TW201041539A - Hair dyeing method - Google Patents

Abstract

Disclosed is a hair dyeing method wherein a hair dye composition having a first agent including an alkaline agent and a second agent including a oxidizing agent, wherein at least one of the first agent and second agent includes a surfactant, impregnates a structural body including a flexible porous material with an apparent density of 15 - 70 kg/m3 and a hardness of 50 - 250 N. Froth is formed by performing an operation that deforms the flexible porous material by means of the application and release of outside force thereupon, and the hair dye composition in froth form is applied to hair, allowed to sit for 3 - 60 minutes, and afterwards washed off.

Description

201041539 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a method of dyeing hair. [Prior Art] The combination of a liquid or milky hair dye has been widely used to prevent the hair from being dyed by the hair to prevent dripping and will be right to -K 〃 The composition is applied to the hair, and a special comb or brush Ο compound is applied to the hair to perform the pilling. The octagonal viscous hair dye group is used... It is difficult to apply the composition to the hair, especially in the root of the hair or the hindbrain. It is necessary to master the partition and control... In this case, it is known that: - the technique - the so-called washing of the blistering Head type dyeing Φ .-fe ^ . 彳 - difficult to balance the south viscosity required to prevent dripping and the non-preferred method used to make blistering. It is proposed that there is a bubble-like blistering volume of km* 毛* hair agent and yin, #1 hair cosmetics. According to the hair makeup mirror, the π ^ 戍 brush is used, and there is no need to use partitioning and matching techniques. This implementation is supported by many users. This technology is fortunate that Φ i β, for example, must be used because of the need to use foaming test #遴Μ雄, i music agent mix, spray volume 3! ^ device and other complex structures ^ ^, so can not avoid the cost increase, and the day The Bifeng system that is sprayed out of the foaming container can be self-contained, and there is a limit to the degree of dance. Therefore, it is also a party-to-constrained restriction. In addition, when it is not 撂1, it becomes a and leaves all π# ~ Do not combine the dyeing agent in the foaming container & Wang. Μ吏Used, for the dyeing of the part, Ά σ knife white hair or for the remaining undyed part 147109.doc 201041539 In addition, Patent Document 2 proposes a system in which a hair dye composition is applied by a structure in which a hair dye composition is impregnated with a hair dye composition. According to the technical proposal, partial dyeing is carried out. Or it is easy to replenish the remaining undyed parts, but it is more complicated to dye all the hairs, which is not so good. [Prior Art Document] [Patent Document] [Patent Document 1] Japanese Patent Laid-Open No. 2〇〇4_339216 Bulletin [Patent Document 2] International Publication No. 2/8/44198 Manual [Invention The present invention provides a hair dyeing method which is carried out by: a second agent containing an alkali agent-containing agent and an oxidizing agent, and at least one of a second agent and a second agent A hair dye composition containing a surfactant, and s/ is further composed of a flexible porous material having an apparent density of 15 to 7 〇 kg/m 3 and a hardness of N, by performing flexibility on the porous Material: an operation of imparting an external force and deforming the external force to cause the hair dye group to foam. The foamed hair dye composition is applied to the hair for 3 to 6 minutes, and then rinsed. Further, the present invention provides a dyeing set comprising: a second hemp dyeing agent composition comprising an alkali agent-containing bismuth agent and an oxidizing agent; the agent 'and the first! At least one of the agent and the second agent contains an interface activity and a structure for foaming a mixture of the first agent and the second agent. The content of the table is 4717.doc 201041539 and the density is 15 to 7 Π / 3 . 7〇_, hardness 5〇, soft porous material [Embodiment] Color = a colorimetric method with excellent operability, simple and no chromatic aberration / corresponding to partial dyeing can also correspond to full-head dyeing Hair dyeing

