TW201131857A - Polymer electrolyte, polymer electrolyte membrane, membrane-electrode assembly and solid polymer-type fuel cell - Google Patents

Polymer electrolyte, polymer electrolyte membrane, membrane-electrode assembly and solid polymer-type fuel cell Download PDF

Info

Publication number: TW201131857A
Authority: TW; Taiwan
Prior art keywords: polymer; polymer electrolyte; aromatic vinyl; block; unit
Prior art date: 2009-11-30

Application number

TW099141196A

Other languages

English (en)

Chinese (zh)

Inventor

Taketomo Yamashita

Tomohiro Ono

Kazuya Shimizu

Keiji Kubo

Nozomu Sugoh

Original Assignee

Kuraray Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2009-11-30

Filing date

2010-11-29

Publication date

2011-09-16

2010-11-29 Application filed by Kuraray Co filed Critical Kuraray Co

2011-09-16 Publication of TW201131857A publication Critical patent/TW201131857A/zh

Links

239000005518 polymer electrolyte Substances 0.000 title claims abstract description 157
239000012528 membrane Substances 0.000 title claims abstract description 75
239000000446 fuel Substances 0.000 title claims abstract description 32
239000007787 solid Substances 0.000 title claims abstract description 17
229920002554 vinyl polymer Polymers 0.000 claims abstract description 209
229920000642 polymer Polymers 0.000 claims abstract description 129
229920001400 block copolymer Polymers 0.000 claims abstract description 96
229920001971 elastomer Polymers 0.000 claims abstract description 7
125000003118 aryl group Chemical group 0.000 claims description 114
-1 aromatic vinyl compound Chemical group 0.000 claims description 92
125000001931 aliphatic group Chemical group 0.000 claims description 46
125000004432 carbon atom Chemical group C* 0.000 claims description 46
150000001875 compounds Chemical group 0.000 claims description 30
229910052799 carbon Inorganic materials 0.000 claims description 28
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 24
239000000470 constituent Substances 0.000 claims description 13
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 13
150000001336 alkenes Chemical group 0.000 claims description 10
125000002897 diene group Chemical group 0.000 claims description 9
239000003792 electrolyte Substances 0.000 claims description 8
239000000126 substance Substances 0.000 claims description 4
125000001183 hydrocarbyl group Chemical group 0.000 claims 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 57
230000008961 swelling Effects 0.000 abstract description 7
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 abstract description 4
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150000002500 ions Chemical class 0.000 description 102
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238000000034 method Methods 0.000 description 66
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239000004593 Epoxy Substances 0.000 description 6
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VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 6
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XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 6
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150000002739 metals Chemical class 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate group Chemical group C(C(=C)C)(=O)[O-] CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
239000006082 mold release agent Substances 0.000 description 1
229930003658 monoterpene Natural products 0.000 description 1
125000002299 monoterpene group Chemical group 0.000 description 1
235000002577 monoterpenes Nutrition 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
239000002120 nanofilm Substances 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
SFBTTWXNCQVIEC-UHFFFAOYSA-N o-Vinylanisole Chemical compound COC1=CC=CC=C1C=C SFBTTWXNCQVIEC-UHFFFAOYSA-N 0.000 description 1
SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000003921 oil Substances 0.000 description 1
235000019198 oils Nutrition 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
150000002923 oximes Chemical class 0.000 description 1
230000020477 pH reduction Effects 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
230000037361 pathway Effects 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920001643 poly(ether ketone) Polymers 0.000 description 1
229920002480 polybenzimidazole Polymers 0.000 description 1
229920000647 polyepoxide Polymers 0.000 description 1
229920002981 polyvinylidene fluoride Polymers 0.000 description 1
238000012545 processing Methods 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
235000019260 propionic acid Nutrition 0.000 description 1
230000001681 protective effect Effects 0.000 description 1
238000010298 pulverizing process Methods 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
150000003242 quaternary ammonium salts Chemical class 0.000 description 1
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
238000006722 reduction reaction Methods 0.000 description 1
238000002407 reforming Methods 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
238000009738 saturating Methods 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical group C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
238000003860 storage Methods 0.000 description 1
150000003440 styrenes Polymers 0.000 description 1
239000000758 substrate Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1
229920005992 thermoplastic resin Polymers 0.000 description 1
230000009466 transformation Effects 0.000 description 1
RRBYUSWBLVXTQN-UHFFFAOYSA-N tricyclene Chemical group C12CC3CC2C1(C)C3(C)C RRBYUSWBLVXTQN-UHFFFAOYSA-N 0.000 description 1
DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
OWUGVJBQKGQQKJ-UHFFFAOYSA-M trimethylsulfanium;chloride Chemical compound [Cl-].C[S+](C)C OWUGVJBQKGQQKJ-UHFFFAOYSA-M 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
RSJKGSCJYJTIGS-BJUDXGSMSA-N undecane Chemical compound CCCCCCCCCC[11CH3] RSJKGSCJYJTIGS-BJUDXGSMSA-N 0.000 description 1
JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
238000001291 vacuum drying Methods 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000008158 vegetable oil Substances 0.000 description 1
239000000052 vinegar Substances 0.000 description 1
235000021419 vinegar Nutrition 0.000 description 1
238000004260 weight control Methods 0.000 description 1
230000002087 whitening effect Effects 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/122—Ionic conductors
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
- H01M8/1018—Polymeric electrolyte materials
- H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
- H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

