TW201216848A

TW201216848A - Mating disruption agent for sucking pests

Info

Publication number: TW201216848A
Application number: TW100127004A
Authority: TW
Inventors: Kiyomitsu Yoshida; Takao Awazu; Shogo Atsumi
Original assignee: Ishihara Sangyo Kaisha
Priority date: 2010-07-29
Filing date: 2011-07-29
Publication date: 2012-05-01
Also published as: CN103140135B; PH12013500318B1; KR20130141451A; TWI501725B; CN103140135A; PH12013500318A1; WO2012015014A1; KR101801427B1; JP2012046504A; JP5860626B2; MY165281A

Abstract

To provide a mating disruption agent for sucking pests which are major pests in rice cultivation. The inventors of the present invention discovered that the application of flonicamid to sucking pests in rice cultivation disrupted pest mating activity, demonstrating a stable and long-term controlling effect. This completely unexpected effect of disrupting pest mating represents a clear departure from the use of flonicamid as a simple pesticide. The present invention relates to a mating disruption agent for rice-feeding sucking pests which contains flonicamid as an active ingredient, and to a method of disrupting mating of such pests by treating with this mating disruption agent.

Description

201216848 六、發明說明：【發明所屬之技術領域】本發明係有關一種吸汁害蟲之交尾動作干擾劑。【先前技術】 ^ N-氰甲基_4_三氟曱基比啶曱醯胺(通稱氟尼胺(fl〇nicamid)) 係在專利文獻1中以化合物No.丨所記載之化合物。於專利文獻2 中，已記載一種有害生物防治劑組成物，其含有含氟尼胺之吡啶系化合物與各種效力增強成分。【專利文獻】專利文獻1 :歐洲專利第580374號公報專利文獻2 :國際公開專利w〇 2009/128409號公報【發明内容】 (發明所欲解決之課題）心在f作領域巾，被視為主要餘之财害蟲的飛細具高繁殖ϋ懷作引起莫A的危害。尤其褐飛祕於直到收翻之間， =數個世代而紐紐，服猶之魏(hGpperbum)為主要的危:宝所謂魏係因褐麵之吸汁危害所導致的稻枯死及域倒下 ΐ ，對於飛_之防治劑係以新尼古丁系殺蟲劑為主彳近年來，由於急遽觀察到對於新尼古丁系殺蟲劑之感受性類，在稻作領域中，正尋求可以成為新主流之防治劑 (解決課題之手段）的防’本紐0狀储包含褐麵之飛細的防/σ中，與其特徵之生態相關聯而進行研究。月下：if之區域無法過冬。例如在日本，主要於6 。與同樣海外飛來性之白細作-比較， &來之讀相虽的低，於飛來之時點的寄生密度中，不會引起大 201216848 的問題。但疋，飛來後，雌成蟲係經歷4天# 鞘之組織内產卵，於25°C經歷卵期間7 之產卵前期而在稻葉苎為下-世代(第1世代)成蟲。第4 ::、虫'蟲期間14天而兩的短翅型。由於短翅型雌蟲不太成触大夕成為繁殖率度以幾何級峨= 益蟲未對觸之㈣有效，且境及法，著眼於ϊίί來防治褐飛為之危害的方使印不解化的方式來進行等^成蟲產印、使其難以產印及低。便。蟲之下一世代個體數或密度降決該課題，具二藥有效成分之中，氟尼胺解戒係指二完= 如此方式，干作的作用。於所生之㈣未受精㈣不^^雌-之產㈣減少，進-步由防治吸汁害二上:'關藉由使氟尼胺對吸汁害蟲起作用而及干擾吸汁害蟲之交尾树的下一世代個體數降低的方法 (發明之效果） / 。續長期間而動作干擾劑及防治方法能夠達成持清界線，達氣尼胺作為單純之殺有害生物劑之使用劃果。例如，進杆二世代個體數降低的完全未被預期之效月田相處理之情形，於所習用之防治劑中，由於201216848 VI. Description of the Invention: [Technical Field to Be Invented by the Invention] The present invention relates to an interfering action interfering agent for sucking juice pests. [Prior Art] ^ N-Cyanomethyl-4_trifluorodecylpyridiniumamine (commonly known as fluninic acid) is a compound described in Patent Document 1 as Compound No. Patent Document 2 describes a pest control agent composition containing a fluorinated nitrile-containing pyridine compound and various potency enhancing components. [Patent Document 1] Patent Document 1: European Patent No. 580374 Patent Document 2: International Publication No. WO-2009/128409 (Summary of the Invention) (The subject to be solved by the invention) The heart is regarded as a field towel, and is regarded as The main waste of the pests of the flying fines with high reproduction and breeding caused the harm of Mo A. In particular, the secret of brown fly is until the turn-over, = several generations and New Zealand, the hGpperbum is the main danger: the so-called Wei system caused by the harm of the brown-faced juice, and the fall of the field ΐ 对于对于飞飞之之之之飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞飞The prevention and control agent (the means to solve the problem) is studied in the prevention of the 'Norwegian 0-shaped storage containing the brown surface, and the correlation with the ecology of its characteristics. Under the moon: The area of if can't be winter. For example, in Japan, it is mainly at 6. Compared with the white paintings of the same overseas flying nature, the readings from & are relatively low, and the parasitic density at the time of flying does not cause the problem of 201216848. However, after flying, the female adult worms undergo 4 days of scabbard tissue spawning, and at 25 °C, they experience the pre-emergence period of the egg period 7 and the rice leaf mites are the lower-generation (first generation) adults. 4::, the insect's period of 14 days and two short-winged types. Because the short-winged females are not too big, the reproductive rate is geometrically 峨 = beneficial insects are not effective (four), and the law and the law, focusing on ϊίί to prevent brown fly from harming The way to carry out the production of the adult insects makes it difficult to produce and low. Will. The number or density of individuals in the next generation of the worm reduces this problem. Among the active ingredients of the two drugs, the flunitamide solution refers to the second end = the way of doing so. (4) Unfertilized (4) Not ^^ Female--(4) Reduced, and the step-by-step is controlled by the control of sucking juice: 'Offer by letting finnish act on the sucking pests and interfere with the weeding tree of the sucking pests Method for reducing the number of individuals in the next generation (the effect of the invention) / . During the extended period of time, the action interfering agent and the prevention and treatment method can reach a clear boundary line, and the use of gas nicotine as a simple killing agent can be used. For example, the situation in which the number of individuals in the second generation of the rod is reduced is completely unanticipated, and in the case of the control agent used,

S 201216848 爾妓__彳，但至少能下一世2:=_人^應用所謂本發明所揭示的「使害蟲之箱處理之产开）㈣」之疋全未預期的效果’例如，適用於育苗騎通常職望縣分細咖發揮吸汁害^ 【實施方式】 (實施發明之最佳形態）成鹽為舒基·4·三氟甲基_3·喊甲醯胺。氟尼胺有形象類$本毛明中，稻寄生吸汁害蟲可舉例：飛為類、葉禪類'椿飛蝨類可舉例：褐飛蝨、白背飛_孔例：黑尾轉等；椿_可_:盲椿、齡類可舉佳可舉例：飛蝨類。飛蝴類及葉蟬類。更進一步較佳可舉例：褐飛蝨。本發明之防治對象的該吸汁害蟲中，殺蟲劑感受性降低之吸汁害蟲。牛例.對新尼古丁系離子系界面活性劑、面活性劑、陰於本發明中，氟尼胺係與習知農辅助劑摻合，能夠製劑成乳劑、粉劑1=情科目同，與各種洋製劑等之各種形態。此處所謂輔助劑可劑、粒劑、懸增黏劑、安定劑、分散劑、濕潤劑、參·載體、懸浮劑、必要時最好適度添加。載體可分為固體、^東^、消泡劑等，體可舉例：澱粉、砂糖、纖維素粉、環糊二:液體，體，固體載 < π、活性碳、大豆粉、 201216848 小麥粉、稻殼粉、木粉、魚粉、粉乳 ^ Ji ^ ίΐ' tTi'^： ίί J' 矽漆土、白奴、黏土、氧化鋁、氧化 '弗石、性粉末等；液體細可舉例：水；乙醇等之礦物喃等之醚類；煤油、燈油、流動j，—吟烷、四氫呋甲苯、三甲苯，苯、環笨、二 Ϊ乙醋、脂肪酸之甘油酯等之酯類’· ;醋也可以將敦尼胺與該效力增強成分」=^合，以成^之^形， =地製劑後加以混合。於此等製1或二稀釋劑而轉成既定之= 明的方ii I於月箱或水田進^處理。於本發為育苗箱處理。水‘解产：“;章別顯著之效果’期望 m解度的農業有效成分之氟尼胺係藉由依昭二從稻作之根部的藥劑吸取作用，因而能夠有效地:及望育里，點; 物(在明ί有效成分氟尼胺係水溶解度非常高的化合嘴你Μ ·>«且《水浴解度.52〇〇mg/L)。由於育苗箱處理用之藥劑必 Ϊ =長f寺續，尋求控制農業有效成分之炫融擠出，另一方得難侍t f尼胺之水溶解度極高的化合物應祕本使用形態變、Sx、、且成物係於解決起因於該氟尼胺水溶解度之問題上為S 201216848 尔妓__彳, but at least the next generation 2:= _ people ^ apply the so-called "production of pests of the box processing" (four) "all unanticipated effects", for example, apply to The seedling rider usually uses a fine coffee to play the juice. ^ Embodiments (Best form for carrying out the invention) The salt is Shuji·4·trifluoromethyl_3·. Flunidamine has an image class $本毛明, rice parasitic sucking pests can be exemplified: fly for the class, leaf zen class '椿fly 虱 class can be exemplified: brown planthopper, white back fly _ hole case: black tail turn; etc. _ _ : For example, the blind cockroach and the age class can be cited as: Fly butterflies and leafhoppers. Still further preferred is exemplified by brown planthopper. In the sucking pest of the object to be treated of the present invention, the insecticide is reduced in the susceptibility of the insecticide. In the present invention, the new nicotine-based ion-based surfactant, surfactant, and yin are blended with a conventional agricultural adjuvant, and can be formulated into an emulsion, a powder 1 = a love subject, and various Various forms such as foreign preparations. Here, the adjuvant agent, the granule, the suspending agent, the stabilizer, the dispersing agent, the wetting agent, the carrier, the suspending agent, and the like are preferably added as appropriate. The carrier can be divided into solid, ^dong^, antifoaming agent, etc., for example, starch, sugar, cellulose powder, cyclodextrin: liquid, body, solid carrier < π, activated carbon, soybean powder, 201216848 wheat flour , rice husk powder, wood flour, fish meal, powdered milk ^ Ji ^ ΐ t tTi'^: ίί J' 矽 lacquered earth, white slave, clay, alumina, oxidized 'fuss, powder, etc.; liquid fine example: water Ethers such as minerals such as ethanol; esters of kerosene, kerosene, flowing j, decane, tetrahydrofuran, toluene, benzene, cyclostene, diacetone, glycerides of fatty acids, etc. The vinegar can also be combined with the potentiation component of the potency to form a ^ shape, and then mixed. In this case, one or two thinners are converted into a predetermined one, and the square ii I is processed in a moon tank or a paddy field. In this case, it is treated as a nursery box. Water's production: "There is a remarkable effect of the chapter" The active ingredient of the agricultural compound, which is expected to have a solution of m, is absorbed by the drug from the root of rice, and thus can be effectively: ; (In the clear, the active ingredient flunis is very high in solubility, the water is very high in the mouth of your mouth · > « and "water bath solution. 52 〇〇 mg / L." Because the treatment box treatment agent must be Ϊ = long f continuation, seeking to control the melting and extruding of the active ingredients of agriculture, the other side is difficult to wait for the solubility of the compound of tf nicotine. The morphological change, Sx, and the system are used to solve the cause of the fluorine. The problem of the solubility of nitrile water is

