TW201215638A - Resin composition and adhesive - Google Patents

Abstract

The present invention provides a resin composition that is suitable for non-solvent adhesives and exhibits high adhesive strength, the resin composition comprising: component (A), which is a (meth)acrylate having one or more (meth)acryloyl groups in molecule terminals or side chains, having one or more main-chain skeletons selected from the group consisting of polyesters, polycarbonates, polyethers, polybutadienes, polyisoprenes, hydrogenated polybutadienes, and hydrogenated polyisoprenes, and having a number-average molecular weight of 500-50,000; component (B), which is an isocyanuric acid derivative represented by general formula (1); component (C), which is a (meth)acrylate having a hydroxyl group; component (D), which is a silane coupling agent; component (E), which is a photopolymerization initiator; and component (F), which is a (meth)acrylate represented by general formula (2) R-O-R' (where R represents a (meth)acryloyl group, and R' represents a C5-C18 alkyl group). The resin composition can be used as an adhesive for polarizing films, cycloolefin polymers, polycarbonates, cellulose triacetates, polyvinyl alcohols, and glass.

Description

201215638 VI. Description of the Invention: [Technical Field to Which the Invention Is Ascribed] The present invention relates to an adhesive. [Prior Art] A cyclic olefin polymer is used in a solder adherent. As a binder of such a ring, a solvent type can be cited. (4) Age-old adhesives. The method of the resin in the resin, as disclosed in Patent Document 1, is: after the red treatment, it is adhered with an instantaneous adhesive. The polarizing film used in the field of liquid crystal display, the PVA is used for the adsorption of the original and the sound, and the 屮 屮 又 又 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以 予以This acetol-based polarizing film is condensed with water and sputum, and it is recognized by the water knife. It is caused by polarized light. The protective film of the polarizing plate is generally made of cellulose triacetate. As an adhesive for attaching a protective film to a polarizing film, an aqueous solution using a polyethylene glycol-based resin is widely used (Patent Document 3). Patent Document 4 reports a diene copolymer, And a dilute vinegar, a photosensitizer, and a sclerosing composition of a sulphate. [Prior Art Document] [Patent Document] [Patent Document 1] 曰本特开昭62_18485号 [Patent Document 2] JP-A-2007-77321 [Patent Document 3] JP-A-2008-065251 [Patent Document 4] JP-A-2008-69239A No. 4/23 201215638 [Summary of the Invention] [Problems to be Solved by the Invention] Let the gun # use the solvent with the solvent. The harmful substances, the solvent volatilization is time-consuming, and it is difficult to get enough! The Nanxun agent system needs to face the jade and the device. This sticky / difficult to get enough -.情 t = If the limb heating the cigarette polymer can improve the adhesion strength, but there are new problems causing the resin deformation. According to the adhesion method disclosed in the patent document i, due to the time-consuming treatment in the primer treatment Problem, * there is a situation where it is difficult to get sufficient adhesion strength. Jli Literature 2 is a feature characterized by containing (meth) propylene vinegar and I line Wei (four) noodles. However, Wuji County contains isomeric cyanuric acid from the viewpoint of improving the adhesion to the substrate. Patent Document 3 discloses that a water-based adhesive such as a polyvinyl alcohol-based adhesive adheres, and since a water-based adhesive such as a +vinyl alcohol-based adhesive needs to be dried for a long period of time, it is inferior in terms of productivity of a polarizing plate. Patent Document 4 does not describe the component (F) used in the present invention based on the viewpoint of exhibiting adhesion