〇 孔 =:!' The above problem can be solved if the hair dye composition is impregnated with a plurality of soft colors and blistering, and the hair is dyed in (4). In the present invention, the term "hair" refers to the hair which is grown on the head, and includes the concept of hair which has been cut from the head, such as a wig or a bundle of hair. Also, the right hair is the hair of a doll or any animal, but it is suitable for human hair. The hair dye composition in the present invention is a concept including both a dye-containing dye composition and a dye-free decolorant composition. The so-called hair dyeing method includes the concept of a hair bleaching method. The hair dye composition in the present invention means a two-part composition containing an alkali agent-containing second agent and a second agent containing an oxidizing agent, which are stored until immediately before use, in addition to the above! A multi-dose composition such as a three-part composition containing a third agent of an oxidizing aid, in addition to the second agent, and the term "total composition" 4 means the combination of the actual application of the mixture into the hair. The whole thing. In the present invention, the term "external force" means a force other than gravity unless otherwise specified. 147109.doc 201041539 [test] $ As the test substance contained in the (9) 1, for example, ammonia, ethanolamine or the like can be used, such as sodium hydroxide, potassium hydroxide or the like. Further, it is also possible to appropriately add hydrogen carbonate as a buffer d! Anthony, gasification, etc., such as money salt or carbonic acid slant, carbonic acid sulphate, etc. & Mixing of the first agent and the second agent in the hair dye composition used in the present invention = PH value (25C) It is preferably 8 to 12, more preferably 9 to u, and the θ system is used as the test agent, and the pH is adjusted to the above range. [Oxidant] As the oxidizing agent, for example, ???: hydrogen peroxide; persulfate such as potassium lysinate or sodium persulfate; perborate such as sodium perchlorate; percarbonate such as sodium sulphate; sodium sulphate Acid-discharging and other acid salts, etc. Among them, the self-deathing is the decolorization of the hair and the stability and effectiveness of the oxidant itself: the second is hydrogen peroxide, and it can also be combined with hydrogen peroxide. Another oxidizing agent such as the above-mentioned persulfate is used as the oxidizing aid. In this case, the composition having the oxidizing aid can be used as the third agent to prepare three agents. Among them, it is preferred to use chlorine peroxide in combination with a persulfate. The oxidizing agent may be used singly or in combination of two or more. The amount of the composition is preferably from 0.5 to 30% by mass, more preferably from 1 to 20% by mass. When only hydrogen peroxide is used as the oxidizing agent, the content of the second agent is higher than that of the product. Preferably, the better is 3 to 6 quality ® with a ratio of 1 to 9 to U straight. / && . ~, the composition of the peroxide in the ~, Li. One should be 'better than 2 to 5% by mass. Further, the decomposition of hydrogen peroxide, the second agent is the inhibition is the pH value of the 2 bad agents to be 2, preferably, better I47] 〇 9. (j〇c 201041539 in combination with hydrogen peroxide and persulfate In use, the amount of human peroxidation t is 0.5 to 10% by mass of the total composition, and the content of persulfate is 0.5 to 25% by mass of the total composition, and the total content of both is preferably the mass % of the buckle. • [Surfactant] * The first agent and the second agent are prepared by mixing air with a hair dye composition by a structure containing a flexible porous material, easily forming a foam, and stabilizing the foam. Either or both of them contain a surfactant. 0 As a surfactant, any of a cationic surfactant, a nonionic surfactant, an amphoteric surfactant, or an anionic surfactant can be used, but a nonionic interface The active agent, the amphoteric surfactant, and the anionic surfactant are preferred. As the cationic surfactant, a single long-chain alkyl quaternary ammonium salt is preferred, and specific examples thereof include decyltrimethyl chloride and chlorination. Lipid trimethyl record, chlorinated camellyl trimethyl Ammonium, chlorinated stearyl dimethyl sulphate, vaporized xylylene sulphate, etc. 〇 (4) sub-interface activator' can be exemplified by polyoxyalkylene ether, polyoxo sulphate scales, advanced Fatty acid recommended sweet and sour vinegar, polyglycerin fatty acid vinegar, higher fatty acid mono or diethanol amine, polyoxyethylene hardened cannabis oil, polyoxyethylene sorbitol liver fatty acid vinegar, polyoxyethylene sorbitol fatty acid vinegar, burnt sugar Alkyl amine oxide, alkyl decyl amine oxide, etc. A. As an amphoteric surfactant, it can be enumerated as (4) Lin, Μ-based beet test, brewed leeks, stone-based beet test, basal-based beet test, amine Continued beet test, etc. As an anionic surfactant, a thiophene acid salt, a burnt group or 147I09.doc 201041539 alkenyl ether sulfate, an alkyl or alkenyl sulfate, an olefin sulfonate, an alkanesulfonic acid a salt, a saturated or unsaturated fatty acid salt, a pyrenyl or alkenyl ether tartrate, an alpha sulphate fatty acid salt, a fluorenyl-mercapto amino acid, a mono- or diester-filled acid, a contiguous succinate, etc. As the alkyl ether sulfate, a polyoxyethylene alkyl ether sulfate can be cited as the anion Examples of the counter ion of the anionic group of the surfactant include alkali metal ions such as sodium ions and potassium ions; alkaline earth metal ions such as calcium ions and magnesium ions; ammonium ions; and carbon atoms having 2 or 3 carbon atoms; a cation of an alkanolamine (e.g., monoethanolamine, diethanolamine, triethanolamine, triisopropanolamine, etc.). The surfactant may be used in combination of two or more kinds, and the content in the total composition is preferably in mass%. In terms of the touch and the emulsification performance, it is preferably 2 to 3 % by mass, and more preferably 3 to 25% by mass. [Flexible porous material; | The so-called flexible porous material is only required to be opened inside. There are countless microporous, soft and deformable materials that can also be used to enhance the sponge of aquatic organisms. (4) Jin, as shown in the standard (4). 1:2400 soft foaming material Anyone. Examples of the soft material include a polyamine vinegar, a vinegar-based polyamine, a nylon, and the like. The so-called soft porous material JIS standard K7222.200S斛 n + main % 6 refers to the apparent density defined by .M05, the efficiency of self-material foaming and the death of the helmet t ς brake combination view And δ is 15~70 kg/m3 'better kg/m3, better a, , , J 疋18~60 j... §And the hardness of the so-called soft porous material, you buckle the c 4 ' The material is produced according to the definition of ° ° 2:2_ method and the efficiency of the foaming of the hair agent composition is 4 ° 4 50-250 147109.doc 201041539

