201203515 、發明說明: 【發明所屬之技術領域】 本發明一般係有關於半導體裝置,並尤其有關於 CMOS薄埋藏氧化物背閘極極薄半導體上覆矽(extremdy thin silicon-on-insulator,ETSOI)裝置以降低使用金屬背問 極控制所帶來的短通道效應。 【先前技術】 ik者各種積體電路元件的尺寸縮小,電晶體(例如場 效電晶體(field effect transist〇rs,FET))歷經了在性能斑 功率消耗方面的大幅改良。這些改良可大部 /中 所使用的元件的尺寸縮小,大至造成了電容電阻_ 低’並增加電晶體的輸出電流'然而,此種在裝置尺寸方 ,^型」縮小所帶來的性能改良,近來 ΐί ,在會因 受到挑戰。^^電㈣^縣^㈣流射變性增加而 (MOSFETs)特別广ΐ屬上化半導體場效電晶體 ,FETS與其他裝置的尺寸縮小 == 域、通道區域、以及閘極的尺寸也隨_。祕臟 越來越小且具有短通道長度的的平 淺源極/汲極接面的必要性。欲:體導致極 (d〇_)橫向擴散進人通道中,淺接面是H = 種擴散對於漏電流以及崩潰性能有負面的影 Ϊ厂= :30奈米至丨00奈米的淺源極/ “ = 置而言要有可接受的性能是必要的。絕 4 201203515 (siliCon-on-insuiator,S0I)技術允許了高速、淺接面裝置的 形成。此外,絕緣層上覆矽裝置藉由降低寄生接面電容而 改良其性能。 在一絕緣層上覆矽基板中,由矽氧化物所形成之一埋 藏氧化物(buired oxide ’ BOX)薄膜,係形成於單晶石夕之 上,並在其上形成一單晶矽薄膜。目前已知有多種用以製 造此絕緣層上覆矽之方法,其一是以佈植氡分離法 (separation-by-implanted oxygen,SIMOX),其中氧係為佈 植於一單晶矽基板中的離子,以形成一埋藏氧化物薄膜。 另一形成一絕緣層上負石夕基板之方法係為晶圓鍵結 (bonding) ’其中具有矽氧化物表層之二半導體基板係在該 矽氧化物表面鍵結,以在此二半導體基板之間形成一埋藏 氧化物層。 淺接面電晶體利用淺溝槽隔離(shall〇w trench isolation,STI)技術來隔離裝置與電路。淺溝槽隔離技術 大幅增加了製造成本,因為此淺溝槽隔離製程需要大量製 程步驟與設備’例如熱氧化、矽氮化物化學氣相沉積 (chemical vapor disposition,CVD)、矽氮化物濕蝕刻、反 應性離子钱刻(reactive ion etch,RIE)、高密度電毁(hdp) 矽氧化物沉積、濕式清潔、化學機械研磨 (chemical-mechanical polishing,CMP)、以及光微影技術 (photolithography)。晶圓的一致性與產率也是考量之一, 因為淺溝槽隔離處理步驟需要額外的加工步驟。 將CMOS元件微小化則使得原本可忽略的參數數字 推升到成為電路設計的重要因素。重要的元件參數包括短 201203515 通道控制以及極薄絕緣層上覆砍(extremeiy thin silicon-on-insulator,ETSOI) ’二者均是為此目的而設計的 新等級電晶體《極薄絕緣層上覆矽係為一完全空乏電荷載 體電晶體元件(亦即在3〇〇K時,通道中的電荷載體濃度 係在1〇3原子/立方公分的數量級或更低),其使用了超薄 石夕通道’其中大部分載體在操作中均為完全空乏(fully depleted ’ FD)。此等級的電晶體所面臨的挑戰在於其Vt 變化以及高外部電阻(Rext)。 此FDSOI電晶體臨界電壓vt,是通道摻雜劑的第一 功率數量級的函數並隨之改變,其同時也隨著原子通道矽 厚度變化而改變,而非一習知PDS〇元件的〇.4數量級。 這是導因於一部分空乏(partially depleted,pD)場效電晶體 中的補償因子,其捕捉了摻雜的空乏深度的改變,且並不 存在於一完全空乏元件中。因此,Vt會隨著摻雜變化而更 劇烈的變化,例如一隨機摻雜波動。 此外,有另一個全新的因素(亦即本體厚度變化)需 要考1。由於極薄絕緣層上覆矽元件是完全空乏,本體厚 ,的變化則導致了在本财所含電荷的變化,而根據高斯 义律(Gauss’slaw),會造成通道電動勢的變化而改變臨界 電壓。 5午多欲改善短通道效應(short-channel effect,SCE)的 ,階電晶體架構,包含有汲極料偏壓降低咖心—以 邮low識g,mBL)以及次臨界擺幅(sub thresh〇id s:ng)。隨著電晶體變小’短通道效應便成為主要因素。 因此,如同超薄絕緣層上覆矽㈤tra thm si丨ic〇n 〇n 201203515 insulator ’ UTSOI)、極薄絕緣層上覆矽背閘極與雙閘極等 結構,應用了非常薄的石夕通道,其在操作時完全空乏主要 載體’對短通道效應提供極佳的控制。背閘極元件則可望 對於隨機摻雜波動提供解決方案,因為Vt可以由背閘極 電動勢所設定,減少對於通道摻雜的依賴。 隨著電晶體在尺寸上的進一步縮小,短通道效應則使 得縮短習知基體矽MOSFET (互補金氧半導體場效電晶 體)閘極長度的能力逐漸消失。單閘極完全空乏絕緣體上 半導體(Single Gate Fully Depleted201203515, invention: [Technical Field] The present invention relates generally to semiconductor devices, and more particularly to CMOS thin buried oxide back-thin silicon-on-insulator (ETSOI) devices To reduce the short channel effect caused by the use of metal back polarity control. [Prior Art] The size of various integrated circuit components is reduced, and transistors (e.g., field effect transistors (FETs)) have undergone significant improvements in power consumption of performance spots. These improvements can be used to reduce the size of the components used in most of them, which is so large that the capacitance resistance _ low 'and increase the output current of the transistor'. However, the performance of the device is reduced in size. Improvement, recently ΐί, will be challenged. ^^Electricity (4)^County^(4) Increased flow denaturation and (MOSFETs) are particularly large-scale semiconductor field effect transistors, and the size of FETS and other devices is reduced == domain, channel region, and gate size are also . The necessity of a shallow source/drain junction with smaller and shorter channel lengths. Desire: The body causes the pole (d〇_) to diffuse laterally into the human channel, and the shallow junction is H = the type of diffusion has a negative impact on leakage current and collapse performance. Factory: :30 nm to 丨00 nm shallow source Pole / " = It is necessary to have acceptable performance. 4 201203515 (siliCon-on-insuiator, S0I) technology allows the formation of high-speed, shallow junction devices. In addition, the insulation layer on the cover device The performance of the parasitic junction capacitance is improved by reducing the parasitic junction capacitance. In the insulating substrate, a buried oxide ' BOX film formed by tantalum oxide is formed on the single crystal stone. And forming a single crystal germanium film thereon. There are various methods for fabricating the overlying germanium on the insulating layer, one of which is separation-by-implanted oxygen (SIMOX), in which oxygen It is an ion implanted in a single crystal germanium substrate to form a buried oxide film. Another method of forming a negative layer on an insulating layer is wafer bonding, in which germanium oxide is present. The second semiconductor substrate