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TW201016545A - Rubber cloth of rubber boat and manufacturing method thereof - Google Patents

Rubber cloth of rubber boat and manufacturing method thereof Download PDF

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Publication number
TW201016545A
TW201016545A TW097142015A TW97142015A TW201016545A TW 201016545 A TW201016545 A TW 201016545A TW 097142015 A TW097142015 A TW 097142015A TW 97142015 A TW97142015 A TW 97142015A TW 201016545 A TW201016545 A TW 201016545A
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Taiwan
Prior art keywords
rubber
fabric
boat
gas
tape
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TW097142015A
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Chinese (zh)
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TWI356789B (en
Inventor
li-hao Lv
zheng-ji Xu
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Formosan Rubber Group Inc
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Priority to TW097142015A priority Critical patent/TW201016545A/en
Publication of TW201016545A publication Critical patent/TW201016545A/en
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Publication of TWI356789B publication Critical patent/TWI356789B/zh

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  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention provides a rubber cloth of rubber boat skin and a manufacturing method thereof. The method includes providing a base fabric, immersing the base fabric in isocyanate, performing a first drying process, immersing the base fabric in a contact type adhesive, and performing a second drying process, wherein the adhesive includes neoprene mixed adhesive and toluene, and then laminating an underside material on top and bottom surfaces of the base fabric respectively, wherein the underside material includes neoprene and chlorine sulfonated rubber, coating a surface material on a surface of the underside material, wherein the surface material includes chlorine sulfonated rubber and performing sulfuring process on the base fabric to which the under side material and the surface material are coated to obtain high weather resistant and durable rubber cloth for rubber boat.

