TW201008967A - Side chained cage shaped siloxane epoxy resin, the preparation method thereof and preparation method of material including the same - Google Patents

Abstract

The invention relates to a side chained cage shaped siloxane epoxy resin, the preparation method thereof and preparation method of material including the same. The side chained cage shaped siloxane epoxy resin includes sides of cage shaped DGEBA functional group connecting the epoxy. The preparation method of the side chained cage shaped siloxane epoxy resin includes reacting epoxy resin with cage shaped DGEBA to form a side chain cage shaped siloxane epoxy resin. The preparation method of material including the side chained cage shaped siloxane epoxy resin comprises reacting DGEBA with side chained cage shaped siloxane epoxy resin to obtain such material. The epoxy resin can be uniformly distributed in side chained cage shaped siloxane epoxy material.

Description

201008967 IX. Description of the invention: [Technical field to which the invention belongs] The preparation method of the present invention, especially the preparation of the surface-shaped Wei-shaped Wei-like Wei and the preparation of the epoxy resin (4) Refers to the method of preparing the cage-like Weiyuan, the oxygen tree age, the preparation method and the preparation method of the material containing the Wei Wei and Wei Wei, which are used in high-performance adhesives, residual protective coatings, The field of composite materials, sub-materials, electronic reduction products and optoelectronic components. ^ [Prior Art] Φ ▲ epoxy resin 贱 good adhesion, mechanical (four) and physical properties, such as tensile strength, impact resistance 2, insulation properties and processability, it is widely considered in composite materials, electronic materials and edge (4) In recent years, (10) the development of the products and optoelectronic components of the former sub-sectors, the ring = the moon is in the light, the degree of breakage, the high resistance, the excellent stability of the size of the special 2 is gradually challenged 'traditional — Some epoxy materials are made by mixing filler materials such as treated clay, glass Weiwei or other neat green lyophilized resin to form an epoxy tree cerium material, but the above-mentioned filling materials have a large amount of granules. The density is high, and the dispersibility in the epoxy resin is 叙 魏 _ _ O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O Patent Announcement Number: Na. . 5. . . In 4563, p〇ss was added only without copolymerization, which easily caused phase separation P0SS dispersibility was not good. Patent No.: usp7〇su 3 = p〇ss using 3 epoxy g旎, the reactivity is quite different from the neem xy, and the t-set phenomenon may still be poor when cross-linking. According to the above, the present invention provides a method for preparing a kind of ship Weiwei-like ring dumping and a greening method for the Weishu gambling material containing the side chain test Wei Wei, due to the cage doubling (P〇SS)^ nanometer particle size And lower density, which has a better fraction in the epoxy resin and this is chemically bonded with the oxygen resin (DGEBA) to form a side chain caged oxirane ring grease. Forming a side chain-like cage to epoxy resin 5 201008967 It has good emulsification resistance and film forming property, and has glass transition. [Inventive content] The method is to provide a surface-like hearing-like resin and its preparation (ie, Γ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The method has the advantages of higher quality. The method is followed by the preparation method of the epoxy resin of the epoxy resin (four) thief city of the epoxy resin of the cage method of Wei Ruying and its preparation of the ring-shaped rim mrir mine oxygen method chain, The fiber-containing cage-shaped snail material has a good anti-oxidation strip and film forming property. The cage-shaped epoxy resin and the preparation method thereof Oxygen-containing side key touch (iv) the only Concept Wei prostitutes. I chain-like Wei Wei resin,

6 201008967 wherein η is an integer of MO; and wherein R is selected from the group consisting of methyl, ethyl, propyl and isobutyl. The method for preparing the epoxy resin of the side chain cage-like siloxane, the steps comprising: reacting the epoxy resin with the caged isocyanatopropyldimethylsilyl-isobutyl-POSS to form a side chain cage siloxane Epoxy resin. The preparation method of the epoxy resin material containing side chain siloxanes comprises the steps of: reacting epoxy resin with caged isocyanatopropyl dimethyl sulphate (POSS) to form a side chain cage 矽An epoxy resin of the oxane; and reacting the epoxy resin with the epoxy resin of the side chain siloxane to obtain an epoxy resin material containing a side chain siloxane. [Embodiment] A more detailed understanding of the present invention and the method of the present invention will be apparent from the following description. The epoxy resin of the side chain cage alkane of the present invention comprises:

