201043157 六、發明說明： 【發明所屬之技術領域】 '本發明係有關非燃燒型吸煙物品用薄片及含此薄片之 非燃燒型吸煙物品，以及該等之製造方法。 【先前技術】 香煙係藉由使煙草燃燒而透過人的味覺、嗅覺以品嘴 煙霧（氣溶膠；aerosol)中的香味之吸煙物品所代表者。 ❹ 近年來，為取代香煙而開發一種未燃燒煙草而可品嚐 香味的非燃燒型吸煙物品（例如：參照專利文獻1、專利文 獻2、專利文獻3)。以往的非燃燒型吸煙物品具有：安裝 於前端之作為發熱構件之熱源部、與含有使香味成分保持 於適當基材中之香味產生材（亦即產生香味之材料）的香味 產生部（亦即產生香味之部分），而熱源部與香味產生部係 以物理性分離。亦即，非燃燒型吸煙物品的製造中，熱源 邛與香味產生部需要各自分別之製作步驟乃為現況。熱源 °主要係使用碳質熱源，此係由含有碳粒與黏合劑（binder) 之碳質材料經擠壓而成之圓柱狀實心成型品。在該碳質熱 源中設有通孔，以發揮作為空氣通路之功能，使熱源初期 易於燃燒，且使通過熱源而暖化之空氣流入香味產生部。 …：而，上述熱源，除了空氣通路之外，為實心物品，盥一 般香煙相比係難以著火。並且，具備由擠壓之實心成型品 ，構成的熱源之非錢寵煙物品，係在㈣丨支煙時， 每次噴煙（puff)之香味成分量的最大值與最小值之差距 大特別疋在抽吸最初第2、3 口時的香味成分量少，平均 321926 3 201043157 每支煙品嚐不到固定的香味。 [先前技術文獻] [專利文獻] [專利文獻1]日本特開昭61-92558號公報 [專利文獻2]曰本特開昭62-48370號公報 [專利文獻3]日本特開平6-311877號公報 【發明内容】 [發明所欲解決之課題] 本發明之第一目的係提供一種非燃燒型吸煙物品用薄 片’藉此，可較以往更簡便地製作非燃燒型吸煙物品。並 且，本發明之第二目的係提供一種非燃燒型吸煙物品，其 熱源較易於著火，且平均每支可品嚐到幾乎固定的香味。 [用以解決課題之手段] 依據本發明之一態樣，係提供一種非燃燒型吸煙物品 用薄片，包含相互鄰接並一體化之碳質熱源薄片部分以及 香味產生薄片部分（亦即產生香味之薄片部分）。 本發明之非燃燒型吸煙物品用薄片可為自行支樓性 者’亦可藉襯片（backing sheet)所支樓。 依據本發明之其它態樣’係提供一種非燃燒型吸煙物 品’備有：圓筒體、與折疊後收納在該圓筒中之本發明的 非燃燒型吸煙物品用薄片。 依據本發明之另一其它態樣，係提供一種非燃燒型吸 煙物品用薄片之製造方法，包含下列步驟： (i)分別調製碳質熱源組成物之漿液（a)以及香味產生組成 321926 201043157201043157 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a sheet for a non-combustible smoking article and a non-combustion type smoking article containing the sheet, and a manufacturing method therefor. [Prior Art] A cigarette is a representative of a smoking article that scented by a person's taste and smell in the mouth of a smoke (aerosol) by burning the tobacco. In recent years, in order to replace cigarettes, a non-combustible smoking article in which unburned tobacco is used to taste the flavor has been developed (for example, refer to Patent Document 1, Patent Document 2, and Patent Document 3). A conventional non-combustion type smoking article includes a heat source portion that is attached to the tip end as a heat generating member, and a flavor generating portion that contains a flavor generating material (that is, a material that generates flavor) that holds the flavor component in a suitable base material (that is, The portion where the aroma is generated), and the heat source portion and the flavor generating portion are physically separated. That is, in the manufacture of a non-combustible smoking article, the heat source enthalpy and the flavor generating portion require separate manufacturing steps as the current state. The heat source ° mainly uses a carbonaceous heat source, which is a cylindrical solid molded product obtained by extruding a carbonaceous material containing carbon particles and a binder. The carbonaceous heat source is provided with a through hole to function as an air passage, so that the heat source is easily burned at the initial stage, and the air warmed by the heat source flows into the flavor generating portion. ...: However, the above-mentioned heat source, in addition to the air passage, is a solid article, and it is difficult to catch fire in general cigarettes. In addition, the non-cheap tobacco article having a heat source composed of a solid molded product is a large difference between the maximum value and the minimum value of the flavor component of each puff. The amount of aroma components in the first 2 and 3 mouths was small, and the average 321926 3 201043157 could not taste a fixed fragrance per cigarette. [PRIOR ART DOCUMENT] [Patent Document 1] JP-A-61-92558 [Patent Document 2] Japanese Patent Laid-Open No. Hei 62-48370 (Patent Document 3) Japanese Patent Laid-Open No. Hei 6-311877 SUMMARY OF THE INVENTION [Problems to be Solved by the Invention] A first object of the present invention is to provide a non-combustion type sheet for smoking articles, whereby a non-combustion type smoking article can be produced more easily than in the past. Further, a second object of the present invention is to provide a non-combustion type smoking article which is more susceptible to ignition than a heat source and which can taste an almost fixed fragrance on average. [Means for Solving the Problem] According to one aspect of the present invention, there is provided a sheet for a non-combustion type smoking article comprising a carbonaceous heat source sheet portion adjacent to