Description

201016545 九、發明說明: 【發明所屬之技術領域】 本發明係㈣-種橡膠艇膠布及其製作方法,_是指一種具有 高耐候性、抗磨損的橡膠艇膠布及其製作方法。 B 、 【先前技術】 橡谬艇係用於除了供水上休閒活動外,更是—個水上 運輸的重要X具’例如船難、水災等,狀在緊急救援時了例如船 難時,漂親程巾橡膠婦需承受相當顧的氣候日夜溫度變化與堅 硬物艘如碓、岩的磨、刮,因此橡#艇所使用之膠布必須具傷相當程度 參的高度耐候、抗磨損與材料間的高接著力才能符合各種實際應用上的 需求。 但就目前市面上料的製作過程所製得轉布,摊耐候性及抗 磨損較低,目此存在對具有高度喃、抗磨損與層間材料間高接著力 的橡膠艇膠布的需求。 有鑪於此,本發明遂針對上述需求,提出一㈣新的橡膝艇膠布 及其製作方法,以有效克服上述之該等問題。 【發明内容】 馨*本發明之主要目的在提供一種橡膠艇膠布及其製作方法,其具有 高耐後性、高抗磨損與層間材料間高接著力之優勢。 為達上述之目的,本發明提供一種橡膠艇膠布,其包含有:一基 布^其係先後含浸過異氛酸鹽(jsocyanate)與接著劑型糊料其中 接著劑型糊料包含有氣丁橡勝混合膠料與甲苯;一第一底料與一第二 底料’其係各貼合於基布侧面上,其中底料包含有氣丁橡膠與氣續化 橡膠,至少—面料,其係貼合於第-底料上,其中面料包含有氣續化 橡膠。 本發明尚提供上述橡夥艇膠布的製作方法,其包含有下列步驟:提 供基布,將該基布全浸於一異氰酸鹽(丨s〇cyanate)後,並進行第 201016545 一次烘乾;再將基布全浸於一接著型糊料後,並進行第二次烘乾,其 中接著型糊料包含氣丁橡膠混合膠料與甲苯;隨後,於基布之上、下 表面各貼合一底料,其中底料包含有氯丁橡膠與氣磺化橡膠·•於底料 之一表面上貼合一面料,其中面料包含有氣橫化橡膠;以及對已貼合 底料與面料之基布進行硫化步驟。 底下藉由具體實施例詳加說明,當更容易瞭解本發明之目的、技 術内容、特點及其所達成之功效。 【實施方式】 本發明之下列實施例中雖然以平織布作為基布來進行說明本發 Ο 明,但並不因此侷限本發明之基布僅可以使用平織布,其它的如聚酯 布、尼龍布、棉布、聚酯/尼龍混紡紗布及其它不同組成纖維的混紡針 織布也可以使用作為基布。 首先,請參閱第1圖,其係本發明之橡膠艇膠布的結構示意圖^ 如圖所示,本發明之橡膠艇膠布10包含有:一先後含浸過異氰酸鹽 (isocyanate)與接著劑型糊料之平織基布12,其中此接著劑型糊料 係氣丁橡谬混合勝料與甲苯以重量比,:3混合所製得;分別位於平織 基布12侧面上的第一底料14與第二底料16,其中此第一底料14與 第一底料16係85Phr (配合比pound per hour)氣丁橡膠、i5phr氣 續化橡膠與適當混合物所組成;一位於第一底料14上的面料,其 係1〇〇phr氣績化橡膠與填充物混煉所組成,且面料18與第二底料 表面經過有硫化處理。 請參閱第2圖,其係本發明之橡膠艇膠布的製作方法步驟流程示 =番如_示,首絲步驟S1所示,將—平織基布置於全浸機之送 心’並將平織基布送至全浸槽中以異氰酸鹽(isocyanate)全 以如步驟泣所示,將已含浸異氰酸鹽之平織基布送至供箱内, CM烤3分鐘;如倾S3所述,再將此平織基布全浸於 啥料中,其中此接著劑麵料係利用氣丁橡膝混合膠料與甲笨以 201016545201016545 IX. Description of the Invention: [Technical Field] The present invention is a four-type rubber boat tape and a manufacturing method thereof, and _ refers to a rubber boat tape having high weather resistance and abrasion resistance and a manufacturing method thereof. B. [Prior Art] The rubber boat is used for leisure activities other than water supply. It is also an important X-boat for water transportation, such as shipwrecks, floods, etc., in the case of emergency rescue, such as shipwrecks, drifting relatives. The rubber scarf of the rubber towel needs to bear the considerable temperature and temperature changes of the weather and the hard objects such as shovel and rock grinding and scraping. Therefore, the rubber tape used by the rubber boat must have a high degree of weather resistance, wear resistance and material between the materials. High adhesion can meet the needs of various practical applications. However, in the current production process of the material on the market, the distribution of weather resistance and wear resistance is low, and there is a demand for a rubber boat tape having a high degree of anti-wear, high abrasion resistance between the interlayer materials. In view of the above needs, the present invention proposes a (four) new rubber knee boat tape and a manufacturing method thereof to effectively overcome the above problems. SUMMARY OF THE INVENTION The main object of the present invention is to provide a rubber boat tape and a method for producing the same, which have the advantages of high post-resistance, high abrasion resistance and high adhesion between layers. In order to achieve the above object, the present invention provides a rubber boat tape comprising: a base fabric which is successively impregnated with an isocyanate and an adhesive of a paste type, wherein the paste of the adhesive contains a rubber butadiene rubber And a toluene; a first primer and a second primer are respectively attached to the side of the base fabric, wherein the primer comprises a gas rubber and a gas-renewing rubber, at least a fabric, which is attached to On the first-base material, the fabric contains a gas-renewing rubber. The present invention further provides a method for fabricating the above-mentioned rubber boat tape, which comprises the steps of: providing a base cloth, completely immersing the base cloth in an isocyanate, and performing the first drying on 201016545 Then, the base cloth is completely immersed in the one-pass type paste, and the second drying is performed, wherein the type paste comprises the gas-butadiene rubber compound and toluene; then, the top and bottom surfaces of the base cloth are attached. a base material, wherein the base material comprises a neoprene rubber and a gas sulfonated rubber. • a fabric is attached to one surface of the base material, wherein the fabric comprises a gas-crossing rubber; and the bonded bottom material and the fabric The base fabric is subjected to a vulcanization step. The purpose, technical contents, features and effects achieved by the present invention will become more apparent from the detailed description of the embodiments. [Embodiment] In the following embodiments of the present invention, although the present invention has been described with a plain woven fabric as a base fabric, the base fabric of the present invention is not limited to the use of a plain woven fabric, and other such as a polyester fabric. Nylon cloth, cotton cloth, polyester/nylon blended gauze and other blended knitted fabrics of different constituent fibers can also be used as the base fabric. First, please refer to FIG. 1 , which is a schematic structural view of a rubber boat tape of the present invention. As shown in the figure, the rubber boat tape 10 of the present invention comprises: an isocyanate and an adhesive paste which are successively impregnated with isocyanate. a plain woven base fabric 12, wherein the adhesive of the adhesive type is a mixture of a gas-filled rubber and a toluene in a weight ratio of: 3; the first primer 14 and the first on the side of the plain woven base fabric 12, respectively. Two primers 16, wherein the first primer 14 and the first primer 16 are 85Phr (pound per hour) gas butadiene rubber, i5phr gas continuous rubber and a suitable mixture; one is located on the first primer 14 The fabric is composed of 1 phr of tempered rubber and a mixture of fillers, and the surfaces of the fabric 18 and the second primer are vulcanized. Please refer to FIG. 2 , which is a flow chart of the manufacturing method of the rubber boat tape of the present invention. The flow chart of the rubber boat tape is shown in the first step, and the flat weave is arranged in the heart of the full dip machine. The cloth is sent to the full dip tank with isocyanate as shown in the step weeping. The plain woven base fabric impregnated with isocyanate is sent to the tank, and the CM is baked for 3 minutes; Then, the flat woven base fabric is fully immersed in the tanning material, wherein the adhesive fabric is made of gas-filled rubber and rubber mixed rubber and a stupid to 201016545