And ethyl, propyl and isobutyl wherein n is an integer of from 1 to 1 Å; and wherein R is selected from one of the group of methyl groups. The preparation method of the invention is as follows (as shown in the first 7 201008967 figure): 'si will be % oxygen resin and cage wire weiweiwei 0^〇eyanat (>pmpyldimethyisiiyi_is 〇bu^i_p〇ss) reacts to form a side chain cage-like gas-fired oxygen. Epoxy resin. The invention relates to a method for preparing an epoxy resin material containing a side chain cage-like gas oxy-sinter, the steps of which include the second figure: S11, the % oxygen resin and the cage polypothala oxynene (10) eyanatopiOpyldimethylsilyWs〇bu _ P〇ss) reacts to form a side chain cage-like alkoxylate epoxy resin; and 〇S12 further reacts the two oxygen resins with the side chain caged oxirane epoxy resin to obtain a side chain caged oxirane Epoxy resin material. Preparation of Side Chain Cage Oxygenated Epoxy Resin Preparation of Side Chain Cage Oxygenane Rings by Isole Cyanat〇pr〇pyldimethylsilyl is〇butyl_p〇ss (IPI-POSS) Oxygen resin (p〇ss_Ep〇xy), the epoxy resin group side chain is provided with a cage-like oxy-oxygen structure, and its chemical reaction formula is as shown in the third embodiment. Such as 丨 (1716 this 1 * (^1 ^ 1 ^ 11 〇 1 into, referred to as 00 £ 8 eight, its ring ® oxygen when $ 18 〇 g / ec 〇 dissolved in 15 g of tetrahydrofuran (tetrahydrofuran) Its solid content is 40wt / /. 2g of caged poly-sesquioxalate (Isocyanatopropyldimethylsilyl-isobutyl-POSS, IPI-POSS for short) is added to the epoxy resin solution (the epoxy resin and the cage polyhalf The weight ratio of the oxane is 5:1), the NCO g energy group on the Ipi_p〇ss is reacted with the hydroxy group on the epoxy resin, and triethylamine (TEA) is added as a catalyst. In 6 (TC), the magnets were mixed and uniformly mixed and refluxed to keep the concentration constant, and the reverse of the functional groups was monitored by Fourier infrared spectrometer (FT_IR). , about 10 hours reaction completely 'formed a solution of a side chain caged alkane-based epoxy resin (POSS-Epoxy). δ 201008967 Preparation of an epoxy resin material containing a side chain caged siloxane to epoxy resin (DGEBA) Add different proportions of side chain cage-like oxylin oxide resin (POSS-Epoxy), stir at room temperature for hours!, then add hardener 4,4,-diamino-benzophenone ( 4,4,-methylenedianiline, also known as 4,4,-diaminodiphenylmethaiie, abbreviated as DDM) 'Place at room temperature! Day' and then vacuum oven for 8 〇 2 hr, 12 〇 < ^ 2 hr, 160 C 4 hr and 180 t: 6 hr conditional baking. The reaction equation is as shown in the fourth figure. The epoxy resin of the side chain cage siloxane is used as the filling reinforcement of the epoxy resin material containing the side chain siloxane. In the second to eleventh steps, epoxy resin (DGEBA) was added to the P〇SS-EP〇xy/THF solution prepared in Example 1, respectively, 2.25, 11.25, 22.5, 33, 75, 67.5, 112.5. 157.5 and 202.5§, the weight ratio of epoxy resin to POSS-Epoxy is 1〇〇/1, 1〇〇/5, 1〇_, 1〇〇/15, respectively. , 100/30, 100/50, contact/70, 1〇〇/9〇, etc., and preparing epoxy resin materials containing side-chain caged oxiranes under the above reaction conditions for thermogravimetric analysis and L〇I The measurement results are shown in Table and Table 2. The structure of the epoxy resin (pOSS_Ep〇xy) of the side-chain caged siloxane is determined by the fact that the modified genus of the present invention is to bond the ruthenium monomer to the DGEBA-type ring to make it react. The interaction between the organic phase of the oxy-resin and the inorganic phase of Shixia Oxygen has a co-formation to increase the compatibility of the Wei-ring-lip. This contribution should be based on the use of ipi-poss as a modifier to react with the dgeba-type epoxy resin oxynitride Ssb-based (OH) to produce an Urethane bond. The dgeba type epoxy resin has a telluride on the main chain. In order to understand the reaction between DGEBA epoxy resin and coupling agent 〇ss, the FT-IR monitoring NCQ functional fine-change shape, the fifth county Wei Wei and the modified _(four) (10) reaction FT-IR spectrum' It can be seen that the NC 〇 functional group 227 ! !! The situation with time 'from the start of the reaction to the reaction time 10 hours after the NC 〇 functional group 227 〇 cml completely disappeared, this phenomenon indicates that the DGEBA type epoxy resin and the coupling agent Ipi_p 〇 Ss reacts. From the FT_IR of the modified epoxy resin in the sixth figure, it can be proved again that nc〇(227〇啦,) has completed the full reaction of 201008967, and the absorption exhibited at 1100 cm 1~1200 cm丨 is si 〇si, in addition In 1726 coffee, it is c=o. From the above data, it shows that the epoxy resin has been successfully modified, and it shows very clear _ characteristic absorption in 913(3)^, which is the fingerprint area of the epoxy group, which can explain the change of f The epoxy resin still retains the epoxy group without being damaged. Structure of epoxy resin material with side chain caged siloxane after hardening FT*IR identification