to various plastics and the reliability of the crucible. The present invention is based on the above-mentioned facts. The object of the present invention is to provide For example, a cycloolefin polymer, a polycarbonate, a cellulose triacetate, a polyvinyl alcohol, a glass, etc., exhibits sufficient adhesive strength in a short period of time, and is an environmentally-friendly adhesive because of a solvent-free type. In order to solve the above problems, the inventors of the present invention have intensively studied and finally completed the present invention. That is, the present invention includes a resin composition of the following components (A) to (F): (A) Component system At the end of the molecule The side chain has more than one (meth) acrylonitrile group, and has a hydride of polyacetate, polycarbonate, polyether, polybutadiene, polyisoprene, polybutadiene, and polyiso One or more than two main chain skeletons selected from the group consisting of hydrides of pentane quinone, and having an average number of 500 to 50,000 (mercapto) acrylates; the inner (B) component is in the general formula [丨] indicates a different isocyanuric acid derivative: general formula [1] 〇X1~R1

NIC 〇C, R2-X2rc, 〇R3 — X3 羟 羟 蛵 (wherein X1 and X2 represent (fluorenyl) propylene oxime, X3 group or (fluorenyl) propylene oxide, Rl R3 represents a carbon number; (C) a component is a (hydrazino) acrylate having a hydroxyl group; (D) a component is a decane coupling agent; (E) a component is a photopolymerization initiator; (F) a component is (fluorenyl) acrylate represented by the general formula [2]: general formula [2] R-〇_r,

(In the formula, R represents a (fluorenyl) acryl-based group, and R represents a carbon group of 5 to ???). 1U 6/23 201215638 In addition, the resin composition is characterized in that the storage modulus of the cured product of the resin composition is in the range of 〇.〇〇~10000000 MPa (23〇C), and the resin composition is composed of a cyclic olefin. One or more selected from the group consisting of a polymer, a polycarbonate, a cellulose triacetate, a polyvinyl alcohol, and a glass are suitable as an adhesive for a film. From the viewpoint of further progress, the present invention is an adhesive composed of the resin, a product, an adhesive for a polarizing film composed of the resin composition, and a cycloolefin polymer composed of the resin composition. Agent. In view of the above, the present invention is an adhesive for a film selected from the group consisting of hydrocarbon polymer, polycarbonate, cellulose triacetate, polystyrene, and glass. From a further viewpoint, the present invention uses one or more selected from the group consisting of polycarbonate (polycarbonate), cellulose triacetate, polyvinyl alcohol and glass. [Effect of the Invention] The resin composition of the present invention is characterized by a solvent-free adhesive strength. And /, there are no [implementation] [for the form of the invention] base, there is more than one (methyl) propylene _ thin, poly; two return: Γΐ, 趟, polybutylene, poly One or more selected from the group consisting of t isoprene; a group consisting of a lithium hydride consisting of 5〇〇~5〇_<((10): domain f frame, number average molecular weight is „group) propylene knocking ester The molecular weight referred to herein is preferably::; the amount measured by the GPC is converted to polystyrene = 7/23 201215638 « , p < A - mono-isoprene, polybutadiene Hydride η = one selected from the group consisting of monoterpene tellurides or two kinds of hydrides, preferably hydrides or diene hydrides, or hydrides or polybutadienes of butadiene The hydride of pentadiene is 8:0; ^ square "more preferably 8)% or more 'optimally more than 90%. Here, hydrogenation = the ratio of the number of all united units of the hydride of the butylate or the hydride of the polyisoprene to the number of monomer units hydrogenated. The (meth) acrylate is a terminal of the above-mentioned main chain skeleton or a (meth) propyl group of the above two or more. Among them, a (meth) acrylonitrile group is preferably present at both ends of the main chain skeleton. The number average molecular weight of the (A) component (mercapto) acrylate is = 50000 'The best of the car is _~25〇〇〇' is the best. By the number of Li Ping ^ knife in this range, - aspects The obtained hardened body has a large hardness and is easy to form an adhesive layer. The viscosity of the resin composition obtained in the other aspect is low, and workability such as mixing during the production process or workability for practical use is improved. (A) component (mercapto) acrylate, which can be exemplified by 曰 Sa Sao Co., Ltd. - NISSaPB TEAL0 (both terminal acrylic acid 3 modified with oxime butadiene oligomer), Japan #达达Company, NlSS〇_pB ΤΕ·_ (both ends, thioglycolic acid modified from butadiene oligomer), UM 203 manufactured by Kumray Co., Ltd. (isoamethylene phthalate) An esterified oligomer of 2-hydroxyethyl methacrylate and a product of Sart 〇mer Co., Ltd. 8/23 201215638 "CN-301" "C N-303" "CN-307" (polybutadiene acrylate oligomer), "ΚΗΡ-11" and "ΚΗΡ-17" (polyester acrylate vinegar oligomer) manufactured by Kokuwon Industrial Co., Ltd. 'UN- 9000PEP" "UN-9200A" (polycarbonate acrylate oligomer). The component (B) is a heterocyanuric acid derivative represented by the general formula [1]. (b) The composition is used from the viewpoint of further improving the adhesion to the substrate (adhered body), improving the water resistance, and achieving a good storage modulus. General formula [1] X^R1 N I C, Ο

0 II CN , R2-X2 Ο R3 - X3 wherein X1 and X2 represent (fluorenyl) propylene oxime, χ 3 represents hydroxy or (decyloxy, R), r2 and "represents carbon number 丨~ Hydrocarbon group of 4. As a derivative of (9) into a different isocyanic acid, it can be exemplified by: isotriazole, lactated Ethylene modified tris(indenyl)acrylic acid I iso-cyanuric acid (Meth)acrylic acid, iso-cyanuric acid epoxy EB modified three Π夂!: ί:: iso-cyanuric acid oxypropane modified tris(meth)acrylic acid and different m酉夂 post-oxygen Institute modified di(methyl)propionic acid butylene oxide modified tris(meth)acrylic acid - θ /, cyanide di(tetra) hydrated i-axis i, etc. Among the derivatives, from the viewpoint of water resistance, it is more than /, cyanuric acid, epoxy, test, di(methyl)-acid, §, iso-trimeric acid, 9/23, 2012,15,638, J or more The selected one of the group consisting of tris(meth)acrylic acid vinegar and isomeric cyanuric acid ethylene oxide modified di/di(meth)acrylic acid vinegar mixture =^ as component (c) Light-based (meth) acrylate, which can be enumerated as having more than one The monomer of (meth)acryl fluorenyl group contains a hydroxyl group. As a monomer containing a mesogenic group, 2 sides of ethyl (methyl) __ group) acrylic acid 2 - butyl vinegar, Acid 2 rhythm vinegar, aliphatic epoxy group (methyl) acridine acid (Daicel UCB company "service _ (1) "Ebecry 丨 12"), epichlorohydrin (hereinafter referred to as ECH) upgrade (methyl Terpene diester (1 ac'DA'U!" made by Nagase Chemical Co., Ltd., "butyric acid mono-acrylate, hexyl) acrylic acid vinegar, dipropylene glycol ( Methyl) acrylate vinegar, ech modified oxy-oxygen, (meth)acrylic acid I, polypropylene glycol (methyl) propionate (n=5_i3), ring = EB (hereinafter referred to as E0) Succinic acid (meth)acrylic acid vinegar, β·carboxylate, fluorenyl hydrazide, dimer isocyanate diacrylate, modified dibenzoic acid di(tetra)propanate Vinegar, ECH modified propylene glycol di(methyl) propylene ^ 酉曰, epoxy propylene (hereinafter referred to as PO modified) double bismuth A epoxy propyl test (methyl) acrylate vinegar, ECH change Glycerol tris(meth)acrylic acid vinegar, £0 modified, acid (methyl) propylene ^, polyethylene _ Polypropylene glycol (meth) acrylic acid vinegar temple. One