方向相關的平行排列(parallel alignment)。因此,創造出一低電阻元件狀態。由於此較低電阻的巨磁阻(GMR)結構,致可有效降低翻轉自由層(巨磁阻(GMR)結構)磁化的所需電流。此外,橫跨阻障 層130的較小電壓可降低超出崩潰電壓的機會,致降低阻障層損壞機會。 Referring to FIG. 8A, a process of “writing to 0” is illustrated, in which the current flow direction flows from the third electrode 224 (electrically coupled to the first ferromagnetic layer 140) to the second electrode 324 (electricity). The second ferromagnetic layer 230 is coupled such that the magnetic direction of the giant magnetoresistance (GMR) structure changes from an anti-parallel alignment to a parallel alignment related to the magnetic direction of the fixed layer 120. Therefore, a low resistance element state is created. Due to this lower resistance giant magnetoresistance (GMR) structure, the required current for inverting the magnetization of the free layer (Giant Magnetoresistive (GMR) structure) can be effectively reduced. In addition, across the barrier The smaller voltage of layer 130 can reduce the chance of exceeding the breakdown voltage, resulting in reduced barrier damage opportunities.

第8B圖說明一”寫入1(write to 1)”的過程,其電流流動方向與”寫入0(write to 0)”過程的電流流動方向相反。在”寫入1(write to 1)”的過程中,電流自第二電極324(電性耦接第二鐵磁層230)流向第三電極224(電性耦接第一鐵磁層140),使得巨磁阻(GMR)結構的磁性方向自一平行排列(parallel alignment)改變為一與固定層120磁性方向相關的反平行排列(anti-parallel alignment)。因此,創造出一高電阻元件狀態。此電流通過巨磁阻(GMR)結構的過程繞過了電流須通過阻障層130與固定層120的必要性。由於此較低電阻的巨磁阻(GMR)結構,致可有效降低翻轉自由層(巨磁阻(GMR)結構)磁化的所需電流。此外,橫跨阻障層130的較小電壓可降低超出崩潰電壓的機會,致降低阻障層130損壞機會。 Figure 8B illustrates a "write to 1" process in which the direction of current flow is opposite to the direction of current flow of the "write to 0" process. In the process of "write to 1", current flows from the second electrode 324 (electrically coupled to the second ferromagnetic layer 230) to the third electrode 224 (electrically coupled to the first ferromagnetic layer 140) The magnetic direction of the giant magnetoresistance (GMR) structure is changed from a parallel alignment to an anti-parallel alignment associated with the magnetic orientation of the fixed layer 120. Therefore, a high resistance element state is created. The process of this current through the giant magnetoresistance (GMR) structure bypasses the necessity of current to pass through the barrier layer 130 and the pinned layer 120. Due to this lower resistance giant magnetoresistance (GMR) structure, the required current for inverting the magnetization of the free layer (Giant Magnetoresistive (GMR) structure) can be effectively reduced. In addition, a smaller voltage across the barrier layer 130 can reduce the chance of exceeding the breakdown voltage, resulting in a reduced chance of damage to the barrier layer 130.

第8C與8D圖說明元件讀取過程的不同實施例。在一實施例中,例如第8C圖所示,該讀取過程藉由施予一小電壓於第一電極124(電性耦接固定層120)與第二電極324(電性耦接第二鐵磁層230)之間並取樣該電流以偵測磁阻式隨機存取記憶體(MRAM)元件的電阻狀態(低或高)。在另一實施例中,例如第8D圖所示,該讀取過程藉由施予一小電壓於第一電極124(電性耦接固定層120)與第三電極224(電性耦接第一鐵磁層140)之間並取樣該電流以偵測自旋力矩傳輸磁阻式隨機存取記憶體(STT-MRAM)元件的電阻狀態(低或高)。由於僅須小電壓執行讀取動作,因此, 讀取過程對阻障崩潰電壓的影響極小。此外,具有讀取及寫入儲存元件的分離電極可允許在元件中對儲存資料進行較高速讀取/寫入存取。 Figures 8C and 8D illustrate different embodiments of the component reading process. In an embodiment, for example, as shown in FIG. 8C, the reading process is performed by applying a small voltage to the first electrode 124 (electrically coupled to the pinned layer 120) and the second electrode 324 (electrically coupled to the second The current is sampled between the ferromagnetic layers 230) to detect the resistance state (low or high) of the magnetoresistive random access memory (MRAM) device. In another embodiment, as shown in FIG. 8D, the reading process is performed by applying a small voltage to the first electrode 124 (electrically coupled to the fixed layer 120) and the third electrode 224 (electrically coupled The current is sampled between a ferromagnetic layer 140) to detect the resistance state (low or high) of the spin torque transmitting magnetoresistive random access memory (STT-MRAM) component. Since only a small voltage is required to perform a read operation, The reading process has minimal impact on the barrier breakdown voltage. In addition, separate electrodes with read and write storage elements allow for higher speed read/write access to stored data in the elements.