of the surface layer is bonded to the surface of the tantalum oxide A buried oxide layer is formed between the two semiconductor substrates. The shallow junction transistor uses a shallow trench isolation (STI) technique to isolate the device and the circuit. The shallow trench isolation technology is greatly increased. Manufacturing cost, because this shallow trench isolation process requires a large number of process steps and equipment 'such as thermal oxidation, chemical vapor disposition (CVD), wet nitride wet etching, reactive ion exchange (reactive ion) Etch, RIE), high-density electrical destruction (hdp) 矽 oxide deposition, wet cleaning, chemical-mechanical polishing (CMP), and photolithography. wafer consistency and yield It is also one of the considerations, because the shallow trench isolation process requires additional processing steps. Miniaturizing CMOS components pushes the negligible parameter numbers to become important factors in circuit design. Important component parameters include short 201203515 channel control And extremeiy thin silicon-on-insulator (ETSOI) 'both are designed for this purpose The new grade of transistor "The ultra-thin insulating layer overlying tantalum is a completely depleted charge carrier transistor element (ie, at 3 〇〇K, the charge carrier concentration in the channel is on the order of 1 〇 3 atoms / cubic centimeter) Or lower), which uses an ultra-thin stone channel, where most of the carriers are fully depleted 'FD' in operation. The challenge for this class of transistors is their Vt variation and high external resistance (Rext). The FDSOI transistor threshold voltage vt is a function of the first order of magnitude of the channel dopant and changes accordingly, which also varies with the thickness of the atomic channel, rather than a conventional PDS device. Magnitude. This is due to a compensation factor in a partially depleted (pD) field effect transistor that captures the change in the depth of the doped depletion and does not exist in a fully depleted element. Therefore, Vt changes more drastically as the doping changes, such as a random doping fluctuation. In addition, there is another brand new factor (ie, variation in body thickness) that needs to be tested1. Since the 矽 element on the extremely thin insulating layer is completely depleted, the thickness of the body changes, which leads to the change of the charge contained in the financial position. According to the Gauss's law, the change of the channel electromotive force changes the criticality. Voltage. 5 noon want to improve the short-channel effect (SCE), the order of the crystal structure, including the bungee bias bias to reduce the heart - post low g, mBL) and sub-threshold swing (sub thresh 〇id s:ng). As the transistor becomes smaller, the short channel effect becomes a major factor. Therefore, as the ultra-thin insulating layer is covered with 矽 (5) tra thm si丨ic〇n 〇n 201203515 insulator ' UTSOI), the ultra-thin insulating layer is covered with a back gate and a double gate, and a very thin stone channel is applied. It is completely depleted during operation. The main carrier' provides excellent control of the short channel effect. The back gate component is expected to provide a solution for random doping fluctuations because Vt can be set by the back gate electromotive force, reducing the dependence on channel doping. As the size of the transistor is further reduced, the short channel effect reduces the ability to shorten the gate length of conventional MOSFETs (complementary MOSFETs). Single Gate Fully Depleted Insulator Semiconductor (Single Gate Fully Depleted
Semiconductor-on-insulator,Single Gate FDSOI)技術已經 被確s忍為用以減少短通道效應以及降低非理想寄生電容 的解決方法之一。然而,此單閘極FDSOI技術可能需要 嚴格的厚度要求以及對絕緣層上的石夕薄膜有均勻一體的 控制,才能達成完全空乏。此外,上述的汲極誘發虛擬基 板偏壓(drain induced virtual substrate biasing,DIVSB)效 應對於單閘極FDSOI技術而言是另一個挑戰。相對地, 雙閘極FDSOI技術可能對於絕緣層上之一半導體厚度有 較不嚴格的要求,可減少沒極誘發虛擬基板偏壓效應,並 可能維持較佳的短通道效應控制以及高轉導 (trans-conductance)。 作為說明並參照至圖1,圖中有一先前技術的極薄絕 緣層上覆矽,其在一基板100之上包括有一埋藏氧化物層 110,在此埋藏氧化物層之上包括有一極薄絕緣層上覆矽 層丨20 ’並在此極薄絕緣層上覆矽層之上包括有一閘極堆 。此閘極堆豐包括一咼介電常數氧化物層丨y位於極薄 絕緣層上覆矽層之上、接著是一高介電常數金屬閘極 201203515 層132、其覆蓋在高介電常數氧化物層之上。 心、’屬區域133係位於高介電常數金屬閘極層之上。每一 /f ^ d 130 ( raised source/drain regions » RSD ) 糸位於極薄絕緣層上覆碎層之上,並接觸至間隙壁。 ㈣Ϊ—第 — 面向中,本發明之—實關描述了一種新穎 战者閘極鎢與洋層源極/沒極區域(RSD)13〇置於極薄絕緣 層上覆矽層之上而與間隙壁15〇接觸。 S知的極薄絕緣層上㈣元件具有—厚埋藏氧化物 (BOX)105 ’經過實驗顯示短通道效應(SCE)僅可改良約 20至40%。隨著HKMG閘極堆疊尺寸的進一步縮小,需 要更佳的短通道效應控制。 ,極薄絕緣層上覆矽層105的厚度介於6奈米至2〇奈 米之間。