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TW200949300A - Luminance-enhanced film - Google Patents

Luminance-enhanced film Download PDF

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Publication number
TW200949300A
TW200949300A TW097144829A TW97144829A TW200949300A TW 200949300 A TW200949300 A TW 200949300A TW 097144829 A TW097144829 A TW 097144829A TW 97144829 A TW97144829 A TW 97144829A TW 200949300 A TW200949300 A TW 200949300A
Authority
TW
Taiwan
Prior art keywords
sea
island
film
yarn
refractive index
Prior art date
Application number
TW097144829A
Other languages
Chinese (zh)
Inventor
Yeon-Soo Kim
Do-Hyun Kim
In-Young Yang
Jin-Soo Kim
Deog-Jae Jo
Original Assignee
Woongjin Chemical Co Ltd
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Publication date
Application filed by Woongjin Chemical Co Ltd filed Critical Woongjin Chemical Co Ltd
Publication of TW200949300A publication Critical patent/TW200949300A/en

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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3025Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3033Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/08Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of polarising materials
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133528Polarisers
    • G02F1/133536Reflective polarizers
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/1336Illuminating devices
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/13363Birefringent elements, e.g. for optical compensation
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133504Diffusing, scattering, diffracting elements
    • G02F1/133507Films for enhancing the luminance

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Polarising Elements (AREA)

Abstract

The present invention relates to a luminance-enhanced film, and more particularly, to a luminance-enhanced film in which island-in-the-sea yarns with birefringence are included in a base material, thus significantly lowering production costs and also rapidly improving luminance. The luminance-enhanced film of the present invention includes a birefringent island-in-the-sea yarn within a base material. Accordingly, unlike a conventional stack type luminance-enhanced film, a luminance enhancement effect is excellent while not forming a number of layers. Further, since several hundreds of layers are not formed in one film, fabrication is very convenient and production costs can be saved greatly.

Description

200949300 九、發明說明: 【發明所屬之技術領域】 本發明關於增大明視度的薄膜,尤其關於某種增大明 視度的薄膜,其中具有雙折射性的海中島紗 (island-in-the-sea yarn)包含於基材申’因而顯著降低製造成 本’並且快速改善明視度。 【先前技術】 © 於資訊顯示科技,顯示裝置的陰極射線管(eath〇de犷町 tube,CRT)在上個半世紀佔有主要地位。然而,配合資訊 時代的快速進展,顯示科技需要各式各樣方法。當中預期 平面顯示器將會於不久的未來成為勝過CRT的科技。不僅 小尺寸測試裝置,可攜式電腦也已經商業化,而現有的crt 方法已經被平面顯示裝置所取代,甚至各式各樣監視器和 電視亦如此。 於平面顯示科技,液晶顯示器(liquid Crystal display, ❹ LCD)、投影顯示 H、«顯示面板(Plasma display panel, PDP)已於電視領域中穩固其市場,故已經成為主流。隨著 相關科技的改進,也預期場發射顯示器(fieid emissi〇n display ’ FED)、電致發光顯示器(electr〇 iuminescent display,ELD)…等將會依據個別特色而佔有一方。液晶顯 示器的使用範圍目前已經擴展到筆記型電腦、個人電腦監 視器、液晶電視、車輛、航空器…等。液晶顯示器大約佔 了平面面板市場的80%,並且隨著從丨998年下半年起對 5 200949300 w- LCD快速增加的需求’故其已經顯示遍及全球的榮景。 傳、充之液晶顯示器具有配置在一對吸收光的光學薄膜 之間的液晶和電極矩陣。於此液晶顯示器,液晶部分受到 電場影響而移動,電場収藉由施加電Μ至二電極所產 生’而使液晶的光學狀態據此發生改變。此過程藉由使「像 素」偏振於特定方向而顯示資訊,像素上則已載有資訊。 為此,液晶顯示器句扭&amp;土邀^ +左 匕括别先學薄膜和後光學薄膜以引發此 種偏振。 不此說此種液晶顯示器的液晶顯示裝置對於由背光所 發出的光具有高使用效率。這是因為由背光所發出的光有 5〇%或更多是被背面光學薄膜所吸收。因此,為了增加此種 液晶顯示裝置的背光使用效率,增大明視度的薄膜遂配置 於光學腔穴和液晶組件之間。 圖二是示範傳統之增大明視度薄膜的原理示意圖。 詳言之,從光學腔穴指向液晶組件之光的ρ偏振光乃 經由增大明視度的薄膜而轉移到液晶組件。光的$偏振光 則從增大明視度的薄膜反射到光學腔穴其從光學腔穴的 擴散反射表面以光偏振方向變成隨機的狀態再反射,然後 ^次轉移到增大明視度的薄膜。因此,S偏振光便被轉換成 可以通過液晶組件之偏振器的ρ偏振光,然後經由增大明 視度的薄膜而轉移到液晶組件。 相對於人射在增大明視度薄膜上的光,S偏振光的選擇 反射和ρ偏振光的透射行為乃由以下所進行:個別光學 層之間的折射率差異、依據堆叠光學層的延伸過程所設定 6 200949300 之每個光學層的光學厚度、光學層的折射率磁a 別平變化,此等是 在以下狀態:具有異向性折射率之平坦片上 — 的光學層以及 具有均向性折射率之平坦片上的光學層乃交替堆疊成複 數。 亦即,入射於增大明視度之薄膜上的光在通過每個光 學層時會經歷S偏振光的反射和p偏振光的透射行為因 此只有入射偏振光的P偏振光被轉移到液晶組件。此外 反射的S偏振光如上所述地從光學腔穴的擴散反射表面以 5 其偏振狀態變成隨機的狀態再反射,然後轉移到增大明視 度的薄膜。據此,或可減少光源產生之光的損失2功率浪 費。 然而,此傳統之增大明視度的薄膜之製造是將均向性 光學層和異向性光學層交替堆疊於具有不同折射率的平坦 片上,並且對堆疊層進行延伸過程,如此則堆疊層在個別 光學層之間具有光學厚度和折射率,其可以針對入射偏振 • 光的選擇性反射和透射做最佳化。據此,問題便在於增大 明視度之薄膜的製程很複雜。 尤其’因為增大明視度之薄膜的每個光學層具有平坦 片結構,故P偏振光和s偏振光必須彼此分開,以因應入 射偏振光之廣範圍的入射角度。據此,問題便在於光學層 的堆疊數目會過度增加,而製造成本便以幾何級數增加。 此外’問題也在於光學表現可能下降,這是因為光學層堆 疊數目過多的結構所造成的光學損失。 7 200949300 【發明内容】 &lt;技術問題&gt; 據此’鑒於先前技術所發生的上述問題來完成本發 明’而本發明的目的是提供增大明視度的薄膜,其容易製 造、製造成本很低,並且藉由取代傳統之堆疊型增大明視 度的薄膜而進一步改進明視效果。 本發明的另一目的是提供具有優異之可視性和光學效 果的增大明視度薄膜。 &lt;技術解決手段&gt; 為了達成上述目的,增大明視度的薄膜可以在基材裡 包括具有雙折射性的海中島紗。 基材最好具有光學均向性和1&gt;4到2.0的折射率。更好 的是基材可以使用以下任一或多者:聚萘二甲酸二乙酯 (PEN)、共聚萘二甲酸二乙酯(co_PEN)、聚對苯二甲酸乙二 酯(PET)、聚碳酸酯(PC)、聚碳酸酯(pc)合金、聚苯乙歸 (PS)、对熱聚本乙稀(ps)、聚曱基丙稀酸曱醋(pmma) '聚 對苯二曱酸丁二酯(PBT)、聚丙烯(PP)、聚乙烯(pE)、丙烯 腈丁二烯苯乙烯(ABS)、聚胺酯(PU)、聚醯亞胺(ρι)、聚氯 乙烯(PVC)、苯乙烯丙烯腈混合物(San)、乙烯醋酸乙稀醋 (EVA)、聚醯胺(PA)、聚縮醛(POM)、酚、環氧樹脂(Ep)、 尿素(UF)、黑色章(MF)、不飽和聚酯(UP)、矽(SI)、彈性體、 環烯烴聚合物。 海中島紗最好可以是在基材一方向中配置成複數。更 好的是海中島紗可以是在基材裡配置成垂直於光源。此 200949300 外’海中島紗可以是公&amp; &amp; = m 或者可以是彼 以在基材裡形 / J Μ疋刀散地配置於基材裡, 此在基材裡接觸而配置 1 此外,海中島紗可 成一或更多層。 ^和海中島紗㈣於二轴方向之折射率的 可以疋G.G3或更小。更好的是基材 於 -軸方向之折射率的差異可以是。.05或更大 下-轴方向是海中島紗的長度方向。 更好的疋剩200949300 IX. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to a film for increasing the visibility, and more particularly to a film for increasing the visibility, wherein the island-in-the-coil having birefringence (island-in-the- Sea yarn) is included in the substrate and thus significantly reduces manufacturing costs and rapidly improves the visibility. [Prior Art] © The information display technology, the cathode ray tube (eath〇de犷machi tube, CRT) of the display device occupied a dominant position in the last half century. However, in line with the rapid advances in the information age, display technology requires a variety of methods. It is expected that flat panel displays will become a technology that outperforms CRT in the near future. Not only small-sized test sets, but also portable computers have been commercialized, and the existing crt method has been replaced by flat-panel display devices, even for a wide variety of monitors and televisions. In the flat display technology, liquid crystal display (LCD), projection display H, «Plasma display panel (PDP) has stabilized its market in the TV field, so it has become the mainstream. With the improvement of related technologies, it is also expected that a field emission display (fieid emissi〇n display ’ FED), an electroluminescence display (ELD), etc. will occupy one party according to individual characteristics. The range of use of liquid crystal displays has now expanded to notebook computers, personal computer monitors, LCD TVs, vehicles, aircraft, etc. LCD monitors account for approximately 80% of the flat panel market, and with the rapid increase in demand for 5 200949300 w-LCDs since the second half of 998, it has already shown its global glory. The liquid crystal display of the transfer and charge has a liquid crystal and an electrode matrix disposed between a pair of optical films that absorb light. In this liquid crystal display, the liquid crystal portion is moved by the influence of the electric field, and the electric field is charged by the application of the electric current to the two electrodes, and the optical state of the liquid crystal is changed accordingly. This process displays information by polarizing the "pixel" in a particular direction, and the pixel already carries information. To this end, the liquid crystal display sentence & soil invites ^ + left to cover the film and the rear optical film to induce this polarization. It is not said that the liquid crystal display device of such a liquid crystal display has high use efficiency for light emitted from a backlight. This is because 5% or more of the light emitted by the backlight is absorbed by the back optical film. Therefore, in order to increase the backlight use efficiency of such a liquid crystal display device, the film 遂 which increases the visibility is disposed between the optical cavity and the liquid crystal module. Figure 2 is a schematic diagram showing the principle of a conventional enhanced brightness film. In detail, the ρ-polarized light of the light directed from the optical cavity to the liquid crystal module is transferred to the liquid crystal module via the film which increases the visibility. The polarized light of light is reflected from the film of increased visibility to the optical cavity, which is re-reflected from the diffuse reflection surface of the optical cavity in a state where the polarization of light becomes random, and then transferred to the film which increases the visibility. Therefore, the S-polarized light is converted into ρ-polarized light which can pass through the polarizer of the liquid crystal module, and then transferred to the liquid crystal element via the film which increases the visibility. The selective reflection of S-polarized light and the transmission behavior of ρ-polarized light are performed as follows with respect to the light emitted by the human on the brightening film: the difference in refractive index between the individual optical layers, the extension process according to the stacked optical layer The optical thickness of each optical layer set to 6 200949300, the refractive index of the optical layer, a flat change, is in the following state: an optical layer on a flat sheet having an anisotropic refractive index and has an isotropic refraction The optical layers on the flat sheets are alternately stacked in a complex number. That is, light incident on the film of increased visibility undergoes reflection of S-polarized light and transmission of p-polarized light as it passes through each optical layer, so that only P-polarized light of incident polarized light is transferred to the liquid crystal module. Further, the reflected S-polarized light is reflected from the diffuse reflection surface of the optical cavity to a random state as described above, and then transferred to the film which increases the visibility. Accordingly, it is possible to reduce the loss of light generated by the light source 2 power waste. However, the conventional method for increasing the brightness of the film is to alternately stack the isotropic optical layer and the anisotropic optical layer on a flat sheet having a different refractive index, and to extend the stacked layer, so that the stacked layer is The individual optical layers have optical thickness and refractive index that are optimized for selective reflection and transmission of incident polarization. Accordingly, the problem is that the process for increasing the brightness of the film is complicated. In particular, since each optical layer of the film of increased visibility has a flat sheet structure, the P-polarized light and the s-polarized light must be separated from each other in order to accommodate a wide range of incident angles of the polarized light. Accordingly, the problem is that the number of stacks of optical layers is excessively increased, and the manufacturing cost is increased geometrically. In addition, the problem is that optical performance may be degraded due to optical losses caused by an excessive number of optical layer stacks. 7 200949300 SUMMARY OF THE INVENTION <Technical Problem> Accordingly, the present invention has been made in view of the above problems occurring in the prior art, and an object of the present invention is to provide a film having increased visibility, which is easy to manufacture and has a low manufacturing cost. And further improving the brightening effect by replacing the conventional stacked type film which increases the visibility. Another object of the present invention is to provide an increased clarity film having excellent visibility and optical effects. &lt;Technical Solution&gt; In order to achieve the above object, a film having a high visibility can include a sea-island yarn having birefringence in a substrate. The substrate preferably has optical homogeneity and a refractive index of 1 &gt; 4 to 2.0. More preferably, the substrate may be used in any one or more of the following: polyethylene naphthalate (PEN), copolymerized polyethylene naphthalate (co_PEN), polyethylene terephthalate (PET), poly Carbonate (PC), polycarbonate (pc) alloy, polystyrene (PS), heat-polymerized ethylene (ps), polymethyl acrylate vinegar (pmma) 'poly terephthalic acid Butane diester (PBT), polypropylene (PP), polyethylene (pE), acrylonitrile butadiene styrene (ABS), polyurethane (PU), polyimine (ρι), polyvinyl chloride (PVC), Styrene acrylonitrile mixture (San), ethylene vinyl acetate (EVA), polydecylamine (PA), polyacetal (POM), phenol, epoxy resin (Ep), urea (UF), black chapter (MF ), unsaturated polyester (UP), bismuth (SI), elastomer, cyclic olefin polymer. Preferably, the sea island yarn may be arranged in a plurality in the direction of the substrate. More preferably, the sea island yarn may be disposed perpendicular to the light source in the substrate. This 200949300 outer 'sea island yarn can be public &amp;&amp; = m or it can be placed in the substrate in the shape of the substrate / J knives scattered in the substrate, which is placed in contact with the substrate 1 The sea island yarn can be one or more layers. ^ and the refractive index of the sea island yarn (4) in the biaxial direction can be 疋G.G3 or less. More preferably, the difference in refractive index of the substrate in the -axis direction may be. .05 or greater The down-axis direction is the length direction of the island yarn in the sea. Better surplus

