201031731 六、發明說明： 【發明所屬之技術領域】 一本發明係一種非塗佈加工方式製得之透明隔熱節能型聚 氯乙烯膠布其製法，具有良好之紅外線及紫外光遮蔽效果進 而達到隔熱及防護的目的。該成品適合應用於建築物玻璃、汽 車窗戶、冷束儲藏展示櫃及有節能訴求等之產品。 【先前技術】 ❿ 鴻光產生絲絲社要有二，包減長介於400nm 〜700nm的可見光及波長範圍介於7〇〇nm〜18〇〇nm的紅外 光（屬於非可視光範圍），而一般應用在建築物玻璃、汽車窗 戶、冷束儲藏展示櫃及有省能訴求之產品，除了必須具備視覺 上透明的要求以外，還必須兼具阻隔紅外光所產生之熱能的功 效，所以必須選用具備光波長選擇性材料，才能有 〜麵nm的紅外光線，達到隔熱功效，並 〜700nm的可見光線透過，以保有視覺上透明的要求。另外， 太陽光中200nm〜40〇nm的紫外光範圍，依波長又可細分成201031731 VI. Description of the invention: [Technical field to which the invention pertains] The invention relates to a transparent heat-insulating and energy-saving polyvinyl chloride tape obtained by a non-coating processing method, which has good infrared and ultraviolet shielding effects and thus achieves separation The purpose of heat and protection. The finished product is suitable for use in building glass, automobile windows, cold beam storage display cabinets, and products with energy saving requirements. [Prior Art] 鸿 Hongguang produces silk wire, which has two kinds of visible light with a wavelength ranging from 400 nm to 700 nm and infrared light with a wavelength ranging from 7 〇〇 nm to 18 〇〇 nm (in the non-visible range). Generally used in building glass, automobile windows, cold-beam storage display cabinets and products with energy-saving requirements, in addition to the requirements of visual transparency, it must also have the effect of blocking the heat generated by infrared light, so it must be selected. With a wavelength-selective material, it is possible to have infrared light with a surface of nm, to achieve thermal insulation, and to transmit visible light of ~700 nm to maintain visually transparent requirements. In addition, the ultraviolet range of 200 nm to 40 〇 nm in sunlight can be subdivided into wavelengths according to the wavelength.
❹ UVA (310nm〜400nm)、UVB (285nm〜310nm)及 UVC (200nm〜285nm)三種波段，其中UVA、UVB會對人體造 成某種程度的傷害，因此在建築玻璃或汽車窗戶用材料中皆會 添加有機UV吸收劑，使該材料具備uv遮蔽的能力，進而 到保護人體的功能。 傳統的隔熱材，如：聚對苯二甲酸乙二脂(p〇|yethy|ene tere^phthhalate 簡稱 PET) ’ 聚碳酸脂(p〇|ycarbonate)，聚丙烯 酸脂或聚甲基丙烯酸脂(po丨yac「y丨ate 〇r p〇|ymethacry丨刪 ，環狀烯(cydico丨efin) ’聚苯乙烯(p〇丨ysty「ene)等，是在塑膠 基材上以乾式或濕式塗佈具有隔熱功能的隔熱材所構成。 ，往J以乾式塗佈加工製成的習知隔熱透明膠臈10如圖 所示係以真二濺鑛或蒸錢方式，將金屬或金屬氧化物等無 201031731 機材料12均勻附著在塑膠基材彳彳的上面而形成隔熱膜。 y以溼式塗佈加工製成的隔熱透明膠膜20，如圖2所示， 係將具隔熱功能的無機顆粒22均勻分散在合適的樹脂23及溶 媒中’經配製成黏度合宜的塗佈液後，再塗佈在塑膠基材21 的上面；經乾燥去除溶媒後，無機顆粒22及樹脂23就形成附 著在塑膠基材21上面的隔熱膜。 『乾式塗佈』或『溼式塗佈』的傳統製程，其共同特徵是： 須經由兩道程序。程序之（一）是先製成片材或薄膜來當 ，基材；程序（二）是利用線外（OfWIne)『乾式塗佈』或『溼 f塗佈』的方式施作於程序（一）所製成的基材表面，使其具 ^紅外線阻隔或紫外線遮蔽的功能。此塗佈法所衍生的問題 有： 濕式塗佈法加工’製程中溶劑揮發，污染空氣，影響 健康； 式塗佈法加卫’塗佈液製備所產生之廢溶織理的環保 ⑶=|佈’需增設設備包括額外之捲出、塗佈、麵、成捲、 而乾式塗佈需增言免濺錄機或蒸錢機，製程設備及加 工成本南，及 ’塗佈後還包括裁 切所增加之餘廢料。 【發明内容】❹ UVA (310nm~400nm), UVB (285nm~310nm) and UVC (200nm~285nm), UVA and UVB will cause some damage to the human body, so it will be used in architectural glass or automotive window materials. The organic UV absorber is added to give the material the ability to shield the uv and protect the body. Traditional insulation materials, such as: polyethylene terephthalate (p〇|yethy|ene tere^phthhalate for short) PET polycarbonate (p〇|ycarbonate), polyacrylate or polymethacrylate ( Po丨yac "y丨ate 〇rp〇|ymethacry丨, cydico丨efin" polystyrene (p〇丨ysty "ene", etc., is applied dry or wet on a plastic substrate The heat-insulating material with heat insulation function is formed. The conventional heat-insulating transparent plastic bottle 10 which is made by dry coating process is oxidized by metal or metal in the form of true splash or steam. No material 201031731 machine material 12 is evenly attached to the