S 201216848 g效的形態。針對摻合量為〗至3G重量％，較佳為q 5至25重量 =本發明=使用的氟尼胺的平均粒徑為丨至湖叫，期望為 1至ΙΟΟμπι，進一步較佳為5至5〇μιη。齡騎使賴雜制咖旨，可糊：乙烯·醋酸乙雜共聚物、乙烯-叔碳酸共聚物、苯乙稀-丙稀酸醋、丙稀酸德物、氧化聚乙烯、胺甲酸曰、陆^ ί脂等。水難溶性_期望作成乳劑使用。特別期夹例.共聚物乳劑。乙烯丙晞酸共聚物乳劑，例如，可後^ 等樹脂乳劑不僅能夠糊皮使用，也能夠混合重。摻1，固形物為αι至30重量％，較佳為1至15 土、=於i發明之**體並未予以特別限定，例如，能夠使用黏粉、料π、碳酸約、絹雲母、〜(商品名）、酸性石膏未予以i詹ί石、波來鐵、綠波縷石等之載體。針對摻合量並 2C 而為4g至".8重量％，較佳⑽至心重量％琥蘭納二# ^游’賊添加賴劑。测射舉例：縣聚氧乙烯、燒基苯續酸納、高級醇硫酸酯、院基萘績酸納、乙烯烧騎、聚氧乙烯苯乙烯基苯基啦酸醋、聚氧此僅===聚t稀苯乙烯基苯基碰酸醋。之情形，針對換^旦早獨使用’也月匕夠混合後使用。使用濕潤劑較佳為0J至5&並未予以特別限制’為_至10重量％ ’ 夠利藉:農藥製造中通常所用之製粒法，例如，能法、壓縮紫#^法、轉動製粒法、轉動流動製粒法、流動層製粒製。、’^、，、攪拌混合製粒法、被覆製粒法、打錠法等而調 201216848 例如，均勻混人患、脂乳劑，利用捏和機^、、，^劑及載體後’添加水難溶性樹粒機燥、整粒^_例等擠出製度，能夠添而進—步控.融擠出速於δ亥組成物中，险了製劑中以穩定確保農藥糾^八成》以外，例如在本發明之農藥製粒性等提高之目的，、’=之目的及/紐於進行製粒之際的作為任意成分％要時也能夠含有界面活性劑、輔助㈣於本發明中，必要時能夠混用劑旦成長調整鮮，於此情形T，也顯示進一步優 ίΪίίΠί ’能夠使適用範圍、藥劑處理之時期、防治活性 ίίίϊ佳的方向物改良。還有，I尼胺與其他農業的有效成 1 t 可以於散布時各自混合所製劑之物而使用，也可以將兩者-併丨而使用。例如，調製該組成物之情形，也能夠將說尼胺與其他以外之農藥成分一併製劑。於本發明中，如此方式，也包含混合有效成分而施用之情形。上述其他農藥中之殺蟲劑、殺壁蝨劑、殺線蟲劑或殺土壤害蟲劑之有效成分化合物，亦即，例如殺蟲性化合物(通稱：包含一为申凊中，或試驗碼）係如佈飛松Qjr0fen0f0s)、敵敵畏 (dichlorvos)、芬滅松(fenamiphos)、撲滅松(fenitrothion)、一品松 (EPN)、一口井農(diazinon)、陶斯松(chlorpyrifos)、曱基毒死碑 (chlorpyrifos-methyl)、歐殺松(acephate)、普硫松(prothiofos)、福赛絕(fosthiazate)、加奪松(cadusafos)、乙拌鱗(dislufoton)、加福松 (isoxathion)、異丙胺填(isofenphos)、愛殺松(ethion)、乙氧嘴咬鱗 (etrimfos)、喧硫磷：(quinalphos)、二甲基亞硝胺(dimethylvinphos)、樂果原藥(dimethoate)、硫丙填(sulprofos)、硫滅松(thiometon)、繁米松(vamidothion)、白克松(pyraclofos)、必芬松(pyridaphenthion)、亞特松(pirimiphos-methyl)、丙蟲填(propaphos)、松必爽粉 201216848 (phosalone)、福木松(formothion)、馬拉松(malathion)、殺蟲畏 (tetrachlovinphos)、毒蟲畏(chlorfenvinphos)、殺填晴(cyanophos)、敵百蟲(trichlorfon)、殺撲填(methidathion)、稻豐散(phenthoate)、 ESP、谷速松(azinphos-methyl)、芬殺松（fenthion)、飛達松 (heptenophos)、甲氧氣(methoxychlor)、巴拉松(parathion)、填克 (phosphocarb)、滅賜松（demeton-S-methyl)、亞素靈 (monocrotophos)、達馬松(methamidophos)、一種氰胺雜環化物 (imicyafos)、甲基巴拉松(parathion-methyl)、托福松(terbufos)、福賜米松(phospamidon)、益滅蝨(phosmet)、托福松(phorate)、巴赛松 (phoxim)、三落松(triazophos)之有機填酸酯系化合物；如加保利(carbaryl)、安丹(propoxur)、得滅克(aldicarb)、加保扶(carbofUran)、硫敵克(thiodicarb)、納乃得(methomyl)、歐殺滅 (oxamyl)、乙硫笨威(ethiofencarb)、比加普(pirimicarb)、丁基滅必蟲(fenobucarb)、丁基加保扶(carbosulfan)、免扶克(benfiiracarb)、免敵克(bendiocarb)、線威(fUrathiocab)、異丙威(isoprocarb)、速滅威(metolcarb)、滅殺威(xylylcarb)、XMC、芬硫克(fenotiiiocarb)之甲醯胺系化合物；培丹(cartap)、硫賜安(thiocyclam)、免速達(bensultap)、蟲殺雙 (thiosultap-sodium)、殺蟲單(monosultap)、殺蟲雙(bisultap)、草酸氫硫賜安(thiocyclam hydrogen oxalate)之沙蠶毒素衍生物；如大克蜗(dicofol)、得脫蜗(tetradifon)、硫丹(endosulfan)、得氣蟎(dienochlor)、地特靈(dieldrin)之有機氯系化合物；如芬布賜(fenbutatin oxide)、錫蜗丹(cyhexatin)之有機金屬系化合物；如芬化利（fenvalerate)、百滅寧（permethrin)、賽滅寧 (cypermethrin)、漠氰菊g旨(deltamethrin)、赛洛寧(cyhalothrin)、七氟菊醋(tefluthrin)、菊醋(ethofenprox)、三氟醚菊醋(flufenprox)、氟氯氰菊酯（cyfluthrin)、芬普寧（fenpropathrin)、護赛寧 (flucythrinate)、氟胺氰菊醋印奶也皿化）、乙氰菊g旨(CyCi〇pr〇thrin)、盈洛寧(lambda-cyhalothrin)、除蟲菊精(pyrethrins)、氰戊菊酯 201216848 (esfenvalerate)、胺菊酯(tetramethrin)、苄口夫菊酯(resmethrin)、對氣二苯醚（protrifenbute)、聯苯菊酯（bifenthrin)、六氯氰菊酯 (zeta-cypermethrin)、阿納寧（acrinathrin)、亞滅寧 (alpha-cypermethrin)、亞烈寧（allethrin)、精高效氣氟氰菊酯 (gamma-cyhalothrin)、反式氣氰菊酯(theta-cypermethrin)、福化利 (tau-fluvalinate)、四溴菊酯(tralomethrin)、丙氟菊酯(profluthrin)、高效氯氰菊酯(beta-cypermethrin)、貝他赛扶寧(beta-cyfluthrin)、美特寧（metofluthrin)、酚丁滅寧（phenothrin)、氟氯苯菊酯 (flumethrin)、第滅寧(decamethrin)之除蠢菊精系化合物；如二福隆(diflubenzuron)、克福隆(chlorfluazuron)、氟苯脲 (teflubenzuron)、氟芬隆(flufenoxuron)、殺鈴脲(triflumuron)、六伏隆(hexaflumuron)、祿芬隆(lufenuron)、雙苯氟脲(novaluron)、多氟脲(noviflumuron)、雙三氟蟲脲(bistrifluron)、β定蜱脲(fluazuron)之苯曱醯基脲系化合物；如美賜平(methoprene)、百利賽芬(pyriproxyfen)、苯氧威 (fenoxycarb)、苯蟲醚(diofenolan)的保幼激素之化合物；如畢達本(pyridaben)之噠α井酮系{匕合物；如芬普蜗（fenpyroximate)、芬普尼（fipronil)、°比蜗胺 (tebufenpyrad)、乙蟲清(ethiprole)、唾蟲酿胺(tolfenpyrad)、乙醯蟲腈(acetoprole)、°比口井氣蟲腈(pyrafluprole)、°比咬氟蟲腈(pyriprole) 之》比唾系化合物；如益達胺(imidacloprid)、烯咬蟲胺(nitenpyram)、啶蟲月米 (acetamiprid)、°塞蟲琳(thiacloprid)、赛速安(thiamet:hoxam)、可尼丁 (clothianidin)、吱蟲胺(nidinotefbran)、達特南(dinotefbran)、硝蟲。塞口井(nithiazine)等之新尼古丁；如得芬諾(tebufenozide)、曱氧蟲酬物nethoxyfenozide)、環蟲醯月^(chromafenozide)、氯蟲醯月#(halofenozide)等之耕系化合物；如螺蟎酯(spirodiclofen)等之特窗酸系化合物；如°密蜗酯(fluacrypyrin)等之嗜球果傘素系化合物；如0密蟲胺(flufenerim)等之胺°比咬系化合物； 201216848 二硝系化合物、有機硫化合物、脲系化合物、三p井系化合物、腙系化合物或是其他化合物，可舉例：如布芬淨(buprofezin)、合，多(hexythiazox)、雙甲月米(amitraz)殺蟲月米(chl〇rdimef〇rm)、氟矽翻酉曰(silafluofen)、π坐輯威(txiazamate)、派滅淨(pymetrozine)、畢汰分(pyrimidifen)、克凡派(chlorfenapyr)、因得克(indoxacarb)、亞酉昆蜗(acequinocyl)、依殺蜗(etoxazole)、賽滅淨(cyromazine)、1，3-二氯丙烯（l，3-dichloropropene)、丁醚脲(diafenthiuron)、異噻蟲唑 (benclothiaz)聯本月井自旨(bifenazate)、螺曱蜗@|(spiromesifen)、螺蟲乙酉旨(spirotetramat)、殿蜗多(propargite)、克芬蜗(clofentezine)、氰氟蟲腙(metaflumizone)、3-溴-N-(2-溴-4-氣-6-(1-環丙基乙基胺甲醯基)苯基)-1-(3-氯吡咬-2-基)-1Η·吡唑-5-曱醯胺、3-溴-N-(4j_2-(l-環丙基乙基胺曱醯基)-6·曱基苯基)-1-(3-氯吡啶-2-基)-1H-吡唑-5-曱醯胺、3-溴-N-(2-溴-4-氯-6-(環丙基曱基胺曱醯基)苯基)-1-(3-氯 0比咬-2-基)-1Η-η比啥-5-曱醯胺、氟蟲酿胺(flubendiamide)、丁氣蜗酯（cyflumetofen)、氯蟲醯胺（chlorantraniliprole)、氰蟲醯胺 (cyantraniliprole)、殺蟎劑（cyenopyrafen)、梨氟喹那宗 (pyrifluquinazone)、芬殺蟎(fenazaquin)、磺胺蟎酯(amidoflumet)、氯苯甲酸曱酯（chlorobenzoate)、氟蟲胺(sulfluramid)、愛美松 (hydramethylnon)、聚乙酸(metaldehyde)、HGW-86、AKD-1022、氯嘉雙醢胺(ryanodine)、《定蟲丙醚(pyridalyl)、增效炔鱗(verbutin)、 0塞0坐桂皮腈(thiazolylcinnanonitrile)之化合物等。進一步也能夠與下列混用、併用：如蘇力菌(Bacillus thuringienses)亞種aizawai、蘇力菌（Bacillus thuringienses)亞種 kurstaki、蘇力菌（Bacillus thuringienses)亞種 israelensis、蘇力菌(Bacillus thuringienses)亞種 japonensis、蘇力菌(Bacillus thuringienses)亞種 tenebrionis、蘇力菌 (Bacillusthuringienses)所生成的結晶蛋白毒素、昆蟲病原病毒劑、昆蟲病原線狀菌劑、線蟲病原線狀菌劑等之微生物農藥；壹等勇 (avermectin)、因滅汀苯甲酸鹽(emamectin benzoate)、密滅汀 (milbemectin)、米爾倍霉素(milbemycin)、多殺菌素(spinosad)、害獲滅（ivermectin)、殺蜗菌素（lepimectin)、DE-175、阿巴汀 201216848 (abamectin)、因滅汀(emamectin)、賜諾特(spinetoram)之抗生物質及半合成抗生物質；如印楝素(azadirachtin)、魚藤酮(r〇tenone)之天然物；避蚊胺(deet)之忌避劑等。上述其他農藥中之殺菌劑的有效成分化合物，亦即殺菌性化合物(通稱；包含一部分申請中；或是日本植物防疫協會試驗碼），例如，可舉例：如滅派林(mepanipyrim)、嘧霉胺(pyrimethanil)、賽普獲汰寧(cyprodinil)、β密菌腙(ferimzone)之苯胺基嘴。定系化合物；如5-氣-7-(4-曱基哌啶-1-基)-6-(2,4,6_三氟苯基)[1，2,4]三氮基 [l，5-a]嘧啶之三氮基嘧啶系化合物；如扶吉胺(fluazinam)之胺0比唆系化合物；如三泰芬（triadimefon)、比多農（bitertanol)、赛福座 (triflumizole)、乙環唾(etaconazole)、丙環唾(propiconazole)、平克座(penconazole)、護矽得(flusilazole)、腈菌唑(myclobutanil)、環克座(cyproconazole)、德克利(tebuconazole)、菲克利(hexaconazole)、呋菌唑（fbrconazole-cis)、撲克拉（prochloraz)、滅特座 (metconazole)、依普座(epoxiconazole)、四克利(tetraconazole)、口咢口米口坐反丁烯二酸鹽(0\卩000仙20匕1111皿加6)、石夕氟哇(5丨卩(：011&2〇16)、丙硫菌唾（prothioconazole)、三泰隆（triadimenol)、粉嗤醇 (flutriafol)、待克利(difenoconazole)、Ι1#'1 坐(fluquinconazole)、腈苯哇（fenbuconazole)、糠菌唑（bromuconazole)、達克利 (diniconazole)、三賽》坐(tricyclazole)、撲殺熱(probenazole)、矽氟唑 (simeconazole)、稻痕酯(peflirazoate)、種菌唾(ipconazole)、易胺座 (imibenconazole)2°^ 系化合物；如滅蜗猛(quinomethionate)之啥D号1#系化合物；如代森猛(maneb)、代森鋅(zineb)、代森猛鋅(mancozeb)、代森福美辞（polycarbamate)、免得爛（metiram)、曱基鋅乃浦 (propineb)、得恩地(thiram)之二硫胺甲酸酯系化合物；如熱必斯(fthalide)、四氯異苯腈(chlorothalonil)、五氯瑞基笨 (quintozene)之有機氯系化合物；如免賴得〇3611011154)、曱基多保淨(此0卩1^1加6-11161；11)4)、貝芬替S 201216848 g effect form. The blending amount is from 〗〖3G wt%, preferably from q 5 to 25 wt. = The present invention = the average particle size of fluniin used is from 丨 to lake, desirably from 1 to ΙΟΟμπι, further preferably from 5 to 5〇μιη. Age riding makes it possible to paste: ethylene·ethyl acetate copolymer, ethylene-tertiary carbonic acid copolymer, styrene-acrylic acid vinegar, acrylic acid, oxidized polyethylene, guanidinium carbamate, Lu ^ 脂 fat and so on. Water insoluble _ is expected to be used as an emulsion. Special period of example. Copolymer emulsion. The ethylene-propionic acid copolymer emulsion, for example, can be used in a resin emulsion such as a paste, and can be mixed. Incorporation of 1, the solid matter is from 1 to 30% by weight, preferably from 1 to 15%, and the body of the invention is not particularly limited. For example, a powder, a material π, a carbonic acid, a sericite, or the like can be used. ~ (trade name), acid gypsum is not a carrier such as i Zhanshi, Bora, and green gangue. For the blending amount and 2C, it is 4g to ".8% by weight, preferably (10) to the heart weight% of the amber. Examples of measuring: county polyoxyethylene, sodium benzoate, higher alcohol sulfate, hospital naphthalene acid sodium, ethylene burning, polyoxyethylene styryl phenyl vinegar, polyoxygenation = poly t-styrene-based phenyl acid vinegar. In the case of the case, it is used for the change of the other. The humectant is preferably used in an amount of from 0 to 5 and is not particularly limited to 'from _ to 10% by weight'. The