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TW201103746A - Plastic sheet and method for making the same - Google Patents

Plastic sheet and method for making the same Download PDF

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Publication number
TW201103746A
TW201103746A TW98125842A TW98125842A TW201103746A TW 201103746 A TW201103746 A TW 201103746A TW 98125842 A TW98125842 A TW 98125842A TW 98125842 A TW98125842 A TW 98125842A TW 201103746 A TW201103746 A TW 201103746A
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Taiwan
Prior art keywords
plastic sheet
polystyrene
base layer
providing
polypropylene
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TW98125842A
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Chinese (zh)
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TWI464059B (en
Inventor
shu-hai Peng
Jian-Bin Deng
Bo Liu
Qing-Ming Yuan
Jiang Yu
Ye Sun
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Fih Hong Kong Ltd
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Priority to TW098125842A priority Critical patent/TWI464059B/en
Publication of TW201103746A publication Critical patent/TW201103746A/en
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Publication of TWI464059B publication Critical patent/TWI464059B/en

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Abstract

The present disclosure provides a plastic sheet and a method for making the plastic sheet. The plastic sheet includes a substrate, the substrate contains polystyrene material. The plastic sheet further includes an abrasion resistance coating formed on one surface of the substrate. The abrasion resistance coating contains polypropylene material and additive agent(s). The method for making the plastic sheet includes: providing polystyrene material and heating it to molten state; providing a form container and rejecting the molten polystyrene into the form container to form a substrate; providing a mixture of polypropylene and additive agent(s) and heating the mixture to molten state; providing another form container and rejecting the molten mixture into the container to form an abrasion resistance coating; providing a rolling machine and rolling the substrate and the abrasion resistance coating to form a integer.

Description

201103746 六、發明說明: 【發明所屬之技術領域】 本發明涉及一種塑膠片 性能的塑膠片材及該塑膠片 【先前技術】 材,尤其涉及一種具有高耐磨 材的製作方法。 停昱的㈣5 _包以材通常要求做到具有 性能。此係因為包裝後的產 …、有優-的耐磨擦BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a plastic sheet having a plastic sheet property and a plastic sheet [Prior Art], and more particularly to a method for producing a highly wear-resistant material. The (4) 5 _ package material that is parked is usually required to have performance. This is because the product after packaging... has excellent wear resistance

