[go: up one dir, main page]

TW200944596A - Methods of thermo-mechanically processing tool steel and tools made from thermo-mechanically processed tool steels - Google Patents

Methods of thermo-mechanically processing tool steel and tools made from thermo-mechanically processed tool steels Download PDF

Info

Publication number
TW200944596A
TW200944596A TW098104717A TW98104717A TW200944596A TW 200944596 A TW200944596 A TW 200944596A TW 098104717 A TW098104717 A TW 098104717A TW 98104717 A TW98104717 A TW 98104717A TW 200944596 A TW200944596 A TW 200944596A
Authority
TW
Taiwan
Prior art keywords
region
temperature
tool
preform
steel
Prior art date
Application number
TW098104717A
Other languages
Chinese (zh)
Other versions
TWI479025B (en
Inventor
Christon L Shepard
David L Turpin
Ronald R Laparre
Alan L Shaffer
Shrinidhi Chandrasekharan
Original Assignee
Dayton Progress Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dayton Progress Corp filed Critical Dayton Progress Corp
Publication of TW200944596A publication Critical patent/TW200944596A/en
Application granted granted Critical
Publication of TWI479025B publication Critical patent/TWI479025B/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D7/00Modifying the physical properties of iron or steel by deformation
    • C21D7/13Modifying the physical properties of iron or steel by deformation by hot working
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/02Hardening articles or materials formed by forging or rolling, with no further heating beyond that required for the formation
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/22Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for drills; for milling cutters; for machine cutting tools
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/008Martensite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2221/00Treating localised areas of an article
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2221/00Treating localised areas of an article
    • C21D2221/01End parts (e.g. leading, trailing end)
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2221/00Treating localised areas of an article
    • C21D2221/02Edge parts
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2221/00Treating localised areas of an article
    • C21D2221/10Differential treatment of inner with respect to outer regions, e.g. core and periphery, respectively

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Articles (AREA)
  • Forging (AREA)
  • Mounting, Exchange, And Manufacturing Of Dies (AREA)
  • Powder Metallurgy (AREA)

Abstract

A method of thermo-mechanically processing a preform (65) composed of tool steel and a tool (18) to modify a workpiece (28). The preform (65) has a region (70) containing austenite. The method comprises establishing the region (70) at a process temperature between a martensitic start temperature and a stable austenitic temperature. While at the process temperature, the region (70) is deformed to change an outer dimension and to modify the microstructure to a depth of 1 millimeter or more. The tool (18) comprises a member (20) composed of tool steel. The member (20) includes a first region (30) that extends from the outer surface (22) to a depth of greater than 1 millimeter and a second region (32). The first region (30) includes a plurality of grains having an average misorientation angle greater than about 34 DEG, an average grain size that is at least 10% smaller than the second region (30), and has a different grain orientation than the second region (30).

Description

200944596 六、發明說明: 【發明所屬之技術領域】 本發明係關於工具鋼之熱機械加工,使用經熱機械加工 之工具鋼形成工具之方法及用於金屬成形及金屬切割應用 之工具。 本申請案為繼年3月13日中請之同在中請中之申請案 第以觸如號之部分連續案,該案主張美國臨時申㈣ 第60/896,729號之權利,該等申請案中之每-者之揭示内 容在此以引用的方式全面地併入本文中。本申請案亦主張 2008年2月15日中請之美國臨時中請案第6i/Q29,236號之權 利,該案在此以引用之方式全面地併入本文中。 【先前技術】 在各種等級之市售碳及合金鋼中,工具鋼等級通常用於 工具經受危險應力、衝擊及/或磨損之應用中。工具鋼通 常以出眾之硬度、耐磨性、保持切割邊緣之能力及高溫下 抗變形性為特徵。因此,工具鋼廣泛應用於金屬成形及金 屬切割應用、檢驗設備及量規以及機械工具中之磨損/衝 擊組件。 各種類型之工具用於諸如機械加工、穿孔、模印加工、 抽拉、粉末壓製、金屬雕刻、銷衝麼及其類似者之金屬成 形及金屬切割應用中。詳言之,衝頭及衝模表示用以穿 孔、打孔及使金屬及非金屬工件成形之類型之金屬成形工 具。切害4工具及插件表示用於機械加工應用以使金屬及非 金屬工件成形之類型之金屬切割工具。塞規、螺紋規、管 138621.doc 200944596 規、環規及校裝盤表示用於檢驗應用之類型之工具。機找 滑件及嵌條表示用於機械工具中之類型之磨損及衝擊組 件。 衝頭及衝模在其使用期限期間經受嚴重及重複負載。詳 . 言之,衝頭易於在使用期間由於其使用期間所經歷之顯著 應力而引發之嚴重斷裂而可能損壞。隨著由具有較高強度 重量比之鋼(諸如超高強度鋼(UHSS)、高級高強度鋼 (AHSS)、相變誘發塑性(丁Rip)鋼、孿晶誘發塑性(TWIP) 鋼、奈米鋼及馬氏體(MART)鋼)所建構之工件之引入,對 金屬成形工具之要求變得更加苛刻。舉例而言,汽車工業 正向更頻繁地將此等類型之高強度、低重量鋼用於車身結 構轉變。 因此’需要·熱機械加工工具鋼文良其機械性質之方法 及具有改良之機械性質的由熱機械加工所形成之工具。 【發明内容】 μ φ 在項實施例中,提供熱機械加工包含工具鋼之預成形 之方法該工具鋼具有馬氏體開始溫度及穩定沃斯田體 μ度。該預成形坯具有一含有沃斯田體之區域,該區域包 •括夕卜表面及用於該外表面之複數個外部尺寸。㈣法包含 .在該馬氏體開始溫度與該穩定沃斯田體溫度之間的一加工 溫度下建立至少該預成形述之該區域。當該預成形场之該 區域處於該加工溫度下時’該區域經變形以改變該區域之 該等外部尺寸中之至少一者及將該區域之微結構由自外表 面延伸之一深度改質為該外表面之下的1毫米或超過1毫米 13862I.doc 200944596 之一深度。在區域變形後,將該區域冷卻至室溫。 在另一實施例中,提供用於機器中以改質工件之工具。 »衾工具包含一包含工具鋼之構件。該構件具有一外表面, 該外表面界定經組態以與機器耦接之第一部分及適用於接 觸工件之第二部分。該構件包括自外表面延伸至大於丨毫 米之深度的第一區域及藉由該第一區域而與外表面分離的 第二區域。第一區域包括具有錯誤定向角分佈的複數個晶 粒,該錯誤定向角分佈具有大於約34。之平均錯誤定向 角;比第二區域小至少10%的平均晶粒大小;且具有與第 一區域中之複數個晶粒之晶粒定向不相同的晶粒定向。 【實施方式】 併入本說明書中且組成本說明書之一部分的隨附圖式說 明本發明之實施例,且與上文之簡要描述及下文之實施例 之詳細描述一起用於解釋本發明之實施例之原理。 根據本發明之一項實施例,一種製造工具之方法包括自 工具鋼製造預成形坯,其中預成形坯之至少一區域為經熱 機械加工的。該預成形坯之區域通常包括工具鋼之大部分 體積或預成形坯之主體部分。舉例而言,對於圓柱形預成 形场幾何形狀’藉由徑向鍛造或平面應變鍛造過程而加工 之熱機械加工區域可將外體積之60%與工具鋼之相對未典 加工影響之剩餘部分之内體積合併。因此,對於簡單預成 形述幾何形狀’區域之體積可至少包括預成形坯之—個橫 剖面之外體積。區域可至少部分地跨越或完全跨越橫剖面 區延伸。因此’在此實施例中,外部體積或改質區域自區 138621.doc -6 - 200944596 域之外表面延伸至大於至少0 039吋(1 mm)之深度,儘管 體積之尺寸可使得深度可更深地延伸入預成形坯_。然 而,區域之深度不必為統一的,實情為區域之一部分中之 深度可小於0.039吋(1 mm)但另一部分中之深度延伸至大 於 0.039忖(1 nim)。 儘管上文將改質區域描述為圍繞内體積之層之形式的外 體積,但改質區域可為不規則形狀區域。舉例而言,此可 為預成形坯之外表面在變形之前具有一個幾何形狀,但接 9 ¥藉由改變區域之外部尺寸中之至少-者來變形以形成具 有不同形狀之物件的狀況。舉例而言,變形可包括橫剖面 區域或另-外部尺寸中之一或多者之改變,該另一外部尺 寸可增加或減少區域之長度。熟習此項技術者將注意到所 加工材料之體積可視許多其他因素而定,包括(但不限於) 預成形坯之大小及形狀以及變形設備之能力及類型。通 常,隨著鍛造設備之負載能力增加及預成形链之大小減 藝小,變形區域可併有預成形坯之較大(若不為全部)部分。 因此,與表面處理操作(諸如珠擊處理及其類似者)不同, 本發明之實施例不限於形成被迫符合部分之先前所建立之 輪廓的薄表面層。此外,本發明之實施例變形工具鋼之較 大部分’且在一些實施例中’判定預成形述之輪麻或外表 面尺寸。在此方面,可跨越預成形坯或工具之主體之厚度 量測預成形坯之區域,且預成形坯之形狀可與工具之最終 形狀不相關》 ' 除影響經加工之工具鋼之體積外,熱機械加工之前的預 138621.doc 200944596 成形柱之幾何形狀或形狀可影響最終微結構。舉例而兮, :堪之形狀可影響或判定晶粒之定向以及熱機械二工 微結構之特性°熟習此項技術者將瞭解,工具鋼預 成形堪可為具有許多橫剖面形狀之複數個組態中之—者, 諸如具有圓形、矩形或多邊形橫剖面之棒料,或具有更複 雜形狀及橫截面之原材料。可基於歷史經驗、工具要求及/ 或加工限制來開發預成形㈣何形狀之判定。舉例而言, 可基於所使用之加工類刑β Τ θ Λ· α 類i及工具之目標、最終幾何形狀來 選擇預成形坯之幾何形狀。 虽區域之溫度保持在根據本發明之不同實施例之如下文 所描述之溫度範圍中時,區域經受變形。在本發明之實施 例中’變形量足以改良變形區域之機械性質。可藉由縮減 比之計算來量化變形量,縮減比經定義為橫剖面區域之歸 ㈣熱機械加工之相對減少。認為區域之性質之改良與變 形量成比例。藉由實例且非限制的’僅僅2〇%之縮減比即 可導致區域之機械性質中之可量測之改良。咸信產生機械 性質中可量測之改良之變形量僅由工具鋼之動態再結晶限 制。