granulation method generally used in the manufacture of pesticides, for example, energy method, compression violet method, rotation system Granular method, rotary flow granulation method, fluidized bed granulation system. , '^,,, stirring mixing granulation method, coating granulation method, tableting method, etc., etc. 201216848 For example, evenly mixed human, fat emulsion, using kneading machine ^,, ^ agent and carrier after 'adding water difficult Soluble tree granules dry, whole grain ^ _ example and other extrusion systems, can be added - step control. Melt extrusion speed in the δ hai composition, dangerous in the preparation of the preparation to ensure that pesticides are corrected, such as In the case of the purpose of improving the granulation property of the pesticide of the present invention, the purpose of '= and the amount of the optional component in the case of granulation, the surfactant may be contained in the present invention, and (4) in the present invention, if necessary, It is possible to mix and adjust the agent to grow freshly. In this case, T also shows that further excellent ίΪίίΠί can improve the scope of application, the period of drug treatment, and the prevention and control activity. Further, it is possible to use I nitrile in combination with other agricultural products, and it is possible to use them in a mixture of the preparations at the time of dispersion, or to use them in combination. For example, in the case of modulating the composition, it is also possible to prepare the nicotinamide together with other pesticide components other than the other. In the present invention, in such a manner, the case where the active ingredient is mixed and applied is also included. An active ingredient compound of an insecticide, a miticidal agent, a nematicide or a soil-killing insecticide in the above other pesticides, that is, for example, an insecticidal compound (generally: one containing the application, or the test code) is Bufeisong Qjr0fen0f0s), dichlorvos, fenamiphos, fenitrothion, epirubicin (EPN), dizinon, chlorpyrifos, chlorpyrifos-methyl ), acephate, prothiofos, fosthiazate, cadusafos, dislufoton, isoxathion, isofenphos, Ethion, etrimfos, quinalphos, dimethylvinphos, dimethoate, sulprofos, sulphur Thiometon, vamidothion, pyraclofos, pyridaphthion, pirimiphos-methyl, propaphos, pine fen powder 201216848 (phosalone), blessing Formothion, marathion, insecticide (te Trachlovinphos), chlorfenvinphos, cyanophos, trichlorfon, methidathion, phenthoate, ESP, azinphos-methyl, fen Fenthion, heptenophos, methoxychlor, parathion, phosphocarb, demeton-S-methyl, monocrotophos, Methamidophos, an imicyanafos, parathion-methyl, terbufos, phospamidon, phosmet, tofusone (phorate), phoxim, triazophos organic compound compounds; such as carbaryl, propoxur, aldicarb, carbofUran ), thiodicarb, methomyl, oxamyl, ethiofencarb, pirimicarb, fenobucarb, butyl plus Carbosulfan, benfiiracarb, bendiocarb, fUrathiocab, isoprocar b), metolcarb, xylylcarb, XMC, fenotiiiocarb, methotrexate; cartap, thiocyclam, bensultap , thiosultap-sodium, monosultap, bisultap, thiocyclam hydrogen oxalate of the toxin derivative; such as dicofol, Organochlorine compounds of tetradifon, endosulfan, dienochlor, and dieldrin; organometallic systems such as fenbutatin oxide and cyhexatin Compounds; such as fenvalerate, permethrin, cypermethrin, deltamethrin, cyhalothrin, tefluthrin, vinegar (ethofenprox), flufenprox, cyfluthrin, fenpropathrin, flucythrinate, fluyanthine vinegar, and acetaminophen CyCi〇pr〇thrin), lambda-cyhalothrin, pyrethrins, cyanamide Pyrethroid 201216848 (esfenvalerate), tetramethrin, resmethrin, protrifenbute, bifenthrin, zeta-cypermethrin, ananin (acrinathrin), alpha-cypermethrin, allethrin, gamma-cyhalothrin, theta-cypermethrin, fua -fluvalinate), trolomethrin, profluthrin, beta-cypermethrin, beta-cyfluthrin, metofluthrin, phenbutin (phenothrin), flumethrin, decamethrin, in addition to succulent compounds; such as diflubenzuron, chlorfluazuron, flubufenzuron, fluoride Flufenoxuron, triflumuron, hexaflumuron, lufenuron, novaluron, noifurumuron, bistrifluron a phenylhydrazinourea compound of fluazuron; Such as metoprene, pyriproxyfen, fenoxycarb, diofenolan, juvenile hormone compounds; such as pyridaben's 哒α well ketone system匕 ;; such as fenpyroximate, fipronil, tebufenpyrad, ethiprole, tolfenpyrad, acetoprole, ° ratio of pyrafluprole, pyripramine (pyriprole) than salivary compounds; such as imidacloprid, nitenpyram, acetamiprid , ° thiacloprid, thiamet: hoxam, clothianidin, nidinotefbran, dinotefbran, and nitid. New nicotine such as nithiazine; such as tuffenozoide, nethoxyfenozide, chromafenozide, halofenozide, etc.; a special window acid compound such as spirodiclofen; a spheroid compound such as fluacrypyrin; an amine ratio biting compound such as flufenerim; 201216848 Dinitrogen compounds, organic sulfur compounds, urea compounds, tri-p compounds, lanthanides or other compounds, such as: buprofezin, hep, hexy (hexythiazox), double methyl moon (amitraz) insecticidal moon rice (chl〇rdimef〇rm), flurazepam (silafluofen), π sitawei (txiazamate), pymetrozine, pyrimidifen, kefanpai ( Chlorfenapyr), indoxacarb, acequinocyl, etoxazole, cyromazine, 1,3-dichloropropene, dibutyl ether urea (diafenthiuron), isothiazolid (benclothiaz) combined with this month (bifenazate), snail @|(spiromesifen), spirotetramat, propargite, clofentezine, metaflumizone, 3-bromo-N-(2-bromo-4-gas) -6-(1-cyclopropylethylaminemethane)phenyl)-1-(3-chloropyridin-2-yl)-1Η·pyrazole-5-decylamine, 3-bromo-N -(4j_2-(l-cyclopropylethylamine fluorenyl)-6-nonylphenyl)-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-decylamine, 3-bromo-N-(2-bromo-4-chloro-6-(cyclopropyldecylamine decyl)phenyl)-1-(3-chloro0-biti-2-yl)-1Η-η啥-5-decylamine, flubendiamide, cyflumetofen, chlorantraniliprole, cyantraniliprole, cyenopyrafen, pear fluoride Pyrifluquinazone, fenazaquin, amidoflumet, chlorobenzoate, sulfluramid, hydramethylnon, metaldehyde, HGW -86, AKD-1022, ryanodine, pyridalyl, verbutin, compound of thiazolylcinnanonitrile, etc.Further, it can be used in combination with, for example, Bacillus thuringienses subspecies aizawai, Bacillus thuringienses subspecies kurstaki, Bacillus thuringienses subspecies israelensis, Bacillus thuringienses. Subspecies japonensis, Bacillus thuringienses subspecies tenebrionis, Bacillus thuringienses, crystallization protein toxins, entomopathogenic virus agents, entomopathogenic linear agents, nematode pathogenic bacteria, etc. Aver 壹 ect (avermectin), emamectin benzoate, milbemectin, milbemycin, spinosad, ivermectin, kill Lepimectin, DE-175, abatatin 201216848 (abamectin), emamectin, spinetorram anti-biomass and semi-synthetic antibiotics; eg azadirachtin, rotenone (r〇tenone) natural product; decoction of decoction (deet). The active ingredient compound of the above-mentioned other pesticides, that is, the bactericidal compound (general name; including a part of the application; or the Japanese Plant Epidemic Prevention Association test code), for example, may be exemplified by: mepanipyrim, pyrimethanil Amine (pyrimethanil), cyprodinil, and imiline-based mouth of fermzone. a compound such as 5-gas-7-(4-mercaptopiperidin-1-yl)-6-(2,4,6-trifluorophenyl)[1,2,4]triazinyl[l , 5-a]pyrimidine triazalpyrimidine compound; such as acetazinam amine 0 oxime compound; such as triadimefon, bitertanol, triflumizole , etaconazole, propiconazole, penconazole, flusilazole, myclobutanil, cyproconazole, tebuconazole, phenanthrene Hexaconazole, fbrconazole-cis, prochloraz, metconazole, epoxiconazole, tetraconazole, mouthwash mouth rice Acid salt (0\卩000xian 20匕1111 dish plus 6), Shixi fluoride (5丨卩 (: 011 & 2〇16), prothioconazole, triadimenol, pink sterol (flutriafol), difenoconazole, Ι1#'1 fluquinconazole, fenbuconazole, bromuconazole, diniconazole, tricyclazole, flutter Probenazole, simeconazole, peflirazoate, ipconazole, imibenconazole 2°^ compound; such as quinomethionate 啥D#1# Compounds; such as maneb, zineb, mancozeb, polycarbamate, metiram, propineb, Thiram thiol compound; such as fthalide, chlorothalonil, quinozene organochlorine compounds; 3611011154), 曱基多保净 (this 0卩1^1 plus 6-161161; 11) 4), Beffen