or two or more of these may be used. In the case of containing a thiol group, it is preferably a (meth) propyl hydrazine 2 and/or a brain modified phenoxy (meth) propylene. The acid vinegar is more preferably 2-ethyl (meth) acrylate vinegar. The component (D) is Wei coupling #j. As a Wei coupling agent, there may be mentioned: γ-mercaptopropyltrimethoxy-wei, ethylene-trimethoxy-wei, ethylene-trivalent three-gas 10/23 201215638 enene gas diethoxy decane, vinyl propyl three曱 矽 矽 、 乙 乙 乙 乙 乙 乙 、 、 、 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 酿 酿 酿 酿 酿 酿 酿 酿 酿 酿 酿 酿 酿 酿 酿 酿 酿 酿 酿 酿 酿 酿4_epoxycyclohexyl) thief soil: oxy decane, γ-glycidoxypropyl tridecyloxy decane, = propyl fluorene oxide boots, guanamine propyl triethoxy Wei, called (amine B, amine propyl dimethoxy decane, Ν _ β - (aminoethyl) - γ-aminopropyl methyl di, γ • urea propyl triethoxy wei, etc. In terms of hydrazine and hydrazine, it is preferably γ-glycidoxypropyltrimethoxydecane γ (meth) propylene oxypropyl tridecyloxy decane and vinyl propyl trimethoxy oxy sulphate The saccharide or two or more selected from the group, more preferably (meth) propylene oxypropyltrimethoxy decane. The (Ε) component is a photopolymerization initiator. It can be exemplified by ultraviolet polymerization initiator and visible light polymerization. The ultraviolet polymerization initiator is exemplified by a stupid 2, a benzophenone, or an acetophenone. Examples of the visible light polymerization initiator include a fluorenylphosphine oxide and a thioxanthone. (thioxanthone), metal aromatic, lanthanide, α-aminoalkyl ketone, etc. Examples of the photopolymerization initiator include benzophenone, 4-phenylidene benzophenone, and awkwardness. Benzoic acid, 2,2-diethoxyacetophenone, bis-diethylaminobenzophenone, acetophenone, benzoin, phenylhydrazine isopropyl ether, 2,2-dimethoxy Benzyl dimethyl ketal, 1-cyclohexyl phenyl ketone, 9-thioxanthone, 2 ethyl thioxanthone, 2,4-dimercapto-thioxanthene Ketone, isopropyl-.sedone, 2,4-diethyl-throtonone, 2,4-diisopropyl-infrathrone, isopropyl...isopropenyl)-2-yl-2- Methylpropanone ketone ' 1-(4-(2-ethoxy)-benzyl)-2-carbyl-2-mercapto-1-propan-1-one, 2-hydroxy-2-曱基_ι_phenylpropene 11/23 201215638 Alkan-1-one, camphorquinone, 2,4,6-trimethylphenylnonyldiphenylphosphine oxide, double (2,4,6-di Mercaptobenzoyl)·stupylphosphine oxide, 2·曱-Bu (4_(methylthio)phenyl)-2-morpholinpropan-1-one, 2-benzyl-2-indanyl-indole_(4-morpholinylphenyl)-1 -丁_小2·二曱胺基_2_(4_indolyl-benzyl) small (4_morpholino-phenyl)-butanthene bis (2,6-dimethoxybenzamide) Base) 2,4,4_trimethyl-pentaphosphine oxide, and the like. Among these, 2,2-dioxaoxy-2-phenylphenylene and/or bis(2,4,6·tridecylbenzylidene)-phenylphosphine oxide is preferred. In order to further enhance the adhesion to various plastics, the adhesive of the present invention may further contain a monofunctional (meth)acrylic acid g in addition to the components (A), (β) and (c). Examples of the (A) component, the component (B), and the monofunctional (fluorenyl) acrylate other than the oxime component include a (fluorenyl) acrylate (indicative component) represented by the general formula [2]. [2] R-0-R, (wherein R represents a (meth) acrylonitrile group 'R, which represents a carbon number of 5 to 18 decyl groups.) ～ is a monofunctional (F) component The acrylate may, for example, be 2-ethylhexyl (meth)acrylate, isodecyl (mercapto)acrylate, n-dodecyl (meth)acrylate, and hexahydrate. From the viewpoint of saliency, it is preferably (decyl) n-dodecyl acrylate. In the formula, the carbon number of R' is preferably 5 to 18, more preferably 6 to 18. By making R The carbon number is in this range, on the one hand, the moisture resistance is improved, and on the other hand, the resin composition is not crystallized, and the adhesion can be improved. The amount of each component of the present invention is, for example, an adhesive. The adhesiveness of the hydrocarbon