❹ 海中島紗的海部分最好可以是均向性,而海中島 島部分最好可以是異向性。 ’ 海中島紗的海部分和島部分相對於二軸方向之折射率 的差異最好可以是0.03或更小,並且海中島紗的海部分和 島。卩刀相對於剩下一軸方向之折射率的差異最好可以是 〇.〇5或更大。在此情況下,剩下一轴方向可以是海中島紗 的長度方向。 海部分最好可以具有14到2 〇的折射率。 海中島紗的島部分可以配置成複數。更好的是海部分 和島部分基於海中島紗橫截面的面積比例可以是2: 8到8 : 海中島紗的海部分最好可以包括以下任一或多者:聚 蔡一甲酸二乙酯(pEN)、共聚萘二甲酸二乙酯(c〇_pEN)、聚 對苯二甲酸乙二酯(PET)、聚碳酸酯(Pc)、聚碳酸酯(PC)合 金、聚笨乙烯(PS)、耐熱聚苯乙烯(ps)、聚甲基丙烯酸甲酯 CPMMA)、聚對苯二曱酸丁二酯(pbt)、聚丙烯(pp)、聚乙烯 (PE)、丙烯腈丁二烯苯乙烯(ABS)、聚胺酯(PU)、聚醯亞 9 200949300 胺(PI)、聚氣乙烯(PVC)、苯乙烯丙烯腈混合物(SAN)、乙烯 醋酸乙烯酯(EVA)、聚醯胺(PA)、聚縮醛(POM)、酚、環氡 樹脂(EP)、尿素(UF)、黑色素(MF)、不飽和聚酯(UP)、矽 (SI)、彈性體、環烯烴聚合物。 海中島紗的島部分最好可以包括以下任一或多者:聚 萘二甲酸二乙酯(PEN)、co-PEN、PET、co_PET、聚對苯二 曱酸丁二酯(PBT)、聚丙烯(pp)。 此外’數個島部分最好可以具有相同的橫截面或不同 的橫截面。更好的是海中島紗可以在長度方向延伸。 增大明視度的薄膜可以進一步包括結構化表面層。更 好的是結構化表面層形成於可以輸出光的表面上。詳言 之’結構化表面層可以具有棱鏡形狀、透鏡形狀或凸透鏡 形狀。在此情況下,形狀可以是規則或不規則地排列。 雙折射海中島紗可以配置或不配置於結構化表面層 中。此外’增大明視度之薄膜的後表面可以經過消光(matt) I 處理。 海中島紗最好可以具有0.3到2〇丹尼(denier)的厚度。 增大明視度薄膜裡的海中島紗數目為每立方公分500到 4,000,000 條。 海中島紗的戴面可以是圓形、卵形或各式各樣非圓形 形狀海部分的折射率可以相等於基材的折射率。 &amp;中島、紗可以是編織於緯紗和末端。更好的是緯紗和 末端中的任一本-Γ· 管可以是海中島紗,而緯紗和末端中的另一 者可以是均向性纖維。 10 200949300 緯々和末端可以由1到200股的海中島紗所形成。 、同時,本發明可以提供包括上述增大明視度之薄骐的 责光單元。此外’背光單元可以包含於液晶顯示装置中: 在此情況下’液晶顯示襄置可以包括相差薄膜和/或吸收海 The sea part of the sea island yarn may preferably be uniform, and the island part of the sea island may preferably be anisotropic. The difference in refractive index between the sea portion and the island portion of the sea island yarn relative to the biaxial direction may preferably be 0.03 or less, and the sea portion and the island of the island yarn in the sea. The difference in refractive index of the file relative to the remaining one axis direction may preferably be 〇.〇5 or more. In this case, the remaining one axis direction may be the length direction of the island yarn in the sea. The sea portion preferably has a refractive index of 14 to 2 Torr. The island portion of the island yarn can be configured in plural. More preferably, the ratio of the area of the sea portion to the island portion based on the cross section of the island yarn may be 2: 8 to 8: The sea portion of the sea island yarn may preferably include any one or more of the following: polycaproterate (pEN), copolymerized polyethylene naphthalate (c〇_pEN), polyethylene terephthalate (PET), polycarbonate (Pc), polycarbonate (PC) alloy, polystyrene (PS) ), heat-resistant polystyrene (ps), polymethyl methacrylate CPMMA), polybutylene terephthalate (pbt), polypropylene (pp), polyethylene (PE), acrylonitrile butadiene benzene Ethylene (ABS), Polyurethane (PU), Polyamide 9 200949300 Amine (PI), Polyethylene (PVC), Styrene Acrylonitrile (SAN), Ethylene Vinyl Acetate (EVA), Polyamide (PA) Polyacetal (POM), phenol, cyclic oxime resin (EP), urea (UF), melanin (MF), unsaturated polyester (UP), bismuth (SI), elastomer, cyclic olefin polymer. The island portion of the island yarn may preferably include any one or more of the following: polyethylene naphthalate (PEN), co-PEN, PET, co_PET, polybutylene terephthalate (PBT), poly Propylene (pp). Further, the 'number of island portions may preferably have the same cross section or different cross sections. Even better, the island yarn can extend in the length direction. The film of increased clarity may further comprise a structured surface layer. More preferably, the structured surface layer is formed on a surface from which light can be output. DETAILED DESCRIPTION The structured surface layer can have a prism shape, a lens shape, or a convex lens shape. In this case, the shapes may be arranged regularly or irregularly. Birefringent sea island yarns may or may not be disposed in the structured surface layer. Further, the rear surface of the film which increases the visibility can be subjected to matt I treatment. The sea island yarn may preferably have a thickness of 0.3 to 2 denier. Increasing the number of sea island yarns in the clarity film is 500 to 4,000,000 per cubic centimeter. The wearing surface of the sea island yarn may be round, oval or a variety of non-circular shaped sea portions having a refractive index equal to the refractive index of the substrate. &amp; Nakajima, yarn can be woven at the weft yarn and the end. More preferably, any of the weft yarns and the ends may be island yarns, and the other of the weft yarns and the ends may be oriented fibers. 10 200949300 The weft and the end can be formed from 1 to 200 strands of sea-island yarn. At the same time, the present invention can provide a light-receiving unit including the above-described thinness of increased visibility. Further, the backlight unit may be included in the liquid crystal display device: In this case, the liquid crystal display device may include a phase difference film and/or absorption.