top of the plastic substrate to form a heat insulation film. y The heat-insulating transparent film 20 made by wet coating processing, as shown in Figure 2, will be separated The thermally functional inorganic particles 22 are uniformly dispersed in a suitable resin 23 and a solvent, and then coated on a suitable coating liquid, and then coated on the plastic substrate 21; after drying to remove the solvent, the inorganic particles 22 and The resin 23 forms a heat-insulating film attached to the upper surface of the plastic substrate 21. The transmission of "dry coating" or "wet coating" The common features of the process are: There are two procedures to be followed. The procedure (1) is to make a sheet or film first, and the substrate; the program (2) is to use the off-line (OfWIne) "dry coating" or " The wet-f coating method is applied to the surface of the substrate prepared by the procedure (1) to have the function of infrared blocking or ultraviolet shielding. The problems derived from the coating method are: wet coating processing 'The solvent evaporates during the process, pollutes the air and affects the health; the coating method adds the environmental protection of the waste-soluble texture produced by the coating liquid preparation (3)=|cloth's need to add equipment including additional roll-out, coating and surface , roll, and dry coating need to increase the sprinkler-free or steamer, process equipment and processing costs south, and 'after coating, including the increase of waste added by cutting.
，可塑劑、安定劑、 ⑷多-道塗佈製程’除了不利於成品良率外，塗 可塑劑混合改質攪拌均勻後再 丨、安定劑、滑劑及色料等進行 4 201031731 混合及膠化時發現所製成之PVC膠布的組 失及問題，而製造透明隔教膜。 熱聚種綱加工方恤之透明隔 白八目的提供一種其隔熱顆粒採内添加方式均 聚氯乙稀膠布。 ❹ :::;=:缺後失==勻產=聚氣乙鱗布 加工成本低廉，產速又快==明隔熱膜或膠布， 採内改以其無機隔熱顆粒 :，'良好_果紫以 卻濕==氣有=之優點:⑴省 蒸鍍之設舰資。⑵_、聽:^ n錄式濺鍍、 製程方式將具備隔熱及紫i線題。⑷採用非塗佈 乙烯膠布配方中，除了能保有料填加於聚氯 度、隔熱及紫外線遮蔽等效果外^膠布之透明性、低霧 本發明之财喊部份特徵析㈣問題。 其它尚包含：a_可塑劑b 之乳乙烯為主要原料’ 色料，其帽熱材先經助劑混^改^劑d.滑劑e.助劑及f. 本發明之製備方法為：先使人 ，熱顆粒及其它添加助劑 配方的可塑劑、無 膠布的壓延機或T-Die機或吹$ f質枓，利用傳統聚氯乙烯 氯乙稀透明膠布。這種隔騎機加卫’製得-種隔熱聚 熱^乙烯透明膠布，不僅保有聚氯 5 201031731 乙烯既有物性，更兼具透明性、低霧度及優異的紅外線及紫外 線遮蔽效果。 本發明直接使用聚氯乙婦膠布的傳統生產製程，可製得隔 熱聚風》乙稀透明膝布’除不必使用塗佈加工之外，更可省卻塗 佈製法的設備投資，亦可避免濕式塗佈製法的廢溶劑環保問 題。因此，本發明的製法具製程簡單、加工成本低廉、產速快 及環保的優點。 、, plasticizer, stabilizer, (4) multi-channel coating process 'In addition to the unfavorable yield of the finished product, the plasticizer is mixed and modified, stirred evenly, then sputum, stabilizer, slip agent and colorant are carried out 4 201031731 Mixing and glue During the chemical process, the problem of the group of the PVC tape produced was found to be a problem, and a transparent diaphragm film was produced. The transparent partition of the hot-collecting processing of the square shirt provides a kind of polyvinyl chloride adhesive tape for the heat-insulating granules. ❹ :::;=: Loss after missing == uniform production = gas-filled squama cloth processing cost is low, production speed is fast == Ming heat-insulating film or tape, mining is changed to its inorganic heat-insulating particles:, 'good _ fruit purple but wet = = gas has = the advantages: (1) provincial evaporation of the ship. (2) _, listen: ^ n recording sputter, process method will have insulation and purple i line questions. (4) In the formulation of non-coated vinyl tape, in addition to the effect of adding material to the degree of polychlorination, heat insulation and ultraviolet shielding, the transparency and low fog of the tape are analyzed. Others include: a_plasticizer b of milk ethylene as the main raw material 