201024251 九、發明說明： 【發明所屬之技術領域】 本發明係關於一種無機聚合物及其製法，且特別是有 關於一種防水無機聚合物及其製法。 【先前技術】 無機聚合物（geopolymer)為一種非晶質（amorph〇us)或 • 半晶質（semi_crystalline)材料，具有優良之物理及化學性 質，例如良好的防火性質、抗化學性質、成型時間短、低 馮製備、低C〇2排放等。無機聚合物可應用於建築材料以 及結構工程，極具發展潛力，有機會取代水泥混凝土而成 為建築材料及結構工程之原料。 然而，無機聚合物為多孔性材料，易受到物理作用而 產生縮放。空氣中之濕氣或鹽分可能會入侵無機聚合物， 造成無機聚合物之白華現象。再者，入侵之濕氣亦會造成 内部建材，如鋼筋等產生材質劣化及腐蝕等問題。 因此，具有防水性的無機聚合物可協助業界在建築材 料上，亟需具有防水性質的無機聚合物及其製法。 【發明内容】 本發明提供-種防水無麟合物_成方法，包括提供驗 t石夕酸質改質溶液’以及將㈣酸鹽礦物加至驗性魏質改質 心液中，⑽獅水無機聚合物，其幅魏_物與驗性梦 5 201024251 酸質改質溶液之重量比值為約G.5〜L5之間。 本發S實施例之防水無機聚合物，包括無機聚合物，其包 礦物，且無機聚合物之内部包括複數個第-孔隙， 料、物之表面包括複數個第二孔隙’以及矽酸質防水材 枓，大抵填滿第一孔隙及第二孔隙。 為讓本發明之上述和其他目的、特徵、和優點能更明 顯易懂’下域舉出較㈣施例，並配合所關式，作詳 細說明如下： 【實施方式】 本發明實施例將驗性矽酸質改質溶液導入無機聚合物 之前驅物中，以進行無機聚合物的聚合反應。透過導入鹼 性發酸質改質溶液’可使所形成之無機聚合物具有較低之 孔隙率’而增進無機聚合物的防水性質。 本發明實施例之防水無機聚合物的形成方法包括將鋁 矽酸鹽礦物加至鹼性矽酸質改質溶液中而形成。適合本發 月之紹發酸鹽礦物包括任何可於驗性溶液中溶出梦離子或 銘離子之礦物、固體、或廢棄物。於驗性溶液中所溶出之 包含矽離子及/或鋁離子之膠體顆粒之間，可產生架橋作 用。經脫水乾燥後’可形成具強度之無機聚合物。適合本 發明之鋁矽酸鹽礦物例如有高嶺土、變高嶺土、膨潤土、 燃煤灰渣、煉鋼爐渣、骨材、砂、或前述之組合。其中， 變高嶺土可經由焙燒高嶺土而獲得，焙燒溫度介於約650 6 201024251 °C〜800°C之間，較佳為約700°C。變高嶺土表面之矽及鋁 在鹼性環境下，將更容易析出以提供無機聚合物聚合所需 之膠體。 本發明實施例添加的鹼性溶液可將鋁矽酸鹽礦物中之 矽離子及鋁離子溶出，且矽酸質改質劑與之共聚合而形成 防水無機聚合物。在一實施例中，鋁矽酸鹽礦物與鹼性矽 酸質改質溶液之重量比值為約1.0〜2.0之間。在另一實施例 中，鋁矽酸鹽礦物與鹼性矽酸質改質溶液之重量比值為約 ❹ 0.8〜1.5之間。在又一實施例中，鋁矽酸鹽礦物與驗性矽酸 質改質溶液之重量比值為約1.2〜1.8之間。本發明實施例之 鹼性矽酸質改質溶液包括將矽酸質改質劑加入鹼性溶液中 而得。 適合本發明之矽酸質改質劑包括有機矽改質劑，例如 曱基矽醇鹽、矽樹脂、矽烷、有機矽乳液、或前述之組合。 在一實施例中，矽酸質改質劑與鋁矽酸鹽礦物之重量比值 為約0.02〜0.2之間。在另一實施例中，矽酸質改質劑與鋁 ® 矽酸鹽礦物之重量比值為約0.04〜0.1之間。在又一實施例 中，矽酸質改質劑與鋁矽酸鹽礦物之重量比值為約 0.05〜0.08之間。 適合本發明之鹼性溶液包括氳氧化鈉、氫氧化鉀等水 溶液、或前述之組合。在一實施例中，驗性溶液之氫氧化 鈉或氫氧化鉀的濃度介於約0.1N〜10N之間。在另一實施 例中，鹼性溶液之氫氧化鈉或氫氧化鉀的濃度介於約 0.5N〜5N之間。在又一實施例中，驗性溶液之氫氧化鈉或 7 201024251 氫氧化鉀的濃度介於約IN〜3N之間。 在一實施例中，更包括添加矽酸鹽於鹼性矽酸質改 中。矽酸鹽可提供足夠的離子以促進膠體之間的膠結。劑 矽酸鹽包括矽酸鈉、矽酸鉀、或前述之組合。在一實施铷σ的 矽酸鹽與鹼性溶液之Si〇2/M2〇模數比值為〇 75〜1〇，其中， 鈉或钟。在另一實施例中，SiOyMe模數比值為i 〇〜i^ = 又-實施财，魏鹽與驗性溶液之Si(VM2G模數比= 1.25〜1.5 °其巾’ Si02/M20模數中之m2〇若以叫〇為; 指石夕酸齡液㈣的莫耳濃度/魏鈉錄巾氧 性= 液中納的莫耳濃度(㈣的莫耳紐：㈣納溶液中 耳濃度+鹼性溶液中鈉的莫耳濃度)之比值。 、 在一實施例中，進-步將紹料鹽礦物及驗性錢 改質溶液之混合液加人模具巾，並且例如於約呢〜 之間靜置養護成型。料’亦可對_酸㈣物及驗性妙 酸質改質溶液之混合液進行震錄氣，例如可使用機械震 盪裔。經震i除氣後，可維持膠體之均勻性及結構完整性。 本發明實施例之防水無機聚合物包括㈣酸鹽礦物， 且具有複數個第-孔隙於防水無機聚合物中以及且有複 數個第二孔隙於防水無機聚合物之表面。其中，第二孔隙 及第二孔隙大抵财質防水材料填滿。㈣防水材料由紹 雜鹽礦物鱗性錢質改質溶液反應而得。本發明實施 例之防^無合物由於係經由㈣酸鹽礦物與驗性械 液共聚σ而成’矽酸質防水材料可大抵填滿無機 聚合物中之孔隙，可有效避免水氣進人無機聚合物。在一 201024251 實施例中’防水無機聚合物浸泡於水中24小時之吸水量與 一般無機聚合物浸泡於水中24小時之吸水量的重量比值 小於0· 1。在—實施例中’防水無機聚合物與水滴之間的接 觸角大於約75。，具有高疏水性。在一實施例中，防水無 機聚合物之強度大於約550kgf/cm2。在一實施例中，防水 無機聚合物之強度為不包括矽質防水材料之無機聚合物的 約 120%。 ❹ 以下’因不同的實施例其流程大致相同’配比的改變 為主要參數，故列舉測試結果較佳之實施例以進一步說明 本發明之實施方式故。本發明實施例之防水無機聚合物的 形成方法流程圖例如第1圖所示。 【實施例】 實施例1 將回嶺土(kaolinite)置於700X：的高溫爐中焙燒。持溫 3小時以使高嶺土脫羥而轉變成非晶質之變高嶺土。變高 _ 嶺土將作為鋁矽酸鹽礦物之來源。 接著’製備驗性矽酸質改質溶液。將856ml，4N之NaOH 溶液及6052克之矽酸鈉均勻調合成Si02/M20比為1.25的 聚合前驅物，取出前驅物720克再加入80克之矽酸質改質 劑均勻混合以形成鹼性矽酸質改質溶液。 接著’將800克的變高廣土加入8〇〇克之驗性梦酸質 改質溶液’並機械攪拌15分鐘。攪拌後將混合液注入模具 中，並震盪10分鐘。最後，封模並於常溫下養護。膠體硬 化成形後脫模，並進行CNS3763(類號A2047)測試與疏水 9 201024251 性測試。其中，疏水性之測試是以水滴滴於無機聚合物之 表面，並量測水滴與無機聚合物表面之間的接觸角。測試 結果以表一整理如下： 表一 測試項目 品質規定 試驗結果 凝結時間 初凝在1小時以後，終凝 在10小時以内 2-5小時 安定性 不得發生膨脹龜裂或變形 無膨脹龜裂或變形 強度比 強度試驗所得掺和有改質 劑者與未掺和者之試體強 度比應達85%以上。 有摻者為：516(kgf/cm2) 無摻者為：417(kgf/cm2) 試體強度比為123% 吸水比 掺和改質劑無機聚合物之 吸水量（g)/未捧和改質劑 無機聚合物之吸水量（g) 1小時=0.28 5小時=0.19 24 小時=0.09 疏水性 液滴與試體表面呈現的接 觸角可大於75度 79度 實驗結果顯示本發明實施例之防水無機聚合物可通過 CNS3763(類號A2047)測試，且其強度還較一般無機聚合物 高。本發明實施例之防水無機聚合物與水滴之接觸角高達 79 °，顯示其具有優良的疏水性。 以下，列舉本發明其他實施例的製備過程及其測試結 果。 實施例2 將高嶺土(kaolinite)置於700°C的高溫爐中焙燒。持溫 10 201024251 3小時以使高嶺土脫羥而轉變成非晶質之變 UJ 1 5貝。