N, preferably 70 to 200 N 'better is 8 〇 ~ i7 〇 N 〇 〇 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Preferably, it is 15 to 85 • / 25 coffee, and further preferably 20 to 80 / 25 mm 〇 • The structure containing a flexible porous material can have a flexible porous material Two or more kinds of flexible porous materials having different numbers of micropores, apparent density, and hardness may be used, and when two or more kinds of flexible porous 〇f materials are used, for example, they may be combined in a layered or mosaic form. More preferably, they are combined in layers. In the case where the number of micropores of the flexible porous material is as small as 5 to 35/25 mm, two or more kinds of flexible porous materials are used from the viewpoint of preventing the flow of the liquid hair dye composition. It is also preferable to form a structure by layering and layering. When the structure containing the flexible porous material has a layer of two or more layers, the first agent and/or the second agent of the composition may be embedded in the layer or between the layers. It is also preferable to use a woven fabric, a non-woven fabric or a net bag to construct a structure of a soft porous material. Examples of the woven fabric, the non-woven fabric, or the natural fiber, the semi-synthetic fiber, and the synthetic fiber include kapok, rayon, polyvinyl alcohol, polyester, polyethylene-polypropylene, nylon, and the like. The size of the square flexible porous material is as long as it can maintain the hair dye composition and is required to be put up/packed and 11 is used in one hand. The apparent volume is 20 to 500 mL, preferably 3 〇~ 45 blush, more preferably 5 〇 ~ fan mL. Here, the apparent volume refers to a microporous portion including a volume of a flexible porous material in a state where no external force is applied, and the volume is based on the apparent density and quality of the flexible porous material. .doc 201041539 Find the volume. Because the cloth, non-woven fabric or net is attached to the soft porous material, α 4,···························································· The body 'is also not sexual, == body and weaving, non-woven fabric or net and soft two::: The shape of the porous material structure can be geometrically amorphous, three-dimensional, self-made easy to square, Gu Shi μ madness loss, with long illusion or two two-rotation ellipsoid, cylinder, elliptical column is appropriate, such as semi-cylindrical, semi-elliptical = Γ 将该 将该 将该 将该 、 、 、 ,it is good. Further, the portion of the surface of the structure is used to receive the hair dye composition or to make the beans temporarily better. Shaped as a recess or a hole; a recess or a hole, a hemisphere, a cylinder, or the like. The shape 'for example, a rectangular parallelepiped and an oxidized dye intermediate: an oxidative dye suitable for the dyeing agent composition used in the present invention, a ' can be used as a conventional precursor and a coupling agent used in a usual dyeing agent. . Examples of the precursor include p-phenylenediamine, toluene 4 5 -diamine, 2-milo-p-phenylenediamine, p-aminophenylhydrazine, p-methylaminobenzoic acid, ortho-aminophenol, 2,4. - Diaminophenol, N-phenyl p-phenylenediamine, and the like. Further, examples of the coupling agent include m-phenylenediamine, 2,4-diaminophenoxyethanol, m-aminophenol, 2-f-based 5-aminophenol, and 2-methyl _ (2). -Hydroxyethylamino)phenol, resorcinol, naphthol, anthracene, 5•dihydroxynaphthalene, hydroquinone, and the like. The precursor and the coupling oxime may be used singly or in combination of two or more to I47I09.doc -10- 201041539, and the content thereof is preferably 001 to 10% by mass, more preferably 0.1 to 5% by mass, based on the total composition. . [Direct dye] ^ On the other hand, as the direct dye, a known acid dye, a disperse dye, a reactive dye, or the like which can be used in the dyeing agent can be used. Examples of the acid dye include blue hand, purple 4 inch, black 4 inch 1 , orange 2 inch 5, red 22 gamma, red 1 〇 6, yellow 0, acid orange 3, and the like. Examples of the basic dye include basic blue 99, green brown 16, green brown 17, green red, and yellow yellow. Examples of the direct dye other than the acid dye and the basic dye include 2 nitro-p-phenylene diamine, 2-amino-6-gas-4-nitrophenol, and 3-nitro-p-hydroxyethylamino group. Streptophenol, 4_nitro-o-phenylenediamine, 4-amino--3-nitrophenol, 4-hydroxypropylamino-3-nitrophenol, hydrazine, hydrazine-bis (2-hydroxyethyl) Base) _ 2 nitro _ to stupid amine, disperse violet 1, disperse blue 1, disperse black 9, HC blue 2, HC dial 1, HC red 1, HC red 3, HC yellow 2, HC yellow 4, HC yellow 5 ❹ and so on. The direct dyes such as 5H may be used singly or in combination of two or more, and further, the π-disc is included in the total amount of the composition containing the first agent and the second agent. ) is better, and better is 〇.〇1~4% by mass. Further, it is also preferable to use the oxidative dyeing material together with the direct dye in the total amount of the oxidizing dye and the direct dye at this time to be 〇〇5 to 1% by mass based on the total amount of the composition of the first agent and the second agent. , better is 0. Bu 8 mass%. [After-grade alcohol] The hair dye composition used in the present invention is improved in 147109.doc 201041539 in a structure containing a flexible porous leaf, and is improved in 染==, And suppressing the stress during the period of stressing the hair dye composition used in the present invention, and the second agent is used for the purpose of improving the storage stability of the skin and the scalp. - The above contains a higher alcohol. As the high-grade alcohol, it is preferred to have a burning group or a rare base having a carbon number of 1 〇 to 3 Å, preferably 12 to 24, more == to 22, wherein the thiol group and the second (four) group are preferred. It is appropriate. For example, nutmeg, _, stearin, arachidyl alcohol, behenyl alcohol, oleyl alcohol, etc. are mentioned. The same type of alcohol may be used in combination of two or more. The content of the higher alcohol in the mixture of the first agent and the second agent is easily maintained in a structure containing a flexible porous material, foaming property, fine and soft foam, and suppression of the standing period. In terms of drip, to. Preferably, the mass % is preferably 0·1 to 0·8 mass%, and further preferably 0.2 to 〇7 mass|%, 4 si ./贞®/°, and further preferably. ~〇.6 quality%. Further, in the case where the higher alcohol is contained in the first agent, the content is preferably 0.01 to 2% by mass, more preferably 5% by mass to 5% by mass, and further preferably 〇. 2 to 1 by mass. Preferably, in the third of the Jth when the higher alcohol is contained in the second agent, it is preferably from 0.01 to 2% by mass, preferably from 15 to 15% by mass, and further preferably from 0.5 to 1% by mass. [Non-volatile hydrophilic solvent] In the hair dye composition used in the present invention, water and/or an organic solvent is used as a medium. As the organic solvent, a nonvolatile hydrophilic solvent can be used. Therefore, in the period in which the hair dye composition used in the present invention is applied after the hair is placed, the stimulation of the oxidation d can be alleviated by the tomb 147109.doc •12·201041539 in the moisture self-dyeing hair composition. Stimulation of the scalp caused by contraction of sexual components. The non-volatile hydrophilic solvent is preferably a polyhydric alcohol or a lower-order (non-defoaming effect such as a carbon number succinyl ether). The polyhydric alcohol is preferably a carbon number of 2 to 6, for example, Examples thereof include glycerol, L3-butanediol, ethylene glycol, and diol. Examples of the lower alkyl group, diglycerin, propylene glycol, dipropylene glycol, isoprene glycol, and sorbitan ether of the polyol include the above. Polyol

