TW201034700A - Hair dyeing composition - Google Patents
Hair dyeing composition Download PDFInfo
- Publication number
- TW201034700A TW201034700A TW099105357A TW99105357A TW201034700A TW 201034700 A TW201034700 A TW 201034700A TW 099105357 A TW099105357 A TW 099105357A TW 99105357 A TW99105357 A TW 99105357A TW 201034700 A TW201034700 A TW 201034700A
- Authority
- TW
- Taiwan
- Prior art keywords
- group
- red
- alkyl
- hair
- hydrogen
- Prior art date
Links
- 210000004209 hair Anatomy 0.000 title claims abstract description 89
- 239000000203 mixture Substances 0.000 title claims abstract description 87
- 238000004043 dyeing Methods 0.000 title claims abstract description 68
- 239000001257 hydrogen Substances 0.000 claims abstract description 27
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 27
- 150000001875 compounds Chemical class 0.000 claims abstract description 23
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 10
- 230000008878 coupling Effects 0.000 claims abstract description 10
- 238000010168 coupling process Methods 0.000 claims abstract description 10
- 238000005859 coupling reaction Methods 0.000 claims abstract description 10
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000001450 anions Chemical class 0.000 claims abstract description 4
- 150000002989 phenols Chemical class 0.000 claims abstract description 4
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 claims abstract description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 3
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims abstract 4
- 125000002490 anilino group Chemical class [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims abstract 2
- 125000005843 halogen group Chemical group 0.000 claims abstract 2
- 239000000049 pigment Substances 0.000 claims description 71
- 239000000975 dye Substances 0.000 claims description 45
- 125000000217 alkyl group Chemical group 0.000 claims description 44
- 239000000835 fiber Substances 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 claims description 12
- 125000003545 alkoxy group Chemical group 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 239000000982 direct dye Substances 0.000 claims description 7
- 239000003086 colorant Substances 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- 125000003282 alkyl amino group Chemical group 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 125000003277 amino group Chemical group 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 230000037308 hair color Effects 0.000 claims description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 2
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 125000005078 alkoxycarbonylalkyl group Chemical group 0.000 claims 1
- 125000000278 alkyl amino alkyl group Chemical group 0.000 claims 1
- 150000004693 imidazolium salts Chemical class 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- -1 amino- Chemical class 0.000 abstract description 53
- 125000000623 heterocyclic group Chemical group 0.000 abstract description 4
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 79
- 239000010445 mica Substances 0.000 description 42
- 229910052618 mica group Inorganic materials 0.000 description 42
- 235000010215 titanium dioxide Nutrition 0.000 description 40
- 239000004408 titanium dioxide Substances 0.000 description 39
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 32
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
- 239000002253 acid Substances 0.000 description 12
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- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 9
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- 238000002360 preparation method Methods 0.000 description 7
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- 102000011782 Keratins Human genes 0.000 description 6
- 108010076876 Keratins Proteins 0.000 description 6
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- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 6
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- 229910000906 Bronze Inorganic materials 0.000 description 5
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- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 5
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