由於極薄絕緣層上覆矽層1〇5,主動源極汲極與 擴充區域的經驗造成了摻雜劑佈植與活化退火(activati〇n annealing)的難度。雖然佈植仍可進行,但由於缺乏了矽再 結晶(re-crystallization)使得只有部分的摻雜劑受到活 化。來自兩個主動區域的片電阻(sheet resistance)被大幅 k幵’使彳于其靜電性此嚴重劣化。使用一浮層源極/汲極區 域(RSD)130可以用來部分改良此問題,但是擴充電阻才 是性能劣化的主要因素。原位摻雜的浮層源極/汲極是另一 用於極薄絕緣層上覆矽元件的技術,且高快速熱退火 (rapid thermal annealing,RTA)溫度係整合於其中,以降低 電阻並驅動在HKMG堆疊之下的摻雜劑。由於滷素佈植 不適用於良好的Vt控制’造成高vt以及元件貫穿 (punch-through)。 201203515 根據上述的考量,則需要有且有分離呰、 二:的緣層上“件’其丄二= 二:::::得,⑽一本 【發明内容】 在第一面向中,本發明揭露一種新穎的 取允許具纽訊能觸選 本發明之—實施例揭露—極薄絕緣層 ^石夕+ ¥體7C件其具有—薄絕緣層,其包括了薄氧化物 與亂化物絕緣體。此實施例描述了 —極薄絕緣層上覆石夕半 導體70件其在-纟!層或作用為背閘極的薄膜之上,包括一 ,,化物與氮氧化物絕緣體。考量到當溫度高於600。(:且 氧氣存在的情形下可能形成氧化!!,使用制有特別的相 關性。本發明的基本結構包括並保護鎢薄膜,而避免上述 氧化鎢的形成。 在又一面向中,本發明一實施例提供了一極薄絕緣層 上覆石夕局”電'吊數金屬間極(MGHK)完全空乏絕緣層上 覆矽元件(FDSOI),其中鎢背閘極係被一低電阻薄膜氮化 物所包覆以避免在製造過程中形成金屬氧化物。此極薄絕 緣層上覆矽與超薄埋藏氧化物提供了一具有優秀短通道 控制的半導體結構,並大幅改善了汲極誘發偏壓降低 (dram induced bias 丨owering,D1BL)以及次臨界擺幅 (sub-threshold swing)。此半導體結構包括具有背閘極金屬 201203515 的 離 nFET以及PFET,其係由一 ’並且可被獨立施加偏壓。 淺溝槽隔離結構(STI)所隔 *在另一面向中,本發明一實施例提供了一種用以形 一薄埋藏氧化物金屬背閘極極薄絕緣層上覆矽元件的方 法,包括:提供一具有一極薄絕緣層上覆矽之基板, 層上覆矽位於一薄二氧化矽之上的厚度介於6至8奈米, 較佳於10奈米範圍内’以及—極薄梦氮化物層較佳介 於5至10奈米之間,接著是一鶴層其厚度介於1〇至 奈米之間’接著是在厚度介於5 i 1()奈米之極薄石夕氮化 物沉積於一厚埋藏氧化物之上,較佳係由二氧化矽所構成 並在矽基板之上具有介於13〇奈米至2〇〇奈米之深产。一 淺溝槽隔離結構(sti)在pFET以及nFET元件之間^供一 隔離障礙。反應性離子餘刻(reactive i〇n etching,R正)係 用於將-溝槽向下開洞至埋藏氧化物層,並以錢化物作 為隔離。此賴接著以氧化物填充。極薄絕緣層上 件的PFET以及戯丁係利用在犯主動區域中的浮層源極 與及極(RSD)所製造。彻反應性離子似彳將溝槽開洞, 以接觸至背閘極金屬。接著形成一 _壁(spacer)以在浮層 源極與汲極和背閘極金屬之間提供隔離。 2 蒸發金屬填滿而作為背閉極接點。 被 在另一面向中,本發明一實施例提供了 一極薄絕緣層 上覆石夕(ETSOI)元件,其包括—第—埋藏氧化物(Β〇χ) 層位於-絲板之上以及—金屬層其健該Β〇χ 頂上與下薄氮化物層所包圍;一薄第二β〇χ位於該 亡薄鼠化物層之上’以及—薄絕緣層上覆碎層疊置於該薄 弟二BOX之上,其中該第二_層、該上薄氮化物層、 10 201203515 以及該薄絕緣層上覆矽層係接觸至一間隙壁(spacer);以及 一場效電晶體,其具有一閘極堆疊位於該薄絕緣層上覆矽 層之上,該閘極堆疊包括一介電層位於該閘極堆疊之佔用 面積(footprint),該介電層具有該薄絕緣層上覆矽層作為通 在5玄%效電晶體之凹陷通道(recesse(j channel)。 本發明之其他目標、特徵以及優點可由以下的詳細說 明而更臻明顯。需注意的是,詳細說明以及特定實施例雖 用以指出本發明的較佳實施方式,係僅作為說明,且本發 明的各種不同變化可以自然地被實現而不脫離本發明之 範疇。 【實施方式】 接著將以下列有關於本發明之討論與圖示進行本發 ,的詳細說明。請注意本說明書的圖示係僅作為說明用 通二因此並未按照比例。在下列說明中,描述了許多特定 細節以提供對於本發明的徹底瞭解,包括特定結構、成分 與材料、尺寸、製程步驟以及技術等。然而,熟悉該項技 ,者可以理解的是’不需要這些特定細節即可實施本發 明。在其他方面,則不詳述習知的結構或製程步驟,以避 免模糊本發明。 、匕^外可以理解的是當一例如層、區域或基板的元件 =才曰%為位於另一元件「上」或「之上」,可以是直接位 、 元件之上’或者其他介於之間的元件同時存在。相 ^地^當—元件被指稱為「直接位於另一元件上」或「直 位於另一元件之上」,則沒有介於之間的元件。同時可 201203515 以理解的是,當—元件被指稱為「連接至」或「麵合至」 另一 70件,其可直接連接至或耦合至另一元件,或者可能 有中間元件存在。相反地,當一元件被指稱為「直接連接 至」或「直接耦合至」另一元件,則沒有中間元件。 一圖2至9描述了根據本發明一實施例中各製程步驟的 ,不半導體結構,這些步驟較佳係用於形成一具有一薄埋 藏氧化物金屬背閘極極薄絕緣層上覆矽元件之半導體元 件。 以下描述此極薄絕緣體上覆矽半導體元件,其具有從 極薄絕緣層上覆矽選擇性磊晶矽長並具有金屬背閘極 (BG),較佳係由鎢所構成因為鎢的特徵是低電阻,其中 此背閘極係由極薄魏化物層所保護。本發明之此實施例 ,其他實施方式藉由施加一電壓至此金屬背閘極以調控 前閘極臨界電壓vt ’以減少短通道效應(SCE)。臨界電壓Semiconductor-on-insulator (Single Gate FDSOI) technology has been proven to be one of the solutions to reduce short-channel effects and reduce non-ideal parasitic capacitance. However, this single-gate FDSOI technique may require strict thickness requirements and uniform control of the Shishi film on the insulating layer to achieve complete depletion. In addition, the above-described drain induced virtual substrate biasing (DIVSB) effect is another challenge for single-gate FDSOI technology. In contrast, the dual-gate FDSOI technique may have less stringent requirements on the thickness of a semiconductor on the insulating layer, which may reduce the bias induced virtual substrate bias effect and may maintain better short channel effect control and high transduction ( Trans-conductance). By way of illustration and reference to FIG. 1, there is a prior art ultra-thin insulating layer overlying germanium comprising a buried oxide layer 110 over a substrate 100, including a very thin insulating layer over the buried oxide layer. The layer is covered with a layer of germanium 20' and includes a gate stack over the layer of germanium on the very thin insulating layer. The gate stack includes a dielectric constant oxide layer 丨y over the overlying insulating layer on the very thin insulating layer, followed by a high dielectric constant metal gate 201203515 layer 132, which is covered by high dielectric constant oxidation. Above the object layer. The core, 'genus region 133 is located above the high dielectric constant metal gate layer. Each /f ^ d 130 (raised source/drain regions » RSD ) is placed over the overlying layer of the very thin insulating layer and contacts the spacer. (4) Ϊ—第—in the face-to-center, the present invention describes a novel warrior gate tungsten and oceanic source/drain region (RSD) 13〇 placed on the ultra-thin insulating layer over the 矽 layer The spacer 15 is in contact with each other. The (4) component on the very thin insulating layer of S has a thick