'color material, the cap hot material is first mixed with additives, agent d. slip agent e. auxiliary agent and f. The preparation method of the invention is: First, make a plasticizer with hot granules and other additives, a calender-free calender or T-Die machine or a p-type 枓, using a traditional polyvinyl chloride vinyl chloride transparent tape. This type of squadron is reinforced by a kind of heat-insulating heat-polymerized vinyl transparent tape, which not only retains polychlorinated 5 201031731. Ethylene has both physical properties, transparency, low haze and excellent infrared and ultraviolet shielding effects. The invention directly uses the traditional production process of the PVC cloth, and can obtain the heat-insulated and wind-enhanced "Ethylene transparent knee cloth", in addition to not requiring the coating processing, the equipment investment of the coating method can be omitted, and the equipment can be avoided. Environmental protection problems of waste solvents in wet coating process. Therefore, the method of the invention has the advantages of simple process, low processing cost, fast production speed and environmental protection. ,
【實施方式】 本發明的透明隔熱聚氣乙烯膠布30，如圖3所示，是厚 度介於0.02〜2_0mm具透明性及遮蔽紅外線及紫外線特性的 透明軟質或半硬質或硬質膠布；其結構特徵為：厚度介於 0.02〜2_0mm的聚氣乙烯膠布31為基材’其無機隔熱顆粒& 均勻分散於所述的聚氯乙烯膠布31的組織中。 本發明的透明隔熱聚氯乙稀膠布30之製程，包括下列步驟·[Embodiment] The transparent heat-insulating polyethylene rubber tape 30 of the present invention, as shown in FIG. 3, is a transparent soft or semi-rigid or hard tape having a thickness of 0.02 to 2_0 mm and having transparency and shielding infrared rays and ultraviolet rays; The gas-polyethylene tape 31 having a thickness of 0.02 to 2_0 mm is characterized in that the substrate 'its inorganic heat-insulating particles & uniformly dispersed in the structure of the polyvinyl chloride tape 31. The process of the transparent and heat-insulating polyvinyl chloride tape 30 of the present invention comprises the following steps:
(1) 將改質劑0.01〜15.0PHR、紫外線吸收劑0.01〜5.0PHR 、分散劑〇·〇1〜5.0PHR、無機隔熱顆粒〇_〇卜15 〇PHR、可 塑劑0〜45PHR先投入混合機混合改質攪拌均勻，然後再依 序投入聚氣乙烯樹脂100PHR、可塑劑〇〜85PHR、安定劑 0·1 〜15.0PHR、滑劑 〇_卜 15.0PHR、色料 〇〇〜12.0PH$於 混合機混合均勻後，引入萬馬力機均勻混煉； ' (2) 再經輥輪機進一步膠化後，料溫控制在150〜19〇亡送料至 壓延機’加工成型厚度控制於〇.〇5mm〜1.〇mm，隨即'引入 溫度在20〜85°C的水中冷卻硬化，然後經過除水；或熱熔 膠布成型後’或以T-Die機加工成型厚度控制介於〇 〇5|^m 〜2.0mm，或以吹氣成型機力π工成型厚度控制介於〇 〇2mm 〜0.8mm的熱熔膠布後，直接引入步驟(3);及 · ⑶將膠布引入冷卻輪組冷卻定型，經捲取製成本發明 熱聚氯乙烯膠布30。 _ 6 201031731 本發明用之於步驟(1)中的聚氣乙烯樹脂，可選自以塊狀聚合 (Bulk Polymerization)、溶液聚合(Solution Polymerization)、懸浮聚合(Suspension Polymerization)或 乳化聚合(Emulsion Polymerization)所製得的聚氯乙烯聚合物 或共聚物的其中一種或一種以上的組合物。 可塑劑；係選自磷酸酯類、酜酸系、苯三酸酯類、環氧類 偏苯三酸三辛酯(TOTM)、擰檬酸酯、己二酸酯可塑劑聚酯類 或脂肪族二酸酯類可塑劑的其中一種或一種以上。 φ 無機隔熱顆粒；粒徑介於0.005〜2μηη，為視透明度、霧 度等不同物性的需求，可選自二氧化鈦(Ti02)、氧化鋅(ΖηΟ)、 氧化釩(V2〇5)、氧化銦(ln2〇3)、氧化鈽(Ce02)、氧化錫(Sn02)、 氧化銻(St>2〇3)、銦錫氧化物(ιτο)、銻錫氧化物(ΑΤ〇）、銻辞 氧化物(ΑΖΟ)及類似金屬氧化物、硫化鋅(ZnS)的其中一種或 一種以上。 以及六硼化物（包括：六硼化鋼(LaB6)、六硼化鈽(CeB6)、 六硼化镨(PrBe)、六硼化鈥(NdBe)、六硼化釤(SmB6)、六硼化 銪（EuBe)、六硼化亂(GdBe)、六硼化鉞(TbB6)、六硼化鏑 (DyB0)、六蝴化鈥(Η〇Ββ)、六硼化餌(Er*Be)、六爛化録(TmB6)、 © 六硼化镱(YbB6)、六硼化錙(LuBe)、六硼化鳃(SrB6)、六硼化 鈣(CaBe)、六硼化釔(YB6))的其中一種或一種以上。 無機隔熱顆粒選自上述金屬氧化物或六硼化物的一種或 一種以上之混合物。 女疋劑，可選自鋇鋅糸(Ba-Zn系)或妈辞系(Ca-Zn系）或 有機錫系辛硫醇錫(Octyl Tin Mercaptide)等，例如南亞公司出 品LQX_3K-8T、SD-8032S之一種或多種複合安定劑。 滑劑’可以是硬脂酸系、脂肪酸酯系、脂肪酸醢胺類、金 屬石驗類、有機矽系等之滑劑。可利用上述不同種 中之一種或多種甚至全部搭配使用皆可。 、《 助劑包括改質劑、分散劑、或紫外線吸收劑的其中一種或 7 201031731 配喊。添加助細目的，在於做料乙烯膠布 31的組織中之無機隔熱顆粒32達到均勻分散的目的。 ，中所述的改質劑’選自有機魏化合物、有機餘化合 物或有機鈦鋁化合物的其中一種（例如信越公司之Amh〇 s，丨ane Coupling Agent KBM_6〇3)。