and integrated with each other and a flavor generating sheet portion (that is, a flavor generating portion) Sheet portion). The sheet for a non-combustible smoking article of the present invention may be a self-supporting member or may be supported by a backing sheet. According to another aspect of the present invention, a non-combustion type smoking article is provided with a cylindrical body and a sheet for a non-combustible smoking article of the present invention which is housed in the cylinder after being folded. According to still another aspect of the present invention, there is provided a method for producing a sheet for a non-combustion type smoking article comprising the steps of: (i) separately preparing a slurry of a carbonaceous heat source composition (a) and a flavor generating composition 321926 201043157
之步驟。 上述步驟（ii)中， 物（亦即產生香味之組成物）之漿液⑹的步驟 (ii)使漿液（a)及（b)在彡推—，—ai .丄 可使用襯片作為支撐體，並將上述 碳質熱源組成物t液與上料味產纽成物漿液在襯片上 ^ 進行澆鑄。 〇 依據本發明之其它態樣，係提供—種非燃燒型吸 煙物品之製造方法，包含下列步驟： (a) 以上述方法製造吸煙物品用薄片之步輝；以及 (b) 將上述吸煙物品用薄片摺疊並收納在圓筒中之步驟。 [發明效果] 本發明之非燃燒型吸煙物品用薄片係可藉由使碳質熱 源組成物漿液與碳質熱源漿液鄰接並澆鑄且乾燥之極為簡 〇 單之步驟而簡便地製造。僅使用本發明之非燃燒型吸煙物 品用薄片並將其摺疊收納於圓筒體中，即可簡便地製作本 發明之非燃燒型吸煙物品。因本發明之非燃燒型吸煙物品 係將非燃燒型吸煙物品用薄片摺疊並收納於圓筒體中，因 而與具有實心熱源者不同，由於經折疊之碳質熱源薄片與 空氣之接觸面積增大而可使之較容易著火，並且平均每支 吸煙物品可品嚐到幾乎固定的香味。 【實施方式】 以下，一面參照圖示，同時說明本發明。 5 321926 201043157 第1圖係表示依本發明之一態樣的非燃燒型吸煙物品 用薄片10之透視圖。 非燃燒型吸煙物品用薄片1 0係藉由使碳質熱源薄片 部分12與香味產生薄片部分13在襯片u上以橫向鄰接之 狀態進行一體化而成者。碳質熱源薄片部分12之幅寬W 一般為5至20nun，香味產生薄片部分13之幅寬μ —般為 20 至 40mm。 襯片11係使用紙、鋁箔、積層鋁紙等。另外，當經_ 體化之碳質熱源薄片部分12與香味產生薄片部分13"具有 自行支撐性時，不一定需要使用支撐基材。同時，襯片U 在第1圖中係如虛線所示，可分割成：僅將碳質 部分12予以全部墊襯之第！部分Ila、與僅將香 片部分13予以全部墊襯之第2部分Ub。此時，可在含有 薄片10之香煙中，由鋁箔、積層鋁紙等不燃性材料形成第 1部分11b，以使碳質熱源薄片部分燃燒，但同時使香味產 生薄片部分不易燃燒。 碳質熱源薄片部分12係以碳質熱源組成物製作。碳質 熱源組成物基本上含有用以使碳（粒子或纖維）與碳黏結之 黏合劑。所使用之碳的來源並無特別限制，亦可使用習知 之任-種碳。可含之碳的比例為碳質熱源組成物之總重量 的1重量％以上。通常，碳可構成達至礙質熱源組成物之總 重量的80%。 " 使碳粒子或纖維黏結之黏合劑可使用羧甲基纖維素、 甲絲乙基纖維素、祕鹽（例如：藻酸銨、藻酸卸）等。 321926 6 201043157 相對於碳1重量份，黏合劑一般係可依0. 01至50重量份 之比例調配，以0. 011至2重量份之比例調配為佳，又以 0. 083至1. 5重量份之比例調配更佳。黏合劑係作為薄片 形成材。 碳質熱源組成物係為了在初期之抽吸t使氣溶膠容易 產生，而可含有氣溶膠產生物質（亦即產生氣溶膠之物 質）。碳質熱源組成物中所可含之氣溶膠產生物質，由非燃 燒型吸煙物品用薄片之形成容易度的觀點而言，相對於碳 Ο 1重量份，一般可依最多至98重量份之比例調配，以0.053 至8. 9重量份之比例調配為佳，又以0. 167至3. 5重量份 之比例調配更佳。 又，碳質熱源組成物可含有用以降低熱源之最高燃燒 溫度而減少一氧化碳之產生量的碳酸鈣（粒子）以及其它之 無機添加材。該無機添加材，由本發明之非燃燒型吸煙物 品用薄片之形成容易度的觀點而言，相對於碳1重量份， Q 一般可依最多至98重量份之比例使用，以至8. 4重量份之 比例使用為佳，又以0.417至7. 5重量份之比例使用更佳。 更且，碳質熱源組成物亦可含有紙漿、煙草粉末等。 紙漿、煙草粉末之總和，相對於碳1重量份，一般可依最 多至9 8重量份之比例使用，以最多至3重量份之比例使用 為佳。紙漿係使本發明之非燃燒型吸煙物品用薄片更容易 成形，而煙草粉末可改善香味。 進一步而言，碳質熱源組成物中可含有：如硼、鋁、 碎、欽、鐵、銘、錄、辞、錯、錯、銳、錮、釘、錢、把、 7 321926 201043157 等 至 更 銀、錫、鈽、铪、钽、鎢、鍊、餓、銥、鉑、金以及兮 之氧化物或該等之混合物等使一氧化碳降低之觸媒。^ 氧化碳降低之觸媒，相對於碳1重量份，一般可依〇 1重量份之比例使用，以0.02至0.2重量份之比例使用 香味產生薄片部分13係以香味產生組成物製作。香味 產生組成物包含薄片形成材與香味產生劑。薄片形成椅可 使用碳質熱源薄片部分中所使用之黏合劑、如卡德蘭多糖 (curdlan)之葡聚糖（giUCan)等熱不可逆凝固性葡聚糖。熱 不可逆凝固性葡聚糖若加熱至凝膠化臨界溫度以上之溫户 (例如：當其為卡德蘭多醣時則為8(TC以上之溫度）時，即 凝膠化’而此凝膠即使再度加熱亦無法溶解。更且，可將 紙漿與上述黏合劑組合使用而作為薄片形成材。 香味產生薄片部分13所含之香味產生劑中，係包含： 煙葉卒取物、天然植物性香料（例如：甘草、長角豆（s t John’s bread)、李子萃取物、桃子萃取物等）、酸類（例如： 蘋果酸、酒石酸、檸檬酸等）、糖類（例如··葡萄糖、果糖、 異構化糖等）、於驗鹽（例如：檸檬酸於驗等）等親水性香味 產生劑；薄荷腦（menthol) '可可亞類（粉末、萃取物等）、 酯類（例如：乙酸異戊酯、乙酸沈香酯（1 inalyl acetate)、 丙酸異戊酯、丁酸沈香酯等）、天然精油類（植物性之例列 舉如：香草萃取物、綠薄荷（spearmint)、薄荷 (peppermint)、中國肉桂（Cinnamomum cassia)、茉莉花 等；動物性之例列舉如：麝香（musk)、破珀、麝貓香 8 321926 201043157 (civet)、海狸香等）、單體香料（例如：茴香腦（anethole)、 檸檬烯（limonene)、沈香醇（linalool)、丁香驗（eugenol) 等）等疏水性香味產生劑。該等香味產生劑可單獨使用或將 2種以上組合使用。該等香味產生劑之香味產生薄片部分 中的濃度，只要為在將香味產生材加熱時透過味覺·嗅覺而 可充分地滿足使用者之嗜好的濃度即可，該濃度可任意調 整。進一步具體而言，香味產生劑在最後的香味產生材中 0 係以極微量至20重量％之比例存在，以5至1〇重量％之比 例為佳。更且，香味產生劑可使用煙絲或粉末。煙絲或粉 末在香味產生薄片部分中可調配5至80重量％之量。 香味產生組成物宜含有經由加熱而產生氣溶膠之氣溶 膠產生物質。氣溶膠產生物質可使用例如：甘油、丙二醇、 三乙二醇、四乙二醇等多元醇；硬脂酸甲酯、十二碳二酸 二甲酯、十四碳二酸二曱酯等綾酸脂肪酸酯。氣溶膠產生 物質在香味產生薄片部分中可使用1至8〇重量％之量。 Ο 本發明之非燃燒型吸煙物品用薄片1〇可依包含下述 步驟之方法製造·· (i) 分別調製碳質熱源組成物之漿液（a)以及香味產生組成 物之漿液（b)的步驟； (ii) 使漿液（a)以及（b)在支撐體上鄰接並澆鑄的步驟；以 及 (iii) 藉由將上述洗鑄之襞液（a)以及（b)乾燥，而使碳質熱 源薄片部分與香味產生薄片部分以鄰接之狀態進行一體化 之步驟。 321926 9 201043157 步驟（i)中，碳質熱源組成物漿液以及香味產生組成物 漿液係可分別在上述碳質熱源組成物以及上述香味產生組 成物中加水而調製。 步驟（ii)中’於支撐體上使碳質熱源組成物漿液以及 香味產生組成物漿液鄰接並澆鑄。支撐體例如可使用金屬 板。或者，亦可使用上述襯材作為支撐體，並在該襯材上 使碳質熱源組成物漿液（a)與香味產生組成物漿液（b)鄰接 並澆縳。在金屬板上澆鑄時’可製作不含襯材之非燃燒型 吸煙物品用薄片，在襯材上澆鑄時，可製作含有襯材之非 燃燒型吸煙物品用薄片。 步驟（iii)中，將步驟（ii)中所澆鑄之漿液進行乾燥。 乾燥可在60至170°C之溫度中進行。 如第2圖所示’本發明之非燃燒型吸煙物品2〇可藉由 將非燃燒型吸煙物品用薄片10折疊後收納在圓筒體21中 而製造。第3圖係表示非燃燒型吸煙物品用薄片收納在 圓筒體21中之收納型態之一例。