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- A—HUMAN NECESSITIES
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4926—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having six membered rings
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
- A61K2800/4324—Direct dyes in preparations for permanently dyeing the hair
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
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- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Description
201034700 六、發明說明： 【發明所屬之技術領域】 本發明係關於一種用於將角質纖維染色（具體而言，係 .諸如毛髮等人類角質纖維）之組合物，其包含存於適當染 &介質中的至少一種由至少2種具有給定化學式之陽：; 直接染劑組成之混合物及至少一種由陽離子、其組合物組 成之四級銨鹽混合物；其製備方法及其於諸如角質:維'、 羊毛、毛皮、絲、纖維素或聚醯胺等有機材料（尤其是含 有角質之纖維、棉花或耐論且較佳為毛髮，更佳為人類毛 髮）染色中之用途。 【先前技術】 舉例而言，自WO 95/01772、WO 95/15144、歐洲專利 EP 714 954及歐洲專利EP 318 294可知陽離子染劑可用於 染色有機材料，例如，角質、絲、纖維素或纖維素衍生物 以及合成纖維，例如，聚醯胺。陽離子染劑呈現十分鮮 ◎ 壳的色澤。缺點在於其耐水解性及财光性不能令人滿竞、 其在還原或氧化條件下之穩定性經常不足、及其儲存穩定 性經常不施令人滿意（參見：j〇hn F. Corbett:「The Chemistry ofHair-CareProducts」，JSCD 1976年 8月，第 290頁）。 本發明之實際技術問題在於提供可用於染色有機材料之 鮮7C染劑’其可藉由具有良好财洗務性、财光性、耐洗髮 精性及耐摩擦性之深度染色來辨別並且在還原或氧化染色 條件下較佳呈現令人滿意的穩定性。 【發明内容】 146626.doc 201034700 因此，本發明係關於一種毛髮染色組合物，其包含 〇) 具有下式之染劑
(b) 至少一種選自以下各式化合物之染劑
D 係具有式（2a) % 之重氮組份之基團； K 係選自苯胺衍生物、苯酚衍生物之偶合組份之基 團；及雜環狀偶合組份之基團； X 係; -S-;或-N(R8)-; Y 係-CH=，-CR15=;或 _n=;
Ri、R·2、R3及R4彼此獨立地為氫；或Ci_C4烷基；
Rs及R6彼此獨立地為氫；CVC4烷基；或CVC4烷氧 基； R?及R9彼此獨立地為未經取代(^-(：4烷基或經OH-、 CVC4烷氧基_、鹵素_、胺基_、Ci_c4_單或-二烷 基胺基-取代之（:丨-(:4烷基； 146626.doc -6- 201034700
Rs 係氫；或匚广^烷基；
Rio係氫；CVC4烷基；或CN ;
Ru 係未經取代CVC4烷基或經OH-或CN-取代之C「C4 烷基； R12係氫；或CVC4烷基；
Rl3 及尺"彼此獨立地為氫；crc4烷基；或cvc4烷氧 基；或 〇
Rn 及與其所連接氮及碳原子一起形成5-或6-員 環；
Rl5 係氫；或心-山烷基；且 ΑηΓ係無色陰離子；及 (c) 選自下列之四級銨鹽： (ci)具有下式之四級銨鹽 (4) 8 R1 ,6119 R丨 NIRi口 中 其 An,*
Rl6 及R19彼此獨立地為飽和或不飽和、直鏈或具支 鍵脂肪族C1-C3G烧基；或烧氧基、烧氧基艘基烧 基、聚氧基伸烷基、烷基醯胺基、烷基醯胺基烧 基、羥基烷基；包含約12個至約30個碳原子之芳 香族芳基或烷基芳基基團，其中R16、R17、r18及 R19中之至少一個基團表示包含8個至30個碳原子 之基團；
An2係選自包含_離子、填酸根、乙酸根、乳酸根及 146626.doc 201034700 烧基硫酸根在内之群組的陰離子； (以）具有下式之咪嗤鏽鹽 (5)
，其中 R2〇係衍生自牛脂脂肪酸iC】3_c3i烷基或C】3_C31烯基； (C3)具有下式之四級二銨鹽 ⑹ r21 ?22 R24 RiT ^ ~ (CH2)3— N - Rgg R23 係06-(：31烷基； 2Αη3· ;其中 汉22、R23、R24、R_25及R26係選自氫；或^/*烷基；且
An3係選自_離子、乙酸根、磷酸根及硫酸根之陰離 子。 【實施方式】 Q-Cso烧基係（例如）甲基、乙基、丙基、異丙基、正丁 基、第二丁基、第三丁基、正戊基、2·戊基、3_戊基、 2,2'-二甲基丙基、環戊基、環己基、正己基、正辛基、 1，Γ，3,3’-四甲基丁基或2_乙基己基、壬基、癸基、十一烷 土 十一烧基十二燒基、十四院基、十五烧基、十六燒 基或二十烷基。
Cs-Cw烯基係（例如）烯丙基、甲基烯丙基、異丙烯基、 2-丁烯基、3-丁烯基、異丁烯基、正戊_2,4_二烯基、3_甲 基-丁-2-烯基、正辛_2-烯基、正十二碳_2_烯基、異十二碳 146626.doc 201034700 烯基、正十二碳_2-烯基或正十八碳-4-埽基。 芳基係（例如）萘基且較佳為苯基。 ^環狀f機基團係（例如）5員含氮雜環狀基團，諸如味 坐A比蓮坐基、二唾基、t各基、。比°各。定基…惡唾基心塞 唑基；ό員含氮雜環狀基團，諸如哌 次塞 ♦巷、六氫11比D定其、 ㈣基或㈣基；或擁有稠合5員含氮雜環及6員芳香奸 城基團，諸如苯Μ錢、 笑衣 ❹ ❹ 本并咪唑基或苯并三唑基。 坐基、 較佳者系其中在組份⑷之式中， LL >(g Jy ,J, y, tL 1、R2、R3 及 R4 彼 此獨立地為氫；或Cl_C2烧基之毛髮染色組合物。 更佳者係其巾組份⑷對應於下式之毛㈣色組合物
α ⑺ 更佳地’在式（2a)中 R? 及R9彼此獨立地為〇丨-(：4焓1 · 0朴 4烷基，且甚至更佳者係 如下毛髮染色組合物，其中 x 係-NH ;且 Y 係-CH=。 甚至更佳者係如下毛髮染色〜組合物，其中在式⑺中 係具有式（2b)
之基團；其中
K ^ 2氫^基；Cl-c4烧基；Ci_c&氧基；胺基 單-Ci-C4烷基胺基；或二_Ci_c4烷基胺基。 146626.doc 201034700 最佳者係包含下列之毛髮染色組合物： (a) 具有式（Ο之染劑， (b) 至少一種選自以下各式化合物之染劑
(c).如在技術方案1中所定義四級錄鹽。 可提及的組份（Cl)之四級銨鹽之實例係（例如）（ci 〇其中烷 基基團包含約12個至約22個碳原子之二烷基二甲基銨鹽或 烷基三曱基銨鹽，諸如二硬脂基二甲基氯化銨、鯨蠟基三 甲基氯化銨或山蓊基三甲基氣化銨；（c〗2)二（Ci_C2烷基） (Cu-C22烷基）羥基（Cl-C2烷基）銨鹽，諸如油基鯨蠟基羥基 乙基氣化銨·，或（另-選擇為）(eu)具有下式之硬脂醯胺基 丙基二曱基（肉豆蔻醇乙酸酯）氯化銨： 9h3 H3c -{CHgi^CONH -(CH2)3-N-CH2-CO〇C14H29 C|- ch3 其由VAN DYK公司以商標CERAPHYL 70出售。 按照本發明，較佳者係其"2丨至R26相同地或不同地表 示包含約12個至約22個碳原子之烷基或羥基烷基基團之式 (6)四級銨鹽且具體而言’係山薔基三甲基氯化銨、鯨蠟基 146626.doc •10· 201034700 二甲基氯化銨及油基鯨蠟基尹其 7暴羥基乙基氯化銨。 按照本發明，所用組份 丁刀ic)之四級銨鹽較佳地佔 物總重量之大約㈣重量％至1〇重量%且仍更佳地估： 重量之大約0.05重量％至5重量0/〇。 Ο
本發明之毛髮染色組合物適用於染色諸如含有角質之纖 維、平毛、毛皮、、絲、纖維素或聚醯胺、棉花或耐綸等有 機材料且較佳地’適用於染色人類毛髮。所獲得染色可藉 由其色澤深度及其(例如)良好耐洗滌性、耐光性、耐心 精性及耐摩擦性來辨別。本發明毛髮染色組合物之穩定性 (具體而言，係儲存穩定性）係極佳的。 可藉由與其他染劑組合來增加該等染劑之色澤多樣性。 因此，本發明之毛髮染色組合物可與相同類別染劑或其 他類別染劑（尤其是與直接染劑、氧化染劑、二硫化物染 劑、其顏料或混合物）組合。 直接染劑具有天然來源或可以合成方式製備。該等直接 染劑不帶電荷、帶陽離子或陰離子，諸如酸性染劑。 本發明之毛髮染色組合物可與至少一種不同於組份及 (b)染劑之單一直接染劑組合使用。 直接染劑之實例闡述於由Ch. Culnan，H. Maibach編輯之 「Dermatology」’ Verlag Marcel Dekker 公司，紐約，
Basle, 1986年’第 7卷，Ch. Zviak，The Science of Hair
Care ’第7章，第248_25〇頁以及由歐盟委員會（The
European Commission)公開之可自 Bundesver-band der deutschen Industrie-und Handelsunternehmen ftir Arzneimittel, 146626.doc 11 201034700