依據本發明另-方面之增大明視度的薄膜包括基材, 其Χ軸方向折射率可以是nXl,y車由方向折射率可以是咖’ z軸方向折射率可以是nZ1,並且雙折射海中島紗配 t裡。當雙折射海中島紗㈣射率可以是ηχ2、ηγ2、ηζ2 才基材之x、y、z軸折射率當中至少一者可以相等於雙折 射海中島紗的X、y、z軸折射率。在此情況下,更好的是 nX2 &gt;nY2 = nZ1,並且基材是均向性。 g ,备海中島紗之島部分的χ轴方向折射率(其可以 疋海中島紗之島部分的長度方向)可以是ηΧ3、海中島紗之 島部分的y轴方向折射率可以是ηγ3、海中島紗之島部:的 ζ轴方向折射率可以是ηΖ3 ’並且海中島紗之海部分的X轴 :向折射率可以是ηΧ4、海中島紗之海部分的y轴方向折射 ^可以疋η Y4、海中島紗之海部分的z轴方向折射率可以是 =4’則折射率ηΧ3和ηχ4之間或ηγ3和^之間差異的 :二可以是0.15或更大。折射率叫心之間差異的 系巴對值小於〇.〇3。 說明書所用的詞彙則簡短描述如下。 以下情 上,則 ,若無另外敘述,則聚合物具有雙折射性是指 形·光照射在依據方向而具有不同折射率的聚合物 200949300 射於聚合物上的光會折射為二不同方向的光。 均向性」(isotropy)—詞是指當光通過物體時,無論 光的方向為何’物體皆具有固定不變的折射率。 異向性」(anisotropy)—詞是指物體的光學性質會依 據光的方向而有所不同。異向性物體具有雙折射性,其相 對於均向性而言。 光學調變」(optical m〇dulation) 一詞是指照射的光被 反射折射、散射,或者改變光的強度、波移動周期或性 質。 &lt;有利效果&gt; 本發明是增大明視度的薄膜,其中形成一層以於基材 裡包括雙折射海中島紗,而不同於傳統之堆疊式增大明視 度的薄膜。據此,本發明之增大明視度的薄膜可具有增大 明視度的優異效果,同時不必形成許多層。再者,由於數 百層並未堆疊於一薄膜中,故製造上非常方便,並且製造 成本的節省效果極優異。 【實施方式】 從底下配合所附圖式所做的詳細敘述,可以更完整了 解本發明之進一步目的和優點。 之後將參考所附圖式來詳細敘述本發明的具體態樣。 傳統之增大明視度的薄膜乃製造如下:交替堆疊均向 性光學層和異向性光學層於具有不同折射率的平坦片上, 再對堆疊層進行延伸過程,如此在個別光學層之間具有光 12 200949300 予厚度和折射率,其可以針對入射偏振光的選擇性反射和 透射來做最佳化。據此,問題便在於增大明視度之薄膜的 製程變複雜。 尤其’由於增大明視度的薄膜之每個光學層具有平坦 片結構,故p偏振光和s偏振光必須回應於入射偏振光的 廣範圍入射角度而彼此分開。據此,問題便在於光學層的 堆疊數目會過度增加,製造成本也呈幾何級數而增加。此 ^ 外,問題也在於因為結構中的光學層堆疊數目過多,所以 光學表現可能因為光學損失而下降。 鑑於以上問題,於本發明,雙折射海中島紗配置於基 材裡,以使來自光源的入射光在雙折射界面(亦即雙折射海 中島紗的均向性基材之間的邊界界面)發生反射、散射、折 射’因此被光學調變。據此,可以快速改進明視度。 詳言之’由外部光源所發出的光可以大大地區分為S 偏振光和P偏振光。在只需要特定偏振光的情況下,p偏振 _ 光通過增大明視度的薄膜,而不受到雙折射界面的影響。 然而’S偏振光以折射、散射、反射等隨機形式於波長調變, 亦即在雙折射界面調變為S偏振光或P偏振光。如果調變 的光再次反射和照射在增大明視度的薄膜上,則P偏振光 通過增大明視度的薄膜,而S偏振光再度散射或反射。重 複這樣的過程,可以獲得想要的P偏振光。 據此,如果具有雙折射界面的聚合物在聚合物和基材 之間的邊界界面而於基材裡配置成複數,則即使不形成傳 統之堆疊型增大明視度的薄膜,仍可以快速改進明視度。 13 200949300 此外,本發明人已發現:如果使用具有雙折射界面的 聚口物當成一般的雙折射纖維,則優點在於製造成本低且 製以上很方便,此乃由於並非形成堆疊型薄膜,但是一般 的雙折射纖維可能無法應用於取代堆疊型增大明視度的薄 膜之工業領域,這是因為它明視度增大的效果並不顯著。 為了克服上述問題,使用雙折射海中島紗做為具有雙 折射界面的聚合物。尤其可能發現:相較於使用典型纖維 φ 的it况,如果使用雙折射海中島紗,則光學調變效率和明 :見度增大的效果皆有顯著改進。尤其,構成海中島紗的島 部分具有雙折射十生,並且畫分島部分的海部分具有均向 性。在此情況下,不僅海中島紗和基材之間的邊界界面, 同時構成海中島紗内部的許多島部分和海部分之間的邊界 界面’皆具有雙折射界面。據此,相較於雙折射界面僅形 j於基材和雙折射纖維之間邊界界面的典型雙折射纖維而 言,本發明《光學調變的效果增加顯I。因&amp;,本發明的 〇 雙折射海中島紗可以取代堆疊型之增大明視度的薄膜並 且可實際應用於工業領域。 據此,當使用雙折射海中島紗時,增大明視度的效率 要比使用典型雙折射纖維更優異。再者,雙折射海中島紗 包括島部分和海部分,其具有不同光學性質和雙折射界 面而可以形成於海中島紗裡。因此,相較於雙折射界面 並未形成於海中島紗裡的情形,本發明可以顯著改進增大 明視度的效率》 再者,在搓捻數條或數十條海中島紗而形成共軛接合 200949300 纖維的情況下,舉例而言’搓撿10條海中島紗以形成一條 共扼接合纖維,料扼接合纖維中有⑽個雙折射界面, 而可以產纟1〇〇個或更多的光學調變。此外,在製出數條 捻線式海中島紗的情況下’舉例而言,當製造1〇條海中島 紗時’共扼接合纖維中冑⑽個雙折射界面,而可以產生 ⑽個或更多光學調變。本發明此種海中島紗可以使用共挤 製法......等製造,但不限於此。 ΟThe film for increasing the visibility according to another aspect of the present invention includes a substrate whose refractive index in the z-axis direction may be nX1, and the refractive index in the direction of the vehicle may be nZ1 in the direction of the z-axis, and the sea of birefringence Nakajima yarn with t. When the birefringence sea island yarn (4) has a radiance of ηχ2, ηγ2, ηζ2, at least one of the x, y, and z-axis refractive indices of the substrate may be equal to the X, y, and z-axis refractive indices of the birefringent sea island yarn. In this case, it is more preferable that nX2 &gt; nY2 = nZ1, and the substrate is uniform. g, the refractive index of the axis of the island of the island of the sea, which can be the length of the island of the island of the sea, can be ηΧ3, the refractive index of the island of the island of the sea in the y-axis direction can be ηγ3, sea Nakajima Yoshishima Department: The refractive index in the x-axis direction may be ηΖ3 'and the X-axis of the sea portion of the island yarn in the sea: the refractive index may be ηΧ4, the y-axis direction of the sea portion of the sea island yarn is refracted ^ 疋η Y4 The refractive index in the z-axis direction of the sea portion of the sea island yarn may be =4', and the difference between the refractive indices η Χ 3 and η χ 4 or η γ 3 and ^ may be 0.15 or more. The difference between the refractive index and the heart is less than 〇.〇3. The vocabulary used in the manual is briefly described below. In the following case, unless otherwise stated, the polymer has birefringence, which means that the light irradiated on the polymer with different refractive indices according to the direction 200949300, the light incident on the polymer is refracted into two different directions. Light. "isotropy" - the word refers to the fact that when the light passes through the object, regardless of the direction of the light, the object has a fixed refractive index. Anisotropy—The word means that the optical properties of an object will vary depending on the direction of the light. An anisotropic object has birefringence, which is relative to the uniformity. The term "optical m〇dulation" refers to the refracted light being reflected, refracted, or altered in intensity, wave motion period or nature. &lt;Advantageous Effects&gt; The present invention is a film for increasing the visibility, in which a layer is formed to include a birefringent sea island yarn in a substrate, unlike a conventional stacked type film which increases the visibility. According to this, the film of increased brightness of the present invention can have an excellent effect of increasing the visibility without having to form a plurality of layers. Further, since hundreds of layers are not stacked in a film, it is very convenient to manufacture, and the manufacturing cost saving effect is extremely excellent. DETAILED DESCRIPTION OF THE INVENTION Further objects and advantages of the present invention will become more fully apparent from the detailed description of the appended claims. Specific aspects of the invention will be described in detail below with reference to the drawings. Conventional augmented films are manufactured by alternately stacking an isotropic optical layer and an anisotropic optical layer on a flat sheet having a different refractive index, and then extending the stacked layers so as to have between individual optical layers. Light 12 200949300 Pre-thickness and refractive index, which can be optimized for selective reflection and transmission of incident polarized light. Accordingly, the problem is that the process for increasing the brightness of the film becomes complicated. In particular, since each optical layer of the film of increased visibility has a flat sheet structure, p-polarized light and s-polarized light must be separated from each other in response to a wide range of incident angles of incident polarized light. Accordingly, the problem is that the number of stacks of optical layers is excessively increased, and the manufacturing cost is also increased geometrically. In addition to this, the problem is that optical performance may be degraded due to optical loss due to the excessive number of optical layer stacks in the structure. In view of the above problems, in the present invention, the birefringent sea-island yarn is disposed in the substrate such that the incident light from the light source is at the birefringent interface (ie, the boundary interface between the isotropic substrates of the island fibers in the birefringent sea) Reflection, scattering, and refraction occur, so they are optically modulated. According to this, the visibility can be quickly improved. In detail, the light emitted by an external light source can be broadly classified into S-polarized light and P-polarized light. In the case where only a specific polarized light is required, the p-polarized light passes through the film which increases the visibility without being affected by the birefringent interface. However, the 'S-polarized light is modulated at a wavelength in a random form such as refraction, scattering, reflection, etc., that is, at the birefringent interface, it is converted into S-polarized light or P-polarized light. If the modulated light is again reflected and illuminated on the film which increases the visibility, the P-polarized light passes through the film which increases the visibility, and the S-polarized light is again scattered or reflected. By repeating such a process, desired P-polarized light can be obtained. According to this, if the polymer having the birefringent interface is disposed in the substrate at a boundary interface between the polymer and the substrate, the film can be quickly improved even if the conventional stacked type film having increased visibility is not formed. Brightness. 13 200949300 In addition, the inventors have found that if a polycondensate having a birefringent interface is used as a general birefringent fiber, the advantage is that the manufacturing cost is low and the above is convenient, because a stacked film is not formed, but generally Birefringent fibers may not be used in the industrial field of replacing stacked-type films with increased visibility because the effect of increased brightness is not significant. In order to overcome the above problems, a birefringent sea island yarn is used as a polymer having a birefringent interface. In particular, it has been found that the effect of optical modulation efficiency and brightness increase is significantly improved if birefringent sea island yarns are used compared to the use of typical fiber φ. In particular, the island portion constituting the island yarn of the sea has birefringence, and the sea portion of the divided island portion has an average orientation. In this case, not only the boundary interface between the sea island yarn and the substrate but also the boundary interface between many island portions and the sea portion inside the sea island yarn have a birefringent interface. Accordingly, the effect of the optical modulation is increased by one compared to the typical birefringent fiber in which the birefringent interface is formed only at the boundary interface between the substrate and the birefringent fiber. Because of &amp;, the bismuth birefringent sea island yarn of the present invention can replace the stacked type of film which increases the visibility and can be practically applied in the industrial field. Accordingly, when birefringent sea-island yarns are used, the efficiency of increasing the visibility is superior to that of the typical birefringent fibers. Further, the birefringent sea island yarn includes an island portion and a sea portion which have different optical properties and a birefringent interface and can be formed in the sea island yarn. Therefore, the present invention can significantly improve the efficiency of increasing the visibility as compared with the case where the birefringence interface is not formed in the sea island yarn. Further, the conjugate is formed in the number of tens or tens of sea island yarns. In the case of joining 200949300 fibers, for example, '10 nautical island yarns are formed to form a conjugated fiber, and there are (10) birefringent interfaces in the enamel bonding fiber, which can produce 1 〇〇 or more. Optical modulation. In addition, in the case of producing a plurality of twisted-type sea-in-the-sea yarns, for example, when manufacturing one strand of sea-in-the-sea yarn, the 扼(10) birefringent interfaces in the fibers are joined together, and (10) or more can be produced. Multiple optical modulation. The sea island yarn of the present invention can be produced by a co-extrusion method or the like, but is not limited thereto. Ο

因此可以S兒.冑了製造微纖維,典型的海中島紗採用 島部分做為微纖維,其係沖提(elute)海部分之後所留下,而 不管雙折射。S而於本發明巾,雖然、海中島紗的海部分並 未沖提,但是如其原樣地使用具有海部分和島部分光學性 質的海中島紗。於本發明,假設島部分具有異向性且海部 分具有均向性。然而,即使當島部分具有均向性且海部分 具有異向性時,也可以實現本發明的目的。 本發明將參考所附圖式來詳加描述。 圖2是根據本發明具體態樣之增大明視度薄膜的示意 截面圖。詳言之,增大明視度的薄膜具有海中島紗2 1〇,其 具有雙折射性而自由排列於均向性基材200裡。此時基材 200可以使用的材料包括熱塑性和熱固性聚合物,而目標範 圍的光學波長可以通過此聚合物。最好適當的基材2〇〇可 以是非晶質或半晶質的,並且可以包括單一聚合物、共聚 物或其摻合物。詳言之,可以使用:聚碳酸酯(PC);對排和 同排的聚苯乙烯(PS);烷基苯乙烯;烷基,例如聚甲基丙烯 酸甲酯(PMMA)和PMMA共聚物,芳香族和脂肪族的懸垂 15 200949300 (甲基)丙烯酸酯;乙氧化和丙氧化(甲基)丙烯酸酯;多官能 基的(曱基)丙烯酸酯;丙烯酸化環氧樹脂;環氧樹脂;其他 乙烯不飽和物質;環狀烯烴和環狀烯烴共聚物;丙烯腈丁 二烯苯乙烯 (ABS);苯乙烯丙烯腈共聚物(SAN);環氧樹 脂;聚乙烯環己烷;PMMA /聚氟乙烯摻合物;聚氧化苯合 金;苯乙烯嵌段共聚物;聚醯亞胺;聚砜;聚氯乙烯;聚 二甲基矽氧烷(PDMS);聚胺酯;不飽和聚酯;聚乙烯;聚 丙烯(PP);聚對苯二甲酸二烷酯,舉例而言,聚對苯二曱酸 乙二酯(PET);聚對萘二曱酸二烷酯,舉例而言,聚萘二曱 酸二乙酯;聚醯胺;離子聚合物;醋酸乙烯酯/聚乙烯共 聚物;醋酸纖維素;醋酸丁酯纖維素;氟聚合物;聚苯乙 烯-聚乙烯共聚物;PET和PEN共聚物,例如聚烯烴PET 和PEN ;聚碳酸酯/脂肪族PET摻合物。更好的是可以單 獨或組合使用:聚萘二曱酸二乙酯(PEN)、共聚萘二曱酸二 乙酯(co-PEN)、聚對苯二曱酸乙二酯(PET)、聚碳酸酯(PC)、 聚碳酸酯(PC)合金、聚苯乙烯(PS)、耐熱聚苯乙烯(PS)、聚 甲基丙烯酸甲酯(PMMA)、聚對苯二曱酸丁二酯(PBT)、聚 丙烯(PP)、聚乙烯(PE)、丙烯腈丁二烯笨乙烯(ABS)、聚胺 酯(PU)、聚醯亞胺(PI)、聚氯乙烯(PVC)、苯乙烯丙烯腈混 合物(SAN)、乙烯醋酸乙烯酯(EVA)、聚醢胺(PA)、聚縮醛 (POM)、酚、環氧樹脂(EP)、尿素·黑色素(UF.MF)、不飽 和聚酯(UP)、矽(SI)、彈性體、環烯烴聚合物(COP,曰本 ΖΕΟΝ公司、日本JSR公司)。再者,基材也可以包含添加 劑,例如抗氧化劑、光穩定劑、熱穩定劑、潤滑劑、分散 16 200949300 劑、紫外線吸收劑、白色顏料、榮 系尤瑨白劑,只要它們不 會有損於上述的物理性質。 海&quot;島紗210可以採用的材料最好具有光學雙折射性 和優異的光學透射性。較佳而言’雖然海中島紗21〇可以 具有與基# 200相同的材料’但是所採用的材料之光學性 質是雙折射的。此外,將均向性材料轉換為雙折射材料的 方法已經典型已知。舉例而言’如果均向性材料在適合的 ΟTherefore, it is possible to manufacture microfibers. The typical sea island yarn uses the island portion as a microfiber, which is left after the elute sea portion, regardless of birefringence. In the towel of the present invention, although the sea portion of the sea-island yarn is not washed, the sea-island yarn having the optical properties of the sea portion and the island portion is used as it is. In the present invention, it is assumed that the island portion has an anisotropy and the sea portion has an isotropic property. However, the object of the present invention can be achieved even when the island portion has an isotropic property and the sea portion has an anisotropy. The invention will be described in detail with reference to the drawings. Figure 2 is a schematic cross-sectional view of an enlarged elevation film in accordance with an embodiment of the present invention. In detail, the film of increased visibility has a sea island yarn 2 1 〇 which is birefringent and freely arranged in the oriented substrate 200. Materials that can be used with substrate 200 at this point include thermoplastic and thermoset polymers, and the optical wavelengths of the target range can pass through the polymer. Preferably, a suitable substrate 2 can be amorphous or semi-crystalline and can comprise a single polymer, copolymer or blend thereof. In detail, it is possible to use: polycarbonate (PC); opposite rows and the same row of polystyrene (PS); alkyl styrene; alkyl, such as polymethyl methacrylate (PMMA) and PMMA copolymer, Aromatic and aliphatic drape 15 200949300 (meth) acrylate; ethoxylated and propoxylated (meth) acrylate; polyfunctional (fluorenyl) acrylate; acrylated epoxy; epoxy; Ethylene unsaturated substance; cyclic olefin and cyclic olefin copolymer; acrylonitrile butadiene styrene (ABS); styrene acrylonitrile copolymer (SAN); epoxy resin; polyethylene cyclohexane; PMMA / polyfluorine Ethylene blend; polyoxybenzene alloy; styrene block copolymer; polyimine; polysulfone; polyvinyl chloride; polydimethyl siloxane (PDMS); polyurethane; unsaturated polyester; Polypropylene (PP); polyalkylene terephthalate, for example, polyethylene terephthalate (PET); poly-p-naphthalene dicarboxylate, for example, polynaphthalene Diethyl acrylate; polyamine; ionic polymer; vinyl acetate/polyethylene copolymer; cellulose acetate; Butyl cellulose; fluoropolymer; polystyrene - polyethylene copolymer; PET and PEN copolymers, such as polyolefins and PET PEN; polycarbonate / aliphatic PET blends. More preferably, it can be used singly or in combination: polyethylene naphthalate (PEN), copolymerized polyethylene naphthalate (co-PEN), polyethylene terephthalate (PET), poly Carbonate (PC), polycarbonate (PC) alloy, polystyrene (PS), heat resistant polystyrene (PS), polymethyl methacrylate (PMMA), polybutylene terephthalate (PBT) ), polypropylene (PP), polyethylene (PE), acrylonitrile butadiene (ABS), polyurethane (PU), polyimine (PI), polyvinyl chloride (PVC), styrene acrylonitrile mixture (SAN), ethylene vinyl acetate (EVA), polyamine (PA), polyacetal (POM), phenol, epoxy resin (EP), urea · melanin (UF.MF), unsaturated polyester (UP ), bismuth (SI), elastomer, cycloolefin polymer (COP, 曰本ΖΕΟΝ, Japan JSR). Furthermore, the substrate may also contain additives such as antioxidants, light stabilizers, heat stabilizers, lubricants, dispersions 16, 200949300, UV absorbers, white pigments, and scent whites, as long as they are not damaged. The above physical properties. The material that the sea &quot;island yarn 210 can employ preferably has optical birefringence and excellent optical transmission. Preferably, although the sea island yarn 21 can have the same material as the base #200, the optical properties of the material used are birefringent. Further, a method of converting an isotropic material into a birefringent material has been generally known. For example, 'if the uniform material is suitable Ο