換言之’可將變形量保持在有效引起微結構動態地再 結晶之臨限值以下。若變形之微結構再結晶,則可觀測與 未經再結晶之微結構相比之機械性質之可量測之降低。特 定機械性質之降低可為至少約2〇%。然而,即使可觀測到 降低’但與藉由在所指定之溫度範圍以上之溫度下熱處理 工具鋼而製備之工具相比,機械性質仍然可改良,如以下 將更詳細地描述。熟習此項技術者將瞭解,除變形量外, 138621.doc 200944596 動態再結晶視工具鋼之組份及變形發生時之溫度而定。 如以上所闡述,熱機械加工包括在工具鋼預成形坯保持 在高溫下時塑性變形工具鋼預成形坯。儘管可使用其他合 適變形加工,能夠塑性變形預成形坯之合適加工包括(但 不限於)鍛造加工,諸如徑向鍛造、環軋、迴轉鍛造、型 鍛、觸變成形(thixoforming)、沃斯成形(ausforming)及溫/ 熱鍛粗。舉例而言’技術亦可包括主要變形方向不為大體 上垂直於預成形坯之縱轴之技術。如上所論及,其他技術 (諸如高溫下之珠擊處理)產生極微弱變形且因此被排除, 因為需要程度較深之塑性變形以提供機械性質之必要改 良。 一種此加工為平面應變鍛造,其主要產生工具鋼預成形 坯之徑向及圓周塑性變形。因此,平面應變鍛造可限制垂 直於所施加之負載之方向上的晶粒伸長。結果,預成形堪 可沿其長度及圍繞其周邊呈現機械性質之大體上均一分 佈。因此,在一項實施例中,平面應變鍛造包括在特定方 向上產生極少(若存在)之晶粒伸長的塑性變形加工。然 而’當熱機械加工工具鋼預成形坯時,可使用能夠塑性變 形預成形坯之以上論及之加工之任何組合。 在另一實施例中,現有工具可充當預成形坯。舉例而 言,除未使用之工具外,現有工具可包括使用之工具、受 損之工具或損壞之工具。現有工具經熱機械加工,如本文 中所描述’以便再製造或再加工該工具以恢復其效用。 如以上所提供,熱機械加工包括在預成形坯之區域保持 138621.doc 200944596 在尚加工溫度下時塑性變形該區域。可藉由將預成形坯自 較高溫度冷卻纟建立變形㈣預成形链之溫度。此過程可 包括(僅藉由實例)自熔化之原材料鑄造工具鋼之小坯或預 成形坯,將所鑄造之預成形坯冷卻至較低加工溫度且在加 工溫度下將其變形。或者,可藉由自室溫或接近室溫之溫 度加熱預成形坯來使得該預成形坯達到加工溫度(變形於 該加工溫度下發生),如下文較詳細描述。 詳口之’且參看圖1,預成形链於高於工具鋼之馬氏體 轉變(Ms)之開始溫度(馬氏體開始溫度)但低於工具鋼之穩 定沃斯田體溫度(AG)(當預成形坯含有沃斯田體時)的加: 溫度下變形。MS為在冷卻期間沃斯田體至馬氏體之轉變起 之脈度且AC3為在加熱期間肥粒鐵至沃斯田體之轉變 完成之溫度》 此外,如圖1中表明,沃斯田體開始溫度(ACi)表示在加 熱期間沃斯田體開始形成之溫度。熟習此項技術者將瞭 解’ Ms、AC丨及AC3係各自視工具鋼之特定組份而定。因 此,本文十所冑述之Ms、AC丨或AC3與特定溫度共同被提 及之任何例項並非意欲將Ms、ACi或AC3之定義限制為彼 特定溫度。 繁於以上所定義之溫度且根[項實施例,當工具鋼預 成形述處於MAAC3之間的溫度下且當區域含有沃斯田體 (例如’亞穩沃斯田體)時’工具鋼預成形述之全部或一部 分被加工’亦即’工具鋼預成形迷經塑性變形或锻造。因 此’工具鋼預成形链之變形區域具有如下文所描述之某些 13862J.doc •10· 200944596 改良之機械性質。舉例而言,當微結構主要為穩定沃斯田 體時’與在高於ac3之溫度下變形預成形坯相比,變形區 域之衝擊強度或韌性之改良可大至少約,且在另一實 例中,可大至少50%。 如以上所介紹’在—項實施例t,該方法包括將工昇鋼 預成形坯加熱至一溫度範圍使得預成形坯之至少一部分含 冑沃斯田體。熟習此項技術者將注意到,可利用許多不同 度曲線圖以在變形之前使得工具鋼預成形坯處於以上所 罾 肢之溫度範圍内。僅藉由實例,且參看圖!,可將工具 鋼預成形述自低於Ms之溫度加熱至高於ACi之加工溫度(標 記10)。此實例中,溫度為約1530Τ(約832它),且AC3為 約2250 F (約1232 c)。工具鋼預成形坯可接著經變形,同 時將其保持在AC丨與AC3之間的加工溫度。 另-溫度曲線圖可包括將卫具鋼預成形链自低於&之溫 度加熱至八(^與八(:3之間的溫度,且接著在將其變形之前 ❹ 將該工具鋼預成形坯冷卻至高於MS之加工溫度(標記u)。 在圖1A所展示之另一實施例中,溫度曲線圖可包括將工具 鋼預成形述加熱至高於AC3,且接著在將其變形之前將工 • 具鋼預成形坯冷卻至八^與八。之間的加工溫度(標記12)或 • 冷卻至Ms與八(^之間的加工溫度(標記13)。 在變形期間’加工溫度可增加、減少或保持大體上相 同,儘管區域之溫度保持在AC3與Ms之間。如圖1及1八所 不’變形發生處之溫度(例如,1〇、u、丨2及丨3處)描繪為 水平線。儘管水平線可表示等溫條件,熟習此項技術者將 138621.doc • 11 - 200944596 瞭解實際加工溫度中之—些 期間,工具鋼預成形:之實m,在變形 ±5昨(±28。〇。控制溫度 ^加工-度可變化 可需要經由閉路溫度反饋持在大體上等溫條件 秋而w 饋_系統來有意地加熱或散熱。 降:二:,或降低可在變形期間發生。溫度升高或 2!可為有意的或為在變形期間未控制溫度之結果。舉例 而^在-些實施例中’歸因於藉由變形將能量添加至預 ^之料,預成料之溫度可增加至mF(8rc)。 二:量:變為熱量,且若未藉由排熱或散熱來補償,則 ^升局區域之溫度。因此,加工溫度可升高或降低使 ^域之溫度在高於ACi之溫度處開始但在低於Μ之溫 度處結束,或在低於ACl之溫度處開始且在高於Μ之溫 度處結束。在其他實施例中,可在變形發生時有意地冷卻 區域以降低區域之溫度。然而’應注意,若預成形链溫度 在變形過程期間顯著變化,則晶粒之動態再結晶可降低區 域之衝擊強度及勒性。因此,等溫過程(亦即,在變形期 間保持工具鋼預成形坯之實際加工溫度大體上為常數)可 最大化區域之強度、韌性及其他機械性質,如下文所描 述。 田 繼續參看圖1及1A,儘管可利用各種加熱及冷卻過程, .但控制加工溫度及加工時間以避免碳化物鼻端14或貝氏體 鼻端16。熟習此項技術者將瞭解,在低於ACi之溫度下, 若區域在此萼範圍中之溫度下保持過長,則工具鋼可沈殿 碳化物或貝氏體。藉由實例,M2 AISI工具鋼預成形远可 138621 .doc -12· 200944596 在無顯著碳化物《貝氏體相形成<情況下於至少2分鐘之 時&内變形U ’預成形&可保持於此範圍中之溫度下 的時間量至少取決於工具鋼之組份及溫度,以及其他因 素。 在熱機械加工後,預成形坯經冷卻至較低溫度。可藉由 強制空氣對流或在冷卻預成料至室溫之前將區域保持在 中等溫度來達成冷卻或淬火。熟習此項技術者將瞭解,淬 Ο200944596 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to thermomechanical processing of tool steel, a method of forming a tool using thermo-machined tool steel, and a tool for metal forming and metal cutting applications. This application is a part of the serial case of the application in the middle of the same year on March 13th. The case claims the rights of the US Provisional Application (4) No. 60/896,729. The disclosure of each of the disclosures is hereby incorporated by reference in its entirety. This application also claims the benefit of U.S. Provisional Application No. 6i/Q29,236, filed on Feb. 15, 2008, which is hereby incorporated by reference in its entirety. [Prior Art] Among various grades of commercially available carbon and alloy steels, tool steel grades are commonly used in applications where the tool is subjected to hazardous stress, shock and/or wear. Tool steels are often characterized by superior hardness, wear resistance, ability to maintain cutting edges, and resistance to deformation at elevated temperatures. As a result, tool steels are widely used in metal forming and metal cutting applications, inspection equipment and gauges, and wear/impact components in machine tools. Various types of tools are used in metal forming and metal cutting applications such as machining, perforation, die-cutting, drawing, powder pressing, metal engraving, pinning, and the like. In particular, the punches and dies represent metal forming tools of the type used to pierce, punch, and shape metal and non-metal workpieces. Shear 4 tools and inserts represent metal cutting tools of the type used for machining applications to shape metal and non-metal workpieces. Plug gauges, thread gauges, tubes 138621.doc 200944596 gauges, ring gauges and school plates represent tools used to verify the type of application. Machine Finding Slides and Inserts represent wear and impact components of the type used in machine tools. Punches and dies are subjected to severe and repeated loads during their lifetime. In particular, the punch is susceptible to damage during use due to severe breakage caused by significant stress experienced during its use. With steels with higher strength to weight ratio (such as ultra high strength steel (UHSS), advanced high strength steel (AHSS), phase change induced plastic (Dip Rip) steel, twin induced plasticity (TWIP) steel, nano The introduction of workpieces constructed of steel and martensite (MART) steel has become more demanding on metal forming tools. For example, the automotive industry is increasingly using these types of high-strength, low-weight steels for body structure transformations. Therefore, there is a need for a method for thermomechanical processing of steel and its mechanical properties, and a tool formed by thermomechanical processing having improved mechanical properties. SUMMARY OF THE INVENTION μ φ In an embodiment, a method of thermomechanically processing a preform comprising tool steel is provided. The tool steel has a martensite start temperature and a stable Worth field μ degree. The preform has a region containing a Worth field that includes a surface and a plurality of outer dimensions for the outer surface. (d) The method comprises establishing at least the pre-formed region at a processing temperature between the martensite start temperature and the stable Worth field temperature. When the region of the preformed field is at the processing temperature, the region is deformed to change at