buried oxide (BOX) 105'. It has been experimentally shown that the short channel effect (SCE) can only be improved by about 20 to 40%. As the HKMG gate stack size is further reduced, better short channel effect control is required. The thickness of the overlying germanium layer 105 on the very thin insulating layer is between 6 nm and 2 nm. Due to the ultra-thin insulating layer overlying the germanium layer 1〇5, the experience of active source drain and extended regions has made it difficult to implant and activate the annealing. Although implantation is still possible, only a portion of the dopant is activated due to the lack of re-crystallization. The sheet resistance from the two active regions is greatly k幵', which is seriously deteriorated due to its electrostatic properties. The use of a floating source/drain region (RSD) 130 can be used to partially improve this problem, but the expansion resistor is a major factor in performance degradation. The in-situ doped floating layer source/drain is another technique for overlying the germanium element on the very thin insulating layer, and a rapid thermal annealing (RTA) temperature system is integrated therein to reduce the resistance and The dopant is driven under the HKMG stack. Since halogen implants are not suitable for good Vt control, high Vt and punch-through are caused. 201203515 According to the above considerations, it is necessary to have and have separate 呰, two: on the edge layer "pieces" 丄 = = = 2::::: 得, (10) one [invention] In the first aspect, the present invention It is disclosed that a novel allowable touch can be used to select the present invention - an embodiment disclosed - an extremely thin insulating layer, a thin layer of insulating material, which comprises a thin oxide and a disordered insulator. This embodiment describes that a very thin insulating layer overlying a 70-layer of a semiconductor layer on a film or a gate electrode, including a compound and an oxynitride insulator, is considered to have a high temperature. In the case of 600: (and oxygen may form oxidization!!, the use of the system has a special correlation. The basic structure of the present invention includes and protects the tungsten film while avoiding the formation of the above tungsten oxide. An embodiment of the present invention provides a very thin insulating layer overlying a stone-like "electrical" hanging metal inter-electrode (MGHK) completely depleted insulating layer overlying germanium element (FDSOI), wherein the tungsten back gate is a low resistance Thin film nitride coated to avoid fabrication The formation of a metal oxide. The ultra-thin buried oxide on the ultra-thin insulating layer provides a semiconductor structure with excellent short-channel control and greatly improves the buckling-induced bias reduction (dram induced bias 丨owering, D1BL). And a sub-threshold swing. The semiconductor structure includes an off-nFET and a PFET having a back gate metal 201203515, which is biased by a '' and can be independently biased. Shallow trench isolation structure (STI) In another aspect, an embodiment of the present invention provides a method for forming a thin buried oxide metal back gate very thin insulating layer overlying germanium element, comprising: providing a thin insulating layer The substrate is covered, and the thickness of the layer on the layer is between 6 and 8 nm, preferably in the range of 10 nm, and the thin layer of nitride is preferably between 5 and 10. Between the nanometers, followed by a layer of heavier between 1 〇 and nanometers' followed by a thin layer of nitrides deposited in a thick burial oxide at a thickness of 5 i 1 () nanometers. Preferably, it is composed of cerium oxide There is a deep production of 13 〇 nanometers to 2 〇〇 nanometers on the ruthenium substrate. A shallow trench isolation structure (sti) provides an isolation barrier between the pFET and the nFET element. Reactive ion remnant ( Reactive i〇n etching, R positive) is used to open the trench to the buried oxide layer and isolate it with the bulk material. This is then filled with oxide. The PFET of the very thin insulating layer is The pedestal is made by the source and the pole (RSD) of the floating layer in the active area. The reactive ions resemble the opening of the trench to contact the back gate metal. Then a _ wall is formed. ) to provide isolation between the source of the floating layer and the drain and back gate metal. 