Reformwaren und Korperpflegemittel e.V·，Mannheim以磁 碟形式獲得之「Europaisches Inventar der Kosmetikrohstoffe」 (1996年）中。 進而言之，陽離子硝基苯胺及蒽醌染劑可用於與本發明 之毛髮染色組合物組合。 本發明之毛髮染色組合物亦可與酸性染劑（例如，可自 國際名稱（顏色索引）或商品名稱已知之染劑）組合。 此等酸性染劑可作為單一組份或以其任一組合使用。 本發明之毛髮染色組合物亦可與選自由（例如）硝基苯 胺、硝基苯二胺、硝基胺基苯酚、蒽醌、靛酚、吩嗪、吩 。塞嗓、雙°比β坐琳酮、雙°比°圭氮雜衍生物及次曱基染料組成 之群之不帶電荷染劑組合。 進而言之，本發明之毛髮染色組合物亦可與硫化物染劑 組合使用。硫化物染劑之實例揭示於（例如）WO 05/097051 中〇 進而言之，本發明之毛髮染色組合物亦可與彩色顏料組 合使用。 有機顏料較佳選自D&C紅色30號（還原紅1) ; D&C紅色 3 6號（顏料紅4);胭脂紅；D&C紅色6號Ba色澱；D&C紅色 7號Ca色澱；D&C紅色30號A1色澱；D&C紅色30號滑石粉 色澱；D&C紅色27號A1色澱；D&C紅色28號A1色澱；D&C 紅色33號A1色澱；D&C紅色21號A1色澱。 具體相關者係在下表1中所列示顏料/色彩： 146626.doc -12- 201034700
表la :颜料/色彩之實例(组份(b)) 顏色索引 編號 法定及常用名稱 CAS登記 編號 10006 顏料綠8 16143-80-9 10020 酸性綠1 19381-50-1 10316(2) Ext.D&C黃色7號；酸性黃1 ;萘酚黃S 846-70*8 11680 顏料黃1 2512-29-0 11710 顏料黃3 6486-23-3 11725 顏料橙1 6371-96-6 11920 溶劑橙1 2051-85-6 12010 溶劑紅3 6535-42-8 12085 (2) D&C紅色36號；顏料紅4 ;火焰紅 2814-77-9 12120 顏料紅3 2425-85-6 12150 溶劑紅1 1229-55-6 12370 顏料紅112 6535-46-2 12420 顏料紅7 6471-51-8 12480 顏料掠 6410-40-8 12490 顏料紅5 6410-41-9 12700 分散黃16 4314-14-1 13015 E 105 ;酸性黃9 2706-28-7 14270 E 103 ;酸性橙6 547-57-9 14700 FD&C紅色4號；食品紅1 ;麗春紅(ponceau)sx 4548-53-2 14720 E 1M ;酸性紅14 ;食品紅3 ;偶氮玉紅；紅色酸性 染料(Carmoisine) 3567-69-9 14815 E 125 ;食品紅2 ~~ 3257-28-1 633-96-5 15510(2) D&C橙色4號，酸性橙7 ;橙色π 15525 顏料紅68 ~ 5850-80-6 ----J 146626.doc • 13- 201034700 表la :颜料/色彩之實例(组份(b)) 顏色索引 編號 法定及常用名稱 CAS登記 編號 15580 顏料紅51 227-459-1 15620 酸性紅88 1658-56-6 15630 顏料紅49 1248-18-6 15800:1 D&C紅色31號；顏料紅64:1 ;鮮亮的色澱紅R 6371-76-2 15850 D&C紅色6號；顏料紅57 ;立索玉紅B 5858-81-1 15850:1 (2) D&C紅色7號；顏料紅57:1 ;立索玉紅BCa 5281-04-9 15865 (2) 顏料紅48 3564-21-4 15880:1 D&C紅色34號；顏料紅63:1 ;深栗色；芳淑栗色 (Fanchon Maroon);色殿棗紅色(Lake Bordeaux)B 6417-83-0 15980 E 111 ;食品橙2 2347-72-0 15985 (2) FD&C黃色6號；E 110 ;食品黃3 ;曰落黃；曰落黃 FCF ;橙黃色S 2783-94-0 16035 FD&C紅色40號；食品紅17 ;誘惑紅；誘惑紅AC 25956-17-6 16230 酸性橙10 1936-15-8 16255(2) E U4 ;酸性紅18 ;食品紅7 ;麗春紅4R ;胭脂蟲 紅A 2611-82-7 16290 E 126 ;酸性紅41 5850-44-2 17200(2) D&C紅色33號；酸性紅33 ;酸性品紅 3567-66-6 18050 酸性紅1 3734-67-6 18130 酸性紅155 10236-37-0 18690 酸性黃121 5601-29-6 18736 酸性紅180 6408-26-0 18820 酸性黃11 6359-82-6 18965 酸性黃17 6359-98-4 146626.doc -14 - 201034700
表la :颜料/色彩之實例(组份⑼） 顏色索引 法定及常用名稱 CAS登記 編號 編號 19140(2) FD&C黃色5號；E 102 ;酸性黃23 ;酒石黃 1934-21-0 20040 顏料黃16 5979-28-2 20170 D&C棕色1號·’酸性橙24 ;間笨二紛標 1320-07-6 20470 黑色(Noir)W 699 1064-48-8 21100 顏料黃13 5102-83-0 21108 顏料黃83 5567-15-7 21230 溶劑黃29 6706-82-7 24790 酸性紅163 13421-53-9 26100 D&C紅色17號’ >谷劑紅23 ;蘇丹紅in ;托尼紅 85-86-9 (Toney Red) 27290 (2) 酸性紅73 5413-75-2 27755 E 152 ;食品黑2 2118-39-0 28440 E 151 ;亮黑1 ;食品黑1 ;亮黑BN ;黑色PN 2519-30-4 40215 直接橙34 1325-54-8 40800 β-胡蘿蔔素(合成）；食品橙5 7235-40-7 40820 E 160e ;食品撥6; 阿蔔-8,胡蘿蔔素醛(C 30) 1107-26-2 40825 E 160f ;食品橙7; β-阿蔔_8,胡蘿蔔素酸(C 30)之乙基 1109-11-1 酯 40850 角黃素；E 161g ;食品橙8 514-78-3 42045 酸性藍1 129-17-9 42051 (2) E 131 ;酸性藍3 ;專利藍v 3536-49-0 42053 FD&C綠色3號；食品綠3 ;固綠FCF 2353-45-9 42080 酸性藍7 3486-30-4 146626.doc -15· 201034700 表la :颜料/色彩之實例(组份(b)) 顏色索引 編號 法定及常用名稱 CAS登記 編號 42090 FD&C藍色1號；酸性藍9(鈉鹽）；食品藍2 ;亮藍 FCF ;專利藍AC 3844-45-9 -DifeC藍色4號，酸性藍9(錢鹽）；α綠(Alphazurine) 7G ;羊毛罌紅(Erioglaucine) 6371-85-3 42100 酸性綠9 4857-81-2 42170 酸性綠22 5863-51-4 42510 驗性紫14 632-99-5 42520 鹼性紫2 3248-91-7 42735 酸性藍104 6505-30-2 44045 驗性藍26 2580-56-5 44090 E142 ;酸性綠50 ;綠色S 3087-16-9 45100 酸性紅52 3520-42-1 45190 酸性紫9 6252-76-2 45220 酸性紅50 5873-16-5 45350 D&C黃色8號；S复性黃73 ;螢光素鈉 518-47-8 45350:1 D&C黃色7號；溶劑黃94 ;螢光素 2321-07-5 45370 (2) 酸性橙11 45370:1 D&C橙色5號；溶劑紅72 ;二溴螢光素 596-03-2 45380 (2) D&C紅色22號；酸性紅87 ;伊紅(Eosin)Y 17372-87-1 45380:2 D&C紅色21號；溶劑紅43 ;四溴螢光素 15086-94-8 45396 溶劑橙16 24545-86-6 45405 酸性紅98 6441-77-6 45410(2) D&C紅色28號；酸性紅92 ;焰紅染料(Phloxine)B 18472-87-2 45410:1 D&C紅色27號；溶劑紅48 ;四溴四氣螢光素 13473-26-2 146626.doc •16- 201034700 Ο Ο 表la :颜牵 夺/色彩之實例(组份(b)) 顏色索引 編號 法定及常用名稱 CAS登記 編號 45425 D&C紅色11號；酸性紅％ ;黃藻紅(Erythr〇sine Yellowish)Na 33239-19-9 45425:1 D&C橙色10號；溶劑紅73 ;二碘螢光素 38577-97-8 45430 (2) E 127; FD&C紅色3號；酸性紅51 ;赤蘚紅；食品紅 14 16423-68-0 47000 D&C黃色11號；溶劑黃33 ;啥琳黃 8003-22-3 47005 D&C黃色10號；E104 ;酸性黃；食品黃13 ;喹啉 黃；金絲雀黃 8004-92-0 50325 酸性紫50 229-951-1 50420 酸性黑2 8005-03-6 51319 顏料紫23 6358-30-1 58000 顏料紅83 ;茜素 72-48-0 59040 D&C綠色8號；溶劑綠7 ;濃縮。比喃素 6358-69-6 60724 分散紫27 - ~ 19286-75-0 60725 D&C备'色2號；溶劑紫13 ;茜粗紛紅紫ss 81-48-1 60730 ExtD&C紫色2號；酸性紫43 4430-18-6 61565 D&C綠色6號；溶劑綠3 ;酿茜綠ss 128-80-3 61570 D&C綠色5號；酸性綠25 4403-90-1 61585 酸性藍80 4474-24-2 62045 酸性藍65 ..... 