TW201320129A - Metal-insulator-metal capacitor structure and method for manufacturing the same - Google Patents
Metal-insulator-metal capacitor structure and method for manufacturing the same Download PDFInfo
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 70
- 239000002184 metal Substances 0.000 title claims abstract description 70
- 239000003990 capacitor Substances 0.000 title claims abstract description 61
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 23
- 239000010410 layer Substances 0.000 claims abstract description 416
- 230000009977 dual effect Effects 0.000 claims abstract description 40
- 239000002356 single layer Substances 0.000 claims abstract description 12
- 230000004888 barrier function Effects 0.000 claims description 106
- 239000000463 material Substances 0.000 claims description 29
- 229910052758 niobium Inorganic materials 0.000 claims description 15
- 239000010955 niobium Substances 0.000 claims description 15
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 14
- 229910052802 copper Inorganic materials 0.000 claims description 14
- 239000010949 copper Substances 0.000 claims description 14
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 claims description 11
- 229910003468 tantalcarbide Inorganic materials 0.000 claims description 11
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 claims description 11
- NNBKCAMHTYOBQS-UHFFFAOYSA-I N(=O)[O-].[Nb+5].N(=O)[O-].N(=O)[O-].N(=O)[O-].N(=O)[O-] Chemical compound N(=O)[O-].[Nb+5].N(=O)[O-].N(=O)[O-].N(=O)[O-].N(=O)[O-] NNBKCAMHTYOBQS-UHFFFAOYSA-I 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 229910052797 bismuth Inorganic materials 0.000 claims 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 claims 1
- 238000005530 etching Methods 0.000 description 14
- 238000000151 deposition Methods 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 229910052814 silicon oxide Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 230000010354 integration Effects 0.000 description 3
- 238000007517 polishing process Methods 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- AJHQUQJABBRDOW-UHFFFAOYSA-N [Nb].[La] Chemical compound [Nb].[La] AJHQUQJABBRDOW-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- RHDUVDHGVHBHCL-UHFFFAOYSA-N niobium tantalum Chemical compound [Nb].[Ta] RHDUVDHGVHBHCL-UHFFFAOYSA-N 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
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Abstract
Description
本發明係有關於一種電容結構,且特別是有關於一種金屬-絕緣層-金屬電容(Metal-Insulator-Metal Capacitor,MIMCAP)結構及其製作方法。The present invention relates to a capacitor structure, and more particularly to a Metal-Insulator-Metal Capacitor (MIMCAP) structure and a method of fabricating the same.
金屬-絕緣層-金屬電容通常是由絕緣層以及被絕緣層分隔的兩個金屬電極組成,其具有尺寸小,電容穩定以及寄生效應小等優點。The metal-insulator-metal capacitor is usually composed of an insulating layer and two metal electrodes separated by an insulating layer, which have the advantages of small size, stable capacitance, and small parasitic effect.
隨著積體電路技術的發展,金屬-絕緣層-金屬電容已經被廣泛的應用。為了實現金屬-絕緣層-金屬電容與積體電路中其他電子元件的電性連接,目前,通常是將金屬-絕緣層-金屬電容與積體電路之內連接(interconnection)結構整合在一起。但是,在習知積體電路技術中,整合金屬-絕緣層-金屬電容與內連接結構的製程步驟繁多,通常需要進行多次的絕緣層以及金屬層的沈積與蝕刻,從而導致製作成本增加,也使得金屬-絕緣層-金屬電容與內連接結構的整合結構複雜。With the development of integrated circuit technology, metal-insulator-metal capacitors have been widely used. In order to realize the electrical connection between the metal-insulating layer-metal capacitor and other electronic components in the integrated circuit, at present, the metal-insulating layer-metal capacitor is usually integrated with the internal connection structure of the integrated circuit. However, in the conventional integrated circuit technology, the process steps of integrating the metal-insulating layer-metal capacitor and the interconnect structure are numerous, and it is usually required to perform multiple depositions and etching of the insulating layer and the metal layer, thereby causing an increase in manufacturing cost. It also complicates the integrated structure of the metal-insulator-metal capacitor and the interconnect structure.
有鑑於此,本發明提供一種金屬-絕緣層-金屬電容結構,其結構簡單,有利於降低製作成本。In view of this, the present invention provides a metal-insulating layer-metal capacitor structure, which has a simple structure and is advantageous for reducing manufacturing costs.
本發明提供一種金屬-絕緣層-金屬電容結構之製作方法,其製作步驟簡單,有利於降低製作成本。The invention provides a metal-insulating layer-metal capacitor structure manufacturing method, which has simple manufacturing steps and is advantageous for reducing the manufacturing cost.
為達上述及其它優點,本發明提出一種金屬-絕緣層-金屬電容結構,包括第一介電層、第一電極層、絕緣阻擋層、第二介電層以及第二電極層。第一電極層鑲嵌於第一介電層中。絕緣阻擋層覆蓋第一介電層以及第一電極層,絕緣阻擋層為單層結構。第二介電層位於絕緣阻擋層上。第二電極層鑲嵌於第二介電層中,並位於第一電極層上方而與絕緣阻擋層接觸。To achieve the above and other advantages, the present invention provides a metal-insulating layer-metal capacitor structure including a first dielectric layer, a first electrode layer, an insulating barrier layer, a second dielectric layer, and a second electrode layer. The first electrode layer is embedded in the first dielectric layer. The insulating barrier layer covers the first dielectric layer and the first electrode layer, and the insulating barrier layer has a single layer structure. The second dielectric layer is on the insulating barrier layer. The second electrode layer is embedded in the second dielectric layer and is located above the first electrode layer to be in contact with the insulating barrier layer.