溫度條件下拉伸,則均向性材料會使其聚合物分子加以定 向,因此會具有雙折射性。 更好的是可以選擇使用以下任一或更多者:聚萘二甲 酸二乙酯(PEN)、共聚萘二甲酸二乙酯(c〇_pEN)、聚對苯二 甲酸乙二酯(PET)、共聚對苯二甲酸乙二酯(c〇_pET)、聚碳 酸酯(pc)、聚碳酸酯(PC)合金、聚苯乙烯(ps)、耐熱聚苯乙 烯(PS)、聚甲基丙烯酸甲酯(PMMA)、聚對苯二甲酸丁二酯 (PBT)、聚丙烯(PP)、聚乙烯(pE)、丙烯腈丁二烯苯乙烯 (ABS)、聚胺酯(PU)、聚醯亞胺(ρι)、聚氣乙烯苯乙 烯丙稀腈混合物(SAN)、乙烯醋酸乙烯酯(EVA)、聚醯胺 (PA)、聚縮搭(p0M)、酚、環氧樹脂(Ep)、尿素黑色素 (UF,MF)、不飽和聚酯(UP)、矽(SI)、彈性體、環烯烴聚合 物’做為海部分和島部分。在此情況下,海部分和島部分 S中者可以具有均向性,而海部分和島部分當中另一者 可以具有異向性。更好的是島部分可以具有異向性,並且 海部分可以具有均向性。舉例而言,海中島紗的海部分可 以使用均向性C0_PEN,而其島部分可以使用雙折射性 17 200949300 PEN。海中島紗的海部分和島部分都可以使用具有不同光學 性質的樹脂。 此外,於具有光學均向性基材和雙折射性的海中島紗 中,依據空間x、y、z軸之折射率的實質匹配或不匹配程度, 對於光線散射程度會有影響,而此光線即依據對應抽所偏 振。-般來說,散射能力的變化乃正比於折射率不匹配程 度的平方。據此,如果依據特定轴之折射率的不匹配程度 ❹增加,則依據該對應軸所偏振的光線就會更強烈地散射。 然而,當依據特定轴的不匹配程度小時,依據該對應轴所 偏振的光線便散射較少。於依據特定軸之基材折射率實質 相等於海中島紗折射率的情形下,由平行此轴之電場所偏 振的入射光便不會散射,而無論海中島紗一部分的尺寸、 形狀、密度為何,但是入射光可以通過海中島紗。再者於 依據特定軸之基材折射率實質相等於海中島紗折射率的情 形下,光線並未實質散射但通過物體。據此,於本發明, 〇 基材和海中島紗相對於二軸方向之折射率的差異最好為 0·03或更小,並且基材和海中島紗相對於剩下一軸方向之 折射率的差異為0.05或更大。在此情況下,ρ波通過基材 和海中島紗的雙折射界面。然而,s波會經歷光學調變,被 反射、散射或折射,然後轉換形式為S波或p波。其中p 波再次通過增大明視度的薄膜和經歷光學調變。 詳言之’雙折射海中島紗的島部分最好可以具有異向 性’而其海部分最好可以具有均向性。假設異向性島部分 於X軸方向的折射率是nX3、異向性島部分於y轴方向的折 200949300 射率是nY3、異向性島部分於z轴方向的折射率是nZ3,並 且均向性海部分於x軸方向的折射率是nX4、均向性海部分 於y軸方向的折射率是nY4、均向性海部分於z軸方向的折 射率是nZ4,則折射率nX3和nX4之間差異的絕對值最好 是〇.〇5或更大,更好的是〇·15或更大。在此情況下,折射 率ηΥ3和ηΥ4之間和/或ηΖ3和似之間差異的絕對值可 以是小於0.03。When stretched under temperature conditions, the isotropic material will orient its polymer molecules and will therefore have birefringence. More preferably, one or more of the following may be used: polyethylene naphthalate (PEN), polyethylene naphthalate (c〇_pEN), polyethylene terephthalate (PET) ), copolymerized ethylene terephthalate (c〇_pET), polycarbonate (pc), polycarbonate (PC) alloy, polystyrene (ps), heat-resistant polystyrene (PS), polymethyl Methyl acrylate (PMMA), polybutylene terephthalate (PBT), polypropylene (PP), polyethylene (pE), acrylonitrile butadiene styrene (ABS), polyurethane (PU), polypyrene Amine (ρι), polystyrene ethylene styrene acrylonitrile mixture (SAN), ethylene vinyl acetate (EVA), polydecylamine (PA), polycondensation (p0M), phenol, epoxy resin (Ep), urea Melanin (UF, MF), unsaturated polyester (UP), strontium (SI), elastomer, cycloolefin polymer 'as part of the sea and island. In this case, the sea portion and the island portion S may have an orientation, and the other of the sea portion and the island portion may have an anisotropy. More preferably, the island portion may be anisotropic and the sea portion may have an orientation. For example, the sea portion of the sea island yarn can use the uniformity C0_PEN, while the island portion can use the birefringence 17 200949300 PEN. Resins with different optical properties can be used in both the sea and island parts of the island yarn. In addition, in a sea-island yarn having an optically oriented substrate and birefringence, depending on the degree of substantial matching or mismatch of the refractive indices of the x, y, and z axes of the space, the degree of light scattering is affected, and the light is affected. That is, according to the corresponding polarization. In general, the change in scattering power is proportional to the square of the degree of refractive index mismatch. Accordingly, if the degree of mismatch of the refractive index according to the specific axis increases, the light polarized according to the corresponding axis is more strongly scattered. However, when the degree of mismatch according to a particular axis is small, the light polarized according to the corresponding axis scatters less. In the case where the refractive index of the substrate according to a specific axis is substantially equal to the refractive index of the island yarn in the sea, the incident light polarized by the electric field parallel to the axis does not scatter, regardless of the size, shape and density of a part of the island yarn in the sea. However, incident light can pass through the island yarn. Furthermore, in the case where the refractive index of the substrate according to a particular axis is substantially equal to the refractive index of the island yarn in the sea, the light does not substantially scatter but passes through the object. Accordingly, in the present invention, the difference in refractive index of the tantalum substrate and the sea-island yarn with respect to the biaxial direction is preferably 0.03 or less, and the refractive index of the substrate and the sea island yarn relative to the remaining one axis direction. The difference is 0.05 or more. In this case, the ρ wave passes through the birefringent interface of the substrate and the island yarn in the sea. However, the s-wave undergoes optical modulation, is reflected, scattered, or refracted, and then converted into an S-wave or a p-wave. The p-wave again passes through the film that increases the visibility and undergoes optical modulation. In particular, the island portion of the 'birefringent sea island yarn may preferably have an anisotropy' and the sea portion may preferably have an anisotropy. It is assumed that the refractive index of the anisotropic island portion in the X-axis direction is nX3, the refractive index of the anisotropic island portion in the y-axis direction is 200949300, the refractive index is nY3, and the refractive index of the anisotropic island portion in the z-axis direction is nZ3, and both The refractive index of the slanting sea portion in the x-axis direction is nX4, the refractive index of the isotropic sea portion in the y-axis direction is nY4, and the refractive index of the isotropic sea portion in the z-axis direction is nZ4, and the refractive indices nX3 and nX4 The absolute value of the difference between the two is preferably 〇. 〇 5 or greater, and more preferably 〇 15 or greater. In this case, the absolute value of the difference between the refractive indices η Υ 3 and η Υ 4 and / or η Ζ 3 and the like may be less than 0.03.

:更好的是於海中島紗拉伸於X軸方向的情形下,折射 率ηχ3和ηΧ4之間差異的絕對值可以是〇 〇5或更大,並且 ㈣=ΠΥ3# ηΥ4之間以及ηΖ3#〇 ηΖ4之間差異的絕對值 可以疋小於〇_〇3。在此情況下,增加光學調變效率是有利 的。在此情況下,可以造成nX3 &gt; nY3 = ηΖ3。 島部分最好可以包括纖維外套以環繞著纖維核心_ 增大:視度的薄膜最好可以包括數個光學調變纖維而帶有 5 t截面並且一或更多種填充物和島部分可以包括雙 斤射聚合物質(例如雙折射膽固醇)。再者,-或更多個光學 調變纖維和島部分最好可以拉伸於長度方向。 關於本發明之雙折射海中島紗的形狀,海中島紗的截 ° 、依據其目的而具有任意形狀,並且可以具有各式各 t非圓形截®,例如圓形、㈣、多邊形。以類似的方 :、海中島紗的島部分截面可以具有非圓形截面,例如圓 /㈣、多邊形,而無論其形狀類別為何。 |^| 3 至_/ 1 1是根據本發明具體態樣之雙折射海中島紗的 哉面圖。如從圖3到&quot;可以看到:於本發明,可以依據其 19 200949300 光學調變目的而有效率地控制島部分的形狀、尺寸數 =…典型海中島紗3。。的截面圖,其中大約二 =分遍是由海部分310a所區分。圖4為海中島紗的 截面圖,其令海部分遍的面積大於島部分舰的面積。 圖5為海中島紗的截面圖,其中海中島紗的形狀是印形。 於圖6,島部分测為㈣,並且島部分32〇d曲折地排列。 ❹ ❹ 此夕’雖然該海中島紗的橫截面具有矩形結構,但是也可 以具有多邊形結構或非圓形截面。 如圖7和8所示範,島邱八” Λ __ 士, 、 # ^刀32(^可以位在海中島紗的 、,或者海部分310f可以位在海中島紗的中央。 :某些具體態樣’島部分可以不具有相同的尺 1而…圖9和10所示範,海中島紗可以包括島部分 g 32lg’其橫截面尺寸不同。於此特定具體態 者⑽g)可以具有比島部分之另—者(叫)相對 :大的橫截面。島部分可以對應於二組或更多組的不同尺 :二且可以具有實f不同的尺寸。再者,如圖&quot;所示, 1和/或均向性覆鞠33Gi可以加到島部分320i。 、、每部ίΓΓ吕’數個島部分可以配置在海中島紗裡,並且 島每=島部分的面積比例最好可以是2:8到8:2。海中 = 具’ °·”&quot;0丹尼的厚度,並&quot;。到 基材裡。=(母立方公分的數目)海中島紗最好可以配置在 膜之λ材者’海部分的折射率可以相等於增大明視度薄 、之基材的折射率。 此外,穿透基材裡之雙折射海中島紗的光可以在雙折 20 200949300 射界面加以光學調變,如上所述。詳言之,圖12是穿透本 發明之雙折射海中島紗的光路徑截面圖。在此情況下,p波 (實線)穿過雙折射海中島紗400而不受到雙折射界面(亦即 基材和雙折射海中島紗400之間的邊界表面以及雙折射海 中島紗400裡島部分420a和海部分410a之間的邊界表面) 所影響’但是S波(虛線)則在雙折射界面(亦即基材和雙折 射海中島紗400之間的邊界表面和/或雙折射海中島紗4〇〇It is better that in the case where the island yarn is stretched in the X-axis direction, the absolute value of the difference between the refractive indices η χ 3 and η Χ 4 may be 〇〇 5 or more, and (4) = ΠΥ 3 # η Υ 4 and η Ζ 3 # The absolute value of the difference between 〇ηΖ4 can be less than 〇_〇3. In this case, it is advantageous to increase the optical modulation efficiency. In this case, nX3 &gt; nY3 = ηΖ3 can be caused. Preferably, the island portion may comprise a fiber jacket to surround the fiber core. The increased: dioptric film may preferably comprise a plurality of optically modulated fibers with a 5 t section and one or more filler and island portions may comprise Double pounds of polymer (such as birefringence cholesterol). Further, - or more of the optically modulated fibers and island portions may preferably be stretched in the length direction. Regarding the shape of the birefringent sea island yarn of the present invention, the cut of the sea island yarn has an arbitrary shape depending on the purpose, and may have various t-circular cuts, for example, a circle, a (four), and a polygon. In a similar way: the island section of the island yarn can have a non-circular cross section, such as a circle / (four), a polygon, regardless of its shape category. |^| 3 to _/ 1 1 is a side view of a birefringent sea island yarn according to a specific aspect of the present invention. As can be seen from Fig. 3 to &quot;&quot;, in the present invention, the shape and size of the island portion can be efficiently controlled according to its 19 200949300 optical modulation purpose = ... typical sea island yarn 3. . A cross-sectional view in which approximately two = divisions are distinguished by sea portion 310a. Figure 4 is a cross-sectional view of the island yarn in the sea, which makes the area of the sea part more than the area of the island part ship. Fig. 5 is a cross-sectional view of an island yarn in the sea, in which the shape of the island yarn in the sea is a printed shape. In Fig. 6, the island portion is measured as (4), and the island portions 32〇d are arranged in a zigzag manner. ❹ ❹ ❹ ’ ′′ Although the cross-section of the sea-goal island yarn has a rectangular structure, it may have a polygonal structure or a non-circular cross section. As shown in Figures 7 and 8, the island Qiu Ba Λ _ _ 士, , # ^刀32 (^ can be located in the sea in the island yarn, or the sea part 310f can be located in the center of the sea island yarn. : Some specific states The 'island portion may not have the same ruler 1 and... as exemplified in Figures 9 and 10, the sea island yarn may include the island portion g 32lg' having a different cross-sectional dimension. The specific embodiment (10)g) may have another than the island portion - (called) relative: large cross section. The island part can correspond to two or more sets of different feet: two and can have different sizes of real f. Again, as shown in the figure, 1 and / Or the average coverage 33Gi can be added to the island portion 320i. Each of the several island parts can be arranged in the sea island yarn, and the area ratio of the island to the island portion can preferably be 2:8 to 8:2. The sea = with ' ° · · &quot; 0 Danny thickness, and &quot;. Into the substrate. = (the number of mother cubes) The sea island yarn is preferably disposed in the λ of the film. The refractive index of the sea portion can be equal to the refractive index of the substrate having a thinner apparent brightness. In addition, the light that penetrates the birefringent sea island yarn in the substrate can be optically modulated at the bi-fold 20 200949300 interface, as described above. In particular, Figure 12 is a cross-sectional view of a light path through the birefringent sea island yarn of the present invention. In this case, the p-wave (solid line) passes through the birefringent sea island yarn 400 without being subjected to the birefringent interface (i.e., the boundary surface between the substrate and the birefringent sea island yarn 400 and the birefringent sea island yarn 400). The boundary surface between the island portion 420a and the sea portion 410a is affected by 'but the S wave (dashed line) is at the birefringent interface (i.e., the boundary surface between the substrate and the birefringent sea island yarn 400 and/or the birefringent sea) Nakajima Yarn 4〇〇