4368-56-3 69800 E 130;還原藍4 81-77-6 69825 g&C藍號；還原藍6 ;陰丹士林藍(Indanthrene Blue) ’ 卡朋 士林藍 130-20-1 71105 還原撥7 ;顏料撥43 4424-06-0 73000 還原藍1 ;靛藍色 482-89-3 146626.doc -17- 201034700 表la :颜料/色彩之實例(组份(b)) 顏色索引 編號 法定及常用名稱 CAS登記 編號 73015 FD&C藍色2號，E 132，食品藍1 ;散藍；毅藍脑 脂紅 860-22-0 73360 D&C紅色30號；還原紅1 ;赫林頓桃紅(Hdind〇ne Pink)CN 2379-79-0 73385 還原紫2 5462-29-3 73900 顏料紫19 1047-16-1 73915 顏料紅122 16043-40-6 74100 顏料藍16 547-93-6 74160 顏料藍15 147-14-8 74180 直接藍86 1330-38-7 74260 顏料綠7 1328-53-6 75100 天然黃色6 27876-94-4 75120 胭脂樹橙提取物；E 160b ;天然撥色4 1393-63-1 75125 E 160d，番蘇紅素 502-65-8 75130 β-胡蘿蔔素(天然）；E 160a ;天然棕色5 ;天然黃 色26 7235-40-7 75135 E 161d ;天然黃色27 ;玉紅黃質 3763-55-1 73-40-5 75170 鳥糞素；天然白色1 75300 E 1〇〇 ’天然黃色3 ;薑黃(Turmeric Yellow);薑黃 素；印度西紅花(Indian Saffixm) ' *_ — 458-37-7 75470 姻脂蟲提取物；E 120 ;天然紅色4 ;胭脂蟲紅；胭 脂紅；胭脂紅酸 1343-78-8 1390-65-4 1260-17-9 83-72-7 11006-34-1 75480 指甲花 ^ 75810 E 140 & E 141 ;葉綠素；葉綠素與葉綠酸之銅錯合 物；鉀納銅；葉綠酸；天然綠色3 146626.doc -18 · 201034700 表la :颜料/色彩之實例(组份⑻） 顏色索引 編號 法定及常用名稱 CAS登記 編號 7700 鋁粉；E 173 ;顏料金屬1 ;鋁 4729-90-5 77002 礬土；顏料白24 1332-73-6 77004 顏料白19 ;膨潤土 1302-78-9 77007 群青藍；顏料藍29 1317-97-10 群青紅 1345-00-2 群青紫；顏料紫15 12769-96-9 77013 群青綠；顏料綠24 77015 顏料紅101 ;顏料紅102 77019 雲母；顏料白20 12001-26-2 滑石粉；顏料白26 14807-96-9 77120 顏料白21 ;顏料白22 7727-43-7 77163 氯氧化鉍；顏料白14 7787-59-9 77220 碳酸辦；E 170 ;顏料白18 471-34-1 77231 顏料白25 ;硫酸約 7778-18-9 77288 氧化鉻綠；顏料綠17 1308-38-4 77289 氫氧化鉻綠；顏料綠18 ;吉勒特綠（Guignet Green);綠色顏料 12001-99-9 77346 姑藍色，顏料藍28 1345-16-0 77400 77400 青銅粉；紅銅粉；顏料金屬2 7440-50-8 77480 E 175 ;金；顏料金屬3 7740-57-5 146626.doc -19- 201034700 表la :颜料/色彩之實例(组份(b)) 顏色索引 編號 法定及常用名稱 CAS登記 編號 77489 E 172 ;氧化亞鐵 1345-25-1 77491 三氧化二鐵；E 172 ;顏料紅101 & 102 ;顏料棕 6&7 1309-37-1 77492 水合三氧化二鐵；E 172 ;顏料黃42 & 43 ;顏料棕 6&7 20344-49-4 77499 四氧化三鐵；E 172 ;顏料黑11 ;顏料棕6 & 7 1317-61-9 77510 77520 亞鐵氰化鐵；顏料藍27 ;普魯士藍 14038-43-8 77713 碳酸鎂；顏料白18 546-93-0 77742 錳紫；顏料紫16 10101-66-3 77745 磷酸錳 10124-54-6 77820 銀；E 174 7440-22-4 77891 二氧化鈦；E 171 ;顏料白6 13463-67-7 77947 氧化鋅；顏料白4 1317-13-2 酸性紅195 12220-24-5 二硬脂酸鋁 300-92-5 花色素苷；E 163 11029-12-2 甜菜根紅；E 162 89957-89-1 7659-95-2 檸檬酸祕 溴甲酚綠 76-60-8 溴百里酚藍 76-59-5 硬脂酸鈣 1592-23-0 辣椒黃素，辣椒玉紅素；E 160c ;辣椒提取物 465-42-9 E 150 ;天然棕色10 ;焦糖 8028-89-5 146626.doc -20- 201034700 表la :颜料/色彩之實例(组份(b)) 顏色索引 編號 法定及常用名稱 CAS登記 編號 亞鐵氰化鐵銨 25869-00-5 E 101 ;乳黃素；核黃素 83-88-5 乙酸鉛 301-04-2 硬脂酸鎂 557-04-0 硬脂酸鋅 557-05-1 表lb :色澱之結構： 色澱(FDA名稱） CI號 名稱 相應染劑之結構 D&C紅色6號Ba 色澱 15850 顏料紅57鈉鹽 ^V^SOgH D&C紅色7號 15850:1 顏料紅57.1 鈣鹽 ch3 ίΓ^Η c0C〇H D&C紅色21號A1 色澱 45380:2 溶劑紅43 δΓ Pr H〇TsSr° γΎ10 Br人人— u D&C紅色22號A1 色澱 45380 酸性紅87 D&C紅色27號A1 色澱 45410:1 溶劑紅48 mMc 146626.doc -21 - 201034700 表lb :色澱之結構： 色澱(FDA名稱） CI號 名稱 相應染劑之結構 D&C紅色28號A1 色澱 45410 酸性紅92 NaoyyxJyi D&C紅色30號A1 & Talk色澱 73360 還原紅1=顏料 紅181 0 CHi D&C紅色33號A1 &Zr色澱 17200 酸性紅33 D&C黃色10號A1 色澱 47005 食品黃13 H 0 及 ma FD&C黃色5號A1 色澱 19140 酸性黃23 Na鹽 ^丫 S〇aH HOGC FD&C黃色6號A1 色澱 15985 食品黃3Na鹽 |0爿 δ FD&C藍色1號八1 色澱 42090 酸性藍9 146626.doc -22- 201034700 表lc : Calisha 色彩顏料(Ciba): 經處理珍珠 名稱 INCI名稱 Calisha羅曼銀色珍珠OD 雲母及二氧化鈦及鯨蠛基二甲聚矽氧烧 Calisha羅曼魅力紫色OD 雲母及二氧化鈦及録蝶基二甲聚石夕氧烧 Calisha羅曼魅力藍色珍珠OD 雲母及二氧化鈦及鯨壌基二甲聚石夕氧燒 Calisha羅曼魅力綠色OD 雲母及二氧化鈦及錄蝶基二甲聚石夕氧燒 Calisha羅曼金色珍珠OD 雲母及一氧化欽及紅色鐵氧化物及絲壤基二 曱聚矽氧烷 Calisha羅曼青銅色珍珠OD 雲母及紅色鐵氧化物及錄蠛基二甲聚石夕氧烧 Calisha羅曼燈色珍珠OD 雲母及紅色鐵氧化物及鯨蠟基二甲聚石夕氧院 Calisha羅曼紅色珍珠OD 雲母及紅色鐵氧化物及鯨壌基二曱聚石夕氧烧 Calisha現代星光珍珠OD 雲母及二氧化鈦及鯨蟻基二甲聚石夕氧烧 Calisha現代魅力藍色珍珠〇D 雲母及二氧化鈦及鯨蠟基二甲聚石夕氧烷 Calisha現代魅力金色珍珠〇D 雲母及二氧化鈦及綠躐基二甲聚石夕氧烧 Calisha現代魅力紫色OD 雲母及二氧化鈦及鯨蠟基二甲聚石夕氧烷 Calisha現代紫紅色珍珠OD 雲母及紅色鐵氧化物及二氧化鈦及鯨蠟基二 甲聚矽氧烷 Calisha現代褚色珍珠OD 雲母及紅色鐵氧化物及二氧化鈦及鯨蠟基二 曱聚矽氧烷 Calisha現代黑色珍珠OD 雲母及二氧化鈦及黑色鐵氧化物及鯨蠟基二 甲聚矽氧烷 Calisha現代深褐色珍珠〇D 雲母及二氧化鈦及紅色鐵氧化物胭脂紅及鯨 蠟基二甲聚矽氧烷 Calisha現代綠色珍珠OD 雲母及二氧化鈦及紅色鐵氧化物及亞鐵氰化 鐵及鯨蝶基二甲聚矽氧烧 Calisha現代銀色珍珠〇D 雲母及一氧化鈦及錄壤基二曱聚石夕氣烧 146626.doc •23- 201034700 表lc : Calisha 色彩顏料(Ciba): 經處理珍珠 ~~~ Calisha現代魅力綠色OD 雲母及二氧化鈦及二氧化錫及鯨蠟基二曱聚 矽氧烷 Calisha現代金色珍珠OD 雲母及—氧化鈦及紅色鐵氧化物及綠壤基二 甲聚碎氧烷 Calisha現代青銅色珍珠〇D 雲母及紅色鐵氧化物及鯨蠟基二甲聚矽氧烷 Calisha現代玫瑰紅色珍珠〇D 雲母及紅色鐵氧化物及鯨蠟基二甲聚矽氧烷 Calisha藝術裝飾銀色珍珠〇D 雲母及二氧化鈦及鯨蠟基二甲聚矽氧烷 Calisha藝術裝飾魅力紫色〇D 雲母及二氧化鈦及録蟻基二甲聚發氧烧 Calisha藝術裝飾魅力藍色珍 珠OD 雲母及二氧化鈦及鯨蠟基二甲聚矽氧烷 Calisha藝術裝飾魅力綠色〇D 雲母及二氧化鈦及鯨蠟基二甲聚矽氧烷 Calisha藝術裝飾金色珍珠〇D 雲母及紅色鐵氧化物及二氧化鈦及鯨蠟基二 甲聚矽氧烷 Calisha藝術裝飾青銅色珍珠 OD 雲母及紅色鐵氧化物及鯨蠟基二甲聚矽氧烷 Calisha藝術裝飾橙色珍珠OD 雲母及紅色鐵氧化物及鯨蠟基二曱聚矽氧烷 Calisha藝術裝飾紅色珍珠OD 雲母及紅色鐵氧化物及鯨蠟基二甲聚矽氧烷 Calisha羅曼銀色珍珠CL 雲母及二氧化鈦 Calisha羅曼魅力紫色CL 雲母及二氧化鈦 Calisha羅曼魅力藍色珍珠CL 雲母及二氧化鈦 Calisha羅曼魅力綠色CL 雲母及二氧化鈦 Calisha羅曼金色珍珠CL 雲母及二氧化欽及紅色鐵氧化物 Calisha羅曼青銅色珍珠CL 雲母及紅色鐵氧化物 Calisha羅曼橙色珍珠CL 雲母及紅色鐵氧化物 Calisha羅曼紅色珍珠CL 雲母及紅色鐵氧化物 Calisha現代星光珍珠CL 雲母及二氧化鈦 146626.doc • 24 · 201034700