S 12 201216848 (carbendazim)、腐絕(thiabendazole)、麥穗寧(fuberiazole)之咪唑系化合物；如克絕(cymoxanil)之氰基乙醯胺系化合物；如滅達樂(metalaxyl)、右滅達樂(metalaxyl-M)、精曱霜靈 (mefenoxam)、口咢霜靈（0Xadixyl)、呋醯胺（0ftjrace)、本達樂 (benalaxyl)、右本達樂(benalaxyl-M、別名 kiralaxyl、chiralaxyl)、呋霜靈(fiiralaxyl)、醋菌胺(cyprofiiram)、萎銹靈(carb〇xin)、氧化萎銹靈(oxycarboxin)、噻呋醯胺(thifluzamide)、白克列(boscalid)、聯苯吡菌胺(bixafen)、異噻菌胺(isotianil)、噻醯菌胺(tiadinil)、環丙 0比菌胺(sedaxane)之胺苯系化合物；如益發靈(dichlofluanid)之績胺系化合物；如氫氧化銅(cupric hydroxide)、有機銅（羥基喹啉銅)(oxine copper)之銅系化合物；如殺蚊寧(hymexazol)之異σ号。坐系化合物；如福赛德(fosetyl-Al)、脫克松(tolclofos-Methyl)、S-苯偶醯二異丙基硫代構酸酯、0-乙基-S,S-二苯基二硫代填酸醋、乙基氫磷酸鋁、護粒松(edifenphos)、丙基喜樂松(ipr〇benfos)之有機磷系化合物；如蓋普丹(captan)、敵菌丹(captafol)、滅菌丹(folpet)之酞醯亞胺系化合物；如撲滅寧(procymidone)、依普同(iprodione)、免克寧(vinclozolin) 之二羧基醯亞胺系化合物；如福多寧(flutolanil)、滅普寧(mepronil)之苯曱醢苯胺系化合物；如吡噻菌胺(penthiopryad)、3-(二氟曱基)小曱基-N-[(1RS，4SR， 9RS)-1，2,3,4-四氮-9-異丙基-1，4-曱氧基奈-5-基坐_4_曱蕴胺與 3-(二氟曱基)-1-甲基_N-[(1RS，4SR, 9SR)-1,2,3,4·四氫-9-異丙基 -1，4-曱氧基萘-5-基]吡唑-4-曱醯胺之混合物（萘吡菌胺 (isopyrazam))、矽噻菌胺(silthiopham)、氰菌胺(fenoxanil)、福拉比 (fbrametpyr)之酿胺系化合物； 13 201216848 如氟吡菌醢胺(fluopyram)、苯醯菌胺(zoxamide)之苯曱醯胺系化合物；如赛福寧(triforine)之。比σ井系化合物；如佛尼胺(flonicamid)、比芬諾(pyrifenc^i1^11 定系化合物；如芬瑞莫(fenarimol)之甲醇系化合物；如苯銹。定(fenpropidin)之派。定系化合物；如芬普福(fenpropimorph)、三得芬(tridemorph)之嗎琳系化合物；如三苯經錫(fentin hydroxide)、三苯醋錫(fentin acetate)之有機锡糸化合物；如戊菌隆(pencycuron)之脲系化合物；如達滅芬(dimethomorph)、氟嗎琳(flumorph)之桂皮酸系化合物；如乙霉威(diethofencarb)之胺曱酸苯酯系化合物；如略菌腈(fludioxonil)、拌種洛(fenpiclonil)之氰°比°各系化合物；如亞托敏(azoxystrobin)、克收欣(kresoxim-methyl)、苯氧菌胺 (metominostrobin)、三 I 敏（trifloxystrobin)、0定氧菌酉旨 (picoxystrobin)、將趟菌胺(oryzastrobin)、趟菌胺(dimoxystrobin)、百克敏(pyraclostrobin)、氟π密菌S旨(fluoxastrobin)之嗜球果傘素系化合物；如口号β坐菌g旨(famoxadone)之D号唾咬二酮系化合物；如韓樂寧(ethaboxam)之β塞β坐曱醯胺系化合物；如丙森辞(iprovalicarb)、苯β塞菌胺(benthiavalicarb-isopropyl)之 '结頁氨醯胺系化合物；如曱基-N_(異丙氧羰基)-L-纈氨醯基-(3RS)-3-(4-氯笨基)-β-丙氨酸酯(valiphenalate)之醯胺酸系化合物；如σ米唾菌酮(fenamidone)之味°坐π定酮系化合物；如環酿菌胺(fenhexamid)之經醯胺苯系化合物；如氟硫滅(flusulfamide)之苯爾胺系化合物；如赛芬胺(cyflufenamid)之月亏醚系化合物； 14 201216848 蒽醌系化合物；巴豆酸系化合物；如維利摄素(validamycin)、嘉賜徽素(kasugamycin)、保粒黴素 (polyoxins)之抗生物質；如雙胍辛胺乙酸鹽(iminoctadine)、單寧(dodine)之胍系化合物；如6-三級丁基-8-氟-2,3-二甲基喹琳_4_基醋酸g旨(異丁乙氧嗤琳(tebufloquin))之喹淋系化合物；如(Z)-；2-(2-氟-5_(三氟曱基)苯硫基)_2_(3_(2_曱氧苯基)四氫嗟 0坐-2-亞基)乙腈(嗟唾烧(flutianil))之四氫嗟唾系化合物；其他之化合物可舉例：本卡布（pyribencarb)、亞賜圃 (isoprothiolane)、百快隆(pyroquilon)、速滅淨(dici〇mezine)、快諾芬(quinoxyfen)、普拔克鹽酸鹽(pr〇pamocarb hydrochloride)、氯化 ^r(chloropicrin)、邁隆(dazomet)、斯美地納鹽(metam-sodium)、咬醯菊胺(nicobifen)、滅芬農(metrafenone)、UBF-307、雙氯氰菌胺 (diclocymet)、丙氧喹啉(pr〇qUinazid)、吲唑磺菌胺(amisuibrom ;別名amibromdole)、3-(2,3,4-三甲氧基-6-曱基苯曱醯基)-5-氯-2-甲氧基-4-曱基吼啶、4-(2,3,4-三曱氧基-6-曱基苯曱醯基)-2,5-二氯-3-三氟曱基11比咬、甲氧苯σ定菌（pyri〇fen〇ne)、雙炔酿菌胺 (mandipropamid)、氟 η比菌胺（f|UOpic〇iide)、環丙醯菌胺 (carpropamid)、二曱基苯乙基曱醇(meptyidinocap)、n_[(3，，4，-二氣 -1，1·二曱基)苯醯甲基]-3-三氟甲基-2-吡啶甲醯胺、N-[(3，，4，-二氯 _1，1_二甲基)苯醯曱基]-3-甲基-2-噻吩甲醯胺、N-[(3’，4，-二氣-1,1-二曱基)苯醯曱基]-1-曱基-3-三氟曱基-4-°比峻曱醯胺、N-[[2，-曱基 _4’-(2-丙氧基)-U_二曱基]苯醯曱基]-3-三氟甲基-2-吡啶曱醯胺、 Ν·[[2’-曱基_4’-(2-丙氧基)-1,1-二甲基]苯醯曱基]_3_曱基_2_噻吩曱、N-[[r-曱基·4’_(2·丙氧基甲基]苯醯曱基甲基_3_ 三氟曱基-4-吡唑甲醯胺、N_[[4，-(2-丙氧基)-1,1-二曱基]苯醯曱基]_3_三氟甲基_2_吡啶甲醯胺、Ν·[[4’_(2_丙氧基)_Uc甲基]苯醯曱基]-3-甲基-2-噻吩曱醯胺、N_[[4，_(2_丙氧基曱基]苯醯曱基]-1_曱基-3-三氟曱基-4-吡唑曱醯胺、Ν·[[2，_曱基-4，-(2-戊氧 15 201216848 基)-l，l-二甲基]苯醯甲基]-3-三氟甲基_2_吡啶甲醯胺、N-[[4, -(2-戊氧基)-1，1-二甲基]苯醯曱基]_3_三氟甲基_2_吡啶甲醯胺、高米綜 (ferimzone)、葚孢菌素（spiroxamine)、S2188(胺苯吡菌酉同 (fenpyrazamine))、S-2200、ZF-9646、BCF-05 卜 BCM-06 卜 BCM-062 等。、於本發，中，因為氟尼胺之處理量係根據對象作物、處理方法、製劑形悲專之條件而不同，難以一概加以規定，通常為〇! 至24,000g/ha。散布處理之情形，氟尼胺之處理量通常為〇j至 10,000g/ha ’期望為1至i，_g/ha，進一步期望為1〇至鄉，而f" ’ ί進一步期望為25至500g/ha。水面處理之情形，氟尼胺 5 ^ l,〇〇0g/ha , 1〇 ^ ? 期望為50至600g/ha。育苗箱處理之情形，就尼胺 ^至l〇0g/箱，期望為。。丨至1〇g/箱，進一步期望為二】 700ΡΡ^ίίί=ίί5ϋα〇5 至上〇〇〇卿接著，舉例本發明之數個^的實 Τ至20〇PPm 〇本發明之解釋並未受限定。、&久L，但猎由此等例子， (1)-種稻寄生吸汁害蟲之交尾動效成分的氟尼胺。復y其係含有作為有葉輝㈣害蟲為峨類及有二該害蟲為飛細。吸汁害蟲之交尾動作干擾劑來防治該宝^成刀的氟尼胺之稻寄生 (5)種方法，其係處理含有作為、 ___方法，其‘ ⑺在⑺所記翻枝’㈣該害蟲之下吸汁害蟲之交尾動斜_來干擾該竭氟尼胺之稻寄生世代個 •世代個 16 201216848 體數，保護稻作免受該害蟲之禍害。 (8) 在(5)所記載的方法，其中氟 24,000 g/ha予以處理。有效成勺量為以0.1至 (9) 在(5)所記載的方法，其中該處理 (10) 在(5)所記載的方法，直中在二，處理。劑。、尺田内處理該交尾動作干擾 (11) 在(5)所§己載的方法，其中在育# & & + π» 擾劑。月田相内處理該交尾動作干 (12) 在(5)所記載的方法，其中在水之處理量，進銳尼胺之散布處理= 1至 (13) 在(5)所記載的方法，其中在水田内^ 處理量，進行氟尼胺之水面處理而防治該害蟲。，__之 μ (i4il(5)所記載的方法’其中在育苗箱内，以_1至l〇〇g/ 相之處理董，進行處理氟尼胺而防治該害蟲。 (15) -種有害生物防治用組成物，其^ 方法之氟尼胺與水難溶性樹脂。判、杜叫己載的 (16) 在(15)記載的有害生物防治用組成物，其尼胺與水難溶性樹脂形成基質。才削T齓或(16)記載的組成物，其中水難溶性樹脂為乙烯-丙饰酸共聚物。 (18) 在(15)至(17)中任-項之記載的組成物，其更含有濕潤劑。 (19) 在(15)至(17)中任-項之記載的組成物，其中氣尼胺均粒徑為1至ΙΟΟμιη。 (20) 在(18)記載的組成物，其中氟尼胺之平均粒徑為丨至i⑻ μηι。 (21) —種有害生物防治用組成物，其在(15)至(17)中任一項 (19)所記載的組成物為粒劑。〃 (22) —種有害生物防治用組成物，其在(18)或(2〇)所記載的組成物為粒劑。 (23) 在(21)記載的組成物之製造方法，其中為具有進行氟尼胺 17 201216848 及乙烯-丙烯酸共聚物之混合/混授/製粒與乾燥之步驟。 (24)在(22)記載的組成物之製造方法，其巾具有進行氟尼乙烯-丙烯酸共聚物之混合/混授/製粒與乾燥之步驟。樹脂㈣一種有害生物防治用組成物，其係含有氟尼胺與水難溶性 (26)在(25)記載的有害生物防治用組成物，尼胺與水難溶性樹脂形成基質。牡表剎甲貺嫦酸^2。5)或(26)記載的組成物，射水難_脂為乙烯-丙其更巾任—奴記娜細議組成物，均粒任—她她成物，其愤尼胺之平叫。⑽在⑽記載的組成物，其中氟尼胺之平均粒徑為1至麵驗成物’其在⑼網中任一項或物為，其在⑽綱記載的組成 (33) 在(31)記載的組成物之製造方法乙烯-丙烯酸共聚物之混合/卿製粒與乾燥之步驟有進侃尼祕 (34) 在(32)喊敝祕之製造方法，射乙婦=稀酸共聚物之混合/混檀/製粒與乾燥之中步驟有進乱胺及實施例解釋定i己載本發明之實施例’但本發明並非受此等實施例之製劑例1 混合氟尼胺1重量份 '膨土(豐順司製)76重量份之==: GR-3靴魏鹽水終三洋化缸#公卿重量份、s繼 201216848 要之水量二^水溶液、日本製紙—1公司製)3重量份與必得農藥粒劑。匕見彻擠出製粒機製粒後’進行乾燥、整粒後獲製劑例2 苯乙量份、碳酸練末92.3重量份、及聚氧乙烯 f、之後iMSGrpGl 5G96、東邦化學卫業公司製)3重量 =後口 # 讀之含27w/w%乙婦.丙烯酸共聚物的水性乳，· f,YTEC W111(東邦化學工#公_)，加人必要之水篁A I用撥出機而製粒後，進行乾燥、整粒後獲得農藥粒劑。、製劑例3 尼胺2重量份、黏土 92·3.重量份及聚氧乙烯苯乙烯基本基醚硫&^旨(S〇rp〇1 5096、東邦化學工業公司製)3重量份之後，添加10重量份之含27w/w%乙稀_丙稀酸共聚物名：HYTEcwm(東邦化學工#公司製)），加人必要之; 攪，利用擠出機而製粒後’進行乾燥、整粒後獲得農藥粒劑。 5式驗例1:藉氟尼胺育苗箱處理所獲得之對於褐飛蝨的防治效果在1.2cmxl.2cm單元苗(3棵/株)之根珠部，以15mg ai/株之比例，於育苗箱中處理依照製劑例1所調製之粒劑。氟尼胺處理一天後，連土壤一起從單元拔起稻作，丨盆各移植丨株，將水深保持於3 cm。準備2個小型溫室，在各小型溫室内氟尼胺處理、無處理分別設置24盆。於移植10、17及30日後，室溫下放飼褐飛蝨 (Nilaparvata lugens)成蟲各100隻。放蟲後每隔一定期間測定寄生在稻作之每24株稻作的成蟲數及所新生的下一世代之幼蟲數。將結果顯示於表1及圖1。還有，於圖1中，〇 — 〇(圓符號)係表示於氟尼胺處理區中之成幼蟲數(隻），△ — △(三角符號；)係表示於無處理區中之成幼蟲數(隻）。 … [表1] 19 201216848 第1表褐飛蝨的成幼蟲寄生數/24株(隻) 稻移植後之天數 17 18 21 25 29 35 39 45 51 57 63 氟尼胺處理區 2 9 12 27 61 146 94 149 301 687 566 無處理區 5 21 114 458 722 609 300 479 1050 1775 1100 於表1及圖1中，從無處理之成幼蟲數的推移，稻移植後第 29天為第1世代之波峰，稻移植後第57天為第2世代之波峰。稻移植後第39天’成幼蟲數減少，能夠推測為第1世代成蟲所生之印為辉化前之狀態。另外’ 3次之成蟲放飼係於實際之水田中，假想褐飛蟲從其他地域飛來的場面。此狀況下，於氟尼胺處理區中，未觀，到第1世代之波峰，也大幅抑制第2世代成幼蟲數。試驗例2 :對於褐飛蝨的交尾動作干擾作用將ω粒之稻子播種於40mmx4〇mm之脫脂棉中，準備長度約 — 备稻田係利用含有有效成分敦尼胺2⑻ppm之水溶液進 η處理、風乾，置入玻璃管瓶(内徑4〇_高度75麵；容量所二;齡幼产之時點起’以無_處理之稻苗而飼育1隻後^夭钯尾丨狀之褐飛蝨⑽aparvata lugens)的成蟲。從羽化後第7天，pi綱係以浸潰處理稻而前每1隻蟲。於羽化天抓走 =處和隻在-起而_ 針對浸潰處理稻—f盡yg二* ，、後羽化第14天使其產卵、拿除。生出的下一世代^^^處理區)與無藥劑處理稻苗(無處理區)所另外二得下—世代幼蟲之產生數。無處理區，翔尾狀態下無下—世代健之產生，在將結果顯示^ 2尾之麵，測得下—世代幼蟲之產生數。 [表2]S 12 201216848 (carbendazim), thiabendazole, fuberiazole imidazole compound; cyanoxamine compound such as cymoxanil; such as metalaxyl, dextromethorphan Metalaxyl-M, mefenoxam, 0Xadixyl, furosemide (0ftjrace), benalaxyl, bentaxol-M, alias kiralaxyl, chiralaxyl ), furiralaxyl, cyprofiiram, carb〇xin, oxycarboxin, thifluzamide, boscalid, biphenyl An amine benzene compound of bixafen, isotianil, tiadinil, sedaxane; an amine compound such as dichlofluanid; Such as cupric hydroxide, copper compound of organic copper (oxine copper); such as the different σ of hymexazol. Sitrate compounds; such as fosetyl-Al, tolclofos-Methyl, S-phenylene diisopropyl thioate, 0-ethyl-S, S-diphenyl Organic phosphorus compounds such as dithio acid vinegar, ethyl ethyl aluminum phosphate, edifenphos, and ipr〇benfos; such as captan, captafol, A bismuth imine compound which sterilizes folpet; a dicarboxy quinone imine compound such as procymidone, iprodione, or vinclozolin; such as flutolanil, Benzoquinone-based compound of mepronil; such as penthiopryad, 3-(difluoroindolyl) fluorenyl-N-[(1RS, 4SR, 9RS)-1,2,3 , 4-tetrazolium-9-isopropyl-1,4-decyloxyna-5-yl sitting _4_曱-amine and 3-(difluoroindolyl)-1-methyl_N-[( 1RS, 4SR, 9SR)-1,2,3,4·tetrahydro-9-isopropyl-1,4-nonyloxynaphthalen-5-yl]pyrazole-4-decylamine mixture (naphthylpyridinium) Isoprozam, silthiopham, fenoxanil, fbrametpyr amine compound; 13 201216848 such as fluopyrazine Yram), a benzoguanamine compound of zoxamide; such as triforine. Specific ratios of σ wells; such as flonicamid, phenanol (pyrifenc^i1^11); methanolic compounds such as fenarimol; such as fenpropidin. a compound such as a fenpropimorph or a tridemorph; an organotin compound such as fentin hydroxide or fentin acetate; a urea compound of pencycuron; a cinnamic acid compound such as dimethomorph or flumorph; a phenylamine phthalate compound such as diehofencarb; (fludioxonil), fenpiclonil cyanide ratio ° various compounds; such as atropine (azoxystrobin), kresoxim-methyl, metominostrobin, trifloxystrobin , oxytocin, oryzastrobin, dimoxystrobin, pyraclostrobin, fluoxastrobin, fluoxastrobin; Such as the slogan β sputum g (famoxadone) D No. a compound; such as Han Leing (ethaboxam) beta-supplemented amide amine compound; such as iprovalicarb, benthiavalicarb-isopropyl's 'salt amidoxime-based compound; -N_(isopropyloxycarbonyl)-L-amidoxime-(3RS)-3-(4-chlorophenyl)-β-alanine (valiphenalate) a proline-based compound; The taste of fenamidone is a compound of quinone ketone; a guanamine compound such as fenhexamid; a benzoamide compound such as flusulfamide; Cyflufenamid) effluent ether compound; 14 201216848 lanthanide compound; crotonic acid compound; such as validamycin, kasugamycin, polyoxins antibiotics; Bismuth octylamine acetate (iminoctadine), tannin (dodine) lanthanide compound; such as 6-tertiary butyl-8-fluoro-2,3-dimethylquinolin-4-yl acetate a quinone compound of tebufloquin; such as (Z)-; 2-(2-fluoro-5-(trifluoromethyl)phenylthio)_2_(3_(2_曱-oxyphenyl)tetra Hydroquinone 0 sitting-2-subunit) acetonitrile (嗟嗟 ( (fl Utinian)) tetrahydroquinone salivary compounds; other compounds can be exemplified by: pyribencarb, isoprothiolane, pyroquilon, dici〇mezine, vebufen ( Quinoxyfen), pr〇pamocarb hydrochloride, chloro (chloropicrin), dazomet, metam-sodium, nichofien, annihil Metrafenone, UBF-307, diclocymet, propoxyquinoline (pr〇qUinazid), carbazolam (amisurobrom; alias amberromdole), 3-(2,3,4- Trimethoxy-6-mercaptophenyl))-5-chloro-2-methoxy-4-indenyl acridine, 4-(2,3,4-trimethoxy-6-nonylbenzene曱醯-)-2,5-dichloro-3-trifluoromethyl 11-bite, pyri- fen sputum (pyri〇fen〇ne), diacetyl glucosamine (mandipropamid), fluoro-n-bispermidine (f|UOpic〇iide), carpropamid, meptyidinocap, n_[(3,,4,-diox-1,1·didecyl)benzene醯Methyl]-3-trifluoromethyl-2-pyridinecarboxamide, N-[(3,4,-dichloro-1,1-dimethyl)phenylhydrazinyl]-3-methyl -2- Thiopheneamine, N-[(3',4,-dioxa-1,1-dimercapto)phenylindolyl]-1-mercapto-3-trifluoromethyl-4-° ratio Indoleamine, N-[[2,-fluorenyl-4'-(2-propoxy)-U-diindenyl]phenylhydrazinyl]-3-trifluoromethyl-2-pyridiniumamine, Ν·[[2'-mercapto_4'-(2-propoxy)-1,1-dimethyl]phenylhydrazino]_3_mercapto-2- thiophene, N-[[r- Indenyl 4'_(2·propoxymethyl]phenylhydrazinylmethyl_3_trifluoromethyl-4-pyrazolecarbamamine, N_[[4,-(2-propoxy)- 1,1-dimercapto]benzoyl]_3_trifluoromethyl_2_pyridinecarboxamide, Ν·[[4'_(2_propoxy)_Ucmethyl]phenyl fluorenyl] -3-methyl-2-thiophene decylamine, N_[[4,_(2-propoxyindolyl)benzoyl]-1 -indolyl-3-trifluoromethyl-4-pyrazole Indoleamine, Ν·[[2,_曱基-4,-(2-pentyloxy-15 201216848)-l,1-dimethyl]phenylhydrazinemethyl]-3-trifluoromethyl_2_ Pyridylcarbamide, N-[[4, -(2-pentyloxy)-1,1-dimethyl]benzoinyl]_3_trifluoromethyl-2-pyridinecarboxamide, high-m (ferimzone), spiroxamine, S2188 (fenpyrazamine), S-2200, ZF-9646, BCF-05 Bu BCM-06 Bu BCM-062 . In this issue, because the treatment amount of flunidom is different depending on the target crop, the treatment method, and the condition of the preparation, it is difficult to specify it, usually 〇! to 24,000g/ha. In the case of dispersion treatment, the treatment amount of fluniin is usually 〇j to 10,000 g/ha 'expected to 1 to i, _g/ha, further expected to be 1 〇 to township, and f" ' ί further expected to be 25 to 500 g /ha. In the case of surface treatment, fluniin 5 μl, 〇〇0g/ha, 1〇 ^ ? is expected to be 50 to 600 g/ha. In the case of the nursery box treatment, the nitrile ^ to l 〇 0g / box is expected. .丨 to 1〇g/carton, further expectation is two] 700ΡΡ^ί ί 〇〇〇接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着接着. , & Long L, but hunting such as the example, (1) - the transpiration of the rice parasitic sucking pests of the active ingredient of finnish. The complex y is contained as a worm (4) pest as a mites and two of the pests as a fly ash. The parasitic action of the squirting insect pests to control the snails of the snails of the snails of the snails (5), the method of which contains the method of ___, which is '(7) in the stalk of (7) Under the suction of pests, the entanglement of the insects interferes with the rice parasitic generation of the flunitamide, and the number of the population is protected from the pest. (8) The method according to (5), wherein the fluorine is treated at 24,000 g/ha. The effective amount of the scoop is 0.1 to (9) in the method described in (5), wherein the treatment (10) is carried out in the method described in (5). Agent. The treatment of the mating action in the ruler field (11) is contained in (5) the method of §, which is in the # && + π» turbulence agent. The processing described in (5) in the method of (5), wherein the amount of water treated, the dispersion treatment of the ruthenium amine = 1 to (13), the method described in (5), Among them, the amount of treatment in the paddy field is treated with water surface treatment of flunidom to control the pest. , __μμ (method described in i4il (5), in which the treatment of fluanilide is carried out in the nursery box with _1 to l〇〇g/phase to control the pest. (15) - Species (Fluorine and water-insoluble resin). The composition for pest control according to (15), which is formed by a nitrile and a poorly water-soluble resin. The composition described in any one of (15) to (17), wherein the water-insoluble resin is a composition described in any one of (15) to (17). (19) The composition according to any one of (15) to (17), wherein the gas nicotine has a particle diameter of from 1 to ΙΟΟμηη. (20) The composition according to (18), The average particle diameter of the fluniin is 丨 to i(8) μηι. (21) A composition for controlling pests, wherein the composition according to any one of (15) to (17) is a granule. (22) A composition for controlling a pest, wherein the composition according to (18) or (2) is a granule. (23) The method for producing a composition according to (21), wherein Have progress (24) A method for producing a composition according to (22), wherein the towel has a vinylidene fluoride-acrylic acid copolymer, and a step of mixing/mixing/granulating and drying the composition of the composition of the composition of the invention. Step of mixing/mixing/granulation and drying. Resin (4) A pest control composition containing fluniline and water-insoluble (26) The pest control composition described in (25), nitrile Forming a matrix with a poorly water-soluble resin. The composition of the sputum brake formazan acid ^2.5) or (26), the water injection is difficult _ fat is ethylene - propyl, its more towels - slaves, detailed composition, Granules - she is a product, her anger is called. (10) The composition according to (10), wherein the average particle diameter of the fluniin is from 1 to the surface tester, and any one of the (9) nets is the composition (33) of (10) (31) The method for producing the composition described is a mixture of ethylene-acrylic acid copolymer/clearing and drying, and the step of drying and granulating is carried out. (34) In (32) shouting secret manufacturing method, shooting a woman = dilute acid copolymer The steps in the mixing/mixing sanding/granulation and drying process are as described in the Examples of the present invention. However, the present invention is not subject to the formulation examples of the above examples. 1 part by weight of the mixed flunitamide 'Expanded soil (Fengshun system) 76 parts by weight ==: GR-3 boots Wei salt water final Sanyo Chemical cylinder #公卿重量份, s following 201216848 water amount 2 ^ aqueous solution, Nippon Paper - 1 company) 3 parts by weight And must-have pesticide granules. After seeing the granulation mechanism of the extrusion granules, 'drying, granulating, and then obtaining the styrene content of the preparation example 2, 92.3 parts by weight of the carbonic acid, and polyoxyethylene f, after iMSGrpGl 5G96, manufactured by Toho Chemical Co., Ltd.) 3 weight = back mouth # read with 27w / w% women. Acrylic copolymer water-based milk, · f, YTEC W111 (Dongbang Chemical Industry # 公_), add the necessary water 篁 AI with a dispenser After the granules, the granules of the pesticide are obtained by drying and granulating. In the preparation example 3, after 2 parts by weight of nicotine, 92.3% by weight of clay, and 3 parts by weight of polyoxyethylene styrene basic ether sulfur and sulphur (S〇rp〇1 5096, manufactured by Toho Chemical Co., Ltd.), Add 10 parts by weight of a 27w/w% ethylene-acrylic acid copolymer name: HYTEcwm (manufactured by Toho Chemical Co., Ltd.), and add necessary; stir, granulate by an extruder, and then dry, A pesticide granule is obtained after the whole granule. Example 5: The control effect on the brown planthopper obtained by the treatment of fluniline seedling box was at the root bead of 1.2cmxl.2cm unit seedlings (3 plants/plant), and the ratio of 15mg ai/plant was in the nursery box. The granules prepared in accordance with Formulation Example 1 were treated. One day after the treatment with flunidom, the soil was pulled from the unit together with the soil, and the alfalfa was transplanted to each other to maintain the water depth at 3 cm. Two small greenhouses were prepared, and 24 pots were set in each of the small greenhouses with flunisamide treatment and no treatment. After 10, 17 and 30 days of transplantation, 100 adults of Nilaparvata lugens were fed at room temperature. After the larvae, the number of adults per 24 rice cultivars in rice cultivation and the number of larvae in the next generation of the new generation were measured at regular intervals. The results are shown in Table 1 and Figure 1. Further, in Fig. 1, 〇-〇 (circle symbol) indicates the number of larvae (only) in the fluniin treatment zone, and Δ - △ (triangle symbol) indicates larvae in the untreated zone. Number (only). ... [Table 1] 19 201216848 The number of larval parasitic larvae of the brown planthopper of the first table / 24 strains (only) The number of days after rice transplant 17 18 21 25 29 35 39 45 51 57 63 Fluonamide treatment zone 2 9 12 27 61 146 94 149 301 687 566 untreated area 5 21 114 458 722 609 300 479 1050 1775 1100 In Table 1 and Figure 1, the number of larvae from no treatment, the 29th day after rice transplant is the peak of the first generation, rice The 57th day after transplantation is the peak of the 2nd generation. On the 39th day after rice transplantation, the number of larvae was reduced, and it can be presumed that the first generation of adults was printed as a state before the prevalence. In addition, the '3rd adult insect feeding system is in the actual paddy field, and it is assumed that the brown flying insects fly from other areas. In this case, in the fluniin-treated area, the number of larvae of the second generation was also greatly suppressed by the peak of the first generation. Test Example 2: Interference with the action of the tailings of the brown planthopper The rice of the omega grain was sown in cotton wool of 40 mm x 4 mm, and the preparation length was about - the paddy field was treated with an aqueous solution containing the active ingredient Dunlin 2 (8) ppm, air-dried, and placed. The glass tube bottle (inner diameter 4〇_height 75 surface; capacity 2; from the time of the infancy), the adult of the larvae (10) aparvata lugens, which is bred with no _ treated rice seedlings. On the 7th day after emergence, the pi system was treated with impregnation of rice for each insect. In the feathers, the day is caught and the place is only at the beginning of the _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The next generation of ^^^ treatment area) and the non-agent treated rice seedlings (no treatment area) are the second to the next generation - generation of larvae. There is no treatment area, there is no under the state of Xiang tail - generation generation, and the number of generations of the next generation larvae is measured on the surface of the result. [Table 2]