類似第6A與6B圖元件前述過程的讀取/寫入過程可應用於例如第7A與7B圖所示的實施例。例如,請參閱第7A圖,藉由利用元件的第一電極124(電性耦接第二鐵磁層230)與第二電極324(電性耦接固定層120)誘發一寫入過程。為執行一讀取動作,一實施例可利用第一電極124(電性耦接第二鐵磁層230)與第二電極324(電性耦接固定層120)。在另一實施例中,第一電極124(電性耦接第二鐵磁層230)與第三電極224(電性耦接第一鐵磁層140)可用來讀取元件。 The read/write process of the foregoing process like the elements of Figs. 6A and 6B can be applied to, for example, the embodiments shown in Figs. 7A and 7B. For example, referring to FIG. 7A, a writing process is induced by using the first electrode 124 of the component (electrically coupled to the second ferromagnetic layer 230) and the second electrode 324 (electrically coupling the pinned layer 120). In order to perform a read operation, an embodiment may utilize a first electrode 124 (electrically coupled to the second ferromagnetic layer 230) and a second electrode 324 (electrically coupled to the pinned layer 120). In another embodiment, the first electrode 124 (electrically coupled to the second ferromagnetic layer 230) and the third electrode 224 (electrically coupled to the first ferromagnetic layer 140) can be used to read the component.

根據一實施例,第9圖說明例如上述磁阻式隨機存取記憶體(MRAM)元件的一陣列。一寫入源極線(write source line(SL))連接第6A圖所示元件的第二電極324,一寫入位元線(write bit-line(BL))連接第6A圖所示元件的第三電極224,以及一讀取位元線(read bit-line(BL))連接第6A圖所示元件的第一電極124。 According to an embodiment, FIG. 9 illustrates an array of magnetoresistive random access memory (MRAM) elements, such as described above. A write source line (SL) is connected to the second electrode 324 of the component shown in FIG. 6A, and a write bit line (BL) is connected to the component shown in FIG. The third electrode 224, and a read bit line (BL) are connected to the first electrode 124 of the element shown in Fig. 6A.

雖然本發明已以較佳實施例揭露如上,然其並非用以限定本發明,任何熟習此項技藝者,在不脫離本發明之精神和範圍內,當可作更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。 While the present invention has been described in its preferred embodiments, the present invention is not intended to limit the invention, and the invention may be modified and retouched without departing from the spirit and scope of the invention. The scope of protection is subject to the definition of the scope of the patent application attached.

100‧‧‧晶圓 100‧‧‧ wafer

110‧‧‧介電層 110‧‧‧ dielectric layer

115‧‧‧第二介電層 115‧‧‧Second dielectric layer

120‧‧‧固定層 120‧‧‧Fixed layer

124‧‧‧第一電極 124‧‧‧First electrode

130‧‧‧阻障層 130‧‧‧Barrier layer

135‧‧‧第三介電層 135‧‧‧ third dielectric layer

140‧‧‧第一鐵磁層 140‧‧‧First Ferromagnetic Layer

145‧‧‧第四介電層 145‧‧‧fourth dielectric layer

220‧‧‧間隙層 220‧‧‧ gap layer

224‧‧‧第三電極 224‧‧‧ third electrode

230‧‧‧第二鐵磁層 230‧‧‧Second ferromagnetic layer

324‧‧‧第二電極 324‧‧‧second electrode

a‧‧‧上圖案化層橢圓圖案的寬度 a‧‧‧The width of the elliptical pattern on the patterned layer

A‧‧‧下圖案化層橢圓圖案的寬度 A‧‧‧The width of the elliptical pattern of the patterned layer

A/2‧‧‧橢圓形狀的中心線 A/2‧‧‧ elliptical shape centerline

b‧‧‧上圖案化層橢圓圖案的長度 B‧‧‧ Length of the elliptical pattern on the patterned layer

B‧‧‧下圖案化層橢圓圖案的長度 B‧‧‧The length of the elliptical pattern of the patterned layer

D1‧‧‧自下圖案化層邊緣至上圖案化層側向邊緣的一側向距離 D1‧‧‧From the side of the lower patterned layer to the lateral edge of the upper patterned layer