表lc : Calisha 色彩顏料(Ciba): 經處理珍珠 Calisha現代魅力藍色珍珠CL 雲母及二氧化鈦 Calisha現代魅力金色珍珠CL 雲母及二氧化鈦 Calisha現代魅力紫色CL 雲母及二氧化鈦 Calisha現代紫紅色珍珠CL 雲母及紅色鐵氧化物及二氧化鈦 Calisha現代赭色珍珠CL 雲母及紅色鐵氧化物及二氧化鈦 Calisha現代黑色珍珠CL 雲母及二氧化鈦及黑色鐵氧化物 Calisha現代深褐色珍珠CL 雲母及二氧化鈦及紅色鐵氧化物及胭脂紅 Calisha現代綠色珍珠CL 雲母及二氧化鈦紅色鐵氧化物亞鐵氰化鐵 Calisha現代銀色珍珠CL 雲母及二氧化鈦 Calisha現代魅力綠色CL 雲母及二氧化鈦及二氧化錫 ~~ 雲母及二氧化鈦及紅色鐵氧化物 Calisha現代金色珍珠CL Calisha現代青銅色珍珠CL 雲母及紅色鐵氧化物 - Calisha現代玫瑰紅色珍珠CL 雲母及紅色鐵氧化物 -- Calisha藝術裝飾銀色珍珠cl 雲母及二氧化鈦 ~ Calisha藝術裝飾魅力紫色cl 雲母及二氧化鈦 ' — Calisha藝術裝飾魅力藍色珍 珠CL 雲母及二氧化鈦 ~~~ ~- Calisha藝術裝飾魅力綠色珍 珠CL 雲母及二氧化鈦 ~---—'-- Calisha藝術裝飾金色珍珠CL 云母及紅色鐵氧化物及- Calisha藝術裝飾青銅色珍珠 CL 雲母及紅色鐵氧化物 -- Calisha藝術裝飾橙色珍珠CL 雲母及紅色鐵氧化物 -- Calisha藝術裝飾紅色珍珠CL 雲母及紅色鐵氧化物 '一·--- 無機顏料 ~~---—…〜一…—— ^--- 146626.doc -25- 201034700
表lc : Calisha 色彩顏料(Ciba): 經處理珍珠 Calisha現代鮭魚紅色氧化物 紅色鐵氧化物
Calisha現代黑色氧化物 Calisha現代墨黑色氧化物 Calisha現代日光黃色氧化物 Calisha現代黃色氧化物 Calisha現代群青藍 Calisha現代群青紫 Calisha藝術裝飾氫氧化物路 Calisha藝術裝飾氧化物鉻綠 綠 黑色鐵氧化物 黑色鐵氧化物 黃色y氧化物 黃色鐵氧化物 群青藍
色澱 群青紫 氫氧化物鉻綠 氧化物鉻綠
FD&C藍色1號A1色澱 D&C紅色21號A1色澱 D&C紅色27號A1色澱
Calisha藝術裝飾藍色1號色澱 Calisha藝術裝飾紅色21號色澱 Calisha藝術裝飾紅色27號色澱 Calisha藝術裝飾紅色30號AL.色澱 Calisha藝術裝飾紅色3〇號滑石粉 色澱
Calisha藝術裝飾紅色33號色澱 Calisha藝術裝飾紅色4〇號从.色澱 Callsha藝術裝飾紅色6號色殿HD Calisha藝術裝飾紅色7號色澱HD Calisha藝術裝飾黃色5號色澱HP Calisha藝術裝飾黃色6號al.色澱 146626.doc D&C紅色30號A1色澱
D&C紅色33號A1色澱 FD&C紅色40號A1色澱 D&C紅色6號Ba色澱 D&C紅色7號Ca色澱 FD&C黃色5號A1色澱 FD&C黃色6號A1色澱 •26- 201034700 如在本說明中所用干擾顏料係懸浮體顆粒。該等懸浮體 顆粒較佳地具有不大於約5微米之厚度，更佳地，不大於 約2微米’仍更佳地，不大於約以米。該等懸浮體顆粒較 . ㈣具有至少約0.02微米之厚度，更㈣，至少約〇〇5微 #，甚至更佳地’至少約〇. i微米且仍更佳地，至少約0.2 微米。 進而s之’本發明之毛髮染色組合物亦可與氧化染劑系 統組合使用。 〇 最初狀態並非染劑而是染劑前體之氧化染劑按照其化學 特性可分為顯色化合物及偶合化合物。 適宜氧化染劑闡述於（例如） -德國專利DE 19 959 479,具體而言，在第2卷，16 至第3卷，I. 11中； -由 Ch_ Culnan，H· Maibach編輯之「Dermatology」，
Verlag Marcel Dekker公司，New York，Basle, 1986， ◎ 第 7卷，Ch. Zviak，The Science 〇f Hair Care，第 8 章，第264-267頁（氧化染劑）中。 較佳顯色化合物係（例如）在對位或鄰位經經取代或未經 取代羥基或胺基殘基取代之一級芳香族胺、或二胺基n比啶 衍生物、雜環狀腙、4-胺基吼唑衍生物或2,4,5,6_四胺基嘧 D定衍生物。 進而言之，可使用諸如鹽酸鹽或硫酸鹽等呈其生理相容 性酸加成鹽形式之顯色化合物。具有芳香族〇]^基團之顯 色化合物在呈其鹽形式以及鹼（諸如鹼金屬_酚鹽）時亦為適 146626.doc -27- 201034700 宜的。 較佳顯色化合物揭示於德國專利DE 19959479，第？百 I. 8-29中。 乐z貝’ 偶合化合物係間-笨二胺衍生物、萘盼 '間苯二紛 / 酚衍生物、吡唑啉嗣及間-胺基苯酚衍生物，且 最佳地，為揭示於德國專利DE 19959479,第1頁，〗· W至 第3頁，I. u中之偶合化合物。 進。之，可自冑氧化之化合物可與本發明之毛髮染色 組合物組合使用。 μ γ自動氧化化合物係在芳香料中具有兩個以上取代基 之芳香族化合物，其具有極低氧化還原電位且因此在暴露 於空氣中時可經氧化。#助此等化合物所獲得_色很穩定 且具有耐洗髮精性。 可自動氧化化合物係（例如）苯、吲哚、或吲哚，尤其是 5,6-二經基w β朵或5,6_二經基4丨B朵。 本發明之毛髮染色組合物亦可與天然染劑組合使用諸 如紅色指曱花、中性指曱花、黑色指甲花、洋甘菊花、檀 香木、紅余、歐鼠李屬樹皮（Rhamnus frangula bark)、鼠 尾草葉、坎佩切木（campeche wood)、茜草根、兒茶、 sedre及朱草根（alkanet root)。 進而言之’本發明之毛髮染色組合物亦可與加帽重氮化 化合物組合使用。 適宜重氮化化合物係（例如）在WO 2004/019897中之式（1)_ (4)化合物（橋接規（bridging gage)上及二）及在該參考文獻中 146626.doc -28- 201034700 所揭示相應水溶性偶合組份（Ι)_(ιν)。 本發明亦係關於包含太欲 心月毛髮染色組合物 色有機材料（較佳為含角f 了用於杂 配物。 乍儿敢佳為人類毛髮）之調 適當染色介質（或栽齋丨）桶赍 . 執刎）通㊉係由水或水與至少一種有機 溶劑之混合物構成，該右M、> π ν種有機 取衫機$财溶解在水 溶解之化合物。作為有機溶劑， ⑼充刀 異丙醇等Ci-C4低碳數醇、諸 乙醇及 Ο 知堵如苯甲醇等芳香族醇以及1 類似產物及混合物。 啤 1八 較佳地，該等溶劑可以佔半 永巴組合物總重量之大約介於 1重量％與40重量〇/〇間之丨左 、 门之比例存在，且仍更佳地，大約介於 5重量％與3 0重量。/。間之比例存在。 、 較佳地，本發明之毛髮染色組合物可以佔用於處理（較 佳地’染色）有機材料之組合物總重量之〇顧_5重量％ (在 下文中僅以「％」表示)’具體而言，0.005-4。/。，更具體而 〇 言，〇.2_3〇/〇的數量納入該組合物中。 本發明之染色組合物之pH通常大約介於間且較 佳地’大約介於5與10之間。可藉助常用於將角質纖維染 色之酸化劑或鹼化劑將該pH調節至期望值。 該等調配物可以不同的技術形式應用於含角質纖維，較 佳地，應用於人類毛髮。 調配物之 技術形式係（例如）溶液（尤其是增稠水性溶液或 洗髮精、粉末、凝膠、或 含水醇性溶液）、乳膏、泡沫、 乳液 146626.doc -29· 201034700 驾慣上，將該等染色組合物以50_100 g之量施用於含角 質之纖維。 調配物之較佳形式係即用組合物或多組件染色裝置或 「套組」或任一具有若干隔室之多組件封裝系統，如在 (例如）美國專利US 6，190,421，第2卷，L 16至31中所述。 即用染色組合物之pH值通常為自2至u，較佳地，自5至 10 ° 本發明之一個較佳實施例係關於染劑調配物其中本發 月之毛髮染色組合物係呈粉末形式。倘若出現如在（例如） 德國專利DE 197 13 698 ,第2頁，L 26至54及第3頁，j 51 至第4頁，I. 25及第4頁，I. 41至第5頁I· 59中所述穩定性 及/或溶解性問題，則較佳使用粉末調配物。 適宜美容性毛髮護理調配物係毛髮滋養製劑，例如，呈 洗髮精及潤髮乳形式之毛髮洗滌製劑；毛髮護理製劑，例 如，諸如喷劑、乳膏、凝膠、洗劑、慕絲及油、毛髮保養 劑、定型乳膏、定型凝膠、潤發脂、毛髮沖洗劑、發膜 (treatment pack)、深層修護髮膜hair加以咖叫 專預/兹養製劑或免洗產品（leave_〇n pr〇duct);毛髮成型製 劑（hair-structuring preparation)，例如，用於永久性捲髮 之毛髮k捲製劑（熱燙劑、溫和燙劑、冷烫劑）、毛髮拉直 製劑、液體毛髮固型製劑、毛髮定型泡沫（hair f〇ams)、毛 髮定型喷劑（hairspray);漂白製劑，例如，過氧化氫溶 液、淡化色澤之洗髮精、漂白乳膏、漂白粉末、漂白膏糊 或油；暫時性、半永久性或永久性染髮劑、含有自身氧化 146626.doc •30· 201034700 染劑之製劑、或天_髮劑’諸如指甲花或洋甘菊。 對於在人類毛髮j*估田二 > 丄^ 吏用而a，本發明之染色組合物通常 可納"生美谷載劑中。適宜水性美容載劑包括(例 如）勸、o/w、0/w/0、w/〇/w或m乳液及各種各樣的 微滴乳液、乳膏、噴劑、乳液、凝膠、粉末以及含有表面 活性劑之發泡溶液，例如，洗髮精或其他適肢含角質之 纖維的製劑。此等使用形式具體闡述Research Disclosure
Ο 42448 (1999年8月）中。倘若必需，則亦可能將該等染色組 合物納入無水裁密|丨Φ，2 戰* ^甲，如在（例如）美國專利US-3 369 970 ’尤其是第1卷，L 7〇至第3卷，I. 55中所述。本發明 之染色組合物亦特別適用於在德國專利de_a 3 829 87〇中 所述染色方法，使用染色梳或染色刷。 水性載劑成份係以常用數量存於本發明之染色組合物 中，舉例而言，乳化劑可以〇5至3〇重量％之濃度存於該等 染色組合物中且增稠劑係以佔染色組合物總量之0· 1至25 重量％之濃度存在。 染色組合物之其他載劑闡述於（例如）由Ch. Culnan，H.