polymer is not high, and it is preferably used in the following aspects from the viewpoint of having high adhesion strength to other adhesives and also 12/23 201215638. (A) Composition, ( B) into The amount of the component (C) and the component (F) to be used is the total amount of the component (A), the component (B), the component (C), and the component (F). Preferably, the component (A): B) Ingredients: (C) Ingredients: (F) Ingredients = 〇.1~%: 0.1~90: 0.1~90: Bu 60 (mass ratio), more preferably 0.5-45: 5~80: 1~70: 5 to 50 (mass ratio), preferably 1 to 40: 10 to 70: 2 to 60: 1 〇 to 45 (mass ratio). (D) The amount of the component used is relative to the component (A) and the component (B). The total amount of the component (C) and the component (F) to be used is preferably 0.001 to 10 parts by mass, more preferably 0.01 to 5 parts by mass, most preferably 0.1 to 3 parts by mass, based on 100 parts by mass of the component (F). The amount of the component used is preferably 0.001 to 3 parts by mass, more preferably 0.001 to 3 parts by mass, based on 1 part by mass of the total of the component (A), the component (B), the component (C), and the component (F) to be used. 0 to 1 to 20 parts by mass, preferably 5 to 15 parts by mass. The resin composition of the present invention can be used in the range which does not impair the object of the present invention, and a phosphate coupling agent, a graft copolymer, and a solvent can be used. ,Incremental materials, reinforcing materials, plastic 剤' tackifiers, dyes, pigments, flame retardants' antioxidant Storage modulus 0.001~lOOOOOOOMPa agent, and an additive such as a surfactant. Composition preferably has a 23 ° C) of (tensile mode, frequency 1Ηζ

13/23 The cured product of the resin composition of the present invention preferably has a high adhesion strength of 201215638 cellulose acetate. Especially for cyclic olefin polymers and third degree. The cycloolefin polymer of the present invention is a cyclic olefin such as a core-reducing terpene monomer (the cycloolefin Γ f is derived from norbornene and a polyplastic resin. The cycloolefin polymer may be exemplified by the constituent unit of the I early body. a hydrate, a hydride, a substance, etc., which are obtained by using a mixture of two or more kinds of cyclic olefins, two or more kinds of cyclic olefins, a ring-shaped poly-chain hydrocarbon, and/or an aromatic dimerization of a vinyl group. It is also possible to add the copolymerization to the commercially available ring-collecting pure compound, and the compound is as follows: 八 牛 丨 如 . : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : 〇 〇 s 、 、 、 、 ZE ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART ART 三 三 三 三 三The method of adhering to the present invention is as follows. For example, at least one of the two adhesive bodies is preferably coated with an adhesive to a thickness of 0.0001 to 5 mm by the surface of the adhesive. After that, the adherends are attached to each other' at a wavelength of 200 to 500 nm, and the accumulated light amount is 200 to 6000 mJ/cm2, and the irradiation time is 1 The adhesive is hardened under the condition of 6 sec. to adhere the adherend. [Examples] Hereinafter, the present invention will be described in further detail by way of Experimental Examples, but the present invention is not limited thereto, and the components described in the adhesives of the experimental examples are The following compounds were selected: (Compound) (A) Ingredients: NISSO-PB TE-2000, manufactured by Nippon Soda Co., Ltd. (two ends 14/23 201215638 end phthalic acid i was modified to dilute polymer, the number average molecular weight was 2000 -PB TEAI-1000 (both at the end, the number average molecular weight is (A): NISSO-based NISSO-based acrylic acid S is a modified hydrogenated butadiene-based oligomer 1000, and the hydrogenation rate is 90% or more.) :KHp_17 (polyacetic acid