least one of the outer dimensions of the region and the microstructure of the region is modified from a depth extending from the outer surface One depth for the outer surface of 1 mm or more than 1 mm 13862I.doc 200944596. After the area was deformed, the area was cooled to room temperature. In another embodiment, a tool for use in a machine to modify a workpiece is provided. »The 衾 tool contains a component that contains tool steel. The member has an outer surface that defines a first portion that is configured to couple with the machine and a second portion that is adapted to contact the workpiece. The member includes a first region extending from the outer surface to a depth greater than 丨m and a second region separated from the outer surface by the first region. The first region includes a plurality of crystal grains having a misaligned angular distribution having a greater than about 34. The average misorientation angle; an average grain size that is at least 10% smaller than the second region; and has a grain orientation that is different from the grain orientation of the plurality of grains in the first region. The embodiments of the present invention are described in conjunction with the accompanying drawings, in which The principle of the example. In accordance with an embodiment of the present invention, a method of making a tool includes fabricating a preform from tool steel, wherein at least a region of the preform is thermo-machined. The area of the preform typically includes a majority of the volume of the tool steel or the body portion of the preform. For example, for a cylindrical preformed field geometry, a thermomechanically machined region machined by a radial forging or plane strain forging process can balance 60% of the outer volume with the remainder of the tool steel's relative atypical processing effect. The inner volume is merged. Thus, the volume of the region of the simple pre-formed geometry can include at least the volume outside the cross-section of the preform. The region may extend at least partially across or completely across the cross-sectional area. Thus, in this embodiment, the outer volume or modified region extends from the outer surface of the region 138621.doc -6 - 200944596 to a depth greater than at least 0 039 吋 (1 mm), although the size of the volume may allow the depth to be deeper Extending into the preform _. However, the depth of the area does not have to be uniform, and the depth in one part of the area may be less than 0.039 吋 (1 mm) but the depth in the other part may extend to more than 0.039 忖 (1 nim). Although the modified region is described above as an outer volume in the form of a layer surrounding the inner volume, the modified region may be an irregular shaped region. For example, this may be a condition in which the outer surface of the preform has a geometry prior to deformation, but is deformed by at least the outer dimensions of the region to form articles having different shapes. For example, the deformation can include a change in one or more of a cross-sectional area or another-outer dimension that can increase or decrease the length of the area. Those skilled in the art will appreciate that the volume of material being processed can be determined by a number of other factors including, but not limited to, the size and shape of the preform and the ability and type of the deforming device. Generally, as the load capacity of the forging equipment increases and the size of the preformed chain decreases, the deformed area may have a larger (if not all) portion of the preform. Thus, unlike surface treatment operations, such as bead blasting and the like, embodiments of the present invention are not limited to forming a thin surface layer that is forced to conform to previously established contours. Moreover, embodiments of the present invention deform a majority of the tool steel 'and in some embodiments' to determine the preformed outer or outer surface dimensions. In this aspect, the area of the preform can be measured across the thickness of the body of the preform or tool, and the shape of the preform can be independent of the final shape of the tool, 'except for the volume of the tool steel being machined. Pre-138621.doc 200944596 before thermomechanical processing The geometry or shape of the shaped column can affect the final microstructure. For example, the shape can influence or determine the orientation of the grains and the characteristics of the thermomechanical microstructure. Those skilled in the art will appreciate that tool steel preforming can be a plurality of groups having many cross-sectional shapes. In the state, such as a bar with a circular, rectangular or polygonal cross section, or a material with a more complex shape and cross section. The determination of the pre-formed (four) shape can be based on historical experience, tool requirements, and/or processing constraints. For example, the geometry of the preform can be selected based on the processing class β Τ θ Λ α α and the target of the tool, the final geometry. The region undergoes deformation although the temperature of the region remains in the temperature range as described below in accordance with various embodiments of the present invention. In the embodiment of the invention, the amount of deformation is sufficient to improve the mechanical properties of the deformed region. The amount of deformation can be quantified by the reduction ratio calculation, and the reduction ratio is defined as the relative reduction of the cross-sectional area (4) thermomechanical processing. It is considered that the improvement of the nature of the area is proportional to the amount of deformation. An example and non-limiting 'only 2% reduction ratio can result in a measurable improvement in the mechanical properties of the zone. The improved amount of deformation that can be measured in the mechanical properties of the salt is limited only by the dynamic recrystallization of the tool steel. In other words, the amount of deformation can be kept below the threshold that effectively causes the microstructure to recrystallize dynamically. If the deformed microstructure is recrystallized, a measurable decrease in mechanical properties compared to the unrecrystallized microstructure can be observed. The reduction in specific mechanical properties can be at least about 