A lower alkyl ether or a poly-lower alkyl ether (for example, a di-lower alkyl ether). Among them, monomethyl mystery or monoethyl ether of 7 liters of alcohol is preferable, and specific examples thereof include ethylene glycol monoethylene glycol monoethyl ether, diethylene glycol monomethyl ether, and diethylene glycol monoethyl ether. These may also be used in combination of two or more types. The content of the non-volatile hydrophilic solvent in the total composition of the hair dye composition is preferably from 0 to 01% by mass in terms of reducing the effect of scalp stimulation and also improving the quality of the foam when the liquid temperature is low. More preferably, the mass % is further improved by 0.2 to 2 mass%. [pH adjuster] In the hair dye composition used in the present invention, in addition to the above-mentioned alkali agent, the following substances can be used as a regulator: from the viewpoint of storage stability of the composition: inorganic acid such as hydrochloric acid or phosphoric acid Organic acids such as citric acid, glycolic acid, and lactic acid, hydrochlorides such as ammonium sulfate and monoethanolamine hydrochloride, phosphates such as potassium dihydrogen phosphate and disodium hydrogen phosphate. [Other Components] In the hair dye composition used in the present invention, in addition to the above components, other components which are usually used as a cosmetic raw material may be added. As a blending purpose of such a component, it may be mentioned that impregnation promotion, beading, 147109.doc -13-201041539 anticorrosion, metal capping, stabilization, oxidation resistance, ultraviolet absorption, moisturizing, product coloring, aroma, etc., more specifically Examples thereof include animal and vegetable fats and oils, higher fatty acids, preservatives, chelating agents, proteins, protein hydrolyzates, amino acids, plant extracts, ultraviolet absorbers, vitamins, pigments, and perfumes. [Viscosity] The viscosity (25C) of the first agent is preferably 1 to 1, 2 〇〇 mPa.s, more preferably 3 to 1,000 mPa.s, and further preferably 5 to 9 Å mPa.s. The viscosity of the second agent (25. 〇 is preferably 1 to 300 mPa.s, more preferably 3 to 2 〇〇mpa s, and further preferably 5 to 1 〇 0 mPa.s. The first dose and the second The viscosity of the mixture of the agents (25. 〇 is 1 to 1, 〇〇〇mPa.s, preferably 3 to 800 mPa.s, more preferably 5 to 5 〇〇 mPa.s, and further preferably 10 to 250 mpa.s. Further, the value of the viscosity is obtained by using a B-type rotational viscometer (model τν_ι〇) manufactured by Tokyo Keiki Co., Ltd. to rotate the rotor by 1 minute. The measurement is performed in order, and the measurement is completed at the time when the measurement is possible without exceeding the scale. The measurement of the rotation speed after the non-transmission is small. By setting the viscosity (4) of the mixed solution to the above range, it is easy to maintain the content. In the structure of the flexible porous material, it is not easy to be in the period of the structure until the foaming, and the foaming efficiency is good. Further, it can be easily applied to the hair and the hair when formed into a bubble shape. The method has the advantages of molybdenum setting/package/end affinity, and the hair dye composition which is not easy to produce dripping after application to the hair. In the above-mentioned range, it is sufficient to add a water-soluble substance such as ethanol, or a content type. The content of _ 彡 类, higher alcohol or the like [hair dyeing method j 147109.doc -14 - 201041539 application before hair combing hair - / "The combination of hair dyes is π 炎 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 Partition operation using π-pan, it is better not to perform partitioning = It is easy to apply the toner composition to the head operation later. h冉····························· In view of the fact that it can be dyed and dyed, and it is better to obtain a sufficient dyeing effect, it is better that P will not be used until the finishing of the dyeing process (4). The liquid is not dilute and prevents dripping, and obtains sufficient dyeing effect. 2L' is better for dry hair. Before the dyeing treatment, the hair is shampooed before the dyeing treatment. Drying: The so-called dry hair means that at least it will be washed And the water adhered to the main liquid is removed until it is not dripped in a natural state, and the state of being dried by a towel or dried by a hair dryer is and in the hair dyeing method of the present invention. The first sample containing the test agent is mixed with the second agent containing the oxidizing agent, and the mixture is impregnated into the structure containing the flexible porous material. The external force is applied to the flexible porous material and the external force is released to deform the mixture. Operation to foam the hair dye composition. Here, "deformation" means the process of changing the shape by the process of imparting and releasing external force, and whether it is restored to the original when the external force is completely released. The shape is irrelevant. x 'For the release of the external force, it means that the external force 147l09.doc -15- 201041539 is completely released, the partial release is either the general agent and the second agent is not mixed, and the person can also make the first w such „ and immersed in the structure Yin, with the bubble. At this time, the order of _# ' 仃 5 5 与 与 与 与 与 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造 构造It is also possible to make the first agent and the second agent alternate for a long time and # multiple times. Yu Yuzhu also has a sub-combination with j 乂$, which is the same as the first dose of 盥 弟 3 3 3 , , , , , , , , , , , , , , , , , , , , 禾 禾 禾 禾 禾 禾 禾 3 3 3 3 3 3 3 In the case where the first agent and the second agent are mixed into the mixture of the first agent and the second agent, the structure can also be foamed in the containing body. Containing liquid such as water. Further, in the dyeing agent composition used in the present invention, the active agent, the higher alcohol, and the non-volatile hydrophilicity may be used in the dyeing agent composition used in the present invention. Solvents, etc. The total composition of the composition of the composition includes the concept of impregnation in the structure. When the structure is impregnated with the sputum of the hair dye group, the external body is deformed by applying an external force to the structure, and then the hair dye composition 3 is immersed while releasing the external force. It is preferred to construct a hair dye composition in each body of the body. The foaming system repeats an operation of applying an external force to the structure to deform it. The method of applying the external force may be, for example, clamping, pressing, twisting, rubbing the structure, or the like with a specific prop, or by grasping, pressing, turning, or rubbing by hand. In the case of using a hand, it is preferable to use both hands or use only one hand to grasp the hair dye composition simply and efficiently by one hand. Regarding the number of times the structure is deformed, each time the structure is impregnated (four) at least once is preferably '2 to 5 G times, more preferably 147,109.doc •16·201041539 & and good 疋3 to 25 Times. Repeating the frequency of making the deformation of the structure is every second and