TW201218951A - Control agent for sigatoka and method for controlling thereof, and use thereof - Google Patents
Control agent for sigatoka and method for controlling thereof, and use thereof Download PDFInfo
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- TW201218951A TW201218951A TW100134701A TW100134701A TW201218951A TW 201218951 A TW201218951 A TW 201218951A TW 100134701 A TW100134701 A TW 100134701A TW 100134701 A TW100134701 A TW 100134701A TW 201218951 A TW201218951 A TW 201218951A
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- Prior art keywords
- leaf spot
- banana
- spot disease
- disease
- leaf
- Prior art date
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- YNWVFADWVLCOPU-MAUPQMMJSA-N uniconazole P Chemical compound C1=NC=NN1/C([C@@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MAUPQMMJSA-N 0.000 description 1
- JARYYMUOCXVXNK-IMTORBKUSA-N validamycin Chemical compound N([C@H]1C[C@@H]([C@H]([C@H](O)[C@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)CO)[C@H]1C=C(CO)[C@H](O)[C@H](O)[C@H]1O JARYYMUOCXVXNK-IMTORBKUSA-N 0.000 description 1
- LESVOLZBIFDZGS-UHFFFAOYSA-N vamidothion Chemical compound CNC(=O)C(C)SCCSP(=O)(OC)OC LESVOLZBIFDZGS-UHFFFAOYSA-N 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- WCJYTPVNMWIZCG-UHFFFAOYSA-N xylylcarb Chemical compound CNC(=O)OC1=CC=C(C)C(C)=C1 WCJYTPVNMWIZCG-UHFFFAOYSA-N 0.000 description 1
- 239000005943 zeta-Cypermethrin Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
- FJBGIXKIXPUXBY-UHFFFAOYSA-N {2-[3-(4-chlorophenyl)propyl]-2,4,4-trimethyl-1,3-oxazolidin-3-yl}(imidazol-1-yl)methanone Chemical compound C1=CN=CN1C(=O)N1C(C)(C)COC1(C)CCCC1=CC=C(Cl)C=C1 FJBGIXKIXPUXBY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
- A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicines Containing Plant Substances (AREA)
- Steroid Compounds (AREA)
Abstract
Description
201218951 六、發明說明: 【發明所屬之技術領域】 本發明為有關琶筹、科植物,尤其為防除發生於香蒸 之葉斑病之以亞賜圃(isoprothi〇lane)為有效成分之葉: 病防除劑及其防除方法及其使用。 【先前技術】 屬於芭焦科芭蕉屬之植物,尤其香蕉為食用果實之 品種群之總稱,而指其果實而t,該植物主要栽谇於中 國、臺灣等之東亞;菲律賓、印尼、泰國、越南;之東 南亞;印度等之西亞;巴西、厄瓜多爾、哥斯大黎加、 墨西哥、瓜地馬拉、哥倫比亞、秘魯等之中南美;坦桑 尼亞、剛果、烏干達、南非等之非洲,也施行大規模農 業栽培而整年栽培。於這些各國栽培,所收成之香蕉乃 向世界各地輸出。 ' 於香蕉栽培,包括莖部之根部在地下,於地上部高 伸出如莖之部分(葉鞘部)乃稱偽莖,實際上葉鞘重疊^ 層,由偽莖之前端大伸出長楕圓形之葉(葉身),更由偽 莖之先端伸出果軸(pedunele),於其前端形成包括果指 (finger)、果房(utricie)之全房(bunch),於全房生育香萑 香焦之收成後’此偽莖部(親株)乃於地上部1〜2m前後之 處切斷。於其時將由地下之根部新出現之新偽莖部(子株) 同樣地繁殖、或將新偽莖部(子株)分株繁殖,來反覆香 蕉之收成。於香蕉之栽培,將葉(機能葉)殘留幾片頗為 重要’由隶後葉之抽出(開花前)至收成有3個月,故^ 於開花期必須將機能葉至少殘留丨2〜丨3片左右之必要 -4 - 201218951 若機能葉之片數為不充分而不能期待高品質之香焦之收 成時,於栽培途中其株乃被採伐。 就香蕉栽培之主要病害而言有葉斑病,有黃色之黃 葉斑病(Yellow Sigatoka)及黑色之黑葉斑病(BUck Sigatoka)。黃葉斑病為起因於香舊生球腔菌 (Mycosphaerella musicola)、黑葉斑病為起因於斐濟球腔 菌(Mycosphaerella fijiensis)之病害’尤其黑葉斑病為發 生於高溫多濕時,使香蕉之葉變成黑色且阻礙光合成而 使收成量減半之病害。葉斑病之潜伏期間為3週至2個 月,其後,罹患之香蕉之初期病徵為於由頂葉起4〜5片 下之古葉之葉背出現小斑點,不久沿葉脈產生黃色之條 斑,逐漸地病斑擴大而變成暗褐色。若被害加重,則幾 乎所有之葉枯死而下垂,只留下中心葉之1〜2片。這些 病害之防除為由監視香蔑之葉部開始,依感染之最幼葉 之位置與感染程度來判斷,有感染擴大疑慮之葉全部切 除。 一旦確認葉斑病發生,則多用猛辞乃浦(Mancozeb) 等有機硫系殺菌劑、四氣二氰苯(Chlorothalonil)等有機 氯系殺菌劑、嘧霉胺(Pirimethanil)等嘧啶系殺菌劑、三 得芬(Tridemorph)、芬普福(denpropimorf)等嗎啉系殺菌 劑、待克利(difenoconazole)、比多農(Bitertanol)、普克 利(Propiconazole)、氟環嗤(Epoxiconazole)等三唾系殺菌 齊J、吼嗅缝菌醋(Pyraclostrobin)、〇密菌醋(azoxystrobin) 等之曱氧基丙烯酸酯系(s t r 〇 b i 1 u r i η)殺菌劑,這些殺菌劑 乃以10曰至20曰之間隔散布數種。 -5- .201218951 本發明之葉斑病防除劑之有效成分化合物之亞賜圃 為以1,3-二硫戊壞-2-亞丙二酸二異丙g旨(diiS0pr0pyi 1,3-dithiolan-2-ylidenemalonate)所表示之化合物,作為 稻熱病防除劑以「富士一」之商品名販賣,為公知之化 合物(參照例如非專利文獻1)。但於非專利文獻1未記載 也無暗示亞賜圃可作為發生於芭蕉科植物(尤其香焦)之 葉斑病防除劑之使用,長期作為稻熱病防除劑使用之亞 賜圃’未曾嘗試作為香蕉葉斑病防除之使用。此於殺菌 劑領域,依對象作物、對象病害不同而有效藥劑相異, 發現有市場性之效果須要過度之試行錯誤之故。 先前技術文獻 非專利文獻 非專利文獻 1 The Pesticide Manual 14th Edition (British Crop Production Council) 【發明内容】 (發明欲解決之課題) 如上所述,葉斑病之防除對香蕉栽培雖為最重要課 題,但依先前技術因須多次藥劑處理,故其勞力頗大, 更因耐藥性菌之出現使葉斑病之防除更困難。故殷求可 減低處理藥劑量而環境負荷少之新穎葉斑病防除劑及 力之防除方法。 (解決課題之手段) 本發明者為解決上述課題反覆致201218951 VI. Description of the Invention: [Technical Field to Which the Invention Is Applicable] The present invention relates to a plant which is an active ingredient of the plant, especially for controlling leaf spot caused by the steaming of leaf spot disease: isoprothi〇lane: Disease control agent and its control method and use thereof. [Prior Art] A plant belonging to the genus Babaco, especially the banana, which is the general name for the group of edible fruits, and refers to its fruit and t. The plant is mainly planted in East Asia such as China and Taiwan; Philippines, Indonesia, Thailand, Vietnam; Southeast Asia; West Asia such as India; Central and South America such as Brazil, Ecuador, Costa Rica, Mexico, Guatemala, Colombia, Peru; Africa, Tanzania, Congo, Uganda, South Africa, etc. Cultivation in agriculture and cultivation throughout the year. Cultivated in these countries, the harvested bananas are exported to all parts of the world. 'In the cultivation of bananas, the roots of the stems are underground, and the parts of the stems that protrude from the top of the ground (the leaves and sheaths) are called pseudo-stems. In fact, the leaves and sheaths overlap, and the front of the pseudo-stalks protrudes long and round. The leaf of the shape (leaf body) extends from the apex of the pseudostem to the pedunele, forming a whole body including a finger and a utricie at the front end thereof. After the harvest of the scented scented coke, the pseudo-stem part (parent plant) was cut at the front and back of the ground 1 to 2 m. At that time, the new pseudo-stems (sub-strains) newly emerging from the roots of the underground are propagated in the same manner, or the new pseudo-stems (sub-plants) are mutated to reproduce the harvest of the bananas. In the cultivation of bananas, it is quite important to leave a few pieces of leaves (functional leaves) from the leaves of the stalks (before flowering) to the harvest for 3 months, so the functional leaves must remain at least 2~丨3 during the flowering period. Necessary for the film - 4 - 201218951 If the number of functional leaves is insufficient and the high-quality fragrant harvest cannot be expected, the plant will be harvested during the cultivation. There are leaf spot diseases in the main diseases of banana cultivation, yellow yellow leaf spot disease (Yellow Sigatoka) and black black leaf spot disease (BUck Sigatoka). Yellow leaf spot disease is caused by Mycosphaerella musicola and black leaf spot disease is caused by the disease of Mycosphaerella fijiensis. Especially black leaf spot disease occurs when it is hot and humid. The leaves of the banana turn black and hinder the synthesis of light and reduce the amount of harvest by half. The latent period of leaf spot disease is 3 weeks to 2 months. Thereafter, the initial symptom of the banana that is affected is that there are small spots on the back of the leaves of the ancient leaves from 4 to 5 pieces from the parietal lobe, and a yellow strip is formed along the veins soon. Spot, gradually the lesions expand and become dark brown. If the victim is aggravated, almost all the leaves die and sag, leaving only 1 or 2 of the central leaves. The prevention of these diseases is judged by monitoring the leaves of the citron, depending on the location of the youngest leaves and the degree of infection, and all the leaves with the infection expansion are all removed. Once the leaf spot disease is confirmed, an organic sulfur-based fungicide such as Mancozeb, an organic chlorine-based bactericide such as Chlorothalonil, or a pyrimidine-based bactericide such as pyrimethanil is used. Tri- bactericidal agents such as temporane fungicides such as Tridemorph and denpropimorf, difenoconazole, Bitertanol, Propiconon, and