戀冥 領土將作為鋁矽酸鹽礦物之來源。 β 接著調整不同比例之矽酸質改質劑製備鹼性矽酸 質溶液。將856ml，4Ν之NaOH溶液、6052充夕故 ? 几〈♦酸納、 及20克之石夕酸質改質劑均勻混合以形成鹼性矽酸質改質201024251 IX. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to an inorganic polymer and a process for the preparation thereof, and more particularly to a water-repellent inorganic polymer and a process for the preparation thereof. [Prior Art] A geopolymer is an amorphous (amorphous) or semi-crystalline material with excellent physical and chemical properties such as good fire resistance, chemical resistance, and molding time. Short, low von preparation, low C〇2 emissions, etc. Inorganic polymers can be applied to building materials and structural engineering, and have great potential for development. They have the opportunity to replace cement concrete as a raw material for building materials and structural engineering. However, inorganic polymers are porous materials that are susceptible to physical effects and scale. Moisture or salt in the air may invade the inorganic polymer, causing the whiteness of the inorganic polymer. In addition, the intrusion of moisture can also cause problems such as deterioration of materials and corrosion of internal building materials such as steel bars. Therefore, the water-repellent inorganic polymer can assist the industry in the construction of materials, and it is desirable to have an inorganic polymer having a waterproof property and a process for producing the same. SUMMARY OF THE INVENTION The present invention provides a method for producing a water-repellent non-laminar compound, which comprises providing a tau-acid modified solution, and adding a (tetra) acid salt mineral to an artificial Wei quality-modified heart liquid, (10) lion The water-inorganic polymer, the weight ratio of the acid-like modified solution is between about G.5 and L5. The water-repellent inorganic polymer of the embodiment of the present invention comprises an inorganic polymer, which comprises a mineral, and the interior of the inorganic polymer comprises a plurality of first pores, the surface of the material comprises a plurality of second pores, and the tannin is waterproof. The material is filled with the first pore and the second pore. The above and other objects, features, and advantages of the present invention will become more apparent and <RTIgt; </ RTI> <RTIgt; </ RTI> </ RTI> <RTIgt; The bismuth citrate modification solution is introduced into the precursor of the inorganic polymer to carry out polymerization of the inorganic polymer. The water-repellent property of the inorganic polymer is enhanced by introducing a basic acid-based acid-modifying solution 'to make the formed inorganic polymer have a lower porosity'. The method for forming a water-repellent inorganic polymer according to an embodiment of the present invention comprises forming an aluminosilicate mineral by adding it to an alkaline tantalate-based reforming solution. The soda acid minerals suitable for this month include any minerals, solids, or wastes that can dissolve Dream Ion or Ming ions in an intestine solution. Bridging between the colloidal particles containing cerium ions and/or aluminum ions dissolved in the test solution can occur. After dehydration drying, an inorganic polymer having strength can be formed. Aluminosilicate minerals suitable for the present invention are, for