TW201204397A

TW201204397A - Hair cosmetic composition, method for using same, and hair-cosmetic-related product

Info

Publication number: TW201204397A
Application number: TW100117120A
Authority: TW
Inventors: Yuki Sasao; Namiko Fujishiro
Original assignee: Hoyu Kk
Priority date: 2010-07-28
Filing date: 2011-05-16
Publication date: 2012-02-01
Also published as: JP2012031072A; WO2012014570A1; CN103140210A; JP5762701B2; TWI531378B

Abstract

Disclosed is a hair cosmetic composition that is made into a foam by a non-aerosol foamer container and applied to hair. Said composition produces a good foam, coats well, and does not drip off during application. Said hair cosmetic composition contains: (A) at least 10% by mass of a non-ionic surfactant; (B) a cationic surfactant; and (C) at least one surfactant selected from among anionic surfactants and ampholytic surfactants.

Description

201204397 六、發明說明：【發明所屬之技術領域】本發明涉及毛髮化妝品組合物、其使用方法及毛髮化妝用品。更具体而言，本發明涉及通過非氣膠劑成型容器 (/ — 才一 v —容器）形成泡狀劑型来使用的毛髮化妝品组合物、其使用方法及含有該毛髮化妝品组合物和非氣膠劑成型容器而構成的毛髮化妝用品。【先前技術】已知在使用時將染髮劑或毛髮的脫色、脫染劑等毛髮化妝品形成泡狀劑型來使用。若以泡狀劑型使用這些毛髮化妝品，則可期待以下優點：易於無斑點而均勻地塗佈於毛髮上；即使不使毛髮化妝品呈高粘度化，在塗佈於毛髮上時也可防止滴落；可省去廣泛使用的凝膠狀或乳膏狀毛髮化妝品在使用時的毛髮粘連的煩惱等。以泡狀劑型使用的毛髮化妝品可大致分為氣膠劑型和非氣膠劑型。氣膠劑型使用液化氣那樣的喷射劑，通過利用氣膠劑形成氣泡以將劑型形成泡狀。非氣膠劑型不使用喷射劑，而使用栗成型裝置或擠壓成型裝置、其他非氣膠劑成型容器(以下簡稱為“成麼容器，，)形成包裹空氣的氣泡’將劑型形成泡狀。在先技術文獻專利文獻 3 201204397 專利文獻1 :曰本特開平09-1368 1 8號公報專利文獻2 :曰本特開平10-287534號公報專利文獻3 :曰本特開2007-291015號公報專利文獻4 :日本特開2008-291020號公報在上述專利文獻i、專利文獻2中公開了通過氣膠劑將劑型形成泡狀來使用的氧化染髮劑組合物或染髮劑組人物。另外，在上述專利文獻3、專利文獻4中公開了通過非氣膠劑成型容器將劑型形成泡狀來使用的染髮劑等。【發明内容】發明所要解決的課題可是，在非氣膠劑型泡狀毛髮化妝品中，雖㈣易獲得與毛髮的親和性或塗佈於毛髮時的延展性相對良好的泡沫，但有形成易於經時地消泡的泡沫的傾向。 λ 為消除對非氣膠劑型泡狀毛髮化妝品的上述不足，例如考慮改良作為起泡劑的界面活性劑的摻混。歹在專利文獻1、專利文獻2中公開的氣膠劑型泡狀染髮劑中穆混了比較多的界面活性劑。但是，由於氣膠劑型和非氣膠劑型的起泡機制和氣泡構成存在差異，所以認為與起泡性和料特性有關的界面活性劑的效果也大不相同®此，未直接以這些文獻中公開的界摻混作為參考^ ^ 在專利文獻3中公開色劑/染髮劑中，通過摻混的非氣膠劑型泡狀2劑式毛髮脫向級醇，在防止塗佈於毛髮時製 201204397 劑滴落的同時，在1劑/2劑混合時摻混達2〜1〇重量％的界面活性劑，改良起泡性。但是，發明的效果特殊，為保與摻混高級醇有關的低溫時的起泡性，，。、 1卞马界面活性劑，優選組合使用陰離子界面活性劑和非離子界面活性劑，其中的非離子界面活性劑在i劑/2劑混合時在不足_重量的範圍内使用。 /在專利文獻4中公開的非氣膝劑型泡狀2劑式染髮船毛髮脫色劑中’作為起泡劑優選使用界面活性劑，但發明的要點在於製劑粘度的最優化，雖然涉及摻混的界面活性劑的種類和摻混量，但是未發現多少具有實質意義的公開。針對上述在先技術文獻中關於泡狀毛髮化妝品中摻混界面活性劑的公開情況，本申請申請人在日本特願 2009-247089號（在提交本巾請時未公開）中提出了通過將陰離子型界面活性劑和陽離子型界面活性劑的離子性不同的界面活性劑分別摻混A i劑和2劑以維持泡狀劑型的毛髮化妝品組合物。但是，在進一步深入研究時獲知，在該毛髮化妝品組合物中，在將丨劑與2劑混合時，形成了認為是陽離子-陰離子複合物的不溶物，所以當希望通過非氣膠劑成型容器起泡時，因這樣的複合物引起排出差，無法獲侍優質的泡沫。因此，本發明將以下問題作為應解決的技術課題：提供可獲得優質的泡沫、在毛髮上的塗佈性優異塗佈於毛髮上時不滴落的毛髮化妝品組合物，所述組合物為通過非氣膠劑成型容器形成泡狀劑型以適用於毛髮的毛髮化妝品組合物。 201204397 解決課題的手段 (第1發明的構成）解決上述課題的本申請第丨發 ^ ^ , J傅成為用於在使用時通過非氣膠劑成型容器形成泡〜土 Μ過用於毛桊的车髮化妝品組合物’所述毛桊化路韻分。㈣化妝'组合物含有以下㈧成分 (A) 10質量％以上的非離子型界面活性劑。 (B) 陽離子型界面活性劑。 (C)選自陰離子型界面活性劑和以上。兩性界面活性劑中的 1種在上述第1發明中’“1〇質量％以上，，意味著在2劑式毛髮化妝品組合物中’“在第1劑與第2劑混合時為1〇質量％以上”。同樣地’在本申請說明書中，只要無特殊規定，規定某種成分的含量的數值均意味著在2劑式毛髮化妝品組合物中，“在第1劑與第2劑混合時的含量”。 (第2發明的構成）用於解決上述課題的本申請第2發明的構成為上述第 1發明的毛髮化妝品組合物，所述毛髮化妝品組合物為使用時將第1劑和第2劑的混合液形成泡狀劑型以適用於毛髮的2劑式組合物’其在所述第i劑中摻混(b)成分，在所述第2劑中摻混（〇成分。 (第3發明的構成）用於解決上述課題的本中請第3發明的構成為上述第 6 201204397 1發明或第2發明的毛髮組合物為毛髮化妝品組合物，所述毛髮化妝品組合物為染髮劑、毛髮脫色劑或毛髮脫染劑。 (第4發明的構成）用於解決上述課題的本申請第4發明的構成為毛髮化妝叩組合物的使用方法，所述使用方法為將第i發明〜第3 ^項的毛髮化妝品組合物通過非氣膠劑成型容器形成泡狀劑型以適用於毛髮。 (第5發明的構成）用於解決上述課題的本申請第5發明的構成為毛髮化妝用品’所述毛髮化妝用品含有第1發明〜第3發明中任一項的毛髮化妝品組合物和用於將該毛髮化妝品組合物形 /包狀劑型的非氣膠劑成型容器而構成。發明的效果々根據第i發明，可提供毛髮化妝品組合物，其在通過非乱膠劑成型容器形成泡狀劑型時可獲得優質的泡沫’與此同時在毛髮上的塗佈性優異，塗佈於毛髮時不滴落。，即，作為基本效果，含有（B)成分的陽離子型界面活性劑和(C)成分的陰離子型界面活性劑的毛髮化妝品组合物在形成泡狀劑型时可獲得枯稠（壬千壬千）的泡床。但另一方面，從由於這些界面活性劑的相互作用而形成複合物的觀點出發，若用於非氣膠劑成型容器，則導致其排出差。 =卜1致排出差的泡沫若塗佈於毛髮，則產生放置時滴落等問題，在泡耐久性方面也不令人滿意。 7 201204397 但是，在第1發明中、通過進-步加入10質量％以上的非離子型界面活性劑作為⑷成分，可消除非氣膠劑成型谷Is的上述排出差，谁而姐古進而乂回泡的膜強度，使泡難以消失，獲得在起泡性、泡的皙从..^ 質也、泡的硬度等方面優質的泡沫。該泡沫在毛髮上的塗佈性（與毛髮的親和性、塗佈時的延展性)也好’在塗佈於毛髮時保持堅固的泡狀，難以消泡，所以在放置時不滴落。芸非雜2 m 非離子型界面活性劑的摻混量不足 10質量％m充分獲得上述效果。需要說明的是，作為（c)成分，也可與陰離子型界面活性劑同時使用兩性κ I面活性劑或代替陰離子型界面活性劑使用兩性界面活性劊0 f 眾所周知，兩性界面活性劑在鹼性、側的pH區域以陰離午形式存在’在酸性一側的阳區域、陽離子形式存在。氧化染髮劑或毛髮脫色脫染劑在第1 劑與第2劑混合時呈驗性。因此，在上述毛髮化妝品組合物的清况下，兩性界面活性劑實質上表現出陰離子型界面活性劑的订為，同樣顯示出針對陰離子型界面活性劑敍述的上述作用.效果。根據第2發明，通過將第丨劑中摻混的⑻成分的陽離界面活性劑與第2劑中摻混的（C)成分的陰離子型界面 ;1生劑或兩性界面活性劑混合，生成因兩者的相互作用而 ',的粘稠的泡沫，但由於兩者在到第1劑與第2劑混合. 起泡時為止都未接觸，所以各劑的穩定性保持良好。的警據第3發明’提供作為毛髮化妝品組合物特別優選、施方式的染髮劑、毛髮脫色劑&毛髮脫染劑。 8 201204397 根據第4發明’提供用於將毛髮化妝品組合物製成良好的非喷霧劑型泡狀劑型以適用於毛髮的有效方法。根據第5發明，提供含有毛髮化妝品組合物和用於將 5亥毛髮化妝品組合物混合形成泡狀劑型的非氣膠劑成型容器而構成的簡便的毛髮化妝用品。【實施方式】接著，對包括最佳方式在内的實施本發明的方式進行說明。 [毛髮化妝品組合物] 本發明的毛髮化妝品組合物為用於在使用時通過非氣膠劑成型容器形成泡狀劑型以適用於毛髮的組合物，作為必需成分’分別含有作為（A)成分& 1〇質量％以±的非離子型界面活性劑、作為（B)成分的陽離子型界面活性劑、作為 (C)成分的選自陰離子型界面活性劑和兩性界面活性劑中 .的1種以上界面活性劑。 ^滿足以上條件的前提下，毛髮化妝品組合物的種類無限疋’優選染髮劑、毛髮脫色劑剧或毛髮脫染劑。作為染髮劑，可示例出氧化染髮劑或酸例出氧化染髮劑。杂㈣’但特別優選示作為毛髮化妝品組合物’也包含】劑別優選2劑式毛髮化妝品組合物。在2劑：合物中，也包含將第i劑或第2劑進 '且 J,. , 步刀割成多個製劑而構成的組合物。例如可示例出 A Z劑式虱化染髮劑中， 9 201204397 代替在第1劑中摻混（B)成分的同時在第2劑中摻混（c)成分的構成，將第1劑分割成含有通常的氧化染髮劑第丨劑成分的製劑和摻混（B)成分的製劑構成染髮劑的情況，或將第2劑分割成含有通常的氧化染髮劑第2劑成分的製劑和摻混（C)成分的製劑構成染髮劑的情況等。 [必需成分在第1劑和第2劑中的摻混形態] 當毛髮化妝品組合物為2劑式時，（A)成分〜(c)成分在第1劑和第2劑中的摻混形態基本無限定，可任意選擇，但優選將（B)成分和（〇成分摻混到互不相同的製劑中特別優選分別將（B)成分摻混到第！劑中，而將（c)成分摻混到第2劑中。當將（B)成分和（C)成分摻混到互不相同的製劑中時，通過使兩者摻混量的品質比（C)/(B)處於〇〇1〜5的範圍内，更易於維持泡狀劑型。通過使品質&(C)/(B)處於〇〇5〜2的範圍内可使此效果更為顯著。在以上情況下’（A)成分也可摻混到第i劑和第2劑中的任一方中，在總摻混量達到1〇質量％的前提下，也可分散摻混到第1劑和第2劑的雙方中。另外，在第1劑處於鹼性區域、第2劑處於酸性區域的2劑式氧化染髮劑等2劑式毛髮化妝品組合物中，當作為（C)成分合用陰離子型界面活性劑和兩性界面活性劑時，如上所述，由於兩性界面活性劑在第丨劑中以陰離子形式存在，在第2劑中以陽離子形式存在，所以從防止形成平衡離子的觀點出發，優選以各劑中的界面活性劑極性 10 201204397 相同的方式摻混兩性活性劑。此外，也可將(A)成分〜(C)成 ^ 成刀僅摻混到第1劑和第2劑中的任一方中。當毛髮化妝組合物為1劑式酸性染髮劑等時，(A)成分〜(C)成分的各成分摻混到同一製劑中。 [毛髮化妝品組合物的劑型等] 乍為1劑式毛髮化妝品組合物在起泡前的劑型或2劑式毛髮化妝品組合物中的第1劑和第2劑在起泡前的劑里例如可列舉出固體狀、水溶液態、分散液態、乳化物狀、凝膠狀、泡沫狀和乳膏狀。作為固體狀劑型，例如可出私末狀和片劑。當製成固體狀劑型時，從混合第1 第齊J時刀散性優異的觀點出發，優選為粉末狀。需要說明的疋’例如當將帛i劑製成固體狀劑型時，將第2 劑製成含有水的製劑。總之，在1劑式毛髮化妝品組合物中，對其製劑的劑型無特殊限^;在2劑式毛髮化妝品組口物中力疋在其第i劑與第2劑混合時能夠嫁保各自流動性的劑型，則劑型無特殊限定。，另外，就毛髮化妝品組合物而言，在⑽式的情況下，其製=中含有水作為用於起泡的基材，在2劑式的情況下劑和第2劑中的至少一方中含有水作為用於起泡的。基材。水的含量優選為40質量％以上，更優選為60質量％以上。 [(A)成分] 品組合物中摻混有10質雖然（A)成分摻混量的上本發明的（A)成分為毛髮化妝量％以上的非離子型界面活性劑。 11 201204397 限無限定，但例如可限制在4〇質量％以下。作為非離子型界面活性劑’可示例出以下物質，但不限定於此。非離子型界面活性劑可單獨使用其中的1種也可將其中的2種以上合用。特別是若將HLB為丨5以上的親水性非離子型活性劑與HLB為9以上、不足15的親油性非離子型活性劑合用，則製劑的穩定性好。HLB(親水親油平衡值：Hydrophile-LipophUe Balance)可根據公知的 Griffin式計算得出。聚氧乙烯（以下簡稱為p〇E)十六烷基醚、P0E十八烧基醚、POE二十二烧基醚、p〇E油烯基醚、p〇E十二烷基醚、POE十二烧基醚、poe辛基十二烷基醚、p〇E己基癸基醚、P0E異十八烷基醚、P〇E癸基十五烷基醚、p〇E 癸基十四烷基醚、POE烷基（ci 2〜14)醚等P〇£烷基醚。 2. POE壬基苯基醚、Poe辛基苯基醚等p〇E烷基苯基。 3· POE失水山梨糖醇單油酸酯、poe失水山梨糖醇單硬脂酸酯、POE失水山梨糖醇單軟脂酸酯、p〇E失水山梨糖醇單月桂酸酯、POE失水山梨糖醇三油酸酯等p〇E失水山梨糖醇脂肪酸酯。 4· POE甘油單硬脂酸酯、P0E甘油單肉豆蔻酸酯等 P0E甘油單脂肪酸酯。201204397 VI. Description of the Invention: [Technical Field] The present invention relates to a hair cosmetic composition, a method of using the same, and a hair cosmetic product. More particularly, the present invention relates to a hair cosmetic composition for forming a foamed dosage form by a non-aerated agent molding container, a method of using the same, and a hair cosmetic composition and a non-air adhesive. A hair cosmetic product formed by molding a container. [Prior Art] It is known that a hair cosmetic such as a hair dye or a hair bleaching and decoloring agent is formed into a foaming form at the time of use. When these hair cosmetics are used in a foam form, the following advantages are expected: it is easy to apply uniformly to the hair without spots; and even if the hair cosmetic is not made to have a high viscosity, it can be prevented from dripping when applied to the hair. The trouble of hair sticking when the gel-like or cream-like hair cosmetic which is widely used is used can be omitted. Hair cosmetics for use in a foam form can be roughly classified into a gas gel type and a non-air gel type. The gas gel type uses a propellant such as a liquefied gas, and bubbles are formed by using a gas gel to form a foam form. The non-air-gel type does not use a propellant, but uses a chestnut molding device or an extrusion molding device, and other non-aerogel molding containers (hereinafter simply referred to as "forming containers," to form air-encapsulated air bubbles" to form a foaming form. CITATION LIST Patent Document 3 201204397 Patent Document 1: Japanese Patent Application Laid-Open Publication No. Hei No. Hei. No. Hei. No. Hei. In the above-mentioned Patent Document i and Patent Document 2, an oxidative hair dye composition or a hair dye group person which is formed by forming a foam form into a foam form by a gelling agent is disclosed in the above-mentioned Patent Document No. 2008-291020. Patent Document 3 and Patent Document 4 disclose a hair dye or the like which is used to form a foam in a non-aerated gel molding container. [Explanation] The problem to be solved by the invention is that it is in a non-aerogel type blister hair cosmetic. Although (4) it is easy to obtain a foam having a relatively good affinity with hair or a ductility when applied to hair, there is a tendency to form a foam which is easily defoamed with time. For the above-mentioned deficiencies of the non-aerogel type blister hair cosmetic, for example, it is considered to improve the blending of the surfactant as a foaming agent. 