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TW201008356A - Planar heating source - Google Patents

Planar heating source Download PDF

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Publication number
TW201008356A
TW201008356A TW97130300A TW97130300A TW201008356A TW 201008356 A TW201008356 A TW 201008356A TW 97130300 A TW97130300 A TW 97130300A TW 97130300 A TW97130300 A TW 97130300A TW 201008356 A TW201008356 A TW 201008356A
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Taiwan
Prior art keywords
layer
heat source
surface heat
heating
disposed
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TW97130300A
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Chinese (zh)
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TWI380730B (en
Inventor
Ding Wang
Chang-Hong Liu
Shou-Shan Fan
Kai-Li Jiang
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Hon Hai Prec Ind Co Ltd
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Priority to TW97130300A priority Critical patent/TWI380730B/en
Publication of TW201008356A publication Critical patent/TW201008356A/en
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Publication of TWI380730B publication Critical patent/TWI380730B/en

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Abstract

The present invention relates to a planar heating source. The planar heating source includes at least two electrodes and a heating layer. The at least two electrodes are separately disposed and electrically contacted with the heating layer. The heating layer includes a plurality of carbon nanotubes. The carbon nanotubes are entangled with each other.

Description

201008356 九、發明說明: 【發明所屬之技術領域】 .的面ίΓ涉及—種面熱源,尤其涉及—種基於奈米碳管 的面熱源。 【先前技術】 熱源在人們的生產、生活、科研令起著重要的作用。 ::源係熱源的一種,其特點為面熱源具有一平面結構, ^寺加,物體置於該平面結構的上方對物體進行加敎, ❹磨:可對待加熱物體的各個部位同時加熱,加熱面 :、、均勻且效率較高。面熱源已成功用於工業領域、 =領域或生活領域等,如電加熱器、紅外治療儀、電暖 ,丨、雨f::熱源一般包括一加熱層和至少兩個電極,該至 電=置於該加熱層的表面,並與該加熱層的表面 - 田接加熱層上的電極通入低電壓電流時,埶量 層釋放出來。現在市售的面熱源通常採用:屬 參絲作為加熱層進行電熱轉換。然而,電熱絲的 鹿折斷’特別係,曲或繞折成-定角度時,故 :並U二。另’以金屬製成的電熱絲所產生的熱量係 能二^ / °夕卜輕射的’其電熱轉換效率不高不利於節省 非,屬碳纖維導電材料的發明為面熱源的發展帶來了 ^ 米用妷纖維的加熱層通常在碳纖維外部塗覆一層防 碳作電熱_的元件以代替金屬電熱絲。由於 、較好的韌性,這在一定程度上解決了電熱絲強 201008356 度不咼易折斷的缺點。然而,由於碳纖維仍係以普通波長 向外散熱,故並未解決電熱轉換率低的問題。為解決上述 問題,採用碳纖維的加熱層一般包括多根碳纖維熱源線鋪 •設而成。該碳纖維熱源線為一外表包裹有化纖或者棉線的 V電心線該化纖或者棉線的外面浸塗一層防水阻燃絕緣 材料。所述導電芯線由多根碳纖維與多根表面粘塗有遠紅 .外塗料的棉線纏繞而成。導電芯線中加入粘塗有遠紅外塗 料的棉線,一來可增強芯線的強度,二來可使通電後碳導 ϋ纖維發出的熱量能以紅外波長向外輻射。 然而,採用碳纖維紙作為加熱層具有以下缺點:第一, 碳纖維強度不夠大,柔性不夠好,容易破裂,需要加入棉 線提高碳纖維的強度,限制了其應有範圍;第二,碳纖維 本^的電熱轉換效率較低,需加入枯塗有遠紅外塗料的棉 線提高電熱轉換效率,不利於節能環保;第三, J纖維熱源線再製成加熱層’不利於大面積製作,不利於 =勻I·生的要求’同時,不利於微型面熱源的製作。 ❾ 有#於此’提供—種具有強度大’電熱轉換效率較高, 源且發熱均句’大小可控,可製成大面積或 者从型的面熱源實為必要。 【發明内容】 設置於源’其包括·一基底;-加熱層,該加熱層 敎層電面;至少兩電極間隔設置且分別與該加 二中’所述加熱層包括-奈米碳管層,該夺 “厌s層包括複數個相互纏繞的奈米碳管。 所、成i目ϊ與先前技術’所述之面熱源具有以下優點:第-, 、不米碳管層巾的奈米碳f無序㈣,具有报好的動 201008356 ,丄可,曲折疊成任意形狀而不破裂,故具有較長的使用 f命。第二’奈米碳管層中的奈米碳管均句分佈,奈米碳 s層具有2勻的厚度及電阻,發熱均勻’奈米碳管的電熱 •轉換效率尚,故該面熱源具有升溫迅速、熱滯後小、熱交 ,,度陕的特點。第三’奈米碳管的直經較小,使得奈米 石反营層具有較小的厚度,可製備微型面熱源,應用於微型 器件的加熱。 f 【實施方式】 ❹ =下將結合附圖詳細說明本技術方案面熱源。 請參閱圖1及圖2,本技術方案實施例提供一種面献 源1〇,該面熱源10包括一基底18、一反射層17、一加 :、層16第-電極12、—第二電極14和—絕緣保護 層15。所述反射層17設置於基底18的表面。所述加埶 ^ 16設置於所述反射層17的表面。所述第—電極^ 第二電極14間隔設置,並分別與該加熱層16電接觸, 用於使所述加熱層16卡流過電流。所述絕緣保護層Η 〇,置於所述加熱層16的表面,並將所述第一電極Η和 =二電極14覆蓋1於避免所述加熱層16吸附外界雜 質。 所述基底18形狀不限,其具有—表面用於支樓加熱 曰或者反射層17。優選地,所述基底18為一板狀美 =其:料可為硬性材料’如:陶竞、玻璃、樹脂、二 央專’亦可選擇柔性材料’如:塑膠或柔性纖維等。杏 =料該面熱源1〇在使用時可根據需要弯折: 任思形狀。其中,基底18的大小不限,可依據實際 進行改變。本實施例優選的基底18為一陶瓷基板。 8 201008356 量,層17的設置用來反射加熱層16所發的熱 :加:二!熱的方向,用於單面加熱,並進-步提 •:=屬率氧=反㈣17的材料為一白色絕緣材 •反射声以屬^ 金屬鹽或陶瓷等。本實施例中, 該;5 ^品二氧化二鋁層,其厚度為100微米〜〇.5毫米。 =叮、17可通過減射或其他方法形成於該基底以表 = Γ 所述反射層17也可設置在基底18遠離 和即所述基底18設置於所述加熱層16 ❹^述反射層17之間,進—步加強反射層17反射敎量 的作用。所述反射層17為—可選擇的結構。所述加熱層 ^接5又置在基底18的表面,此時面熱源10的:埶 方向不限,可用於雙面加熱。 ”、、 所述加熱層16設置於基底18的表面’用於加熱。所 熱層16包括-奈米碳管層,該奈米碳管層本身具有 疋的粘性,可利用本身的粘性設置於基底18的表面, 可通過枯、(劑s又置於基纟18的表面。所述之枯結劑為 ❹:膠。該奈来碳管層的長度、寬度和厚度不限,可根據 實際需要選擇。本技術方案提供的奈米碳管層的長度為 1〜10厘米,寬度為1〜10厘米,厚度為i微米〜2毫米。 可以理解,奈米碳管層的熱回應速度與其厚度有關。在 相同面積的情況下,奈米碳管層的厚度越大,熱回應速 度越慢;反之,奈米碳管層的厚度越小,熱回應速度越 快。 所述奈米碳管層包括相互纏繞的奈米碳管,請參閱 圖3。所述之奈米碳管之間通過凡德瓦爾力相互吸引二纏 繞,开> 成網路狀結構。該奈米碳管層中,奈米碳管為均 9 201008356 勻分佈,無規則排列,使得該奈米碳管層呈各向同性; 奈米碳管相互纏繞’故該奈米碳管層具有很好的柔韌 性’可彎曲折疊成任意形狀而不破裂,請參閲圖4。該奈 米碳管層中的奈米碳管包括單壁奈米碳管、雙壁奈米碳 管及多壁奈米碳管中的一種或多種。所述單壁奈米碳管 的直徑為0.5奈米〜10奈米,雙壁奈米碳管的直徑為1〇 奈米〜15奈米’多壁奈米碳管的直徑為ι.5奈米〜5〇奈米。 *亥奈米奴管的長度大於50微米。本實施例中,奈米碳管 ❹的長度優選為200〜900微米。 本實施例中,加熱層16採用厚度為1〇〇微米的奈米 碳官層。該奈米碳官層的長度為5厘米,奈米碳管層的 寬度為3厘米。利用奈米碳管層本身的粘性,將該奈米 碳管層設置於基底18的表面。 所述第一電極12和第二電極14由導電材料組成,該 第一電極12和第二電極14的形狀不限,可為導電薄膜、 金屬片或者金屬引線。優選地,第一電極12和第二電極 ❹Li句為:ίΠ薄膜。該導電薄膜的厚度為〇.5奈米〜_ 微未。該導電薄膜的材料可為金屬、合金、銦錫氧化物 録錫氧化物(ΑΊΌ)、導電銀膠 '導電聚合物或導 =性不未碳管等。該金屬或合金材料可為銘、銅、鶴、銷、 所诚把、絶或其任意組合的合金。本實施例中, 電極12和第二電極14的材料為金屬鈀膜,厚声 有利二述金屬1巴與奈米碳管具有較好的潤濕效果: 有利於所述第一電極12及第二電極14與所述 之間形成良好的電接觸,減少歐姆接觸電阻。♦、日 所边之第-電極12和第二電極14可設置在加熱^ 201008356 16的,表面上也可設置在加熱層i6的不同表面上。其 二庙第田一電極12和第二妹14間隔設置,以使加熱層 於面熱源10時接入一定的阻值避免短路現象產 ==作為加熱層16的奈米碳管層本身有很好的粘附 電極12和第二電極14直接就可與奈米碳管 層之間形成很好的電接觸。 另,所述之第一電極12和第二電極14也可通過一 電粘結劑(圖未不)設置於該加熱層16的表 ❹現第一電極12和第二電極14與加熱二接 觸的同時,還可將所述第一電極12和第二電極Η更好 加熱層16的表面上。本實施例優選的導電枯結 劑為銀膠。 ° 乂理解帛電極12和第二電極14的結構和材料 :不限’其設置目的係為了使所述加熱層16中流過電 :斑^所述第一電極12和第二電極14只需要導電, m ^处加熱層16之間形成電接觸都在本發明的保護範 圍内。 =述絕緣保護層15為—可選擇結構,其材料為一絕 ,材料,如:橡膠、樹脂等。所述絕緣保護層15厚度不 =可根據實際情況選擇。所述絕緣保護層15覆蓋於所 述第一電極12、第二電極14和加熱層16之上,可使該 面熱源10在絕緣狀態下使用’同時還可避免所述加埶層 中的奈来碳管吸附外界雜質。本實施例中,該絕緣保 谩層15的材料為橡膠,其厚度為〇5〜2毫米。 本技術方案實施例的面熱源10在使用時,可先將面熱 Μ切的第一電極12和第二電極14連接導線後接入電源: 11 201008356 2入電源後熱源10 t的奈米碳管層即可輻射 長範圍的電磁波。所述面献源20 ϋ # 4 # / ^ …、席2U 了與待加熱物體的表面直 2觸。或者’由於本實施例中作為加熱層 層中的奈米碳管具有良好的導電性 ”未厌g •身P绍且古一 — ΛΑ ώ ^且該奈米碳管層本 =物穩定性,所述面熱源20可與 捋加熱物體相隔一定的距離設置。 稽大案實施例中的面熱源10在奈米碳管層的面 積大小疋時,可通過調節電源電壓大小和夺米 ❹厚二可輻射出不同波長範圍的電磁波。電源電 小 二奈米:炭管層的厚度和麵熱源、1〇 的波長 t即虽電源電壓大小一定時,奈米碳管層的厚度越 2面熱源iO輻出電磁波的波長越短,該面熱源1〇可產 一可見錢輻射’·奈米碳管層的厚度越薄,面轨源ι〇 t出電磁波的波長越長,該面熱源10可產生-紅外線就輻 10=碳管層的厚度一定時,電源電壓的大小和麵熱源 10輻出電磁波的波長成反比。即當奈米碳管層的厚度一定 β時,電源電壓越大,面熱源W輻出電磁波的波長越短,該 面熱源10可產生一可見光熱輻射;電源電壓越小,面熱源 1〇輻出電磁波的波長越長,該面熱源1〇可產生一紅外熱 輻射。 、… 奈米碳官具有良好的導電性能以及熱穩定性,且作為 一理想的黑、體結構’具冑比較高的熱輻射效率。將該面熱 源10暴露在氧化性氣體或者大氣的環境中,其中奈米碳管 層的厚度為5毫米,通過在1〇伏〜3〇伏調節電源電壓,該 面熱源10可輕射出波長較長的電磁波。通過溫度測量儀發 現該面熱源10的溫度為5〇〇c〜5〇(rc。對於具有黑體結構 12 201008356 ,其所對應的溫度為2〇〇t〜45(rc時就能發出 率爭\ ^的熱輕射(紅外線),此時的熱輻射最穩定、效 力赦二用°亥奈米奴菅層製成的發熱元件,可應用於電 口…、益、紅外治療儀、電暖器等領域。 =一步地j將本技術方案實施例中的面熱源1〇放入— 、、/i 置中通過在80伏〜150伏調節電源電壓,該面熱 ❹ "' .可輻射出波長較短的電磁波。當電源電壓大於15〇 二’ ^面熱源、1〇陸續會發出紅光、黃光等可見光。通過 二=凋置儀發現該面熱源1〇的溫度可達到15〇〇艺以上, _會產生一普通熱輻射。隨著電源電壓的進一步增大, =熱源10還能產生殺死細菌的人眼看不見的射線(紫外 光),可應用於光源、顯示器件等領域。 所述之面熱源具有以下優點:第―,由於奈米碳管具 ^較好㈣度幼性,奈㈣f層的強度較大,奈米碳管 太的柔性好’不易破裂,使其具有較長的使用壽命。第二, 不米碳管層中的奈米碳管均勻分佈,奈米碳管層具有均勻 、^度及電阻,發熱均勻,奈米碳管的電熱轉換效率高, 故該面,源具有升溫迅速、熱滯後小、熱交換速度快、輕 ^效率尚的特點。第三,奈米碳管的直徑較小,使得奈米 ,管層具有較、的厚度,可製備微型面㈣,應用於微型 器件的加熱。 θ綜上所述,本發明確已符合發明專利之要件,遂依法 提出專利申請。惟,以上所述者僅為本發明之較佳實施例, 自不能以此限制本案之申請專利範圍。舉凡熟悉本案技藝 =人士援依本發明之精神所作之等效修飾或變化,皆應涵 蓋於以下申請專利範圍内。 13 201008356 [圖式簡單說明】 圖1為本技術方案實施例的面熱源的結構示意圖。 圖2為圖1沿線的剖面示意圖。 圖3為本技術方案實施例的奈米碳管層的掃描電鏡照 圖4為本技術方案實施例的奈米碳管層的照片。 【主要元件符號說明】 面熱源 10 第一電極 12 第二電極 14 絕緣保護層 15 加熱層 16 反射層 17 基底 18201008356 IX. Description of the invention: [Technical field of the invention] The surface of the invention relates to a surface heat source, in particular to a surface heat source based on a carbon nanotube. [Prior Art] Heat sources play an important role in people's production, life, and scientific research. :: A source heat source, characterized in that the surface heat source has a planar structure, ^ Temple plus, the object is placed above the planar structure to strengthen the object, honing: the various parts of the object to be heated are simultaneously heated, heated Face:, uniform and efficient. The