second times, and the second time is better than 2 to 3 times. What is better is that the operation of deforming the structure can be continuous. The rows may also be separated by an interval. When the interval is n, the interval is within P, preferably 30, within, and more preferably within 10 seconds. In addition, by squeezing the s-shaped structure by hand, the ugly main body and the object 盏 夺 , , 以 以 以 以 以 以 以 以 以 以 以 手上 手上 手上 ❹ ❹ ❹ ❹ ❹ ❹ ❹ ❹ ❹ ❹ ❹ ❹ ❹ ❹ ❹ ❹ ❹ It is appropriate. ^ ^ When the /pack-like hair dye composition is applied to a 1 s, the blister hair dye composition & l, + ding ^ ^ can be applied from the structure by hand, or it can be used If it is placed on the brush guide and applied, it can also be applied directly to the hair and directly applied to the foamed hair dye composition by directly contacting the hair. When the hair dye composition is applied to the hair, as long as the foamy hair dye can be attached, rubbed, attached to the hair, or the like, the foamed hair dye composition can be moved to the hair, JJ rain Ren Si method. Further, in the process of disposing the foam, there is also a case where the state of the bubble is changed by the application of an external force by the s-like hair dye composition, and the shape of the bubble is further immersed, but the change of the shape I of the bubble at this stage does not include In the "re-foaming" described later. : When it is applied by hand, it is made of a synthetic hair made of a dyeing agent, and the & substance is impervious, and is made of synthetic rubber or natural rubber. Gloves are suitable. If the blister-like enamel-like wood-like hair composition is applied to the hair at the same time as the size of the lemon, it is preferably taken in the hands of the hands and is easily applied to the hair by hand. Thus, one hand is used to perform the operation of foaming the hair dye composition on the structure, and the other hand is used to take the bubbles. Following 147109.doc -17· 201041539 :, the foamy hair dye composition which is temporarily taken to the hand is applied to the hair 2 = the operation of foaming on the structure, and repeated application to the hair. This series is very easy to operate and can be changed in a short time to reduce the hand holding. One or both of the right 5 ho gloves are partially or wholly connected to one or a plurality of the above-mentioned structures, or are subsequently formed into a body, which is preferable, and the range of application of the bubble may be the whole hair. It can also be only a specific part. That is, the area of the hair to be dyed is the whole hair or only a specific part: Regarding the application operation, the amount of the hair dye composition which can be used for foaming can be applied in several times. In the case of multiple applications, it can be applied to the entire hair area to be dyed, and the different parts of the poem area can be repeated and applied to the whole area of the hair-splitting area. It is also possible to re-foam between the application and the next application. According to the hair dyeing method of the present invention, the foaming hair dye composition can be applied in a short time because the partitioning operation which is widely used in the application of the conventional hair dye composition is not required. Therefore, the application of the foamed hair portion can be started from the hairline as it is from the previous liquid or milky two-part hair dye composition. As long as the application is started from the part that you want to start, it is advisable to start from the growth margin of the hair or the part of the distribution line. In order to apply the blister hair dye composition applied to the hair to the root of the hair 4, the bubble weight to be disappeared is a stable bubble, the wood color boundary in the case of partial dyeing is blurred, etc., so as to be applied to the hair. It is preferred that the blister hair dye composition be foamed again on the hair. It can be placed again after foaming after application, and can be repeatedly foamed and placed again. Further, the application of the blister dyeing 147l09.doc -18- 201041539 hair styling composition, re-foaming, and placing may be repeated. When foaming again, gas can be injected, or a device such as a vibrating machine or a brush can be used, or a finger can be used for shampooing, and it is better to use a finger for shampooing - the action of _ The reason is that the two-part hair dye composition can be applied throughout the roots of the hair. The speed of re-foaming by a vibrating machine or a brush or by using a finger for shuffling is preferably controlled by a bubble that does not scatter.此处 Here, the period of re-foaming may be after the bubble has completely disappeared, or during the process of bubble loss, or before the bubble of the application changes. Alternatively, it can be applied within the entire range of the bubble to be applied, or it can be used during the application process. The foaming can be repeated once in a row or intermittently. Here, if the vibrating machine or the brush for re-foaming or the finger is continuously in contact with one of the heads, or if it is again contacted within 1 second even if it is temporarily left, the foaming is continued again. The key is to observe the applied portion and at least the liquid is properly foamed before the application of the bubble. By foaming the bubble that is about to disappear, the drip can be prevented regardless of the nature of the bubble. Further, by the composition of the hair dye composition or the structure, even if the properties of the foam are different, it is possible to change into a foam suitable for hair dyeing by re-foaming. It is also conceivable that if the composition of the hair dye composition or the structure is specific, the drip can be prevented and the foam suitable for hair dyeing can be easily maintained, but at this time, it is preferably a bubble. After the application of the hair dye composition, the foaming is performed at least once again as early as possible. By blistering again in an earlier period, the chromatic aberration of the range to be applied can be prevented. As a period of time, the blister-like hair dye composition on the hair of 147109.doc -19- 201041539 is applied within 5 minutes after the application, the cup is smashed with two η and two, and more preferably within 3 minutes, and thus better It is within 1 minute. After the final blister hair dye composition is applied, it is allowed to stand for 3 to 6 minutes, preferably 5 to 3 minutes, and the hair is washed and dried. In the present invention, the final shelf time after application of the blister hair dye composition refers to the total amount required after the application of all the blister hair dye compositions in the whole head or the desired portion until the rinsing Time is a concept that includes the time required for re-foaming in addition to the time of simple placement. Washing can be simple washing, shampooing, washing with shampoo after washing. After shampooing, it is also better to treat the hair cosmetic after shampooing such as conditioner. [Examples] Example 1 Using a hair dye and a structure shown below, the Japanese male (white hair content rate: about 5% of the anterior head, about 60% of the right head, and about 40% of the left head, The right head of the posterior head is about 1%) (the average hair length is 4 for dyeing.