裡島部分420a和海部分410a之間的邊界表面)的影響下被 光學調變。 …果,大部分的S波經由光學調變(例如反射、散射或 折射)而返回光源。返回的s波於反射之後再度變成s波或 P波’然後通過增大明視度的薄膜。據此,如果如上所述使 用雙折射海中島紗,則增大明視度的效率要比使用典型雙 折射纖維的情形來得優異。雙折射海中島紗包括島部分和 海部分’其具有不同的光學性質因此雙折射界面可以形 成於海中島紗裡。據此’相較於雙折射界面並未形成於海 中島紗裡的情形,本發明增大明視度的效率可以顯著增加。 此外,數個海中島紗可以是拉伸於-方向並且配置在 土材裡更好的疋海中島紗21〇 1以配置在基材裡而垂直 於先源。在此情況下’ τ以將光學調變效率放到最大。另 一方面,如果適當的祛 〜也阶署Si 的海中島紗210可以彼此 刀散地配置,或者雙折射 以彼&quot;加可以彼此接觸或可 ,於海中島紗21〇彼此接觸的情況下,它們可 以緊抢形式地形成一層而排列。 21 200949300 再者,舉例而言,如果排列三種或更多種橫截面為不 同直徑圓形的海中島紗,則將垂直於長轴方向之截面中彼 此相鄰的三圓形中心連起來所獲得的三角形就變成不等邊 三角形。此外,在垂直於海中島紗之長軸方向的截面(圓柱 體)中,圓柱體的排列造成第一層的圓形與第二層的圓形彼 此接觸。然而,相對於每個海中島紗而言,只要滿足以下 條件:「每個海中島紗與二條或更多條不同的海中島紗接 觸’它們在其圓柱體的侧面上彼此接觸」。在此範圍裡, 5 舉例而言,於第一層的圓形與第二層的圓形彼此接觸的架 構中,則第二層的圓形與第三層的圓形彼此之間以插入的 支撐介質所隔開,並且第三層的圓形與第四層的圓形彼此 接觸也是可能的。 於垂直於海中島紗長軸方向之截面中連接彼此直接接 觸的三圓形中心的三角形,其至少二邊的邊長最好是大約 相同。尤其,三角形的三個邊長最好是大約相同。此外, 6 有關於海中島紗在增大明視度薄膜之厚度方向的堆疊狀 態,數層堆疊的方式最好是依序彼此接觸。再者,具有幾 乎相同直徑之圓柱體的海中島紗更佳的是緊密地填充。 據此,於此更佳的形式中,數個海中島紗在垂直於其 長軸方向之截面中的圓形直徑具有幾乎相同的圓柱體,並 且截面中之位置要比最外表面層更裡面的海中島紗係接觸 著雙折射體,亦即六個不同的圓柱體是在該圓柱體的侧面 上。 此外’相對於1立方公分之増大明視度的薄膜,最好 22 200949300 有利的是雙折射海中島紗佔i體積%到9G體積%。如 中島紗的編1%或更小,則增大明視度的效果就不顯 著。如果海中島紗的體積為9〇%或更大,則可能產生問題《, 這是因為雙折射界面造成散射増加,因此產生光學損失The boundary surface between the island portion 420a and the sea portion 410a is optically modulated. ..., most of the S waves return to the source via optical modulation (such as reflection, scattering or refraction). The returned s wave becomes s-wave or P-wave again after reflection and then passes through a film that increases the visibility. According to this, if the birefringent sea island yarn is used as described above, the efficiency of increasing the visibility is superior to the case of using the typical birefringent fiber. The birefringent sea island yarn comprises an island portion and a sea portion 'which have different optical properties so that the birefringent interface can be formed in the sea island yarn. Accordingly, the efficiency of the present invention for increasing the visibility can be significantly increased as compared with the case where the birefringence interface is not formed in the sea island yarn. In addition, several sea-in-the-sea yarns can be stretched in the - direction and placed in the soil to better the sea bream yarn 21 〇 1 to be placed in the substrate perpendicular to the source. In this case 'τ to maximize the optical modulation efficiency. On the other hand, if the appropriate 祛 也 也 的 的 的 的 的 的 的 的 的 的 的 的 的 的 的 Si Si Si Si Si Si Si Si Si Si Si Si Si Si Si Si Si Si 210 210 210 210 210 210 210 210 210 Si Si They can be arranged in a tightly formed form. 21 200949300 Furthermore, for example, if three or more sea island yarns having different circular cross-sections are arranged, the three circular centers adjacent to each other in the cross section perpendicular to the long axis direction are obtained. The triangle becomes an inequilateral triangle. Further, in the section (cylinder) perpendicular to the long axis direction of the island yarn in the sea, the arrangement of the cylinder causes the circular shape of the first layer to contact the circular shape of the second layer. However, with respect to each of the island yarns, as long as the following conditions are satisfied: "Every sea island yarn is in contact with two or more different sea island yarns" which are in contact with each other on the side of the cylinder. In this range, for example, in a structure in which the circular shape of the first layer and the circular shape of the second layer contact each other, the circular shape of the second layer and the circular shape of the third layer are inserted into each other. It is also possible that the support media are separated, and the circular shape of the third layer and the circular shape of the fourth layer are in contact with each other. The triangles of the three circular centers that are directly in contact with each other in a section perpendicular to the long axis direction of the island yarn in the sea are preferably at least about the same side length. In particular, the three side lengths of the triangle are preferably about the same. In addition, regarding the stacking state of the sea-island yarn in the thickness direction of the bright-view film, the stacking of the plurality of layers is preferably sequentially in contact with each other. Furthermore, sea island yarns having cylinders of almost the same diameter are more preferably tightly packed. Accordingly, in this preferred form, the plurality of sea-in-the-sea yarns have substantially the same cylindrical shape in a circular diameter in a section perpendicular to the long-axis direction thereof, and the position in the cross-section is more inside than the outermost surface layer. The island yarns in the sea are in contact with the birefringent body, that is, six different cylinders are on the side of the cylinder. Further, it is preferable to use a film having a large brightness of 1 cubic centimeter, preferably 22 200949300. It is advantageous that the birefringent sea island yarn accounts for i% by volume to 9 g% by volume. If the Nakajima yarn is 1% or smaller, the effect of increasing the visibility is not significant. If the volume of the island yarn in the sea is 9〇% or more, there may be a problem. This is because the birefringence interface causes scattering and thus causes optical loss.

再者,500到條雙折射海中島紗可以配置在1立方 公分之增大明視度的薄膜裡。雙折射海中島紗裡的島部分 截面直徑也可以對光學調變產生顯著效果。如果雙折射= 中島紗裡每個島部分的截面直徑小於光學波長’則折射、 散射、反射效果會下降’因此幾乎無法產生光學調變。如 果島部分的截面直徑太大,則光會從雙折射海中島紗的表 面經歷規則反射’並且其他方向的擴散就極不顯著。對齊 之島部分的截面直徑可以依據光學物體所欲用途來改變。 舉例而言,纖維的直徑可以與電磁射線的波長高度相關, 這在特定用途下很重要,並且需要不同直徑的纖維以便反 射、散射或穿透可見光、紫外線、紅外線、微波。 增大明視度的薄膜最好可以依據其目的而包括結構化 表面層。圖13到18是根據本發明具體態樣的增大明視度 薄膜之結構化表面的截面圖。於圖13,增大明視度薄膜的 入射表面和出射表面可以平行於光源5〇〇a所發出的光。在 此情況下,如圖14所示,位在光源5001)上(相鄰於光源5〇〇b) 的雙折射海中島紗52 1 b可以緊密地配置’而遠離光源5〇〇b 的雙折射海中島紗520b可以鬆散地配置。 結構化表面層可以形成於輸出光的表面上。結構化表 面層可以具有稜鏡形狀、透鏡形狀或凸透鏡形狀。詳言之, 23 200949300 於圖15,增大明視度薄膜上之輸出光的表面可以具有彎曲 表面53 0c ’其為凸透鏡形狀。彎曲表面530c可以將穿過表 面的光加以聚焦或散焦。此外,如圖1 6所示,稜鏡圖案530d 可以形成於光出射表面。在此情況下,雙折射海中島紗52〇d 可以不形成於結構化表面層53 0d,如圖16所示;雙折射海 中島紗520e可以同時形成於基材和表面層53〇e,如圖17Furthermore, the 500-to-bar birefringent sea-island yarn can be placed in a film of 1 cubic centimeter of increased visibility. The cross-sectional diameter of the island portion in the birefringent sea island yarn can also have a significant effect on optical modulation. If the birefringence = the cross-sectional diameter of each island portion in the mid-island yarn is smaller than the optical wavelength, the refraction, scattering, and reflection effects are lowered', so that optical modulation is hardly produced. If the cross-sectional diameter of the island portion is too large, the light will undergo regular reflection from the surface of the island yarn in the birefringent sea and the diffusion in other directions will be extremely insignificant. The cross-sectional diameter of the aligned island portion can vary depending on the intended use of the optical object. For example, the diameter of the fibers can be highly correlated with the wavelength of the electromagnetic radiation, which is important for a particular application and requires fibers of different diameters to reflect, scatter or penetrate visible light, ultraviolet light, infrared light, microwaves. Preferably, the film which increases the clarity can comprise a structured surface layer depending on its purpose. 13 through 18 are cross-sectional views of a structured surface for increasing the clarity film in accordance with an embodiment of the present invention. In Fig. 13, the incident surface and the exit surface of the increased brightness film may be parallel to the light emitted by the light source 5a. In this case, as shown in FIG. 14, the birefringent sea island yarn 52 1 b located on the light source 5001) (adjacent to the light source 5〇〇b) can be closely arranged 'and away from the light source 5〇〇b The refracted sea island yarn 520b can be loosely arranged. A structured surface layer can be formed on the surface of the output light. The structured surface layer may have a serpentine shape, a lens shape or a convex lens shape. In particular, 23 200949300 In Fig. 15, the surface of the output light on the brightening film may have a curved surface 53 0c ' which is a convex lens shape. The curved surface 530c can focus or defocus the light passing through the surface. Further, as shown in FIG. 16, the 稜鏡 pattern 530d may be formed on the light exit surface. In this case, the birefringent sea island yarn 52〇d may not be formed on the structured surface layer 53 0d as shown in FIG. 16; the birefringent sea island yarn 520e may be simultaneously formed on the substrate and the surface layer 53〇e, such as Figure 17

所不;或者雙折射海中島紗52〇f可以只形成於結構化表面 層53 Of,如圖18所示。 經由消光處理可以把凹凸部分形成於增大明視度薄膜 的後表面,其可以賦予抗刮性質。在對本發明不會造成不 利效果的情況下可以如此進行。 此外,光源發送的光可以包括自然光和偏振光,並且 可以使用幾種具有雙折射性的材料做為雙折射海中島紗。 然而,從指向、截面形狀穩定性、耐用性......等的觀點來 看,雙折射海中島紗最好是實心的。 如圖19和20所示,海中島紗最好可以使用緯紗61〇&amp;、 6〇〇b和經紗600a、610b所編織。緯紗和經紗當中任一者可 以是海中島紗,而緯紗和經紗當中另—者可以是均向性纖 維。緯紗或經紗最好可以制1冑咖線的海中島紗而形 本發明的雙折射海中島紗 列於一方向而成編織物或線軸 著。可以使用已知方法來進行 或是編織物或線軸的編織過程 可加以紡紗和延伸,並且排 .、:後·次渗以基材並使之固 海中島紗的捻線和延伸過程 ’但未特別受限於此。在將 24 200949300 編織物或線軸&amp;滲以基材並使之固著時,可以使用以下方 法或類似者.浸泡非編織物於單體和/或寡聚物溶液(亦即 基材的4驅物),然後使用光和/或熱來聚合此支撐介質的 刖驅物;浸泡編織物或線軸於支撐介質的聚合物溶液,然 後移除冷劑,將支撐介質製成細微粉末,使細微粉末浸滲 於編織物或線轴中,然後熔化之。 ❹No; or the birefringent sea island yarn 52〇f may be formed only on the structured surface layer 53 Of, as shown in FIG. The uneven portion can be formed on the rear surface of the film of the augmented brightness by the matting treatment, which can impart scratch resistance. This can be done without causing adverse effects to the present invention. Further, the light transmitted from the light source may include natural light and polarized light, and several materials having birefringence may be used as the birefringent sea island yarn. However, from the viewpoints of pointing, cross-sectional shape stability, durability, etc., the birefringent sea-island yarn is preferably solid. As shown in Figures 19 and 20, the sea island yarns are preferably woven using weft yarns 61〇 &amp;, 6〇〇b and warp yarns 600a, 610b. Any of the weft and warp yarns may be sea island yarns, and the other of the weft yarns and warp yarns may be oriented fibers. Preferably, the weft or warp yarn can be made into a seaweed yarn of a line of coffee. The birefringent sea island yarn of the present invention is formed in a direction to form a braid or a bobbin. It can be carried out by a known method or the weaving process of the braid or the bobbin can be spun and stretched, and the rear and back penetration of the substrate and the solidification of the yarn in the sea island yarn can be carried out. It is not particularly limited to this. When the 24 200949300 woven fabric or bobbin &amp; is infiltrated with the substrate and fixed, the following method or the like may be used. The non-woven fabric is immersed in the monomer and/or oligomer solution (ie, the substrate 4). Driving, then using light and/or heat to polymerize the ruthenium drive of the support medium; soaking the braid or the polymer solution of the bobbin to the support medium, then removing the cold agent, making the support medium into a fine powder, making the fine The powder is impregnated into the braid or spool and then melted. ❹