在本發明之一實施例中,上述之絕緣阻擋層之材質包括氮化矽(SiN)、碳化矽(SiC)、氮碳化矽(SiCN)或氮氧化矽(SiON)。In an embodiment of the invention, the material of the insulating barrier layer comprises tantalum nitride (SiN), tantalum carbide (SiC), niobium oxynitride (SiCN) or niobium oxynitride (SiON).
在本發明之一實施例中,上述之第一電極層與第二電極層之材質為銅。In an embodiment of the invention, the material of the first electrode layer and the second electrode layer is copper.
為達上述及其它優點,本發明提出一種金屬-絕緣層-金屬電容結構,包括第一介電層、第一電極層、絕緣阻擋層、第二介電層、第二電極層以及雙鑲嵌(dual damascene)結構。第一電極層鑲嵌於第一介電層中。絕緣阻擋層形成於第一介電層以及第一電極層上。第二介電層形成於絕緣阻擋層上。第二電極層鑲嵌於第二介電層中,並位於第一電極層上方而與絕緣阻擋層接觸。雙鑲嵌結構鑲嵌於第二介電層以及絕緣阻擋層中而電性連接至第一電極層。To achieve the above and other advantages, the present invention provides a metal-insulating layer-metal capacitor structure including a first dielectric layer, a first electrode layer, an insulating barrier layer, a second dielectric layer, a second electrode layer, and a dual damascene ( Dual damascene) structure. The first electrode layer is embedded in the first dielectric layer. An insulating barrier layer is formed on the first dielectric layer and the first electrode layer. A second dielectric layer is formed on the insulating barrier layer. The second electrode layer is embedded in the second dielectric layer and is located above the first electrode layer to be in contact with the insulating barrier layer. The dual damascene structure is embedded in the second dielectric layer and the insulating barrier layer to be electrically connected to the first electrode layer.
在本發明之一實施例中,上述之絕緣阻擋層為單層結構。In an embodiment of the invention, the insulating barrier layer is a single layer structure.
在本發明之一實施例中,上述之絕緣阻擋層之材質包括氮化矽、碳化矽、氮碳化矽或氮氧化矽。In an embodiment of the invention, the material of the insulating barrier layer comprises tantalum nitride, tantalum carbide, niobium nitrite or niobium oxynitride.
在本發明之一實施例中,上述之第一電極層與第二電極層之材質為銅。In an embodiment of the invention, the material of the first electrode layer and the second electrode layer is copper.
在本發明之一實施例中,上述之第二電極層與雙鑲嵌結構的材質相同。In an embodiment of the invention, the second electrode layer is the same material as the dual damascene structure.
在本發明之一實施例中,上述之絕緣阻擋層為複合層結構。複合層結構包括位於第一介電層上之第一絕緣層以及位於第一絕緣層上之第二絕緣層。第一絕緣層之材質包括氮化矽、碳化矽、氮碳化矽或氮氧化矽。第二絕緣層之材質包括未摻雜的矽玻璃(undoped silicate glass,USG)、氧化鉭(Ta2O5)、氧化鋯(ZrO2)或氧化鋁(Al2O3)。In an embodiment of the invention, the insulating barrier layer is a composite layer structure. The composite layer structure includes a first insulating layer on the first dielectric layer and a second insulating layer on the first insulating layer. The material of the first insulating layer includes tantalum nitride, tantalum carbide, niobium nitrite or niobium oxynitride. The material of the second insulating layer includes undoped silicate glass (USG), yttrium oxide (Ta 2 O 5 ), zirconia (ZrO 2 ) or aluminum oxide (Al 2 O 3 ).
為達上述及其它優點,本發明提出一種金屬-絕緣層-金屬電容結構之製作方法,其包括以下步驟。於第一介電層中形成第一開口。於第一開口內填入第一電極層。形成絕緣阻擋層,覆蓋第一介電層以及第一電極層,絕緣阻擋層為單層結構。於絕緣阻擋層上形成第二介電層。於第二介電層中形成第二開口,其中第二開口位於第一電極層上方並暴露出部分之絕緣阻擋層。於第二開口內填入第二電極層,以使第二電極層與絕緣阻擋層接觸。To achieve the above and other advantages, the present invention provides a method of fabricating a metal-insulator-metal capacitor structure comprising the following steps. A first opening is formed in the first dielectric layer. The first electrode layer is filled in the first opening. An insulating barrier layer is formed to cover the first dielectric layer and the first electrode layer, and the insulating barrier layer has a single layer structure. A second dielectric layer is formed on the insulating barrier layer. A second opening is formed in the second dielectric layer, wherein the second opening is over the first electrode layer and exposes a portion of the insulating barrier layer. The second electrode layer is filled in the second opening to bring the second electrode layer into contact with the insulating barrier layer.
在本發明之一實施例中,上述之絕緣阻擋層之材質包括氮化矽、碳化矽、氮碳化矽或氮氧化矽。In an embodiment of the invention, the material of the insulating barrier layer comprises tantalum nitride, tantalum carbide, niobium nitrite or niobium oxynitride.
在本發明之一實施例中,上述之第一電極層與第二電極層之材質為銅。In an embodiment of the invention, the material of the first electrode layer and the second electrode layer is copper.
在本發明之一實施例中,上述之製作方法更包括於第二介電層以及絕緣阻擋層中形成雙鑲嵌開口,雙鑲嵌開口位於第一電極層上方並暴露出部分之第一電極層;以及於雙鑲嵌開口內填入雙鑲嵌結構,電性連接至第一電極層。In an embodiment of the invention, the method further includes forming a dual damascene opening in the second dielectric layer and the insulating barrier layer, the dual damascene opening being over the first electrode layer and exposing a portion of the first electrode layer; And filling the dual damascene opening into the dual damascene opening, electrically connecting to the first electrode layer.