所述的分散劑，選(1) Adding modifier 0.01~15.0PHR, UV absorber 0.01~5.0PHR, dispersing agent 〇·〇1~5.0PHR, inorganic insulating particles 〇_〇卜15 〇PHR, plasticizer 0~45PHR first mixed The machine is mixed and modified to stir evenly, and then the polygas vinyl resin 100PHR, plasticizer 〇~85PHR, stabilizer 0·1 ～15.0PHR, slip agent 〇_15.0PHR, colorant 〇〇~12.0PH$ After the mixer is evenly mixed, it is introduced into the 10,000-horse machine for uniform mixing; ' (2) After further gelling by the roller mill, the material temperature is controlled at 150~19, and the feed is sent to the calender. The thickness of the forming is controlled at 〇.〇5mm ~1.〇mm, then 'introduced to cool in water at 20~85 °C, then pass through water; or hot melt adhesive tape after forming' or T-Die machined forming thickness control between 〇〇5|^ m ~ 2.0mm, or the hot-melt tape of 〇〇2mm ~0.8mm is controlled by the blow molding machine force, and then directly introduced into step (3); and (3) the tape is introduced into the cooling wheel set to cool the shape. The hot polyvinyl chloride tape 30 of the present invention is formed by coiling. _ 6 201031731 The present invention is used in the polystyrene resin in the step (1), which may be selected from Bulk Polymerization, Solution Polymerization, Suspension Polymerization or Emulsion Polymerization. Or one or more compositions of the obtained polyvinyl chloride polymers or copolymers. a plasticizer; selected from the group consisting of phosphates, citric acid, trimellitic acid esters, epoxy triisooctyl trimellitate (TOTM), citric acid esters, adipate plasticizers, polyesters or fats. One or more of the group diester plasticizers. φ Inorganic thermal insulation particles; particle size between 0.005~2μηη, which can be selected from different physical properties such as transparency and haze, and can be selected from titanium dioxide (Ti02), zinc oxide (ΖηΟ), vanadium oxide (V2〇5), indium oxide. (ln2〇3), cerium oxide (Ce02), tin oxide (Sn02), cerium oxide (St>2〇3), indium tin oxide (ιτο), antimony tin oxide (ΑΤ〇), 锑 氧化物 oxide ( ΑΖΟ) and one or more of a similar metal oxide or zinc sulfide (ZnS). And hexaboride (including: hexaboride steel (LaB6), lanthanum hexaboride (CeB6), bismuth hexaboride (PrBe), lanthanum hexaboride (NdBe), lanthanum hexaboride (SmB6), hexaboride EuBe, hexaboride (GdBe), lanthanum hexaboride (TbB6), lanthanum hexaboride (DyB0), hexafluorene (Η〇Ββ), hexaborated bait (Er*Be), six Rotten Record (TmB6), © YBB6, LuBe, SrB6, Calcium Hexaboride (CaBe) One or more. The inorganic heat insulating particles are selected from one or more of the above metal oxides or hexaborides. The female bismuth agent may be selected from the group consisting of bismuth zinc bismuth (Ba-Zn) or gynecological (Ca-Zn) or organotin oxysulfide (Octyl Tin Mercaptide), such as LQX_3K-8T, SD produced by South Asia Company. One or more complex stabilizers of -8032S. The slip agent' may be a slip agent such as a stearic acid type, a fatty acid ester type, a fatty acid guanamine type, a metal stone type, or an organic lanthanum type. One or more of the above different types may be utilized, or even all of them may be used in combination. "Auxiliaries include one of modifiers, dispersants, or UV absorbers or 7 201031731. The purpose of adding the fineness is to achieve the purpose of uniform dispersion of the inorganic heat insulating particles 32 in the structure of the vinyl tape 31. The modifier "described" is selected from one of an organic Wei compound, an organic residual compound or an organotitanium aluminum compound (for example, Amway's Amh〇 s, 丨ane Coupling Agent KBM_6〇3). Said dispersant, selected