surface heat source has been successfully used in industrial fields, = fields or living areas, such as electric heaters, infrared therapeutic devices, electric heating, helium, rain f:: heat sources generally include a heating layer and at least two electrodes, the electric = The enthalpy layer is released when it is placed on the surface of the heating layer and a low voltage current is applied to the electrode on the surface of the heating layer. Commercially available surface heat sources are now commonly used: as a heating layer for electrothermal conversion. However, the deer of the electric heating wire is broken, especially when it is bent or twisted into a fixed angle, so: U and U. In addition, the heat generated by the electric heating wire made of metal can be lighter than that of the electric heating conversion. The electrothermal conversion efficiency is not high, which is not conducive to saving. The invention of the carbon fiber conductive material has brought about the development of the surface heat source. ^ The heating layer of bismuth fiber is usually coated with a layer of carbon-proof electric heating element on the outside of the carbon fiber instead of the metal heating wire. Due to the good toughness, this solves the shortcomings of the electric heating wire strength 201008356 degree. However, since the carbon fiber is still radiated outward at a normal wavelength, the problem of low electrothermal conversion rate is not solved. In order to solve the above problems, the heating layer using carbon fiber generally includes a plurality of carbon fiber heat source lines. The carbon fiber heat source line is a V-core wire wrapped with chemical fiber or cotton thread. The outer surface of the chemical fiber or cotton thread is dip coated with a waterproof flame-retardant insulating material. The conductive core wire is formed by winding a plurality of carbon fibers and a plurality of surfaces coated with a far red color. The cotton wire coated with the far-infrared coating is added to the conductive core wire to enhance the strength of the core wire. Secondly, the heat generated by the carbon fiber after the energization can be radiated outward at the infrared wavelength. However, the use of carbon fiber paper as the heating layer has the following disadvantages: First, the carbon fiber strength is not large enough, the flexibility is not good enough, and it is easy to be broken. It is necessary to add cotton wire to increase the strength of the carbon fiber, and limit its proper range; second, the electric heating of the carbon fiber The conversion efficiency is low, and it is necessary to add the cotton wire coated with the far-infrared coating to improve the electrothermal conversion efficiency, which is not conducive to energy conservation and environmental protection. Thirdly, the J fiber heat source line is further made into a heating layer, which is not conducive to large-area production, which is not conducive to = uniform I· The requirements of life' at the same time are not conducive to the production of micro-surface heat sources. ❾ There is a kind of surface heat source that has a high intensity and a high electrothermal conversion efficiency, and the source and the heat are all controllable, and can be made into a large area or a type of surface heat source. The invention provides a source 'which includes a substrate; a heating layer, the heating layer is a layer of electricity; at least two electrodes are spaced apart and respectively, and the heating layer includes a carbon nanotube layer The surface heat source of the "an s layer including a plurality of intertwined carbon