D2‧‧‧上圖案化層與第三電極之間的一側向距離 The lateral distance between the patterned layer and the third electrode on D2‧‧

D3‧‧‧自第三電極至下圖案化層側向邊緣的一側向距離 D3‧‧‧One-way distance from the third electrode to the lateral edge of the lower patterned layer

第1~5圖及第6A-6B圖係根據一實施例,說明一相變化記憶體的形成方法。 FIGS. 1 to 5 and 6A-6B illustrate a method of forming a phase change memory according to an embodiment.

第7A~7B圖說明磁阻式隨機存取記憶體(MRAM)元件的另一實施例。 7A-7B illustrate another embodiment of a magnetoresistive random access memory (MRAM) device.

第8A~8D圖係根據一實施例,說明設定/清除記憶狀態(寫入)及讀取記憶狀態的方法。 8A to 8D are diagrams illustrating a method of setting/clearing a memory state (writing) and reading a memory state, according to an embodiment.

第9圖係根據一實施例,說明一磁阻式隨機存取記憶體(MRAM)陣列。 Figure 9 illustrates a magnetoresistive random access memory (MRAM) array in accordance with an embodiment.

100‧‧‧晶圓 100‧‧‧ wafer

110‧‧‧介電層 110‧‧‧ dielectric layer

115‧‧‧第二介電層 115‧‧‧Second dielectric layer

120‧‧‧固定層 120‧‧‧Fixed layer

124‧‧‧第一電極 124‧‧‧First electrode

130‧‧‧阻障層 130‧‧‧Barrier layer

135‧‧‧第三介電層 135‧‧‧ third dielectric layer

140‧‧‧第一鐵磁層 140‧‧‧First Ferromagnetic Layer

145‧‧‧第四介電層 145‧‧‧fourth dielectric layer

220‧‧‧間隙層 220‧‧‧ gap layer

224‧‧‧第三電極 224‧‧‧ third electrode

230‧‧‧第二鐵磁層 230‧‧‧Second ferromagnetic layer

324‧‧‧第二電極 324‧‧‧second electrode

D1‧‧‧自下圖案化層邊緣至上圖案化層側向邊緣的一側向距離 D1‧‧‧From the side of the lower patterned layer to the lateral edge of the upper patterned layer

D2‧‧‧上圖案化層與第三電極之間的一側向距離 The lateral distance between the patterned layer and the third electrode on D2‧‧

D3‧‧‧自第三電極至下圖案化層側向邊緣的一側向距離 D3‧‧‧One-way distance from the third electrode to the lateral edge of the lower patterned layer

Claims (12)