In the seventh figure, after hardening, the epoxy resin material containing the side-bonded cage-like Oxygen-burning material is micro-spectroscopy, and it can be seen that the characteristic absorption peak of 9M cm $ epoxy group has completely disappeared, but it appears in 1196. The characteristic is that the peak of the filament DDM (10) is completely inverted by about 48 W, which is the characteristic absorption peak of the benzene ring, and em 1 is the characteristic absorption peak of c=c. The i3i4 coffee is an umbrella structure of CH. At 1051 cm, it is an asymmetrical structure of Si_〇-Si. 3 Since the present invention utilizes the 〇h_ on the epoxy resin with the -NC0 functional group to react with 〇h_ on the epoxy resin to produce an urethane structure, there are c=〇 at 1726 cm 1 and 3291 cm ^. Gu bonding, and there is no absorption peak at 2270 cm, indicating that the added (four) _ Shi Xi oxygen burning has completely reacted 0 29

After Si Solid-state NMR = FT4R, the final gate Si-NMR was determined to confirm the structural confirmation of the further progress. The eighth picture is the ipi_p〇ss s touch coffee e

The results of Sl-NMR identification are shown in the figure. In _68 Qing, it is the characteristic peak of the third-order Wei pull, and the pick-up Ppm is the characteristic peak of the fourth-grade Shi Xi dumping (cage-like main structure), and Bu 1〇鹏The characteristic peak of si_cH. 3 ninth _ attached drink recognition egg record _ extract Lai Wei Wei-burning ring reading paving with Solid _% Cong identification results, Yu Cai found these three characteristics = set and fine · characteristics ♦ position _, therefore Oxygen (4) (10) ^ not ·, also added to the human ring dip fat will shadow _ ship mixed semi-Wei burning structure. Thermal property analysis 10 ❺ ❹ 201008967 Glass transition temperature (Tg) Add different proportions of P〇SS-Epoxy S DGEBA type epoxy difficult, which can be used for c, and then the epoxy resin with side chain 魏 魏 魏 _ 'Measurement, for dynamic analysis of the heating rate of 20 c / min. In the glass rotation _ test towel (such as needle _ and, can be said to contain the following ring β L (four) (four) blush content increased tree, & value L ί: itself is a nano-level reinforcing material (one two τ ( ΤΟΓ^^effect)°^ After POSS F,·, the Tg value will start to decrease slowly. From the tenth figure, it can be found that the addition amount of P〇SS-EP〇Xy is less than 7〇%, and the height of the mixed material is high. (10)t; upgrade to 172 t (additional, 1 ^ plus and the next day W kernel in P〇SS-Ep〇xy added 9〇% to ^; the value will decrease with the increase of the amount, down to 157. (: The reason is that the three-dimensional structure of the cage SS leads to an increase in the free volume, and the crosslink density is small, so the Tg is lowered. Thermogravimetric analysis test (TGA) j hardened epoxy resin material containing side chain cages The sample, with the material splitting $cracking property' to 1G/mint: warming the scales of money and gas, the Wei test alone, the refining of the fruit can be obtained by Td〆5 wt / heat weight loss temperature > and coke rate The thermal stability of the material.