第3圖中，1枚薄片1〇 係經折疊後收納於圓筒體21中，而形成由前端的熱源部朝 後端的香味產生部延伸之空氣流道1〇1。 本發明之非燃燒型吸煙物品20可藉由如上述般將非 燃燒型吸煙物品用薄片10折疊後收納在圓筒體21中的相 較於以往方法為非常簡便之步驟而進行製造，例如亦可期 待由自動控制機器（Robot)進行製造。 收納本發明之非燃燒型吸煙物品用薄片1〇的圓筒體 21可由例如一般的香煙捲紙、再生煙草片（以壓延法、聚 321926 10 201043157 液法、造紙法所製之再生煙草片或不織布再生煙草片等）、 高基量（basis Weight)之捲紙（基量5〇g/m2以上）的紙片； 鋁片、積層鋁紙等所構成。圓筒體21可規定成：包含點火 端之前端部、包含連接有後述說明的濾器之基端的基端 部、以及位於前端部與基端部之間的中間部。於經折疊後 收納在圓筒體之薄片中，碳質熱源薄片部分係配置在圓筒 體的前端部内。 0 更且，本發明之非燃燒型吸煙物品20可在與熱源側相 反之端部具有一般香煙所使用之濾器22。濾器22係由一 般香煙所使用之濾器材料（例如：纖維素乙酸酯纖維束）所 構成，其外周係由捲紙（未圖示）所捲繞。收納本發明之非 燃燒型吸煙物品用薄片1〇的圓筒體21與濾器22係例如經 由包覆外周JH»體之捲紙而連接。捲紙可使用一般的香煙捲 紙。並且，濾器22與一般的香煙相同，能以接裝紙（tipping paper)連接至吸煙物品本體。 〇 本發明之非燃燒型吸煙物品用薄片10的碳質熱源薄 片部分12，可在折疊狀態下，與一般的香煙相同地，由打 火機在短時間内（例如2秒）點著火。點著火後，由吸口端 部（濾器22)抽吸吸煙物品1〇時，空氣會被吸進而通過以 收納在圓筒體21中之薄片所形成的空氣流道，並因碳質熱 源薄片部分12之燃燒熱而經加熱。該經加熱之空氣在通過 香味產生薄片部分13時，會將其加熱而產生香味。所產生 之香味係介由濾器22而使吸煙者品嚐。由本發明之非燃燒 型吸煙物品用薄片10所構成之非燃燒型吸煙物品2〇，係 321926 11 201043157 由第1、2次抽吸至最後的抽吸均可呈現幾乎固定的香味。 另外’非燃燒型吸煙物品20為了稀釋抽吸成分（例如 二氧化碳）而可具有在抽吸時用以取入空氣的開口。 [實施例] 其次，依據實施例說明本發明’惟本發明並不受該等 實施例所限定。 實施例1以及比較例1至2 分別以混合機混合由碳粒子30重量％、碳酸鈣45重量 %、甘油15重量％以及藻酸銨（黏合劑）10重量％所構成之碳 質熱源混合物，與由煙草粉末58重量％、紙漿3〇重量％、 甘油5重量％以及曱基羥乙基纖維素（黏合劑）7重量％所構 成之香味產生混合物。在各混合物中添加該等在作成漿液 時所需之量的水，分別調製成碳質熱源混合物之漿液與香 味產生混合物之漿液。使該等2種漿液鄰接並澆鑄，使金 屬板上之厚度成為015mm後，在設定於8(Tc的恆溫槽中 約乾燥1小時。如此，得到碳質熱源薄片部分與香味產生 薄片為鄰接並一體化之吸煙物品用薄片。碳質熱源薄片部 分切成幅寬（參照第i圖之们）為1〇mm且長度為9〇mm者， 香味產生薄片部分切成幅寬（參照第1圖之W2)為31mm且 長度為90mm者。 第4圖係具有由碳質材料經擠壓而成的實心成形體 (圓柱體）作為加熱源之市售的非燃燒型吸煙物品（商品名 稱· AIRS)30之概略的剖面圖。該非燃燒型吸煙物品3〇係 具備經紙片342包覆之以由碳質材料經擠壓而成的實心成 12 321926 201043157 形體341所構成之加熱源43。緊接著加熱源μ而設有氣 • 32。該氣溶勝產生部32係由收納在不燃性圓 间體 +之含有甘油的氣溶膠產生材322所構成。緊接 ‘著氣溶膠產生部32而設有香味產生部36。該香味產生= 3 6係由收納在不燃性圓筒體3 6工中之含有煙絲的香味產生 材362所構成。在香味產生部％之基端，連接著經紙片 382包覆之具有由纖維素乙酸醋纖維束所構成的渡器構材 ◎ 381之滤器冑38。氣溶膠產生部32之基端部分、香味產生 部36與濾器部38係經捲紙4〇包覆該等之外周面。貫穿捲 紙40與紙片382而設有直至濾器構材為止之開口 〇p。 由第4圖所示之非燃燒型吸煙物品3〇取出加熱源34 與氣溶膠產生部32，相對地將由上述之碳質熱源薄片部分 與香味產生薄片經一體化而成之薄片如第3圖所禾般摺 疊、插入，製作本發明之吸煙物品（實施例〇。 而且，將與實施例1使用之碳質熱源混合物相同組成 〇的混合物擠壓成形為實心圓柱狀，並將成為空氣流道之軸 方向的溝設於外周面内，而製作加熱源。以該加熱源取代 第4圖之非燃燒型吸煙物品的加熱源34，製作比較例1之 吸煙物品。 比較例2之吸煙物品係如上所述，使用第4圖所示之 市售的非燃燒型吸煙物品（商品名稱：AIRS)。 將以上製作之實施例1的吸煙物品試樣與比較例1、2 的吸煙物品，在加拿大之被動吸煙（Passive Smoking)條件 (吸煙容量55mL/2秒；吸煙間隔30秒；逃氣塊（vent block) 13 321926 201043157 100%)下吸煙。點著火時’比較例1的吸煙物品與比較例2 的吸煙物品係依據日本煙草協會（TI0J)法，必須以電氣式 打火機加熱30秒鐘，相對於此’實施例1的吸煙物品試樣 係與一般香煙相同，以2秒鐘即可點著火。 此外’分別使本發明之吸煙物品試樣、比較例1及2 的吸煙物品以自動抽煙機抽吸7次。並採集每次抽吸之 煙’測定總粒子狀物質（TPM)之量。將結果示於以下之表1。 [表1] 抽吸次數 (次） 每次抽吸之TPM量（ms) 實施例1 比較例1 比較例2 1 1.48 0. 72 0. 22 2 2. 14 1. 38 2.20 3 2. 12 1.40 6. 11 4 2. 07 3. 13 8. 34 5 1. 69 7. 17 12.73 6 1. 24 9. 15 5. 95 7 — 6. 30 4. 80 由表1所示結果可確認，相較於使用由擠壓成形品所 構成的加熱源之比較例1的吸煙物品，本發明之吸煙物品 可改善吸煙初期（至第3次抽吸為止）的TPM量。特別是， 在使用由擠壓成形品所構成的加熱源之比較例1、2的吸煙 物品中，在中間的抽吸（接近第5次抽吸至第6次抽吸）時 之TPM量明顯增大，顯示具有高的極大值之廓線。相對於 321926 14 201043157 ^ 此作為本發月之吸·煙物品的實施例1之吸煙物品，可知 其每次抽吸之TPM量的變化幅度小，每次抽吸之TPM量的 極大值與極小值之階差降低，而可品嚐平均每支幾乎固定 的味道。並且，相較於比較例2之以往的吸煙物品，可確 認實施例1之本發明的吸煙物品已改善吸煙初期的TMp量。 【圖式簡單說明] 第I*圖係概略表示依本發明之一態樣的非燃燒型吸煙 0 物品用薄片之透視圖。 帛2 ®餘略表示本判之非職魏煙物品的-例 之透視圖。 第3圖係表不將第2圖所示非燃燒型吸煙物品在與長 袖方向正交之方向予以切斷而成之剖面的剖面圖。 第4圖係表示將市售之非燃燒型吸煙物品（曰本煙草 產業（股）製，商品名：AIRS)在長軸方向予以切斷而成之剖 面的剖面圖。 〇 【主要元件符號說明】 10 非燃燒型吸煙物品用薄 [片 11 襯片 11a 經墊襯之第1部分 lib 經墊襯之第2部分 12 碳質熱源薄片部分 13 香味產生薄片部分 20 非燃燒型吸煙物品 21 圓筒體 22 遽器 30 非燃燒型吸煙物品 32 氣溶膠產生部 34 加熱源 36 香味產生部 38 遽器部 40 捲紙 321926 15 201043157 101 空氣流道 321 不燃性圓筒 322 氣溶膠產生材 341 實心成形體 342 紙片 361 不燃性圓筒 362 香味產生材 381 濾器構材 382 紙片 W1 碳質熱源薄片部分之幅寬 W2 香味產生薄片部分之幅寬 OP 開口 16 321926The steps. In the above step (ii), the step (ii) of the slurry (6) of the substance (that is, the composition for producing aroma) causes the slurry (a) and (b) to be pushed, and the ai. And casting the above-mentioned carbonaceous heat source composition t liquid and the upper material flavoring product slurry on the lining. According to another aspect of the present invention, there is provided a method of manufacturing a non-combustible smoking article comprising the steps of: (a) producing a step of a sheet for smoking articles by the above method; and (b) using the above smoking article The step of folding and accommodating the sheet in the cylinder. [Effect of the Invention] The non-combustion type smoking article sheet of the present invention can be easily produced by a step of arranging a carbonaceous heat source composition slurry adjacent to a carbonaceous heat source slurry and casting it, and