^的共聚物分㈣、含魏份分散贼含氟絲分散劑的其 中一種或一種以上搭配而成（例如Βγκ公司之D丨 byk-185)。所述的紫外線吸收劑，選自絲苯基苯并三 外線吸收劑、龜基二苯甲_紫外線吸收綱其中一種二 種以卜。 色料’·可視產品的色相需求时添加’或為有機系 或為無機系色料，亦可採無機、有機色料混合方式。” 本發明的透明隔熱聚氣乙烯膠布3〇可以單層 】途可以如圖4所示，多層聚氯乙烯膠布叠合在—起使用，或 者，如圖5所示，與他種塑膠基材4〇疊合在一起使用。 、下面將以實施例更具體地說明本發明，雖然以較佳之實施 例被露加以詳述’惟本發明之技術及權利範圍不受其所限 本發明之各項物性評估方法如下： 、 ⑴可見光穿透率及霧度測試： 採用 Tokyo Denshoku Ca，Ltd. Haze Meter，型號為 ^C-ΗΙΠ ’測試下面實施例之聚氯乙烯膠布的光透過率及霧 X值’其方法符合JIS K7705規範。可見光穿透率越高、霧 度值越低代表聚氯乙烯膠布的透明性越佳。 (2)紅外線遮蔽率測試： ，用台’ 號為LT_3()QQ，測試實施例之隔熱膠 平顏:合JIS R31〇6魏。紅外線阻隔率愈高代表 t虱乙浠膠布的隔熱效果越佳。 ⑶紫外線阻隔率測試·· 採用H0YA機台’型號為LT_3〇〇〇，測試實施例之隔熱膠 8 201031731 布，其方法符合JIS R3106規範。紫外線阻隔率愈高代表 聚氯乙烯膠布的阻隔UV效果越佳。 〔實施例1〕 生產厚度0.2mm軟度40PHR的透明隔熱聚氣乙烯膠布 3〇，其製法為： ❹The copolymer is divided into one or more of the copolymers of the displacing thief-containing displacing agent (for example, D丨 byk-185 of Βγκ). The ultraviolet absorbing agent is selected from the group consisting of a silk phenyl benzotriene absorbent and a turtle base benzophenone ultraviolet absorbing agent. The colorant'·when the color of the visible product is required to be added' is either organic or inorganic, or inorganic or organic color mixing. The transparent heat-insulating polystyrene rubber tape of the present invention can be used in a single layer. As shown in FIG. 4, a plurality of layers of polyvinyl chloride tape are laminated and used, or, as shown in FIG. 5, a plastic base is used. The invention will be described in more detail below with reference to the preferred embodiments of the present invention, which are described in detail in the preferred embodiments. The physical property evaluation methods are as follows: (1) Visible light transmittance and haze test: Light transmittance and fog of the polyvinyl chloride tape of the following examples were tested using Tokyo Denshoku Ca, Ltd. Haze Meter, model number ^C-ΗΙΠ ' The value of X is 'in accordance with JIS K7705. The higher the visible light transmittance and the lower the haze value, the better the transparency of the PVC tape. (2) The infrared shielding rate test: The table number is LT_3() QQ, test the example of the thermal insulation rubber flat: JIS R31〇6 Wei. The higher the infrared blocking rate, the better the thermal insulation effect of the t虱 浠 浠 tape. (3) UV blocking rate test · · Adopt H0YA machine 'model Test example for LT_3〇〇〇 Insulation adhesive 8 201031731 cloth, the method is in accordance with JIS R3106. The higher the ultraviolet blocking rate, the better the UV blocking effect of the polyvinyl chloride tape. [Example 1] Production of transparent insulating gas gathering with a thickness of 0.2 mm and a softness of 40 PHR. Ethylene tape 3 〇, the preparation method is: ❹
⑴依表1的特定配方，先將無機隔熱顆粒LaBe添加量 0.25PHR、改質劑〇.81PHR、分散劑〇 17pHR、紫外線吸 收劑0.8PHR、安定劑3PHR、可塑劑40PHR及聚氯乙稀 樹脂100PHR等原物料依序投入混合機(Hensche丨Mixer N.P.C製’ 300L)混合均勻後，引入萬馬力機(N p c製，】〇〇L 落門式)均勻混煉； ⑵再經二支輥輪式輥輪機(N PC製，輥輪速差1:1.15)膠化後， 料皿控制在150〜19CTC ’送料至四輪逆型壓延機(N.P.C 製，規格24" χ72,）’厚度管制在〇 2mm的熱熔膠布。隨 即引入溫度在20〜85°C的水中冷卻硬化，再經過除水後； ⑶將膠布引入冷卻輪組冷卻定型，經捲取即製 軟度/0PHR的隔熱聚氣乙烯透明膠布3〇。 測試結果如表1所示，光透過率高達72%，霧度】7%， 顯示所製得的透明隔熱聚氯乙烯膠布3Q具備透明性，其紅外 線遮蔽率67%，紫外線阻隔率99%。 、 〔實施例2〕 1的特定配方，將無機隔熱顆粒CeB6添加量 0.25PHR > #J 0.81PHR 1 厚度CUmm軟度40PHR的透明隔熱聚氣乙烯膠布3〇。 酿- ΐΐί果如表1戶斤示’光透過率高達70%，霧度2謂， Γΐί仔的透明隔熱聚氣乙烯膠布30具備透明性，其光透 過。、系於實加例1，其紅外線遮蔽率64%，亦僅:欠於實施例 9 201031731 1，其紫外線阻 析出的現象。 隔率99%，且加工過程中無機隔熱顆粒不會有 〔實施例3〕 依表1的特定配方，將無機隔熱顆粒AT〇添加量18pHR 及LaBe添加量〇_25PHR、改質劑添加量6 97PHR等原料， ，用實施例1的製法生產厚度。_2咖軟度4〇pHR的透明隔 熱聚氯乙烯膠布30。 