*Dyeing agent: The first agent A and the second agent A described in Table 1 The viscosity of the total composition of the first agent and the second agent mixed at a mass ratio of 1:1 is 15 mPa·s, pH The value is 1 〇. 〇• Structure A: A flexible porous material is made into a rectangular parallelepiped of 7×5×4 cm, and a hemispherical concave portion having a diameter of 2 cm is provided at a central portion of one plane of 7×5 Cm. The flexible porous material was a foamed E-pass product EGT-C manufactured by Inoac Corporation. The flexible porous material had an apparent density of 22 kg/m3 and a hardness of 115 N. 147109.doc -20- 201041539 Mix 5 g of the first agent A and 5 g of the second agent A until the hook is applied, and the entire mixture is impregnated into the structure A once, and the structure is placed in 15 seconds. A is pinched 20 times for foaming. The structure a is applied to the right side of the head, and the foamed hair composition is applied to the hair. After the application, the finger was again foamed by performing an action such as washing the finger back and forth between the right front head and the right rear head within 1 second, and left for 3 minutes. Again, it was again foamed by performing an action such as shampooing the finger back and forth for 15 times in the second shovel head to the right dorsum head for 15 minutes. After the hair dye composition was washed with water, the whole head was washed twice with shampoo. After drying, confirm that there is no white hair on the right side of the head and that there is no unnatural discontinuity with the anterior or posterior head. 'Send and dye the left head. 5 g of the first agent a and the second JA of 5 $ are mixed until uniform, and the entire mixture is impregnated into the structure A once, and the structure and A are grasped twice in 15 seconds. Foaming. The k-body A is attached to the left ear, and the foamed hair dye composition is applied to the hairy hair to perform the same treatment as the above-mentioned right side hair dyeing. As a result, there is no difference between the right side head and the left side head σ卩. , can not confirm the white hair. Further, although the front head and the back are white, there is no unnatural discontinuity compared with the left and right heads. Example 2 The whole head (medium long hair, average hair length of about 15 cm) was applied to Japanese women (white hair content rate and total head length without deviation) using the following hair dyes and structures. Dyeing.