drying it in a very simple manner. The non-combustible smoking article of the present invention can be easily produced by simply using the sheet for non-combustible smoking articles of the present invention and folding and storing the sheet in a cylindrical body. Since the non-combustion type smoking article of the present invention folds and stores the non-combustion type smoking article in the cylindrical body, unlike the one having a solid heat source, the contact area of the folded carbonaceous heat source sheet with air is increased. It can make it easier to catch fire, and on average, each smoking article can taste almost fixed fragrance. [Embodiment] Hereinafter, the present invention will be described with reference to the drawings. 5 321926 201043157 Fig. 1 is a perspective view showing a sheet 10 for a non-combustion type smoking article according to an aspect of the present invention. The non-combustion type smoking article sheet 10 is obtained by integrating the carbonaceous heat source sheet portion 12 and the flavor generating sheet portion 13 in the laterally adjacent state on the lining u. The width W of the carbonaceous heat source sheet portion 12 is generally 5 to 20 nun, and the width of the aroma-generating sheet portion 13 is generally 20 to 40 mm. The lining sheet 11 is made of paper, aluminum foil, laminated aluminum paper or the like. Further, when the carbonaceous heat source sheet portion 12 and the flavor generating sheet portion 13" have self-supporting properties, it is not necessary to use a supporting substrate. At the same time, the lining U is shown as a broken line in Fig. 1 and can be divided into: only the carbonaceous portion 12 is completely lined up! The portion Ila and the second portion Ub which are only lining the scent portion 13 are entirely provided. At this time, in the cigarette containing the sheet 10, the first portion 11b may be formed of a non-combustible material such as aluminum foil or laminated aluminum paper to partially burn the carbonaceous heat source sheet, but at the same time, the flavor-generating sheet portion is less likely to be burned. The carbonaceous heat source sheet portion 12 is made of a carbonaceous heat source composition. The carbonaceous heat source composition basically contains a binder for bonding carbon (particles or fibers) to carbon. The source of the carbon to be used is not particularly limited, and any of the conventional carbons may be used. The proportion of carbon which may be contained is 1% by weight or more based on the total weight of the carbonaceous heat source composition. Typically, carbon can constitute up to 80% of the total weight of the constituents of the heat source. " The binder for bonding carbon particles or fibers may be carboxymethyl cellulose, methyl ethyl cellulose, secret salt (for example, ammonium alginate, alginic acid). _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The proportion of parts by weight is better. The binder is used as a sheet forming material. The carbonaceous heat source composition may contain an aerosol generating substance (i.e., an aerosol generating substance) in order to facilitate the generation of the aerosol at the initial suction t. The aerosol-generating material which can be contained in the composition of the carbonaceous heat source can be generally up to 98 parts by weight based on 1 part by weight of the carbon oxime from the viewpoint of easiness of formation of the sheet for the non-combustible smoking article. 5重量份的优选优选优选。 The blending, preferably from 0.053 to 8.9 parts by weight, and more preferably from 0. 167 to 3.5 parts by weight. Further, the carbonaceous heat source composition may contain calcium carbonate (particles) and other inorganic additives for reducing the maximum combustion temperature of the heat source and reducing the amount of carbon monoxide generated. 0重量份。 