example, kaolin, metakaolin, bentonite, coal ash slag, steelmaking slag, aggregate, sand, or a combination thereof. Among them, metakaolin can be obtained by calcining kaolin, and the calcination temperature is between about 650 6 201024251 ° C to 800 ° C, preferably about 700 ° C. The surface of the kaolinite and the aluminum are more likely to precipitate in an alkaline environment to provide the colloid required for the polymerization of the inorganic polymer. The alkaline solution added in the embodiment of the present invention can dissolve the cerium ions and aluminum ions in the aluminosilicate mineral, and the ceric acid modifying agent is copolymerized therewith to form a water-repellent inorganic polymer. In one embodiment, the weight ratio of the aluminosilicate mineral to the alkaline phthalate modifying solution is between about 1.0 and 2.0. In another embodiment, the weight ratio of the aluminosilicate mineral to the alkaline phthalate modifying solution is between about 0.8 and 1.5. In yet another embodiment, the weight ratio of the aluminosilicate mineral to the anatifying tannin modification solution is between about 1.2 and about 1.8. The alkaline phthalate modification solution of the embodiment of the present invention comprises the addition of a phthalic acid modifier to an alkaline solution. The bismuth acid modifier suitable for the present invention includes an organic hydrazine modifying agent such as a mercapto decyl alkoxide, an anthracene resin, a decane, an organic hydrazine emulsion, or a combination thereof. In one embodiment, the weight ratio of the phthalic acid modifier to the aluminosilicate mineral is between about 0.02 and about 0.2. In another embodiment, the weight ratio of the phthalic acid modifier to the aluminum silicate mineral is between about 0.04 and about 0.1. In still another embodiment, the weight ratio of the phthalic acid modifier to the aluminosilicate mineral is between about 0.05 and 0.08. The alkaline solution suitable for the present invention includes an aqueous solution of sodium hydride, potassium hydroxide or the like, or a combination thereof. In one embodiment, the concentration of sodium hydroxide or potassium hydroxide in the test solution is between about 0.1 N and 10 N. In another embodiment, the concentration of sodium hydroxide or potassium hydroxide in the alkaline solution is between about 0.5 N and 5 N. In yet another embodiment, the concentration of sodium hydroxide or 7 201024251 potassium hydroxide of the test solution is between about 1 and 3 N. In one embodiment, the addition of citrate to the alkaline citrate is further included. Citrate provides enough ions to promote cementation between the colloids. The phthalate includes sodium citrate, potassium citrate, or a combination of the foregoing. In a 铷 的 的 的 与 碱性 碱性 碱性 碱性 碱性 碱性 与 与 与 与 与 与 / / / / / / / / / / / / / / / / / 〜 〜 In another embodiment, the SiOyMe modulus ratio is i 〇~i^ = again - implementation of the Si, Wei salt and the test solution of Si (VM2G modulus ratio = 1.25 ~ 1.5 ° its towel 'Si02 / M20 modulus M2〇 if it is called 〇; refers to the concentration of erhu acid (4) molar concentration / Wei sodium recording towel oxygen = liquid molar concentration in the liquid ((4) Moer New: (four) nano-solution concentration of middle ear + alkali The