2 The vaporized metal fills up as a back-closed junction. In another aspect, an embodiment of the present invention provides an extremely thin insulating layer overlying stone (ETSOI) device including a -first buried oxide (germanium) layer over the wire plate and - The metal layer is surrounded by the top and bottom thin nitride layers; a thin second β〇χ is located on the thin layer of the mouse layer and the thin insulating layer is overlaid on the thin layer. Above the BOX, wherein the second layer, the upper thin nitride layer, 10 201203515, and the thin insulating layer overlying the germanium layer are in contact with a spacer; and a field effect transistor having a gate The stack is disposed on the thin insulating layer over the germanium layer, the gate stack includes a footprint of the dielectric stack on the gate stack, the dielectric layer having the thin insulating layer overlying the germanium layer as a pass The other objects, features, and advantages of the present invention will become more apparent from the following detailed description. It should be noted that the detailed description The preferred embodiments of the present invention are for illustrative purposes only. The various changes of the present invention can be naturally achieved without departing from the scope of the present invention. [Embodiment] The following detailed description of the present invention will be made in the following discussion of the present invention. The drawings are to be regarded as illustrative only, and are not intended to However, it will be understood by those skilled in the art that the present invention may be practiced without these specific details. In other respects, conventional structures or process steps are not described in detail to avoid obscuring the invention. It can be understood that when a component such as a layer, region or substrate is "on" or "above" another element, it can be a direct bit, a component above or other intervening component. Existence. When the component is referred to as "directly on another component" or "directly on top of another component", there is no intervening element. It is also understood that at the same time, 201203515, when the element is referred to as "connected to" or "faced to" another 70 pieces, it may be directly connected or coupled to another element, or there may be intermediate elements present. In contrast, when an element is referred to as being "directly connected to" or "directly coupled to" another element, there is no intermediate element. Figures 2 through 9 depict steps in various processes in accordance with an embodiment of the present invention, not semiconductor Structure, these steps are preferably used to form a semiconductor component having a thin buried oxide metal back gate very thin insulating layer overlying germanium element. The following describes an extremely thin insulator overlying germanium component having a very thin insulating The layer is coated with a selective epitaxial length and has a metal back gate (BG), preferably consisting of tungsten because tungsten is characterized by low resistance, wherein the back gate is protected by an extremely thin, far-dyed layer. In this embodiment of the invention, other embodiments reduce the short channel effect (SCE) by applying a voltage to the metal back gate to regulate the front gate threshold voltage vt'. Threshold voltage
Vt變化的控制係由此薄絕緣層上覆矽的厚度與摻雜劑 (dopant)所提供。 圖2描述了可以用於本發明一實施例的一初始結構。 此初始結構可包括一極薄絕緣層上覆矽(s〇I)層1〇〇,以下 稱為極薄絕緣層上覆矽通道或ETS〇I,其係位於極薄n 埋藏氧化物(BOX)層1〇1之上。在此埋藏氧化物1〇1之 下,一極薄矽氮化物1〇2係用以保護一金屬背閘極(BG) 103不至於層化(delaminate)。以第二極薄埋藏介電質,矽 氮化物104係被沉積以包覆金屬背閘極丨〇3並將其與一厚 埋藏氧化物(BOX) 1〇5隔離,其厚度係較佳介於丨4〇奈 米至200奈米的數量級。最後,加入一矽基板丨〇6以作為 201203515 一處理基板。 料所Z tif 板⑽可餘何半導體材 ^戶斤構成^包括但不限於,碎、錯、梦錯1碳、補碳、 石申化鎵、氮化鎵、石申化銦、磷化銦、以 族或nm族化合物半導體。半導體基板1〇6也可包括一 有機半導體或一層化半導體,例如矽/碎鍺。 通道議的厚度為大約3奈米至奈米,並 係k於相藏氧化物1()1之上,較佳厚度介於8奈米至 奈米之間。厚度較佳為1G奈米至2G奈米之間的金屬背 閘f(BG)層104,係被包覆於一上薄石夕氮化物層1〇2與一 下薄石夕氮化物層104之間’每一層的厚度較佳介於5奈米 至10奈米之間,保護背閘極層不會層化。 參照至圖3,此初始結構包括一第一凹陷,其係形成 於ETSOI通道1〇〇並下陷至厚埋藏氧化物i〇s以及石夕氣 化物108的隔離襯底,隔離金屬背閘極1〇4與ets〇i通 道層100。