nanotubes. The surface heat source described in the prior art" has the following advantages: the -, -, and the carbon nanotubes of the carbon nanotubes Carbon f disorder (four), with good movement 201008356, 丄 可, 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲 曲Distribution, nano carbon s layer has 2 uniform thickness and electrical resistance, uniform heating 'nano carbon tube electric heating · conversion efficiency is still, so the surface heat source has the characteristics of rapid temperature rise, small thermal hysteresis, heat exchange, and degree of Shaanxi. The direct transmission of the third 'nanocarbon tube is small, so that the reverse layer of the nano-stone has a small thickness, and a micro-surface heat source can be prepared for heating of the micro device. f [Embodiment] ❹ = the lower part will be attached The figure details the surface heat source of the technical solution. Please refer to FIG. 1 and FIG. 2, the technology The embodiment provides a surface source 1 that includes a substrate 18, a reflective layer 17, an additive layer, a layer 16 first electrode 12, a second electrode 14, and an insulating protective layer 15. The reflective layer 17 is disposed on the surface of the substrate 18. The ridges 16 are disposed on the surface of the reflective layer 17. The first electrodes and the second electrodes 14 are spaced apart and electrically contacted with the heating layer 16, respectively. The electric current is caused to flow through the heating layer 16. The insulating protective layer is placed on the surface of the heating layer 16, and the first electrode and the second electrode 14 are covered 1 to avoid the heating. The substrate 16 adsorbs foreign matter. The shape of the substrate 18 is not limited, and has a surface for heating the crucible or the reflective layer 17. Preferably, the substrate 18 is a plate-shaped beauty=it: the material may be a hard material' Such as: Tao Jing, glass, resin, Eryang special 'can also choose flexible materials' such as: plastic or flexible fiber, etc. Apricot = material This surface heat source 1 弯 can be bent as needed when using: Ren Si shape. The size of the substrate 18 is not limited and can be changed according to the actual. The preferred base of this embodiment 18 is a ceramic substrate. 8 201008356 Quantity, layer 17 is set to reflect the heat generated by the heating layer 16: plus: two! hot direction, for single-sided heating, and step-by-step introduction:: = rate oxygen = The material of the anti-(four) 17 is a white insulating material. • The sound is reflected by a metal salt or a ceramic. In this embodiment, the layer of the aluminum oxide layer has a thickness of 100 μm to 〇.5 mm. 17 may be formed on the substrate by subtractive or other methods to indicate that the reflective layer 17 may also be disposed away from the substrate 18 and that the substrate 18 is disposed between the heating layer 16 and the reflective layer 17. Further, the effect of reflecting the amount of reflection of the reflective layer 17 is enhanced. The reflective layer 17 is an optional structure. The heating layer 5 is placed on the surface of the substrate 18 at this time: the direction of the surface heat source 10: Not limited to, can be used for double-sided heating. The heating layer 16 is disposed on the surface of the substrate 18 for heating. The heated layer 16 includes a carbon nanotube layer, which itself has a ruthenium viscosity and can be disposed by utilizing its own viscosity. The surface of the substrate 18 can pass through, and the agent s is placed on the surface of the base 18. The dead agent is ❹: glue. The