在本發明之一實施例中,形成上述之雙鑲嵌開口包括以下步驟。首先,在形成第二開口時,同時於第二介電層中形成第三開口,第三開口位於第一電極層上方並暴露出部分之絕緣阻擋層。然後,移除第三開口所暴露出之部分絕緣阻擋層,以形成暴露出部分之第一電極層之雙鑲嵌開口。In an embodiment of the invention, forming the dual damascene opening described above comprises the following steps. First, when the second opening is formed, a third opening is simultaneously formed in the second dielectric layer, and the third opening is located above the first electrode layer and exposes a portion of the insulating barrier layer. Then, a portion of the insulating barrier layer exposed by the third opening is removed to form a dual damascene opening of the exposed first electrode layer.
在本發明之一實施例中,移除上述之第三開口所暴露出之部分絕緣阻擋層包括以下步驟。首先,於第二介電層上形成圖案化遮罩層,以覆蓋第二開口,並暴露出第三開口。然後,移除圖案化遮罩層所暴露出的部分之絕緣阻擋層。之後,移除圖案化遮罩層。In an embodiment of the invention, removing a portion of the insulating barrier layer exposed by the third opening includes the following steps. First, a patterned mask layer is formed on the second dielectric layer to cover the second opening and expose the third opening. Then, the portion of the insulating barrier layer exposed by the patterned mask layer is removed. After that, the patterned mask layer is removed.
本發明實施例之金屬-絕緣層-金屬電容結構及其製作方法是利用鑲嵌(damascene)技術形成第一電極層以及第二電極層,並以單層結構的絕緣阻擋層隔開第一電極層與第二電極層。由於此單層結構的絕緣阻擋層不但是做為電容結構中的絕緣層,更可在形成第二電極層時可用作蝕刻阻擋層,從而使得形成的金屬-絕緣層-金屬電容結構簡單,有利於降低製作成本。在另一實施例中,金屬-絕緣層-金屬電容結構更包括雙鑲嵌(dual damascene)結構,形成於第二介電層以及絕緣阻擋層中,而電性連接至第一電極層。此雙鑲嵌結構可與第二電極層於同一製程製作完成,從而簡化了金屬-絕緣層-金屬電容與內連接結構的整合結構以及製程步驟,有利於降低製作成本。The metal-insulating layer-metal capacitor structure of the embodiment of the invention and the manufacturing method thereof are formed by using a damascene technique to form the first electrode layer and the second electrode layer, and separating the first electrode layer by a single-layer insulating barrier layer And a second electrode layer. Since the insulating barrier layer of the single-layer structure is not only used as an insulating layer in the capacitor structure, but also can be used as an etching barrier layer when forming the second electrode layer, so that the formed metal-insulating layer-metal capacitor structure is simple. Helps reduce production costs. In another embodiment, the metal-insulating layer-metal capacitor structure further includes a dual damascene structure formed in the second dielectric layer and the insulating barrier layer and electrically connected to the first electrode layer. The dual damascene structure can be fabricated in the same process as the second electrode layer, thereby simplifying the integration structure of the metal-insulating layer-metal capacitor and the inner connecting structure and the manufacturing steps, thereby reducing the manufacturing cost.
為讓本發明之上述和其他目的、特徵和優點能更明顯易懂,下文特舉較佳實施例,並配合所附圖式,作詳細說明如下。The above and other objects, features and advantages of the present invention will become more <RTIgt;
圖1A至圖1E,為本發明第一實施例之金屬-絕緣層-金屬電容之製作方法的示意圖。1A to 1E are schematic views showing a method of fabricating a metal-insulating layer-metal capacitor according to a first embodiment of the present invention.
請參閱圖1A,在本實施例中,首先,例如是利用鑲嵌(damascene)技術在第一介電層110中鑲嵌形成第一電極層120。具體地,先於第一介電層110中形成第一開口112,再於第一介電層110表面沈積金屬層(例如銅層)並使其填入第一開口112中,之後利用化學機械研磨(chemical mechanical polishing,CMP)製程移除第一開口112之外的金屬層,從而形成位於第一開口112內之第一電極層120。在本實施例中,第一電極層120是銅鑲嵌層。Referring to FIG. 1A, in the embodiment, first, the first electrode layer 120 is inlaid in the first dielectric layer 110 by, for example, a damascene technique. Specifically, a first opening 112 is formed in the first dielectric layer 110, and a metal layer (for example, a copper layer) is deposited on the surface of the first dielectric layer 110 and filled into the first opening 112, after which the chemical mechanical mechanism is utilized. A chemical mechanical polishing (CMP) process removes a metal layer other than the first opening 112 to form a first electrode layer 120 located within the first opening 112. In the present embodiment, the first electrode layer 120 is a copper damascene layer.
請參閱圖1B,然後,形成絕緣阻擋層130,覆蓋第一介電層110以及第一電極層120。絕緣阻擋層130為單層結構,且其材質例如包括氮化矽(SiN)、碳化矽(SiC)、氮碳化矽(SiCN)、氮氧化矽(SiON)或其他具有高介電常數的材料。在本實施例中,絕緣阻擋層130的介電常數例如是5。絕緣阻擋層130的厚度例如是介於200埃~1500埃。Referring to FIG. 1B , an insulating barrier layer 130 is formed to cover the first dielectric layer 110 and the first electrode layer 120 . The insulating barrier layer 130 has a single layer structure, and its material includes, for example, tantalum nitride (SiN), tantalum carbide (SiC), tantalum niobium carbide (SiCN), niobium oxynitride (SiON), or other materials having a high dielectric constant. In the present embodiment, the dielectric constant of the insulating barrier layer 130 is, for example, 5. The thickness of the insulating barrier layer 130 is, for example, between 200 Å and 1500 Å.