發生摩擦,若該塑膠片材的:;=程=塑:片材 ί發,而附著於產品的表面,對產品的外觀面造成; 木 '、,而習知的常用來對電子 材的财磨性較差,Μ σ Μ …丁 C㈣χκ本乙烯片 Π°的運輸過程中很容易發生掉粉現 象對被包裝的電子產品外觀面造成污染。 【發明内容】 鑒於此冑必要&供一種具有高耐磨性能的塑膠片材。 另外,還有必要提供〜種上述塑勝片材的製作方法。 祕種塑膠片材’其包括—基層,該基層包含有聚苯乙 ’;斗’該塑膠片材還包括—形成於基層—表面的耐磨 Θ ’該耐磨層由聚丙烯及添加劑材料製成。 一種塑膠片材的製作方法,其包括如下步驟: &供預疋里的聚本乙婦並將該聚苯乙稀加熱至炼融狀 態; ”、、 長1供成型谷器,將該炫融的聚苯乙稀射出至★玄成划 容器尹形成一基層; 供預疋量的聚丙烯與添加劑的混合料並將該混合料 201103746 加熱至熔融狀態; 提供另一成型容器,將該熔融的混合料射出至該另一 • •成型容器中形成一耐磨層; . 提供一輥壓機,將該基層與耐磨層輥壓成型為一體。 相較於習知技術,所述塑膠片材藉由在聚苯乙稀基層 的表面覆合一具有較強耐磨性能的耐磨層,進而提高了聚 苯乙烯塑膠片材的耐磨損性能,可有效防止聚苯乙烯塑膠 片材的掉粉現象,使被包裝的產品外觀面不受影響。 • 【實施方式】 請參閱圖1所示,本發明一較佳實施方式的塑膠片材 10包括一基層11及形成於基層11 一表面的耐磨層13。 所述基層11主要由聚苯乙烯材料製成。該基層11中 還可含少量的滑石粉。 所述财磨層13由聚丙稀與添加劑的混合材料製成。該 添加劑包括有硬脂酸、硬脂辞及色母。所述色母可為白色 或彩色。所述添加劑可增強耐磨層13的耐磨擦性能及柔韌 • 性能。該耐磨層13中聚丙烯、硬脂酸、硬脂鋅及色母的質 量比可在25〜30 : 3〜8 : 0.01〜0.2 : 0.01-0.5之間。一般情 況下,該耐磨層13的厚度小於基層11的厚度。 所述塑膠片材10中聚苯乙烯的含量可在55〜65%之間。 請參閱圖2所示,本發明一較佳實施方式製作所述塑 膠片材10包括如下步驟: 步驟S1 :提供預定量的聚苯乙烯並將該聚苯乙烯加熱 至熔融狀態。所述聚笨乙烯中可添加少量的滑石粉,以改 善聚苯乙烯的性能。 201103746 步驟S2:提供-成型容器,將該熔融的聚苯乙稀射出 至該成型容器中形成-基層u。該成型容器優選為一具有 平滑底面的矩形谷器。該基層乜的厚度可在〜〇 9mm之 間。成型後的基層11可自然冷卻至室溫(約2(rc )。 步驟S3 :將預定量聚丙婦與添加劑的混合料加熱至炫 融狀態。所述添加劑包括有硬脂酸、硬脂鋅及色读。該耐 磨層13中聚丙稀、硬脂酸、硬脂鋅及色母的質量比可在 25〜30 : 3〜8 : 0.01 〜〇.2 ·· 〇.〇1〜〇 5 之間。 步驟S4:提供另一成型容器,將該溶融狀的聚丙稀與 添加劑的混合料射出至該另—成型容器中形成〆财磨層 13。該耐磨層13的厚度可在〇 〇5〜〇 imm之間。成型後的 耐磨層13進行自然冷卻至室溫(約2〇。〇)。 步驟S5 .提供一輥壓機,將所述冷卻後的基層11與 耐磨層13輥壓成型為一體,製得所述塑膠片材1〇。 對所述塑膠片材10進行了耐磨耗測試。測試方法為: 抓用美國進口的沙輪cs_1〇,在測試負重為l〇〇〇g的條件 下對所述耐磨層13的表面測試1〇〇〇轉。測試結果表明, 塑膠片材10的掉粉量為6〜8mg,基本達到聚對笨二甲酸乙 二酯(PET)塑膠的耐磨耗級別(相同測試條件下掉粉約 4mg) ’大大低於聚笨乙婦的掉粉量(約50〜65mg)。 所述塑膠片材1〇可製成為形式多樣的包裝片材,如包 裝袋、緩衝塾、託盤等。 本發明較佳實施方式的塑膠片材藉由在聚苯乙烯基層 的表面覆合一具有較強耐磨性能的耐磨層,進而提高了聚 苯乙烯塑膠片材的耐磨損性能,可有效防止聚苯乙烯塑膠 201103746 片材的掉粉現象,使被包裝的產品外觀不受影響。 【圖式簡單說明】 * 圖1係本發明一較佳實方式塑膠片材的示意圖; . 圖2係本發明一較佳實施方式塑膠片材的製作方法流 程圖。 【主要元件符號說明】 塑膠片材 10 基層 11 耐磨層 13Friction occurs, if the plastic sheet::=process=plastic: sheet ί hair, and attached to the surface of the product, causing the appearance of the product; wood ', and the commonly used to the electronic material The grinding property is poor, and Μ σ Μ 丁 ( ( ( ( 本 本 本 本 本 本 本 本 本 本 本 本 本 本 本 的 ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° ° SUMMARY OF THE INVENTION In view of this, it is necessary to provide a plastic sheet having high abrasion resistance. In addition, it is also necessary to provide a method for producing the above-mentioned plastic sheet. The secret plastic sheet comprises a base layer comprising polystyrene, and the plastic sheet further comprises a wear resistant layer formed on the surface of the base layer. The wear layer is made of polypropylene and additive materials. to make. A method for manufacturing a plastic sheet, comprising the steps of: & for a polymethylene in the pre-baked and heating the polystyrene to a smelt state; ”, a length of 1 for forming a barn, the dazzle The molten polystyrene is injected to the ★ Xuancheng container to form a base layer; the premixed polypropylene and the additive mixture is heated and the mixture 201103746 is heated to a molten state; another molding container is provided, the melting is provided The mixture is injected into the other • forming a wear layer in the forming container; a roll press is provided to roll-form the base layer with the wear layer. The plastic sheet is compared to the prior art. The material is coated on the surface of the polystyrene substrate to cover a wear-resistant layer with strong wear resistance, thereby improving the wear resistance of the polystyrene plastic sheet, and effectively preventing the polystyrene plastic sheet. The powder falling phenomenon causes the appearance of the packaged product to be unaffected. [Embodiment] Referring to FIG. 1, a plastic sheet 10 according to a preferred embodiment of the present invention includes a