歹In the air-gel type blister hair dye disclosed in Patent Document 1 and Patent Document 2, There are a lot of surfactants. However, due to the difference in foaming mechanism and bubble composition between the aerosol and non-aerogel types, the effect of surfactants related to foaming and material properties is considered to be very different. Therefore, it is not directly incorporated by the boundary disclosed in these documents as a reference. ^ In the coloring agent/dyeing agent disclosed in Patent Document 3, by blending a non-aerogel type blister 2 type hair detachment alcohol, Preventing the 201204397 agent from dripping while applying to the hair, mixing 2~1% by weight of the surfactant when mixing 1 dose or 2 doses, improving the foaming property. However, the effect of the invention is special, to protect Foaming property at low temperature associated with blending higher alcohols, 1, hummer surfactant, preferably using anionic surfactant and nonionic surfactant in combination, wherein the nonionic surfactant is in the agent /2 Mixture It is used in the range of less than _ weight. / In the non-aerobic knee-type blister-type two-agent hair dyeing hair decoloring agent disclosed in Patent Document 4, it is preferable to use a surfactant as a foaming agent, but the gist of the invention lies in the preparation. The optimization of the viscosity, although relating to the kind and blending amount of the blended surfactant, has not found much substantive disclosure. The disclosure of the above-mentioned prior art literature on blending surfactants in blister hair cosmetics In this case, the applicant of the present application proposed in the Japanese Patent Application No. 2009-247089 (not disclosed in the filing of the present application) that the surfactants having different ionic properties of the anionic surfactant and the cationic surfactant are separately doped. A hair agent and two doses were mixed to maintain the hair cosmetic composition of the foam form. However, it has been found in further intensive studies that in the hair cosmetic composition, when the tanning agent is mixed with the two agents, an insoluble matter which is considered to be a cationic-anionic complex is formed, so when it is desired to form the container by a non-aerated agent When foaming, due to such a composite, the discharge is poor, and it is impossible to obtain a good quality foam. Therefore, the present invention has the following problems as a technical problem to be solved: a hair cosmetic composition which is excellent in applicability on a hair and excellent in applicability on hair, and which does not drip when applied to hair, the composition is passed The non-aerated gel forming container forms a foaming dosage form to be suitable for hair cosmetic compositions. 201204397 Means for Solving the Problem (Configuration of the First Invention) The present invention, which solves the above problems, is a method for forming a bubble by a non-aerogel molding container at the time of use. The hair cosmetic composition 'the hairy rhyme road. (4) The makeup 'composition contains the following (VIII) component (A) 10% by mass or more of a nonionic surfactant. (B) Cationic surfactant. (C) is selected from the group consisting of an anionic surfactant and the above. One of the amphoteric surfactants is '1% by mass or more in the first invention, which means that in the two-part hair cosmetic composition, 'the quality is 1 混合 when the first agent and the second agent are mixed. "% or more". Similarly, in the specification of the present application, unless otherwise specified, the numerical value of the content of a certain component means that in the two-part hair cosmetic composition, "when the first agent and the second agent are mixed The content of the second aspect of the present invention is the hair cosmetic composition of the first aspect of the present invention, wherein the hair cosmetic composition is the first agent and the first A mixture of two doses forms a foamed dosage form for a two-part composition suitable for hair', in which the component (b) is blended in the first agent, and the second agent is blended (〇 component. (3) The composition of the third invention of the present invention is the hair cosmetic composition which is a hair dye composition, and the hair cosmetic composition is a hair coloring composition. Hair bleaching agent or hair decoloring agent. (Configuration of the Invention) The fourth invention of the present application for solving the above problems is a method for using a hair cosmetic composition, which is a method of using the hair cosmetic composition of the first invention to the third item The gel-molding container is formed into a foaming form to be applied to the hair. (Configuration of the fifth invention) The hair cosmetic article of the fifth aspect of the present invention, which is to solve the above-mentioned problems, includes the first invention to the third invention. A hair cosmetic composition according to any one of the invention, and a non-aerated agent molding container for forming the hair cosmetic composition/package type. Advantageous Effects of Invention According to the first invention, a hair cosmetic composition can be provided. When a foamed dosage form is formed by a non-adhesive molding container, a high-quality foam can be obtained, and at the same time, it is excellent in coating property on the hair, and does not drip when applied to the hair. That is, as a basic effect, it contains ( The hair cosmetic composition of the cationic surfactant of the component B) and the anionic surfactant of the component (C) can be obtained in a thick form when forming a foamy dosage form. On the other hand, from the viewpoint of forming a composite due to the interaction of these surfactants, if it is used for a non-aerogel molding container, the discharge is poor. When it is applied to the hair, there is a problem such as dripping during placement, and it is not satisfactory in terms of foam durability. 7 201204397 However, in the first invention, a nonionic interface of 10% by mass or more is further added. As the component (4), the active agent can eliminate the above-mentioned discharge difference of the non-aerogel-forming valley Is, and the film strength of the sputum and the smear of the smear, so that the bubble is difficult to disappear, and the blistering property of the foaming property is obtained. High-quality foam, such as quality, foam hardness, etc. The foam has good coatability on the hair (affinity with hair, ductility during coating), and 'stable foam shape when applied to hair. It is difficult to defoam, so it does not drip when placed. The blending amount of the non-hetero 2 m nonionic surfactant is less than 10% by mass, and the above effects are sufficiently obtained. It should be noted that as the component (c), it is also known to use an amphoteric κ I surfactant or an anionic surfactant in combination with an anionic surfactant. The amphoteric surfactant is well known, and the amphoteric surfactant is alkaline. The pH region on the side exists in the form of a cloudy and noon, 'the positive region on the acidic side, and the cation form. The oxidative hair dye or the hair bleaching and decoloring agent is tested when the first agent and the second agent are mixed. Therefore, in the case of the above-mentioned hair cosmetic composition, the amphoteric surfactant substantially exhibits an anionic surfactant, and the above-described effects and effects described for the anionic surfactant are also exhibited. According to the second aspect of the invention, the anionic interface of the component (C) in which the component (8) blended in the second agent is blended with the (C) component blended in the second agent is mixed with a bioactive surfactant or amphoteric surfactant. Because of the interaction between the two, the viscous foam is mixed with the first agent and the second agent. The foaming is not contacted at the time of foaming, so the stability of each agent is kept good. The third aspect of the invention provides a hair dye, a hair bleaching agent, and a hair dyeing agent which are particularly preferred as a hair cosmetic composition. 