請參閱圖1C,之後,於絕緣阻擋層130上形成第二介電層140。在本實施例中第一介電層110與第二介電層140的材質例如是氧化物。Referring to FIG. 1C, a second dielectric layer 140 is formed on the insulating barrier layer 130. In the present embodiment, the material of the first dielectric layer 110 and the second dielectric layer 140 is, for example, an oxide.
請參閱圖1D至1E,在本實施例中,例如是利用鑲嵌技術在第二介電層140中鑲嵌形成第二電極層150。具體地,請參閱圖1D,先於第二介電層140中形成第二開口142。其中,第二開口142位於第一電極層120上方並暴露出部分之絕緣阻擋層130。Referring to FIGS. 1D to 1E, in the present embodiment, the second electrode layer 150 is inlaid in the second dielectric layer 140 by, for example, a damascene technique. Specifically, referring to FIG. 1D, a second opening 142 is formed in the second dielectric layer 140. The second opening 142 is located above the first electrode layer 120 and exposes a portion of the insulating barrier layer 130.
承上述,在第二介電層140中形成第二開口142時,可利用絕緣阻擋層130做為蝕刻終止層,意即利用第二介電層140與絕緣阻擋層130之間的蝕刻選擇比,使用以蝕刻第二介電層140的蝕刻製程停止於絕緣阻擋層130。因此,在第二開口142形成之後,部分絕緣阻擋層130會由第二開口142暴露出來。In the above, when the second opening 142 is formed in the second dielectric layer 140, the insulating barrier layer 130 can be used as an etch stop layer, that is, the etching selectivity ratio between the second dielectric layer 140 and the insulating barrier layer 130 is utilized. The insulating barrier layer 130 is stopped using an etching process that etches the second dielectric layer 140. Therefore, after the second opening 142 is formed, a portion of the insulating barrier layer 130 is exposed by the second opening 142.
請參閱圖1E,在第二介電層140表面沈積金屬層(例如銅層),並使其填入第二開口142中而覆蓋絕緣阻擋層130,再利用化學機械研磨製程移除第二開口142之外的金屬層,從而形成位於第二開口142內且與絕緣阻擋層130接觸的第二電極層150。在本實施例中,第二電極層150是銅鑲嵌層。Referring to FIG. 1E, a metal layer (for example, a copper layer) is deposited on the surface of the second dielectric layer 140, and is filled in the second opening 142 to cover the insulating barrier layer 130, and then the second opening is removed by a chemical mechanical polishing process. A metal layer other than 142, thereby forming a second electrode layer 150 located within the second opening 142 and in contact with the insulating barrier layer 130. In the present embodiment, the second electrode layer 150 is a copper damascene layer.
在形成第二電極層150之後,此及大致形成本實施例之金屬-絕緣層-金屬電容結構100。詳細來說,金屬-絕緣層-金屬電容結構100包括第一介電層110、第一電極層120、絕緣阻擋層130、第二介電層140以及第二電極層150。第一電極層120鑲嵌於第一介電層110中。絕緣阻擋層130覆蓋第一介電層110以及第一電極層120,絕緣阻擋層130為單層結構。第二介電層140位於絕緣阻擋層130上。第二電極層150鑲嵌於第二介電層140中並位於第一電極層120上方而與絕緣阻擋層130接觸。After the second electrode layer 150 is formed, the metal-insulating layer-metal capacitor structure 100 of the present embodiment is substantially formed. In detail, the metal-insulating layer-metal capacitor structure 100 includes a first dielectric layer 110, a first electrode layer 120, an insulating barrier layer 130, a second dielectric layer 140, and a second electrode layer 150. The first electrode layer 120 is embedded in the first dielectric layer 110. The insulating barrier layer 130 covers the first dielectric layer 110 and the first electrode layer 120, and the insulating barrier layer 130 has a single layer structure. The second dielectric layer 140 is on the insulating barrier layer 130. The second electrode layer 150 is embedded in the second dielectric layer 140 and is located above the first electrode layer 120 to be in contact with the insulating barrier layer 130.
特別的是,在金屬-絕緣層-金屬電容結構100中,絕緣阻擋層130更是做為間隔第一電極層120與第二電極層150的介電層。由此可知,在製作本實施例之金屬-絕緣層-金屬電容結構100的製程中並無需額外進行兩電極之間的介電層之沈積,因此不但有利於降低製作成本,更可製作出結構簡單的金屬-絕緣層-金屬電容結構100。In particular, in the metal-insulating layer-metal capacitor structure 100, the insulating barrier layer 130 is further used as a dielectric layer separating the first electrode layer 120 and the second electrode layer 150. Therefore, in the process of fabricating the metal-insulating layer-metal capacitor structure 100 of the embodiment, it is not necessary to additionally deposit the dielectric layer between the two electrodes, thereby not only reducing the manufacturing cost, but also fabricating the structure. Simple metal-insulator-metal capacitor structure 100.
需要注意的是,在形成第二開口142的製程中,也可能因過度蝕刻(over etch)而蝕刻掉部分的絕緣阻擋層130。因此,在形成第二開口142之後,絕緣阻擋層130的剩餘厚度係視原先所沈積之厚度以及用以蝕刻第二介電層140之蝕刻液對於絕緣阻擋層130的蝕刻速率來決定。It should be noted that in the process of forming the second opening 142, a portion of the insulating barrier layer 130 may also be etched away due to over etch. Therefore, after the second opening 142 is formed, the remaining thickness of the insulating barrier layer 130 is determined by the thickness of the original deposition and the etching rate of the etching solution for etching the second dielectric layer 140 to the insulating barrier layer 130.