base layer 11 and a surface formed on the base layer 11. Wear layer 13. The base layer 1 1 is mainly made of polystyrene material. The base layer 11 may also contain a small amount of talc powder. The enrichment layer 13 is made of a mixed material of polypropylene and additives. The additive includes stearic acid and hard fat. And the color masterbatch, the color masterbatch may be white or colored. The additive may enhance the abrasion resistance and flexibility and performance of the wear resistant layer 13. The wear layer 13 is made of polypropylene, stearic acid, zinc stearate and The mass ratio of the masterbatch may be between 25 and 30: 3 to 8: 0.01 to 0.2: 0.01 to 0.5. In general, the thickness of the wear layer 13 is smaller than the thickness of the base layer 11. The plastic sheet 10 is gathered. The content of styrene may be between 55 and 65%. Referring to Figure 2, the plastic sheet 10 is formed according to a preferred embodiment of the present invention comprising the following steps: Step S1: providing a predetermined amount of polystyrene and The polystyrene is heated to a molten state. A small amount of talc may be added to the polystyrene to improve the properties of the polystyrene. 201103746 Step S2: providing a molded container, and ejecting the molten polystyrene to the Forming a base layer u in the molding container. The molding container preferably has one The rectangular bottom of the sliding bottom surface. The thickness of the base layer can be between ~ 〇 9 mm. The formed base layer 11 can be naturally cooled to room temperature (about 2 (rc ). Step S3: mixing a predetermined amount of polypropylene with additives The material is heated to a molten state. The additive comprises stearic acid, zinc stearate and color reading. The mass ratio of polypropylene, stearic acid, zinc stearate and color masterbatch in the wear layer 13 can be 25~30 : 3 to 8 : 0.01 〇 2 2 2 2 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤 步骤The ruthenium layer 13 is formed in the middle. The thickness of the wear layer 13 can be between 〇〇5 and 〇imm. The formed wear layer 13 is naturally cooled to room temperature (about 2 Torr. 〇). Step S5. A roll press is provided, and the cooled base layer 11 and the wear-resistant layer 13 are roll-formed into one body to obtain the plastic sheet 1〇. The plastic sheet 10 was subjected to a wear resistance test. The test method is as follows: The sand wheel cs_1〇 imported from the United States is grasped, and the surface of the wear layer 13 is tested for 1 turn under the condition that the test load is l〇〇〇g. The test results show that the powder loss of the plastic sheet 10 is 6~8mg, which basically reaches the wear resistance level of the polyethylene (PET) plastic (about 4mg under the same test conditions). The amount of powder dropped by the polystyrene (about 50~65mg). The plastic sheet 1 can be made into a variety of packaging sheets, such as a packaging pouch, a buffer, a tray, and the like. The plastic sheet of the preferred embodiment of the present invention can improve the wear resistance of the polystyrene plastic sheet by covering a surface of the polystyrene base layer with a wear-resistant layer having a strong wear resistance. Prevent the powder drop phenomenon of polystyrene plastic 201103746, so that the appearance of the packaged product is not affected. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing a plastic sheet of a preferred embodiment of the present invention; Fig. 2 is a flow chart showing a method of fabricating a plastic sheet according to a preferred embodiment of the present invention. [Main component symbol description] Plastic sheet 10 Base layer 11 Wear layer 13