2%. However, mechanical properties can be improved as compared to tools prepared by heat treating tool steel at temperatures above the specified temperature range, even though a decrease can be observed, as will be described in more detail below. Those skilled in the art will appreciate that in addition to the amount of deformation, 138621.doc 200944596 dynamic recrystallization depends on the composition of the tool steel and the temperature at which the deformation occurs. As explained above, thermomechanical processing involves plastically deforming tool steel preforms while the tool steel preforms are maintained at elevated temperatures. Suitable processing for plastically deformable preforms may include, but is not limited to, forging processing, such as radial forging, ring rolling, rotary forging, swaging, thixoforming, Voss forming, although other suitable deformation processes may be used. (ausforming) and warm/hot forging. For example, the technique may also include techniques in which the primary direction of deformation is not substantially perpendicular to the longitudinal axis of the preform. As discussed above, other techniques, such as bead blasting at high temperatures, produce very weak deformation and are therefore eliminated because of the need for deeper plastic deformation to provide the necessary improvements in mechanical properties. One such process is planar strain forging, which primarily produces radial and circumferential plastic deformation of the tool steel preform. Therefore, planar strain forging can limit the elongation of the grains perpendicular to the direction of the applied load. As a result, preforming can exhibit a substantially uniform distribution of mechanical properties along its length and around its perimeter. Thus, in one embodiment, planar strain forging includes plastic deformation processing that produces very little, if any, grain elongation in a particular direction. However, when thermoforming a tool steel preform, any combination of the above-described processes capable of plastically deforming the preform can be used. In another embodiment, an existing tool can act as a preform. For example, in addition to unused tools, existing tools may include tools used, damaged tools, or damaged tools. Existing tools are thermomechanically processed as described herein to remanufacture or rework the tool to restore its utility. As provided above, thermomechanical processing includes maintaining the zone 138621.doc 200944596 in the region of the preform to plastically deform the region at the processing temperature. The temperature of the preformed chain can be established by deforming the preform from a higher temperature. This process may include (by way of example only) casting a blank or preform of tool steel from the molten raw material, cooling the cast preform to a lower processing temperature and deforming it at the processing temperature. Alternatively, the preform can be brought to a processing temperature (deformed at the processing temperature) by heating the preform from room temperature or near room temperature, as described in more detail below. Detailed description 'and referring to Figure 1, the preformed chain is above the martensitic transformation (Ms) of the tool steel (the martensite start temperature) but lower than the stabilized Worth field temperature (AG) of the tool steel (When the preform contains a Worth field): Deformation at temperature. MS is the pulse of the transition from Worth to Martensite during cooling and AC3 is the temperature at which the transition from ferrite to Worth is completed during heating. In addition, as shown in Figure 1, Worthfield The body onset temperature (ACi) represents the temperature at which the Worth field begins to form during heating. Those skilled in the art will understand that the 'Ms, AC丨 and AC3 systems are each dependent on the specific component of the tool steel. Therefore, any of the examples in which Ms, AC丨 or AC3, as described in conjunction with the specific temperature, are not intended to limit the definition of Ms, ACi or AC3 to a specific temperature. Multiplying the temperature defined above and the root [item embodiment, when the tool steel preform is described at a temperature between MAAC3 and when the region contains a Worth field (eg 'Asian Worth Field') All or part of the forming process is processed 'i.e.' the tool steel preformed blister is plastically deformed or forged. Therefore, the deformed region of the tool steel preformed chain has some of the improved mechanical properties of 13862J.doc •10· 200944596 as described below. For example, when the microstructure is primarily a stable Worth field, the improvement in impact strength or toughness of the deformed region can be at least about as compared to deforming the preform at a temperature higher than ac3, and in another example Medium, can be at least 50% larger. As described above, in the embodiment, the method includes heating the worker steel preform to a temperature range such that at least a portion of the preform contains the 胄沃斯田体. Those skilled in the art will appreciate that many different degrees of profile can be utilized to bring the tool steel preform into the temperature range of the above-described limb prior to deformation. Just by example, and see the picture! The tool steel preform can be heated from a temperature below Ms to a processing temperature above ACi (mark 10). In this example, the temperature is about 1530 Torr (about 832 it) and AC3 is about 2250 F (about 1232 c). The tool steel preform can then be deformed while maintaining it at a processing temperature between AC丨 and AC3. The other-temperature profile may include heating the preform steel chain from a temperature below & to a temperature between eight and eight (: 3, and then deforming the tool steel before deforming it) The billet is cooled to a processing temperature above the MS (mark u). In another embodiment, shown in Figure 1A, the temperature profile can include heating the tool steel preform to a temperature above AC3 and then working before deforming it. • The steel preform is cooled to a processing temperature between 8 and 8. (marked 12) or • cooled to a processing temperature between Ms and 八 (^13). During the deformation, the processing temperature can be increased. Decrease or remain substantially the