length, width and thickness of the carbon nanotube layer are not limited, according to the actual The carbon nanotube layer provided by the technical solution has a length of 1 to 10 cm, a width of 1 to 10 cm, and a thickness of 1 micrometer to 2 mm. It can be understood that the thermal response speed of the carbon nanotube layer and its thickness are understood. In the case of the same area, the greater the thickness of the carbon nanotube layer, the slower the thermal response speed; conversely, the smaller the thickness of the carbon nanotube layer, the faster the thermal response speed. Including the intertwined carbon nanotubes, please refer to Fig. 3. The carbon nanotubes are attracted to each other by van der Waals force, and the network structure is formed. In the carbon nanotube layer, The carbon nanotubes are evenly distributed on the 9 201008356, and the irregular arrangement makes the nano The tube layer is isotropic; the carbon nanotubes are intertwined 'so the carbon nanotube layer has good flexibility' and can be bent into any shape without breaking, see Figure 4. The carbon nanotube layer The carbon nanotubes in the middle include one or more of a single-walled carbon nanotube, a double-walled carbon nanotube, and a multi-walled carbon nanotube. The diameter of the single-walled carbon nanotube is 0.5 nm to 10 nm. The diameter of the double-walled carbon nanotubes is 1 〇 nanometer ~ 15 nanometers. The diameter of the multi-walled carbon nanotubes is ι.5 nm ~ 5 〇 nanometer. * The length of the hemi nanotubes is greater than 50 In this embodiment, the length of the carbon nanotubes is preferably 200 to 900 μm. In this embodiment, the heating layer 16 is a nano carbon layer having a thickness of 1 μm. The length is 5 cm, and the width of the carbon nanotube layer is 3 cm. The carbon nanotube layer is placed on the surface of the substrate 18 by the viscosity of the carbon nanotube layer itself. The first electrode 12 and the second electrode 14 is composed of a conductive material, and the shapes of the first electrode 12 and the second electrode 14 are not limited and may be a conductive film, a metal piece or a metal lead. Preferably, The first electrode 12 and the second electrode ❹Li are: Π Π film. The thickness of the conductive film is 〇.5 nm~_micro. The material of the conductive film can be tinned by metal, alloy, indium tin oxide. (ΑΊΌ), conductive silver plastic 'conductive polymer or conductive = non-carbon tube, etc. The metal or alloy material can be Ming, copper, crane, pin, honest, absolutely or any combination of alloys. In the embodiment, the material of the electrode 12 and the second electrode 14 is a metal palladium film, and the thick sound is advantageous for the metal 1 bar and the carbon nanotube to have better wetting effect: facilitating the first electrode 12 and the second electrode The electrode 14 forms a good electrical contact with the ohmic contact resistance. The first electrode 12 and the second electrode 14 can be disposed on the heating surface of 201008356 16, and the surface can also be disposed on the heating layer. I6 on different surfaces. The second temple of the second field electrode 12 and the second sister 14 are spaced apart so that the heating layer is connected to the surface heat source 10 to a certain resistance value to avoid short circuit phenomenon. == The carbon nanotube layer itself as the heating layer 16 is very The good adhesion electrode 12 and the second electrode 14 directly form a good electrical contact with the carbon nanotube layer. In addition, the first electrode 12 and the second electrode 14 may also be disposed on the surface