Chemical & Material Sciences (AREA)
Sustainable Energy (AREA)
Electrochemistry (AREA)
Crystallography & Structural Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Sustainable Development (AREA)
Physics & Mathematics (AREA)
Spectroscopy & Molecular Physics (AREA)
General Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Graft Or Block Polymers (AREA)
Conductive Materials (AREA)
Inert Electrodes (AREA)
Manufacture Of Macromolecular Shaped Articles (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Fuel Cell (AREA)

TW099141196A 2009-11-30 2010-11-29 Polymer electrolyte, polymer electrolyte membrane, membrane-electrode assembly and solid polymer-type fuel cell TW201131857A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP2009271018		2009-11-30

Publications (1)

Publication Number	Publication Date
TW201131857A true TW201131857A (en)	2011-09-16

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JP (1)	JP5629692B2 (ja)
TW (1)	TW201131857A (ja)
WO (1)	WO2011065460A1 (ja)

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US8012539B2 (en)	2008-05-09	2011-09-06	Kraton Polymers U.S. Llc	Method for making sulfonated block copolymers, method for making membranes from such block copolymers and membrane structures
US8263713B2 (en)	2009-10-13	2012-09-11	Kraton Polymers U.S. Llc	Amine neutralized sulfonated block copolymers and method for making same
US9429366B2 (en)	2010-09-29	2016-08-30	Kraton Polymers U.S. Llc	Energy recovery ventilation sulfonated block copolymer laminate membrane
US9394414B2 (en)	2010-09-29	2016-07-19	Kraton Polymers U.S. Llc	Elastic, moisture-vapor permeable films, their preparation and their use
CN103201298B (zh)	2010-10-18	2015-06-24	科腾聚合物美国有限责任公司	生产磺化的嵌段共聚物组合物的方法
US9861941B2 (en)	2011-07-12	2018-01-09	Kraton Polymers U.S. Llc	Modified sulfonated block copolymers and the preparation thereof
KR20150047492A (ko) *	2012-08-23	2015-05-04	가부시키가이샤 구라레	고분자 전해질 막
TWI551615B (zh) *	2014-12-31	2016-10-01	奇美實業股份有限公司	共軛二烯－乙烯基芳香烴共聚物
JP7103912B2 (ja) *	2018-10-24	2022-07-20	トヨタ自動車株式会社	橋架け構造を有するプロトン伝導膜及び燃料電池

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JP4802354B2 (ja) *	1999-12-27	2011-10-26	住友化学株式会社	高分子電解質およびその製造方法
JP2005246800A (ja) *	2004-03-04	2005-09-15	Jsr Corp	プロトン伝導性複合膜およびその製造方法
JP2006210326A (ja) *	2004-12-27	2006-08-10	Kuraray Co Ltd	固体高分子型燃料電池用高分子電解質膜、膜−電極接合体及び燃料電池
EP1986257B1 (en) *	2006-02-13	2012-05-23	Kuraray Co., Ltd.	Polyelectrolyte film, film-electrode assembly, and solid-polymer-type fuel cell
EP2157646A4 (en) *	2007-06-04	2011-12-28	Kuraray Co	Polymer electrolyte, polymer electrolyte membrane, membrane-electrode assembly, and solid polymer fuel cell
KR101556425B1 (ko) *	2008-02-06	2015-10-01	가부시키가이샤 구라레	막-전극 접합체 및 고체 고분자형 연료 전지

2010
- 2010-11-26 WO PCT/JP2010/071088 patent/WO2011065460A1/ja not_active Ceased
- 2010-11-26 JP JP2011543309A patent/JP5629692B2/ja not_active Expired - Fee Related
- 2010-11-29 TW TW099141196A patent/TW201131857A/zh unknown

Also Published As

Publication number	Publication date
JPWO2011065460A1 (ja)	2013-04-18
JP5629692B2 (ja)	2014-11-26
WO2011065460A1 (ja)	2011-06-03

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TWI451623B (zh)	2014-09-01	高分子電解質膜、膜-電極接合體及固體高分子型燃料電池
JP5118484B2 (ja)	2013-01-16	固体高分子型燃料電池用電解質積層膜、膜−電極接合体及び燃料電池
JP5276442B2 (ja)	2013-08-28	高分子電解質、高分子電解質膜、膜−電極接合体及び固体高分子型燃料電池
TW201131857A (en)	2011-09-16	Polymer electrolyte, polymer electrolyte membrane, membrane-electrode assembly and solid polymer-type fuel cell
JP5191139B2 (ja)	2013-04-24	高分子電解質、高分子電解質膜、膜−電極接合体及び固体高分子型燃料電池
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JP2006210326A (ja)	2006-08-10	固体高分子型燃料電池用高分子電解質膜、膜−電極接合体及び燃料電池
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TW201034281A (en)	2010-09-16	Multilayer electrolyte membrane, membrane-electrode assembly and fuel cell
WO2010047329A1 (ja)	2010-04-29	有機―無機複合電解質、電解質膜、膜―電極接合体及び燃料電池
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JP2007258003A (ja)	2007-10-04	高分子電解質膜、膜−電極接合体及び固体高分子型燃料電池
JP2011103176A (ja)	2011-05-26	電解質積層膜、膜−電極接合体及び固体高分子型燃料電池
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