8 201204397 According to the fourth invention, an effective method for applying a hair cosmetic composition to a good non-spraying type foaming form to apply to hair is provided. According to the fifth aspect of the invention, there is provided a simple hair cosmetic comprising a hair cosmetic composition and a non-aerogel molding container for mixing a hair cosmetic composition to form a foam formulation. [Embodiment] Next, an embodiment for carrying out the invention including the best mode will be described. [Hair cosmetic composition] The hair cosmetic composition of the present invention is a composition for forming a foamy dosage form by a non-aerated agent molding container to be suitable for hair, and is contained as an essential component as a component (A) & 1% by mass of a nonionic surfactant, a cationic surfactant as the component (B), and an anionic surfactant and an amphoteric surfactant as the component (C) The above surfactants. ^ Under the premise of satisfying the above conditions, the type of the hair cosmetic composition is infinitely preferred, preferably a hair dye, a hair bleaching agent or a hair dyeing agent. As the hair dye, an oxidative hair dye or an acid oxidative hair dye can be exemplified. The (four)' is particularly preferably shown as a hair cosmetic composition'. Also included is a two-part hair cosmetic composition. In the two-agent: a composition comprising the i-th agent or the second agent, and the knives are cut into a plurality of preparations. For example, in the case of AZ-type sputum hair dye, 9 201204397, instead of blending the component (B) in the first agent, and mixing the component (c) in the second agent, the first agent is divided into The preparation of the usual oxidative hair dye ninth component and the preparation of the component (B) constituting the hair dye, or the second agent is divided into a preparation containing the second oxidative hair dye component and blending (C) The preparation of the component constitutes a hair dye or the like. [Mixed form of the essential component in the first agent and the second agent] When the hair cosmetic composition is in a two-part form, the blended form of the component (A) to the component (c) in the first agent and the second agent It is basically unlimited, and it can be arbitrarily selected, but it is preferable to mix (B) component and (〇 component into mutually different preparations, and it is especially preferable to mix (B) component into the agent| When it is blended into the second agent, when the component (B) and the component (C) are blended into different preparations, the quality ratio (C)/(B) of the blending amount is set to 〇〇 In the range of 1 to 5, it is easier to maintain the foaming dosage form. This effect can be made more remarkable by setting the quality &(C)/(B) in the range of 〇〇5 to 2. In the above case, '(A The component may be blended into either of the first agent and the second agent, and may be dispersed and blended into both the first agent and the second agent, provided that the total blending amount is 1% by mass. Further, in the two-part hair cosmetic composition such as a two-part oxidative hair dye in which the first agent is in the alkaline region and the second agent is in the acidic region, an anionic interface is used as the component (C). In the case of the agent and the amphoteric surfactant, as described above, since the amphoteric surfactant is present in the anionic form in the second agent and in the form of a cation in the second agent, it is preferable to prevent the formation of the counter ion from the viewpoint of preventing the formation of the counter ion. Surfactant polarity in each agent 10 201204397 The amphoteric active agent is blended in the same manner. In addition, the component (A) to (C) can be blended into only the first agent and the second agent. When the hair cosmetic composition is a one-part acid hair dye or the like, each component of the components (A) to (C) is blended in the same preparation. [Formulation of a hair cosmetic composition, etc.] 乍 is 1 dose Examples of the first and second agents of the hair cosmetic composition in the form of a pre-foaming or a two-part hair cosmetic composition include a solid, an aqueous solution, a dispersed liquid, and an emulsion. In the form of a solid dosage form, for example, a blister form and a tablet can be obtained. When a solid dosage form is prepared, the scalpel property is excellent when mixing the first and second J. Starting, it is preferably in the form of a powder. 'For example, when the 帛i agent is made into a solid dosage form, the second agent is made into a preparation containing water. In short, in the one-part hair cosmetic composition, there is no particular limitation on the dosage form of the preparation; The type of the hair cosmetic composition is not limited to the dosage form in which the first agent is mixed with the second agent, and the dosage form is not particularly limited. Further, in the case of the hair cosmetic composition, in the formula (10) In this case, water is contained as a base material for foaming, and in the case of a two-part formula, at least one of the agent and the second agent contains water as a base material for foaming. It is preferably 40% by mass or more, and more preferably 60% by mass or more. [(A) Component] The product composition is blended with 10 substances. The component (A) of the present invention is blended with the amount of the component (A). A nonionic surfactant of more than % by weight. 11 201204397 The limit is not limited, but it can be limited to, for example, 4% by mass or less. The following are exemplified as the nonionic surfactant; however, the present invention is not limited thereto. One type of the nonionic surfactant may be used alone or two or more of them may be used in combination. In particular, when a hydrophilic nonionic active agent having an HLB of 丨5 or more and a lipophilic nonionic active agent having an HLB of 9 or more and less than 15 are used in combination, the stability of the preparation is good. HLB (Hydrophile-LipophUe Balance) can be calculated according to the well-known Griffin formula. Polyoxyethylene (hereinafter abbreviated as p〇E) cetyl ether, P0E octadecyl ether, POE behenyl ether, p〇E oleyl ether, p〇E lauryl ether, POE Twelve alkyl ether, poe octyl lauryl ether, p〇E hexyl decyl ether, P0E isostearyl ether, P〇E decyl pentadecyl ether, p〇E decyltetradecane P-alkyl ether such as a base ether or a POE alkyl (ci 2 14) ether. 2. POE nonylphenyl ether, Poe octyl phenyl ether, etc. p〇E alkylphenyl. 3· POE sorbitan monooleate, poe sorbitan monostearate, POE sorbitan monocaprotate, p〇E sorbitan monolaurate, POE sorbitan trioleate and other p〇E sorbitan fatty acid ester. 4. POE glycerol monostearate, P0E glycerol monomyristate, etc. P0E glycerol mono-fatty acid ester.