Epoxiconazole曱 丙烯酸 〇 〇 〇 〇 az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az az Spread a few kinds. -5- .201218951 The active ingredient of the leaf spot control agent of the present invention is a 1,3-dithiolan-2-malonate diisopropyl g (diiS0pr0pyi 1,3-dithiolan) The compound represented by -2-ylidenemalonate is sold as a rice fever control agent under the trade name of "Fuji", and is a known compound (see, for example, Non-Patent Document 1). However, it is not described in Non-Patent Document 1 and it does not suggest that the use of the leaf spot disease control agent which occurs in the plant of the Musa family (especially the fragrant coke) has long been used as a rice fever control agent. Use of banana leaf spot control. In the field of fungicides, depending on the target crop and the target disease, the effective medicaments are different, and it is found that the market effect requires excessive trial and error. [PRIORITY CLAIM OF THE INVENTION] The Pesticide Manual 14th Edition (British Crop Production Council) [Problems to be Solved by the Invention] As described above, the prevention of leaf spot disease is the most important issue for banana cultivation. However, according to the prior art, it is necessary to treat the drug several times, so the labor is quite large, and it is more difficult to prevent leaf spot disease due to the emergence of drug-resistant bacteria. Therefore, it is necessary to reduce the amount of the novel leaf spot control agent and the force control method which can reduce the amount of the treatment agent and have less environmental load. (Means for Solving the Problem) The present inventors have solved the above problems in order to solve the problem
於完成本發明。 覆致力研究之結果,發 處理香蕉,則可以比先 防除香蕉葉斑病,而終 -6 - 201218951 亦即本發明為有關至少以下之各發明。 (1) 一種葉斑病(Sigatoka)防除劑,係用以防除發生、 芭蕉科植物之葉斑病之葉斑病防除劑,其特徵為含於 亞賜圃為有效成分。 乂 (2) 如(1)項之葉斑病防除劑,其中芭蕉科植物為香 薦。 (3) 如(1)或(2)項之葉斑病防除劑,其中葉斑病乃起 因於香焦生球腔菌(Mycosphaerella musicola)之葉斑病 (4) 如(1)或(2)項之葉斑病防除劑,其中葉斑病乃起 因於斐濟球腔菌(Mycosphaerella fijiensis)之葉斑病。 (5) —種葉斑病之防除方法,係用以防除發生於芭蕉 科植物之葉斑病之葉斑病之防除方法,其特徵在於發生 或預測會發生葉斑病之芭蕉科植物之植物體處理以亞賜 圃為有效成分之藥劑之有效量。 (6) 如(5)項之葉斑病之防除方法,其中芭蕉科植物 香蕉。 (7) 如(5)或(6)項之葉斑病之防除方法,其中處理方 去為於香蕉之葉身部至偽莖部散布或塗布處理、向香蕉 生月之周邊土壤灌注處理、或向香蕉之偽莖部注入處理。 (8) 如(5)或(6)項之葉斑病之防除方法,其中葉斑病 乃起因於香蕉生球腔菌之葉斑病。 (9) 如(5)或(6)項之葉斑病之防除方法,其中葉斑病 乃起因於斐濟球腔菌之葉斑病。 (10) —種香蕉子株之葉斑病之防除方法,其特徵為 用以防除發生於香蕉子偽莖株之葉斑病,於發生或預測 ,201218951 會發生葉斑病之香蕉親偽莖株之* 斑病防除劑之有效量予以% 葉身部至偽莖部,將葉 月又處理 ^、 生育之周邊土壤灌注處理、或η禾或塗布處理、向香蕉 (11) 如(10)項之葉斑在^ °香蕉之偽莖部注入處理。 两之防除方 因於香蕉生球腔菌之葉斑病。’、法’其中葉斑病乃起 (12) 如(10)項之葉斑病 七 之防除方法,1 Λ i 因於斐濟球腔菌之葉斑病。 /、中葉斑病乃起 J、艰圾病之使用 有效成分之藥劑供葉斑病防除 /、係以亞賜圃為 為有效成分之藥劑處理於發士用、其特徵為以亞賜圃 蕉科植物之植物體以防除該病:預測會發生葉斑病之芭 (14)如(13)項之防除葉斑 為香蕉。 届之使用,其中芭蕉科植物 (15) 如(14)項之防除葉斑、虑 ή 病之使用,其中處理方法為 於香焦之葉身部至偽莖部予以埒太 卞以政布或塗布處理、向香萑 生育之周ϋ土壤灌注處理、或向香薦之偽莖部注入處理: (16) 如(U)或(14)項之防除葉斑病之使用其中葉斑 病乃起因於香蕉生球腔菌之葉斑病。 (17)如(13)或(14)項之防除葉斑病之使用,其中葉斑 病乃起因於斐濟球腔菌之葉斑病。 (發明之效果) 依本發明可有效防除發生或預測會發生於琶焦科植 物(尤其香蕉)之葉斑病。將以亞賜圃為有效成分之葉斑 病防除劑之有效量於香蕉之葉身部、偽莖部等散布或塗 布處理、於香蕉生育之周邊土壤灌注處理、或於偽莖部The present invention has been completed. As a result of the research, the banana can be treated with banana leaf spot, and the invention is at least the following inventions. (1) A leaf spot disease (Sigatoka) inhibitor, which is a leaf spot control agent for controlling leaf spot disease of a plant of the family Musa, and is characterized by being contained in Aspirin as an active ingredient.乂 (2) For the leaf spot control agent of (1), the Musa plant is recommended. (3) A leaf spot control agent according to (1) or (2), wherein leaf spot disease is caused by leaf spot disease of Mycosphaerella musicola (4) such as (1) or (2) Leaf spot disease control agent, wherein leaf spot disease is caused by leaf spot disease of Mycosphaerella fijiensis. (5) A method for controlling leaf spot disease, which is a method for controlling leaf spot disease which occurs in leaf spot disease of Musa plants, and is characterized in that plants of the Musa plant which develop or predict leaf spot disease occur The body treats an effective amount of a pharmaceutical agent which has an active ingredient. (6) The method of controlling leaf spot disease according to item (5), wherein the banana family banana. (7) The method for controlling leaf spot disease according to item (5) or (6), wherein the treatment side is to disperse or coat the leaf body part of the banana to the pseudo stem portion, and infuse the soil around the banana birth month, Or inject the treatment into the pseudo stem of the banana. (8) The method for controlling leaf spot disease according to item (5) or (6), wherein leaf spot disease is caused by leaf spot of the bacterium of the genus Banana. (9) A method of controlling leaf spot disease according to item (5) or (6), wherein leaf spot disease is caused by leaf spot of the genus Fibulae of Fiji. (10) A method for controlling leaf spot disease of a banana seed plant, which is characterized in that it is used to prevent leaf spot disease which occurs in a banana leaf pseudo-stem plant, and occurs or predicts that a banana leaf progeny stem plant with leaf spot disease occurs in 201218951 The effective amount of the spot disease control agent is %% to the pseudo-stem part, and the leaf month is treated again, the surrounding soil is infused, or η禾 or coating treatment, and the banana (11) is as in (10) The leaf spot is injected into the pseudo stem of the ^ ° banana. The prevention of the two is due to the leaf spot of the bacterium of the banana. ', Law' where leaf spot disease is caused by (12) leaf leaf spot 7 (10), and 1 Λ i due to leaf spot disease of Fibulae. /, the middle leaf spot disease is the use of the active ingredient of J, the disease of the disease for leaf spot control /, is the use of the drug as the active ingredient of the treatment of the use of the medicinal herbs, characterized by Acacia The plant of the family plant to prevent the disease: it is predicted that leaf spot disease will occur (14), such as (13), the leaf spot is banana. For the use of the plant, the plant of the Musa family (15), such as (14), is used to prevent leaf spot and disease, and the treatment method is to treat the stalk of the scented stalk to the pseudo-stem. Injecting into the soil of the scented scorpion, or injecting it into the pseudo-stem of the fragrant stalk: (16) For the use of leaf spot prevention (U) or (14), the leaf spot is caused by banana Leaf spot disease of the bacterium. (17) The use of leaf spot prevention according to (13) or (14), wherein the leaf spot disease is caused by leaf spot of the genus Fibulae of Fiji. (Effect of the Invention) According to the present invention, leaf spot disease which occurs or is predicted to occur in plants of the genus Corydalis (especially banana) can be effectively prevented. The effective amount of the leaf spot disease control agent which uses Yatson as an active ingredient is spread or coated on the leaf body and pseudo stem of the banana, infused into the surrounding soil of the banana, or in the pseudo stem