of the heating layer 16 through an electrical adhesive (not shown). The first electrode 12 and the second electrode 14 are in contact with the heating electrode. At the same time, the first electrode 12 and the second electrode 还可 can also be better heated on the surface of the layer 16. A preferred conductive dry binder of this embodiment is a silver paste. ° 乂Understand the structure and material of the erbium electrode 12 and the second electrode 14: not limited to the purpose of setting the electric current in the heating layer 16: the first electrode 12 and the second electrode 14 need only be electrically conductive It is within the scope of the present invention to form electrical contacts between the heating layers 16 at m ^ . The insulating protective layer 15 is an optional structure, and the material thereof is a material such as rubber or resin. The thickness of the insulating protective layer 15 is not = can be selected according to actual conditions. The insulating protective layer 15 covers the first electrode 12, the second electrode 14 and the heating layer 16, so that the surface heat source 10 can be used in an insulated state while avoiding the nephew in the twisted layer. The carbon tube absorbs foreign impurities. In this embodiment, the insulating protective layer 15 is made of rubber and has a thickness of 〇5 to 2 mm. When the surface heat source 10 of the embodiment of the present technical solution is used, the first electrode 12 and the second electrode 14 which are hot-cut can be connected to the power source after being connected to the power source: 11 201008356 2 The carbon source of the heat source 10 t after the power source is turned into The tube layer can radiate a long range of electromagnetic waves. The surface source 20 ϋ # 4 # / ^ ..., the seat 2U is 2 touches to the surface of the object to be heated. Or 'because the carbon nanotubes in the heating layer in the present embodiment have good conductivity", the body is not dissipated, and the body of the carbon nanotube layer is stable. The surface heat source 20 can be disposed at a certain distance from the heating object. The surface heat source 10 in the embodiment of the case can adjust the power supply voltage and the thickness of the rice when the area of the carbon nanotube layer is 疋. It can radiate electromagnetic waves of different wavelength ranges. The power supply is small: the thickness of the carbon tube layer and the surface heat source, the wavelength t of 1〇, that is, the thickness of the carbon nanotube layer is 2, the heat source iO, although the power supply voltage is constant. The shorter the wavelength of the radiated electromagnetic wave, the light source of the surface can produce a visible radiation radiation. The thinner the thickness of the carbon nanotube layer, the longer the wavelength of the surface rail source ι〇t electromagnetic wave, the surface heat source 10 can be generated. - Infrared radiation 10 = When the thickness of the carbon tube layer is constant, the magnitude of the power supply voltage is inversely proportional to the wavelength of the electromagnetic wave radiated from the surface heat source 10. That is, when the thickness of the carbon nanotube layer is constant β, the power supply voltage is larger, the surface heat source The shorter the wavelength of the electromagnetic wave radiated by W, the surface heat source 10 A visible light heat radiation is generated; the smaller the power supply voltage is, the longer the wavelength of the surface heat source 1 〇 emits electromagnetic waves, the surface heat source 1 〇 can generate an infrared heat radiation. ,... The