5· P0E山梨醇四油酸酯、poe山梨醇六硬脂酸酯、poE 山梨醇單月桂酸酯、POE山梨醇蜂蠟等ρ〇Ε山梨醇脂肪酸酷0 12 201204397 6. POE氫化蓖麻油、p〇E蓖麻油。 7_聚乙二醇單油酸酯、聚乙二醇單硬脂酸酯、聚乙二醇单月桂酸ϊ旨。 8_親油型甘油單油酸酯、親油型甘油單硬脂酸酯、自乳化型甘油單硬脂酸酯等甘油高級脂肪酸酯。 9. 失水山梨糖醇單油酸酯、失水山梨糖醇倍半油酸西曰、失水山梨糖醇三油酸酯、失水山梨糖醇單硬脂酸酯、失水山梨糖醇單軟脂酸酯、失水山梨糖醇單月桂酸酯等失水山梨糖醇脂肪酸酯。 10. POE羊毛脂、pOE羊毛脂醇、p〇E山梨醇羊毛脂等羊毛脂衍生物。 11 ·月桂酸二乙醇醯胺、椰子油脂肪酸二乙醇醯胺等燒醇醯胺。 12. POE硬脂醯胺等poe脂肪醯胺。 1 3 ·蔗糖脂肪酸酯。 14. 二甲基十二烷胺氧化物等烷基胺氧化物。 15. 月桂基葡糖苷、烷基（8〜16)葡糖苷等烷基葡糖苦。 16. 卵磷脂衍生物氫化大豆卵磷脂、氫化蛋黃印填脂等。 [(B)成分] 本發明的（B)成分為毛髮化妝品組合物中摻混的陽離子型界面活性劑。雖然（B)成分的摻混量無限定，但優選設定在0.1〜10質量0/〇的範圍内，特別優選設定在〇 5〜5質量％的範圍内。 13 201204397 作為陽離子型界面活性劑’例如可示例出十二烧基三甲基氣化敍、十六烧基二甲基氣化録（西曲氣鍵）、十八燒基二甲基氣化錄（十八烧基三曱基氯化敍只于了 U小卜" 乇二々厶夕口 VK)、烷基三甲基氣化銨、二十二烷基三甲基氯化紹（一十二烧基三甲基氣化錄</\二小卜y乇二々 △夕口 V F )、二（十八烷基）二甲基氣化銨（二（十八烷基）二甲基氣化錢）、十六炫基三甲基溴化錄、十八院基三甲基溴化銨、羊毛脂脂肪酸胺基丙基乙基二甲基銨乙基硫酸鹽（工千A硫酸今y V y脂肪酸了 S y 7。口 ΰ小工千小、2 /千小 7 >乇二々Λ)、十八烷基三曱基糖精銨、十六烷基三甲基糖精銨、二十二烷基三甲基曱基硫酸銨和Quaternium (夕才夕二々厶）-91等，但不限定於此。陽離子型界面活性劑可單獨使用1種，但從起泡性和感觸層面出發，優選合用 2種以上。 [(C)成分] 本發明的（C)成分為毛髮化妝品組合物中摻混的陰離子型界面活性劑和/或兩性界面活性劑yC)成分的掺混量無限定，但優選設定為0.05〜1〇質量％範圍内，特別優選設定為〇·1〜3質量％範圍内。作為（C)成分，可不例出以下物質，但不限定於此〇(c) 成分可單獨使用其中的1種或合用其中的2種以上。在（C)成分中，作為陰離子型界面活性劑，例如可示例出POE十』基醚蜂酸鈉等垸基越硫酸鹽，+二烧基硫酸鈉、十六十八烷基硫酸鈉、十六烷基硫酸鈉等烷基硫酸鹽， 201204397 烯基鍵硫酸鹽’烯基硫酸鹽，鏈烯烴磺酸鹽，鏈烷烴磺酸鹽’飽和或不飽和脂肪酸鹽，烷基或烯基醚羧酸鹽，&_磺化脂肪酸鹽’椰油醯楚胺酸三乙醇胺（椰油醯鼓胺酸tea) 等N-酿基胺基酸型界面活性劑，磷酸單或二酯型界面活性劑’和硫代號轴酸酯等。作為這些界面活性劑的陰離子基團的對離子’例如可列舉出鈉離子、鉀離子和三乙醇胺。在（C)成分中’作為兩性界面活性劑，可示例出以下物質。 1. 挪油脂肪醯胺丙基二曱基胺基乙酸甜菜鹼（肀シ油月曰肪酉文7 <卜7 口匕。小^〆千小7 /酢酸K夕彳 > )、棕糊’由月曰肪酿胺丙基二甲基胺基乙酸甜菜鹼、月桂醯胺丙基一甲基胺基乙酸甜菜鹼（月桂醯胺丙基甜菜鹼）、蓖麻油醯胺丙基二甲基胺基乙酸甜菜鹼等脂肪醯胺丙基二甲基胺基乙I甜菜鹼及其鈉鹽、鉀鹽或三乙醇胺鹽。 2. 癸基二甲基胺基乙酸甜幕鹼、十二烷基二甲基胺基乙酸甜菜驗、十四烷基二曱基胺基乙酸甜菜鹼、十六烷基一甲基胺基乙酸甜菜鹼、十八烷基二甲基胺基乙酸甜菜驗、油稀基二曱基胺基乙酸甜菜鹼、二十二烷基二甲基胺基乙酸甜菜鹼、椰油烷基二甲基胺基乙酸甜菜鹼等烷基二甲基胺基乙酸甜菜鹼及其鈉鹽、鉀鹽或三乙醇胺鹽。 3. 椰油醯两性基乙酸Na (N_椰油醯（亇シ油脂肪酸7 シ心）-N’·羧曱基·Ν,_羥乙基乙二胺）、椰油醯两性基丙酸Na (N_挪油醯_N’_羧乙基-N，-羥乙基乙二胺）、月桂醯两性基乙酸Na (N-月桂醯-N，-羧甲基_N，·羥乙基乙二胺）、橄欖油醯 15 201204397 两性基乙酸Na、可可脂醯两性基乙酸Na、芝麻油醯两性基乙酸Na、甜扁桃油醯两性基乙酸Na(只4 一卜7 —乇> 卜、7 >示酢酸Na)、硬脂醯两性基乙酸鹽、棕櫚油醯两性基乙酸Na、花生油醯两性基乙酸Na、葵花籽油醯两性基乙酸Na、棉籽油醯两性基乙酸Na等N-醯基胺基乙基_Ν·2_ 羥乙基胺基羧酸鹽。 4 ·椰油醢兩性基二乙酸Na、椰油醯兩性基二丙酸Na 和月桂醯兩性基二乙酸Na等Ν·醯基胺基乙基-N-竣基曱氧基乙基胺基羧酸鹽。 5.羥基烷基（C12-14)羥基乙基肌氨酸。 [毛髮化妝品組合物的類別] 本發明的毛髮化妝品組合物無限定，例如作為氧化染髮劑、酸性染髮劑、毛髮脫色劑或毛髮脫染劑構成。特別優選作為氧化染髮劑或毛髮脫色劑構成。 (氧化染髮劑）氧化染髮劑包含含有鹼劑和氧化氧化劑的…’分解毛髮的黑色素，由氧：劑 Π的氧化聚♦’進行染髮。氧化染料可分為染料中心和發色劑。也可摻混驗性染料、磺：4中間體散染料等直接染料代替酸性染料。 t染料、分作為染料中間體，例如可列舉笑二胺類、二苯胺類、_吐甘本—胺類、胺基酚類、5· P0E sorbitol tetraoleate, poe sorbitol hexaearate, poE sorbitol monolaurate, POE sorbitol beeswax, etc. 〇Ε sorbitol fatty acid cool 0 12 201204397 6. POE hydrogenated castor oil, p 〇E castor oil. 7_polyethylene glycol monooleate, polyethylene glycol monostearate, polyethylene glycol monolaurate. 8_ glycerin higher fatty acid esters such as lipophilic glycerol monooleate, lipophilic glyceryl monostearate, and self-emulsifying glyceryl monostearate. 9. sorbitan monooleate, sorbitan sesquiolee sesquiolee, sorbitan trioleate, sorbitan monostearate, sorbitan A sorbitan fatty acid ester such as monostearate or sorbitan monolaurate. 10. Lanolin derivatives such as POE lanolin, pOE lanolin alcohol, p〇E sorbitol lanolin. 11 · lauric acid diethanolamine, coconut oil fatty acid diethanolamine, etc. 12. POE stearylamine and other poe fatty guanamine. 1 3 · Sucrose fatty acid ester. 14. An alkylamine oxide such as dimethyldodecylamine oxide. 15. Alkyl glucoside such as lauryl glucoside or alkyl (8~16) glucoside. 16. Lecithin derivative hydrogenated soybean lecithin, hydrogenated egg yolk sealant and the like. [Component (B)] The component (B) of the present invention is a cationic surfactant blended in a hair cosmetic composition. Although the blending amount of the component (B) is not limited, it is preferably in the range of 0.1 to 10 mass%/Torr, and particularly preferably in the range of 5 to 5 mass%. 13 201204397 As a cationic surfactant, for example, didecyl trimethyl gasification, hexadecyl dimethyl gasification (Western gas bond), octadecyl dimethyl gasification can be exemplified. Recorded (Eight-burning base triterpene chloride chlorinated only in U Xiaobu " 乇二々厶夕口VK), alkyl trimethylated ammonium sulfate, behenyl trimethyl chloride Twelve-burning trimethyl gasification recorded </\ two small y y 乇々々夕口 V V ) , di ( octadecyl ) dimethyl ammonium hydride ( di ( octadecyl ) Methyl vaporized money), hexadecyl trimethyl bromide, 18 yards of trimethylammonium bromide, lanolin fatty acid aminopropyl ethyl dimethyl ammonium ethyl sulphate Sulfuric acid y V y fatty acid S y 7. ΰ ΰ 小小小, 2 / thousand small 7 > 乇々Λ 、), octadecyl tridecyl saccharinate ammonium, cetyl trimethyl saccharin ammonium And, but not limited to, behenyltrimethylammonium sulphate and Quaternium-91. The cationic surfactant may be used singly or in combination of two or more kinds in terms of foaming and feeling. [(C) component] The component (C) of the present invention is not limited in the amount of the anionic surfactant and/or the amphoteric surfactant yC) blended in the hair cosmetic composition, but is preferably set to 0.05~ Within the range of 1% by mass, it is particularly preferably set within the range of 〇·1 to 3% by mass. The component (C) is not limited to the following, but it is not limited to the above, and the component (c) may be used alone or in combination of two or more. In the component (C), as the anionic surfactant, for example, sulfhydryl sulfate such as POE decyl ether bee sodium sulfate, sodium disulfonate sodium sulfate, sodium hexadeca sulphate sulfate, or the like can be exemplified. Alkyl sulfates such as sodium hexaalkyl sulfate, 201204397 Alkenyl linkage sulfate 'alkenyl sulfates, alkene sulfonates, alkane sulfonates' saturated or unsaturated fatty acid salts, alkyl or alkenyl ether carboxylic acids Salt, & sulfonated fatty acid salt 'coco oleic acid triethanolamine (cocoate tartamine tea) and other N-glycosyl acid type surfactant, phosphate mono- or diester type surfactant And thiolated acid esters and the like. Examples of the counter ion ' of the anionic group of these surfactants include sodium ion, potassium ion and triethanolamine. As the amphoteric surfactant in the component (C), the following materials can be exemplified. 1. Norwegian Fat Amidylpropyl Dimercaptoacetate Betaine (Oyster Oil 曰酉 7 7 < 卜 7 口匕. Small ^ 〆 thousand small 7 / 酢 K K 彳彳 gt;), brown Paste 'Aminopropyl dimethylaminoacetic acid betaine, lauryl propyl monomethylamino acetic acid betaine (lauryl propyl betaine), castor oil lysine propyl dimethyl Fatty amidoxime dimethylaminoethyl betainine such as arylaminoacetate betaine and its sodium, potassium or triethanolamine salt. 2. Tertyldimethylammonium acetate sweet base, dodecyldimethylaminoacetate beet, tetradecyl decylaminoacetic acid betaine, cetyl monomethylamino acetic acid Betaine, octadecyldimethylaminoacetic acid beet test, oil dithioglycine aminoacetate betaine, behenyldimethylaminoacetic acid betaine, cocoalkyl dimethylamine Alkyl dimethylaminoacetic acid betaine such as beta acetate, and its sodium, potassium or triethanolamine salt. 3. Cocoa amphoteric acetic acid Na (N_cocoa bismuth (Oyster fatty acid 7 シ heart)-N'·Carboxynonyl hydrazine, 羟 hydroxyethyl ethylenediamine), cocoa amphoteric propionic acid Na (N_Norphine_N'_carboxyethyl-N,-hydroxyethylethylenediamine), Lauryl Ammonium Acetate Na (N-Lauryl-N,-Carboxymethyl_N, · Hydroxyethyl Ethylenediamine), olive oil 醯15 201204397 Amphoteric acid Na, cocoa butter, amphoteric acid, Na, sesame oil, amphoteric acid, Na, sweet almond oil, amphoteric acid, Na, (only 4, ab, 7 乇) , 7 > Naic Acid Na), Stearic Amphoacetate, Palm Oil, Amphoteric Acid, Na, Peanut Oil, Amphoteric Acid, Na, Sunflower Seed Oil, Amphoteric Acid, Na, Cottonseed Oil, Amphoteric Acid, Na, etc. - mercaptoaminoethyl _ Ν 2 hydroxyethyl amino carboxylate. 