The look of the Wei resin containing the side chain cage-like Wei resin is POSS (wt%) 1.00 0.17 0.79 L52 2.17 3.85 5.56 6.86 7.90 16.6?

POSS-Epoxv (wt%> · 0 POSS

10 15 30 50 70 90 100 0.00000 0.00533 0.01667 0.03334 0.05001 0J0D02 0Λ6670 0-2333S 0.30006 0-33333 246.42 330.73 329.98 320.97 304.52 262.29 255.55 254.1⁄2 291.84 278.55 15.15 15.52 16.89 17.71 17.80 17.S9 18.04 19.41 19.92 22.05 14.48 14.75 16.20 17.02 17.16 17.2S 17.29 1B.61 19.21 21.41 Add 1 Wt ° / from the hair of Table 1. The p〇ss-Ep〇xy can increase the Td from 24,642 to 201008967, 330,73. The reason is that the poly-halogenes are a nano-reinforcing material, and the addition of the polymer to the polymer material will have a nano reinforcing effect. Therefore, it has a better hydrazine cracking temperature than the epoxy resin which is not added to the stone. However, due to the introduction of the cage-shaped polyclimatosis, the Nc〇 bond segment has no Nc〇 bond segment, and the Qing bond segment does not have flammability, resulting in early thermal cracking, and thus the amount of addition to the Shiyang oxygenator increases. With the reduction of 'but compared with pure epoxy resin', there is still a publication of the nanocomposite with the addition of Shixi oxygen. Furthermore, when a higher _oxygen addition ratio is added (generate p〇ss_EpGxy and ^ exposure-S-Ep〇Xy), the % will increase. It is speculated that there may be uncracked NC〇 segments on the polymer bond segment, and the Wei-burn structure is introduced. When the machine is heated, $ will move.

The protective layer, so the un-cracked NCO segment is affected by the protective layer, and the cracking rate ^ leads to an increase in the thermal cracking temperature. _ From the twelfth figure, when the introduction into the Shixi oxygen hospital, the coke formation rate increases with the increase of the content of the Xizhou oxygen burning, and the 800 t coke formation rate is also increased from 14.48 to 2141. The increase in the amount of coke households can be improved by the fact that the mirrors and the health materials are produced in the domain. From this, it can be seen that the addition of the inorganic ceramics of the Shixia oxygen is improved for the heat resistance and thermal stability of the epoxy resin. Anaerobic index (LOI) From Table 2, the flame retardant properties of the test piece prepared by adding P〇SS-EP〇xy to epoxy resin were known. Since the inorganic ceramsite is introduced into the resin, when the temperature is burned at a high temperature, the surface of the material will produce a (10) network structure and the product will have good flame retardancy. It is found from Table 2 that when the amount of 2 P〇SS-EP〇xy added = 50%, the flame resistance of the material can be improved to 28, which has exceeded the flame retardancy standard of %. However, if the content is above 7〇%, L〇I is reduced, because the structure of the cage 卩(10) increases the free volume, and the hardening cross-linking effect is poor, resulting in poor flame-retardant f, so from all the test , 3G%, 5G% & 7Q% pC) SS_EpGxy addition ratio can be selected to select a preferred reaction concentration. 12 201008967