Maibach編輯之「Dermatology」，Verlag Marcel Dekker公 司 ’ New York，Basie，1986，第 7 卷，ch· Zviak，The Science of Hair Care，第 7章，第 248-250頁，尤其是在第 243 頁，I. 1至第 244 頁，I. 12 中。 本發明之毛髮染色組合物可以膏糊狀製劑（水性或非水 性）或以乾燥粉末形式儲存於液體中。 當染劑及佐劑一起以液體製劑儲存時，該製劑應為實質 146626.doc •31 - 201034700 上無水以便於減少該等化合物反應。 本發明之染色組合物可包含已知可用於此等製劑之任一 活性成份、添加劑或佐劑’如表面活性劑、溶劑、驗、 酸、香料、聚合物佐劑、增稠劑及光穩定劑。 在本發明之毛髮染色組合物中較佳使用下列佐劑：非離 子型聚合物、陽離子麼聚合物、丙烯醯胺/二甲基二烯丙 基氣化錢共聚物、四級銨化聚乙稀醇、兩性離子及兩性聚 合物、陰離子型聚合物、增稠劑、成㈣（她tuHng agent)、毛髮調理化合物、蛋白水解產物芳香油二甲 基異山梨醇及環糊精、增溶劑、去屑活性成份、用於調節 PH值之物質；泛醇、泛酸、尿囊素…比略。定酮曱酸及其 鹽、植物提取物及維他命；膽固醇；光穩定劑及uv吸收 劑、稠度調節冑、脂肪及躐、脂肪烧醇_醯胺、聚乙二醇 及聚丙二醇、錯合劑、膨脹及滲透物質、諸如乳膠等遮光 劑；珠光劑、推進劑、抗氧化劑；含糖聚合物、四級銨 鹽、或抑菌劑。 本發明之染色組合物通常包含至少一種表面活性劑。適 宜表面活性劑係兩性離子或兩性表面活性劑，或更佳為陰 離子型、非離子型及/或陽離子型表面活性劑。 適宜陰離子型表面活性劑之特徵在於陰離子基團可賦予 水溶性，例如，羧酸根、硫酸根、磺酸根或磷酸根基團及 具有大約10個至22個碳原子之親脂性烷基基團。另外，二 醇或聚乙二醇醚基團、酯、醚及醯胺基團以及羥基基團亦 可存於該分子中。 146626.doc -32- 201034700 較佳陰離子型表面活性劑係烷基硫酸鹽、在烷基基團中 具有10個至18個碳原子及在分子中具有至多12個二醇醚基 團之烧基聚乙二醇醚硫酸鹽及鱗叛酸以及（尤其是）飽和及 (尤其是）不飽和Cg-C22叛酸（諸如油酸、硬脂酸、異硬脂酸 及棕櫚酸）之鹽。 兩性表面活性劑係除c8-c18-烷基或-醯基基團外在分子 中含有至少一個游離胺基基團及至少一個_C〇〇H或-S03H 基團並能夠形成内鹽之表面活性化合物。適宜兩性表面活 ❹ 性劑之實例包括N-烷基甘胺酸、N_烷基丙酸、N—烷基胺基 丁酸、N-烷基亞胺基二丙酸、…羥基乙基_N_烷基醢胺基 丙基甘胺酸、N-烷基牛磺酸、N-烷基肌胺酸、2-烷基胺基 丙酸及烧基胺基乙酸，各自在烷基基團中具有大約8個至 1 8個破原子。尤佳兩性表面活性劑係N_椰油烷基胺基丙酸 鹽、椰油醯基胺基乙基胺基丙酸鹽及ci2_Ci8醯基肌胺酸。 適宜非離子型表面活性劑闡述於w〇 〇〇/1〇519中，具體 〇 而° ’第45頁，L 11至第50頁，L 12。非離子型表面活性 «J 3有（例如）多元醇基團、聚伸烷基二醇醚基團或多元醇 與聚二醇醚基團之組合作為親水性基團。 、可用於本發明染色組合物之陽離子型表面活性劑之實例 尤其是四級錄化合物。 烧基醯胺基胺，尤其是脂肪酸醯胺基胺（諸如可以名稱 Tego Amid® 18獲得之硬脂基醯胺基丙基二_曱基胺）亦可作 為較佳表面活性劑存於本發明染色組合物中。該等不僅可 藉由良好調理作用而且亦可(尤其)藉由其良好生物降解性 146626.doc •33· 201034700 來辨別。 尽發明之另一較佳實施例係 色組合物處理含角質之纖維的方法 該方法包含於還原試#丨存在時處理毛髮。 通常，可將該等染多细人榀, 質之纖維。|色，，且口物以50侧代量施用於含角 上文所述氧化劑亦可用七 澤變淡之淡化色澤之組合物。：、過程之别使毛髮色 :二本::月：係關於一種用於同時染色及烫捲角質纖 維之方法，其包含如下步驟 (a)用淡化色澤之組合物處理毛髮， ⑻視情況用還原性捲髮劑處理該毛髮；及 ⑷用本發明之毛髮染色組合物處理該毛髮。 進而言之，此方法亦適用於柔順毛髮。 本’X明之毛髮染色纽合物適用 即，當第-次對毛髮實施染色時)以及用色(亦 或者勵或部分毛髮進行染色(例如；隨後再次染色 毛、體毛及/或鬍鬚之染色）。’、 於眉毛、睫 可藉由⑽如)用手、梳、刷、或 合之瓶按摩來將本發明之毛 /、梳或… 在本發明之染色過程中，染色是否：、施：於毛髮。 實施可視擬獲得的色彩明暗而定。疋於另—染劍存在時 其他較佳者係用於染色含角質纖 發明之毛髮染色組合物}其包含用本 及氧化劑處理該含角質纖维。 146626.doc -34- 201034700 pH:::色：程通常涉及淡化色澤’亦即，其涉及在驗性 物，使二質之纖維施用鹼與水性過氧化氫溶液之混合 :髮=::::=髮上且隨後沖洗毛髮。尤其在 可使”、、色素淡化並使毛髮受到染色。 八鐘般’使含有氧化劑之組合物在纖維上保留〇至15 刀:，具體而言，在15t至45t:下保留0至5分鐘，其數量 Ο 〇 化例如)過硫酸鹽或經稀釋過氧化氫溶液、過氧 化if諸如脲過氧广氫凝缪、驗土金屬過氧化物、有機過氧 於半jc久性首過减物、三聚氰胺過氧化物）或偶若使用基 叮/ ,直接毛髮染劑之修容餅（如〜州如），則亦 可鈿用鹼金屬溴酸鹽固色劑。 最二氧化劑係過氧化氮’以佔相應組合物之 2重”。至30重量％，更佳地，約3重量%至2〇重量%及最佳 地，6重量％至12重量％之濃度使用。 該等氧化劑可以佔染色組合物總量之較佳地，自請％ =，尤其是自0.01%至1%之量存於本發明染色组合物。 一般而言，於鹼(例如，氨、鹼金屬碳酸鹽、鹼土金屬 (鉀或鐘）碳酸鹽、諸如單乙醇胺、二乙醇胺或三乙醇 烧醇胺、驗金屬(納)氫氧化物、驗土金屬氫氧化物 之化合物）存在時用氧化劑實施染色， 八 % Λ 其中 ,N—R—Ν 146626.doc -35- «6 201034700 R係伸丙基殘基，其可經OH或Cl-C4烧基取代，
Rs R4尺5及尺6彼此獨立地或彼此依賴地為氫、（^-(^烷 基或羥基-(CVC4)烷基。 3有氧化劑之組合物之pH值通常為約2至7且具體而言， 係約2至5。 將包3本發明毛髮染色組合物之調配物施用於含角質纖 維（較佳地，係毛髮）上之一個較佳方法係藉由使用多組件 染色裝置或「套組」或任一其他多組件封裝系統來實現， 如在（例如）WO 97/20545，第4頁，19至j 27中所述。 下列實例用於闡明該等染色方法而非對該等方法加以限 制。除非另外指明，否則份數及百分比均以重量計。所指 定染劑數量係相對於被著色材料而言。 應用實例： 鹼性藍色丨24與鹼性紅色51、鹼性黃色87及鹼性橙色31 及四級錢鹽之組合用於染色毛髮 為了確定耐洗滌性，在相同條件下對兩組毛髮束實施染 色。用市售洗髮精（GOLDWELL definiti〇n c〇i〇r &
Highlights，色彩調理洗髮精）洗滌—組經染色毛髮，對每 束處於自來水（水溫度：37°C+/- lt ;流速l/min)中之 毛髮使用大約0.5 g洗髮精。最後，將該等毛髮束用自來水 沖洗，用紙巾壓緊、梳理並用毛髮乾燥器乾燥或在室溫下 乾燥。將此程序重複10次。 隨後按照由 Herbst&Hunger 編寫之 Industriai 〇rganic Pigment，第 2版，第 61 頁，Nr 10: DIN 54 〇〇l8i982. 146626.doc -36- 201034700 「Herstellung und Bewertung der Anderung der Farbe」， ISO 105-A02-1993使用灰色標度（Grey Scale)評定經洗滌髮 束組相對於未經洗滌髮束組之色彩損失。 實例1 : 將一種含有下列之潤髮乳 成份 w/w% 錄壤醇 3.00% 鯨蝶硬脂醇聚醚-25 0.50% 二硬脂基二甲基氯化銨 1.00% 四級銨-80 0.50% 檸檬酸 補足至pH=5 鹼性藍124 0.025 鹼性黃87 0.060 鹼性橙31 0.010 驗性紅51 0.015 香料；防腐劑 適量 水 補足至100% 施用於一束經洗髮精洗滌之正金黃色及灰色毛髮。在15 min後，將該髮束沖洗並乾燥。 將該髮束染成具有良好灰色覆蓋度之棕色。 實例2 : 將一種含有下列之潤髮乳 成份 w/w% 録蝶醇 3.00% 146626.doc -37- 201034700 鯨蠟硬脂醇聚醚-20 0.50% 羥丙基瓜爾膠，羥丙基三甲基氯化銨 1.00% 四級銨-80 0.50% 檸檬酸 補足至pH=5 氰雙苯丙烯酸辛酯 0.1 丁基甲氧基聯苯曱醯基甲烷 0.1 香料；防腐劑 適量 鹼性藍124 0.1 鹼性橙31 0.1 水 補足至100% 施用於一束經洗髮精洗滌之金黃色毛髮。在5 min後， 將該髮束沖洗並乾燥。該發束染成棕色。 實例3 : 將一種含有0.1 %下列成份之潤髮乳 成份 w/w% 録蝶硬脂醇，録堪硬脂基硫酸鈉 3.00% 鯨蠛硬脂醇聚醚-25 0.50% 二硬脂醯基乙基二氣化銨 1.00% 四級錄-80 0.50% 檸檬酸 補足至pH=5 甲基硫酸樟腦苯曱烷胺 0.1 水楊酸乙酯 0.1 鹼性藍124 0.5 驗性紅51 0.5 香料；防腐劑 適量 水 補足至100% 146626.doc -38- 201034700 施用於一束經洗髮精洗滌之金黃色毛髮。