4 · Cocoon amphoteric diacetate Na, cocoon amphoteric dipropionic acid Na and lauryl amphoteric acid diacetic acid Na isomer, mercaptoaminoethyl-N-mercaptomethoxyethylaminocarboxylate Acid salt. 5. Hydroxyalkyl (C12-14) hydroxyethyl sarcosine. [Category of Hair Cosmetic Composition] The hair cosmetic composition of the present invention is not limited, and is, for example, composed of an oxidative hair dye, an acid hair dye, a hair bleaching agent or a hair dyeing agent. It is particularly preferably constituted as an oxidative hair dye or a hair bleaching agent. (Oxidation Hair Coloring Agent) The oxidative hair coloring agent contains a melanin which decomposes hair containing an alkali agent and an oxidizing oxidizing agent, and is dyed by an oxidative polymerization of oxygen: a hydrazine. Oxidation dyes can be classified into dye centers and color formers. It is also possible to incorporate an acid dye such as a direct dye such as an inactive dye or a sulfonate: 4 intermediate disperse dye. t dyes and fractions As the dye intermediates, for example, simamines, diphenylamines, _tugaben-amines, aminophenols,

—胺基笨胺類、N 二胺基吡啶類及其鹽類❶作為鹽類，土本二胺類、硫酸鹽及乙酸鹽等。 ‘' 例如可列舉出鹽酸鹽、 16 201204397 發色劑為通過與染料中間體結合而發色的化合物，可根據需要包含於第丨劑中。作為發色劑，例如可列舉出間苯一酚、連苯三酚、兒茶酚、間胺基苯酚、間苯二胺、2,4-二胺基苯酚、1，2,4_苯三酚、甲苯·3,4·二胺、甲苯_2,4·二胺、氣酿、a-萘紛' 2,6-二胺基吼啶、！，$_二羥基萘、5_胺基鄰 γ酚、對曱基胺基苯酚、2,4_二胺基苯氧基乙醇、沒食子酸、單寧酸、沒食子酸乙g旨、沒食子酸甲酉旨、沒食子酸丙酯、子$ (2 -經基乙基胺基）_2·甲基苯紛及其鹽。。氧化染髮劑中染料中間體的含量優選為〇〇1〜1〇質量 °/〇 ’更優選為〇 1〜5晳蔷。/ a $ ,, 5貨量/〇。®染料中間體的含量不足0.01 時有得不到充分的染色性之虞。由於即使染料中 :體的含量超過10質量％，染色性也不進一步提高，所以有染髮的經濟性降低之虞。作為上述氧化染料以外的染料，帛i劑也可適當含有格7如準標準藥品原料規格（醫藥部外品原料規直接年6月發行’藥事日報社）中收載的氧化染料和直接染料中的至少一種。驗劑在促進第2劑含右髮提高毕料斜“ 有的氧化劑作用的同時，膨潤毛你丨‘ 田此提同染色性。作為鹼劑， 11列舉出氨水、烷醇胺、基酴釦汰灿* 頁機胺頬、無機鹼、鹼性胺丞敲和硫酸鹽^作為有基q 3品員，例如可列舉出2-胺基-2-甲迅i，3-丙二醇和胍。作為氫氧彳”，、…'機鹼，例如可列舉出氫氧化鈉、飞軋化鉀、碳酸鈉、碳酸鉀、銨。作為鹼性胺A納灰黾銨、碳酸氫鈉和碳酸氫土文，例如可列舉出精胺酸和離胺酸以及 17 201204397 驗性胺基酸鹽。作為驗性胺基酸的鹽，例如可列舉作為硫酸鹽，可列舉出硫酸銨。鹽。鹼劑的含量優選為在混合第1劑和第2劑的氧化染髮劑中PH達到㈤範圍的量^若阳不^當在第劑中含有作為氧化劑的過氧化氫時，有無法充分化氫的作用之虞。若使用時的pH超過12，則髮劑塗佈於毛髮時，有易產生損傷毛髮等缺陷之虞。第2劑至少含有氧化劑。氧化劑使氧化染料發生氧化聚合=發色。作為氧化劑，例如可列舉出過氧化氣、腺過氧化氫、黑色素過氧化物、過碳酸鈉、過碳酸钟、過侧酸鈉、過删酸钟、過氧化納、過氧化卸、過氧化鎮、過氧化鋇、過氧化約、過氧化錄、硫酸鹽的過氧化氮加合物、碟 ^鹽的過氧化氫加合物和焦磷酸鹽的過氧化氫加合物。第2劑中氧化劑的含量優選為。」〜1〇〇質量％，更優選為0.5〜8·0%。當氧化劑的含量不足〇1質量％時有難以吏氧化木料充分氧化聚合之虞。當氧化劑的含量超過1〇〇質量％時，有易損傷毛髮之虞。 (酸性染髮劑） 1·生染髮劑通常冑i劑式，液性為ρΗ2 5〜4 〇左右的 =性，使酸性染料與帶陽離子性的毛髮形成離子鍵。作為 !·生木料，例如可列舉出硝基染料、偶氮染料、亞硝基染 —本基甲烷染料、咕噸染料、喹啉染料、蒽醌染料、鼓藍染料等。 4乍為酸性染料’更具體而言，可示例出紅色2號、紅 18 201204397 色3號、紅色102號、紅色1〇4號' 號、紅色227號、紅色23〇號 5遽、紅色_ 色202號、黃色203號、橙色2() 巴5號、汽徂巳205旒、橙色2〇 402號、綠色3號、綠色2〇4號、綠色虎板色號、藍色1號、藍色2號、籃…、紫色401 色4CH號等。藍色2〇2喊、褐色2。1號、黑酸性染髮劑中酸性染料的含 7 〜5質詈0/ 苗優選為0.01〜3質量％〇貝1 /0更 (毛髮脫色劑）毛髮脫色劑包含含有驗劑的第1#^含有氧 2劑，分解毛髮的黑色素，使毛髮. 的第石咏·S•不含右氫化染料這-點外，則毛髮脫色劑基二氧地構成。減4劑同樣 (毛髮脫染劑）毛髮脫染劑通常為2劑式，主要目的王要目的在於毛髮的脫 (毛髮中染有的染料的分解），在與毛卷盼丨l " ^你兴乇髮脫色劑的比較中，在第1劑中摻混驗劑的同時，進一+妓 ^ 延步摻混作為鹼劑的—矛的過硫酸鹽作為輔助脫色劑的方面存在差異。劑為孝末狀或顆粒狀、片狀等，第2劑為液態。作為過硫酸鹽，優選示例出過硫酸的鹼金屬鹽，特別優選示例出過硫酸卸或過硫酸鈉。過硫酸鹽的摻混量無吧定，但優選為2.0〜25質量％的範圍内，更優選為jug質量％的範圍内。 [毛髮化妝品組合物中的其他成分] 19 201204397 在1劑式毛髮化妝品組合物物的第1劑和第2劑中，。 " 彳式毛髮化妝品組合性成分、水溶性高分子化:據而要適當選擇含有例如油等。、螯合劑、無機鹽、分散劑作為油性成分，例如可列舉高級脂肪駿、&其廿1 冋級醇、油脂、蠟、烴、 &基甘油鍵、、石夕闕作為高級醇，例如可 … 基癸醇、硬脂醇、異硬^六貌醇（錄蠛醇）、2_己花生醇、山葵醇、2_辛^醇十六醇混合物、油醇、基十四醇和羊毛月^ 一醇、月桂醇、肉豆蔻醇、癸非氣膠劑型的泡狀劑型塗佈2將毛髮化妝品組合物製成滴落效果的作用。、髮上時具有增進防止製劑作為油脂’例如可列舉牛油樹油脂、杏仁油毛月曰、橄欖油、山茶油、油、芝麻油、玉蜀泰油、、二向曰葬油、大豆油、棉軒萄籽油、鱷梨油、澳洲堅果油糠油、未胚芽油、葡油。蓖秦油、椰子油和月見草作為躐，例如可列舉出蜂希蒙得木油和羊毛脂。小燭樹蠟、巴西棕櫚蠟、作為烴’例如可列舉婦、氮化聚異丁稀、礦物油！：鍵稀煙寡聚物、聚異丁微晶躐和凡士林。 “'烯、聚丁烯、聚乙烯、作為高級脂肪酸，例棕櫚酸、硬脂酸、山㈣、^舉出月桂酸、肉豆缝酸、共硬脂酸、12-羥基硬脂酸、油 20 201204397 酸和羊毛脂脂肪酸。作為烧基甘油赫，办丨丄例如可列舉出鯊肝醇、鮫肝油醇和異十八烷基甘油醚。私成作為酿’例如可列舉出己二酸二異丙醋、肉豆丙酿、辛酸十六㈣、異壬酸異壬s|、肉豆M酸辛=異烷酯、棕櫚酸異丙酯 '礓一酯、肉豆蔻酸異十二俨奸 ^ ^ ..^ _ 烷酗、棕櫚酸2-乙基己醋、乾麻油酸 ^ 烷s曰具有10〜30碳原子數的脂肪酸膽固醇酯/ 毛固醇酯、乳酸十六栌一+ ，、烷酉曰、醋酸羊毛脂、二-2-乙基己酸乙一醇酿、季戊四醇胳狀缺此醇月日肪I g日、二季戊四醇脂肪酸酯、癸酸十/、燒醋、三癸酸廿4 久甘油S曰、蘋果酸二異十八烷酯、琥珀酸二辛醋和2-乙基己酸十六烷酯。作為矽酮’例如可列舉出二曱基聚矽氧烷(二甲矽油）、甲基苯基聚碎氧垸、十甲基環.五㈣烧、十二甲基環，夕氧烧末端經基改質二甲基聚石夕氧烧、具有㈣〜1〇，刪、平句聚。度的高聚切酮、聚喊改質⑦酮、胺基改質石夕酮、甜菜鹼改質矽酮、、p真 J坑基改質矽酮、烷氧基改質矽酮、羧基改質矽酮和氟改質矽酮。作為多元醇，例如石丨丨I山例如了列舉出二元醇和甘油。作為二元醇，例如可列舉出乙-醢、_ Q —醇一甘醇、三甘醇、聚乙二醇、丙一醇、一縮二丙_贿醇、異丙二醇和1，3-丁二醇。作為甘油，例如可列皋屮斗』芈出甘油、雙甘油和聚甘油。作為水溶性高分早彳卜人私门刀千化合物，例如可列舉出羧甲基纖維素、經乙基纖維素、：r私知塔& ^ 歲私和環糊精。作為螯合劑，例如可 21 201204397 列舉出乙二胺四乙酸（EDTA，依地酸）、羥乙基乙二胺二酸（HEDTA)及其鹽、二乙烯三胺五乙酸及其鹽類 Μ及輕乙二磷酸（HEDP、依替膦酸）及其鹽類。作為無機鹽，例如可列舉出氣化鈉、硫酸鈉。作為分散劑’例如可列舉出硬脂酸鎂。除此之外’ 1劑式毛髮化妝品組合物或2劑式毛髮化妝品組合物的第1劑和第2劑中還可含有選自例如糖類、防腐劑、穩定劑、pH調節劑、植物提取物、生藥提取物、維生素類、香料及紫外線吸收劑、以及“準標準藥品原料規格’’（2006年6月發行，藥事日報社）中收載的物質中的至少一種0 [毛髮化妝品組合物的使用方法] 本發明的毛髮化妝品組合物的使用方法為將上述毛髮化妝品組合物通過非氣膠劑成型容器形成泡狀劑型以適用於毛髮的方法。作為非氣膠劑成型容器，只要在具有可對毛髮化妝品組合物進行非氣膠劑型起泡和排出功能的前提下，就無限定°優選可使用下文所述非氣膠劑成型容器進行起泡。 [毛髮化妝用品] 本發明的毛髮化妝用品含有用於在使用時製成非氣膠劑型泡狀劑型以適用於毛髮的上述毛髮化妝品組合物和用於將該毛髮化妝品組合物形成泡狀劑型的非氣膠劑成型容而構〇作為非氣膠劑成型容器的代表例，可列舉出泵成型裝 22 201204397 置和擠壓成型裝置。泵成型裝置通過按壓操作泵壓頭部將收納液（例如毛髮化妝品的第i劑/第2劑混合液）形成泡狀排出，將收納液與空氣混合呈泡狀排出的泡排出器安裝於容器本體的口頸部。日本特開2007_275777號公報等中公開了泵成型裝置，是公知的。擠壓成型裝置通過用手指擠壓軟質合成樹脂製容器本體（重複對容器的壓縮操作和解除壓縮操作）’將±述的收納液和$氣導入成型用排出頭的氣液混合室，通過泡排出器將形成的泡沫從喷嘴排出。在日本特開2008-291024號公報和雜誌“Fragrance J〇urnai & ”、、以^十—…”的扣⑽“月期中刊登的文獻染髮技術的新動向（-泡狀染髮技術的開發_)，，等中記載有擠壓成型裝置，是公知的。非氣膠劑成型容器的泡排出器具有i個或多個形成泡珠的多孔質膜。作為多孔質膜的材質，可列舉出尼龍、聚酉旨、聚乙稀、聚丙稀等。作為多孔質膜的目數，優選例如 50〜300目。實施例以下對本發明的實施例進行說明。本發明的技術範圍不因以下實施例而受到限定。 (2劑式染髮劑的構成）準備表1“第1劑，，欄中作為例W〜例1-5 *出的組成的染髮劑第1劑和表2“第2劑，，攔中作為例〜例2_6示出的組成的染髮劑第2劑，按照表3“組合，，欄所示選擇性I组 23 201204397 合上述第1劑和第2劑，構成實施例1〜實施例8、比較例 1〜比較例5的2劑式染髮劑。在表1和表2中，表示第1劑或第2劑的成分含量的數值表示第1劑或第2劑中的質量％單位的含量，而不表示第1劑與第2劑混合時的含量。另外，對於屬於本發明的（A)成分〜(C)成分中的任一類的成分，在表左侧的攔外標注其分類。表1和表2所示的屬於（A)成分的“POE(7)烷基 (C12〜14)醚”和“p〇E(5)烷基（C12〜14)醚”為烷基鏈碳原子數為12〜14的POE烷基醚混合原料，表1所示的作為（A)成分的“烷基（8〜16)葡糖苷’’為烷基鏈碳原子數為8〜16的烷基葡糖苷混合原料》此外’在表2中在成分名稱後標注“※” 標記的成分為 Dow Corning Toray Co., Ltd.(東 k .夕' 々：？ —二 > 夕、'社）製的FZ-4671 (胺乙基胺丙基曱基矽氧烷-二曱基矽氧烷共聚物（2〇%)p (2劑式染髮劑的評價）按品質比1:1的比例將上述各實施例、各比較例的第i 劑和第2劑收納入上述非氣膠劑成型容器（泵成型裝置）製成混合液，通過按壓操作該泵壓頭部呈泡狀的排出上述混合液，對各實施例、各比較例的泡質、塗佈性和滴落性進仃評價。在這裏，作為泵成型裝置，使用（株）吉野工業所製商品名W_5721、WP成型泵L噴嘴型（氣/液混合比：13/1, 排出量：〇.9g (按壓^欠），多孔質膜：9〇目的聚乙稀製筛環2個）。具體而言，對於“泡質，，，綜合評價起泡性、泡的質地、 24 201204397 泡的硬度。對於“塗你柯” , 炎怖性’砰價形成泡狀染髮劑塗佈於假髮上時&延展的難易程度和塗佈的難易程度。對於“滴落性”’經時觀察評價形成泡狀染髮劑塗佈於假髮上後30分鐘内滴落的難易程度。在對上述，包質、“塗佈性’，、“滴落性，，等評價專案進—Amino strepamines, N-diaminopyridines and salts thereof are used as salts, terpenoids, sulfates and acetates. For example, a hydrochloride salt may be mentioned. 