Table 2 LOI DGEBA (%) POSS-Epoxy (wt%) POSS (g) POSS (wt%) LOI 100 0 0 0 22 100 of different POSS-Epoxy content epoxy resin materials containing side chain siloxanes 1 0.00333 0,17 24 100 5 0.01667 0.79 24 100 10 0.03334 1.52 24 100 15 0.05001 2,17 24 100 30 0.10002 3.85 26 100 50 0.16670 5.56 28 100 70 0.23338 6.86 27 100 90 0.30006 7.90 25 0 1ί» 0.33333 16.67 23 X Light Diffraction Test (XRD) In the study of morphology, this study first identified its structure by XRD (eg, Figure 13). The characteristic absorption peak position of pure Isocyanatopropyldimethylsilyl-isobutyl-POSS was found by the map at 20= 8° (d = 5.53A) and 2Θ=19° ((1 = 2.37Α) two positions, so it can be judged that IPI-P0SS is not a cuboid helium, but a rectangle. From bottom to top, respectively, caged polysesasiloxane and lwt%, 5wt%, 10wt%, I5wt%, 30wt°/〇, 50wt%, 70wt%, 90wt%, and 100% by weight of side chain cages Oxygen-based epoxy resin, also found in epoxy resin materials containing side chain cage-like alkane in 2Θ = if there is a characteristic absorption The peak has a broad and smooth curve. Since the diamine hardener reacts with the epoxy functional group on the epoxy resin, it causes entanglement between the chain and makes the molecular chain arrangement more confusing. In other words, the molecular chain structure of the product is amorphous, so in the X-my map, the characteristic peak is a broad and smooth curve. Furthermore, a higher ratio is added. 13 201008967 = Shi Xi Oxygen Cong her purpose, and there is no difference. 8. Sigh 2θ = ΐ 9. Two = can be inferred riding _ contains _ New Wei red Wei tree hoof material under peak, uniformity, and no phase separation phenomenon. Morphology of Scanning Electron Microscopy (SEM) = Observed observation 'The formation of the epoxy-like material of the side chain cage-like oxygen chamber II's good uniformity' can be observed by scanning electron microscopy Microscopic organic and inorganic =

Oblique_to the sixteenth-scanning electron microscopy of her material interception_image^ is added 5% POSS_Epoxy containing side chain cage-like stone epoxy resin material ^ submicroscope 匕 million times the determination of the side When the key caged Wei Wei's epoxy tree moon material = Tian 1 found no wealth reduction compound distribution material hook. Add a higher p〇ss_Ep ratio (15%, 5G%), and use a scanning electron microscope to magnify the 30,000 times of the epoxy resin when the epoch is converted by the fifteenth _ sixteen_wei chain == = When it’s good, it’s not going to be a ship’s phenomenon. — SEM-EDX Si-mapping. Figures 17 to 19 show the inclusion of 5%, 15%, and 5 (%) side chain cages, respectively. When the 1⁄4 (4) of the hoofed material is touched, the highlights of the figure are divided into the distribution of the thief. The collection of fresh cages and semi-weilang resin nano-composites is used for testing. It can be known from the figure that in addition to knowing that it contains strontium atoms, it is more important to know that there is a job in the Wei Academy. The distribution of the weftane compound of the material towel is quite dispersed and uniform without agglomeration. In the test of optical properties of optical properties, this study used UV/Vis to test the light transmittance of the obtained epoxy resin material containing side chain siloxanes (such as the twentieth figure), and found that the dirty _E The amount of addition of 5 〇 * is a critical point. When the amount of p〇SS-Epoxy added is >50 wt%, the epoxy resin material containing side chain alkoxysilane exhibits white fog phenomenon, and the higher the amount of p0SS_Ep〇xy added, the higher the inorganic content, and the ring of 14 201008967 The compatibility of the oxyresin is also poor, and therefore the light transmittance of the epoxy resin material containing the side chain siloxane is also decreased as the amount of POSS-Epoxy added increases. In summary, the epoxy resin of the side chain cage-like siloxane of the present invention is a new type of reinforcing filler. In the thermal property test of the present invention, the residual amount of TGA can be increased from 14.48 wt% to 2141. %, while the cracking temperature is higher than pure epoxy. In terms of flame retardancy, the LOI can also be more than 28 to explain its excellent performance. It is also pointed out that the epoxy resin material containing the side chain cage-like dream oxygen burning has excellent stability and flame retardancy. In addition, in the study of structural type, the results obtained by this study using x_my show that the material containing the side chain cage (4) Wei Zhiwei is a non-crystalline crane structure. There is no characteristic peak of poly-sesquiterpene oxide in the higher cage-like polypyrexate, which also confirms the good self-sufficiency of the prepared chain-like cage Weisweiwei shovel material. There is no age away from Wei. 3 j-key cage, sub-scanning microscope (SEM) found that the epoxy resin material of the side chain cage-like siloxane of the present invention has no phase separation phenomenon of phase I and raw H. In the Si_ma_g map, it is also found that the Shixia oxygen burn has a good and uniform distribution. In the test of optical properties, it can be found that p〇ss_Ep〇x}^ is a critical point when adding 5 〇 edge. Adding ^ in POSS-Epoxy, because the compatibility of shixi oxy-combustion with epoxy resin is poor, The poorer the light transmittance of the nano-compliant material. A one-step test of the cleavage kinetics revealed that with the increase in the amount of POSS-Epoxy added, the cracking of the Wei-Ling material containing the side chain caged Weiwei material showed that it had excellent stability. "The preparation of the 含 丨 纽 纽 纽 _ _ 本 本 本 本 本 本 本 本 本 本 本 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽 纽Developed epoxy resin material with side chain caged siloxanes. It can be used for the construction of secret public engineering projects, _ military equipment and various types of fire protection coatings, household decoration fillers, in addition, this The invention also has excellent light impurities, and therefore can be taken into account in the lens protective layer of the photoelectric element, the display accessories, etc. 15 201008967 However, only the above, only The present invention is not limited to the embodiments of the present invention, and the equivalents and modifications of the structures, features, and spirits of the present invention should be included in the present invention. Patent application: [Simplified description of the drawings] The first figure is a flow chart of the steps for preparing the epoxy resin of the side chain cage-shaped decane of the present invention. The second figure is the side chain cage of the invention (4) Wei's epoxy _ The step of preparing green for the material. 帛二目^本(4) Schematic diagram of the chemical reaction of the epoxy resin prepared by the DGEBA to prepare the side chain caged siloxane. The fourth figure is the ring of the invention. Schematic diagram of the chemical reaction of epoxy resin (DGEBA) and side chain caged alkoxylate epoxy resin.