在5 min後， 將該髮束沖洗並乾燥。該發束染成紫色。 實例4 : 將一種含有下列之潤髮乳 成份 w/w% 鯨蠟醇 3.00% 鯨蝶硬脂醇聚醚-25 0.50% 山薔基三曱基氯化銨 1.00% 聚四級銨-10 0.50% 檸檬酸 補足至pH=5 二甲聚矽氧烷 0.9 苯基三曱基聚矽氧，聚矽氧四級銨-15，月桂醇聚醚-4 (Polysil 1849) 2.5 聚矽氧-15 0.8 鹼性藍124 0.1 鹼性藍151 0.1 鹼性黃87 0.4 香料；防腐劑 適量 水 補足至100% 施用於一束經洗髮精洗滌之經漂白毛髮。在5 min後， 將該髮束沖洗並乾燥。該髮束染成綠色。 實例5 : 將一種含有下列之潤髮乳 成份 w/w% 録壤醇 3.00% 146626.doc -39- 201034700 鯨蝶硬脂醇聚醚-25 0.50% 山备基三曱基氯化敍 1.00% 聚四級1安-10 0.50% 檸檬酸 補足至pH=5 二曱聚矽氧烷 0.9 苯基三曱基聚矽氧，聚矽氧四級銨-15，月桂醇聚醚-4 (Polysil 1849) 2.5 聚矽氧-15 0.8 鹼性藍124 0.1 鹼性藍151 0.1 鹼性黃87 0.4 香料；防腐劑 適量 水 補足至100% 施用於一束經洗髮精洗滌之經漂白毛髮。在5 min後， 將該髮束沖洗並乾燥。該髮束染成綠色。 實例6 : 將一種含有下列之染色乳液（pH=6.4) 0.05%染劑鹼性藍色124 0.1 5°/(•鹼性藍色99 0.07%鹼性棕色17 0.04%鹼性黃色57 0.15%鹼性棕色16 0.01 %鹼性紅色76 0.01 %鹼性紅色51
0.01°/。HC紅色 BN 146626.doc •40- 201034700 0.01% HC紅色 3 0.01% 3-硝基-對-羥基乙基胺基苯酚 0.05% HC藍色 2 3 · 5 %細增1硬脂酵 1.5%指甲花 10.5%核桃 1.0%鯨蠟硬脂醇聚醚30 0.5%乙二醇二硬脂酸酯 3.0%硬脂醯胺DEA 1.0%油基兩性經丙基績酸鈉 0.5 %聚四級銨-1 〇 〇·1% Tinovis CD (二甲基丙烯醯胺/乙基三甲基氯化銨曱 基丙烯酸酯共聚物’丙二醇二辛酸酯/二癸酸酯，PPG4 + 二烧醇聚謎-6 ’ C10-11異鏈烧烴） 0.5%胺基丙基二甲聚矽氧烧 水補足至100% 在室溫下施用於經漂白人類毛髮3 〇分鐘並沖洗。結果係 具有良好牢度之泛紅棕色染色。 實例7 : 將一種含有下列之染色乳液（ρΗ=6·4) 0.05%染劑鹼性藍色124 〇·15%鹼性藍色99 0.07%鹼性棕色17 0.04%鹼性黃色57 146626.doc -41 - 201034700 0.15%鹼性棕色16 0.01%鹼性紅色76 0.01 %鹼性紅色51 0.01% HC紅色 BN 0.01% HC紅色 3 0.01% 3-硝基-對-羥基乙基胺基苯酚 0.05% HC藍色 2 0.01 %鹼性藍色26 0.01%鹼性藍色75 3.5%鯨蠟硬脂醇 1.5%指甲花 10.5%核桃 1.0%鯨蠟硬脂醇聚醚30 0.5%乙二醇二硬脂酸酯 3.0%硬脂醯胺DEA 1.0%油基兩性羥丙基磺酸鈉 0.5°/。聚四級銨-10 0.1% Tinovis CD (二曱基丙烯醢胺/乙基三甲基氣化銨曱 基丙烯酸酯共聚物，丙二醇二辛酸酯/二癸酸酯，PPG-1 十三烷醇聚醚-6，Cl0-11異鏈烷烴） 0.5%胺基丙基二甲聚矽氧烷 水補足至100% 在室溫下施用於經漂白人類毛髮30分鐘並沖洗。結果係 具有良好牢度之泛紅棕色染色。 146626.doc -42-
Claims (1)
- 201034700 七、申請專利範圍： 1· 一種毛髮染色組合物，其包含 (a)具有下式之染劑 Ο(b)至少一種選自以下各式化合物之染劑 R其中 D 係具有式（2a)之重氮組份之基團 Ο K 係選自苯胺衍生物、苯酚衍生物之偶合組份之基 團’及雜ί哀狀偶合組份之基團； X 係; -s-;或-n(r8)_ ; Y 係 _CH= ; -Cr15=;或_心； Rl、汉2、R3及R4彼此獨立地為氫；4Cl-c4烷基； Κδ 及R6彼此獨立地為氫；CVC4烷基；或（^-(：4烷氧 基； R? 及R9彼此獨立地為未經取代CVC4烷基或經OH-、 Ci-C4烧氧基_、鹵素-、胺基-、c^-CV單或-二烧基 胺基•取代之Ci-C^烷基； 146626.doc 201034700 Rs係氫；或（^-〇:4烷基； Rio係氫；CVC4烷基；或CN ; R11 係未經取代烷基或經OH-或CN-取代之 烧基； Ri2係氫；*CVC4烷基； Rn 及Ri4彼此獨立地為氫；CVC4烷基；或C1-C4烷氧 基；或 Rl3及R"與其所連接氮及碳原子一起形成5-或6-員 環； RlS係氫；或Ci-C4烷基；且 Αηΐ·係無色陰離子；及 (C) (Cl) 選自下列之四級錢鹽： 具有下式之四級銨鹽 (4);其中 Ri6及R19彼此獨立地為飽和或不飽和、直鏈或具支鍵 脂肪族CVCm烷基；或烷氧基、烷氧基羰基烷基、 聚氧基伸烷基、烷基醯胺基、烷基醯胺基烷基、 羥基烷基；包含約12個至約3〇個碳原子之芳香族 芳基或烷基芳基基團，其中R16、R17、R18&R19* 之至少一個基團表示包含8個至30個碳原子之基 團； An 係選自包含函離子、磷酸根、乙酸根、乳酸根及 烧基硫酸根之群組的陰離子； 146626.doc 201034700 (ο)具有下式之咪唑鐺鹽，其中 R20係衍生自牛脂脂肪酸之c 13-C3l 院基或 cl3_c3i 烯 〇3)具有下式之四級二銨鹽R21 係 c6-c31 烷基； 、R23、r24、r25及r26係選自氫；或Ci_c4燒基；且 Αη3·係選自_離子、 子0 乙酸根、磷酸根及硫酸根之陰離 2. 如請求項1之組合物’其中在組份⑷之式⑴中，r R2、R3及R4彼此獨立地為氫；或Ci_C2烷基。 3. 如請求項1或2之組合物，其中組份（a)對應於下式4. 如請求項1至3中任一項之組合物，其中 R« 係氫；或CVC4烷基。 5. 如請求項1至4中任一項之組合物’其中在式（2a)中 R? 及尺9彼此獨立地為烷基。 6. 如請求項丨至5中任一項之組合物，其中在式（2a)中 146626.doc 201034700 X 係-NH ;且 Y 係-CH=。 7·如請求項1至6中任一項之組合物，其中在式（2)中 Κ 係具有式（2b) 之基團；其中 R27係氫；羥基；CVC4烷基；CVC4烷氧基； 單-CrC4烷基胺基；或二_Ci_c4烷基胺基。 8.如請求項1至7中任一項之組合物，其包含 (a) 具有式（1)之染劑， (b) 至少一種選自以下各式化合物之染劑(c)如靖求項1所定義之四級銨鹽。 9. 如請求項1至8 Φ /工 = 中任一項之組合物，其包含選自下 色劑作為額外組份 (d) 直接染劑； (e) 氧化染劑； (f) 二硫化物染劑； (8) 顏料； 或其混合物。 146626.doc 201034700 1U. 一種 —-^ 八-π 1 之染色組合物施用於該等角質纖維。 η· 一種用於將角質纖維染色之方法，其包含如下步驟 (a) 用淡化色澤之組合物處理毛髮， (b) 視情況用還原性捲髮劑處理該 (c) 用如諳灰：^ , 及 至9中任一項之毛髮汍 該毛髮。 发木色組合物處理〇 I46626.doc 201034700 四、指定代表圖： (一) 本案指定代表圖為：（無） (二) 本代表圖之元件符號簡單說明： 五、本案若有化學式時，請揭示最能顯示發明特徵的化學式：146626.doc -4-
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| CN (1) | CN102333515B (zh) |
| BR (1) | BRPI1007997B1 (zh) |
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| MX2011008687A (es) * | 2009-02-25 | 2011-09-06 | Basf Se | Composicion de tinte de cabello. |
| GB201205900D0 (en) | 2012-04-02 | 2012-05-16 | Perachem Ltd | Hair treatment methods |
| GB201205911D0 (en) | 2012-04-02 | 2012-05-16 | Perachem Ltd | Hair treatment method |
| DE102015203002A1 (de) * | 2015-02-19 | 2016-08-25 | Henkel Ag & Co. Kgaa | Färbemittel für keratinische Fasern enthaltend eine Kombination aus drei Farbstoffen |