acetoacetate acrylate oligomer, number I average molecular weight of 4 〇〇〇〇) manufactured by Gyeongsang Industrial Co., Ltd. (A) E 匕 ^ 公司 公司 公司 公司 p p p p 聚 聚 聚 聚Amino citrate acrylic acid S 14 substances, the number average molecular weight is 5 〇〇〇) (9) Ingredients: iso-cyanuric acid epoxide modified tri-di-di-acrylic acid (East Asian synthesis M j 13) , 3 / 2 propylene vinegar is a mixture of tripropylene acid and diacrylate) / (8) Ingredients: different Polycyanate Ethylene Oxide Diacrylic Acid Sigma-215, manufactured by Toagosei Co., Ltd. (C) Ingredients: 2-Hydroxyethyl methacrylate ("GE-610" manufactured by Mitsubishi Gas Corporation) Hydroxy (indenyl) acrylate (D) is a Shishi siu coupling agent, γ-glycidoxypropyltrimethoxy shixiyuan ("信_4〇3" manufactured by Shin-Etsu Chemical Co., Ltd.) (D) Component: decane Coupling agent, γ-methacryloxypropyltrimethoxy decane ("ΚΒΜ_5〇3", manufactured by Shin-Etsu Chemical Co., Ltd.) (Ε) Ingredients: Photoinitiator, 2,2-dimethoxy-2-benzene Ethyl ketone ("IRGACURE651", manufactured by Ciba Specialty Chemicals) (E) Ingredients: Photoinitiator, oxidized bis(2,4,6-trimethylphenyl)-phenylphosphine (Ciba Specialty Chemicals, Inc.) "IRGACURE 819" (F) Ingredients: Dodecyl methacrylate ("L" manufactured by Kyoeisha Chemical Co., Ltd.) 15/23 201215638 [Comparative composition] Benzyl methacrylate (LightEsterBZ, manufactured by Kyoeisha Chemical Co., Ltd.) ") as a comparison of (A) and (F) components. A comparison of the (A) component and the (F) component was carried out using decyl acrylate (r Ught Ester M, manufactured by Kyoeisha Chemical Co., Ltd.). Diethylaminoethyl thioglycolate (rLight, manufactured by Kyoeisha Chemical Co., Ltd.)

Ester DE") (Comparison of Q components. (Continuous test example) The adhesive composition consisting of the resin composition shown in Table 1 was prepared, and various physical properties were measured. Various physical properties were measured as follows unless otherwise specified. The film was measured at a temperature of 23 ° C. [Photocurability] The surface of the test piece (width 25 inmX | 25 mm x thickness 2.0 mm) of the ZEONEX 480R (manufactured by Nippon Paint Co., Ltd.) was applied to a thickness of 0.08 mm. It was cured by irradiation with a curing device manufactured by Fusion Co., Ltd. using a hot-electrode discharge lamp at a wavelength of 375 nm and a cumulative light amount of 2000 mJ/cm 2 for 15 seconds. The recording hardening rate was used as photocurability. The hardening rate was FT-IR, and the following. Calculated by formula (hardening rate) = [100-((absorption spectrum intensity of double bond of carbon after hardening) / (absorption spectrum intensity of double bond of carbon and carbon before hardening)] x 丨〇〇 (% [Evaluation of adhesion of cycloolefin polymer (tensile strength between ZEONEX test pieces)] A Teflon (registered trademark) tape having a thickness of 80 μηιχ11.5 mm and a length of 25 mm was used as a spacer, and ZEONEX480R (曰本ΖΕΟΝ) was used as an adhesive. Test piece (width 25〇1!11>&l t; long 25111111><thickness 2.〇111111) adhered to each other (adhesion area 3.125 cm2). After hardening, the tensile strength was measured using the test 16/23 201215638 test piece adhered by an adhesive. The adhesion condition was based on [ [Photocuring property] The method described in [Evaluation of adhesion of cellulose diacetate (peeling strength between test pieces of cellulose triacetate (manufactured by Fujifilm Co., Ltd.)]] using a coating bar to a thickness of 1 cellulose triacetate (Fuji film) Test pieces (width & 10 mmxi 50 mm x thickness 0.08 mm) adhered to each other. After hardening, the test piece adhered with an adhesive was used to measure 180. Peel strength. The stretching speed was 5 mm/min. According to the method described in [Photocurability] [Evaluation of Adhesion of Polyvinyl Alcohol (Peel Strength between Test Pieces of Polyvinyl Alcohol (Kuraray))] Using