Hair dye. The first agent B described in Table 1 and the second agent B shown in Table 2 147109.doc 201041539 The first agent and the second agent are in mass ratio! :1 The total composition after mixing has a viscosity of 200 mPa·s and a pH of 1 〇 构造. Structure B: The flexible porous material is made into a rotating elliptical with a long axis of 8 cmx and a short axis of 5 cm. For the flexible porous material, SD for the Ever Light cleaning machine manufactured by BHdgest® was used. The flexible porous material has an apparent density of 28 kg/m3 and a hardness of 16 〇 n. 25 g of the first agent B and 25 g of the second agent B were placed in a 2 〇〇 mL 2 capped container, and mixed by shaking. About a quarter of the total composition to be mixed was contained in the structure B, and the structure B was kneaded in 20 seconds to cause foaming. The structure B is applied from the right head to the front head, and the foamed hair dye composition is applied to the hair. After the application, foaming was again performed by performing an operation such as shampooing the finger by looping 15 times in the vicinity of the application site for 10 seconds. Then, the remaining total composition is similarly impregnated into the structure B by about one-third of the amount, and the foaming is applied three times to the hair near the initial application site, and is re-started near the application site. Bubble operation".

Further, 25 g of the first agent b and 25 g of the second agent 3 were placed in the above-mentioned 2 mL of the lidded container, and the container was shaken and mixed. About a quarter of the total composition to be mixed was impregnated into the structure B, and the structure B was kneaded 20 times in 5 seconds to cause foaming, and the structure B was attached from the left head. To the head, a foamed hair dye composition is applied to the hair. After the application, the foaming was again performed by performing an operation such as shampooing the finger by rotating the finger 15 times in the vicinity of the application site in 1 second. Then, the remaining total composition is similarly impregnated into the structure B H7I09.doc -22- 201041539 by about one-third of each time, and three times of "foaming, applied to the hair near the first application site on the left side" , the operation of re-foaming near the application site". The application amount to the hair dye composition of the hair is 100 g in total. Finally, the foaming was again performed by performing an action such as shampooing by moving the finger 30 times in 20 seconds, and the foamed hair dye composition was applied to the entire head and left for 15 minutes. After the hair dye composition was washed with water, the whole head was washed twice with shampoo. After drying, no white hair was confirmed in the whole head. [Table 1]

(% by mass: all contents are effective) First dose A First dose B Aminophenol 0.20 0.20 Resorcinol 2.00 2.00 Meta-aminophenol 0.10 0.10 5-Amino o-cresol 0.10 0.10 Indole-2- 5-Diamine 2.20 2.20 Hydrochloric acid 2,4-diaminophenoxyethanol 0.10 0.10 Mercapto glucoside n 6.20 _ Tridecyl alcohol polyether-9+2 0.50 - Lauryl polyether-23^ 2.00 _ Nutmeg Alcohol, 4 0.20 - Sodium lauryl sulfate 2.70 4.00 Oleic acid 6 - 4.40 Ethanol 10.00 - Propylene glycol 4.00 _ Polyquaternium-6" 0.80 _ Polyquaternium-7$8 1.00 _ Polyquaternium 22+9 0.40 Ascorbic acid 0.40 _ EDTA-2Na (diamethylenediaminetetraacetate) 0.10 Sodium nitrite 0.50 0.10 147109.doc -23 - 201041539 Manufactured by Nalco Jap an Company, manufactured by Nalco Japan * 1 : Kao Manufacturing *2 : Made by Lion *3 : Kao Corporation Manufacturing *4 : Kao Corporation Manufacturing *5 : Kao Corporation Manufacturing *6 : Kao Corporation Manufacturing *7 : Nalco Japan Gong *8 : *9 :

Mydol 10 Leocol TD-90 Emulgen 123P Kalcol 4098 Emal 327 Lunac OA Merquat 100 Merquat 2200 Merquat 280 Sodium Chloride 3.00 0.80 Ammonia 0.84 - Ethanolamine - 2.98 Ammonium bicarbonate 2.50 - Purified water Residual amount Residual viscosity (mPa > s) / pH 20/9.0 850/10.2 [Table 2] (% by mass: all effective amounts) 2nd agent A 2nd agent B hydrogen peroxide 5.71 5.95 sodium hydroxide 0.029 0.029 sodium laureth sulfate n 0.60 0.60 cetyl alcohol 12 0.48 0.48 Myristyl” 0.28 0.28 Phosphoric acid M Appropriate amount of etidronate 0.08 0.08 decanoic acid via Kelin 0.04 0.04 Purified water remaining amount 147109.doc -24- 1 1 : Kaoman made Emal 327 *2 : Kao The company manufactures Kalcol 6870 201041539 *3 : Kao Co., Ltd. manufactures Kalcol 4098 *4 : Adjusts the pH to 3.5. Examples 3 to 6 Except that the structure used is replaced with the structures C to F, and Example 11 §] In the case of the sample, the right side of the Japanese male is dyed. • Structure C: The flexible porous material 1 is made into a rectangular parallelepiped of 7x5x2 cm, and a hemisphere with a radius of 1 cm is placed at the center of a plane of 5 cm. Concave Furthermore, the flexible porous material 2 is made into a rectangular parallelepiped of 7 x 5 x 2 cm, and is bonded to a rectangular parallelepiped made of the flexible porous material i in a plane of 7 x 5 cm. The flexible porous material 1 is made of Inoac Corporati〇n. Manufactured foamed ether EFF. The flexible porous material i has an apparent density of 21 kg/m3 and a hardness of 59 N. The flexible porous material 2 is made of foamed etherate manufactured by Inoac Corp. ECA. The flexible porous material 2 has an apparent density of 26 kg/m3 and a hardness of 130 N. The hair dye composition is impregnated on the side of the flexible porous material and foamed. The flexible porous material is made into a rectangular parallelepiped of 7χ5χ3, and is placed in the front end of Daniel's nylon stockings, and the insertion part is sealed by the industrial polystyrene thread #80. The flexible porous material is used by Bridgest〇ne. Made by the company