參 測试結果如表1所示，光透過率高達69%，霧度2.6%， *，属不所製得的透明隔熱聚氣乙烯膠布3〇具備透明性，其紅外 =蔽率91% ’紫外線阻隔率99% ’顯示所製得的透^隔熱 聚氯乙烯料3Q具備優異光透過率，與比糊1相當，但其 、’1線遮蔽率則遠優於比較例彳，其加工過程中無機隔熱顆粒 不會有析出的現象。 〔比較例1〕 依表1的特定配方，將無機隔熱顆粒AT0 15PHR、改質 ^10.77 PHR等原料使用實施例i的製法生產厚度〇 2mm軟 ❿ 度40PHR的透明隔熱聚氣乙稀膠布30。 測試結果如表1所示，光透過率19%，霧度1〇 4%，其 紅外線遮蔽率91%，紫外線阻隔率99%，顯示所製得厚^ 0.2mm透明隔熱聚氯乙烯膠布3〇具備相當優異紅外線遮蔽率 及紫外線阻隔率，但其光透過率低，霧度高，為其主要缺點， 顯示ΑΤΟ添加量偏高所致。 〔比較例2〕 除厚度為0.2mm外，所製得的透明隔熱聚氯乙烯膠布3〇 的原物料配方及製法皆同實施例彳，無機隔熱顆 τ 量 2.2PHR。 201031731 測試結果如表1所示，光透過率69%，霧度2.6%，其紅 外線遮蔽率43%，紫外線阻隔率99%顯示所製得厚度0 2mm 透明隔熱聚氯乙烯膠布30具備透明性、且具備中等程度紅外 線遮蔽率，但較實施例卜3差，其加工過程中無機隔熱顆粒不 會有析出的現象。 〔比較例3〕 生產厚度0.2mm軟度40PHR的聚氣乙烯透明膠布，其 _ 原物料配方除不含無機隔熱顆粒、改質劑、分散劑外，其製^ 皆同實施例1。 、 測試結果如表1所示，光透過率高達86%，霧度14 其紅外線遮蔽率僅8%，紫外線阻隔率98%，比較實施例^^3 ，不：光透鱗較高，但紅外線遮蔽率幾乎無效，與—般 相同。 V V 〔比較例4〕 減ΐίίΪ 軟度4GPHR的聚氣乙稀透明膠布，盆 ❹Π 不甘3改質劑、分散劑外’無機隔熱難ΑΤΟ ^ ϋ 加量2.2PHR，其餘皆同比較例2。 ^添 測5式結果如表1所示’光透過率高達50%，霧产12 η〇/ 芯外線遮蔽率僅29%，紫外線_率m，心所製0二 乙烯透明膠布，因為沒有使用改質劑3 化。而且，加工過程中會有析出現象 〗^ 膠布產品的加工性及分散性品質❶ V '稀透明 〔比較例5〕 以尺寸 100mm*100mm*0 3m 物件，測量其光透過率、霧产 的，，，、色透明玻璃為對照 丰霧度紅外線遮蔽率及紫外線阻隔率。 201031731 測試結果如表1所示，顯示無色透明玻璃的紅外線遮蔽率 及紫外線阻隔率確實不佳，較實施例1〜3相差很多。 本發明，雖然以較佳之實施例被露加以詳述，惟本發明之 技術及權利範圍不受其所限制，由以下申請專利範圍所界定。 Φ ❿ 12 201031731 表1 實施方式 配方用量單位為：PHR (每百份重量樹脂） 名稱 實施例 1 實施例 2 實施例 3 比較例 1 比較例 2 比較例 3 比較例 4 比較例 5 基材 聚氯 乙烯 100 100 100 100 100 100 100 — 玻璃 — — — — — — 無色透 明玻璃 配 可塑劑 DINP 40 40 40 40 40 40 40 — 無機隔 熱顆粒 ΑΤ0 — — 1.8 15 2.2 — 2.2 — LaBe 0.25 — 0. 25 — — — — — CeBe — 0.25 — — — — — — 安定劑 鋇鋅系 3 3 3 3 3 3 3 — 方 滑劑 硬酯酸 0.4 0.4 0.4 0.4 0.4 0.4 0.4 — 改質劑 0.81 0.81 6.97 10.77 4.02 — — — 助劑 分散劑 0.17 0.17 0.95 2.61 0.75 — — — 紫外線吸 收劑 0.8 0.8 0.8 0.8 0.8 0.8 0.8 — 基材厚度(mm) 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.3. 物 光透過率（％) 72 70 69 19 69 86 50 93 霧 度⑻ 1.7 2.0 2.6 10.4 2.6 1.4 12.0 0.6 性 紅外線遮蔽率(％) 67 64 91 91 43 8 29 22 紫外線阻隔率(％) 99 99 99 99 99 98 98 27 加工過程無機隔 熱顆粒是否析出 否 否 否 否 否 否 會 — 13 201031731 【圖式簡單說明】 圖1係以驾知乾式塗佈加工製得的透明隔熱膠膜的斷面放大 圖。 圖2係以習知赋塗佈加卫製得的翻隔熱咖的斷面放大 圖。 圖3係以非塗佈加工製得的本發明具遮蔽紅外線及紫外線效 果的透明隔熱聚氣乙烯膠布的斷面放大圖。 © 圖4係本發明的透明隔熱聚氯乙烯膠布以多層疊合在一起使 用的示意圖。 圖5係本發明的透明隔熱聚氣乙烯膠布與另一片塑膠基材疊 合在一起使用的示意圖。 【主要元件符號說明】 ⑩ 1〇._.透明隔熱膠膜 11…塑膠基材 12·.·金屬或金屬氧化物等無機物 20_··透明隔熱膠膜 21…塑膠基材 22·..無機隔熱顆粒 23...樹脂 3〇…透明隔熱聚氣乙烯膠布 31…聚氣乙烯膠布 32···無機隔熱顆粒 40· •塑膠基材 14(1) According to the specific formula of Table 1, the inorganic insulating particles LaBe added amount 0.25PHR, modifier 〇.81PHR, dispersant 〇17pHR, UV absorber 0.8PHR, stabilizer 3PHR, plasticizer 40PHR and polyvinyl chloride The raw materials such as resin 100PHR are sequentially put into a mixer (Hensche丨Mixer NPC system '300L) and uniformly mixed, and then introduced into a 10,000 horsepower machine (N pc system, 〇〇L falling door type) for uniform mixing; (2) two rolls After the wheeled roller turbine (N PC system, the roller speed difference is 1:1.15), the material is controlled at 150~19CTC 'Feed to the four-wheel reverse calender (NPC system, size 24" χ72,)' thickness control In the 〇 2mm hot melt tape. Then, the temperature is cooled and hardened in water of 20 to 85 ° C, and then the water is removed; (3) The tape is introduced into the cooling wheel set to be cooled and shaped, and the heat-insulating gas-gum vinyl transparent tape of softness/0 PHR is prepared by winding. The test results are shown in Table 1. The light transmittance is as high as 72% and the haze is 7%. It shows that the transparent insulating PVC tape 3Q has transparency, and its infrared shielding rate is 67%, and the ultraviolet blocking rate is 99%. . [Example 2] The specific formulation of 1, the amount of inorganic heat-insulating particles