ratio of the molar concentration of sodium in the solution. In one embodiment, the mixture of the salt mineral and the test money modification solution is further added to the mold towel, and for example, between about 〜 It can be used for static and maintenance molding. The material can also be used for seismic recording of the mixture of _acid (four) and the test acid-sensitizing solution. For example, mechanical shock can be used. After deaeration by shaking i, the colloid can be maintained evenly. The water-repellent inorganic polymer of the embodiment of the present invention comprises a (iv) acid salt mineral having a plurality of first pores in the water-repellent inorganic polymer and a plurality of second pores on the surface of the water-repellent inorganic polymer. Wherein, the second pore and the second pore are substantially filled with the financial waterproof material. (4) The waterproof material is made of Shaoxian salt mineral scale The product of the invention is obtained by reacting the money quality modifying solution. The anti-male compound of the embodiment of the invention is formed by the copolymerization of the (tetra) acid salt mineral and the mechanical mechanical liquid σ. The pores can effectively prevent moisture from entering the inorganic polymer. In the example of 201024251, the weight ratio of the water-repellent inorganic polymer immersed in water for 24 hours and the general inorganic polymer immersed in water for 24 hours is less than 0. 1. In the embodiment - the contact angle between the water-repellent inorganic polymer and the water droplets is greater than about 75. It has a high hydrophobicity. In one embodiment, the strength of the water-repellent inorganic polymer is greater than about 550 kgf/cm2. In the embodiment, the strength of the water-repellent inorganic polymer is about 120% of the inorganic polymer excluding the enamel waterproof material. ❹ The following 'the flow is substantially the same according to different embodiments' The change of the ratio is the main parameter, so the test is listed BEST MODE FOR CARRYING OUT THE INVENTION The flow chart of the method for forming a water-repellent inorganic polymer according to an embodiment of the present invention is shown in Fig. 1. EXAMPLES Example 1 Kaolinite was placed in a 700X: high temperature furnace for calcination. The temperature was maintained for 3 hours to dehydroxate the kaolin and transform into amorphous metakaolin. Higher _ Lingling will be used as aluminum bismuth The source of the acid salt. Then 'prepare the phthalic acid modification solution. 856ml, 4N NaOH solution and 6052g sodium citrate were uniformly adjusted into a SiO2/M20 ratio of 1.25 polymerization precursor, and the precursor was removed 720g. Then add 80 grams of bismuth acid modifier to mix evenly to form an alkaline tantalate modification solution. Then '800 grams of high-altitude soil is added to 8 grams of the experimental dream acidification solution' and mechanically stirred 15 Min. After stirring, the mixture was poured into the mold and shaken for 10 minutes. Finally, the mold is sealed and cured at room temperature. The colloid was hardened and demolded, and subjected to CNS3763 (class No. A2047) test and hydrophobic 9 201024251 sex test. Among them, the hydrophobicity test is to drip water