same, although the temperature of the zone remains between AC3 and Ms. The temperatures at which the deformation occurs (eg, 1〇, u, 丨2, and 丨3) are depicted as Horizontal line. Although the horizontal line can represent isothermal conditions, those skilled in the art will learn 138621.doc • 11 - 200944596 to understand the actual processing temperature during some of the period, tool steel preforming: the real m, in the deformation ± 5 yesterday (± 28 〇. Control temperature ^ processing - degree can be changed The closed-circuit temperature feedback is held in a substantially isothermal condition and the feed is intentionally heated or dissipated. Drop: two:, or the decrease can occur during deformation. The temperature rises or 2! can be intentional or deformed The result of the temperature is not controlled during the period. For example, in some embodiments, 'the temperature of the pre-form can be increased to mF (8rc) due to the addition of energy to the pre-form by deformation. It is heat, and if it is not compensated by heat removal or heat dissipation, the temperature of the area is raised. Therefore, the processing temperature can be raised or lowered so that the temperature of the domain starts at a temperature higher than ACi but lower than Μ. The temperature ends or ends at a temperature below the ACl and ends at a temperature above Μ. In other embodiments, the region may be intentionally cooled to reduce the temperature of the region when deformation occurs. However, it should be noted that If the pre-formed chain temperature changes significantly during the deformation process, dynamic recrystallization of the grains can reduce the impact strength and strength of the region. Therefore, the isothermal process (ie, maintaining the actual processing of the tool steel preform during deformation) The temperature is generally normal The number) can maximize the strength, toughness and other mechanical properties of the zone, as described below. The field continues with reference to Figures 1 and 1A, although various heating and cooling processes can be utilized, but the processing temperature and processing time are controlled to avoid carbide noses. End 14 or bainite nose 16. It will be understood by those skilled in the art that at temperatures below ACi, if the zone remains too long at temperatures in this range, the tool steel can be slab carbide or Bayesian. By way of example, M2 AISI tool steel preforming can be as long as 138621 .doc -12· 200944596 in the absence of significant carbide "bainite phase formation" in at least 2 minutes & internal deformation U 'preform The amount of time that & can remain at this temperature depends at least on the composition and temperature of the tool steel, as well as other factors. After thermomechanical processing, the preform is cooled to a lower temperature. Cooling or quenching can be achieved by forced air convection or by maintaining the zone at a moderate temperature before cooling the preform to room temperature. Those skilled in the art will understand that quenching

火可包括其他冷卻方法或介f,包括(例如)水或油泮火。 藉由額外實例,區域可經受低溫處理,其中區域在一或多 ㈣段中冷卻至約·15(TF(約-101〇c)與約-30昨(約_赋) 之間的溫度以將大百分比之殘留沃斯田體轉換至馬氏體。 可藉由(例如)液氮達成低溫處理,且該處理可主要與似 D2工具鋼結合使用,儘管含有顯著百分比之殘留沃斯田體 之其他工具鋼可自此類型之處理獲益。淬火速率大於工具 鋼之臨界冷卻速率’亦即,用於防止非理想轉變(諸如,、 碳化物鼻端!4及貝氏體鼻端16)之連續冷卻之最小速率。 因此’冷卻速率足㈣免亞敍斯吨至非理想分解產物 (諸如碳化物或貝氏體)之顯著轉變。亦可利用較快冷卻速 率,儘管較快冷卻速率限於彼等不會熱衝擊區域或以其他 方式扭變工具鋼預成形坯者。 、 此外,在-項實施例中,冷卻之後具有__或多個回火過 舉例而σ回火可包括將區域加熱至約85〇卞( 4541 )與約! 〇崎(約537。〇)之間的溫度歷時約μ鐘至約 6〇刀鐘之間。回火藉由將殘留沃斯田體轉換至馬氏體來改 I38621.doc J3- 200944596 質微結構。如此項技術尹已知,可使用多次回火循環以轉 換殘留沃斯田體。熟習此項技術者將理解,視工具鋼之組 伤預成形堪之幾何形狀及大小、容許之歹麦留沃斯田體量 及所使用之回火處理之數目而定,回火可包括加熱至較高 或較低溫度歷時較短或較長時段。根據一項實施例,淬火 後,在回火之前區域不在AG或高於A。之溫度下經熱處 理。此外,區域可不被加熱至高於該區域在變形期間所經 歷之任何溫度。換言之,預成形达可經再加熱,然而,任 何後繼再加熱期間之溫度不會顯著地降低或更改由於在穩 定沃斯田體溫度與馬氏體開始溫度之間的溫度下變形區^ 中之沃斯田體而建立之應變或差排。 在另-實施例中’該方法進一步包括在熱機械變形過程 後將工具鋼預成形述修整為工具。修整可包括材料移除過 ㈣產生最終狀之形狀及/或表面"面層。舉例而 S ’習知修整過程可包括機械加工、研磨、砂磨/抛光, 或其組合以製備用於使用之工具。然而,修整可需要僅移 除少量材料以將預成形述形成為工具。舉例而言,變形可 包括近淨形鍛造過程使得(在變形後)需要預成㈣之微小 後續加工(若存在)以產生工具。 -或多個次要過程可跟隨在卫具之冷卻或修整之後。次 要過程包括以某-方式在工具上形成塗層或進一步改質工 具之表面。例示性次要過程包括使用抗磨材料熱喷塗或覆 蓋工具之變形區域或整個工具。其他次要過程包括藉由塗 佈技術在工具之工作表面上塗覆塗層,該等塗佈技術包括 138621.doc •14· 200944596 (但不限於)物理氣相沈積(PVD)、化學氣相沈積(CVD)或鹽 浴塗佈。其他表面改質技術包括離子植入、雷射或電漿硬 化技術、氮化或碳化,其可用以改質工具之工作表面處之 表面層。應瞭解,可以任合組合來使用各種不同次要過程 以進一步改質工具。 如以上所闡述,預成形坯包含工具鋼。工具鋼表示一種 ' 類別之鋼,用於切割、成形或以其他方式成形另一材料之 工具由該工具鋼製得。工具鋼可藉由熱處理呈現硬化且可 〇 經回火以達成所要之機械性質。舉例而言,可自諸如冷加 工、熱加工、高速工具鋼等級材料或專屬工具鋼等級之各 種不同類別之工具鋼製造預成形坯。詳言之,工具鋼為 鐵-¼ (Fe-C)合金系統,其碳含量在約〇 35重量%至約1 重量%之範圍内,且在另一實例中,藉由視所要求之碳化 物相(若存在)而定的預期之其他碳含量而在約〇85重量% 至約1.30重量。/0之範圍内。 φ 工具鋼通常含有碳化物形成元素之添加物,諸如,釩 (V)、鎢(W)、鉻(Cr)、鉬(Mo)或其組合。視合金添加物而 定,一或多種碳化物相(例如M6c、m2c、m23c6、M7Cpt - M4C)可能沈澱,儘管如此項技術中已知可形成其他類型之 • 碳化物。極少例外,工具鋼不含有有意添加物鎳(Ni)0鎳 為已知之沃斯田體相穩定劑。然而,工具鋼可含有微量 (至多0.3重量〇/〇)此元素。 表1展示可用以製造根據本發明之實施例之工具的例示 陡工具鋼之重量百分比形式之標稱組份(工具鋼之其餘部 138621 .doe •15· 200944596 分為鐵(Fe))。藉由實例,表1 _工具鋼之ac3位於約 2100°F (約1149t)與約2400T (約1316。〇之間的範圍内, ACi溫度位於約1380T (約749°C )與約1680T (約915.6〇C )之 間的範圍内,且Ms位於約320T (約160。〇與約480T(約 249°C )之間的範圍内。 表1The fire may include other cooling methods or media, including, for example, water or oil bonfires. By way of an additional example, the zone can be subjected to a low temperature process in which the zone is cooled in one or more (four) segments to a temperature between about 15 (TF (about -101 〇 c) and about -30 yesterday (about _). A large percentage of the residual Worth field is converted to martensite. Low temperature treatment can be achieved by, for example, liquid nitrogen, and this treatment can be used primarily in combination with D2 tool steel, although it contains a significant percentage of residual Worth field Other tool steels can benefit from this type of treatment. The quenching rate is greater than the critical cooling rate of the tool steel', ie to prevent non-ideal transformations (such as, carbide nose! 4 and bainite nose 16) The minimum rate of continuous cooling. Therefore, the 'cooling rate is sufficient (4) to significantly convert from the Assyrian to non-ideal decomposition products (such as carbide or bainite). Faster cooling rates can also be utilized, although faster cooling rates are limited to Such as not to thermally impact the area or otherwise twist the tool steel preform. Further, in the embodiment, there is __ or multiple tempering after cooling, and σ tempering may include heating the area To approximately 85〇卞 ( 4541 ) and The temperature between Miyazaki (about 537. 