CeB6 added 0.25PHR >#J 0.81PHR 1 thickness CUmm softness 40PHR transparent heat-insulating polyethylene tape 3 〇. Brewing - ΐΐ 果 果 如 如 表 ’ ’ ’ ’ ’ ’ ’ ’ ’ ’ ’ ’ ’ ’ ’ 光 光 光 光 光 光 光 光 光 光 光 光 光 光 光 光 光 光 光 光 光 光 光 光 光According to the actual example 1, the infrared shielding rate is 64%, and it is only due to the phenomenon that the ultraviolet light is inhibited in the embodiment 9 201031731. The separation rate is 99%, and the inorganic heat-insulating particles will not be in the process of processing. [Example 3] According to the specific formula of Table 1, the inorganic insulating particles AT〇 addition amount 18pHR and LaBe addition amount 〇25PHR, modifier added A raw material such as 6 97 PHR was used to produce a thickness by the method of Example 1. _2 Coffee softness 4 〇 pHR transparent heat-insulating PVC tape 30. The test results are shown in Table 1. The light transmittance is as high as 69% and the haze is 2.6%. * It is a transparent transparent heat-insulating polyethylene tape that is not made to have transparency, and its infrared=cover rate is 91%. 'UV blocking rate of 99%' shows that the obtained transparent insulating polyvinyl chloride material 3Q has excellent light transmittance, which is comparable to that of paste 1, but its '1 line shielding ratio is far superior to the comparative example. There is no precipitation of inorganic heat-insulating particles during processing. [Comparative Example 1] According to the specific formulation of Table 1, a raw material such as inorganic heat insulating particles AT0 15PHR and modified 10.77 PHR was produced by the method of Example i to produce a transparent heat-insulating polyethylene-polyethylene tape having a thickness of mm 2 mm and a softness of 40 PHR. 30. The test results are shown in Table 1. The light transmittance is 19%, the haze is 1〇4%, the infrared shielding rate is 91%, and the ultraviolet blocking rate is 99%. It shows that the thickness is 0.2 mm transparent insulating PVC tape 3 〇 has a very good infrared shielding rate and ultraviolet blocking rate, but its light transmittance is low, and the haze is high, which is the main disadvantage, indicating that the amount of strontium added is high. [Comparative Example 2] Except for the thickness of 0.2 mm, the raw material formulation and preparation method of the transparent heat-insulating polyvinyl chloride tape 3〇 obtained were the same as those in the examples, and the inorganic heat insulating material τ amount was 2.2 PHR. 201031731 The test results are shown in Table 1. The light transmittance is 69%, the haze is 2.6%, the infrared shielding rate is 43%, and the UV blocking rate is 99%. The thickness is 0 2mm. The transparent insulating PVC tape 30 has transparency. Moreover, it has a moderate infrared shielding rate, but it is inferior to the embodiment, and the inorganic insulating particles do not precipitate during the processing. [Comparative Example 3] A polyethylene-gas transparent tape having a thickness of 0.2 mm and a softness of 40 PHR was produced, and the formulation of the raw material was the same as in Example 1 except that the inorganic heat-insulating particles, the modifier, and the dispersant were not contained. The test results are shown in Table 1. The light transmittance is as high as 86%, the haze 14 has an infrared shielding rate of only 8%, and the ultraviolet blocking rate is 98%. The comparative example ^^3, no: the light permeation scale is high, but the infrared rays The masking