droplets on the surface of the inorganic polymer, and measure the contact angle between the water droplets and the surface of the inorganic polymer. The test results are summarized as follows: Table 1 Test item quality regulations Test results Condensation time Initial condensation after 1 hour, final condensation within 10 hours 2-5 hours Stability shall not occur expansion cracking or deformation without expansion cracking or deformation In the strength ratio strength test, the strength ratio of the test body blended with the modifier and the unblendered sample should be more than 85%. The blender is: 516 (kgf/cm2) No blender: 417 (kgf/cm2) The sample strength ratio is 123%. The water absorption ratio of the inorganic polymer blended with the modifier is not absorbed. Water absorption amount of the inorganic polymer (g) 1 hour = 0.28 5 hours = 0.19 24 hours = 0.09 The contact angle of the hydrophobic droplets with the surface of the test piece may be greater than 75 degrees 79 degrees. The experimental results show that the waterproof of the embodiment of the present invention The inorganic polymer can be tested by CNS3763 (class No. A2047) and its strength is also higher than that of general inorganic polymers. The contact angle of the water-repellent inorganic polymer with water droplets in the examples of the present invention is as high as 79 °, indicating that it has excellent hydrophobicity. Hereinafter, the preparation process and test results of other embodiments of the present invention are enumerated. Example 2 Kaolinite was placed in a high temperature furnace at 700 ° C for firing. Holding temperature 10 201024251 3 hours to transform the kaolin into amorphous change UJ 1 5 shell. The territory of Love will serve as a source of aluminosilicate minerals. β Next, adjust the different ratios of the citrate modifier to prepare an alkaline bismuth solution. 856ml, 4Ν NaOH solution, 6052 ? 故 几 几 ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦ ♦
接著’將800克的變高嶺土加入約8〇〇克之鹼性矽酸 質改質溶液，並機械攪拌15分鐘。攪拌後將混合液注入模 具中，並震盪1〇分鐘。最後，封模並於常溫下養護。膠體 硬化成形後脫模，並進行CNS3763(類號錢47)測試^疏 水性測試。測試結果以表二整理如下·· 一 IL 表二 測試項目 品質規定 p--- 試驗铨罢 凝結時間 初凝在1小時以後，終凝 在10小時以内 2-5小時 安定性 不得發生膨脹龜裂或變形 ^膨脹龜裂或變形 強度比 強度試驗所得掺和有改質 劑者與未掺和者之試體強 度比應達85%以上。 有摻者為：379(kgf/cm2) 無摻者為：417(kgf/cm2) 义體強度比為90%。 吸水比 掺和改質劑無機聚合物之 吸水量（g)/未掺和改質劑 無機聚合物之吸水量（g) 1小時=0.28 5小時=0.19 24小時=〇 〇9 疏水性 液滴與試體表面呈現的接 觸角可大於75度 75度 實施例3 將高嶺土 (kaolinite)置於700。(：的高溫爐中焙燒。持溫 201024251 3小時以使鬲嶺土脫羥而轉變成非晶質之變高嶺土。變高 屬土將作為紹矽酸鹽礦物之來源。 一調整不同濃度之Na〇H溶液。將856ml，2N之NaOH 备液6052克之石夕酸納、及8〇克之石夕酸質改質劑均句混 合以形成鹼性矽酸質改質溶液。 接著，將8〇〇克的變高嶺土加入約8〇〇克之鹼性石夕酸 質改質溶液，並機械攪拌15分鐘。攪拌後將混合液注入模 具中，並震盪10分鐘。最後，封模並於常溫下養護。膠體 硬化成形後脫模，並進行CNS3763(類號A2047)測試與疏 水性測試。測試結果以表三整理如下： 表三 ---- 測試項目 ---- 品質規定 試驗結果 凝結時間 ' —--- 初凝在1小時以後，終凝 在10小時以内 2-5小時 安定性 不得發生膨脹4裂或變形 無膨義裂或變形 強度比 強度试驗所得捧和有改質 劑者與未掺和者之試艘強 有摻者為：151.1(kgf/cm2) 無摻者為：147.7(kgf/cm2) --—-^ 吸水比 」变比應達85%£J·。 試體強度比為102% 掺和改質劑無機聚合物之 吸水量（g)/未掺和改質劑 1小時=0.28 5小時=0.19 --------— _^機聚合物之吸水營 24小時=〇 〇9 疏水性 —---—_ 液滴與試體表面呈現的接 觸角可大於 65度 雖然本發明已以數個較佳實施例揭露如上、然其並非 201024251 用以限定本發明，任何所屬技術領域中具有通常知識者， 在不脫離本發明之精神和範圍内，當可作任意之更動與潤 飾，因此本發明之保護範圍當視後附之申請專利範圍所界 定者為準。