重量比1 : 3混合所製得;如步驟S4所述,將已含浸接著劑型糊料之 平織基布送至烘箱,以130°C烘烤3分鐘;如步驟S5所述,利用壓延 貼合機將一底料壓延至預設厚度後,貼合於上述平織基布之單一側表 面上,形成第一底料;再如步驟S6所述,利用壓延貼合機將上述之底 料壓延至預設厚度後,貼合於上述平織基布之另一側表面上,形成第 二底料;然後如步驟S7所述,利用壓延貼合機將一面料壓延至預設厚 度後,貼合於第一底料上(底料單次單面貼合);如步驟S8所述,將 已貼合面料後之平織基布送入鼓筒式加硫褲或加硫罐加硫,以160°C 進行15分鐘的硫化過程;最後如步驟S9所述進行收捲,即可獲得本 發明之具高耐後性、耐磨性與材料間具高接著性的橡膠艇膠布。 上述之底料係85phr (pound per hour)氣丁橡膠、I5phr氣磺化 橡膠與適當混合物經萬馬力混煉機混練後,再以二滚輪(粗輪、細輪) 充分混合,其中混合時的溫度維持在70〇c〜85〇c。 而上述之面料係以萬馬力混煉機將100phr氣磺化橡膠與填充物 混煉後’再以二滾輪(粗輪、細輪)充分混合,其中混合時的溫度維 持在70°c〜85°c。 唯以上所述者’僅為本發明之較佳實施例而已,並賴來限定本 發明實施之範圍。故即凡依本發明中請範_狀特徵及精神所為之 均等變化或修飾,均應包括於本發明之申請專利範圍内。 【圖式簡單說明】 第1圖係本發明之橡膠艇膠布的結構示意圖。 示意圖 〇 第2圖係本發明之橡膠艇膠布的製作方法步驟流程 【主要元件符號說明】 1〇橡膠艇谬布 12平織基布 14第一底料 16第二底料 18面料Prepared by mixing 1:3 by weight; as described in step S4, the woven base fabric containing the paste-type paste is sent to an oven and baked at 130 ° C for 3 minutes; as described in step S5, by calendering After calendering a primer to a predetermined thickness, it is attached to a single side surface of the plain woven base fabric to form a first primer; and as described in step S6, the above-mentioned primer is calendered by a calendering laminator to After the thickness is preset, it is bonded to the other side surface of the flat woven base fabric to form a second primer; then, as described in step S7, a fabric is rolled to a predetermined thickness by a calendering laminator, and then bonded to On the first primer (single material single-sided bonding); as described in step S8, the flat woven base fabric after the bonded fabric is sent into the drum type sulfurizing pants or the sulfurizing tank to add sulfur to 160°. C is subjected to a vulcanization process for 15 minutes; finally, winding is carried out as described in the step S9, and the rubber boat tape of the present invention having high after-wear resistance, abrasion resistance and high adhesion between materials can be obtained. The above-mentioned bottom material is 85phr (pound per hour) gas rubber, I5phr gas sulfonated rubber and appropriate mixture are mixed by 10,000 horsepower mixer, and then fully mixed with two rollers (coarse wheel, fine wheel), wherein mixing The temperature is maintained at 70〇c~85〇c. The above-mentioned fabric is mixed with 100 phr of gas sulfonated rubber and filler after 10,000 horsepower mixer, and then fully mixed with two rollers (coarse wheel, fine wheel), wherein the temperature during mixing is maintained at 70 ° c ~ 85 °c. The above description is only a preferred embodiment of the invention and is intended to limit the scope of the invention. Therefore, any change or modification of the present invention in accordance with the present invention should be included in the scope of the present invention. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing the structure of a rubber boat tape of the present invention. 〇 Fig. 2 is a flow chart of the manufacturing method of the rubber boat tape of the present invention. [Main component symbol description] 1 〇 rubber boat 12 12 flat woven base fabric 14 first primer 16 second primer 18 fabric