The fifth figure is the mR spectrum of the reaction of the epoxy resin (DGEBA) with polysilsesquioxane (IP1-P〇SS). = Six figures are the iFT_IR spectrum of the epoxy resin of the side chain caged siloxane of the present invention. The seventh figure is a map of the gambling material of the New Zealand Red County tree after hardening of the present invention. The figure is an identification spectrum of the solid state of the polypothala oxysulphur of the present invention.第九 The ninth figure is a spectrum of the solid-state 29Si-NMR identification of the epoxy resin material containing side chain cage siloxane. The tenth graph is a graph showing the relationship between the epoxy resin material of the side chain cage-like siloxane and the glass transition temperature of the side chain cage-like oxy-oxygenated epoxy resin (POSS-Epoxy) containing different weight percentages. ^S*f | The figure is an epoxy resin material containing a side chain 4-oxo alkane of an epoxy resin containing different weight percentages of side chain cage alkane and 5 wt ° /. Thermal weight loss temperature diagram. 11 is the weight percentage of the epoxy resin of the side-chain-like Coke Oxygen-containing epoxy resin containing the side chain caged siloxane of different weight percentages in the 8 〇〇〇 CT coke Figure. The thirteenth figure is the XRJ of the side of the epoxy resin containing the side chain caged siloxane of different weight percentages. Fig. 14 is a scanning electron micrograph of an epoxy resin material containing a side-chain cage-like Oxygen-oxygenated epoxy resin containing 5% side chain caged siloxane. - Fig. 15 is a scanning electron micrograph of an epoxy resin material containing a side chain cage-like oxaxy oxide of an epoxy resin containing 15% of a side chain caged siloxane. Fig. 16 is a scanning electron micrograph of an epoxy resin material containing a side chain cage-like oxy-cylylene oxide of an epoxy resin of 5 〇% side chain cage-like stone. Fig. 17 is a diagram showing the enthalpy spectrum of the epoxy resin material containing the side-chain cage-like Oxygen-oxygenated epoxy resin of the epoxy resin added with 5% side chain cage-like siloxane.帛+八图 is a graph of the analysis of the stone enamel spectrum of the epoxy resin material containing the side-chain cage-like oxoxane of the epoxy resin of the side-chain cage-like stone-like oxygen chamber of the present invention. Fig. 19 is a diagram showing the 矽 矽 矽 矽 环氧树脂 环氧树脂 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 Fig. 10 is a UV/Vis diagram of an epoxy resin material containing a side chain cage-like siloxane according to the present invention containing side chain cages of different weight percentages. [Main component symbol description] None ❹ 17

Claims (1)