The inorganic additive, the non-combustion type of the article for the formation of a sheet of the present invention, with respect to 1 part by weight of the carbon, Q can be used up to a ratio of up to 98 parts by weight, up to 8.4 parts by weight The ratio is preferably used, and is preferably used in a ratio of 0.417 to 7.5 parts by weight. Further, the carbonaceous heat source composition may also contain pulp, tobacco powder, or the like. The sum of the pulp and the tobacco powder is generally used in a proportion of up to 98 parts by weight, based on 1 part by weight of the carbon, and preferably used in a proportion of up to 3 parts by weight. The pulp system makes the sheet for non-combustible smoking articles of the present invention easier to form, and the tobacco powder can improve the flavor. Further, the carbonaceous heat source composition may contain: such as boron, aluminum, broken, chin, iron, Ming, recorded, resigned, wrong, wrong, sharp, 锢, nail, money, put, 7 321926 201043157, etc. A catalyst that reduces carbon monoxide, such as silver, tin, antimony, bismuth, antimony, tungsten, chains, hungry, antimony, platinum, gold, and antimony oxides or mixtures thereof. The catalyst for reducing carbon oxide is generally used in an amount of 1 part by weight based on 1 part by weight of carbon, and is used in a ratio of 0.02 to 0.2 part by weight. The flake-generating sheet portion 13 is produced as a flavor generating composition. The fragrance generating composition contains a sheet forming material and a flavor generating agent. The sheet forming chair can use a binder used in the carbonaceous heat source sheet portion, a thermolabile coagulated glucan such as dextran of curdlan (giUCan). If the heat irreversible coagulating glucan is heated to a temperature above the gelation critical temperature (for example, when it is a Caldonia polysaccharide, it is 8 (temperature above TC), that is, gelling' and the gel Even if it is heated again, it cannot be dissolved. Further, the pulp can be used in combination with the above-mentioned binder as a sheet forming material. The flavor generating agent contained in the flavor generating sheet portion 13 includes: tobacco leaf extract, natural vegetable flavor (eg licorice, st John's bread, plum extract, peach extract, etc.), acids (eg malic acid, tartaric acid, citric acid, etc.), sugars (eg · glucose, fructose, isomerization) Hydrophilic aroma generators such as sugar, etc., salt test (eg, citric acid test, etc.); menthol 'cocoa subclass (powder, extract, etc.), esters (eg, isoamyl acetate, 1 inalyl acetate, isoamyl propionate, butyrate butyrate, natural essential oils (plant examples such as: vanilla extract, spearmint, peppermint, Chinese meat) (Cinnamomum cassia), jasmine, etc.; examples of animal species such as: musk, bot, civet 8 321926 201043157 (civet), beaver incense, etc., monomeric spices (eg: anethole, A hydrophobic aroma generating agent such as limonene, linalool, eugeol, etc. These flavoring agents may be used singly or in combination of two or more. The concentration in the portion may be a concentration that satisfies the taste of the user sufficiently by transmitting the taste and smell when the flavor generating material is heated, and the concentration may be arbitrarily adjusted. Further specifically, the flavor of the flavor generating agent at the end The amount of 0 in the produced material is present in a ratio of a very small amount to 20% by weight, preferably in a ratio of 5 to 1% by weight. Further, the flavor generating agent may use cut tobacco or powder. The cut tobacco or powder may be in the flavor generating sheet portion. The amount of the aroma generating composition preferably contains an aerosol generating substance which generates an aerosol by heating. The aerosol generating substance can be used, for example: Polyols such as oil, propylene glycol, triethylene glycol, tetraethylene glycol; decanoic acid fatty acid esters such as methyl stearate, dimethyl dodecate or didecyltetradecanoate. Aerosol production The substance may be used in an amount of from 1 to 8 % by weight in the aroma-generating sheet portion. 薄片 The sheet for non-combustible smoking article of the present invention may be produced by the method comprising the following steps: (i) separately modulating a carbonaceous heat source a slurry of the composition (a) and a slurry (b) of the aroma-generating composition; (ii) a step of adjoining and casting the slurry (a) and (b) on the support; and (iii) by The mash (a) and (b) are dried, and the carbonaceous heat source sheet portion and the flavor-generating sheet portion are integrated in a state of being adjacent to each other. 