nano carbon official has good electrical conductivity and thermal stability. And as an ideal black and body structure' has a relatively high heat radiation efficiency. The surface heat source 10 is exposed to an oxidizing gas or an atmosphere, wherein the thickness of the carbon nanotube layer is 5 mm, 1 〇 〜 3 〇 调节 adjust the power supply voltage, the surface heat source 10 can lightly emit electromagnetic waves with a long wavelength. The temperature of the surface heat source 10 is found by a temperature measuring instrument to be 5 〇〇 c 5 〇 (rc. for a black body structure 12 201008356, the corresponding temperature is 2〇〇t~45 (when rc can issue a thermal light shot (infrared), the heat radiation is the most stable, the effect is the second. The heating element made of the enamel layer can be applied to the fields of electric ports, benefits, infrared therapeutic devices, electric heaters, etc. = One step is to put the surface heat source 1 in the embodiment of the present technical solution into -, , /i Centering by adjusting the supply voltage at 80 volts to 150 volts The surface is hot "'. It can radiate electromagnetic waves with a shorter wavelength. When the power supply voltage is greater than 15〇2' surface heat source, 1〇 will emit visible light such as red light and yellow light. It is found by the second=falling instrument. The temperature of the surface heat source can reach 15 〇〇 or more, and _ will generate a common heat radiation. With the further increase of the power supply voltage, the heat source 10 can also generate rays (ultraviolet light) that are invisible to the human eye that kills the bacteria. It can be applied to the fields of light source, display device, etc. The surface heat source has the following advantages: ―, because the carbon nanotubes have a good (four) degree of juvenileness, the strength of the na(4)f layer is large, and the carbon nanotubes are too The flexibility is 'not easy to break, so it has a long service life. Second, the carbon nanotubes in the carbon nanotube layer are evenly distributed, the carbon nanotube layer has uniformity, ^ degree and resistance, and the heat is uniform. The carbon-carbon tube has high electrothermal conversion efficiency, so the source has the characteristics of rapid temperature rise, small heat lag, fast heat exchange rate, and light efficiency. Third, the diameter of the carbon nanotubes is small, so that the nano tube layer has a relatively thick thickness, and the micro surface (four) can be prepared for heating of the micro device. In summary, the present invention has indeed met the requirements of the invention patent, and has filed a patent application in accordance with the law. However, the above description is only a preferred embodiment of the present invention, and it is not possible to limit the scope of the patent application in this case. Equivalent modifications or variations made by persons in accordance with the spirit of the present invention are intended to be within the scope of the following claims. 13 201008356 [Simple Description of the Drawings] FIG. 1 is a schematic structural view of a surface heat source according to an embodiment of the present technical solution. Figure 2 is a cross-sectional view along line of Figure 1. Fig. 3 is a scanning electron microscope of the carbon nanotube layer of the embodiment of the present invention. Fig. 4 is a photograph of the carbon nanotube layer of the embodiment of the present invention. [Main component symbol description] Surface heat source 10 First electrode 12 Second electrode 14 Insulating protective layer 15 Heating layer 16 Reflecting layer 17 Substrate 18