〇) lasts from about μ to about 6 gongs. The tempering is changed by converting the residual Worth field to martensite. I38621.doc J3- 200944596 Microstructures. Such a technique is known, and multiple tempering cycles can be used to convert the residual Worth field. Those skilled in the art will understand that the shape and size of the tool steel can be preformed and allowed. Depending on the amount of Meredithian volume and the number of tempering treatments used, tempering may include heating to a higher or lower temperature for a shorter or longer period of time. According to one embodiment, after quenching, back The zone before the fire is not heat treated at a temperature of AG or higher than A. Furthermore, the zone may not be heated above any temperature experienced by the zone during deformation. In other words, the preform may be reheated, however, any subsequent The temperature during heating does not significantly reduce or modify the strain or differential row established by the Worth field in the deformation zone at a temperature between the stable Worth field temperature and the martensite start temperature. In the embodiment, the method One step includes trimming the tool steel preform into a tool after the thermomechanical deformation process. The trimming may include material removal (4) resulting in a final shape and/or surface "surface. For example, the S' conventional trimming process may include Machining, grinding, sanding/polishing, or a combination thereof to prepare a tool for use. However, trimming may require removing only a small amount of material to form the preform into a tool. For example, the deformation may include near net shape The forging process requires (after deformation) a small subsequent processing (if present) of the pre-formed (d) to produce the tool. - or multiple secondary processes may follow the cooling or trimming of the implement. The secondary process includes a certain way Forming a coating on the tool or further modifying the surface of the tool. An exemplary secondary process includes thermal spraying or covering the deformed area of the tool or the entire tool with an anti-wear material. Other secondary processes include coating the working surface of the tool by coating techniques including 138621.doc •14·200944596 (but not limited to) physical vapor deposition (PVD), chemical vapor deposition (CVD) or salt bath coating. Other surface modification techniques include ion implantation, laser or plasma hardening techniques, nitridation or carbonization, which can be used to modify the surface layer at the working surface of the tool. It should be appreciated that any of a variety of secondary processes can be used in any combination to further modify the tool. As explained above, the preform comprises tool steel. Tool steel represents a type of steel from which tools for cutting, forming or otherwise forming another material are made. The tool steel can be hardened by heat treatment and can be tempered to achieve the desired mechanical properties. For example, preforms can be made from a variety of different types of tool steels, such as cold work, hot work, high speed tool steel grade materials, or exclusive tool steel grades. In particular, the tool steel is an iron-1⁄4 (Fe-C) alloy system having a carbon content ranging from about 35% by weight to about 1% by weight, and in another example, by the desired carbonization. The expected other carbon content, if any, is from about 85% by weight to about 1.30 by weight. Within the range of /0. The φ tool steel usually contains an additive of a carbide forming element such as vanadium (V), tungsten (W), chromium (Cr), molybdenum (Mo) or a combination thereof. Depending on the alloy addition, one or more carbide phases (e.g., M6c, m2c, m23c6, M7Cpt-M4C) may precipitate, although other types of carbides are known to be formed in the art. With few exceptions, the tool steel does not contain the intentional additive nickel (Ni) 0 nickel as the known Vostian bulk stabilizer. However, tool steels may contain trace amounts (up to 0.3 weight 〇/〇) for this element. Table 1 shows the nominal composition of the weight percent of the exemplary steep tool steel that can be used to make the tool according to an embodiment of the present invention (the rest of the tool steel 138621.doe •15·200944596 is divided into iron (Fe)). By way of example, Table 1 _ tool steel ac3 is located between about 2100 °F (about 1149t) and about 2400T (about 1316. 〇, ACi temperature is about 1380T (about 749 ° C) and about 1680T (about Within the range between 915.6 〇C), and Ms is in the range between about 320 T (about 160 〇 and about 480 T (about 249 ° C). Table 1

〇 此外,預成形坯亦可包含粉末金屬材料或,詳言之,粉 末金屬工具鋼。通常藉由實體研磨或以其他方式將工具鋼 之主體塊製成許多小的個別粒子、將粉末金屬注入鑄模或 將粉末金屬通過衝模以產生弱内聚粉質壓成體且如此項技 術中已知地燒結該粉質壓成體來製得粉末金屬工具鋼預成 形坯。由粉末金屬工具鋼形成之工具通常表徵為具有作為 其製造方法之結果的各向同性性質。然而,當根據本文中 所揭示之實施例加工時,相對於根據習知燒結及/或熱等 靜壓方法加工之粉末金屬工具,工具之性質得以改良。 、如本文中所揭示’加u具鋼改具鋼之微結構。如 以上所閣㉚,工具鋼在其含有沃斯田體時變形。如此項技 術中已知,沃斯田體具有面心立方(fec)晶體結構且馬氏 體具有體心正方(bet)晶體結構^因為其較高數目之滑動 138621.doc -16 · 200944596 面,一般熟習此項技術者認為沃斯田體與馬氏體相比具有 較高延展性。一般熟習此項技術者一般認可在高於ac3之 溫度下形成之任何沃斯田體為穩定的。亦即,在高於ac3 之溫度下’沃斯田體通常不分解成其他相。在低於AC3之 溫度下,沃斯田體已知為不穩定的且通常稱為亞穩,因為〇 In addition, the preform may also comprise a powdered metal material or, in other words, a powder metal tool steel. The bulk of the tool steel is usually solidified or otherwise formed into a plurality of small individual particles, the powder metal is injected into the mold or the powder metal is passed through a die to produce a weakly cohesive powder compact and has been The powder metal tool steel preform is obtained by sintering the powder compact into a body. Tools formed from powder metal tool steel are typically characterized as having isotropic properties as a result of their method of manufacture. However, when processed in accordance with the embodiments disclosed herein, the properties of the tool are improved relative to powder metal tools that are processed according to conventional sintering and/or hot isostatic pressing methods. As disclosed herein, the microstructure of the steel is modified. As in the above cabinet 30, the tool steel is deformed when it contains a Worth. As is known in the art, the Worth field has a face-centered cubic (fec) crystal structure and the martensite has a body-centered bet crystal structure ^ because of its higher number of sliding 138621.doc -16 · 200944596 faces, Those who are familiar with this technology generally believe that the Worth field has higher ductility than martensite. Those of ordinary skill in the art generally recognize that any Worth field formed at temperatures above ac3 is stable. That is, at temperatures above ac3, the Worth field does not normally decompose into other phases. At temperatures below AC3, the Worth field is known to be unstable and is often referred to as metastable because