此外以另一種方法來說,本發明可以使用熔融擠製 方法來實施。詳言之,垂直於分散排列在基材裡的雙折射 海中島紗之長轴方向的截面若為多邊形,則可以採用以下 的輪廓擠製法,其將擠製機的釋出口畫分成數個限制區, 而把構成雙折射海中島紗的樹脂從每個喷絲頭擠出成為多 邊形’並且從該等噴絲頭之間㈣絲㈣出構成基材的樹 脂。垂直於分散排列在支撐介質裡的雙折射海中島紗之長 轴方向的截面若為實質圓形,則可以採用以下的輪廓擠製 法:將擠製㈣釋出口 ί分成數個喷絲帛,而把構成雙折 射海中島紗的樹脂從截面中為連續的喷絲頭擠出成為圓柱 形式’並且從料喷絲頭之間时絲頭㈣構成基材的樹 脂。於此等情況,可以設計擠製機和限制區,以使不同種 類的融化樹脂以特定形式從擠製機的噴絲頭交替擠出,因 而形成上述分散排列的結構。 此外,本發明可以提供 匕枯尽發明前述 之增大明視度的薄膜,並且也可以提供包括該背光單元的 液晶顯示裝置。在此情況下,液晶顯示裝置可 Α匕栝相差 缚膜和/或吸收型偏振薄膜。 25 200949300 結果,於使用雙折射海中島紗(其在增大明視度的薄膜 裡包括配置於均向性海部分的異向性島部分)做為雙折射纖 維的情形下,不僅基材和雙折射海中島紗之間產生光學調 變效果,同時雙折射海中島紗裡的異向性島部分和均向性 海部分之間也產生光學調變效果。據此,可以顯著增加增 大明視度薄膜的光學調變效果。尤其海中島紗經检線形成 共軛接合纖維之後,它們編織成末端和緯紗的形式而配置 在增大明視度的薄膜,可以獲得優異的光學調變效果,此 非使用典型的雙折射纖維所能相比。 &lt;發明實施模式&gt; 現在將配合具體態樣和實驗範例來詳細敘述本發明。 底下的具體態樣和實驗範例僅在示範本發明,並且本發明 的範圍並不受限於底下的具體態樣和實驗範例。 &lt;具體態樣1&gt; 由異向性 PEN (nx=i.88,ny=1.57,nz=1 57)所構成的 ^ 37個島部分配置在均向性co-PEN (nx=i.57,ny=157 ’Further, in another approach, the invention can be practiced using a melt extrusion process. In detail, if the cross section perpendicular to the long axis direction of the birefringent sea island yarn dispersed in the substrate is a polygon, the following contour extrusion method may be employed, which divides the discharge drawing of the extruder into several restrictions. In the region, the resin constituting the birefringent sea island yarn is extruded from each spinneret into a polygonal shape, and the resin constituting the substrate is drawn from the (four) filaments (four) between the spinnerets. If the cross section perpendicular to the long axis direction of the birefringent sea island yarn dispersed in the support medium is substantially circular, the following contour extrusion method may be employed: the extruded (four) release outlet ί is divided into several spinnerets, and The resin constituting the birefringent sea island yarn is extruded into a cylindrical shape from a continuous spinneret in a cross section and constitutes a resin of the substrate from the filament head (four) between the spinnerets. In such cases, the extruder and the restriction zone can be designed such that different types of melted resin are alternately extruded from the spinneret of the extruder in a particular form, thereby forming the above-described dispersed arrangement. Further, the present invention can provide a film which increases the visibility of the aforementioned invention, and can also provide a liquid crystal display device including the backlight unit. In this case, the liquid crystal display device may be a phase difference film and/or an absorbing polarizing film. 25 200949300 As a result, in the case of using birefringent sea-island yarns, which include an anisotropic island portion disposed in the isotropic sea portion in a film having increased visibility, as a birefringent fiber, not only the substrate and the double The optical modulation effect is produced between the refraction of the island yarns in the sea, and the optical modulation effect is also produced between the anisotropic island portion and the isotropic sea portion in the birefringent sea island yarn. Accordingly, the optical modulation effect of the enhanced brightness film can be significantly increased. In particular, after the yoke-bonded fibers are formed by the warp yarns in the sea, they are woven into the form of the ends and the weft yarns and are disposed in the film which increases the visibility, and an excellent optical modulation effect can be obtained, which is not the use of typical birefringent fibers. Can compare. &lt;Invention Modes&gt; The present invention will now be described in detail in conjunction with specific aspects and experimental examples. The following specific examples and experimental examples are merely illustrative of the invention, and the scope of the invention is not limited to the specific examples and experimental examples. &lt;Specific Aspect 1&gt; ^ 37 island portions composed of anisotropic PEN (nx=i.88, ny=1.57, nz=1 57) are arranged in the uniformity co-PEN (nx=i.57) ,ny=157 '

’1.57)做的填充物裡。於此組成’使用以下條件進行捻 線··未拉伸紗150 / 24,紡紗溫度305t,紡紗速度為每分 鐘1500公尺,經過三次拉伸而獲得拉伸紗5〇/24。此時製 造的海中島紗包含由異向性ΡΕΝ (ηχ=1 88,町=ι Μ, ηζ~1·57)所構成的37個島部分,其配置在均向性c〇_pEN =X=1·57’ ny=1·57’ nz=1.57)做的填充物裡。將 4 2〇〇 股製 造的海中島紗(由於24股生紗做為一組,所以纖維股的真正 數目為100,800股,亦即4,200x24)平行纏繞在毫米線 26 200949300 軸上之後’纏繞的線軸則放在後表面已進行消光處理的Pc 合金片上’然後使用特定張力來堆疊。在此,PC合金片的 折射率為1.57。之後,環氧基丙烯酸酯和胺曱酸乙酯丙烯 酸醋做的混合式紫外線硬化塗覆樹脂(其折射率為1 54)塗 覆在堆疊了纖維的PC合金片上以及在引入鏡面滾壓的地 方’然後再經歷主要和次要的紫外線硬化過程,藉此製造 當中堆疊了雙折射海中島紗的摻合片。雖然塗覆樹脂在紫 ❹ 外線塗覆硬化之前顯示的折射率為丨·54,但是硬化之後顯 不的折射率為1.57。基於此事實,製造了厚度4〇〇微米之 增大明視度的薄膜。 &lt;具體態樣2&gt; 以相同於具體態樣!的方式製造厚度4〇〇微米之增大 明視度的薄膜’例外的是島部分的數目為217。 &lt;具體態樣3&gt; 以相同於具體態樣2的方式製造厚度400微米之增大 ❹ Θ視度的薄膜,例外的是用於具體態樣2的海中島紗經歷 四-人共軛接合(50 / 24x4)以獲得2〇〇/ 96生紗,然後再使 用。 &lt;具體態樣4&gt; 為了簡化具體態樣2所用纖維混合於PC片的過程,編 織4’200股_’而使用線轴得到緯紗密度為每英对5〇條, =纏繞4,·股以使之平行排列減度W毫米,如具體 Μ 1所述。織物經過平織讀使緯紗密度減到最小。製 造的編織物在從片狀擠製模具上經過線捲釋出的同時便堆 27 200949300 疊於pc片上,如具體態樣1所述,然後再塗以塗覆劑和加 以硬化’藉此製出厚度400微米之增大明視度的薄膜。 &lt;具體態樣5&gt; 為了改進增大明視度薄膜的光學使用效率,將結構化 表面層形成於具體態樣3的增大明視度薄膜上。以相同於 具體痣樣3的方式製造厚度4〇〇微米之增大明視度的薄膜, 例外的是於摻合片製程期間使用稜鏡圖案滾壓以形成結構 化表面層。 ❹ &lt;比較例1 &gt; 以相同於具體態樣1的方式製造厚度400微米之增大 月視度的薄膜’例外的是使用未拉伸的均向性纖維丨/ 24 ’其由C0_PEN (nx=ny=nz=l 57)所構成,而非雙折射海中 島紗。 &lt;比較例2&gt; 以相同於具體態樣1的方式製造厚度400微米之增大 ❹%視度的薄膜’例外的是使用未拉伸的紗,其具有海中島 結構(包含24個島部分),而由pET (nx=ny=nz=i 5乃和 c〇-PEN (nx=ny=nz=l 57)所構成。 &lt;比較例3 :&gt; 將IV 0.53的PEN樹脂加以聚合而非依據具體態樣^ 雙折射海中島紗之後,製出未拉伸紗1 50 / 24的生紗。 時使用以下條件進行擒線:纺紗溫度3051,纺紗速度 為每分鐘1500公圮 私说作 a尺所獲仟的未拉伸紗在1 50°C的溫度範 圍拉伸三次,因而制, , 製出50 / 24的拉伸紗。拉伸的pen纖維 28 200949300 顯示雙折射性,並且各方向的折射率為nx=188、ny=i 57、 nz=1.57。以相同於具體態樣1的方式製造厚度400微米之 增大明視度的薄膜,例外的是包含著雙折射性PEN纖維, 而非具體態樣1的海中島紗。 &lt;實驗範例&gt; 針對依據具體態樣1到5和比較例1到3所製造之择 大明視度的薄膜,評估以下物理性質,其結果列於表i。 1 ·明視度 為了測量所製造之增大明視度薄膜的明視度,進行以 下測試。在配備了擴散板、二片擴散片、增大明視度薄膜 的52英吋直接照光式背光單元上組裝面板之後,使用bm-7 測試器(韓國TOPCON公司)在9點測量明視度,並且列出 其平均值》 2. 穿透度 依據ASTM D2003方法,穿透度使用COH500A分析儀 (日本NIPPON DENSHOKU公司)來測量。 3. 偏振度 偏振度使用RETS-200分析儀(日本OTSKA公司)來測 4^ ° 4.溼度吸收因數 依據ASTM D5 70,增大明視度的薄膜浸泡在23°C的水 中達24小時,然後測量此過程前後的重量%變化。 5_ 片芽度(sheet sprout) 增大明視度的薄膜組裝於52英吋的背光單元’再留在 29 200949300 60°C、75%的恆溫恆濕條件下96小時’然後加以溶解,以 便用肉眼觀察增大明視度的薄膜所產生的芽。觀察的結果 以〇、△、&gt;&lt;來註記。(〇:良正常,X:差) 6.抗紫外線性質 增大明視度的薄膜使用SMDT51H (韓國SEI MYUNG VACTRON有限公司)之130毫瓦輸出的紫外線燈(365奈米) 於高度10公分處照射1〇分鐘。使用SD-5000分析儀(日本 NIPPON DENSHOKU公司)測量此過程前後的γι (YeU〇w Ο‘1.57) made in the filler. The composition was subjected to the following conditions: the untwisted yarn 150 / 24, the spinning temperature was 305 t, the spinning speed was 1,500 m per minute, and the drawn yarn was obtained 5 times/24 after three times of stretching. The sea island yarn manufactured at this time contains 37 island parts composed of anisotropic ΡΕΝ (ηχ=1 88, machi = ι Μ, ηζ~1·57), which is arranged in the uniformity c〇_pEN =X =1·57' ny=1·57' nz=1.57) in the filling. The sea-island yarn made of 4 2 strands (because of 24 strands of raw yarn as a group, the true number of fiber strands is 100,800 strands, ie 4,200x24) is wound in parallel on the millimeter line 26 200949300 shaft. The spools are placed on Pc alloy sheets whose back surface has been matted and then stacked using specific tension. Here, the refractive index of the PC alloy sheet was 1.57. Thereafter, a mixed ultraviolet curable coating resin (having a refractive index of 154) made of epoxy acrylate and amine acetoacetate acrylate was coated on the fiber-stacked PC alloy sheet and introduced into the mirror roll. 'Then then undergoing major and minor UV hardening processes, thereby producing blended sheets in which birefringent sea island yarns are stacked. Although the coating resin exhibited a refractive index of 丨·54 before the outer coating of the enamel coating, the refractive index after curing was 1.57. Based on this fact, a film of increased brightness of 4 〇〇 micron was produced. &lt;Specific Aspect 2&gt; is the same as the specific aspect! The way to make a thickness of 4 〇〇 micron increases the brightness of the film 'except for the number of island portions is 217. &lt;Specific Aspect 3&gt; A film having a thickness of 400 μm and an increase in Θ Θ is produced in the same manner as in the specific aspect 2, except that the sea-island yarn for the specific aspect 2 undergoes four-human conjugate bonding. (50 / 24x4) to get 2 〇〇 / 96 raw yarn before using. &lt;Specific Aspect 4&gt; In order to simplify the process in which the fibers used in the specific aspect 2 are mixed with the PC sheet, 4'200 strands are woven, and the bobbin is used to obtain a weft density of 5 strands per inch, = 4 windings, In order to arrange them in parallel by a reduction of W mm, as described in detail Μ 1. The fabric is subjected to a flat weave to minimize the weft density. The manufactured braid is released from the sheet extrusion die while the stack 27 200949300 is stacked on the pc sheet, as described in the specific aspect 1, and then coated with a coating agent and hardened. A film of increased brightness of 400 microns is produced. &lt;Specific Aspect 5&gt; In order to improve the optical use efficiency of the high-definition film, the structured surface layer was formed on the enlarged vision film of the specific aspect 3. An augmented film having a thickness of 4 μm was produced in the same manner as the specific pattern 3 except that a ruthenium pattern was rolled during the blending sheet process to form a structured surface layer. ❹ &lt;Comparative Example 1 &gt; A film having a thickness of 400 μm for increasing the degree of refraction was produced in the same manner as in the specific aspect 1 except that an unstretched oriented fiber 丨 / 24 ' was used by C0_PEN ( Nx=ny=nz=l 57) is constructed instead of birefringent sea island yarn. &lt;Comparative Example 2&gt; A film having a thickness of 400 μm and an increase in % visibility was produced in the same manner as in the specific aspect 1 except that an unstretched yarn having an island structure in the sea (including 24 island portions) was used. And consists of pET (nx=ny=nz=i 5 and c〇-PEN (nx=ny=nz=l 57). &lt;Comparative Example 3:&gt; The PEN resin of IV 0.53 was polymerized. Non-refractory yarns of 1 50 / 24 are produced after the birefringence of the sea island yarn. The twisting is performed using the following conditions: spinning temperature 3051, spinning speed 1500 ft. per minute The undrawn yarn, which is said to be a ruler, is stretched three times at a temperature of 150 ° C, thereby producing a 50 / 24 drawn yarn. The stretched pen fiber 28 200949300 shows birefringence, And the refractive index in each direction is nx=188, ny=i 57, nz=1.57. A film of increased brightness of 400 micrometers is produced in the same manner as in the specific aspect 1, except that the birefringence PEN is contained. Fiber, not the sea-island yarn of the specific aspect 1. &lt;Experimental example&gt; The selection made according to the specific aspects 1 to 5 and the comparative examples 1 to 3 The film of the apparent brightness was evaluated for the following physical properties, and the results are shown in Table 1. 1 · Brightness In order to measure the apparent brightness of the manufactured high-vision film, the following test was carried out. After assembling the panel on a 52-inch direct-illumination backlight unit with a diffuser and a high-definition film, the bm-7 tester (TOPCON, Korea) was used to measure the brightness at 9:00 and the average value was listed. The penetration is measured according to the ASTM D2003 method, and the penetration is measured using a COH500A analyzer (NIPPON DENSHOKU, Japan) 3. Polarization degree of polarization is measured using a RETS-200 analyzer (OTSKA, Japan) 4^° 4. Humidity absorption Factor According to ASTM D5 70, the film with increased clarity is immersed in water at 23 ° C for 24 hours, and then the change in weight % before and after the process is measured. 5_ 片 sprout (sheet sprout) The film with increased clarity is assembled at 52 The backlight unit of the inch is then left at 29 200949300 60 ° C, 75% under constant temperature and humidity conditions for 96 hours' and then dissolved to visually observe the buds produced by the film of increased clarity. The results of the observation are 〇, △, &gt;&lt;Remarks. (〇: Good normal, X: Poor) 6. UV-resistant properties increase the visibility of the film using SMDT51H (Korea SEI MYUNG VACTRON Co., Ltd.) 130 mW output UV lamp (365 nm) Irradiation for 1 minute at a height of 10 cm. Γι (YeU〇w 前后 before and after this process was measured using an SD-5000 analyzer (NIPPON DENSHOKU, Japan)