16 201204397 A color former is a compound which is colored by binding to a dye intermediate, and may be contained in a second preparation as needed. Examples of the coloring agent include m-benzene phenol, pyrogallol, catechol, m-aminophenol, m-phenylenediamine, 2,4-diaminophenol, and 1,2,4-benzene. Phenol, toluene·3,4·diamine, toluene-2,4·diamine, gas brewing, a-naphthalene 2,6-diamino acridine,! , $_dihydroxynaphthalene, 5-amino-o-gamma phenol, p-nonylaminophenol, 2,4-diaminophenoxyethanol, gallic acid, tannic acid, gallic acid , gallic acid formazan, propyl gallate, sub-(2-aminoethylamino)_2-methylbenzene and its salts. . The content of the dye intermediate in the oxidative hair dye is preferably 〇〇1 to 1 〇 mass ° / 〇 ' more preferably 〇 1 to 5 蔷. / a $ ,, 5 volume / 〇. When the content of the dye intermediate is less than 0.01, sufficient dyeability is not obtained. Since the dyeing property is not further improved even if the content of the dye in the body exceeds 10% by mass, the economical efficiency of hair dyeing is lowered. As a dye other than the above-mentioned oxidative dye, the oxime agent may also contain an oxidative dye and a direct dye contained in the standard of the raw material of the pharmaceutical raw material (the Pharmacy Daily, published in June). At least one of them. The test agent promotes the second agent to contain the right hair to increase the slanting of the material. At the same time as the oxidizing agent, the swelling hair is the same as the dyeing property. As an alkaline agent, 11 lists ammonia water, alkanolamine, and hydrazine. As a member of the group of q 3 , for example, 2-amino-2-methyl i, 3-propanediol and hydrazine can be cited as a group of amines, inorganic bases, basic amines, and sulfates. Examples of the hydrazine hydroxide, and the organic base include sodium hydroxide, fly-rolled potassium, sodium carbonate, potassium carbonate, and ammonium. As the basic amines A, ash, ammonium hydrogencarbonate and hydrogencarbonate, for example, arginine and lysine and 17 201204397 test amine acid salts can be cited. The salt of the organic acid to be tested is, for example, a sulfate, and ammonium sulfate is exemplified. salt. The content of the alkali agent is preferably such an amount that the pH reaches the range of (5) in the oxidative hair dye in which the first agent and the second agent are mixed. If the hydrogen peroxide as an oxidizing agent is contained in the first agent, the hydrogen may not be sufficiently hydrogenated. The role of the shackles. When the pH at the time of use exceeds 12, when the hair is applied to the hair, there is a tendency to cause defects such as damage to the hair. The second agent contains at least an oxidizing agent. The oxidizing agent oxidizes the oxidative dye to form a color. Examples of the oxidizing agent include peroxygen gas, gland hydrogen peroxide, melanin peroxide, sodium percarbonate, percarbonate, sodium peracetate, acid peroxide, sodium peroxide peroxide, peroxide deoxidation, and peroxide oxidation. , ruthenium peroxide, peroxidation, peroxidation, persulfate adduct of sulfate, hydrogen peroxide adduct of disc salt and hydrogen peroxide adduct of pyrophosphate. The content of the oxidizing agent in the second agent is preferably. 〜1〇〇% by mass, more preferably 0.5~8·0%. When the content of the oxidizing agent is less than 质量1% by mass, it is difficult to sufficiently oxidize and polymerize the oxidized wood. When the content of the oxidizing agent exceeds 1% by mass, there is a tendency to damage the hair. (Acid hair dye) 1. The hair dye is usually in the form of a solution, and the liquidity is about ρΗ2 5~4 =, so that the acid dye forms an ionic bond with the cationic hair. Examples of the raw wood material include a nitro dye, an azo dye, a nitroso dye-based methane dye, a xanthene dye, a quinoline dye, an anthraquinone dye, and a drum blue dye. 4乍 is an acid dye' More specifically, red 2, red 18 201204397 color 3, red 102, red 1〇4, red 227, red 23 遽 5 遽, red _ Color 202, yellow 203, orange 2 () Ba 5, car 205 旒, orange 2 〇 402, green 3, green 2 〇 4, green tiger plate color, blue 1 , blue Color 2, basket..., purple 401 color 4CH number, etc. Blue 2〇2 shout, brown 2. No.1, black acid hair dye, acid dye containing 7~5 mass詈0/ seedling is preferably 0.01~3 mass% mussel 1 /0 more (hair bleaching agent) hair bleaching The agent contains the first dose of oxygen containing the test agent, and the melanin which decomposes the hair, so that the hair sputum·S• does not contain the right hydrogen dye, the hair decolorizer is dioxobic. Less 4 agents (hair decoloring agent) Hair decoloring agent is usually 2 dosage forms, the main purpose of the king is to remove the hair (decomposition of the dye dyed in the hair), in the hope of the hair roll " In the comparison of the decolorizing agent, in the first agent, there is a difference in the aspect of the addition of the test agent, and the persulfate of the spear as an alkali agent is added as an auxiliary decolorizing agent. The agent is filial or granular, flake, etc., and the second agent is in a liquid state. As the persulfate, an alkali metal salt of persulfuric acid is preferably exemplified, and particularly, persulfate or sodium persulfate is exemplified. The blending amount of the persulfate is not determined, but is preferably in the range of 2.0 to 25% by mass, and more preferably in the range of jug% by mass. [Other components in the hair cosmetic composition] 19 201204397 In the first agent and the second agent of the one-part hair cosmetic composition. " Combination of hair-type hair cosmetic ingredients, water-soluble polymerization: It is necessary to appropriately select, for example, oil. Examples of the chelating agent, the inorganic salt, and the dispersing agent include, for example, a high-grade fat, an oxime, an oil, a fat, a wax, a hydrocarbon, a <RTI ID=0.0> Can be... sterol, stearyl alcohol, iso-hard hexamethylene alcohol (recorded sterol), 2_hexaphalanol, sorbitol, 2 octyl alcohol cetyl alcohol mixture, oleyl alcohol, pentyl alcohol and wool month ^ A foamy dosage form coating 2 of monool, lauryl alcohol, myristyl alcohol, and non-air gel type forms the hair cosmetic composition into a drip effect. When it is applied, it has an enhanced preventive preparation as a fat or oil. For example, it can be mentioned as shea oil, almond butter, olive oil, camellia oil, oil, sesame oil, jade oil, two-way funeral oil, soybean oil, Cotton ginseng seed oil, avocado oil, macadamia oil, eucalyptus oil, and grape oil.蓖Qin, coconut oil and evening primrose As cockroaches, for example, beemond oil and lanolin are listed. Candelilla wax, carnauba wax, and hydrocarbons are exemplified by women, nitrided polyisobutylene, and mineral oil! : Bonded smoke oligomers, polyisobutylene microcrystals and petrolatum. "'ene, polybutene, polyethylene, as a higher fatty acid, such as palmitic acid, stearic acid, mountain (four), ^ lauric acid, myristic acid, co-stearic acid, 12-hydroxystearic acid, oil 20 201204397 Acid and lanolin fatty acids. As a glyceryl glycerol, for example, shark liver alcohol, citrate alcohol, and isostearyl glyceryl ether can be cited. Propylene vinegar, peas, octanoic acid, hexanoic acid, hexanoic acid, isophthalic acid, succinic acid, isophthalic acid, octyl palmitate, isopropanyl palmitate, isopropyl myristate ..