若在AC3與Ms之間的溫度下保持延長時段,則分解為其他 相。存在於本文中所描述之溫度範圍内的沃斯田體為亞穩 的。儘管不希望被理論限制,但咸信亞穩沃斯田體(儘管 與沃斯田體具有相同之晶體結構)殘留應變歷程。 含有亞穩沃斯田體之預成形坯之塑性變形導致與單獨自 此等溫度之間淬火或在高於AG之溫度下鍛造預成形坯且 接著淬火所得之微結構不同的微結構。變形區域之所得微 結構及材料性質可取決於工具鋼之類型、熱機械加工之類 型、沃斯田體中所誘發之應變量、誘發應變之速率及在哪 -溫度下執行熱機械加卫。舉例而言,MdACi之間的溫 度下的亞穩沃斯田體之熱機械加卫可產生與及之 間的溫度下的亞穩沃斯田體之熱機械加卫所產生之微結構 不相同的微結構。然而,在任—狀況下,變形區域呈現改 良之機械性質。 作為在此等溫度範圍下變形沃斯田體之結果,在一 施例中’微結構為細粒狀 變烙區域中晶粒或 體^均大小可比在藉由習知過程所製得之卫具中觀測 之彼等小至少1〇% ’且在另一實例 在—此宭始 ^王y約25%。 在二實巾,細絲微結構㈣於料^另一過程 I3862I.doc -17- 200944596 期間沿較多晶粒邊界之碳化物相之均一沈澱。 此外,另一微結構特徵可包差排密度之增加。如此項技 術中已知,差排為結晶固體中之線性缺陷,諸如在沃斯田 體中 ㈤例不性差排由晶體内額外半面之原子形成,儘 吕其他類型之差排為已知的且已知許多類型之差排同時形 成於單一晶體中。此外’晶粒邊界可由一或多個差排表 不。在多晶材料中(例如預成形坯之工具鋼材料),鄰近晶 體之間存在的晶粒邊界為一個晶粒之晶格與鄰近晶粒之晶 格之間的錯配區域。隨著鄰近晶粒之間的錯配或錯誤定向 角之度數自零度增加(鄰近晶粒之晶體結構對準於零度), 晶粒邊界處之差排密度增加。因此,晶粒之間錯誤定向角 之量測為差排密度之量測,尤其為晶粒邊界處之差排密 度。變形工具鋼預成形坯之區域與藉由在高於Ac3之溫度 下熱鍛造或根據習知方法之熱處理來變形類似組份之區域 相比將晶粒之間的錯誤定向角增加至較大度數。經變形、 /卒火及回火後之馬氏體晶粒可在(例如)大於約3 4。之平均角 處定向錯誤,且在另一實例中,馬氏體晶粒為至少約4〇。 之平均定向錯誤。此外,在一項實施例中,區域之差排密 度比習知過程之經熱锻造或經熱處理部分大至少2 $ %。舉 例而言,可藉由使用電子背向散射繞射(EBSD)或X-光繞射 (XRD)技術來量測差排密度及晶粒大小。除改良變形區域 之衝擊強度外’在變形期間或在後繼加熱或冷卻操作中, 高差排密度位置可提供晶核形成點以用於碳化物相之沈 澱。 138621.doc -18- 200944596 變形區域亦可呈現晶粒結構 形區域之橫剖面圖中,曰 疋向。詳言之,在變 當相對於彼此排列或定向時 或具有另-形狀使得 佳流量或方向性^佳 "#體地對微結構提供較 中之-者的方向、相對於工 ”之表面 佳定向之另-區域的方向心=方:或相對於亦具有較 向。在—項實施例中,變較佳定向可在任何方 且之工^ 變域中晶粒之較佳定向符合工If it is kept at an extended temperature between AC3 and Ms, it is decomposed into other phases. The Worth field body present in the temperature range described herein is metastable. Although it is not intended to be limited by theory, it is believed to be a residual strain history of the Yassworth Worth (although having the same crystal structure as the Worth). The plastic deformation of the preform containing the metastable Worth field results in a microstructure different from that obtained by quenching the temperature alone or forging the preform at a temperature higher than the AG and then quenching. The resulting microstructure and material properties of the deformed zone may depend on the type of tool steel, the type of thermomechanical processing, the amount of strain induced in the Worth field, the rate at which the strain is induced, and at which temperature the thermomechanical reinforcement is performed. For example, the thermomechanical reinforcement of the metastable Worth field at the temperature between MdACi can produce a microstructure that is different from that produced by the thermomechanical reinforcement of the metastable Worth field at the temperature between Microstructure. However, in any case, the deformed area exhibits improved mechanical properties. As a result of the deformation of the Worth field in these temperature ranges, in one embodiment, the microstructure or grain size in the fine-grained grain-changing region is comparable to that obtained by a conventional process. They are at least 1% less in the middle observations and in another instance - this is about 25%. In the two real towels, the filament microstructure (4) is uniformly precipitated along the carbide phase of more grain boundaries during the process I3862I.doc -17- 200944596. In addition, another microstructure feature can increase the difference in packing density. As is known in the art, the difference is a linear defect in a crystalline solid, such as in the Worth field (5), the anomalous row is formed by the atoms of the additional half of the crystal, and the difference between the other types is known. Many types of differential rows are known to be formed simultaneously in a single crystal. In addition, the grain boundaries can be represented by one or more difference rows. In polycrystalline materials (e.g., tool steel materials for preforms), the grain boundaries present between adjacent crystals are mismatched regions between the crystal lattice of one crystal grain and the crystal lattice of adjacent crystal grains. As the degree of mismatch or misorientation between adjacent grains increases from zero (the crystal structure of adjacent grains is aligned to zero), the difference in density at the grain boundaries increases. Therefore, the measurement of the misorientation angle between the crystal grains is measured as the difference in the density of the discharge, especially the difference in density at the grain boundaries. The area of the deformed tool steel preform is increased to a larger degree than the area where the similar component is deformed by hot forging at a temperature higher than Ac3 or heat treatment according to a conventional method. . The martensite grains after deformation, fire and tempering may be, for example, greater than about 34. The average angle is misorientated, and in another example, the martensite grains are at least about 4 Å. The average orientation error. Moreover, in one embodiment, the difference in area density is at least 2% greater than the hot forged or heat treated portion of the prior art process. For example, the differential row density and grain size can be measured by using electron backscatter diffraction (EBSD) or X-ray diffraction (XRD) techniques. In addition to improving the impact strength of the deformed region, the high differential displacement position may provide a nucleation site for precipitation of the carbide phase during deformation or in subsequent heating or cooling operations. 138621.doc -18- 200944596 The deformed area can also appear in the cross-sectional view of the grain structure area, 曰 疋. In particular, when they are arranged or oriented relative to each other or have a different shape, such that the flow or directionality is good, the surface of the microstructure is provided to the surface of the microstructure. The direction of the other direction of the preferred direction = square: or relative to the direction. In the embodiment, the preferred orientation can be in any direction and the preferred orientation of the die in accordance with the work.