—第2表 20 201216848 : 90分鐘以内結束交尾。 :未交尾。交尾新尼打綠細錢性降低之_齡統的通稱換ί對於代表的新尼古丁系殺蟲劑之，稱议達贼受性降低之褐麵’同樣地進行辦，針尼胺區而作一對比’測得下一世代幼蟲之產生數。將 [表3] 一世代蟲數(隻) 87 交尾動作之有無- Table 2 20 201216848 : Ending the mating within 90 minutes. : Not crossed. The new nicotine-based insecticide, which represents the new nicotine-based insecticide, is said to be the same as the brown-faced thief. A comparison 'measured the number of larvae produced in the next generation. [Table 3] The number of generations of insects (only) 87

Λ1Α_ 氟尼胺處理區無處理區 ※^:交尾動作未被觀察 ※匕：1〇分鐘以内結束交尾試驗例4 :對於白背飛蝨的交尾動作干擾作用將試驗例2之褐飛蟲置換成白背賴(s〇gatdla ，同 =進行試驗’針對I尼胺處理區及無處理區而作—對比，測得世代幼蟲之產生數。將結果顯示於表4。 [表 4] ' 珩Η衣父尾動作之有下一世代蟲數(售）氟尼胺處理區 4a 〇無處理區〇※卜 130 ※a .交尾動作未被觀察〇 ※匕：30分鐘以内結束交尾。試驗例5 :對於斑飛蝨的交尾動作干擾作用將》式驗例2之褐飛触置換成斑飛兹(La〇(jeiphax striatella)，同 ;地進行雜，針職尼胺處理區及無處理區而作—對比，測得下一世代幼蟲之產生數。將結果顯示於表5。 [表 5] ' 21 201216848Λ1Α_ There is no treatment area in the fluniin treatment area ※^: The tailing action is not observed. ※匕: Ending the tailing test within 1 minute. Example 4: Interference with the action of the tailing movement of the white-backed planthopper White back Lai (s〇gatdla, same = test) for the I nitrile treated area and no treatment area - comparison, the number of generations of larvae was measured. The results are shown in Table 4. [Table 4] ' 珩Η The number of the next generation of the worms is sold (the sale) The fluamine treatment area 4a 〇 no treatment area 〇 ※ 130 ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ ※ 交交交。。。。。。。。。。。。。。。。。。 For the interference effect of the tailings of the spotted cockroach, replace the brown fly touch of the test example 2 with the zebras (Lai (jeiphax striatella), the same; the ground mixed, the needle nitrile treated area and the untreated area - Contrast, the number of larvae produced in the next generation was measured. The results are shown in Table 5. [Table 5] ' 21 201216848