| FR3045346B1 (fr) | 2015-12-21 | 2019-08-30 | L'oreal | Composition de coloration comprenant un colorant direct de structure triarylmethane, et une silicone |
| ITUA20164246A1 (it) * | 2016-06-09 | 2017-12-09 | Beauty & Business S P A | Composizione per colorare capelli |
| FR3060994B1 (fr) | 2016-12-22 | 2020-10-02 | Oreal | Procede de coloration des fibres keratiniques mettant en oeuvre au moins un colorant azinium particulier et au moins un colorant fluorescent |
| JP6781900B2 (ja) * | 2016-12-27 | 2020-11-11 | ホーユー株式会社 | 毛髪処理剤組成物 |
| CN109562047B (zh) * | 2017-03-29 | 2021-12-14 | 株式会社漫丹 | 染发料组合物 |
| CN113660925A (zh) * | 2019-04-04 | 2021-11-16 | 花王株式会社 | 毛发化妆品 |
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| GB880798A (en) | 1959-08-20 | 1961-10-25 | Unilever Ltd | Compositions for dyeing human hair |
| GB1249438A (en) | 1970-04-14 | 1971-10-13 | Gillette Industries Ltd | 3,7-diaminophenoxazinium salts |
| CH678679B5 (zh) * | 1987-09-05 | 1992-04-30 | Sandoz Ag | |
| JPH07119367B2 (ja) | 1987-11-24 | 1995-12-20 | 株式会社日本化学工業所 | カチオン性染料 |
| DE3829870A1 (de) | 1988-09-02 | 1989-04-13 | Henkel Kgaa | Farbstoffloesungen fuer die haarfaerbung |
| TW311089B (zh) * | 1993-07-05 | 1997-07-21 | Ciba Sc Holding Ag | |
| TW325998B (en) | 1993-11-30 | 1998-02-01 | Ciba Sc Holding Ag | Dyeing keratin-containing fibers |
| EP0714954B1 (de) | 1994-11-03 | 2002-09-25 | Ciba SC Holding AG | Kationische Imidazolazofarbstoffe |
| FR2741798B1 (fr) | 1995-12-01 | 1998-01-09 | Oreal | Composition de teinture eclaircissante pour fibres keratiniques comprenant un colorant direct specifique |
| CA2252499A1 (fr) | 1996-04-25 | 1997-10-30 | L'oreal | Procede de teinture des fibres keratiniques avec des precurseurs de colorants d'oxydation et des colorants directs en poudre |
| DE19713698C1 (de) | 1997-04-03 | 1998-06-04 | Goldwell Gmbh | Verfahren zum gleichzeitigen Färben und Dauerwellen von menschlichen Haaren |
| FR2782451B1 (fr) * | 1998-08-19 | 2004-04-09 | Oreal | Composition de teinture pour fibres keratiniques avec un colorant direct cationique et un sel d'ammonium quaternaire |
| FR2782452B1 (fr) | 1998-08-24 | 2001-11-16 | Oreal | Composition de teinture pour fibres keratiniques avec un colorant direct cationique et un agent teniso-actif non-ionique |
| DE19959479A1 (de) | 1999-12-10 | 2001-07-05 | Wella Ag | Verfahren zum Färben von Haaren |
| JP2002220329A (ja) * | 2001-01-25 | 2002-08-09 | Hoyu Co Ltd | 染毛剤組成物 |
| DE10144881A1 (de) * | 2001-09-12 | 2003-03-27 | Wella Ag | Mittel zur Färbung von Keratinfasern |
| AU2003258664A1 (en) | 2002-09-02 | 2004-03-19 | Ciba Specialty Chemicals Holding Inc. | Method of colouring porous material |
| BRPI0508391B1 (pt) | 2004-04-08 | 2017-10-10 | Ciba Specialty Chemicals Holding Inc | Method of dyeing fibers containing keratin, and composition |
| DE102005013488A1 (de) * | 2005-03-21 | 2006-09-28 | Henkel Kgaa | Mittel zum gleichzeitigen Färben und Aufhellen von keratinhaltigen Fasern |
| MX2011008687A (es) * | 2009-02-25 | 2011-09-06 | Basf Se | Composicion de tinte de cabello. |
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| WO2010097339A3 (en) | 2010-11-11 |
| EP2400947A2 (en) | 2012-01-04 |
| BRPI1007997A2 (pt) | 2016-03-01 |
| JP2012518615A (ja) | 2012-08-16 |
| JP5988586B2 (ja) | 2016-09-07 |
| JP2015017109A (ja) | 2015-01-29 |
| WO2010097339A2 (en) | 2010-09-02 |
| JP2017075157A (ja) | 2017-04-20 |
| JP6347822B2 (ja) | 2018-06-27 |
| US8257448B2 (en) | 2012-09-04 |
| KR101322111B1 (ko) | 2013-10-29 |
| BRPI1007997B1 (pt) | 2018-05-29 |
| US20120012128A1 (en) | 2012-01-19 |
| EP3459520A1 (en) | 2019-03-27 |
| KR20110120345A (ko) | 2011-11-03 |
| CN102333515A (zh) | 2012-01-25 |
| CN102333515B (zh) | 2015-11-25 |
| MX2011008687A (es) | 2011-09-06 |
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