Ever Light SB. The flexible porous material has an apparent density of 28 kg/m3 and a hardness of 140 N. 147109.doc -25- 201041539 •Construction E: The flexible porous material is made into a rectangular parallelepiped of 7x14x1.5 cm and placed in a mesh bag for polyester tableware cleaning machine. #80 Seal the insertion port. The above flexible porous material used was Ever Light TD manufactured by Bridgestone. The flexible porous material has an apparent density of 20 kg/m3 and a hardness of 90 N. 构造•Structure F··The flexible porous material is made into a hemisphere having a radius of 4 cm, and is provided at the center of the flat portion by 3×2×1 cm. Rectangular recess. The flexible porous material was a foamed diethyl ether EC A manufactured by Inoac Corporation. The flexible porous material had an apparent density of 26 kg/m 3 and a hardness of 130 N. Example 7, Example 8, and Comparative Examples 1 to 3 The structure including the flexible porous material described in Table 3 was first. Immediately after impregnating 5 g of the first dose A, 5 g of the second dose A was foamed and applied to the right head hair (white hair content of about 10%) in the order described in Table 4. [Table 3] Structure G Structure Η Structure XI Structure Χ 2 Structure Χ 3 Softness Inoac Corporation Bridgestone Inoac Corporation Inoac Corporation Bridgestone Porous Materials Manufacturing Company Manufacturing Company Manufacturing Company Manufacturing Company Manufacturing Foamed Ethyl ERB Ever Light RY Foamed Ethene EFS Foamed Ether EZQ-S Ever Light DL Apparent Density 30 kg/m3 35 kg/m3 20 kg/m3 13 kg/m3 60 kg/m3 Hardness 100 N 170 Μ 20 N 60 N 45 N Shape J The above-mentioned flexible porous material, 7x5x4 cm rectangular parallelepiped 147109.doc -26- 201041539 [Table 4]

The foaming was carried out by pinching the structure 2 times in 12 seconds. —^ 造造Χ3 Although it is possible to restore the bribe by grasping the structure and farming, but the structure is difficult to reproduce, it is difficult to repeat the grasping and dancing. 3 Ο ο The structure is attached to the right head hair and the hair dye is combined. The object is applied to the hair, and re-foaming is performed by an operation such as shampooing in which the opening and closing of the finger is repeated 15 times in the vicinity of the application site for 10 seconds. After standing for 5 minutes, the hair was again foamed by repeating the operation of opening and closing the finger 15 times in the vicinity of the application site for 15 times. Further, it was allowed to stand for another 5 minutes, and was again foamed by an operation such as shampooing in which the opening and closing of the fingers were repeated 3 times in the vicinity of the application site for 2 minutes. After the hair dye composition was washed with water, the whole head was washed twice with shampoo. Get ample blistering and easy to apply to your hair. Foaming again on the hair without dripping the hair. Apply the body to the scales and apply the dye to the hair for 15 minutes. After the hair dye composition was washed with water, the entire head was washed twice with a hair rinse. Although a part of the foamed hair dye composition can be applied to the hair ', most of it is dripped from the structure and cannot be applied to the hair. White hair was not confirmed in the dyed portion, and the boundary with the non-stained portion was not clear and natural. The application of the hair dye composition is insufficient, and white hair is confirmed in the dyed portion. The boundaries with the non-stained parts are clear and unnatural. 147109.doc 27-

Claims (1)

201041539 VII 1. Patent application range: = dyeing method, which is carried out by the following methods: U containing the first and the oxidizing agent, and at least the second agent - Τ 3 with surfactant dyeing The hair styling composition '3 is immersed in a structure containing ± 碧 皆 * 岔 岔 为 为 为 为 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 15 硬度 硬度 硬度 四 四 四 四 四 四 四 四The material imparting force and the operation of dissipating the external force to deform the bristles, and the blistering hair dye composition is applied to the hair, and after being left for 3 to 60 minutes, the rinsing is performed. . 2. The hairy method of claim 1 wherein the amount of the surfactant in the total composition of the hair dye is from 1 to 50% by mass. 3. The method of claim 1 or 2, wherein the blistering hair dye composition is applied to one part of the hair or the whole part of the hair. dyeing. 4. The hair dyeing method according to any one of claims 1 to 3, wherein the structural system comprises one or more layers of a layer comprising a flexible porous material. 5. The hair dyeing method according to any one of claims 1 to 4, wherein after applying the blister hair dye composition to the hair, the hair dye composition is foamed again on the hair until it is washed until. 6. A dyeing set comprising: a hair dye composition comprising a first agent comprising an alkali agent and a second agent comprising an oxidizing agent, and at least one of the first agent and the second agent comprises an interface The active agent; and the structure 'S is used for foaming a mixture of the P agent and the second agent, and contains a flexible porous material having an apparent density of 15 to 70 kg/m 3 and a hardness of 50 to 250 N, which is 147109.doc 201041539 material. 147109.doc 201041539 IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbolic symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the best indication of the characteristics of the invention. Chemical formula: (none) 147109.doc -2-