氧化物107 i真人此凹陷而形成一淺溝槽隔離結 構(STI) 〇 友仍參照至圖3,較佳厚度為7奈米以下的此二層極薄 矽氮化物層102與1〇4,係各設置於金屬背閘極(BG) 1〇4The control of the change in Vt is thus provided by the thickness of the overlying thin layer of the insulating layer and the dopant. Figure 2 depicts an initial structure that can be used in an embodiment of the invention. The initial structure may include a very thin insulating layer overlying 矽(s〇I) layer 1〇〇, hereinafter referred to as an ultra-thin insulating layer overlying germanium channel or ETS〇I, which is located in a very thin n buried oxide (BOX) ) Above layer 1〇1. Under the buried oxide 1〇1, a very thin tantalum nitride 1〇2 is used to protect a metal back gate (BG) 103 from delaminate. With a second very thin buried dielectric, a tantalum nitride 104 is deposited to coat the metal back gate 3 and is isolated from a thick buried oxide (BOX) 1〇5, the thickness of which is preferably between丨 4 〇 nanometer to the order of 200 nanometers. Finally, a substrate 丨〇6 was added to process the substrate as 201203515. The material of the Z tif board (10) can be composed of any semiconductor material, including but not limited to, broken, wrong, dreamy, 1 carbon, carbon supplement, stellite gallium, gallium nitride, indium sulphide, indium phosphide A group or a group of compound semiconductors. The semiconductor substrate 1 6 may also include an organic semiconductor or a layered semiconductor such as tantalum/mash. The thickness of the channel is about 3 nm to nanometer and k is above the phase 1 oxide 1, preferably between 8 nm and nanometer. A metal back gate f (BG) layer 104 having a thickness of preferably between 1 G nm and 2 G nm is coated on a thin layer of thin silicon nitride layer 1 〇 2 and a thin layer of thin silicon nitride layer 104 The thickness of each layer is preferably between 5 nm and 10 nm, and the back gate layer is not layered. Referring to FIG. 3, the initial structure includes a first recess formed in the ETSOI channel 1〇〇 and recessed to the thick buried oxide i〇s and the isolated substrate of the Xixi vaporization 108, the isolated metal back gate 1 〇4 and ets〇i channel layer 100. The oxide 107 i is recessed to form a shallow trench isolation structure (STI). Still referring to FIG. 3, the two-layer ultra-thin tantalum nitride layers 102 and 1 4 having a thickness of 7 nm or less are preferably used. Each set is set on the metal back gate (BG) 1〇4
之上與之下。在本發明—實施例中,一薄絕緣體氮化矽襯 底108將背閘極1〇4與淺溝槽絕緣體(STI)氧化物填充 物丨07隔離,其中ST]作用為位於後續的pFET與nFET 元件(未示)之間的隔離屏障。 201203515 凊參照至圖4,其顯示一金氧互補半導體場效電晶體 (MOSFET)半導體元件之—側視剖面圖。此初始元件上 提供有-閘極堆叠其包括—高介電f數氧化物層131於凹 陷ETSOI通道曾的上表面之上,並接著在此高介電常數 氧化物層之上a又置一咼介電常數金屬閘極(MGHK) 。 此較佳係由鎢133所構成的金屬區域(因為鎢的低電阻) 係位於MGHK層的上方。此閘極堆疊的閘極介電質可包 括一氧化物、一氮化物、一氮氧化物、或上述的多層堆疊。 问介電々數介電材料包括但不限於,氧化給(Hf〇2)、 氧化锆(Zr〇2)、氧化鑭(La2〇3)、氧化鋁(Al2〇3)、氧化鈦 (Ti〇2)、鈦酸鳃(srTi〇3)、鋁酸鑭(LaA1〇3)、氧化釔(Υ2〇3)、 氮氧化铪(Hf^)xNy)、氮氧化鍅(Zr〇xNy)、氮氧化鑭 (La2OxNy)、氣氧化紹(八12〇為)、氮氧化鈦(Ti〇為)、氮氧 化鈦锶(SrTiOxNy)、氮氧化鋁鑭(LaA1〇xNy)、氮氧化釔 (Y2〇xNy)、上述之任一石夕酸鹽、以及上述之任一合金。 此互補金氧半導體場效電晶體元件(MOSFET)更包 括一源極區域與一汲極區域(未示)位於ETS〇I通道 之内、在閘極堆疊所佔面積的位置。此閘極堆疊可以利用 沉積多種材料層、光微影並蝕刻之後而形成。或者,可以 利用一替代閘極製程以形成此閘極堆疊。 位於ETSOI層之中的通道區域係直接位於閘極堆疊 的下方、介於MOSFET的源極區域與汲極區域之間。^ >間隙壁丨係接著附加於閘極堆疊的側壁之上。在一 主動源極-汲極(SD)區域之中,係加上一浮層源極與汲 極(RSD)丨30並接觸至間隙壁。 、 14 201203515 ^圖5係為描繪形成背閘極層(BG)的示意圖。較佳 係以反應性離子蝕刻(RIE)而蝕刻一溝槽,並停止於背 閘極層104之上。接著形成一大約1〇至15奈米厚的一厚 間隙壁110 ’以隔離ETS0I場效電晶體元件以及主動浮層 源極-汲極區130。接著繼續進行反應性離子蝕刻製程以將 一溝槽向下開洞至埋藏氧化物層,並以矽氮化物作為一隔 離層。此溝槽接著以一氧化物沉積而填滿。 的極薄絕緣層上覆碎(ETS〇I)元件均較佳以此方式製 成,並在源極·汲極主動區域中包括有一浮層源極盥汲極 (RSD) 130 〇 ' 圖6係為描繪從背閘極溝槽填入金屬填充12〇的示意 圖’較佳湘-選擇㈣填域其他均等的金屬,並以蒸 鑛方式(evaporation)形成。 、 、圖7係為ETS0I元件的側視圖,描綠在源極_沒極區 域中具ί月閘極(BG)的浮層源極與浮層汲極(RSD)130, 並以極薄魏化物層倾叫免層化。接著以反應性離子 钱刻打開接點溝槽以接駐t雜金屬。此接點溝槽較佳 係以蒸鍍金屬填充作為背閘極接點。 ET:此:Γ之後,可使用習知的製程形成包括有此Above and below. In the present invention-embodiment, a thin insulator tantalum nitride substrate 108 isolates the back gate 1〇4 from the shallow trench insulator (STI) oxide fill 丨07, where ST] acts as a subsequent pFET and An isolation barrier between nFET components (not shown). 201203515 Referring to Figure 4, there is shown a side cross-sectional view of a metal oxide complementary semiconductor field effect transistor (MOSFET) semiconductor device. The initial element is provided with a gate stack including a high dielectric f-number oxide layer 131 over the upper surface of the recessed ETSOI channel, and then a further over the high dielectric constant oxide layer咼 Dielectric constant metal gate (MGHK). This preferred metal region consisting of tungsten 133 (because of the low resistance of tungsten) is located above the MGHK layer. The gate dielectric of the gate stack may comprise an oxide, a nitride, an oxynitride, or a multilayer stack as described above. The dielectric dielectric materials include, but are not limited to, oxidized (Hf 〇 2), zirconia (Zr 〇 2), lanthanum oxide (La 2 〇 3), alumina (Al 2 〇 3), titanium oxide (Ti 〇 2), barium titanate (srTi〇3), barium aluminate (LaA1〇3), barium oxide (Υ2〇3), barium