S -8 - 201218951 以注射器等注入處理等,更對香蕉葉斑病長期呈示顯著 之防除效果。又於親偽莖部(親株)處理,更對新由地下 之塊莖部長出之新偽莖部(子株)也有防止葉斑病之發病 之效果且本發明之葉斑病防除劑及防除方法及其使 用,因長期繼續防除效果,故可謀圖藥劑之散布次數之 削減,而減低環境負荷之技術。 【實施方式】 (用以貫施發明之形態) 以本發明可使用之亞賜圃為有效成分之防除劑,一 般以「富士 一 > 士 & 」之商標名呈各種劑型市售,可市售劑之 中購入與本發明之使用目的相應劑型之藥劑。例如作為 月欠布塗布之情形,以乳劑、懸浮劑、油劑、水合劑等 較佳右土壌灌注之情形,則以乳劑、懸浮劑、粒劑、 尺&齊丨等較佳,於葉鞘部注入處理之情形,以乳劑、懸 浮劑、水合劑為較佳劑型。 ^於香慧'栽培’一般每公頃栽培1 500根~2000根之香 焦,但處理藥量係較佳為:於散布、塗布處理之情形, 依有 >丈成/刀置以每公頃2〇〇g〜之範圍;土壤灌注之 清开y ’於周邊土壤依有效成分量每1植物體0.05g〜2g之 範圍向偽里部注入處理之情形,每1植物體有效成分 里以0·05g〜2g之範圍。於各處理法之有效性分量比上述 數値更y ,則無充分效果;過多則也發生無法預測藥害 等之疑慮。注入處理之情形的注入部位,若為香蕉之果 貫於成長期或香蕉果實之收成後’則於由殘留之親偽莖 邛(親株)之地表〇·3m〜2m左右之任意處,將所定藥量注 201218951 入即可。以此處理防除於成長中之香黨發生之葉斑病, 且若為收成後,則也可防除其次由塊莖部發出之發生於 新偽莖部(子株)之葉斑病。 上述之處理雖於任何香蕉之生育階段也有效,但欲 得更優異效果,散布處理或灌注處理乃以新植或收成即 後〜3個月以内,注入處理乃以將親偽莖砍下後至約% 曰處理較佳尤其較佳為散布處理或於灌注處理為2個 月以内,於注入處理為2〇曰以内之較早時期處理尤其較 佳。本發明之葉斑病防除劑由於兼備葉斑病罹患前預防 性處理所得之預防效果及罹患後之發病I處理所得之治 療效果,故可於葉斑病發病前施行預防性處理,也可於 發病後施行治療性處理。 更且本發明之葉斑病防除劑及其防除方法及其使 用’可與先前施行之殺蟲劑或殺菌劑之商業用體系處理 組合。與僅商業用體系處理相較,組合係有產生顯著之 效果。就商業用體系處理而言,可為散布、塗布、灌注、 注入處理等’但以散布處理較為—般性,適合本發明之 組合。將本發明之葉斑病防除劑及其防除方法及其使用 與商業用體系處理組合之情形’其順序乃依葉斑病之發 生狀況而更可it宜選#,以先前進行具有長期之防除效 果之本發明之葉斑病防除劑及其防除方法及其使用為較 佳。 就本發明之葉斑病防除劑及其防除方法及其使用對 象之色1科之植物而言,可為例如葛羅米謝'爾(Gr〇s Mlchel)、嘉雲臺(Cavendish)、洞窟嘉雲臺(Dwarf s -10- 201218951S -8 - 201218951 Injecting treatment with a syringe or the like, and showing a significant control effect on banana leaf spot disease for a long time. In addition, it is treated with a pro-pseudo-stem portion (parent strain), and the new pseudo-stem portion (sub-strain) which is newly produced by the underground tuber minister also has the effect of preventing the onset of leaf spot disease, and the leaf spot control agent and the control method of the present invention and Since it is used for a long period of time, it is possible to reduce the environmental impact by reducing the number of times the drug is dispersed. [Embodiment] (In the form of the invention) The control agent which is used as an active ingredient in the present invention is generally commercially available under various trade names under the trade name "Fuji One >&& Among the commercially available agents, the agent of the dosage form corresponding to the purpose of use of the present invention is purchased. For example, in the case of a monthly smear coating, in the case of an emulsion, a suspending agent, an oil agent, a hydrating agent, etc., it is preferred to use an emulsion, a suspending agent, a granule, a ruler, a ampule, etc., in the sheath portion. In the case of injection treatment, emulsions, suspending agents, and hydrating agents are preferred dosage forms. ^ Yu Xianghui 'cultivation' generally cultivates 1,500 to 2,000 scent of incense per hectare, but the amount of treatment is preferably: in the case of spreading and coating treatment, depending on the hectare / knife set per hectare The range of 2〇〇g~; the clearing of soil perfusion y 'in the surrounding soil according to the amount of active ingredients per plant range of 0.05g ~ 2g into the pseudo-living part of the treatment, each plant body active ingredient in 0 · The range of 05g ~ 2g. If the effectiveness component of each treatment method is y more than the above number, there is no sufficient effect; if too much, there is a doubt that the drug cannot be predicted. The injection site in the case of the injection treatment, if the fruit of the banana is in the growth stage or after the harvest of the banana fruit, is determined at any place from the surface of the remaining pro-pseudo-stem stalk (parent plant), about 3m~2m. The dosage is 201218951. In this way, leaf spot disease caused by the growing fragrant party is prevented, and if it is harvested, it can also prevent leaf spot disease which is caused by the tuber part and occurs in the new pseudo-stem (sub-strain). Although the above treatment is effective in the growth stage of any banana, but the effect is better, the spreading treatment or the perfusion treatment is performed within a period of not more than 3 months after the new planting or harvesting, and the injection treatment is to cut off the pro-pseudo-plum. Preferably, the treatment is preferably carried out in a dispersion treatment or within 2 months of the infusion treatment, and is preferably carried out in an earlier period in which the injection treatment is within 2 inches. The leaf spot control agent of the present invention can also be used for preventive treatment before the onset of leaf spot disease, because it has the preventive effect obtained by the prophylactic treatment of the leaf spot disease and the therapeutic effect obtained after the onset of the disease I. Therapeutic treatment is performed after the onset of the disease. Further, the leaf spot control agent of the present invention and the method for controlling the same and its use can be combined with the commercial system treatment of the previously applied insecticide or bactericide. The combination has a significant effect compared to commercial system only treatment. In the case of commercial system treatment, it may be a dispersion, a coating, a perfusion, an injection treatment, etc., but it is more general in the dispersion treatment, and is suitable for the combination of the present invention. The leaf spot disease control agent of the present invention and the method for controlling the same and the use thereof are combined with the treatment of the commercial system. The order is based on the occurrence of leaf spot disease, and it is more desirable to select #, which has a long-term control effect. The leaf spot control agent of the present invention, a method for controlling the same, and the use thereof are preferred. For the leaf spot control agent of the present invention and the method for controlling the same, and the plant of the color of the object of use, for example, GrGs Mlchel, Cavendish, and a cave can be used. Jiayuntai (Dwarf s -10- 201218951
Cavendish)、洞窟支那(Dwarf Chinese)、艾諾(Enano)、 克支拉(Caturra)、巨人嘉雲臺(Giant Cavendish)、克藍艾 諾(Gran Enano)、大耐因(Grande Naine)、威廉混種 (Williams Hybrid)、巴蕾(Valery)、羅勃絲(Robust)、波 友(Poyo)、拉康坦(Lacatan)、蒙特克里斯特(Monte cristo)、波特倫(Bout rond)、普藍天(Plantain)等芭蕉科 植物之香蕉類,但不限於這些芭蕉科植物。尤其較佳為 一般作為食用而栽培之包括巨人嘉雲臺、洞窟嘉雲臺、 嘉雲臺、普藍天、紅香蕉(品種:摩拉多)、蘋果香蕉、猿 香蕉(品種:先尼利他)、島香蕉(栽培於沖繩、夸美大島 等)、大耐因(巨人嘉雲臺之改良種)、齊夫利(Chifle、普 藍天之一種)等之全部香煮類。 又,於本發明之對象芭蕉科植物中,也包括針對耐 除卓劑性基因、殺蟲性害蟲抵抗性基因、抗病原性物質 產生基因、油糧成分改質或含有胺基酸的增強性狀等之 有用性狀施行基因轉換之基因重組體(G Μ Ο)之相同植 物。 於本發明為改善對葉斑病之效果或防除其他病害蟲 之目的,可將有效成分化合物亞賜圃以外之農園藝用殺 菌劑、與農園藝用殺蟲劑、殺蟎劑、殺線蟲劑、生物農 藥等混合使用。如下例示以這些目的而可混合之農園蓺 用殺蟲劑、殺瞒劑、殺線蟲劑或農園藝用殺菌劑之代表 性化合物,但本發明不受這些限定。Cavendish), Dwarf Chinese, Enano, Caturra, Giant Cavendish, Gran Enano, Grande Naine, William Mix (Williams Hybrid), Valery, Robust, Poyo, Lacatan, Monte cristo, Boundron, Blue Sky (Plantain) Bananas of Musa plants, but not limited to these Musa plants. It is especially preferred to be cultivated as a food, including Giant Kayuntai, Cave Jiayuntai, Jiayuntai, Putian Blue, Red Banana (Variety: Morado), Apple Banana, and Banana (Type: Nielly) , all of the island bananas (cultivated in Okinawa, Kami, etc.), Da Nai (the improved species of the giant Jiayuntai), and Qifu (Chifle, one of the blue sky). Further, in the object of the present invention, the Musa plant also includes an agent for the resistance gene, the insecticidal pest resistance gene, the anti-pathogenic substance-generating gene, the oil grain component modification or the amino acid-containing enhancement. Useful traits such as traits perform the same plant of the gene-transformed genetic recombinant (G Μ Ο). In the present invention, in order to improve the effect on leaf spot disease or to control other pests, the active ingredient compound Acacia can be used as a horticultural fungicide, agricultural and horticultural insecticide, acaricide, nematicide. , biological pesticides and other mixed use. Representative compounds of insecticides, acaricides, nematicides, or agricultural and horticultural fungicides which can be mixed for these purposes are exemplified below, but the present invention is not limited thereto.