321926 9 201043157 In the step (i), the carbonaceous heat source composition slurry and the flavor generating composition slurry are prepared by adding water to the carbonaceous heat source composition and the flavor generating composition, respectively. In the step (ii), the slurry of the carbonaceous heat source composition and the slurry of the flavor generating composition are adjacent to each other and cast on the support. For the support, for example, a metal plate can be used. Alternatively, the above-mentioned lining material may be used as a support, and the carbonaceous heat source composition slurry (a) may be adjacent to and stagnate with the flavor generating composition slurry (b). When casting on a metal plate, a sheet for non-combustible smoking articles containing no lining material can be produced, and when cast on a lining material, a sheet for non-combustible smoking articles containing a lining material can be produced. In the step (iii), the slurry cast in the step (ii) is dried. Drying can be carried out at a temperature of from 60 to 170 °C. As shown in Fig. 2, the non-combustion type smoking article 2 of the present invention can be produced by folding the non-combustion type smoking article sheet 10 and storing it in the cylindrical body 21. Fig. 3 is a view showing an example of a storage type in which the sheet for non-combustion type smoking articles is housed in the cylindrical body 21. In Fig. 3, one sheet 1〇 is folded and stored in the cylindrical body 21, and an air flow path 1〇1 extending from the heat source portion of the tip end toward the fragrance generating portion at the rear end is formed. The non-combustion type smoking article 20 of the present invention can be manufactured by folding the non-combustion type smoking article sheet 10 and storing it in the cylindrical body 21 as described above, which is a very simple step compared with the conventional method, for example, It can be expected to be manufactured by an automatic control machine (Robot). The cylindrical body 21 accommodating the sheet 1 of the non-combustion type smoking article of the present invention may be, for example, a general cigarette paper roll or a reconstituted tobacco sheet (recycled tobacco sheet by calendering method, poly 321926 10 201043157 liquid method, paper making method or Non-woven recycled tobacco sheets, etc.), high-weight (basis weight) roll paper (basis weight 5〇g/m2 or more); aluminum sheet, laminated aluminum paper, etc. The cylindrical body 21 may be defined to include a front end portion at the ignition end, a base end portion including a base end to which a filter to be described later is connected, and an intermediate portion between the front end portion and the base end portion. After being folded, it is housed in a sheet of a cylindrical body, and the carbonaceous heat source sheet portion is disposed in the front end portion of the cylindrical body. Further, the non-combustion type smoking article 20 of the present invention may have a filter 22 for use in a general cigarette at the end opposite to the heat source side. The filter 22 is composed of a filter material (e.g., a cellulose acetate fiber bundle) used in a general cigarette, and its outer periphery is wound by a roll paper (not shown). The cylindrical body 21 and the filter 22 which accommodate the non-combustion type smoking article sheet 1 of the present invention are connected, for example, by a roll paper covering the outer circumference JH» body. A typical cigarette paper can be used for the roll paper. Further, the filter 22 is the same as a general cigarette and can be attached to the smoking article body by tipping paper. The carbonaceous heat source sheet portion 12 of the non-combustion type smoking article sheet 10 of the present invention can be ignited by a lighter in a short time (for example, 2 seconds) in the folded state as in the case of a general cigarette. After the