Index,黃色指數),並且評估其黃度(yellowness index)。 [表1]Index, yellow index), and evaluate its yellowness index. [Table 1]

從表1可以看到具體態樣丨到5之包括雙 紗的增大明視度薄膜,其光學性質遠遠優於包括均島 30 200949300 維的比較例1和2。也可以看到具體態樣1到5之包括雙折 射海中島炒的增大明視度薄膜,其光學性質遠遠優於包括 雙折射纖維的比較例3。 &lt;產業應用性&gt; 本發明之增大明視度的薄膜可以廣泛用於液晶顯示裝 置’例如需要高明視度的行動電話和LCD。 〇 【圖式簡單說明】 圖1是示範傳統的增大明視度之薄膜的原理示意圖; 圖2是根據本發明具體態樣的增大明視度之薄膜的截 面示意圖; 81 3到11是根據本發明具體態樣之雙折射海中島紗的 戴面圖; 圖12是顯示入射於本發明雙折射海中島紗上的光路徑 戴面圖; Ο 圖13到18是本發明的增大明視度薄膜之結構化表面 的截面圖;以及 圖丨9和20顯示根據本發明具體態樣之雙折射光學調 變纖維的排列。 【主 2〇〇 21〇 3〇〇 要元件符號說明】 基材 海中島紗 海中島紗 31 200949300 310a、b、c、d、e、f、g、h、i 海部分 320a、b、c、d、e、f、g、h、i 島部分 321g 島部分 330i 覆鞘 400 海中島紗 410a 海部分 420a 島部分 500a ' b 光源From Table 1, it can be seen that the specific aspect 丨 to 5 includes an enlarged vision film comprising double yarns, the optical properties of which are far superior to those of Comparative Examples 1 and 2 including the average island 30 200949300 dimension. It can also be seen that the specific aspect 1 to 5 includes a double-folded sea-island-enriched high-definition film which is far superior in optical properties to Comparative Example 3 including birefringent fibers. &lt;Industrial Applicability&gt; The film of increased brightness of the present invention can be widely used for liquid crystal display devices, for example, mobile phones and LCDs requiring high visibility. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic view showing the principle of a conventional film for increasing the visibility; FIG. 2 is a schematic cross-sectional view showing a film for increasing the visibility according to a specific aspect of the present invention; 81 3 to 11 are according to the present invention. Fig. 12 is a perspective view showing a light path incident on a birefringent sea island yarn of the present invention; Ο Figs. 13 to 18 are enlarged vision films of the present invention. A cross-sectional view of the structured surface; and Figures 9 and 20 show the arrangement of birefringent optically modulated fibers in accordance with an embodiment of the present invention. [Main 2〇〇21〇3〇〇Required Symbol Description] Substrate Haizhong Island Yarn Island Yarn 31 200949300 310a, b, c, d, e, f, g, h, i Sea part 320a, b, c, d, e, f, g, h, i island portion 321g island portion 330i sheathing 400 sea island yarn 410a sea portion 420a island portion 500a 'b light source

510a' b 基材 520a、b、c、d、e、f 海中島紗 521b 海中島紗 530c 彎曲表面 530d 稜鏡圖案 530e、f 表面層 600a 經紗 600b 緯紗 610a 緯紗 610b 經紗 BLU 背光單元 P P偏振光 S S偏振光 32510a' b Substrate 520a, b, c, d, e, f Sea island yarn 521b Sea island yarn 530c Curved surface 530d 稜鏡 pattern 530e, f Surface layer 600a Warp 600b Weft 610a Weft 610b Warp BLU Backlight unit PP polarized light SS Polarized light 32

Claims (1)