Claims (1)

201008356 十、申請專利範圍 ^ 一種面熱源,其包括: —基底; —加熱層’該加熱層設置於該基底的表面;以及 至少兩電極’該至少兩個電極間隔設置且分別與該加 熱層電接觸,其改良在於, 所述加熱層包括一奈米碳管層,該奈米碳管層包括複 數個相互纏繞的奈米碳管。 ❹=申明專利範圍第1所述之面熱源,其中,所述之奈米 碳管層中的奈米碳管之間通過凡德瓦爾力相互吸引,形 成網路狀結構。 3. ΐΓΐί利範圍第1所述之面熱源,其中,所述奈米碳 4 I:佈,無規則排列,奈米碳管層呈各向同性。 圍第1所述之面熱源,其中,所述之奈米 層的厚度為1微米至2毫米。 mi,圍第1所述之面熱源,其中,所述之夺米 •6 於5〇微米,直徑小於%奈米。、 •申凊專利範圍第1所述之面埶源,並 電極的材料為金屬、合金、銦錫氧物中::述至少兩 導電銀膠、導電聚合物或導電性二::録錫氧化物、 7·如申請專利範圍第”斤述之二Ά官。 電極設置在奈米碳管層的同一表、面:中,所述至少兩 8·如申請專利範圍第,所述之面;:或二不同表面。 材料為柔性材料或硬性材料。’、、、*中’所述基底的 9.如申請專利範圍第8所述之面 料為塑膠或柔性纖維,所述硬性、材^,所述柔性材 艸為陶瓷、玻璃、樹 15 201008356 脂或石英。 10·如申睛專利範圍第i所述之面熱源,豆所述面熱 源進一步包括一反射層。 〃 11. 如申請專利範圍第1〇所述之面熱源,豆所述該反 射層設置於加熱層表面。 12. 如申請專利範圍第1〇所述之面熱源,其中,所述反射 層的材料為金屬氧化物、金屬鹽或陶瓷,厚度為100微 米〜0.5毫米。 ❹13.如申請專利範圍第n所述之面熱源,其中,所述反射 層設置在所述加熱層與基底之間。 14. 如申請專利範圍第11所述之面熱源,其中,所述反射 層設置在所述基底遠離加熱層的表面。 15. 如申請專利範圍第14所述之面熱源,其中,所述面熱 源進一步包括一絕緣保護層設置於所述加熱層表面。 16. 如申請專利範圍第15所述之面熱源,其中,所述絕緣 保護層的材料包括橡膠或樹脂。 16201008356 X. Patent application scope ^ A surface heat source comprising: a substrate; a heating layer 'the heating layer is disposed on a surface of the substrate; and at least two electrodes' are disposed at intervals and respectively electrically connected to the heating layer The contact is improved in that the heating layer comprises a carbon nanotube layer comprising a plurality of intertwined carbon nanotubes. The surface heat source according to claim 1, wherein the carbon nanotubes in the carbon nanotube layer are attracted to each other by a van der Waals force to form a network structure. 3. The surface heat source of the first aspect, wherein the nanocarbon 4 I: cloth is randomly arranged, and the carbon nanotube layer is isotropic. A surface heat source according to the first aspect, wherein the nano layer has a thickness of from 1 μm to 2 mm. Mi, the surface heat source of the first aspect, wherein the rice is 6 μm and the diameter is less than % nanometer. The source of the surface of the patent is described in claim 1, and the material of the electrode is metal, alloy, indium tin oxide: at least two conductive silver paste, conductive polymer or conductive two:: tin oxide The object, 7, such as the scope of the patent application, the second section of the stipulation of the patent. The electrode is disposed in the same surface of the carbon nanotube layer, the surface: the at least two 8. As described in the scope of the patent application, the surface; The material is a flexible material or a hard material. The substrate of the ',, and *' is 9. The fabric of the eighth aspect of the patent application is a plastic or flexible fiber, the hard material, The flexible material is ceramic, glass, tree 15 201008356 grease or quartz. 10 · The surface heat source according to the scope of the patent application scope i, the surface heat source of the bean further comprises a reflective layer. The surface heat source according to the first aspect, wherein the reflective layer is disposed on the surface of the heating layer. 12. The surface heat source according to claim 1, wherein the material of the reflective layer is metal oxide or metal. Salt or ceramic, thickness 100 microns ~ 0.5 milli The surface heat source of claim 11, wherein the reflective layer is disposed between the heating layer and the substrate. The surface heat source of claim 11, wherein The reflective layer is disposed on a surface of the heating layer, wherein the surface heat source further comprises an insulating protective layer disposed on the surface of the heating layer. The surface heat source of claim 15, wherein the material of the insulating protective layer comprises rubber or resin.
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