ignition, the smoking article is sucked by the suction port end (filter 22), the air is sucked and passed through the air flow path formed by the sheet accommodated in the cylindrical body 21, and the carbonaceous heat source sheet is used. Part 12 is heated by heat. The heated air is heated to generate a fragrance when the sheet portion 13 is produced by the fragrance. The resulting aroma is tasted by the smoker through the filter 22. The non-combustible smoking article 2, which is composed of the non-combustion-type smoking article sheet 10 of the present invention, is 321926 11 201043157, and the first to second suctions to the last suction can exhibit almost a fixed fragrance. Further, the non-combustion type smoking article 20 may have an opening for taking in air at the time of suction in order to dilute the suction component (e.g., carbon dioxide). [Examples] Next, the present invention will be described based on examples, but the present invention is not limited by the examples. In Example 1 and Comparative Examples 1 to 2, a carbonaceous heat source mixture composed of 30% by weight of carbon particles, 455% by weight of calcium carbonate, 15% by weight of glycerin, and 10% by weight of ammonium alginate (adhesive) was mixed by a mixer, respectively. A mixture was produced with a fragrance consisting of 58% by weight of tobacco powder, 3% by weight of pulp, 5% by weight of glycerin, and 7% by weight of decyl hydroxyethylcellulose (adhesive). The amounts of water required for the slurry formation are added to each of the mixtures, and a slurry of the mixture of the carbonaceous heat source mixture and the flavor generating mixture is separately prepared. The two types of slurry were placed adjacent to each other and cast to a thickness of 015 mm on the metal plate, and then dried for about 1 hour in a thermostat set at 8 (Tc). Thus, the carbonaceous heat source sheet portion was adjacent to the flavor-generating sheet. An integrated sheet for smoking articles. The carbonaceous heat source sheet is cut into a width (refer to the i-th sheet) of 1 mm and a length of 9 mm, and the portion of the flavor-generating sheet is cut into width (see Figure 1). The W2) is 31 mm and the length is 90 mm. Fig. 4 is a commercially available non-combustible smoking article having a solid molded body (cylinder) extruded from a carbonaceous material as a heating source (trade name · AIRS A schematic cross-sectional view of 30. The non-combustion type smoking article 3 has a heating source 43 formed of a solid body 12 321926 201043157 shaped body 341 which is coated with a paper sheet 342 and extruded from a carbonaceous material. The gas source 32 is provided by the heat source μ. The gas mist generating unit 32 is composed of an aerosol generating material 322 containing glycerin contained in the incombustible round body +. The aerosol generating unit 32 is provided next to the aerosol generating unit 32. There is a fragrance generating portion 36. The fragrance is generated = 3 6 It is composed of a tobacco-containing aroma-generating material 362 housed in the non-combustible cylindrical body 36. At the base end of the flavor generating portion %, the fiber-coated cellulose acetate fiber bundle is attached to the paper sheet 382. The filter member ◎ 381 is configured as a filter 胄 38. The base end portion of the aerosol generating portion 32, the flavor generating portion 36, and the filter portion 38 are covered with the outer peripheral surface via the roll paper 4, and the paper 40 is penetrated. The paper sheet 382 is provided with an opening 〇p up to the filter member. The heat source 34 and the aerosol generating portion 32 are taken out from the non-combustion type smoking article 3 shown in Fig. 4, and the carbonaceous heat source sheet portion is opposed to the above. The sheet which is integrated with the flavor-generating sheet is folded and inserted as shown in Fig. 3 to produce the smoking article of the present invention (Example 〇. Further, the same composition as the carbonaceous heat source mixture used in Example 1 is used. The mixture is extruded into a solid cylindrical shape, and a groove which is an axial