a coating bar, the thickness of 1 () will be polyetherol (Kuraray Co., Ltd.) test pieces (width l〇mmx length 50 mmx thickness 0.08 mm) were adhered to each other. After hardening, the test piece adhered with an adhesive was used to measure 18 Å. Peel strength. The stretching speed was 5 Gmm/min. Conditions are based on the photohardenability] [Using the evaluation of the adhesiveness of the polymer (polycarbonate (manufactured by Teijin Co., Ltd.) test piece tensile strength)] using a thick 80μηιχ 115111111><25111 out of the Teflon (Deng 5 brand) tape For the spacer, the test piece (25 mm long, 25 mm long and 2.0 mm thick) of the fat-filled product (adhered to Teijin Co., Ltd.) is adhered to each other with an adhesive (the area is 3]25, and the adhesion is made. The test piece was measured for tensile strength. The adhesion conditions are based on the method described in [Photocurability]. [Evaluation of Glass Adhesion (Tensile Strength between Heat-Resistant Glass Test Pieces)] A Teflon (registered trademark) tape having a thickness of 80 μηιχ, ll.5 mmx and a length of 25 mm was used as the inter-iWj material, and a heat-resistant glass Pyrex (registered trademark) was used as an adhesive. The test pieces (width Mmmxf heart (four) thick 2 mm) were adhered to each other (adhesion area J'125 cm2). The adhesion conditions are based on the method described in [Photocurability]. After curing the adhesive according to the conditions described in 17/23. 201215638, the adhesive "G-55" made by Electrochemical Industry Co., Ltd. was used inside the test piece to adhere the galvanized steel sheet (width 〇〇 mmx length 25 mm x thickness 2.0 mm) , Engineer Test Service company). After the hardening, the tensile strength was measured using the test piece adhered with an adhesive. The tensile shear strength (unit: MPa) is at a temperature of 23. (:, measured at a tensile speed of 1% in an environment of 50% humidity. [Water resistance (tensile strength between ZEONEX test pieces)] Test piece for evaluation of the above-mentioned cycloolefin = polymer adhesion (adhesive with adhesive) The test piece) was immersed in a warm water of 60 ° C for 24 hours, and the tensile strength was measured using the test piece: [Storage modulus evaluation (storage modulus (23. 〇)] at 23 ° <: temperature measurement. Hardening Adhesive agent, prepared to grow 2 〇 mmxi 5111111) <1 mm thick cured sample. Adhesion conditions are based on the method described in [Photocurability]. The cured sample was evaluated. Using Sensue made by SEiK〇Electronics Co., Ltd.

Modulus DMS210' frequency ιΗζ, strain 〇 5% of the condition change temperature, the dynamic viscoelastic spectrum is measured in the tensile mode, and the storage modulus E ‘ is obtained in (4). ' 18/23 201215638 1 Experimental example 丨 3| Ό Ό do »〇Ό __ o — V~i >10.0 oo 00 ir> loo | Example 1 Experimental example 12 % l〇O >n JQ mo | «Ti \6 >10.0 >10.0 o 〇6 10.0 〇对' 〇Example 1 1 Experiment 洌|| <η o 10.0 •n 1___ ir> O in ON >10.0 12.5 1 16.0 oc 10000 1 Example 1 Experiment Example 10| 〇ΪΝ do in >n __'〇〇1 in a »〇oc >10.0 W-) ON 1 14.0 5500 | Example 1 I experiment 洌9 〇fN in in do »〇>n 1 ' 〇〇1 l〇•n 00 >10.0 10.5 12.5 00 >ri ΗΪ000 1 1 Example 1 | Experimental Example 〇 <N «η •O 10.0 1__loo_1 1 13.0 >10.0 14.5 »n C7^ •T) . 'X ; 2300 | Example 1 1 Experimental Example 7 •/Ί CN § «/Ί «ri d >ri 〇_ι〇〇_1 yr\ o >10.0 10.0 〇<N m 9000 | Example 1 ο «Λί «r *Τ) «Π <n V% V~i ◦ 1 loo 1 *n 1- 10.0 >10.0 o 30 oc rr | iooo | 1 Example 1 | Experimental Example 5 in <N § In in 〇»n Ξ i _ I •nr^i Ό crv >10.0 un 〇r^i 15000 | Example I | Experiment 洌 4 l〇»ny/~) d 〇i/Ί o 〇in r^> o >10.0 10.0 Wi s〇r*-i I 1400 I Example|Experimental Example 3 v> CN S >T) mdo Ό Ξ 1 _ 1 IT) >10.0 i- 10.5 卜>ri I looo I 1 Example 1 I Experimental Example 2 <n <N iT\ do in o loo I «〇•n cA >10.0 »Λ1 OC »n 1000 Implementation洌|Experimental Example 1 o iN fT) ir> do <n »n 100 ΙΛί »n 10.5 >10.0 12.5 16.0 r- V) 1300 Example bbL Miscellaneous φ»1 Έ Έ ΰ ΰ ^C3 I ^C3 I c: sz