rate is almost ineffective, just like the same. V V [Comparative Example 4] Reduced ΐ ίί Ϊ softness 4GPHR of polyethylene gas transparent transparent tape, pot ❹Π Not willing to 3 modifier, dispersant outside 'Inorganic insulation difficult ΑΤΟ ^ ϋ Add 2.2PHR, the rest are the same as Comparative Example 2. ^Addition 5 results as shown in Table 1 'Light transmittance up to 50%, fog production 12 η 〇 / core outside shielding rate is only 29%, UV _ rate m, heart made 0 vinyl transparent tape, because it is not used Modifier 3. In addition, during the processing, there will be a phenomenon such as the processability and dispersibility of the product of the tape. V 'thin transparent [Comparative Example 5] The light transmittance and fog production are measured by the object of size 100mm*100mm*0 3m. ,,, color transparent glass for the contrast of the fog infrared ray shielding rate and ultraviolet blocking rate. The test results of 201031731 are shown in Table 1. It shows that the infrared shielding rate and the ultraviolet blocking rate of the colorless transparent glass are really poor, which is much different from Examples 1 to 3. The present invention is not limited by the preferred embodiments, but is defined by the scope of the following claims. Φ ❿ 12 201031731 Table 1 Embodiment Formulation Unit: PHR (per hundred parts by weight of resin) Name Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Polychlorinated substrate Ethylene 100 100 100 100 100 100 100 — Glass — — — — — — Colourless transparent glass with plasticizer DINP 40 40 40 40 40 40 40 — Inorganic insulation particles ΑΤ0 — — 1.8 15 2.2 — 2.2 — LaBe 0.25 — 0. 25 — — — — — CeBe — 0.25 — — — — — — stabilizer 钡 zinc system 3 3 3 3 3 3 3 — slip agent stearic acid 0.4 0.4 0.4 0.4 0.4 0.4 0.4 — modifier 0.81 0.81 6.97 10.77 4.02 — — — 剂剂剂 0.17 0.17 0.95 2.61 0.75 — — — UV absorber 0.8 0.8 0.8 0.8 0.8 0.8 0.8 — Substrate thickness (mm) 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.3. Light transmittance (%) 72 70 69 19 69 86 50 93 Haze (8) 1.7 2.0 2.6 10.4 2.6 1.4 12.0 0.6 Infrared shielding rate (%) 67 64 91 91 43 8 29 22 UV blocking rate (%) 99 99 99 99 99 98 98 27 Add Process heat-insulating inorganic particles deposited whether No No No No No No will --13,201,031,731] [Brief Description of the drawings Figure 1 is a transparent insulating film of the driving section known dry coating process made enlarged in FIG. Fig. 2 is a cross-sectional enlarged view of a tumbling insulated coffee made by conventionally applying the coating. Fig. 3 is an enlarged cross-sectional view showing the transparent heat-insulating polystyrene tape having the infrared and ultraviolet shielding effect of the present invention which is obtained by non-coating processing. © Fig. 4 is a schematic view showing the use of the transparent heat-insulating polyvinyl chloride tape of the present invention in a plurality of layers. Fig. 5 is a schematic view showing the use of the transparent heat-insulating polystyrene tape of the present invention in combination with another plastic substrate. [Main component symbol description] 10 1〇._.Transparent heat insulation film 11...Plastic substrate 12·.·Metal or metal oxide and other inorganic substances 20_··Transparent heat insulation film 21...Plastic substrate 22·.. Inorganic heat-insulating particles 23...Resin 3〇...transparent heat-insulating gas-filled vinyl tape 31...gas-filled vinyl tape 32···Inorganic heat-insulating particles 40·•Plastic substrate 14