^ _ alkane, palmitic acid 2-ethylhexyl vinegar, dry sesame oil oxalate s 曰 having a fatty acid cholesteryl ester of 10 to 30 carbon atoms / sterol ester, hexadecyl citrate + , alkane曰, acetic acid lanolin, di-2-ethylhexanoate ethyl alcohol, pentaerythritol, stagnation, lack of alcohol, Ig day, dipentaerythritol fatty acid ester, tannic acid ten, burning vinegar, bismuth citrate Long-term glycerin S曰, diisostearyl malate, dioctyl succinate and hexadecyl 2-ethylhexanoate. Polyoxyalkylene (dimethyl hydrazine), methyl phenyl polyoxazide, decamethyl ring, penta(tetra), dodecamethyl ring, oxy-oxygen end-end modified dimethyl polychlorite , with (four) ~ 1 〇, deleted, flat sentence poly. degree of poly-polyketene, poly-modified 7 ketone, amine-modified linalone, betaine modified ketone, p-J pit modified Anthrone, alkoxy-modified fluorenone, carboxy-modified fluorenone, and fluoro-modified fluorenone. Examples of the polyhydric alcohol include, for example, diol and glycerin. B-醢, _ Q - alcohol monoethylene glycol, triethylene glycol, polyethylene glycol, propanol, dipropylene glycol, isopropyl glycol and 1,3-butanediol. As glycerin, for example皋屮皋屮芈芈芈芈芈芈芈甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油甘油Tower & ^ years old private and cyclodextrin. As a chelating agent, for example, 21 201204397 lists ethylenediaminetetraacetic acid (EDTA, edetic acid), hydroxyethyl ethylenediamine diacid (HEDTA) and And diethylenetriamine pentaacetic acid and its salts and light ethylene diphosphate (HEDP, etidronic acid) and salts thereof. Examples of the inorganic salt include sodium carbonate and sodium sulfate. The magnesium stearate is exemplified. In addition, the first agent and the second agent of the 'one-part hair cosmetic composition or the two-part hair cosmetic composition may further contain, for example, a saccharide, a preservative, a stabilizer, pH regulators, plant extracts, crude drug extracts, vitamins, flavors and UV absorbers, and at least one of the substances contained in the "standards for raw materials for quasi-standard drugs" (issued in June 2006, the Pharmaceutical Daily) A method of using a hair cosmetic composition of the present invention is a method of applying the above-described hair cosmetic composition to a hair form by forming a blister form by a non-aerated agent molding container. As a non-aerogel molding container, as long as it has a non-aerogel type foaming and discharging function for the hair cosmetic composition, there is no limitation. Preferably, the non-air-gel molding container described below can be used for foaming. . [Hair Cosmetics] The hair cosmetic of the present invention contains the above-described hair cosmetic composition for making a non-aerated type foaming agent type for use in hair, and a foaming dosage form for forming the hair cosmetic composition. A non-aerogel molding container is a representative example of a non-aerogel molding container, and a pump molding device 22 201204397 and an extrusion molding device are exemplified. The pump molding apparatus presses the pumping head to discharge the storage liquid (for example, the i-th agent/second agent mixture of the hair cosmetic) into a bubble shape, and the bubble discharge device that discharges the storage liquid and the air in a bubble shape is attached to the container. The mouth and neck of the body. A pump molding apparatus is known in Japanese Laid-Open Patent Publication No. 2007-275777, and the like. The extrusion molding apparatus presses the container body of the soft synthetic resin with a finger (repetition of the compression operation and the decompression operation of the container), and introduces the storage liquid and the gas into the gas-liquid mixing chamber of the discharge head for molding, and passes the bubble. The ejector discharges the formed foam from the nozzle. New developments in the literature dyeing technology published in the Japanese version of the publication "Fragrance J〇urnai &", "Fragrance J〇urnai &", and the "10"--" buckle (10) "-- Development of blister hair dyeing technology _ An extrusion molding apparatus is known in the art, and is known. The bubble ejector of the non-aerated material molding container has one or more porous membranes forming bubbles. Examples of the material of the porous film include nylon, polystyrene, polyethylene, and polypropylene. The number of meshes of the porous film is preferably, for example, 50 to 300 mesh. EXAMPLES Examples of the invention are described below. The technical scope of the present invention is not limited by the following examples. (Composition of the two-component hair dye) The first agent of Table 1 "the first agent, the hair dye agent of the composition of the example W to the example 1-5 * and the second agent of the table 2" are prepared in the column. Example 2 - The second agent of the hair dye composition of the composition shown in Example 2_6, according to Table 3 "combination, the column I shown in the column, the selective I group 23 201204397 combined with the first agent and the second agent, constitutes the first embodiment to the eighth embodiment. The two-component hair dye of Comparative Example 1 to Comparative Example 5. In Tables 1 and 2, the numerical value of the component content of the first agent or the second agent indicates the content of the mass % unit in the first agent or the second agent. The content of the first agent and the second agent is not indicated, and the components belonging to any of the components (A) to (C) of the present invention are classified on the left side of the watch. "POE (7) alkyl (C12 14) ether" and "p〇E (5) alkyl (C12 14) ether) belonging to the component (A) shown in Table 1 and Table 2 are alkyl chain carbons. A POE alkyl ether mixed raw material having an atomic number of 12 to 14, and the "alkyl (8-16) glucoside" as the component (A) shown in Table 1 is an alkyl group having an alkyl chain having 8 to 16 carbon atoms. Glucosin mixed raw materials" in addition 'in Table 2 The ingredient name is marked with "※". The ingredient labeled Dow Corning Toray Co., Ltd. (Dong Corning Toray Co., Ltd.) is FZ-4671 (amine ethylamine propyl hydrazine).矽矽 - 曱曱曱 ( 〇 ( 评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价评价The second agent was placed in the non-aerated material molding container (pump molding device) to prepare a mixed liquid, and the pumping head was bubble-shaped to discharge the mixed liquid, and the foams of the respective examples and comparative examples were prepared. In the case of the pumping device, the Yoshino Industrial Co., Ltd. product name W_5721, WP molding pump L nozzle type (gas/liquid mixture ratio: 13/1, discharge) is used. Amount: 〇.9g (pressing ^ owed), porous membrane: 9 mesh of polyethylene mesh sieves.) Specifically, for "foam,, comprehensive evaluation of foaming, bubble texture, 24 201204397 The hardness of the bubble. For the "coating you Ke", the inflammatory 'defective price' forms the foaming hair dye when applied to the wig and the ease of extension The degree of difficulty in coating. For the "drip property", the ease of application of the blister hair dye to the wig on 30 minutes after the application of the blister hair dye is evaluated. , "Drip, etc."