Next, 800 grams of metakaolin was added to about 8 grams of the alkaline phthalic acid upgrading solution and mechanically stirred for 15 minutes. After stirring, the mixture was poured into the mold and shaken for 1 minute. Finally, the mold is sealed and cured at room temperature. After the colloid is hardened and formed, the mold is released, and the CNS3763 (class No. 47) test is tested. The test results are summarized in Table II as follows: · I IL Table 2 Test item quality regulations p--- Test 铨 凝 凝 凝 凝 初 在 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Or the deformation/expansion cracking or deformation strength ratio strength test may be more than 85% of the strength of the test body blended with the modifier and the unblended. The blender was: 379 (kgf/cm2). The blender was: 417 (kgf/cm2). The strength ratio of the prosthesis was 90%. Water absorption ratio of the inorganic polymer blended with the modifying agent (g) / water content of the undoped modifier inorganic polymer (g) 1 hour = 0.28 5 hours = 0.19 24 hours = 〇〇 9 hydrophobic droplets The contact angle presented to the surface of the test piece can be greater than 75 degrees 75 degrees. Example 3 Kaolinite is placed at 700. (: roasting in a high-temperature furnace. Maintaining temperature of 201024251 for 3 hours to convert the sulphate soil into amorphous metakaolin. The high soil will be used as the source of the sulphonate mineral. 〇H solution: 856ml, 2N NaOH preparation solution 6052g of sodium sulphate, and 8 gram of sulphuric acid modifier are mixed to form an alkaline bismuth acid modification solution. Next, 8〇〇 The gram of kaolin was added with about 8 g of alkaline sulphuric acid modified solution and mechanically stirred for 15 minutes. After stirring, the mixture was poured into a mold and shaken for 10 minutes. Finally, the mold was sealed and cured at room temperature. After the colloid hardening is formed, the mold is released, and the CNS3763 (class No. A2047) test and hydrophobicity test are carried out. The test results are summarized as follows: Table 3---- Test item---- Quality regulation test result condensation time'-- -- After 1 hour of initial setting, the final setting should be within 2 hours of 2 to 5 hours. The stability should not be expanded. 4 cracks or deformations are not cracked or the deformation strength is higher than that of the strength test. The model of the tester is strong: 151.1 (kgf/cm2 The non-mixer is: 147.7 (kgf/cm2) ----^ The water absorption ratio should be 85%. J. The strength ratio of the sample is 102%. The water absorption of the inorganic polymer blended with the modifier (g) ) / undoped modifier 1 hour = 0.28 5 hours = 0.19 -------- - _ ^ polymer polymer water camp 24 hours = 〇〇 9 hydrophobic -----_ droplets and The contact angle exhibited by the surface of the test piece may be greater than 65 degrees. Although the invention has been disclosed in several preferred embodiments as above, which is not intended to limit the invention, any one of ordinary skill in the art, without departing from the invention In the spirit and scope of the invention, the scope of protection of the invention is defined by the scope of the appended claims.
13 201024251 【圖式簡單說明】 第1圖顯示本發明一實施例之防水無機聚合物的形成 方法流程圖。 【主要元件符號說明】 無。13 201024251 [Simplified description of the drawings] Fig. 1 is a flow chart showing a method of forming a water-repellent inorganic polymer according to an embodiment of the present invention. [Main component symbol description] None.
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