根據上述金屬-絕緣層-金屬電容結構100之製作方法,金屬-絕緣層-金屬電容結構100的製作可以與積體電路內連接結構的製作整合。圖2為金屬-絕緣層-金屬電容結構與內連接結構之示意圖。請參閱圖2,在本實施例中,繪示的內連接結構30例如是雙鑲嵌內連接結構,其包括導線層31、32以及接觸插塞33、34。為了整合製程,本實施例中,內連接結構30形成於第一介電層110與第二介電層140中。其中,導線層31以及接觸插塞33可與第一電極層110同時製作,導線層32以及接觸插塞34可與第二電極層150同時製作。需要注意的是,在形成內連接結構30的區域第一介電層110與第二介電層140之間或可不形成絕緣阻擋層130。According to the above-described method of fabricating the metal-insulating layer-metal capacitor structure 100, the fabrication of the metal-insulating layer-metal capacitor structure 100 can be integrated with the fabrication of the interconnect structure in the integrated circuit. 2 is a schematic view of a metal-insulating layer-metal capacitor structure and an inner connecting structure. Referring to FIG. 2, in the present embodiment, the illustrated inner connecting structure 30 is, for example, a dual damascene inner connecting structure including wire layers 31, 32 and contact plugs 33, 34. In the embodiment, the inner connecting structure 30 is formed in the first dielectric layer 110 and the second dielectric layer 140. The wire layer 31 and the contact plug 33 can be fabricated simultaneously with the first electrode layer 110, and the wire layer 32 and the contact plug 34 can be fabricated simultaneously with the second electrode layer 150. It should be noted that the insulating barrier layer 130 may not be formed between the first dielectric layer 110 and the second dielectric layer 140 in the region where the interconnect structure 30 is formed.
圖3A至圖3H為本發明第二實施例之金屬-絕緣層-金屬電容之製作方法的示意圖。3A to 3H are schematic views showing a method of fabricating a metal-insulating layer-metal capacitor according to a second embodiment of the present invention.
請參閱圖3A,在本實施例中,首先,例如是利用鑲嵌技術在第一介電層210中鑲嵌形成第一電極層220。具體地,先於第一介電層210中形成第一開口212,再在第一介電層210表面沈積金屬層(例如銅層),並使其填入第一開口212中,之後利用化學機械研磨程移除第一開口212之外的金屬層,從而形成位於第一開口212內之第一電極層220。在本實施例中,第一電極層220是銅鑲嵌層。Referring to FIG. 3A, in the embodiment, first, the first electrode layer 220 is inlaid in the first dielectric layer 210 by using a damascene technique. Specifically, a first opening 212 is formed in the first dielectric layer 210, and a metal layer (for example, a copper layer) is deposited on the surface of the first dielectric layer 210, and is filled in the first opening 212, and then chemistry is utilized. The mechanical polishing process removes the metal layer outside the first opening 212 to form the first electrode layer 220 located within the first opening 212. In the present embodiment, the first electrode layer 220 is a copper damascene layer.
請參閱圖3B,形成絕緣阻擋層230以覆蓋第一介電層210以及第一電極層220。絕緣阻擋層230可以為單層結構。絕緣阻擋層230之材質例如包括氮化矽(SiN)、碳化矽(SiC)、氮碳化矽(SiCN)、氮氧化矽(SiON)或其他具有高介電常數的材料。絕緣阻擋層130的厚度例如是介於200埃~1500埃。絕緣阻擋層230也可以為複合層結構,例如包括第一絕緣層以及第二絕緣層,第一絕緣層形成於第一介電層210以及第一電極層220上,第二絕緣層形成於第一絕緣層上。其中,第一絕緣層之材質包括氮化矽(SiN)、碳化矽(SiC)、氮碳化矽(SiCN)或氮氧化矽(SiON),第二絕緣層之材質包括(undoped silicate galss,USG)或其他具有高介電常數之材料例如氧化鉭(Ta2O5)、氧化鋯(ZrO2)、或氧化鋁(Al2O3)等。第一絕緣層的厚度例如是介於200埃~1500埃。第二絕緣層的厚度例如是介於100埃~1000埃。Referring to FIG. 3B, an insulating barrier layer 230 is formed to cover the first dielectric layer 210 and the first electrode layer 220. The insulating barrier layer 230 may have a single layer structure. The material of the insulating barrier layer 230 includes, for example, tantalum nitride (SiN), tantalum carbide (SiC), niobium lanthanum carbide (SiCN), niobium oxynitride (SiON), or other materials having a high dielectric constant. The thickness of the insulating barrier layer 130 is, for example, between 200 Å and 1500 Å. The insulating barrier layer 230 may also be a composite layer structure, for example, including a first insulating layer formed on the first dielectric layer 210 and the first electrode layer 220, and a second insulating layer formed on the first insulating layer On an insulating layer. The material of the first insulating layer comprises tantalum nitride (SiN), tantalum carbide (SiC), niobium oxynitride (SiCN) or niobium oxynitride (SiON), and the material of the second insulating layer includes (undoped silicate galss, USG) Or other materials having a high dielectric constant such as tantalum oxide (Ta 2 O 5 ), zirconium oxide (ZrO 2 ), or aluminum oxide (Al 2 O 3 ). The thickness of the first insulating layer is, for example, between 200 Å and 1500 Å. The thickness of the second insulating layer is, for example, between 100 angstroms and 1000 angstroms.