200949300 十、申請專利範面: 1. 一種增大明視度的薄膜,其在基材裡包括具有雙折射 性的海中島紗。 2·如申請專利範圍第1項之增大明視度的薄膜,其中基 材具有均向性。 3. 如申請專利範圍第2項之增大明視度的薄膜,其中基 材包括選自組成以下群組中的任一或多者:聚萘二甲酸二 乙S曰(PEN)、共聚萘二曱酸二乙酯(c〇_pEN)、聚對苯二甲酸 © 乙一酯(PET)、聚碳酸酯(PC)、聚碳酸酯(ρ〇合金、聚苯乙 烯(PS)、耐熱聚苯乙烯(Ps)、聚曱基丙烯酸甲酯(PMMA)、 聚對苯二甲酸丁二酯(PBT)、聚丙烯(PP)、聚乙烯(PE)、丙 烯腈丁一烯苯乙烯(ABS)、聚胺酯(PU)、聚醯亞胺(PI)、聚 氯乙烯(PVC)、苯乙烯丙烯腈混合物(SAN)、乙烯醋酸乙烯 知(EVA)、聚醯胺(PA)、聚縮醛(p〇M)、酚、環氧樹脂(Ep)、 尿素(UF)、黑色素(MF)、不飽和聚酯(up)、矽(si)、彈性體、 環烯烴聚合物。 〇 ^ 4. 如申請專利範圍第2項之增大明視度的薄膜,其中基 材的折射率範圍從1.4到2.0。 5. 如申請專利範圍第丨項之增大明視度的薄膜,其中海 中島紗在基材一方向中配置成複數。 6. 如申請專利範圍第1項之增大明視度的薄膜,其中海 中島紗在基材裡配置成垂直於光源。 7_如申請專利範圍第5項之增大明視度的薄膜,其中海 中島紗乃隨機地配置於基材裡。 33 200949300 8. 如申請專利範圍第5項之增大明視度的薄膜,其中海 中島紗在基材裡乃彼此接觸地配置。 9. 如申s月專利範圍第5項之增大明視度的薄膜,其.中海 中島紗在基材裡形成一或更多層β 10·如申請專利範圍第i項之增大明視度的薄膜,其中: 基材和海中島紗相對於二軸方向之折射率的差異是 0.〇3或更小,以及200949300 X. Patent application: 1. A film that increases the visibility, including a birefringent sea-island yarn in the substrate. 2. A film of increased clarity as in claim 1 of the patent application, wherein the substrate has an average orientation. 3. The film of the invention of claim 2, wherein the substrate comprises one or more selected from the group consisting of polyethylene naphthalate (PEN), copolymerized naphthalene Diethyl citrate (c〇_pEN), polyethylene terephthalate (PET), polycarbonate (PC), polycarbonate (ρ〇 alloy, polystyrene (PS), heat resistant polystyrene (Ps), polymethyl methacrylate (PMMA), polybutylene terephthalate (PBT), polypropylene (PP), polyethylene (PE), acrylonitrile butadiene styrene (ABS), polyurethane (PU), polyimine (PI), polyvinyl chloride (PVC), styrene acrylonitrile mixture (SAN), ethylene vinyl acetate (EVA), polyamine (PA), polyacetal (p〇M ), phenol, epoxy resin (Ep), urea (UF), melanin (MF), unsaturated polyester (up), cerium (si), elastomer, cyclic olefin polymer. 〇 ^ 4. The film of the second aspect of the invention, wherein the refractive index of the substrate ranges from 1.4 to 2.0. 5. The film of the invention of increasing the visibility according to the scope of the patent application, wherein the sea island yarn is In the direction of the material, it is arranged in plural. 6. For the film of increased visibility in item 1 of the patent application, wherein the sea island yarn is arranged perpendicular to the light source in the substrate. 7_Additional item 5 of the patent application scope A large-viscosity film in which sea-island yarns are randomly disposed in a substrate. 33 200949300 8. A film of increased clarity as disclosed in claim 5, wherein the sea-island yarns are in contact with each other in the substrate. 9. For example, in the case of increasing the clarity of the film in item 5 of the patent scope of the application, the medium-sea island yarn forms one or more layers of β 10 in the substrate. Degree film, wherein: the difference in refractive index between the substrate and the sea island yarn relative to the biaxial direction is 0. 〇 3 or less, and 基材和海中島紗相對於剩下—轴方向之折射率的差異 是0.05或更大。 11 ·如申请專利範圍第1〇項之增大明視度的薄膜,其中 剩下一轴方向是海中島紗的長度方向。 12.如申請專利範圍第1項之增大明視度的薄膜,其中 增大明視度薄膜裡的海中島紗數目為每立方公| 500到 4,000,000 條 ° 其中 其中 其中 13·如申請專利n圍第i項之增大明視度的薄膜, 海中島紗於長度方向上具有圓形或印形截面。 14.如申凊專利範圍第i項之增大明視度的薄膜, 海中島紗於長度方向上具有非圓形截面。 、 項之增大明視度的薄膜, 1 5.如申請專利範圍第1 海中島紗的海部分為均向性 如甲睛專利範圍第1項之增大 海中島紗的島部分為異向性 17·如申β專利範圍第i項之増大明視度的薄膜,其中. 海中島紗的海部分和島部分相對於二轴方向之折射率 34 200949300 的差異是0.03或更小,以及 =島紗的海部分和島部分相對於剩下一軸方 射率的差異是0.05或更大。 I8·如申請專利範圍第17項之増大明視度的薄膜 剩下-軸方向是海中島紗的長度方向。 19·如申請專利範圍第17項之増大明視度的薄膜,其中 海部分的折射率為1.4到2.0。 Ο 〇’如中凊專利範圍第!項之增大明視度的薄膜,其中 海中島紗的島部分配置成複數。 21.如申請專利ϋ圍帛1;|^之增大明視度的薄膜,其中 海Ρ刀和I σρ分之基於海中島紗橫截面的面積比例是2 : 8 到 8 : 2。 22. 如申凊專利範圍第丨項之增大明視度的薄膜,其中 海中島❼的海部分包括選自组成以下群組中的任一或多 者··聚萘二甲酸二乙酯(PEN)、共聚萘二甲酸二乙酯 _ (C〇-PEN)、聚對苯二甲酸乙二酯(PET)、聚碳酸酯(PC)、聚 奴酸酯(PC)合金、聚苯乙烯(Ps)、耐熱聚苯乙烯(ps)、聚曱 基丙烯酸甲酯(PMMA)、聚對苯二甲酸丁二酯(PBT)、聚丙 烯(PP)、聚乙烯(PE)、丙烯腈丁二烯苯乙烯(ABS)、聚胺酯 (PU)、聚醯亞胺(pi)、聚氣乙烯(pvc)、苯乙烯丙烯腈混合 物(SAN)、乙烯醋酸乙烯酯(EVA)、聚醯胺(pa)、聚縮醛 (POM)、酚、環氧樹脂(EP)、尿素(UF)、黑色素(MF)、不飽 和聚酯(UP)、矽(SI)、彈性體、環烯烴聚合物。 23. 如申請專利範圍第1項之增大明視度的薄膜,其中 35 200949300 ΟThe difference in refractive index between the substrate and the sea island yarn relative to the remaining-axis direction is 0.05 or more. 11 · As for the film of increased visibility of the first paragraph of the patent application, the remaining axis direction is the length direction of the sea island yarn. 12. For example, the film of the invention of claim 1 increases the brightness of the film, wherein the number of sea-island yarns in the high-definition film is 500 to 4,000,000 per cubic meter, of which 13·such as the patent application The film of the i-thin which increases the visibility, the sea-island yarn has a circular or printed cross section in the longitudinal direction. 14. The sea-island yarn has a non-circular cross section in the longitudinal direction as in the invention of the invention for increasing the brightness of the film of item i. The film of the item of increased visibility, 1 5. If the sea part of the first sea of the island yarn is the uniformity, such as the first part of the patent range, the island part of the sea island yarn is anisotropic. · For example, in the film of the scope of the patent of the invention, the difference between the sea portion and the island portion of the sea-island yarn with respect to the biaxial direction of the refractive index 34 200949300 is 0.03 or less, and = island yarn The difference between the sea portion and the island portion with respect to the remaining one axis is 0.05 or more. I8· For example, in the patent application, item 17 of the large-definition film, the remaining-axis direction is the length direction of the sea-island yarn. 19. A film of large apparentness as in claim 17 of the patent application, wherein the sea portion has a refractive index of 1.4 to 2.0. Ο 〇’ such as the patent scope of China! A film of increased visibility, wherein the island portion of the island yarn is arranged in plural. 21. For example, the application of the patent ϋ 帛 ; ; ; ; ; ; ; 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大22. The method of claim 3, wherein the sea portion of the sea bream comprises one or more selected from the group consisting of: polyethylene naphthalate (PEN) ), copolymerized naphthalene dicarboxylate _ (C〇-PEN), polyethylene terephthalate (PET), polycarbonate (PC), polyurethane (PC) alloy, polystyrene (Ps) ), heat-resistant polystyrene (ps), polymethyl methacrylate (PMMA), polybutylene terephthalate (PBT), polypropylene (PP), polyethylene (PE), acrylonitrile butadiene benzene Ethylene (ABS), polyurethane (PU), polyimide (pi), polyethylene (pvc), styrene acrylonitrile (SAN), ethylene vinyl acetate (EVA), polyamine (pa), poly Acetal (POM), phenol, epoxy (EP), urea (UF), melanin (MF), unsaturated polyester (UP), hydrazine (SI), elastomer, cyclic olefin polymer. 23. For example, increase the brightness of the film according to item 1 of the patent scope, 35 200949300 Ο 海中島紗的島部分為異向性,並且包括選自組成以下群組 中的任一或多者:聚萘二甲酸二乙酯(ΡΕΝ)、共聚萘二甲酸 二乙酯(co-PEN)、聚對苯二甲酸乙二酯(pet)、聚碳酸 (PC)、聚碳酸酯(PC)合金、聚苯乙烯(PS)、耐熱聚笨乙^ (PS)、聚甲基丙烯酸甲酯(PMma)、聚對苯二甲酸丁二醋 (PBT)、聚丙烯(PP)、聚乙烯(PE)、丙烯腈丁二烯苯 (ABS)、聚胺酯(PU)、聚醯亞胺(PI)、聚氯乙烯(pvc)、苯乙 烯丙烯腈混合物(SAN)、乙烯醋酸乙烯酯(EVA)、聚醯胺 (P A)、聚縮醛(POM)、酚、環氧樹脂(Ep)、尿素(uf)、黑色 素(MF)、不飽和聚醋(UP)、矽(SI)、彈性體、環烯烴聚合'物。 24,如申請專利範圍第2〇項之增大明視度的薄膜,其中 數個島部分具有相同的橫截面。 25·如申請專利範圍第2〇項之增大明視度的薄媒,其中 數個島部分具有不同的橫截面。 26. 如申請專利範圍第1項之增大明視度的薄膜,其中 基材包括具有不同橫截面形狀的數個海中島紗。 27. 如申β月專利範圍第!項之增大明視度的薄膜,其中 海中島紗延伸於長度方向。 1項之增大明視度的薄膜,進一 28.如申請專利範圍第 步包括結構化表面層。 29.如申請專利範圍第28 結構化表面層形成在輸出光的 3〇·如申請專利範圍第28項 結構化表面層具有棱鏡形狀。 項之增大明視度的薄膜, 表面上。 其中 之增大明視度的薄膜,其中 36 200949300 ❹ 1.如申請專利範圍第30項之增大明視度的薄膜,其中 結構化表面層具有不規則的稜鏡形狀。 3 2.如申請專利範圍第28項之增大明視度的薄膜,其中 結構化表面層具有透鏡形狀。 33·如申請專利範圍第32項之增大明視度的薄臈,其中 、结構化表面層具有不規則的透鏡形狀。 34.如申請專利範圍第33項之增大明視度的薄膜,其中 結構化表面層具有凸透鏡形狀。 士 3 5 .如申請專利範圍第34項之增大明視度的薄膜,其中 結構化表面層具有不規則的凸透鏡形狀。 雒36’如申請專利範圍第28項之增大明視度的薄骐,其中 又折射海中島紗乃配置或未配置於結構化表面層中。 7’如_ 5青專利範圍第28項之增大明視度的薄臈,其中 a明視度薄膜的後表面經過消光處理。 、、每中I .如申β月專利範圍第1項之增大明視度的薄膜,其中 海中島紗的厚度為0.3到20丹尼。 其中 海ίΛΉ請專利範圍第1項之增大明視度的薄膜 海中島紗的島部分具有非圓形戴面。 40.如申請專利 海部分的折射率乃相等於\:之增大明視度的薄膜 5相4於基材的折射率。 4如申請專利銘圖哲 海中島紗編織成緯紗和經紗。之增大明視度的薄臈 42.如申請專 中: 1圍第41項之增大明視度的薄臈,其 3 其中 其中 其中 37 200949300 緯紗和末端中的任一者海中島紗,以及 緯紗和經紗中的另一者是均向性纖維。 43. 如申請專利範圍第41項之增大明視度的薄膜,其中 緯紗和末端是由1到200股的海中島紗所形成。 44. 一種背光單元,其包括根據申請專利範圍第【至杓 項中任一項之增大明視度的薄膜。 45. —種液晶顯示裝置,其包括根據申請專利範圍第 項的背光單元。 0 46. 如申蜻專利範圍第45項的液晶顯示裝置,其中液晶 顯示裝置包括相差薄膜。 47·如申請專利範圍第45項的液晶顯示裝置,其中液晶 顯示裝置包括吸收型偏振薄膜。 48·種增大明視度的薄膜,其包括: 基材其X軸方向折射率是nXl,y轴方向折射率是 nYl ’ z轴方向折射率是nZ1 ; ❹ 雙折射海中島紗,其配置在基材裡, 八中’雙折射海中島紗之x、y、z軸的折射率是ηχ2、 πΥ2 ' πΖ2 9 fin «Μ, 丄 叫暴材的X、y、z軸折射率當中至少一者乃相 等於雙折射海中島炒的折射率。 49·如申請專利範圍第48項之增大明視度的薄膜其中 nX2 &gt; nY2 = nZ2。 5〇.如申請專利範圍第48項之增大明視度的薄膜,其中 基材是均向性。 51_如申請專利範圍第48項之增大明視度的薄膜,其中 38 200949300 田海中島紗之島部分的χ軸方向折射率(其為海中島乡丨、 部分的長度方向)是ηΧ3、海中島紗之島部分的y轴^之島 射率是ηΥ3、海中島紗之島部分的z軸方向折射率是二折 亚且海中島紗之海部分的X軸方向折射率是11X4、海中島紗 海Ρ刀的y軸方向折射率是ηΥ4、海中島紗之海部分的ζ 幸由方向折射率是ηΖ4,目I丨4ιί· 6J· :*· 疋4則折射率ηΧ3和ηΧ4之間或ηΥ3和 ηΥ4之間差異的絕對值是〇 15或更大。 Ο 拚如52如申明專利範圍第51項之增大明視度的薄膜,其中 折射率ΠΖ3和ηΖ4之間差異的絕對值小於〇 〇3。 十一、圈式 如次頁 39The island portion of the island yarn is anisotropic and includes any one or more selected from the group consisting of polyethylene naphthalate (ΡΕΝ), copolymerized naphthalene dicarboxylate (co-PEN). , polyethylene terephthalate (PET), polycarbonate (PC), polycarbonate (PC) alloy, polystyrene (PS), heat-resistant polystyrene (PS), polymethyl methacrylate ( PMma), polybutylene terephthalate (PBT), polypropylene (PP), polyethylene (PE), acrylonitrile butadiene benzene (ABS), polyurethane (PU), polyimine (PI), Polyvinyl chloride (PVC), styrene acrylonitrile mixture (SAN), ethylene vinyl acetate (EVA), polydecylamine (PA), polyacetal (POM), phenol, epoxy resin (Ep), urea (uf ), melanin (MF), unsaturated polyacetate (UP), hydrazine (SI), elastomer, cyclic olefin polymerization. 24. A film of increased clarity as disclosed in claim 2, wherein the plurality of island portions have the same cross section. 25. A thin medium with increased visibility as disclosed in Section 2 of the patent application, wherein several island portions have different cross sections. 26. A film of increased clarity as claimed in claim 1 wherein the substrate comprises a plurality of sea island yarns having different cross-sectional shapes. 27. If you apply for the beta patent range! A film of increased visibility, wherein the island yarn extends in the length direction. A film of increased brightness in the first item. Further, the first step of the patent application includes a structured surface layer. 29. The structuring surface layer of the 228th aspect of the application is formed in the output light. The structural surface layer has a prism shape. The item increases the apparent brightness of the film, on the surface. Among them, a film having an increased visibility, wherein 36 200949300 ❹ 1. A film of increased visibility as disclosed in claim 30, wherein the structured surface layer has an irregular 稜鏡 shape. 3 2. A film of increased clarity as disclosed in claim 28, wherein the structured surface layer has a lens shape. 33. A thin enamel for increasing visibility as disclosed in claim 32, wherein the structured surface layer has an irregular lens shape. 34. A film of increased clarity as in claim 33, wherein the structured surface layer has a convex lens shape. The film of the invention of claim 34, wherein the structured surface layer has an irregular convex lens shape.雒36', as in the application of claim 28, increases the brightness of the thin enamel, wherein the refracted sea island yarn is or is not disposed in the structured surface layer. 7' The thinning of the apparent brightness of item 28 of the _ 5 green patent range, wherein the rear surface of the a bright-vision film is subjected to matting treatment. , each of the I. Such as the increase in the brightness of the film of the first paragraph of the beta patent range, wherein the thickness of the sea island yarn is 0.3 to 20 denier. Among them, Hai ΛΉ ΛΉ ΛΉ 专利 专利 专利 专利 专利 专利 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大 增大40. If the patent application is patented, the refractive index of the sea portion is equal to the refractive index of the film 5 phase 4 of the substrate. 4 If applying for patent Mingtuzhe, Haizhong Island yarn is woven into weft and warp. Increase the brightness of the thin 臈 42. If you apply for the special: 1 around the 41st increase the brightness of the thin 臈, 3 of which 37 of which are 2009 2009300 weft yarn and the end of any of the sea island yarn, and weft The other of the warp yarns is an isotropic fiber. 43. A film of increased clarity as in claim 41 of the patent application, wherein the weft yarn and the end are formed by 1 to 200 strands of sea-island yarn. A backlight unit comprising a film for increasing the visibility according to any one of the above claims. A liquid crystal display device comprising the backlight unit according to the scope of the patent application. The liquid crystal display device of claim 45, wherein the liquid crystal display device comprises a phase difference film. 47. The liquid crystal display device of claim 45, wherein the liquid crystal display device comprises an absorbing polarizing film. 48. A film for increasing visibility, comprising: a substrate having a refractive index in the X-axis direction of nX1, a refractive index in the y-axis direction being nYl 'the refractive index in the z-axis direction is nZ1; ❹ a birefringent sea-island yarn, which is disposed in In the substrate, the refractive index of the x, y, and z axes of the 'birefringent sea-island yarn' is ηχ2, πΥ2' πΖ2 9 fin «Μ, at least one of the X, y, and z-axis refractive indices of the squeaky material. It is equivalent to the refractive index of the birefringent sea-island. 49. A film of increased clarity as in claim 48 of the patent application wherein nX2 &gt; nY2 = nZ2. 5. A film of increased clarity as disclosed in claim 48, wherein the substrate is uniform. 51_The film of the increased brightness of the 48th item of the patent application scope, wherein 38 200949300 Tianhai Zhongdao Yarn Island part of the refractive index of the z-axis direction (which is the length of the sea in the island, part of the length direction) is ηΧ3, Haizhong Island The island ratio of the y-axis of the island of the yarn is ηΥ3, the refractive index of the z-axis direction of the island part of the island of the sea is two folds, and the refractive index of the sea portion of the island yarn is 11X4, and the island yarn is The refractive index of the sea knives in the y-axis direction is ηΥ4, and the sea portion of the sea island yarn is fortunately. The refractive index of the direction is ηΖ4, and the target refractive index is between ηΧ3 and ηΧ4 or ηΥ3. The absolute value of the difference between η and Υ4 is 〇15 or more.拼 拼 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如XI, circle type, such as the next page 39
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