就農園藝用殺蟲劑、殺蟎劑、殺線蟲劑而言,可例 示如XMC(化學名:3,5-二甲笨基胺基曱酸曱酯)、cPCBS 201218951 (chlorfenson)、阿納寧(acrinathrin)、印揀素 (azadirachtin)、甲基谷硫峨(azinphos-methyl)、亞昆 (acequinocyl)、亞滅培(acetamiprid)、乙酿丙醇 (acetoprole)、歐殺松(acephate)、阿巴汀(abamectin)、阿 雉菌素 B(avermectin-B)、0夫蟲胺(amidoflumet)、三亞滿 (amitraz)、棉鈐威(alanycarb)、得滅克(aldicarb)、弟滅 石風威(aldoxycarb)、 奥爾德林(aldrin) 、 α-硫丹 (alpha-endosulfan)、亞滅寧(alpha-cypermethrin)、阿苯 達 °坐(albendazole)、亞列寧(allethrin)、氣唾填 (isazofos)、°塞嗤石粦(isamidofos)、加福松(isoxathion)、亞 芬松(isofenphos)、異丙威(isoprocarb: MIPC)、害獲滅 (ivermectin) '草甘膦(imicyafos)、益達敍 (imidacloprid)、快咪菊酯(imiprothrin)、因得克 (indoxacarb)、益化利(esfenvalerate)、愛芬克 (ethiofencarb)、愛殺松(ethion)、乙蟲清(ethiprole),依 殺滿(etoxazole)、醚菊醋(ethofenprox)、普伏松 (ethoprophos)、乙嘧硫填(etrimfos)、因滅汀 (emamectin)、因滅 丁苯甲酸醋(emamectin-benzoate)、硫 丹(endosulfan)、炔戊菊 g旨(empenthrin)、歐殺滅 (oxamyl)、氧甲基 '•頓(oxydemeton-methyl)、異亞石風磷 (oxydeprofos: ESP)、丙氧咪唑(oxibendazole)、奥芬達唑 (oxfendazole)、油酸鉀(Potassium oleate)、油酸納(sodium oleate)、加奪松(cadusafos)、培丹(cartap)、加保利 (carbaryl) 、 丁基加保扶(carbosulfan)、加保扶 (carbofuran)、伽瑪賽洛寧(gamma-cyhalothrin)、滅殺威 -12- 201218951 (xylylcarb) 啥裕松(quinalphos)、 烯蟲炔酉旨 (kinoprene)、滅奎猛(chin〇methionat)、除線威 (cloethocarb)、可尼丁 (clothianidin)、克分 (clofentezine)、可芬諾(chrornafenozide)、勉安勃 (chlorantraniliprole) ' 四氯乙構(chl〇rethoxyfos)、殺蟲 脎(chlordimeform)、氯丹(chlordane) _、陶斯松 (chlorpyrifos)、陶斯松-曱基(chl〇rpyrifos-methyl)、克凡 派(chlorphenapyr)、殺蟎酯(chl〇rfenson)、毒蟲畏 (chlorfenvinphos)、克福隆(chl〇rfluazuron)、克氣苯 (chlorobenzilate)、氯笨曱酸酯(chl〇robenzoate)、大克 (dicofol)、蔬果璃(salithion)、氰乃松(cyanophos: CYAP)、汰芬隆(diafenthiuron)、胺線鱗(diamidafos)、氰 蟲 苯 酿 胺 (cyantraniliprole) 、 Θ 赛 滅 寧 (theta-cypermethrin)、除蟎靈(dienochlor)、腈嘧芬 (cyenopyrafen)、二"惡苯填(dioxabenzofos)、笨蟲驗 (diofenolan)、Σ-赛滅寧(sigma-cypermethrin)、除線鱗 (dichlofenthion: ECP)、乙氰菊醋(cycloprothrin)、二氯 松(dichlorvos: DDVP)、二硫松(disulfoton)、達特南 (dinotefuran) ' 賽洛寧(cyhalothrin)、賽齡寧 (cyphenothrin)、賽扶寧(cyfluthrin)、 二福隆(diflubenzuron)、丁 氟瞒酯(cyflumetofen)、 氟蜗四°秦(diflovidazin)、環己錫(cyhexatin)、賽滅寧 (cypermethrin)、曱基毒蟲畏(dimethylvinphos)、大滅松 (dimethoate)、四氟曱喊菊醋(dimefluthrin)、石夕護芬 (silafluofen)、赛滅淨(cyromazine)、綠色殺蟲劑 -13· c 201218951 (spinetoram)、貝易諾殺(spinosad)、螺蟎酯 (spirodiclofen)、螺蟲乙酯(spirotetramat)、螺甲蟎酯 (spiromesifen)、氟蟲胺(suifiurarnid)、曱丙硫磷 (sulprofos)、氟啶蟲胺腈(suifoxan〇r)、z-賽滅寧 (zeta-cypermethrin)、地亞農(diazinon)、 r 福化利 (tau-fluvalinate)、邁隆(dazomet)、噻蟲啉(thiacloprid)、 赛速安(thiamethoxam)、硫敵克(thi〇dicarb)、硫賜安 (thiocyclam)、殺蟲單(thiosultap)、殺蟲單鈉 (thiosultap-sodium)、硫磷嗪(thionazin)、硫滅松 (thiometon)、待乙妥(deet)、地特靈(dieldrin)、四氯美文 松(tetrachlorvinphos)、三氯殺蟎砜(tetradifon)、四甲基 氟菊酯(tetramethylfluthrin)、似蟲菊(ietramethrin)、丁 基嘧啶磷(tebupirimfos)、得芬諾(tebufenozide)、吡蟎胺 (tebufenpyrad)、七氟菊酯(tefluthrin)、得福龍 (teflubenzuron)、内吸磷-S-曱基(demeton-S-methyl)' 亞 培松(temephos)、第滅寧(deltamethrin)、托福松 (terbufos)、滅釘螺(tralopyril)、四漠菊 g旨(tralomethrin)、 四氟苯菊酯(transfluthrin)、°坐对威(triazamate)、三嗤石粦 (triazuron)、水揚菌胺(trichlamide)、三氣松(trichlorphon: DEP)、殺蟲脲(triHumuron)' 唾蟲酿胺(tolfenpyrad)、乃 力松(naled: BRP)、尼古丁殺蟲劑(nithiazine)、尼藤吡藍 (nitenpyram)、諾伐隆(novaluron)、多 氟脲 (noviflumuron)、增絲素(hydroprene)、吡蟎胺 (vaniliprole)、辑滅多(vamidothion)、巴拉松(parathion)、 曱基巴拉松(parathion-methyl)、合芬寧(halfenprox)、鹵 -1 4- 201218951 蟲醯胼(halofenozide)、雙三氟蟲脲(bistrifluron)、殺蟲 雙(bisultap)、愛美松(hydramethylnon)、經丙基澱粉 (hydroxy propyl starcl>)、百克(binapacryl)、聯苯肼酯 (bifenazate)、畢芬寧(bifenthrin)、派滅淨(pymetrozine)、 白克松(pyraclorfos)、丁烯氟蟲腈(pyrafluprole)、必芬松 (pyridafenthion)、畢達本(pyridaben)、啶蟲丙醚 (pyridalyl)、β比三 I 嗤唾(pyrifluquinazon)、丁烯 I 蟲腈 (pyriprole)、百利普芬(pyriproxyfen)、比加普 (pirimicarb)、畢汰芬(Pyrimidifen)、亞特松 (pirimiphos-methyl)、除蟲菊精(pyrethrins)、芬普尼 (fipronil)、芬殺蜗(fenazaquin)、芬滅松(fenamiphos)、 溴蟎醋(bromopropylate)、撲滅松(fenitrothion: MEP)、 苯氧威(fenoxycarb)、苯硫威(fenothiocarb)、苯謎菊醋 (phenothrin)、 丁基滅必蝨(fenobucarb)、繁福松 (fensulfothion)、芬殺松(fenthion: MPP)、赛達松 (phenthoate: PAP)、芬化利(fenvalerate)、芬普蟎 (fenpyroximate)、芬普寧(fenpropathrin)、芬笨達唑 (fenbendazole)、福赛絕(fosthiazate)、覆滅蟎 (formetanate)、丁基癌咬碟(butathiofos)、布芬淨 (buprofezin)、吱綫威(furathiocarb)、普亞列寧 (prallethrin)、扶亞寧(fluacrypyrim)、扶吉胺 (fluazinam)、福隆(fluazuron)、氟烯礙(fluensulfone)、氟 蜗脲(flucycloxuron)、護赛寧(flucythrinate) ' 福化利 (fluvalinate)、。比氟硫填(flupyrazofos)、氟芬鈴 (flufenerim)、氟夺隆(flufeno.xuron)、氟芬嘻For agricultural and horticultural insecticides, acaricides, nematicides, for example, XMC (chemical name: 3,5-dimethylphenyl decyl decanoate), cPCBS 201218951 (chlorfenson), analin (for example) can be exemplified. Acrinathrin), azadirachtin, azinphos-methyl, acequinocyl, acetamiprid, acetoprole, acephate, ar Abamectin, avermectin-B, amidoflumet, amitraz, alanycarb, aldicarb, dynasty (aldoxycarb), aldrin, alpha-endosulfan, alpha-cypermethrin, albendazole, allethrin, gas saliva Isazofos), isamidofos, isoxathion, isofenphos, isoprocarb (MIPC), ivermectin 'glyphos (imicyafos), ida Imidacloprid, imiprothrin, indoxacarb, esfenvalerate, Aifen Ethiofencarb, ethion, ethiprole, etoxazole, ethofenprox, ethoprophos, etrimfos, extinction Ememectin, emamectin-benzoate, endosulfan, ementhrin, oxamyl, oxydemeton-methyl , oxydeprofos (ESP), oxibendazole, oxfendazole, Potassium oleate, sodium oleate, cadusafos, Cartap, carbaryl, carbosulfan, carbofuran, gamma-cyhalothrin, chlorpyrifos-12- 201218951 (xylylcarb) 啥Quinolphos, kinoprene, chin〇methionat, cloethocarb, clothianidin, clofentezine, chrornafenozide , chlorantraniliprole 'chl〇rethoxyfos, insecticide (chlordimeform), chlordane _, chlorpyrifos, chl〇rpyrifos-methyl, chlorphenapyr, chl〇rfenson, chlorfenvinphos , chl〇rfluazuron, chlorobenzilate, chl〇robenzoate, dicofol, salithion, cyanophos (CYAP), Diafenthiuron, diamidafos, cyantraniliprole, theta-cypermethrin, dienochlor, cyenopyrafen, two " evil Dioxabenzofos, diofenolan, sigma-cypermethrin, dichlofenthion (ECP), cycloprothrin, dichlorvos (DDVP), Disulfoton, dinotefuran 'cyhalothrin, cyphenothrin, cyfluthrin, diflubenzuron, cyflumetofen, Fluoric spirulina tetrad (diflovidazin), Cyhexatin, cypermethrin, dimethylvinphos, dimethoate, dimefluthrin, silafluofen, race (cyromazine), green insecticide-13· c 201218951 (spinetoram), spinosad, spirodiclofen, spirotetramat, spiromesifen, flubendiles Amine (suifiurarnid), sulprofos, suifoxan〇r, zeta-cypermethrin, diazinon, r fu-fluvalinate ), dazomet, thiacloprid, thiamethoxam, thi〇dicarb, thiocyclam, thiosultap, insecticidal monosodium ( Thiosultap-sodium), thionazin, thiometon, deet, dieldrin, tetrachlorvinphos, tetradifon, Tetramethylfluthrin, ietramethrin, butyl pyrimidine (teb) Upirimfos), tebufenozide, tebufenpyrad, tefluthrin, teflubenzuron, endogenous phosphorus-S-mercapto (demeton-S-methyl) Temephos, deltamethrin, terfufos, tralopyril, trolomethrin, transfluthrin, triazamate, Triazuron, trichlamide, trichlorphon (DEP), trihummuron (triHumuron), tolfenpyrad, naled: BRP, nicotine Insecticide (nithiazine), nitenpyram, novaluron, noifurumuron, hydroprene, vaniliprole, vamidothion, bar Parathion, parathion-methyl, halfenprox, halogen-1 4- 201218951 hafenofozide, bistrifluron, insecticidal double Bisultap), hydramethylnon, hydroxy propyl starcl> ), binapacryl, bifenazate, bifenthrin, pymetrozine, pyraclorfos, pyrafluprole, pyridafenthion, Pyripaben, pyridalyl, beta-pyrfluquinazon, pyriprole, pyriproxyfen, pirimicarb, tidy Pyrimidifen, pirimiphos-methyl, pyrethrins, fipronil, fenazaquin, fenamiphos, bromopropylate, Fenitrothion (MEP), fenoxycarb, fenothiocarb, phenothrin, fenobucarb, fensulfothion, fenthion : MPP), phenothoate (PAP), fenvalerate, fenpyroximate, fenpropathrin, fenbendazole, fosthiazate, mites (formetanate), butyl cancer bite dish (butathiof Os), buprofezin, furathiocarb, prallethrin, fluacrypyrim, fluazinam, fluazuron, fluensulfone Flufluxuron, flucythrinate 'fluvalinate'. Flupyrazofos, flufenerim, flufeno.xuron, flufenium