請參閱圖3C,之後,於絕緣阻擋層230上形成第二介電層240。在本實施例中第一介電層210與第二介電層240的材質例如是氧化物。本實施例之金屬-絕緣層-金屬電容之製作方法與第一實施例之金屬-絕緣層-金屬電容之製作方法之不同之處在於形成第二介電層240之後的步驟。Referring to FIG. 3C, a second dielectric layer 240 is formed on the insulating barrier layer 230. In the present embodiment, the material of the first dielectric layer 210 and the second dielectric layer 240 is, for example, an oxide. The method of fabricating the metal-insulating layer-metal capacitor of the present embodiment is different from the method of fabricating the metal-insulating layer-metal capacitor of the first embodiment in the step after the second dielectric layer 240 is formed.
請參閱圖3D至3H,在本實施例中,例如是利用鑲嵌技術在第二介電層240中鑲嵌形成第二電極層250以及利用雙鑲嵌(dual damascene)技術在第二介電層240與絕緣阻擋層230中鑲嵌形成雙鑲嵌結構260。需要注意的是,第二電極層250與雙鑲嵌結構260實質是利用同一鑲嵌製程製作完成的。Referring to FIGS. 3D to 3H, in the present embodiment, for example, a second electrode layer 250 is inlaid in the second dielectric layer 240 by using a damascene technique, and the second dielectric layer 240 is used by using a dual damascene technique. A dual damascene structure 260 is inlaid in the insulating barrier layer 230. It should be noted that the second electrode layer 250 and the dual damascene structure 260 are substantially fabricated using the same damascene process.
具體地,請參閱圖3D,在本實施例中,先於第二介電層240中形成第二開口242以及第三開口244。其中,第二開口242以及第三開口244均位於第一電極層220上方並分別暴露出部分之絕緣阻擋層230。第三開口244包括溝渠(trench)245以及介層洞(via)246,且溝渠245位於介層洞246上方,並與介層洞246連通。本實施例中,第三開口244包括一個溝渠245以及對應的一個介層洞246。在其他實施例中,第三開口244也可包括一個溝渠以及對應的多個介層洞。換句話說,溝渠245以及介層洞246的數量及設置是根據內連接的實際需要來決定的。需要注意的是,第三開口244可以是以溝渠優先(trench first)的方式製作而成,也可以是以介層洞優先(via first)的方式製作而成,或者也可以是以自行對準(self-aligned)的方式製作而成,在此不予以詳述。Specifically, referring to FIG. 3D , in the embodiment, the second opening 242 and the third opening 244 are formed in the second dielectric layer 240 . The second opening 242 and the third opening 244 are both located above the first electrode layer 220 and respectively expose a portion of the insulating barrier layer 230. The third opening 244 includes a trench 245 and a via 246, and the trench 245 is above the via 246 and is in communication with the via 246. In this embodiment, the third opening 244 includes a trench 245 and a corresponding via 246. In other embodiments, the third opening 244 can also include a trench and a corresponding plurality of via holes. In other words, the number and arrangement of the trenches 245 and vias 246 are determined based on the actual needs of the interconnects. It should be noted that the third opening 244 may be fabricated in a trench first manner, or may be formed in a via first manner, or may be self-aligned. (self-aligned) is made and will not be described in detail here.
形成第二開口242以及第三開口244的方法例如是微影蝕刻法。在第二介電層240中形成第二開口242以及第三開口244時,可利用絕緣阻擋層230做為蝕刻終止層,意即利用第二介電層240與絕緣阻擋層230之間的蝕刻選擇比,使用以蝕刻第二介電層240的蝕刻製程停止於絕緣阻擋層230。因此,在第二開口242以及第三開口244形成之後,部分絕緣阻擋層230會分別由第二開口242以及第三開口244暴露出來。The method of forming the second opening 242 and the third opening 244 is, for example, a photolithography method. When the second opening 242 and the third opening 244 are formed in the second dielectric layer 240, the insulating barrier layer 230 can be utilized as an etch stop layer, that is, etching between the second dielectric layer 240 and the insulating barrier layer 230. The selection ratio is stopped using the etching process to etch the second dielectric layer 240 to the insulating barrier layer 230. Therefore, after the second opening 242 and the third opening 244 are formed, the partial insulating barrier layer 230 is exposed by the second opening 242 and the third opening 244, respectively.
需要注意的是,在形成第二開口242以及第三開口244的過程中也可能因過度蝕刻(over etch)而蝕刻部分的絕緣阻擋層230,因此,在形成第二開口242以及第三開口244之後,絕緣阻擋層230的剩餘厚度係視原先所沈積之厚度以及用以蝕刻第二介電層240之蝕刻液的蝕刻速率對於絕緣阻擋層230的來決定。It should be noted that a portion of the insulating barrier layer 230 may also be etched by over etch during the formation of the second opening 242 and the third opening 244, and thus, the second opening 242 and the third opening 244 are formed. Thereafter, the remaining thickness of the insulating barrier layer 230 is determined by the thickness of the original deposition and the etching rate of the etching solution for etching the second dielectric layer 240 for the insulating barrier layer 230.
之後,移除第三開口244所暴露出之部分絕緣阻擋層230,以形成暴露出部分之第一電極層220之雙鑲嵌開口262。本實施例中,請參閱圖3E,首先,於第二介電層240上形成圖案化遮罩層270,以覆蓋第二介電層240以及第二開口242,並暴露出第三開口244。詳細來說,圖案化遮罩層270的材質例如是光阻材料。Thereafter, a portion of the insulating barrier layer 230 exposed by the third opening 244 is removed to form a dual damascene opening 262 of the exposed first portion of the electrode layer 220. In this embodiment, referring to FIG. 3E , first, a patterned mask layer 270 is formed on the second dielectric layer 240 to cover the second dielectric layer 240 and the second opening 242 and expose the third opening 244 . In detail, the material of the patterned mask layer 270 is, for example, a photoresist material.