Claims (1)

201016545 十、申請專利範園: 1. 一種橡膠艇膠布的製造方法,其包含有下列步驟: 提供一基布; 將該基布全浸於一異氰酸鹽(丨socyanate)後,並進行第一次烘乾; 再將該基布全浸於一接著型糊料後,並進行第二次烘乾,其中該接 著型糊料包含氣丁橡膠混合膠料與甲苯; 於該基布之上、下表面各貼合一底料,其中該底料包含有氣丁橡膠 與氣磺化橡膠; 於該底料之一表面上貼合一面料,其中該面料包含有氣確化橡膠; Φ 以及 對該已貼合底料與面料之基布進行硫化步驟。 2·如申請專利範圍第1項所述之橡膠艇膠布的製造方法,其中該基布 係選自於平織布、聚酯布、尼龍布、棉布、聚酯/尼龍混紡紗布或 其它不同組成纖維的混紡針織布。 3_如申請專利範圍第1項所述之橡膠艇膠布的製造方法,其中該第一 次烘乾係於130°C烘乾3分鐘。 4_如申請專利範圍第1項所述之橡膠艇膠布的製造方法,其中該第一 次烘乾係於一烘箱中進行。 ❹5·如申請專利範圍第1項所述之橡膝艇膠布的製造方法,其中該第二 次烘乾係於130°C烘乾3分鐘。 Λ 6. 如申請專利範圍第1項所述之橡膠艇膠布的製造方法,其中該第二 次烘乾係於一烘箱中進行。 、μ 一 7. 如申請專利範圍第1項所述之轉娜布的製造方法,其中該接著 型糊料係氣丁橡膠混合膠料與甲苯以η: 3重量比混合製成: 8. 如申請專利範圍第1項所述之橡膠艇膠布的製造方法,其中該底料 係85phr (配合比)氣丁橡膠與15phr氣續化橡膠經混煉、 壓延等步驟所製得。 〇與 201016545 9.如申請專利範圍第8項所述之橡膠艇膠布的製造方法,其更混煉有 其它天然或合成膠。 1〇·如申請專利範園第1項所述之橡膝艇膠布的製造方法,其中該面料 係1〇〇phr氣磺化橡膠與適當填充物經混煉、混合與壓延等步称所 製得。 11·如申請專利範圍第8項所述之橡膠艇膠布的製造方法,其中該混合 步驟之溫度是為持在7(TC〜85t。 12.如申請專利範圍第10項所述之橡谬艇膠布的製造方法,其中該混 合步驟之溫度是為持在70eC〜851C。 參 13_如申請專利範園第10項所述之橡膠艇膠布的製造方法,其中該硫 化步驟係利用鼓筒式加硫機或加硫罐加硫。 14. 一種橡膠艇膠布,其包含有: 一基布,其係先後含浸有異氰酸鹽(ls〇cyanate)與接著劑型糊料, 其中該接著劑型糊料包含有氣丁橡膠混合膠料與甲苯; 一第一底料與一第二底料,其係各貼合於該基布側面上,其中該底 料包含有氣丁橡膠與氣磺化橡膠;以及 至少-面料,其係貼合於該第一底料上,其中該面料包含有氣確化 橡膠,且該面料與該第二底料表面經硫化處理。 15. 如申請專利範圍第14項所述之橡膠艇膠布,其中該基布係選自於 平織布、聚醋布、尼龍布、棉布、聚醋,尼龍混紡紗布或其它不同 組成纖維的混紡針織布。 、 16_如申請專利範圍第14項所述之橡膠艇膠布,其中該接著型糊料係 氣丁橡膠混合膠料與甲苯以】:3重量比混合製成。 17_如申請專利範圍第14項所述之橡膠艇膠布,其中該底料係_r 氣丁橡膠與15phf氣續化橡膠經混煉、混合與壓延等步驟所製得。 18·如申料職圍第17韻叙娜祕布,其更鱗有其它天然 或奋赤腺。 9 201016545 19.如申請專利範圍第14項所述之橡膠艇膠布,其中該面料係100phr 氣磺化橡膠與適當填充物經混煉、混合與壓延等步驟所製得。201016545 X. Application for Patent Park: 1. A method for manufacturing a rubber boat tape comprising the steps of: providing a base fabric; immersing the base fabric in an isocyanate and performing the first Drying once; further immersing the base fabric in a subsequent paste, and performing a second drying, wherein the adhesive paste comprises a gas-butadiene rubber compound and toluene; above the base fabric And a bottom material, wherein the bottom material comprises a gas rubber and a gas sulfonated rubber; and a fabric is attached to one surface of the primer, wherein the fabric comprises a gas-reducing rubber; Φ and The bonded base material and the base fabric of the fabric are subjected to a vulcanization step. 2. The method for manufacturing a rubber boat tape according to claim 1, wherein the base fabric is selected from the group consisting of plain woven fabric, polyester cloth, nylon cloth, cotton cloth, polyester/nylon blended gauze or other different compositions. Fiber blended knit fabric. 3_ The method for manufacturing a rubber boat tape according to claim 1, wherein the first drying is performed at 130 ° C for 3 minutes. 4) The method for producing a rubber boat blanket according to claim 1, wherein the first drying is performed in an oven. ❹5. The method of manufacturing the rubber and knee boat tape of claim 1, wherein the second drying is performed at 130 ° C for 3 minutes. Λ 6. The method of manufacturing a rubber boat blanket according to claim 1, wherein the second drying is performed in an oven. The method of manufacturing the singapore according to the first aspect of the invention, wherein the sizing paste is a mixture of a gas-butadiene rubber compound and toluene in a ratio of η:3: 8. The method for manufacturing a rubber boat tape according to the first aspect of the invention, wherein the bottom material is obtained by mixing, calendering and the like with 85 phr (mixing ratio) gas rubber and 15 phr gas continuous rubber. 