S -15- .201218951 (flufenzine)、氟芬普 (flufenoprox)、氟普氧芬 (fluproxyfen)、氟普赛寧(fiubr0Cythrinate)、就苄二酿胺 (flubendiamide)、氟氯苯菊醋(flumethrin)、氣鈴芬 (flurimfen)、普硫美文松(pr〇thi〇fos)、擬除蟲菊醋峻 (protrifenbute)、氟尼胺(fl〇nicamid)、加護松 (propaphos)、歐多(propargite: BPPS)、怖飛松 (profenofos)、丙 I 菊醋(profiuthrin)、安丹(propoxur: PHC)、溴丙酸醋(bromopropylate) 、 β-賽扶寧 (beta-cyfluthrin)、六伏隆(hexaflumuron)、合賽多 (hexythiazox)、庚烯鱗(heptenophos)、百滅寧 (permethrin)、苄氯"塞唑(benclothiaz)、免敵克 (bendiocarb)、免速達(bensultap)、苯蜗特 (benzoximate)、免扶克(benfuracarb)、辛疏構(phoxim)、 裕必松(phosalone)、福賽絕(fosthiazate)、伐線丹 (fosthietan)、 福 賜米松(phosphamidon)、 麟克 (phosphocarb)、益滅松(phosmet: PMP)、渗】陽黴素複合體 (polynactins)、覆滅蠕(formetanate)、福木松 (formothion)、曱拌填(phorate)、機械油(machine oil)、 馬拉硫填(malathion)、倍脈心(milbemycin)、倍脈心 A(milbemycin-A)、密滅 丁(milbemectin)、滅加松 (mecarbam)、倍石泉石粦亞石風(mesulfenfos)、納乃得 (methomyl)、聚乙醛(metaldehyde)、美氟綜 (metaflumizone)、達馬松(methamidophos)、銨美地 (metam-ammonium)、斯美地(metam-sodium)、滅蟲威 (methiocarb)、滅大松(methidathion: DMTP)' 異硫氰酸 -16- 201218951 甲酯 (methylisothiocyanate)、 甲基新癸隨胺 (methylneodecanamide)、曱基巴拉松(methylparathion)、 噁蟲酮(metoxadiazone)、曱氧氣(methoxychlor)、曱氧蟲 醯肼(methoxyfenozide)、甲氧苄氟菊酯(metofluthrin)、 美賜平(methoprene)、曱基碳酸酯(metolcarb)、氣氟醚菊 酯(meperfluthrin)、美文松(mevinphos)、亞素靈 (monocrotophos)、殺螟丹(monosultap)、λ-赛洛寧 (lambda-cyhalothrin)、利阿諾定(ryanodine)、祿芬隆 (lufenuron)、苄呋菊酯(resmethrin)、生物源殺蟲劑 (lepimectin)、魚藤酮(rotenone)、鹽酸左旋咪唑 (levamisol)、氧化芬佈賜(fenbutatin oxide)、酒石酸摩朗 得(morantel tartarate)、曱基溴(Methyl bromide)、氫氧 化三環己基錫(cyhexatin)、氰胺化鈣(Calcium cyanamide)、鈣疏合劑(Calcium polysulfide)、硫 (Sulfur)、及硫酸於驗(nicotine-sulfate)等之農園藝殺蟲 劑、殺瞒劑、殺線蟲劑。 就同樣目的使用之農園藝用殺菌劑而言,可為例如 例示金色制徵素(aureofungin)、氮康唾(azaconazole)、氧 化福美雙殺菌劑(azithiram)、醯基殺真菌劑(acypetacs)、 阿拉酸式苯(acibenzolar)、阿拉酸式苯-S-甲基 (acibenzolar-S-methyl)、亞托敏(azoxystrobin)、防霉靈 (anilazine)、安美速(amisuibrom)、胺基丙基碟酸 (ampropylfos)、三唾并鳴咬(amet〇ctradin)、烯丙醇(allyl alcohol)、阿敵嗎琳(aidimorph)、阿姆巴(amobam)、異。塞 菌胺(isotianil)、異戊酿菌酮(isovaiedi〇ne)、先正達 201218951 (isopyrazam)、種菌唾(ipconazole),依普同(iprodione)、 绳霉威(iprovalicarb)、丙基喜樂松(iprobenfos),依滅列 (imazalil)、克熱淨(iminoctadine)、克熱淨烧苯績酸鹽 (iminoctadine-albesilate) 、 克 熱 淨 三 乙 酸 鹽 (iminoctadine-triacetate)、易胺座(imibenconazole)、烯 效唑(uniconazole)、烯效唑 P(uniconazole-P)、氯唑靈 (echlomezole)、護粒松(edifenphos)、乙環唑 (etaconazole)、噻唑菌胺(ethaboxam),依瑞莫 (ethirimol)、艾天(etem)、乙氧基喧淋(ethoxyquin),依 得利(etridiazole)、嫦肪菌醋(enestroburin),依普座 (epoxiconazole)、毆殺斯(oxadixyl)、嘉保信 (oxycarboxin)、對苯二盼銅(copper-8- quinolinolate)、氧 四環素(oxytetracycline)、經基啥琳銅(c〇pper-oxinate)、 氰霜唑 (oxpoconazole)、 氰霜唑富馬酸鹽 (oxpoconazole-fumarate)、歐索林酸(oxolinic acid)、辛 異噻啉酮(octhilinone)、 呋醯胺(ofurace)、肟醚菌胺 (orysastrobin)、斯美地(metam-sodium)等之土 壤殺菌 劑、嘉賜黴素(kasugamycin)、嗎菌威(carbamorph)、加 普胺(carpropamid)、貝芬替(carbendazim)、嘉保信 (carboxin)、香芹酮(carvone)、喹吖胺(quinazamid)、喹 乙醯醇(quinacetol)、快諾芬(qUin0Xyfen)、滅奎猛 (quinomethionate)、敵菌丹(captafol)、蓋普丹(captan)、 精苯霜靈(kiralaxyl) '喹諾康唑(quinconaz〇ie)、五氯硝 基本(quintozene)、克熱淨(guazatine)、硫雜靈 (cufraneb) ' 福美銅氣(cuprobam)、果綠啶(glyodin)、灰 201218951 徽素(griseofulvin)、甘寶素(climbazole)、曱盼(cresol)、 克收欣甲基(kresoxim-methyl)、乙菌利(chlozolinate)、 克霉 °圭(clotrimazole)、滅痕 〇坐(chlobenthiazone)、雙胺靈 (chloraniformethan)、四氣對醌(chloranil)、四氣喹啉 (chlorquinox)、氯化苦(chloropicrin)、苯并咪唑 (chlorfenazole)、二石肖萘(chlorodinitronaphthalene)、四 氯二氰苯(chlorothalonil)、地茂散(chloroneb)、氰菌胺 (zarilamid)、水楊醯胺基苯(salicylanilide)、賽座滅 (cyazofamid)、焦碳酸二乙 g旨(diethyl pyrocarbonate)、乙 霉威(diethofencarb)、環菌胺(cyclafuramid)、雙氣氰菌 胺(diclocymet)、菌核利(dichlozoline)、苄氣三唑醇 (diclobutrazol)、益發靈(dichlofluanid)、環環醯亞胺 (cycloheximide)、達滅淨(diclomezine)、大克爛 (dicloran)、二氣盼(dichlorophen)、二氯萘 3昆(dichlone)、 雙硫奋(disulfiram)、滅菌填(ditalimfos)、腈硫西昆 (dithianon) 稀。坐醇(diniconazole)、烯 α坐醇 M(diniconazole-M)、鋅乃浦(zineb)、白粉克(dinocap)、 敵菌死(dinocton)、硝辛酯(dinosulfon)、硝丁酯 (dinoterbon)、敵蜗通(dinobuton)、硝戊醋(dinopenton)、 雙硫氧吡啶(dipyrithione)、二苯胺(diphenylamine)、待 克利(difenoconazole)、環 I 菌胺(cyflufenamid)、二氟林 (diflumetorim)、環克座(cyproconazole)、賽普洛 (cyprodinil)、酯菌胺(cyprofuram)等之苯醯胺系化合物、 氰菌靈(cypendazole)、石夕氟》坐(simeconazole)、二曱0^ 盼 (dimethirimol)、達滅芬(dimethomorph)、克絕 201218951 (cymoxanil)、驗菌胺(dimoxystrobin)、甲基溴(methyl bromide) ' 福美辞(ziram)、石夕。塞菌胺(silthiofam)、鏈黴 素(streptomycin)、螺環菌胺(spiroxamine)、戊苯颯 (sultropen)、石夕大烧(sedaxane)、座賽胺(zoxamide)、邁 隆(dazomet)、°塞二唤(thiadiazin)、°塞酿菌胺(tiadinil)、 氟 °塞亞菌胺(thiadifluor)、嗟苯塔唾(thiabendazole)、鈦 氧化物(tioxymid)、硫氯苯亞胺(thiochlorfenphinj)、多保 淨(thiophanate)、多保淨曱基(thiophanate-methyl)、〇塞菌 腈(thicyofen)、克殺蜗(thioqu inox)、滅奎猛 (chinomethionat) ' 噻氟菌胺(thifluzamide)、美福雙 (thiram)、癸鱗錫(decafentin)、四氧硝基苯(tecnazene)、 克枯爛(tecloftalam)、得克胺(tecoram)、四克利 (tetraconazole)、咪菌威(debacarb)、脫氫乙酸 (dehydroacetic acid)、得克利(tebuconazole)、異 丁基乙 氧喹啉(tebufloquin)、多地辛(dodicin)、多果定(dodine)、 十二基苯磺酸雙乙二胺銅錯鹽(Π)、(DBEDC)、嗎菌靈 (dodemorph)、肼菌酮(drazoxolon)、三唑醇 (triadimenol)、三泰芬(triadimefon) 、 丁基三《坐 (triazbutil)、咪唑嗪(triazoxide)、威菌磷(tri amiphos)、 喷 菌醇(triarimol)、水楊菌胺(trichlamide)、三赛唾 (tricyclazole)、滅菌唑(triticonazole)、三得芬 (tridemorph)、二丁基氧化錫(tributyltin oxide)、赛福座 (triflumizole)、二乾敏(trifi〇XyStr〇bin)、赛福寧 (triforine)、曱基益發靈(t〇iyifiuanid)、脫克松曱基 (tolclofos-methyl)、納他徽素(natamyCjn)、代森鈉S -15- .201218951 (flufenzine), flufenoprox, fluproxyfen, fiubr0Cythrinate, flubendiamide, flumethrin , flurimfen, pr〇thi〇fos, pyrethenbute, flunizanid, propaphos, propargite: BPPS), profenofos, profiuthrin, propoxur: PHC, bromopropylate, beta-cyfluthrin, hexaflumuron Hexythiazox, heptenophos, permethrin, benzyl chloride "benbugiaz, bendiocarb, bensultap, benzoximate ), benfuracarb, phoxim, phosalone, fosthiazate, fosthietan, phosphamidon, phosphocarb, Phosmet: PMP, osmotic, polynactins, and mites Ormetanate), formothion, phorate, machine oil, malathion, milbemycin, milbemycin-A, dense Milbemectin, mecarbam, mesulfenfos, methomyl, metaldehyde, metaflumizone, methamidophos ),metam-ammonium, metam-sodium,methiocarb,methasantion (DMTP)' isothiocyanate-16- 201218951 methyl ester (methylisothiocyanate), A