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PI •f •f 3.5 3.5 ι·5 2,0 lb 3.0 0- 0- 5.5 3.'·· 0.'· 0.6 0.6 0.0 100 50 100 100 °°0 100 払5 5.0 P5 30 20 Brick 澎#M4 5·0 5b 60 30 20 Brick heat 15 25 Brick ' '-6 么 5 -5 5.0 5.0 5.0 0.5 0.5 払 5 30 30 30 30 20 Brick 17 17 20 玮澎芰 18 20 20 vlob 7.f 3 100 5 5 30 20 Brick Mai Xuan 21 F'^- O.OOOGOl 0.8 4.0 3.f lb 2.5 1·4 100 5b P5 30 20 蛑蕲1-22 201215638 2 丨 丨 丨 _ _ _ resin composition Show (four) effect. Also shown in the hydrocarbon polymer is a tensile strength above (10). For the three-B-Vinus show 3 mornings, the peel strength above. The peel strength of cm or more is shown for the polyethylene glycol. For polycarbonate, it shows 5 or more purchases. The glass shows a tensile strength of 5.GMPa or more. In the water resistance ^, the tensile strength of 0.3 MPa or more was shown. In particular, the isomeric cyanuric acid derivative in the experimental examples 14 to "without the _) component showed no favorable results from the viewpoints of the substrate properties, water resistance, and storage modulus. In only Example 20 and Test Example 22, the effect of the (f) component, the adhesion of each substrate, the water resistance, and the storage modulus were not favorable. The resin composition of the invention has a sufficient viscosity of the cyclic olefin polymer, polycarbonate, tricellulose, polyether alcohol, and glass in a short period of time and has high water resistance. In particular, since the resin composition of the present invention has excellent adhesion to triethyl, it can be used as a human adhesive composed of cellulose triacetate. And because the resin composition of the present invention polymerizes to a cyclic olefin. Adhesive is excellent, and can be suitably used as a bonding agent for a cyclic olefin polymer. [Simplified description of the drawing] [Explanation of main component symbols] 21/2:

Claims (1)

201215638 VII. Patent Application Range: 1. A resin composition comprising the following components (a) to (f). (^) is one or more (mercapto)-propyl groups in the molecular terminal or side chain. And one of the group consisting of 4 cool, polycarbonate, polydip, polybutyrate, polyisoprene, and isoprene hydride. And the number of 500 to 50000 (meth) acrylate; Knife von von (B) component is the same as the general formula (1) * heterotrimerization of the derivative: general formula [1] R3 -X3 (in the formula X1 And X2 represents a (fluorenyl) propylene oxy group, χ3 represents a trans group or a (meth) propylene fluorenyloxy group, and R!, R2 and R3 represent a hydrocarbon group having a carbon number of 丨4; (C) a component system (D) a decane coupling agent; (E) a photopolymerization initiator; (F) a (meth) acrylate represented by the general formula [2]: General formula [2] r_〇_r, where R represents a (fluorenyl) propylene group, and R' represents a carbon number of 5 to 18 groups. 2. As claimed in the scope of claim Resin composition, in which resin group The storage modulus of the cured product of the product is in the range of 0.001 to 1000 MPa (23. 〇. 22/23 201215638 3. An adhesive, a composition consisting of, for example, the scope of the patent application) Resin group 4. 5. - the original _] or 2 _ 丨 3 of the adhesive' is used in her poly 2: it: 素, 璃, constituting the body is used The adhesive of the third application of the patent scope is as claimed in claim 7, wherein the adhesive body is composed of a cyclic olefin polymer, a polycarbonate, a cellulose triacetate, a polyethylene glycol and a glass. 23/23 201215638 IV. Designated representative map: (1) The representative representative of the case is: No. (2) The symbol of the symbol of the representative figure is simple: 〇5. If there is a chemical formula in this case Please reveal the chemical formula that best shows the characteristics of the invention: None. 3/23