Claims (1)

201103746 七、申請專利範圍: 1. 一種塑膠片材,其包括一基層,該基層包含有聚苯乙 • 烯材料,其中該塑膠片材還包括一形成於基層一表面 . 的耐磨層,該而ί磨層由聚丙稀及添加劑材料製成。 2. 如申請專利範圍第1項所述的塑膠片材,其中所述添 加劑包括有硬脂酸、硬脂鋅及色母。 3. 如申請專利範圍第2項所述的塑膠片材,其中所述聚 丙烯、硬脂酸、硬脂鋅及色母的質量比在25〜30: 3〜8 : • 0.01~0.2 : 0.01 〜0.5 之間。 4. 如申請專利範圍第1項所述的塑膠片材,其中所述塑 膠片材中聚苯乙烯的含量在55~65%之間。 5. 如申請專利範圍第1項所述的塑膠片材,其中所述基 層中還含有滑石粉。 6. —種塑膠片材的製作方法,其包括如下步驟: 提供預定量的聚苯乙烯並將該聚苯乙烯加熱至熔融 狀態; • 提供一成型容器,將該熔融的聚苯乙烯射出至該成 型容器中形成一基層; 提供預定量的聚丙烯與添加劑的混合料並將該混合 料加熱至熔融狀態; ‘ 提供另一成型容器,將該熔融的混合料射出至該另 一成型容器中形成一耐磨層; 提供一輥壓機,將該基層與耐磨層輥壓成型為一體。 7. 如申請專利範圍第6項所述的塑膠片材的製作方法, 其中所述添加劑包括有硬脂酸、硬脂鋅及色母。 201103746 8. 如申請專利範圍第7項所述的塑膠片材的製作方法, 其中所述聚丙烯、硬脂酸、硬脂辞及色母的質量比在 25〜30 : 3〜8 : 0.01 〜0.2 : 0.01 〜0.5 之間。 9. 如申請專利範圍第6項所述的塑膠片材的製作方法, 其中所述基層與耐磨層在輥壓成型前進行自然冷卻。201103746 VII. Patent application scope: 1. A plastic sheet comprising a base layer comprising a polystyrene material, wherein the plastic sheet further comprises a wear layer formed on a surface of the base layer, The 磨磨层 is made of polypropylene and additive materials. 2. The plastic sheet of claim 1, wherein the additive comprises stearic acid, zinc stearate, and a color masterbatch. 3. The plastic sheet according to claim 2, wherein the mass ratio of the polypropylene, stearic acid, zinc stearate and color masterbatch is 25 to 30: 3 to 8: • 0.01 to 0.2: 0.01 Between ~0.5. 4. The plastic sheet according to claim 1, wherein the plastic film material has a polystyrene content of 55 to 65%. 5. The plastic sheet of claim 1, wherein the base layer further comprises talc. 6. A method of making a plastic sheet comprising the steps of: providing a predetermined amount of polystyrene and heating the polystyrene to a molten state; • providing a shaped container to eject the molten polystyrene to the Forming a base layer in the molding container; providing a predetermined amount of the mixture of the polypropylene and the additive and heating the mixture to a molten state; 'providing another molding container, and ejecting the molten mixture into the other molding container A wear layer; a roll press is provided to roll-form the base layer and the wear layer into one body. 7. The method for producing a plastic sheet according to claim 6, wherein the additive comprises stearic acid, zinc stearate, and a color masterbatch. The method for producing a plastic sheet according to claim 7, wherein the mass ratio of the polypropylene, stearic acid, stearin and color masterbatch is 25 to 30: 3 to 8: 0.01 〜 0.2 : between 0.01 and 0.5. 9. The method of producing a plastic sheet according to claim 6, wherein the base layer and the wear layer are naturally cooled prior to roll forming.
TW098125842A 2009-07-31 2009-07-31 Plastic sheet and method for making the same TWI464059B (en)

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GB1566239A (en) * 1977-09-26 1980-04-30 Mitsui Petrochemical Ind Thermoplastic filmforming olefin polymer composition
JP3542363B2 (en) * 1993-08-20 2004-07-14 出光石油化学株式会社 Polystyrene resin multilayer sheet and multilayer container comprising the multilayer sheet
US7736726B2 (en) * 2002-12-17 2010-06-15 Cryovac, Inc. Polymeric film with low blocking and high slip properties

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