行評價時，以在第1劑味〇 M 則和第2劑混合的狀態下（A)成分的含量為9 · 2 5 %的比較例1作武^ # 作為對照（评價的標準）。對於各評價專案，如下列評價標進张_ 心旱所不通過與對照的評價結果進行對比得到的相對評價，按照6個等級進行評價。另外，對於所有實施例、比較例的所有評價項目，由屬於同-小植的10名組員同時進行評價，在這些組員得到的評價結果中採用得到最多的評價結果。將4些评價結果記錄於表3的各評價專案的評價攔中。 <評價標準> + + + ··與對照相比非常優異 + + :與對照相比很優異 + :與對照相比優異一1與對照相比差 :與對照相比很差 ---:與對照相比非常差 25 201204397 [表i] 第1劑例1-1 例1-2 例1-3 例1-4 例1-5 肉豆蔻醇 0.5 0.5 0.5 0.5 0.5 辛基十二醇 0.5 0.5 0.5 0.5 0.5 十二烧基三曱基氣化敍 3 3 — 3 3 十八烧基三甲基氣化銨 1 1 — 1 1 POE(2)十二院基鱗硫酸納 — _ 4 — — POE(21)十二烷基醚 16.5 14.5 14.5 _ 18.5 POE(9)十二烷基醚 — 0.5 0.5 — — POE(7)烷基(C12 〜14)醚 — 0.5 0.5 — — POE(5)烷基(C12 〜14)醚 — 0.5 0.5 _ — POE(9)十三烷基醚 _ 0.5 0.5 — — 烷基(8〜16)葡糖苷 2 2 2 — 2 丙二醇 0.5 0.5 0.5 0.5 0.5 無水乙醇 10 10 10 10 10 異丙醇 5 5 5 5 5 二乙烯三胺五乙酸五鈉 0.2 0.2 0.2 0.2 0.2 強氨水(28%) 5 5 5 5 5 單乙醇胺溶液(70%) 5 5 5 5 5 對苯二胺 1 1 1 1 1 對甲苯二胺 0.5 0.5 0.5 0.5 0.5 香料 0.4 0.4 0.4 0.4 0.4 純化水餘量餘量餘量餘量餘量合計 100 100 100 100 100 26 201204397 [表2]In the case of the evaluation, the comparative example 1 in which the content of the component (A) was 9·25 % in the state in which the first dose of Miso M was mixed with the second agent was used as a control (standard of evaluation). For each evaluation project, the following evaluations were carried out in accordance with the comparison of the results of the comparison with the comparison evaluation results, and the evaluation was performed according to the six levels. In addition, all the evaluation items of all the examples and the comparative examples were evaluated simultaneously by 10 members belonging to the same-small plant, and the most evaluated results were used among the evaluation results obtained by these members. The results of the four evaluations are recorded in the evaluation block of each evaluation project in Table 3. <Evaluation Criteria> + + + ·· Very excellent compared with the control + + : Excellent compared with the control + : Excellent compared with the control 1 - poor compared with the control: poor compared with the control --- : Very poor compared with the control 25 201204397 [Table i] The first dose of the sample 1-1 Example 1-2 Example 1-3 Example 1-4 Example 1-5 Myristyl 0.5 0.5 0.5 0.5 0.5 Octyldodecanol 0.5 0.5 0.5 0.5 0.5 Twelve burnt tridecyl vaporization 3 3 — 3 3 Octadecyl trimethylated ammonium oxide 1 1 — 1 1 POE (2) 12 yards of sodium sulphate — _ 4 — — POE (21) lauryl ether 16.5 14.5 14.5 _ 18.5 POE (9) lauryl ether - 0.5 0.5 - POE (7) alkyl (C12 ~ 14) ether - 0.5 0.5 - POE (5) alkane (C12 ～14) ether — 0.5 0.5 _ — POE (9) tridecyl ether _ 0.5 0.5 — — alkyl (8~16) glucoside 2 2 2 — 2 propylene glycol 0.5 0.5 0.5 0.5 0.5 absolute ethanol 10 10 10 10 10 Isopropanol 5 5 5 5 5 Pentasodium diethylenetriamine pentaacetate 0.2 0.2 0.2 0.2 0.2 Strong ammonia water (28%) 5 5 5 5 5 Monoethanolamine solution (70%) 5 5 5 5 5 Phenylene Amine 1 1 1 1 1 p-toluenediamine 0.5 0.5 0.5 0.5 0.5 perfume 0.4 0.4 0.4 0.4 0 .4 Purified Water Balance Margin Balance Margin Balance Total 100 100 100 100 100 26 201204397 [Table 2]

Ccc B A A A A 第2劑例.2-1 例2-2 例2-3 例2-4 例2-5 例2-6 肉豆蔻醇 0.5 0.5 0.5 0.5 0.5 0.5 POE(2)十二烷基醚硫酸鈉 1 0.5 0.5 — 1 — 十六十八烧基硫酸納 — 0.5 0.5 — — — 月桂醯胺丙基甜菜鹼 — — — — — 1 十二烧基三甲基氣化敍 — — — 1 — — POE(21)十二烷基醚 6 4.5 4.5 6 — 6 POE(7)烷基(C12 〜14)醚 — 0.5 0.5 — — — POE(5)烷基(C12 〜14)醚 — 0.5 0.5 — — — POE(9)十三烷基醚 — 0.5 0.5 — — — 胺乙基胺丙基曱基矽氧烷-二甲基矽氧烷共聚物※ — 0.05 — — — — 聚氧乙烯-曱基聚矽氧烷共聚物 — — 0.1 — — — 氯化0-[2-羥基-3-(三甲基銨)丙基]羥乙基纖維素 — 0.03 0.03 — — — 一縮二丙二醇 0.1 0.1 0.1 0.1 0.1 0.1 苯氧基乙醇 0.2 0.2 0.2 0.2 0.2 0.2 羥乙二磷酸 0.1 0.1 0.1 0.1 0.1 0.1 苯甲酸鈉 0.2 0.2 0.2 0.2 0.2 0.2 過氧化氫水溶液(35%) 16 16 16 16 16 16 純化水餘量餘量餘量餘量餘量餘量合計 100 100 100 100 100 100 27 201204397 [表3]Ccc BAAAA second dose example. 2-1 case 2-2 case 2-3 case 2-4 case 2-5 case 2-6 myristyl 0.5 0.5 0.5 0.5 0.5 0.5 POE (2) sodium lauryl ether sulfate 1 0.5 0.5 — 1 — hexadecyl sulphate sodium sulphate — 0.5 0.5 — — — lauric acid propyl propyl betaine — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — (21) Dodecyl ether 6 4.5 4.5 6 — 6 POE (7) alkyl (C12 ～ 14) ether — 0.5 0.5 — — — POE (5) alkyl (C12 ～ 14) ether — 0.5 0.5 — — — POE(9)tridecyl ether — 0.5 0.5 — — Aminoethylamine propyl fluorenyl oxoxane-dimethyl methoxy olefin copolymer ※ — 0.05 — — — — Polyoxyethylene-fluorenyl fluorene Oxyalkyl Copolymer — 0.1 — — — 0-[2-Hydroxy-3-(trimethylammonium)propyl]hydroxyethylcellulose chloride — 0.03 0.03 — — — Dipropylene glycol 0.1 0.1 0.1 0.1 0.1 0.1 Phenoxyethanol 0.2 0.2 0.2 0.2 0.2 0.2 Hydroxyethylene diphosphate 0.1 0.1 0.1 0.1 0.1 0.1 Sodium benzoate 0.2 0.2 0.2 0.2 0.2 0.2 Hydrogen peroxide solution (35%) 16 16 16 16 16 16 Purified water balance Quantity margin Balance amount Total 100 100 100 100 100 100 27 201204397 [Table 3]

產業上的可利用性根據本發明，可提供可獲得優質的塗佈性優異、塗佈於毛髮、在毛髮上的物，所、十、鉍人此髮上夸不滴洛的毛髮化妝品組卿，所述組合物為揪士 ° ~氧膠劑型泡狀劑型以適用於毛髮的毛髮化妝品組合物。 28INDUSTRIAL APPLICABILITY According to the present invention, it is possible to provide a hair cosmetic group which is excellent in applicability and excellent in coating properties, and which is applied to hair and hair. The composition is a hair cream composition suitable for hair. 28

Claims

201204397 VII. Patent application scope: 通通1: Γ, hair cosmetic composition' The composition is a hair cosmetic OD composition for forming a (four) dosage form (four) heart hair in a molding container using a smear (4) forming surface, which is characterized in that ΓΑ)1〇^^〇/ 贱 is composed of the following components (4) to (C): (8) 10% by mass or less of nonionic surfactant, (B) % ionic surfactant, ϋ selected from anionic interface activity The hair cosmetic composition of the first aspect of the invention is the hair cosmetic composition of claim 1, wherein the hair cosmetic composition is used to form a mixed liquid of the first agent and the second agent. The dosage form is a two-part composition suitable for hair, and the second component of the second component (B) is blended with the component (c). A hair cosmetic composition according to claim 1 or 2, wherein the hair cosmetic composition is a hair dye or a hair bleaching decolorizer. A method for using a seven-part decoloring agent or a hair, which is characterized in that a non-aerated agent forming container is used to form a foaming dosage form to be used in two; a composition to a hair cosmetic product, characterized in that The hair cosmetic composition according to any one of the above claims, and the non-air-gel molding container for forming the hair cosmetic composition of the 201204397 into a foaming dosage form. 30 201204397 IV. Designated representative map: (1) The representative representative of the case is: ( ). (2) A brief description of the symbol of the representative figure: [None] 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: [None] 2