oxynitride (Hf^)xNy), strontium oxynitride (Zr〇xNy), oxynitridation镧(La2OxNy), gas oxidation (eight 〇12〇), titanium oxynitride (Ti〇), TiO3锶, LaA1〇xNy, Y2〇xNy Any of the above-mentioned salts, and any of the above alloys. The complementary MOS field effect transistor (MOSFET) further includes a source region and a drain region (not shown) located within the ETS 〇I channel at a location occupied by the gate stack. This gate stack can be formed by depositing a plurality of material layers, photolithography, and etching. Alternatively, an alternate gate process can be utilized to form the gate stack. The channel region located in the ETSOI layer is directly below the gate stack and between the source and drain regions of the MOSFET. ^ > The spacer tether is then attached to the sidewall of the gate stack. In an active source-drain (SD) region, a floating source and drain (RSD) 丨 30 is applied and contacts the spacer. 14, 201203515 ^ Figure 5 is a schematic diagram depicting the formation of a back gate layer (BG). Preferably, a trench is etched by reactive ion etching (RIE) and stopped on the back gate layer 104. A thick spacer 110' of about 1 〇 to 15 nm thick is then formed to isolate the ETS0I field effect transistor component and the active floating source source-drain region 130. A reactive ion etching process is then continued to tunnel a trench down to the buried oxide layer with germanium nitride as a spacer layer. This trench is then filled with an oxide deposit. The ultra-thin insulating layer-on-chip (ETS〇I) elements are preferably fabricated in this manner and include a floating source drain (RSD) 130 〇' in the source/drain active region. It is a schematic diagram depicting the filling of a metal-filled 12 从 from the back gate trenches. The other is equivalent to the metal, and is formed by evaporation. Figure 7 is a side view of the ETS0I component, depicting the floating source and floating layer drain (RSD) 130 of the ί 月 gate (BG) in the source _ immersed region, and is extremely thin The layer is tilted to avoid stratification. The contact trench is then opened with a reactive ion to pick up the t-metal. The contact trench is preferably filled with a vapor-deposited metal as a back gate contact. ET: This: After Γ, you can use the known process to form including this
兀=的積體電路的剩餘部分。薄間隙壁允許ETS0I σ间"電㊉數介電質與金屬閘極堆疊以及磊晶浮 1=/汲極。所構築的結構提供了 _ ETS0高介電常數金 由二pMG叫元全空乏S01 S件,其中金屬背問極係 、氬化物低電阻所包覆,防止在製造過程中發生金屬 乳此ETSO以及薄埋藏氧化物提供給此半導體結構優 201203515 1的紐通道控制,其大幅改良了汲極誘發偏壓降低以及次 臨界擺幅。本發明一實施例的半導體結構包括了 nFET與 pFET背閘極元件,且可獨立施加偏壓。 圖8顯示了利用極薄矽氮化物1〇2與1〇4將背閘極金 屬鎢103隔離以避免氧化,其中金屬鎢層1〇3因為鎢氧化 物的體積擴張而離層化(deiaminates )。此處使用了核反 應性分析(nuclearreactive analysis ’ NRA)以確認在鎢上所 /儿積的二層不同薄膜的氮濃度。在鎢表面的二氧化矽與矽 均未發現任何氮濃度。極薄矽氮化物9A提供了 0el5 [N] 以作為充足的保護且未發生氧化。 圖9描繪了用以確認極薄矽氮化物薄膜的存在以保護 金屬鎢背閘極的歐傑分析(Auger analysis)。一樣本係由一 二氧化矽表面上之一鎢層之上的矽氮化物薄膜9A所構 ,。在一矽氮化物表面之上沉積一金屬鈷覆蓋層,以進行 厚度分析。此歐傑分析結果顯示了在金屬鈷覆蓋層與鎢表 面之間有一明顯的氮峰值,且並未偵測到氧。相對地,在 鎮與二氧切的接面並未侧到氮,此處特意忽略了薄石夕 氮化物。此分析結果制的結論是,麵表面之上沉積極 薄矽氮化物9A可完全避免氧化且無氧化的發生。 總而言之,以此方法所構築的結構將短通道效應降到 最低。因此,絕緣層上覆矽通道的厚度極薄是非常重要 的。當此薄絕緣層上覆矽的厚度與背閘極層合併在一起, 二者的結合有效地控制了短通道效應以及其中的摻雜 劑。此外,ETSO】高介電常數金屬背閘極完全空乏元件愈 溥埋藏氧化物的結合’不只提供了優良的短通道控制,同 201203515 時大幅降低了汲極誘發偏壓以及次臨界擺幅β 在不脫離本發明精神或必要特性的情況下,可以其他 特定形式來體現本發明。應將所述具體實施例各方面僅視 為解說性而非限制性。因此,本發明的範嘴如隨附申請專 利範圍所示而非如前述說明所示。所有落在申請專利範圍 之等效意義及範圍内的變更應視為落在申請專利範圍的 範疇内。 【圖式簡單說明】 為了立即瞭解本發明的優點,請參考如附圖所示的特 定具體實施例,詳細朗上文簡短敘述的本發明^在瞭解 這些圖不僅描繪本發明的典型具體實施例並因此不將其 視為限制本發明料的情況下,參考附圖以額外的明確性 及細節來說明本發明,圖式中: 圖1為一先前技術極薄絕緣層上覆矽(ETSOI)電曰 體之侧剖面圖; ,2,據本發明—具體實_之一 絕緣層上覆矽基板之側剖面圖; 極/寻 圖3為-第-製程步驟以及對應的 槽隔離結構(STI); Χ久眞 圖=為下一製程步驟,其中形成了 質與金屬背閘極; ^ 驟 圖 描、0 了开乂成月閘極接點與對應的間隙壁的製程步 圖6為沉積金屬填充以接觸至背閘極的步驟; 圖7為根據本發明—具體實施例之最終結構之側剖面 17 201203515 圖,說明了此元件與相伴的介層窗孔接點; 圖8為一核反應分析結果圖,此分析係施加至極薄氮 化物層以及背閘極鎢層介面;以及 圖9係為本發明結構之歐傑分析圖(Auger profile)以 及鎢與鈷覆蓋層介面的分析結果顯示沒有氧化的發生。 【主要元件符號說明】 100基板 101埋藏氧化物層 102極薄石夕氮化物 103金屬背閘極 104第二極薄埋藏介電質 105埋藏氧化物 106梦基板 108薄絕緣體氮化矽襯底 110埋藏氧化物層 120極薄絕緣層上覆矽層 130浮層源極/汲極區域(rSd) 131氧化物層 132兩介電常數金屬閘極 133金屬區域 150間隙壁兀 = the remainder of the integrated circuit. The thin spacers allow ETS0I σ between “electrical dielectric and metal gate stacking and epitaxial floating 1=/汲. The constructed structure provides _ ETS0 high dielectric constant gold by two pMG called full-empty S01 S parts, in which the metal back interrogation system, argon low resistance is coated to prevent metal emulsification and ETSO during the manufacturing process. The thin buried oxide provides the new channel control of the semiconductor structure excellent 201203515 1 , which greatly improves the