〇和 201016545 9. The method for producing a rubber boat tape as described in claim 8 of the patent application, which is further compounded with other natural or synthetic rubber. 1〇·If the method for manufacturing the rubber and knee boat tape described in the first application of the patent garden, the fabric is made of 1 phr gas sulfonated rubber and a suitable filler by mixing, mixing and calendering. Got it. The method for manufacturing a rubber boat tape according to claim 8, wherein the temperature of the mixing step is 7 (TC~85t. 12. The rubber boat according to claim 10 of the patent application scope A method for producing a tape, wherein the temperature of the mixing step is from 70 eC to 851 C. The method for producing a rubber boat tape according to claim 10, wherein the vulcanization step is performed by using a drum type. Adding sulfur to a sulfur machine or a sulfurizing tank. 14. A rubber boat blanket comprising: a base fabric impregnated with an isocyanate (ls〇cyanate) and a binder type paste, wherein the adhesive type paste a first rubber and a second primer, each of which is attached to the side of the base fabric, wherein the primer comprises a gas rubber and a gas sulfonated rubber; And at least a fabric attached to the first primer, wherein the fabric comprises an air-cured rubber, and the fabric and the second primer surface are vulcanized. 15. As claimed in claim 14 Rubber boat tape, wherein the base fabric is selected from Flat woven fabric, polyester vinegar cloth, nylon cloth, cotton cloth, polyester vinegar, nylon blended gauze or other blended knitted fabric of different composition fibers. 16_ The rubber boat tape as described in claim 14 of the patent application, wherein the adhesive type The paste-type gas-butadiene rubber compound and toluene are prepared by mixing: 3 weight ratio. 17_ The rubber boat tape according to claim 14, wherein the base material is _r gas rubber and 15phf gas. The continuation rubber is obtained by mixing, mixing and calendering. 18·If the application is the 17th Yun Sina secret cloth, it has other natural or reddening glands. 9 201016545 19.If the patent application scope The rubber boat tape according to item 14, wherein the fabric is obtained by mixing, mixing and calendering 100 phr of a gas sulfonated rubber with a suitable filler.
TW097142015A 2008-10-31 2008-10-31 Rubber cloth of rubber boat and manufacturing method thereof TW201016545A (en)

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TWI510371B (en) * 2013-02-05 2015-12-01

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TW201338974A (en) * 2012-03-20 2013-10-01 Formosan Rubber Group Inc Ultra-thin rubber structure and its manufacturing method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI510371B (en) * 2013-02-05 2015-12-01

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