Methylneodecanamide, methylparathion, metoxadiazone, methoxychlor, methoxyfenozide, metofluthrin, Metoprene, metolcarb, meperfluthrin, mevinphos, monocrotophos, monosultap, λ-cylonine Lambda-cyhalothrin), ryanodine, Lufenuron, resmethrin, lepimectin, rotenone, levamisol, fenbutatin oxide, tartaric acid Morantel tartarate), Methyl bromide, cyhexatin, calcium cyanamide, Calcium polysulfide, sulfur (Sulfur), and sulfuric acid (nicotine) -sulfate) agricultural and horticultural insecticides, acaricides, nematicides. For the agricultural and horticultural fungicides used for the same purpose, for example, aureofungin, azaconazole, azithiram, acypetacs, Acibenzolar, acibenzolar-S-methyl, azoxystrobin, anilazine, amisuibrom, aminopropyl disc Acid (ampropylfos), amet〇ctradin, allyl alcohol, aidimorph, ambaam, and different. Isopronil, isovaiedi〇ne, Syngenta 201218951 (isopyrazam), ipconazole, iprodione, iprovalicarb, propyl chelsone (iprobenfos), imazalil, iminoctadine, iminoctadine-albesilate, iminoctadine-triacetate, imibenconazole , uniconazole, uniconazole-P, echlomezole, edifenphos, etaconazole, ethaboxam, erimomo Ethirimol), etem, ethoxyquin, etridiazole, enestroburin, epoxiconazole, oxadixyl, jiabaoxin Oxycarboxin), copper-8- quinolinolate, oxytetracycline, c〇pper-oxinate, oxpoconazole, cyansulfazole fumarate Oxpoconazole-fumarate), oxolinic acid , soil bactericides such as octhilinone, ofurace, oressastrobin, metam-sodium, kasugamycin, and carbendazim (carbamorph), carpropamid, carbendazim, carboxin, carvone, quinazamid, quinacetol, quinolfene (qUin0Xyfen) ), quinomethionate, captafol, captan, kiralaxyl 'quinoconazole (quinconaz〇ie), pentachloronitrogen (quintozene), gram Guazatine, cufraneb 'cuprobam, glyodin, ash 201218951 griseofulvin, climbbazole, cresol, kexinxin Kresoxim-methyl, chlozolinate, clottrimazole, chlobenthiazone, chloraniformethan, chloranil, tetrakiline quinoline Chlorquinox), chloropicrin, benzimidazole (chl Orfenazole), chlorodinitronaphthalene, chlorothalonil, chloroneb, zarilamid, salicylanilide, cyazofamid , diethyl pyrocarbonate, diethofencarb, cyclafuramid, dilococymet, dichlozoline, diclobutrazol , dichlofluanid, cycloheximide, diclomezine, dicloran, dichlorophen, dicholium, disulfide Disulfiram), ditalimfos, dithianon dilute. Diniconazole, diniconazole-M, zineb, dinocap, dinocton, dinosulfon, dinotorbon , dinobuton, dinopenton, dipyrithione, diphenylamine, difenoconazole, cyflufenamid, diflumetorim, Phenylamine-based compounds such as cyproconazole, cyprodinil, cyprofuram, cypendazole, simeconazole, and simeconazole Dimethirimol), dimethomorph, seduce 201218951 (cymoxanil), dimoxystrobin, methyl bromide 'ziram', shixi. Silthiofam, streptomycin, spiroxamine, sultropen, sedaxane, zoxamide, dazome, °thiadiazin, tiadinil, thiadifluor, thiabendazole, tioxymid, thiochlorfenphinj , thiophanate, thiophanate-methyl, thicyofen, thioqu inox, chinomethionat 'thifluzamide, Thiram, decafentin, tecnazene, tecloftalam, tecoram, tetraconazole, debacarb, Dehydroacetic acid, tebuconazole, tebufloquin, dodicin, dodine, dodecyl benzene sulfonate False salt (Π), (DBEDC), dodemorph, drazoxolon, Triadimenol, triadimefon, butyl tri"triazbutil, triazoxide, tri amiphos, triarimol, trichlamide ), tricyclazole, triticonazole, tridemorph, tributyltin oxide, triflumizole, trifi〇XyStr〇bin, Triforine, 〇基益发灵 (t〇iyifiuanid), tolclofos-methyl, natamyCjn, dexamethasone
S -20- 201218951 (nabam)、醜菌醋異丙基(nitrothal-isopropyl)、石肖基苯乙 烯(nitrostyrene)、尼瑞莫(nuarimol)、壬基酚磺酸銅 (copper壬基酴項酸)、丙烯酸啥琳酿(halacrinate)、維利 徵素(validamycin)、維利芬(vaiifenaiate)、harpin 蛋白 (harpin protein)、丙硫菌唑(bixafen)、啶氧菌酯 (picoxystrobin)、吡苯醯胺(picobenzamide)、硫氣酚 (bithionol)、比多農(bitertanol)、經基異 °惡 α坐 (hydroxyisoxazole) 、 經 基異0惡0坐在甲 (hydroisoxazole-potassium)、百克(binapacryl)、聯苯 (biphenyl)、粉病靈(piperalin)、殺紋寧(hymexazol)、。坐 菌酯(pyraoxystrobin)、吡喃靈(pyracarbolid)、吡唑醚菌 酯(pyraclostrobin)、吡菌磷(pyraz0phos)、唑胺菌酯 (pyrametostrobin)、芳基苯基酮(pyri〇fenone)、啶菌腈 (pyridinitril)、比芬諾(pyrifenox)、吡啶苯胺基甲酸酯 (pyribencarb) ' 派美尼(pyrimethanil)、氯甲氧0比咬 (pyroxychlor)、 氯 0比 呋 趟(pyroxyfur) 百 快 隆 (pyroqui Ion)、 免 克 寧( vinclozolin)、 噁 ojf 菌 嗣 (famoxadone)、 咪 菌 腈 (fenapanil)、 咪 σφ· 菌 (fenamidone)、 敵 績 鈉 (fenaminosulf) 芬 瑞 莫 (fenarimol)、種衣酯(fenitropan)、氰菌胺(fenoxanil)、°密 菌腙(ferimzone)、福美鐵(ferbam)、三苯錫(fentin)、拌 種咯(fenpiclonil)、胺苯吡菌酮(fenpyrazamine)、氰苯唑 (fenbuconazole)、曱呋醯胺(fenfuram)、苯銹啶 (fenpropidin)、芬普福(fenpropimorph)、環酿菌胺 (fenhexamid)、苯酞(phthalide)、丁疏啶(buthiobate)、丁 -2 1- s 201218951 胺(butylamine)、布瑞莫(bupirimate)、麥穗寧 (fuberidazole)、保米黴素 S(blasticidin-S)、福拉比 (furametpyr)、呋霜靈(furalaxyl)、扶亞寧(fluacrypyrim)、 扶吉胺(fluazinam)、氟 〇密菌酿(fluoxastrobin)、氟^ 三0坐 (fluotrimazole)、氟吡菌胺(fiUOpic〇iide)、氟吡菌醯胺 (fluopyram)、氟醯亞胺(fiuor〇imide)、二甲呋醯胺 (furcarbanil)、氟 °惡。比略酿胺(fiuxapyroxad)、氟啥諾康 唑(fluquinconazole)、氟康唑(furconazole)、氟康唑順 (furconazole-cis)、咯菌腈(fiudi〇x〇nil)、氟矽唑 (flusilazole)、敦硫滅(flusulfamide)、福吉寧(flutianil)、 福多寧(flutolanil)、護汰芬(fiutriafol)、糠酸(furfural)、 拌種胺(furmecyclox)、氟酰菌胺(fiuinetover)、氟嗎啉 (flumorph)、丙氧啥琳(proquinazid)、撲克拉 (prochloraz) ' 撲滅寧(procymidone)、胺丙威 (prothiocarb)、丙硫菌 η坐(pr〇thi〇conazole)、普拔克 (propamocarb)、普克利(pr0piC0naz0ie)、甲基辞乃浦 (propineb) 、 °夫甲硫菌靈(fur0phanate)、撲殺熱 (probenazole)、>臭克座(bromuconazole)、六氣 丁二稀 (hexachlorobutadiene)、菲克利(hexaconazole)、六硫苯 (hexylthiofos)、笨并。惡 α塞嗪(bethoxazin)、苯霜靈 (benalaxyl)、苯霜靈 M(benalaxyl-M)、麥錄靈 (benodanil)、免賴得(benomyl)、彼扶座(pefurazoate)、 酉昆將月示(benquinox)、平克座(penconaz〇ie)、抑菌琳 (benzamorf)、賓克隆(pency curon)、 苯甲經將酸 (benzohydroxamic acid)、苯萎隆(bentaluron) ' 苯噻清S -20- 201218951 (nabam), nitrothal-isopropyl, nitrostyrene, nuarimol, copper nonylphenol sulfonate (copper sulfhydryl acid), Halacrinate, validamycin, vaiifenaiate, harpin protein, bixafen, picoxystrobin, pyridoxamine (picobenzamide), bithionol, bitertanol, hydroxyisoxazole, hydroisoxazole-potassium, binapacryl, Biphenyl, piperalin, hymexazol. Pyraoxystrobin, pyracarbolid, pyraclostrobin, pyraz0phos, pyrametostrobin, pyripenone, pyridine Pyridinitril, pyrifenox, pyripencarb 'pyrimethanil', pyroxychlor, pyroxyfur Pyroqui Ion, vinclozolin, famoxadone, fenapanil, fenamidone, fenaminosulf, fenarimol, species Fenitropan, fenoxanil, ferimzone, ferbam, fentin, fenpiclonil, fenpyrazamine, Fenbuconazole, fenfuram, fenpropidin, fenpropimorph, fenhexamid, phthalide, buthiobate, Ding-2 1- s 201218951 Amine (butylamine), cloth Bupirimate, fuberidazole, blasticidin-S, furametpyr, furalaxyl, fluacrypyrim, fluazinam , fluoxastrobin, fluotrimazole, fiUOpic〇iide, fluopyram, fiuor〇imide, dimethyl Furanamide (furcarbanil), fluorine ° evil. Fiuxapyroxad, fluquinconazole, furconazole, furconazole-cis, fiudix x〇nil, flusilazole ), flusulfamide, flutianil, flutolanil, fiutriafol, furfural, furmecyclox, fiuinetover, Flumorph, proquinazid, prochloraz 'procymidone, prothiocarb, prothiocarb, pr〇thi〇conazole, pupp Propamocarb, pr0piC0naz0ie, propineb, fur0phanate, probenazole, >bromuconazole, hexahydrate Hexachlorobutadiene), hexaconazole, hexylthiofos, stupid. Bethoxazin, benalaxyl, benalaxyl-M, benodanil, benomyl, pefurazoate, 酉昆Benquinox, penconaz〇ie, benzamorf, pency curon, benzohydroxamic acid, bentaluron' benzothiazepine