飛-ί==至5之絲，壯財發财，騎各式各樣之即;對干擾，抑制下一世代個體數。另外，得知忒驗例6 :對於褐飛蝨的交尾動作干擾作用除了利用含有有效成分氟尼胺5〇、試驗例2而進行=== 顯示；;ir作—對比，測得下—世代幼蟲之產生數。將結果Fly - ί== to the 5th wire, strong wealth and wealth, ride all kinds of; that interference, suppress the number of individuals in the next generation. In addition, it was found that the test case 6: the interference effect on the tailing action of the brown planthopper was performed by using the active ingredient fluniamine 5 〇, test example 2 === display; ir for comparison, the next-generation larvae were measured Generate a number. Will result

^ ·.父尾動作未被觀察-◊· 30分鐘以内結束交尾白繼的交尾動作干擾作用處理稻苗二、12.5及3.lppm之水溶液處理區而作—對比，^ ^仃麵’針對l尼胺處理區及無表7。測付下一世代幼蟲之產生數。將結果顯示於 [表η^ ·. The parent tail movement has not been observed - ◊ · End of the 30-minute period of the end of the tail of the white tail of the interference action treatment of rice seedlings 2, 12.5 and 3.lppm of the aqueous treatment area for - contrast, ^ ^ 仃 surface 'for l Nitrile treatment zone and no table 7. The number of larvae produced in the next generation is measured. Display the results in [Table η

S 22 201216848 1 第7表S 22 201216848 1 Table 7

處理區 ※a :交尾動作未被^ ※b : 30分鐘以内結束交尾試驗例8 :對於斑麵的交尾動作干擾作用處理氟尼胺5G、12.5及3.响之水溶液益卢理:純趣例5而進行1擔’針對氟尼胺處理區及而作-對比，測得下—世代幼蟲之產生數將結果顯示 [表8]Treatment area ※a : The tailing action is not ^^b: Ending the tailing test within 30 minutes. Example 8: Interfering with the action of the mating of the spotted surface. Treatment of fluniline 5G, 12.5 and 3. The aqueous solution of Yiluoli: pure fun example 5 and 1 ' 'for the fluniin treatment zone and the comparison - the number of generations of the next generation larvae is measured [Table 8]

第8表 ii尽胺處理區惠尽胺處理區理區理區 ※a •交尾動作未被觀察 ※^ : 30分鐘以内結束交尾。交尾彳^尼古了纽降低之褐_統的外，成:°細之水溶液處理稻苗以作測得下-世代幼蟲之產生數。將結果顯示及於表處^而The eighth table ii The amine treatment area The remedy treatment area The area ※a • The tailing movement is not observed ※^ : The ending is completed within 30 minutes. The tail-tailed 彳 ^ Ni Gu has been reduced by the brown _ system, and the rice seedlings were treated with a fine aqueous solution to measure the number of generations of the next-generation larvae. Display the results and the table

•‘交尾動作未被觀察― ※匕：30分鐘以内結束交尾錢驗例6至9之結果’得知於本發日种，即使對於各式各 23 201216848 ΐΐ 3‘1PPm #之储度的有效成分之情形下，也干所使用的益達胺感受性降低之褐_，本發果，.lPPm权•度的有效成分之情形下，也顯示優異的效試驗例10 :對於偽黑尾葉蟬的交尾動作干择作用將試驗例2之褐飛蟲置換成偽& -對比tir液所處理的既尼贿職及無處理區而作 [ij 之產生數。將結果顯示於表10。• 'The end of the action is not observed'. ※匕: The result of the end of the payment of the money is less than 30 minutes. The result of the test is 6 to 9'. It is known that it is effective for the daily storage of the 23 201216848 ΐΐ 3'1PPm # In the case of the ingredients, it is also used in the case of the brown _, which has a reduced susceptibility to the estamide, and the present invention, and the effective ingredient of the .lPPm weight, also shows excellent efficacy test example 10: for pseudo black-tailed spider mites The tailing action was selected to replace the brown fly of Test Example 2 with the pseudo-amp; - the comparison of the bribes and the untreated areas treated by the tir solution. The results are shown in Table 10.