請參閱圖3F,然後,移除第三開口244內未被圖案化遮罩層270覆蓋的部分之絕緣阻擋層230。例如,可選用能蝕刻絕緣阻擋層230之蝕刻液蝕刻移除由第三開口244所暴露出的部分之絕緣阻擋層230,或採用其他適宜之方法移除由第三開口244所暴露出的部分之絕緣阻擋層230。請參閱圖3G,之後,移除圖案化遮罩層270,從而形成雙鑲嵌開口262以暴露出部分第一電極層220。Referring to FIG. 3F, the insulating barrier layer 230 of the portion of the third opening 244 that is not covered by the patterned mask layer 270 is then removed. For example, the portion of the insulating barrier layer 230 exposed by the third opening 244 may be etched using an etchant capable of etching the insulating barrier layer 230, or the portion exposed by the third opening 244 may be removed by other suitable means. The insulating barrier layer 230. Referring to FIG. 3G, the patterned mask layer 270 is removed, thereby forming a dual damascene opening 262 to expose a portion of the first electrode layer 220.
請參閱圖3H,在第二介電層240表面沈積金屬層(例如銅層),以使其填入第二開口242以及雙鑲嵌開口262中。然後,利用化學機械研磨製程移除第二開口242以及雙鑲嵌開口262之外的金屬層,從而形成位於第二開口242之第二電極層250以及位於雙鑲嵌開口262之雙鑲嵌結構260。位於第二開口242之第二電極層250與絕緣阻擋層230接觸,位於雙鑲嵌開口262之雙鑲嵌結構260電性連接至第一電極層220。本實施例中,第二電極層250與雙鑲嵌結構260具有相同材質例如銅。Referring to FIG. 3H, a metal layer (eg, a copper layer) is deposited on the surface of the second dielectric layer 240 to fill the second opening 242 and the dual damascene opening 262. The second opening 242 and the metal layer outside the dual damascene opening 262 are then removed using a chemical mechanical polishing process to form a second electrode layer 250 at the second opening 242 and a dual damascene structure 260 at the dual damascene opening 262. The second electrode layer 250 located at the second opening 242 is in contact with the insulating barrier layer 230 , and the dual damascene structure 260 located at the dual damascene opening 262 is electrically connected to the first electrode layer 220 . In this embodiment, the second electrode layer 250 and the dual damascene structure 260 have the same material, such as copper.
請繼續參考圖3H,藉由本實施例之金屬-絕緣層-金屬電容之製作方法製作的金屬-絕緣層-金屬電容結構200,其包括第一介電層210、第一電極層220、絕緣阻擋層230、第二介電層240、第二電極層250以及雙鑲嵌結構260。第一電極層220鑲嵌於第一介電層210中。絕緣阻擋層230形成於第一介電層210以及第一電極層220上。第二介電層240形成於絕緣阻擋層230上。第二電極層250鑲嵌於第二介電層240中並位於第一電極層110上方而與絕緣阻擋層230接觸。雙鑲嵌結構260鑲嵌於第二介電層240以及絕緣阻擋層230中,並位於第一電極層220上方而電性連接至第一電極層220。Referring to FIG. 3H, the metal-insulating layer-metal capacitor structure 200 fabricated by the metal-insulating layer-metal capacitor manufacturing method of the embodiment includes a first dielectric layer 210, a first electrode layer 220, and an insulating barrier. Layer 230, second dielectric layer 240, second electrode layer 250, and dual damascene structure 260. The first electrode layer 220 is embedded in the first dielectric layer 210. The insulating barrier layer 230 is formed on the first dielectric layer 210 and the first electrode layer 220. The second dielectric layer 240 is formed on the insulating barrier layer 230. The second electrode layer 250 is embedded in the second dielectric layer 240 and is located above the first electrode layer 110 to be in contact with the insulating barrier layer 230. The dual damascene structure 260 is embedded in the second dielectric layer 240 and the insulating barrier layer 230 , and is disposed above the first electrode layer 220 and electrically connected to the first electrode layer 220 .
本實施例中,第二電極層250與雙鑲嵌結構260利用鑲嵌(damascene)技術同時進行製作,不僅簡化整合內連接結構之金屬-絕緣層-金屬電容結構200,而且無需額外進行金屬層以及絕緣層之沈積,有利於降低製作成本。而且,本實施例是利用絕緣阻擋層230同時做為形成第二開口242的蝕刻終止層以及第一電極層220與第二電極層250之間絕緣層,因而無需額外進行其他的膜層沈積製程。In this embodiment, the second electrode layer 250 and the dual damascene structure 260 are simultaneously fabricated by using damascene technology, which not only simplifies the integration of the metal-insulating layer-metal capacitor structure 200 of the interconnect structure, but also eliminates the need for additional metal layers and insulation. The deposition of layers helps to reduce the manufacturing cost. Moreover, in this embodiment, the insulating barrier layer 230 is used as the etch stop layer for forming the second opening 242 and the insulating layer between the first electrode layer 220 and the second electrode layer 250, so that no additional film deposition process is required. .