S -22- .201218951 (benthi azole) 、 苯 噻 菌 胺 -異 丙 基 (benthiavalicarb-isopropyl)、吡噻菌胺(penthiopyrad) ' 戊苯°比菌胺(penflufen)、白克列(boscalid)、氣痕填 (phosdiphen)、乙膦酸(fosetyl)、乙膦酸鋁(fosetyl-A1)、 保粒黴素(polyoxins)、保粒黴素(polyoxorim)、代森福美 鋅(polycarbamate)、滅菌丹(folpet)、曱 醛 (formaldehyde)、機械油(machine oil)、代森猛(maneb)、 猛鋅乃浦(mancozeb)、曼普胺(mandipropamid)、甲菌利 (myclozolin)、邁克尼(myclobutanil)、米多霉素 (mildiomycin) ' 代森環(milneb)、苯并威(mecarbinzid) ' 確菌威(methasulfocarb)、間氣敵菌酮(metazoxolon)、威 百故(metam)、威百故納鹽(metam-sodium)、滅達樂 (metalaxyl)、滅達樂 M(metalaxyl-M)、免得爛(metiram)、 異琉氰酸曱酉旨(methyl isothiocyanate)、甲基白粉克 (mepthyldinocap)、滅特座(metconazole)、噻菌胺 (metsulfovax)、吱菌胺(methfuroxam)、苯氧菌胺 (metominostrobin)、滅芬農(metrafenone)、滅派林 (mepanipyrim)、精甲霜靈(mefenoxam)、敵瞒普 (meptyldinocap)、滅普寧(mepronil)、滅錢靈(mebenil)、 蛾化曱基(iodomethane)、口比咪。坐(rabenzazole)、氣化苄 烧銨(benzalkonium chloride)、驗性氯化銅(basic copper chloride)、驗性硫酸銅(basic copper sulfate)、金屬銀 (silver)等之無機殺菌劑,次亞氯酸納(sodium hypochlorite)、氫氧化銅(cupric hydroxide)、水合硫劑 (wettable sulfur)、弼硫合劑(calcium polysulfide)、碳酸 -23- 201218951 氫鉀(potassium hydrogen carbonate)、碳酸氫鈉(sodium hydrogen carbonate)、無機硫(sulfur)、無水硫酸銅(copper sulfate anhydride) 、 有 機 錄 (nickel dimethyldithiocarbamate)、有機銅(oxine copper)等之銅 系化合物,硫酸鋅(zinc sulfate)、硫酸銅五水鹽(copper sulfate);等之農園藝用殺菌劑。 (實施例) 以下例示本發明之代表性試驗例,但本發明不受這 些限定。 試驗例1.依亞賜圃之散布處理之香蕉葉斑病防除試驗 (散布處理區) 將亞賜圃40%乳劑2L以水稀釋為100倍,將依每公 頃相當於200L(按有效成分量為800g/ha)之該藥液於新 植栽培之香蕉(植物高1 m,品種:齊夫利(Chifle,普藍天 之一種))之葉身部均勻地散布1次。散布處理後,按2、 9、16、23、30、37、44、51、58日調查各株之機能葉 之片數’算出每株之機能葉之片數。結果如第1表。 試驗例2.依亞賜圃之灌注處理之香蕉葉斑病防除試驗 (灌注處理區) 將亞賜圃40%乳劑2L以水稀釋為8〇〇倍,依每株 1L(按有效成分量為〇 5g)將該藥液於香蕉(植物高 品種:齊夫利(Chifie ’普藍天之一種))之株周邊土壞表面 予以灌注處理。灌注處理後,與試驗例i同樣算出每株 之機能葉之片數。結果如第1表。 201218951 试驗例3.依亞賜圃之注入處理之香蕉葉斑病防除試驗 (注入處理區) 將亞賜圃40%乳劑2L以水稀釋為2倍,用注射器於 香蕉(植物高:1.5m,品種:齊夫利(Chifle,普藍天之一種)) 收成後之親偽莖之地上部1 m左右之處,注入處理 2.5mL(知有效成分量為〇 4g)。注入處理之效果判定乃於 由親偽莖部之根部新出之子偽莖部之每株之機能葉之片 數,與試驗例1同樣算出來評價。結果如第丨表。 比較試驗例1.依商業用體系處理之香蕉葉斑病防除試 驗(商業用體系處理區) 於試驗開始7曰及14曰後,將四氯二氰苯 (Chlorothalonyl)72%流動劑〇 5]L以水稀釋為4〇〇倍,依 每公頃相當於200L(按有效成分量為36〇g/ha)之該藥 液’於香蕉(植物咼:1m,品種:齊夫利(Chifle,普藍天之 一種))之葉身部均勻地散布。21日後,將三得芬 (Tridem0rf)86%油劑 0.4L 及吡唑醚菌酯 (PyraCl〇str〇bin)25%乳劑〇.4L以水稀釋為5〇〇倍,依每 公頃相當於200L (按三得芬之有效成分量為344g/ha,按 0比。坐縫菌酯之有效成分量為1 〇〇g/ha)之該藥液於葉身 部均勻地散布。更於31曰、38曰、45曰及53曰後,將 四氣二氰苯7 2 %流動劑1.5 L以水稀釋為1 3 3倍,將相當 於母公頃200L (按有效成分量為i〇〇8g/ha)之該藥液,於 葉身部均勻地散布。與試驗例1同樣於所定調查日算出 每株之機能葉之片數。結果如第2表。 201218951 又於試驗例1〜3及比較試驗例1之全部之處理區及 無處理區之香蕉葉斑病為自然發生,雖以黑葉斑病為中 心,但與黄葉斑病混合而發生。試驗規模於全部之處理 區為香蕉80株。因於本試驗至開花期有40日以上,故 機能葉只要有8片以上,則對香蕉之生育無障害,可評 價充分防除葉斑病。 第1表於各處理後日數中機能葉之片數/株 處理區 處理日 2 9 16 23 30 37 44 51 58 試驗例1 散布處理區 0 10.0 11.4 11.9 11,9 10.1 9.4 8.4 8.1 8.4 試驗例2 灌注處理區 0 10.1 11.7 12.1 12.9 9.9 9.5 8.9 9.0 8.8 試驗例3 注入處理區 0 10.0 11.7 11.9 12.1 10.1 9.4 8.9 8.4 8.4 比較試驗例1 商業用體系處理區 7、14、21、31、38 、45、53 9.6 10.3 10.7. 10.2 8.5 8.7 7·7 8.1 8.9 無處理區 - 8.8 9.2 9.8 8.2 7.8 因多發生而不能繼續評價 由第1表之結果,與以1次藥劑處理之無處理區相 較,於亞賜圃之散布處理區、灌注處理區或注入處理區 係長期抑制香蕉葉斑病之發病及進展,且機能葉為至處 理5 8日後維持8片以上,呈示充分的葉斑病防除效果。 於全部之處理方法中,亞賜圃之1次處理係顯示與將四 氣二氰苯、三得芬及吡唑醚菌酯之3種藥劑散布7次處 理之商業用體系處理區同等以上之效果。亦即,與先前 技術之商業用體系處理相較,以本發明之亞賜圃為有效 成分之葉斑病防除劑及其防除方法及其使用可謀圖藥劑 處理次數及藥劑量之減低,及得知可奏效解決當初課題 之優異效果。S -22- .201218951 (benthi azole), benthiavalicarb-isopropyl, penthiopyrad 'penflufen, boscalid, Phosdiphen, fosetyl, fosetyl-A1, polyoxins, polyoxorim, polycarbamate, sterilized Dan (folpet), furfural, formoil, machine oil, maneb, mancozeb, mandipropamid, myclozolin, myclobutanil ), mildiomycin 'milneb', mecarbinzid 'methasulfocarb, metazoxolon, metam, meta-existence Metam-sodium, metalaxyl, metalaxyl-M, metiram, methyl isothiocyanate, mepthyldinocap , metconazole, metsulfovax, methfuroxam, benzene Metominostrobin, metrafenone, mepanipyrim, mefenoxam, meptyldinocap, mepronil, mebenil, moth Iodomethane, mouth than microphone. Inorganic fungicide such as rabenzazole, benzalkonium chloride, basic copper chloride, basic copper sulfate, silver, etc., hypochlorous Sodium hypochlorite, cupric hydroxide, wettable sulfur, calcium polysulfide, carbonic acid-23- 201218951 potassium hydrogen carbonate, sodium hydrogen carbonate Carbonate, copper sulphate, copper dimethyldithiocarbamate, oxine copper, etc., zinc sulfate, copper sulfate pentahydrate Copper sulfate); (Examples) Representative test examples of the present invention are exemplified below, but the present invention is not limited thereto. Test Example 1. Banana leaf spot control test (distribution treatment area) of Asian 圃 圃 散 将 将 亚 亚 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 The liquid of 800 g/ha) was uniformly spread once in the leaf body of the newly planted banana (plant height: 1 m, variety: Chifle). After the spreading treatment, the number of functional leaves of each plant was counted on the 2, 9, 16, 23, 30, 37, 44, 51, and 58 days to calculate the number of functional leaves per plant. The results are shown in Table 1. Test Example 2. Banana leaf spot control test (infusion treatment area) of Inya sputum perfusion treatment 2L of 40% emulsion of Aspirin 40% diluted with water, 1 L per plant (according to the effective ingredient amount) 〇5g) The liquid is perfused into the soil surface of the banana (plant high variety: one of Chifie's). After the perfusion treatment, the number of functional leaves per plant was calculated in the same manner as in Test Example i. The results are shown in Table 1. 201218951 Test Example 3. Banana leaf spot control test (injection treatment area) of Inya 圃 注入 将 亚 亚 亚 圃 40% emulsion 4L diluted 2 times with water, with a syringe on banana (plant height: 1.5m , Variety: Chifle (Chifle, one of the blue sky)) After the harvest of the pro-pseudo stems about 1 m above the ground, injection treatment 2.5mL (the amount of active ingredient is 〇 4g). The effect of the injection treatment was judged by the number of functional leaves of each of the pseudo-stem portions newly formed in the root portion of the pro-pseudo-stem portion, and was calculated and evaluated in the same manner as in Test Example 1. The results are shown in the table. Comparative test example 1. Banana leaf spot control test (commercial system treatment area) treated with commercial system. After 7 and 14 weeks from the start of the test, Chlorothalonyl 72% flow agent 〇 5] L is diluted 4 times with water, equivalent to 200L per hectare (according to the active ingredient amount of 36〇g/ha). This liquid is used in bananas (plant 咼: 1m, variety: Chifle, One of the blue sky)) The leaf body is evenly distributed. After 21 days, Tridem0rf 86% oil 0.4L and pyraclostrobin 25% emulsion 〇.4L diluted 5 times with water, equivalent to 200L per hectare (The amount of the active ingredient of the compound is 344 g/ha, and the ratio is 0. The amount of the active ingredient of the sulphate is 1 〇〇g/ha) is evenly distributed in the leaf body. After 31 曰, 38 曰, 45 曰 and 53 ,, 1.5 L of tetrakis-di-cyanobenzene 7 2 % flow agent is diluted with water to 133 times, which is equivalent to 200 L of mother hectare (according to the effective ingredient amount i The solution of 〇〇8g/ha) was evenly spread on the blade body. In the same manner as in Test Example 1, the number of functional leaves per plant was calculated on the scheduled survey day. The results are shown in Table 2. 