buckling induced bias reduction and the sub-threshold swing. A semiconductor structure in accordance with an embodiment of the present invention includes nFET and pFET back gate elements and can be independently biased. Figure 8 shows the use of very thin tantalum nitrides 1〇2 and 1〇4 to isolate the back gate metal tungsten 103 from oxidation, wherein the metal tungsten layer 1〇3 is de-layered due to the volume expansion of the tungsten oxide. . Here, a nuclear reactive analysis (NRA) was used to confirm the nitrogen concentration of the two different films deposited on tungsten. No nitrogen concentration was observed for both cerium oxide and cerium on the tungsten surface. Very thin tantalum nitride 9A provides 0el5 [N] as sufficient protection and no oxidation. Figure 9 depicts an Auger analysis to confirm the presence of a very thin tantalum nitride film to protect the metal tungsten back gate. A sample is constructed of a tantalum nitride film 9A over a tungsten layer on the surface of a germanium dioxide. A metallic cobalt coating was deposited over the surface of the nitride to perform thickness analysis. This Auger analysis showed a significant nitrogen peak between the metallic cobalt coating and the tungsten surface and no oxygen was detected. In contrast, the junction between the town and the dioxin is not lateral to the nitrogen, and the thinner diarrhea is specifically ignored here. The results of this analysis concluded that the deposition of very thin tantalum nitride 9A over the surface of the surface completely prevented oxidation and no oxidation. All in all, the structure constructed by this method minimizes the short channel effect. Therefore, it is very important that the thickness of the overlying channel on the insulating layer is extremely thin. When the thickness of the overlying germanium layer is combined with the back gate layer, the combination of the two effectively controls the short channel effect and the dopant therein. In addition, ETSO] high dielectric constant metal back gates are completely vacant components, and the combination of buried oxides' provides not only excellent short-channel control, but also significantly reduces the buckling-induced bias and sub-threshold swing β at 201203515. The present invention may be embodied in other specific forms without departing from the spirit and scope of the invention. The aspects of the specific embodiments are to be considered as illustrative and not restrictive. Therefore, the scope of the present invention is shown as the scope of the accompanying application patent and is not as shown in the foregoing description. All changes that fall within the meaning and scope of the patent application are deemed to fall within the scope of the patent application. BRIEF DESCRIPTION OF THE DRAWINGS In order to immediately understand the advantages of the present invention, reference is made to the specific embodiments illustrated in the accompanying drawings, The invention will be described with additional clarity and detail with reference to the accompanying drawings in which: FIG. 1 is a prior art ultra-thin insulating layer overlying crucible (ETSOI). A side cross-sectional view of an electric raft; 2, according to the present invention - a side view of a substrate covered with an insulating layer; a pole/seeking 3 is a - the first process step and a corresponding slot isolation structure (STI ; 眞 = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = The step of metal filling to contact the back gate; Figure 7 is a side cross-section of the final structure 17 201203515 in accordance with the present invention, illustrating the contact of the element with the associated via hole; Figure 8 is a nuclear reaction Analysis result graph, this analysis system The addition to the very thin nitride layer and the back gate tungsten layer interface; and Figure 9 is an Auger profile of the structure of the present invention and the analysis of the tungsten and cobalt overlayer interface shows no oxidation. [Main component symbol description] 100 substrate 101 buried oxide layer 102 extremely thin silicon nitride 103 metal back gate 104 second very thin buried dielectric 105 buried oxide 106 dream substrate 108 thin insulator tantalum nitride substrate 110 Buried oxide layer 120 very thin insulating layer overlying germanium layer 130 floating layer source/drain region (rSd) 131 oxide layer 132 two dielectric constant metal gate 133 metal region 150 spacer