201008967 X. Patent application scope: 1. A side chain braided stone oxide epoxy resin, including: H, C: a CHCHv "Ο-..-.... OCH2CH-Cl·% (CH2)3 CH3—ii-CH5 —O—rSi ❹ Si...force...;k .0 RR R—where n is an integer from 1 to i〇; and wherein R is selected from methyl and B One of the group of propyl, propyl and isobutyl groups 2. The preparation method of the epoxy resin of the side chain cage hospital, the steps of which include: · epoxy resin and bismuth polyhalogen The alkane 2 = t_pyldimethylsilyl_isGbutyl_poss) reacts to form a side-chain cage-like oxalate 13⁄4 emulsion resin. φ 3. Preparation of ^ 峨 魏 Wei Wei Wei Wei Jia: Formation of heteropoly hexa-Wei morphological formation __状# _物峨峡(四)_Preparation of alkane epoxy · The purpose of Wei Weiwu _ chain cage矽 矽: 5:1 〇 鳞 纯 魏 魏 魏 Wei Wei Wei Wei Wei Wei Wei Wei Wei Wei Wei Wei Wei Wei Wei Wei Wei Wei Wei Wei Wei Preparation; the formation of the Xixia oxythermal reaction to form the side, the cage-like stone 聋 聋 201008967 appearance of the gas-making resin step, let the _ JL _ epoxy resin and the cage poly-semi-stone oxidative reaction step Diethylamine I t application description of the Qi (4) Wei Zhihuan _ preparation of the appearance of epoxy resin: sudden:: = c tender reaction to form the pot Wei Wei Ο 7.nrr:Trrrr,-: =: one - Huai cage The Epoxy Resin Reaction of the Weiwei Formation is obtained by the side chain cage 8' 矽 oxygen i cage polymorphic oxidative reaction to form the side bond cage +, the tender lion is compiled in the fourth _ 9·: ^ ΓΓ 围 circumference 7 The epoxy resin material containing the side bond containing Weixuan is prepared by reacting the epoxy tree and the cage polypothalamite to form the side key cage shape, which is more than the secret pattern. Wei Ji and his post (4) The amount of 10, ===7 of the epoxy resin material containing the side bond cage-like epoxy material is ΐ ΐ ΐ 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二 二In the step, a step of catalyzing the reaction of 4% lysine and the caged polyp-halus oxysphate is further included. 7 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The reaction temperature of the step of the oxygenating resin is 6 〇{>c. 12', as described in claim 7, the side chain cage-like gas-fired epoxy resin material made of 201008967, the method of f, wherein the epoxy resin and the cage poly-half stone The reaction time of the step of reacting the epoxy resin forming the side chain cage-like siloxane was 10 hours. I3·If Shen Hao specializes in her 7th riding, the cage-like Wei Weiwei resin material is made of 'the oxygen-touching and domain-like miscellaneous special anti-Qing Lai side chain cage Wei Wei Wei Wei resin step towel It also includes the steps of the lion's sentence and the return. 4. The method for manufacturing a side chain-like cage-like epoxy resin material according to claim 7 of the patent scope, the method of the invention, the towel and the side chain cage 7 oxygen burning The epoxy resin reaction obtained the reaction temperature of the Weihai 3 side key Wei Weiquan Wei fine material, and the reaction temperature was room temperature. _ . Such as _ Μ Μ Μ 帛 帛 帛 帛 帛 帛 ( ( ( ( ( 四 四 四 四 四 四 四 四 四 四 四 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏 魏The reaction time of the step of the epoxy resin material of the side chain of the side chain is i hours. For example, Shen π specializes in the preparation of the method for the preparation of the 7-year-old Weiling 6 Weiling material, which is obtained by reacting the epoxy resin with the epoxy resin of the side chain caged siloxane. In the step of the side-chain cage-like rhodium-oxocycloolefin resin material, the step of adding a hardener is further included. For example, the 18' of the epoxy resin material containing the side chain cage-like oxirane described in the scope of claim 16 is the 4', and the hardener is 4,4'-diaminobenzophenone (4,4). '-Methylenedianiline). The preparation of the epoxy resin material containing the side chain cage alkane described in the patent scope of claim 16 is prepared by the step of adding the hardener, and further comprises the step of leaving it at room temperature for one day. The method for preparing an epoxy resin material containing a side chain cage-like alkaloid according to claim 18, wherein the step of leaving the room at room temperature further comprises a baking step.