201218951 Banana leaf spot disease in all of the treatment areas and the non-treatment areas of Test Examples 1 to 3 and Comparative Test Example 1 occurred naturally, and although it was centered on black leaf spot disease, it was mixed with yellow leaf spot disease. The trial scale was 80 bananas in all treatment areas. Since there are more than 40 days in the flowering period from this test, as long as there are more than 8 functional leaves, there is no obstacle to the birth of bananas, and leaf spot disease can be fully evaluated. Table 1 Number of functional leaves in each day after treatment/Processing area treatment day 2 9 16 23 30 37 44 51 58 Test Example 1 Dispersion treatment area 0 10.0 11.4 11.9 11,9 10.1 9.4 8.4 8.1 8.4 Test Example 2 Infusion treatment area 0 10.1 11.7 12.1 12.9 9.9 9.5 8.9 9.0 8.8 Test example 3 Injection treatment area 0 10.0 11.7 11.9 12.1 10.1 9.4 8.9 8.4 8.4 Comparative test example 1 Commercial system treatment area 7, 14, 21, 31, 38, 45, 53 9.6 10.3 10.7. 10.2 8.5 8.7 7·7 8.1 8.9 No treatment area - 8.8 9.2 9.8 8.2 7.8 The result of the first table cannot be continuously evaluated due to multiple occurrences, as compared with the untreated area treated with one treatment. The spreading treatment area, perfusion treatment area or injection treatment area of Yashen has long-term inhibition of the onset and progression of banana leaf spot disease, and the functional leaves are maintained for more than 8 pieces after treatment for 58 days, showing sufficient leaf spot control effect. Among all the treatment methods, the treatment of the sub-sputum showed that it was equal to or more than the commercial system treatment area in which the three kinds of chemicals of tetrakidhidylbenzene, tripdene and pyraclostrobin were dispersed seven times. effect. That is, compared with the prior art commercial system treatment, the leaf spot control agent having the active ingredient of the present invention and the method for controlling the same, and the use thereof, can reduce the number of treatments and the amount of the drug, and I learned that it can work to solve the excellent results of the original project.
-26- S 201218951 試驗例4.亞賜圃之葉斑病防除試驗(依病害指數之評價) 將亞賜圃4 0 %乳劑1 L與芭蕉空散用添加油(商品 名:SPRAYTEX)7L以水15L稀釋,將每公頃23L(按有 效成分為400g/ha)之該溶液,於香蕉(植物高:i.5m,品種: 大耐因)之葉身部均勻地散布處理。處理為其後施行每週 1次,合計1 〇週10次之藥劑處理,開始認定病害發生 之處理3星期後’更施行每週被害度之調查。調查之方 法為依卞述Gauhi改良之Stover法之基準’調查葉之被 害程度,將其平均作為病害指數算出。結果如第2表。 又,本s式驗中香焦葉斑病為自然發生,雖以黑葉斑 病為中心,但與黄葉斑病混合發生。試驗規模為香蕉9 株。於水試驗只要病害指數為2. 〇以下’則於香蕉之生 育無障審’可評價為充分防除葉斑病。 基率 症狀 〇 無病徵 j 由線之微徵〜病斑10個 2 由病斑11個〜葉面積5%以下之被害 3 葉面積5。/〇〜15%之被害 4 葉面積16%〜33%之被害 5 葉面積34%〜50%之被害 6 葉面積50%以上之被害 第2表病害指數 -27- 201218951 第2表病害指數 查日(週) 3 4 5 6 7 8 9 10 亞賜圃 0 0 0.01 0.04 0.08 0.23 0.32 0.84 無處理 0.06 0.33 0.5 1.01 2.26 2.82 2.97 2.91 由第2表之結果,得知亞賜圃處理區以初期感染或 無法認定斑點症狀之健全葉數較多,至1 0週後,病害指 數降至1以下,但無處理區為由第7週起香蕉之生育發 生障害之病害指數上昇至2以上;與無處理區對比亞賜 圃處理區,得知顯然抑制香焦葉斑病之發病及進展。亦 即,本發明之香蕉葉斑病防除劑及防除方法及其使用, 不只顯然抑制香蕉葉斑病之發病及進展,且可達成抑制 植物體全體受葉斑病被害之效果,其結果為香蕉充分生 育且維持高品質。 【圖式簡單說明】 無。 【主要元件符號說明】 無。 -28- λ-26- S 201218951 Test Example 4. Control of leaf spot disease control by A. sinensis (according to evaluation of disease index) Add 7 ml of emulsion of Ace 圃 40% emulsion and 7 L of plantain oil (trade name: SPRAYTEX) The solution was diluted with 15 L of water, and 23 L of the solution per hectare (400 g/ha of the active ingredient) was uniformly spread on the leaf body of the banana (plant height: i.5 m, variety: Dainin). The treatment was carried out once a week for a total of 1 week and 10 times for the treatment of the drug, and the treatment of the occurrence of the disease was started 3 weeks later. The method of investigation is to investigate the degree of damage of the leaf based on the reference to the Gauth's improved Stover method, and calculate the average as the disease index. The results are shown in Table 2. In addition, in this s test, the fragrant leaf spot disease occurs naturally, although it is centered on black leaf spot disease, but it is mixed with yellow leaf spot disease. The scale of the experiment was 9 bananas. In the water test, as long as the disease index is 2. 〇 below, then the banana breeding can be evaluated as adequate to prevent leaf spot disease. Base rate Symptoms 〇 No symptoms j Micro-signure from the line ~ 10 lesions 2 From the lesions 11 ~ The area of the leaf is less than 5% of the damage 3 Leaf area 5. /〇~15% of the victim 4 Leaf area 16%~33% of the victim 5 Leaf area 34%~50% of the victim 6 Leaf area 50% or more of the victim 2nd disease index -27- 201218951 The second table disease index Day (week) 3 4 5 6 7 8 9 10 圃 圃 0 0 0.01 0.04 0.08 0.23 0.32 0.84 No treatment 0.06 0.33 0.5 1.01 2.26 2.82 2.97 2.91 From the results of the second table, it is known that the Athena treatment area is initially infected. Or the number of healthy leaves that cannot be identified as spot symptoms is high. After 10 weeks, the disease index falls below 1 or less, but the disease-free index of bananas from the 7th week is increased to 2 or more; The treatment area was treated with the Bianjia treatment area, and it was learned that the onset and progression of the leaf spot disease were clearly inhibited. That is, the banana leaf spot control agent and the method for controlling the same according to the present invention and the use thereof not only inhibit the onset and progression of banana leaf spot disease, but also achieve the effect of inhibiting the damage of the leaf spot of the whole plant body, and the result is banana. Fully fertility and maintain high quality. [Simple description of the diagram] None. [Main component symbol description] None. -28- λ
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| JP2022136336A (en) * | 2019-08-21 | 2022-09-16 | 日産化学株式会社 | Method for controlling sigatoka disease |
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