根據上述金屬-絕緣層-金屬電容結構200之製作方法,金屬-絕緣層-金屬電容結構200的製作可以與積體電路內連接結構的製作整合。圖4為金屬-絕緣層-金屬電容結構與內連接結構之示意圖。請參閱圖4,在本實施例中,繪示的內連接結構40例如是雙鑲嵌內連接結構,其包括第一導線層41、第二導線層42以及接觸插塞43、44。為了整合製程,本實施例中,內連接結構40形成於第一介電層210與第二介電層240中。其中,第一導線層41及接觸插塞43可與第二電極層250以及雙鑲嵌結構260同時製作,第二導線層42以及接觸插塞44可與第一電極層220同時製作。需要注意的是,在形成內連接結構40的區域第一介電層210與第二介電層240之間或可不形成絕緣阻擋層230。According to the above-described method of fabricating the metal-insulator-metal capacitor structure 200, the fabrication of the metal-insulator-metal capacitor structure 200 can be integrated with the fabrication of the interconnect structure in the integrated circuit. 4 is a schematic view of a metal-insulating layer-metal capacitor structure and an inner connecting structure. Referring to FIG. 4 , in the embodiment, the illustrated internal connection structure 40 is, for example, a dual damascene inner connection structure including a first wire layer 41 , a second wire layer 42 , and contact plugs 43 , 44 . In the embodiment, the inner connecting structure 40 is formed in the first dielectric layer 210 and the second dielectric layer 240. The first wire layer 41 and the contact plug 43 can be fabricated simultaneously with the second electrode layer 250 and the dual damascene structure 260, and the second wire layer 42 and the contact plug 44 can be fabricated simultaneously with the first electrode layer 220. It should be noted that the insulating barrier layer 230 may not be formed between the first dielectric layer 210 and the second dielectric layer 240 in the region where the interconnect structure 40 is formed.
本發明實施例之金屬-絕緣層-金屬電容結構及其製作方法是利用鑲嵌(damascene)技術形成第一電極層以及第二電極層,並且利用絕緣阻擋層同時做為形成第二開口時的蝕刻終止層以及用以間隔第一電極層與第二電極層的絕緣層,從而使得形成的金屬-絕緣層-金屬電容結構簡單,有利於降低製作成本。在另一實施例中,金屬-絕緣層-金屬電容結構更包括雙鑲嵌(dual damascene)結構,形成於第二介電層以及絕緣阻擋層中,而電性連接至第一電極層。此雙鑲嵌結構可與第二電極層於同一製程製作完成,從而簡化了金屬-絕緣層-金屬電容與內連接結構的整合結構以及製程步驟,有利於降低製作成本。The metal-insulating layer-metal capacitor structure of the embodiment of the invention and the manufacturing method thereof are to form the first electrode layer and the second electrode layer by using a damascene technique, and simultaneously use the insulating barrier layer as the etching for forming the second opening The termination layer and the insulating layer for spacing the first electrode layer and the second electrode layer make the formed metal-insulator-metal capacitor structure simple, which is advantageous for reducing the manufacturing cost. In another embodiment, the metal-insulating layer-metal capacitor structure further includes a dual damascene structure formed in the second dielectric layer and the insulating barrier layer and electrically connected to the first electrode layer. The dual damascene structure can be fabricated in the same process as the second electrode layer, thereby simplifying the integration structure of the metal-insulating layer-metal capacitor and the inner connecting structure and the manufacturing steps, thereby reducing the manufacturing cost.
雖然本發明已以較佳實施例揭露如上,然其並非用以限定本發明,任何熟習此技藝者,在不脫離本發明之精神和範圍內,當可作些許之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。While the present invention has been described in its preferred embodiments, the present invention is not intended to limit the invention, and the present invention may be modified and modified without departing from the spirit and scope of the invention. The scope of protection is subject to the definition of the scope of the patent application.
30、40...內連接結構30, 40. . . Internal connection structure
31、32...導線層31, 32. . . Wire layer
33、34、43、44...接觸插塞33, 34, 43, 44. . . Contact plug
41...第一導線層41. . . First wire layer
42...第二導線層42. . . Second wire layer
100、200...金屬-絕緣層-金屬電容結構100, 200. . . Metal-insulator-metal capacitor structure
110、210...第一介電層110, 210. . . First dielectric layer
112、212...第一開口112, 212. . . First opening
120、220...第一電極層120, 220. . . First electrode layer
130、230...絕緣阻擋層130, 230. . . Insulating barrier
140、240...第二介電層140, 240. . . Second dielectric layer
142、242...第二開口142, 242. . . Second opening
244...第三開口244. . . Third opening
245...溝渠245. . . ditch
246...介層洞246. . . Via hole
150、250...第二電極層150, 250. . . Second electrode layer
260...雙鑲嵌結構260. . . Double mosaic structure
262...雙鑲嵌開口262. . . Double inlaid opening
270...圖案化遮罩層270. . . Patterned mask layer
圖1A至圖1E為本發明第一實施例之金屬-絕緣層-金屬電容結構之製作方法之示意圖。1A to 1E are schematic views showing a method of fabricating a metal-insulating layer-metal capacitor structure according to a first embodiment of the present invention.
圖2為本發明第一實施例之金屬-絕緣層-金屬電容結構與內連接結構之示意圖。2 is a schematic view showing a metal-insulating layer-metal capacitor structure and an inner connecting structure according to a first embodiment of the present invention.
圖3A至圖3H為本發明第二實施例之金屬-絕緣層-金屬電容結構之製作方法之示意圖。3A to 3H are schematic views showing a method of fabricating a metal-insulating layer-metal capacitor structure according to a second embodiment of the present invention.
圖4為金屬-絕緣層-金屬電容結構與內連接結構之示意圖。4 is a schematic view of a metal-insulating layer-metal capacitor structure and an inner connecting structure.
100...金屬-絕緣層-金屬電容結構100. . . Metal-insulator-metal capacitor structure
110...第一介電層110. . . First dielectric layer
112...第一開口112. . . First opening
120...第一電極層120. . . First electrode layer
130...絕緣阻擋層130. . . Insulating barrier
140...第二介電層140. . . Second dielectric layer
142...第二開口142. . . Second opening
150...第二電極層150. . . Second electrode layer
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