一種磁阻式隨機存取記憶體(magnetoresistive random access memory,MRAM),包括:一固定磁性層;一阻障層,鄰近該固定磁性層;以及一巨磁阻(giant magnetoresistance,GMR)結構,鄰近該阻障層,該巨磁阻(GMR)結構包括一第一磁性層、一第二磁性層與一導電層,該導電層插入於該第一磁性層與該第二磁性層之間,該第一磁性層之尺寸不同於該第二磁性層之尺寸。 A magnetoresistive random access memory (MRAM) comprising: a fixed magnetic layer; a barrier layer adjacent to the fixed magnetic layer; and a giant magnetoresistance (GMR) structure, adjacent The barrier layer, the giant magnetoresistance (GMR) structure includes a first magnetic layer, a second magnetic layer and a conductive layer, the conductive layer is interposed between the first magnetic layer and the second magnetic layer, The size of the first magnetic layer is different from the size of the second magnetic layer. 如申請專利範圍第1項所述之磁阻式隨機存取記憶體(MRAM),更包括:一第一電極,電性耦接該固定磁性層;一第二電極,電性耦接該巨磁阻(GMR)結構之該第一磁性層;以及一第三電極,電性耦接該巨磁阻(GMR)結構之該第二磁性層。 The magnetoresistive random access memory (MRAM) of claim 1, further comprising: a first electrode electrically coupled to the fixed magnetic layer; and a second electrode electrically coupled to the giant a first magnetic layer of a magnetoresistive (GMR) structure; and a third electrode electrically coupled to the second magnetic layer of the giant magnetoresistive (GMR) structure. 如申請專利範圍第1項所述之磁阻式隨機存取記憶體(MRAM),其中該第一磁性層較該第二磁性層鄰近該阻障層,該第二磁性層之厚度大於該第一磁性層之厚度。 The magnetoresistive random access memory (MRAM) according to claim 1, wherein the first magnetic layer is adjacent to the barrier layer than the second magnetic layer, and the thickness of the second magnetic layer is greater than the first The thickness of a magnetic layer. 如申請專利範圍第1項所述之磁阻式隨機存取記憶體(MRAM),其中該固定磁性層、該阻障層與該第一磁性層具有相同之長度與寬度,且該導電層與該第二磁性層具有相同之長度與寬度。 The magnetoresistive random access memory (MRAM) of claim 1, wherein the fixed magnetic layer, the barrier layer and the first magnetic layer have the same length and width, and the conductive layer The second magnetic layer has the same length and width. 如申請專利範圍第1項所述之磁阻式隨機存取記憶 體(MRAM),其中該固定磁性層與該阻障層具有相同之長度與寬度,且該第一磁性層、該導電層與該第二磁性層具有相同之長度與寬度。 Reluctance random access memory as described in claim 1 The body (MRAM), wherein the fixed magnetic layer has the same length and width as the barrier layer, and the first magnetic layer, the conductive layer and the second magnetic layer have the same length and width. 一種磁阻式隨機存取記憶體(magnetoresistive random access memory,MRAM),包括:一固定層;一阻障層,鄰近該固定層;一巨磁阻(giant magnetoresistance,GMR)結構,鄰近該阻障層,該巨磁阻(GMR)結構包括一第一磁性層、一第二磁性層與一導電層,該導電層插入於該第一磁性層與該第二磁性層之間;一第一寫入電極(write electrode),耦接該第一磁性層;以及一第二寫入電極,耦接該第二磁性層。 A magnetoresistive random access memory (MRAM) comprising: a fixed layer; a barrier layer adjacent to the fixed layer; a giant magnetoresistance (GMR) structure adjacent to the barrier a giant magnetoresistive (GMR) structure comprising a first magnetic layer, a second magnetic layer and a conductive layer, the conductive layer being interposed between the first magnetic layer and the second magnetic layer; a write electrode coupled to the first magnetic layer and a second write electrode coupled to the second magnetic layer. 如申請專利範圍第6項所述之磁阻式隨機存取記憶體(MRAM),其中該第一磁性層之長度大於該第二磁性層之長度。 The magnetoresistive random access memory (MRAM) according to claim 6, wherein the length of the first magnetic layer is greater than the length of the second magnetic layer. 如申請專利範圍第6項所述之磁阻式隨機存取記憶體(MRAM),其中該第一磁性層之長度大於該固定層之長度。 The magnetoresistive random access memory (MRAM) according to claim 6, wherein the length of the first magnetic layer is greater than the length of the fixed layer. 一種磁阻式隨機存取記憶體(magnetoresistive random access memory,MRAM),包括:一固定層;一阻障層,鄰近該固定層;一第一磁性層,鄰近該阻障層; 一導電層,鄰近該第一磁性層;一第二磁性層,鄰近該導電層;一第一電極,直接耦接該第一磁性層;以及一第二電極,直接耦接該第二磁性層。 A magnetoresistive random access memory (MRAM) comprising: a fixed layer; a barrier layer adjacent to the fixed layer; a first magnetic layer adjacent to the barrier layer; a conductive layer adjacent to the first magnetic layer; a second magnetic layer adjacent to the conductive layer; a first electrode directly coupled to the first magnetic layer; and a second electrode directly coupled to the second magnetic layer . 如申請專利範圍第9項所述之磁阻式隨機存取記憶體(MRAM),其中該固定層、該阻障層與該第一磁性層具有相同之長度與寬度。 The magnetoresistive random access memory (MRAM) according to claim 9, wherein the fixed layer, the barrier layer and the first magnetic layer have the same length and width. 如申請專利範圍第9項所述之磁阻式隨機存取記憶體(MRAM),其中該第一磁性層、該導電層與該第二磁性層之寬度大於該固定層之寬度。 The magnetoresistive random access memory (MRAM) according to claim 9, wherein the width of the first magnetic layer, the conductive layer and the second magnetic layer is greater than the width of the fixed layer. 如申請專利範圍第9項所述之磁阻式隨機存取記憶體(MRAM),更包括一第三電極,耦接該固定層。 The magnetoresistive random access memory (MRAM) according to claim 9, further comprising a third electrode coupled to the fixed layer.
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CN103247753B (en) 2015-09-16

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