下一之結果，得知於本發日种，對於偽黑尾葉蟬抑制效果試驗例u:藉氟尼胺育苗箱處理所獲得之對於褐麵的防治於30cmx60cm之育苗箱中，以6、12、24艿％奸 =育苗箱中處理依照該製劑例2所調製 ga f rtn tWm^24 ^ ： aL· 天f 域而移植至丨區32m2之圃場。於移 20=天場―2，放飼褐飛蝴各5〇〇㈣ il it 移植％、89及％天寄生在稻作之每24株稻作有’在作為參考之圖2中，針對氣尼胺處理區果==The next result was found in the seedling box of the pseudo-black-tailed spider mites in the present day, and the control effect of the pseudo-black-tailed spider mites was obtained in the nursery box of 30 cm x 60 cm obtained by the treatment of the fluramide seedling box. 12, 24%% trait = treatment in the nursery box was transplanted to the market of 32 m2 in the sputum area according to the ga f rtn tWm^24 ^ : aL · day f domain modulated by the preparation example 2. In the move 20 = Tianchang - 2, feed the brown fly butterfly each 5 〇〇 (four) il it transplant %, 89 and % of the parasitic in the rice crop every 24 rice plants have 'in the reference to Figure 2, for gas Nitrile treatment area ==

S 24 4 201216848 •氟尼胺處理區之情形而於表示圖中。·_φ(黑色圓符號)係表示在 24§&|/1〇&說尼胺處理區之成幼蟲數(隻），口 — 口（白色四角符號)係表不盈達胺粒劑處理區之成幼蟲數(隻），△ —△(白色三角符號)係表示達特南粒劑處理區之成幼蟲數(隻）’ X — x(x符號)係表示無處理區之成幼蟲數(隻）。處理濃度稻移植後之天數(天） 70 78 89 96 氟尼胺處理區 36 g ai/10 a 11 3 17 78 氟尼胺處理IS 24gai/10 a 14 5 14 47 氟尼胺處理菡 12 g ai/10 a 88 16 8 106 氟尼胺處理區 6 g ai/10 a 53 5 6 70 ..益達胺水合劑處理(¾ 24 g ai/10 a 9 44 170 50 達特南水溶劑處理區 24 g ai/10 a 11 28 72 116 無處理區 77 166 610 355 [表 11] 第11表 5次放蟲係在西南暖地之水田中，配合褐飛蝨從他地域飛來，時期而實施。從無處理之成幼蟲數的推移，稻移植後第的天為弟1世代(下一世代)之波峰。在對照劑starkie箱粒劑處理區中了雖然直到調查開始之移植7〇天後已抑制寄生成幼蟲密度，但錢轉變成增加。喊在對關Admife絲猶观，姻樣地^ 調查開始之移植70天後已抑制寄生成幼蟲密度，但其後轉變加，觀察到移植後第89天為第i世代(下一世代)之波峰。此狀^ 下，在亂尼胺處理區中’未觀察到第丨世代(下一世 ΪΪΓ瓣生祕蟲數。此結果，本發_在具有藥鍋舰吸汁害果試驗例12 :藉氟尼胺莖葉處理所獲得之對於褐麵的防治效藉插缺機而移植至1區32m2之圃場。於移植％、犯、Η 及65天後，對於圃場麵m2，放飼褐飛_蟲各·隻及㈣_ 25 201216848 出穗期，利用150L/1〇a之散布水量而進行氟葉處设置無處理區、派滅淨水合劑(商品名：Chess 戒====溶=將= 第12表S 24 4 201216848 • The situation of the fluniin treatment zone is shown in the figure. · _φ (black circle symbol) indicates the number of larvae (only) in the 24 § & | / 1 〇 & nitrite treatment zone, mouth - mouth (white horn symbol) is not treated with amine granules The number of larvae in the area (only), △ - △ (white triangle symbol) indicates the number of larvae in the Datnam granule treatment area (only) ' X — x (x symbol) indicates the number of larvae in the untreated area (only). Days after treatment of concentrated rice transplants (days) 70 78 89 96 Flunidamine treatment zone 36 g ai/10 a 11 3 17 78 Fluanisil treatment IS 24gai/10 a 14 5 14 47 Fluanidil treatment 菡12 g ai /10 a 88 16 8 106 Flunidamine treatment zone 6 g ai/10 a 53 5 6 70 .. edamine hydrating agent treatment (3⁄4 24 g ai/10 a 9 44 170 50 Dartnan water solvent treatment zone 24 g ai/10 a 11 28 72 116 No treatment area 77 166 610 355 [Table 11] Table 11 The fifth locust is carried out in the paddy field of the southwestern warm land, and it is carried out in the same period as the brown planthopper flies from the area. The number of larvae changes, and the day after rice transplant is the peak of the first generation (next generation) of the younger brother. In the control agent starkie box granule treatment area, although the parasitization has been inhibited 7 days after the start of the investigation. The larvae density, but the money turned into an increase. Shouting in the opposite of the Admife silk, the marriage sample ^ investigation began to transplant 70 days after the inhibition of parasitic larval density, but after the conversion, observed on the 89th day after transplantation The peak of the i-th generation (next generation). This is the case, and the third generation is not observed in the messy amine treatment zone. The number of petals of the mystery. This result, the hair _ in the case of the medicine pot ship sucking fruit test case 12: the control effect of the brown face obtained by the treatment of the flavanis stems and leaves is transplanted to the 1st district 32m2 After the transplant, %, guilt, Η, and 65 days later, for the 圃 scene m2, feed the brown fly _ worm each · only and (4) _ 25 201216848 heading period, use 150L / 1 〇 a of the amount of water to carry out the fluorine leaf Set no treatment area, send clean water hydrating agent (trade name: Chess ring ==== solution = will = table 12

—二H在西南暖地之水田巾，齡褐飛紐他地域飛來世攸無處理之成幼蟲數的推移，處理第19天為第1 夠之波蜂。在處理第26天，成幼蟲數逐漸減少，能二劍Γ所齡之㈣解化前之狀態，於對照娜滅淨水溶劑處理區中皆顯示高的密度抑制效果。此狀況 t處理區中未觀察到第1世代(下—世代)之波峰，直到【==:】與對照劑同等地抑制寄生成幼蟲數。，__職树蟲害的吸汁申It引用在2010年7月29日所提出申請的日本專利專利說明書、申請專利範圍、圖示及摘要之 π内合’作為本發明之專利說明書的揭示而被摘錄。- The second H is in the southwestern warm land of the waterfield towel, the age of the brown fly in the New Zealand area. The number of larvae that have not been treated in the world is changed, and the 19th day is the first enough wave bee. On the 26th day of treatment, the number of larvae gradually decreased, and the state before the disintegration of the second sword was able to exhibit a high density inhibition effect in the solvent treatment zone of the control. In this case, the peak of the first generation (lower-generation) was not observed in the treatment zone until [==:] inhibited the number of parasitic larvae as much as the control agent. The __ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ extract.

S 26 201216848 【圖式簡單說明j 圖1係顯示氟尼胺粒劑之依昭女放飼試驗之際的下-世代個體數抑所進行褐飛蝨成蟲係顯示氟尼胺育苗箱處理用粒劑之依處理所進行褐飛蝨成蟲放飼試驗之際的下一世代個體數抑制效果之結果的圖形。【主要元件符號說明】無0 27S 26 201216848 [Simplified illustration of the figure j Figure 1 shows the number of lower-generation individuals at the time of the feeding trial of fluniamide granules. The adult plant of the brown planthopper showed the granules of the flonitamine seedling box treatment. A graph showing the results of the suppression effect of the next generation of individuals on the occasion of the feeding trial of the brown planthopper, the adult, according to the treatment. [Main component symbol description] None 0 27

Claims

201216848 VII. Scope of application for patents: ^ The raw material of the raw material is used as a dry _, and its age is as effective as i, such as the application of sashimi 1 slave _ oblique _, the insecticide as the active ingredient of flunisamide rice 4. A pest that crosses the tail / stands ί Γ the pest. : 4 parasitic action of rice parasitic sucking pests; containing (four) = cis, (four) - step 4 of the # ray for interference green, its cap step 7 such as ^ two generations of individuals 'protected rice from the pests of the disease. Item 4 is a pest interfering action method in which the fluni gas is treated with α 1 to 24,000 *. The method for interfering with the pests of the fourth item of the soil circumference, wherein the treatment of the insects of the four items of the insects is carried out in the nursery box. Γ.5— ί 有有生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物生物A composition for pest control according to claim 10, wherein the water-resistant bath resin is an ethylene-acrylic acid copolymer. 12. For the pest control composition of the first paragraph of the patent scope of May, it further contains a humectant. 13. The composition for pest control according to claim 12, wherein the humectant is polyoxyethylene styryl phenyl ether sulfate. 14. The composition for pest control according to the first aspect of the invention, wherein the flunisamide has an average particle diameter of from 1 to 100 μm. 28 S 201216848 § 15. A composition for pest control, which is exemplified in the scope of the patent application. The composition for pest control is a granule. 16. The method for controlling a pest control according to claim 15 which comprises the step of performing a copolymerization and drying of fluniin and ethylene-acrylic acid. This σ / this withdrawal of pellets 17.- lipid pests (four) inspection joints, listening to Wei-nil and water-insoluble trees == please patent fine 丨 7 items have * biology (four) reliance, which also contains L9 into one Matter = 5 matter _ composition, which is like ___ π, the pattern: 29