direction of the air flow path is provided in the outer peripheral surface to form a heat source. The heat source 34 of the non-combustion type smoking article of FIG. 4 is replaced by the heat source. Making Comparative Example 1 The smoking article of Comparative Example 2 was as described above, and the commercially available non-combustible smoking article (trade name: AIRS) shown in Fig. 4 was used. The smoking article of Example 1 prepared above was compared with the smoking article. The smoking articles of Examples 1 and 2 were smoked under the conditions of Passive Smoking in Canada (smoking capacity 55 mL/2 seconds; smoking interval 30 seconds; vent block 13 321926 201043157 100%). The smoking article of Comparative Example 1 and the smoking article of Comparative Example 2 were heated by an electric lighter for 30 seconds in accordance with the Japan Tobacco Association (TI0J) method, and the smoking article sample of the first embodiment was generally The cigarettes are the same, and you can catch the fire in 2 seconds. Further, the smoking article samples of the present invention and the smoking articles of Comparative Examples 1 and 2 were respectively sucked 7 times by an automatic smoking machine. The amount of total particulate matter (TPM) was determined by collecting the smoke per suction. The results are shown in Table 1 below. [Table 1] Number of puffs (times) TPM amount per breath (ms) Example 1 Comparative Example 1 Comparative Example 2 1 1.48 0. 72 0. 22 2 2. 14 1. 38 2.20 3 2. 12 1.40 6. 11 4 2. 07 3. 13 8. 34 5 1. 69 7. 17 12.73 6 1. 24 9. 15 5. 95 7 — 6. 30 4. 80 The results shown in Table 1 can be confirmed. In the smoking article of Comparative Example 1 using a heating source composed of an extruded product, the smoking article of the present invention can improve the amount of TPM in the initial stage of smoking (up to the third suction). In particular, in the smoking articles of Comparative Examples 1 and 2 using the heat source composed of the extruded products, the amount of TPM was significantly increased in the middle suction (near the fifth suction to the sixth suction). Increase to display a profile with a high maximum value. With respect to the 321926 14 201043157 ^, as the smoking article of the first embodiment of the smoking article of the present month, it can be seen that the amount of change in the amount of TPM per suction is small, and the maximum and minimum amount of TPM per suction is small. The step of the value is reduced, and the average taste is almost fixed. Further, compared with the conventional smoking article of Comparative Example 2, it was confirmed that the smoking article of the present invention of Example 1 has improved the amount of TMp at the initial stage of smoking. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a perspective view schematically showing a non-combustion type smoking article sheet according to an aspect of the present invention.帛 2 ® 余略 represents a perspective view of the case of the non-professional Wei smoke article. Fig. 3 is a cross-sectional view showing a cross section of the non-combustion type smoking article shown in Fig. 2 cut in a direction orthogonal to the long sleeve direction. Fig. 4 is a cross-sectional view showing a cross section of a commercially available non-combustible smoking article (manufactured by Sakamoto Tobacco Co., Ltd., trade name: AIRS) cut in the longitudinal direction. 〇【Main component symbol description】 10 Non-combustion type smoking article thin [Piece 11 lining 11a lining part 1 lib lining part 2 12 carbonaceous heat source sheet portion 13 scent generating sheet portion 20 non-combustion Type smoking article 21 Cylindrical body 22 Tube 30 Non-combustion type smoking article 32 Aerosol generating unit 34 Heating source 36 Fragrance generating unit 38 Tube part 40 Rolling paper 321926 15 201043157 101 Air flow path 321 Incombustible cylinder 322 Aerosol Material 341 Solid molded body 342 Paper sheet 361 Non-combustible cylinder 362 Fragrance-generating material 381 Filter member 382 Paper W1 Carbonaceous heat source sheet portion width W2 Fragrance-producing sheet portion width OP opening 16 321926