二』Γ之表面輪廓。舉例而言,較佳定向可符合由 大體上:兩個相交表面所形成的表面輪廓。晶粒結構可 大體上平行於每一表面同時自第一 面)過渡至接近邊緣之咏 、、卞仃於個表 面、Μ 第二方向(其平行於第二表 。預成形枉之初始形狀(在加工之前存在於預成形柱中 1何碳化物或合金帶)及加工技術可為判定變形區域中 日日粒之較佳定向的主要因素。 :此,在一項實施例中,變形區域之特徵在於上述微結 /徵中之兩者或兩者以上之組合。舉例而言,變形區域 2有小平均晶粒大小之晶粒大小分佈,且晶粒可相對於 八之工作表面或工具軸而較佳定向。此外,區域可表徵 為具有相對高差排密度。在一項實施例中,區域可進一步 表徵為,有較精細的、較均—分佈的碳化物相或位於晶粒 及鬲差排饴度位置處之相。此外,特性可能不會在變 形區域内之位置之間顯著變化,儘管顯著變化可存在於兩 或兩個以上獨立形成之區域之間。舉例而言,預成形坯 之。ρ分可具有由相對低差排密度區域分離之相對高差排密 I38621.doc -19- 200944596 度:域。區域之間差排密度之變化可歸因於所使用之不同 l程(例如,徑向鍛造相比於平面應變鍛造)、不同鍛 率或強度、不同溫度等。 、 :為理論所限制,發明者咸信來自熱機械加工之外部能 量可用以在亞穩沃斯田體相内形成精細晶粒結構,野晶粒 結構提供定向’増加差排密度或產生其之組合。在淬火 後’變形亞穩沃斯田體有利地影響最終形成之微結構。此 外,來自熱機械加工之外部能量可有助於微結構中碳化物 相之沈;殿。舉例而言’咸信低於ACi之溫度下之熱機械加 工降低亞穩沃斯田體中碳之可溶性,且因此,促進碳化物 沈殿。在相關實施例中,碳化物相可在變形期間或在冷卻 期間或在變形與冷卻兩者期間沈澱於晶粒邊界及/或差排 位點。sub,與纟高之溫 形坯相比,除其他改良之性質外,在低於aCi之溫度下經 ^工之工具鋼預成形述呈現更大強度。此外,咸信此溫度 範圍中差排密度之增加與在高於ACi之溫度下經熱機械加 工之預成形链相比顯著較高。 如以上所闡述,預成形坯之變形區域之特徵在於與習知 過程(例如,同於AC3之溫度下的熱處理及/或熱鍛造)相比 之改良性質。因此,自工具鋼預成形坯製得之工具可(例 如)呈現較長使用壽命。改良之性質可包括衝擊強度(根據 夏比(Charpy)測試)、韌性、硬度或耐磨性中之一或多者或 其組合之改良。藉由比較,根據本發明之一項實施例經加 工之M2 AISI工具鋼之預成形坯之變形區域之衝擊強度可 138621.doc .20- 200944596 比在呵於Ah之溫度下變形或在無鍛造情況下經熱處理之 類似組伤之工具高至少50%。在任何實施例中,較長工具 壽命可歸因於對在使用期間所經歷之增強之抗衝擊性、抗 其他應力性或抗研磨條件性。 參看圖2A及2B且根據本發明之另一實施例,工具18包 括具有外表面22之構件20 ’外表面22通常包括用以連接或 耦接至機器(未展示)之第一部分24及以工作表面26為代表 性形式之第二部分,工作表面26在工具丨8用於金屬成形及 金屬切割應用時接觸工件28 ^此外,外表面22封閉且界定 工具鋼之主體體積或主體質量之外邊界。如圖2^中最佳展 示,至少一區域3〇形成於(如本文中所描述)經封閉之主體 體積内。且,當區域30不由工具18之全部主體體積組成 時,構件20可具有另一區域32 ,區域32與區域3〇相比在微 結構特性中之一或多個方面不同,且因此,在以上所描述 之性質方面不同。 在一項實施例中’藉由再次參看圖2A,構件20經伸長且 外表面22界定筒或柄34,頭部36安置於柄34之一個末端, 且具有尖端40之鼻端或本體38安置於柄34之與頭部36相對 之末端。尖端40上承載之工作表面26沿切割邊緣44與尖端 40之側壁42接合。切割邊緣44界定一拐角,側壁42及工作 表面26沿該拐角匯合。切割邊緣44及工作表面26共同界定 工具18之接觸工件28之表面的部分。工件28可包含將由工 具18在金屬成形或金屬切割應用中加工之材料。 當沿工具18之縱軸或中線50觀察時’伸長構件2〇之柄34 138621.doc 21 · 200944596 卞二具有合適橫剖面輪廓,諸如圓形、矩形、正方形 形橫剖面輪廟。柄34及本體38可具有相同區之橫剖 面輪廓,或本體38可具有較小橫剖面區以在柄34及本體38 之間提供起伏區域52°在某些實施例中,柄34及本體38關 於中線5〇對稱女置,且詳言之’可具有以中線50為中心之 環狀或圓形橫剖面輪廓。Second, the surface contour of the skull. For example, the preferred orientation may conform to a surface profile formed by substantially: two intersecting surfaces. The grain structure may be substantially parallel to each surface simultaneously transitioning from the first face to the edge of the edge, to the surface, to the second direction (which is parallel to the second table. The initial shape of the preformed crucible ( The presence of a carbide or alloy ribbon in the preformed column prior to processing and processing techniques can be a major factor in determining the preferred orientation of the solar particles in the deformed region. Here, in one embodiment, the deformed region It is characterized by a combination of two or more of the above microjunctions/signals. For example, the deformed region 2 has a grain size distribution with a small average grain size, and the crystal grains can be relative to the working surface or tool axis of the eight In addition, the regions can be characterized as having a relatively high difference in row density. In one embodiment, the regions can be further characterized by a finer, more uniform-distributed carbide phase or in the grains and ruthenium. The phase at the location of the difference in taper. In addition, the characteristics may not vary significantly between locations within the deformed region, although significant variations may exist between two or more independently formed regions. For example, preforming The ρ segment can have a relative height difference separated by a relatively low difference density region. I38621.doc -19- 200944596 degrees: domain. The difference in the difference in density between regions can be attributed to the different l-pass used. (for example, radial forging compared to plane strain forging), different forgings or strengths, different temperatures, etc., : Limited by theory, the inventor is convinced that external energy from thermomechanical machining can be used to stabilize the Vostian The fine grain structure is formed in the bulk phase, and the wild grain structure provides a directional '増 plus difference density or a combination thereof. After quenching, the 'deformed metastable Worth field beneficially affects the final microstructure. In addition, from the heat The external energy of machining can contribute to the sinking of the carbide phase in the microstructure; for example, thermomechanical processing at temperatures below ACi reduces the solubility of carbon in the metastable Worth field, and therefore Promoting carbide slabs. In related embodiments, the carbide phase may precipitate at grain boundaries and/or misalignment sites during deformation or during cooling or during both deformation and cooling. Warm shape In contrast, in addition to other improved properties, the tool steel preforming at a temperature lower than aCi exhibits greater strength. In addition, the increase in the difference in density in the temperature range is higher than in ACi. The thermoformed preformed chain is significantly higher at temperatures compared to the temperature. As explained above, the deformed region of the preform is characterized by a conventional process (eg, heat treatment and/or hot forging at the same temperature as AC3). Compared to improved properties, tools made from tool steel preforms can, for example, exhibit a long service life. Improved properties can include impact strength (according to Charpy test), toughness, hardness, or An improvement in one or more of the wear resistance or a combination thereof. By comparison, the impact strength of the deformed region of the preform of the processed M2 AISI tool steel according to an embodiment of the present invention may be 138621.doc.20 - 200944596 At least 50% higher than tools that are deformed at the temperature of Ah or that are heat treated without forging. In any embodiment, the longer tool life can be attributed to enhanced impact resistance, other stress resistance, or anti-grinding conditions experienced during use. Referring to Figures 2A and 2B and in accordance with another embodiment of the present invention, the tool 18 includes a member 20 having an outer surface 22. The outer surface 22 generally includes a first portion 24 for attachment or coupling to a machine (not shown) and for operation. Surface 26 is a second portion of a representative form that contacts workpiece 28 when tooling 8 is used for metal forming and metal cutting applications. Further, outer surface 22 is closed and defines the outer volume of the tool steel or the outer mass of the body. . As best shown in Figure 2, at least one region 3〇 is formed (as described herein) within the enclosed body volume. Moreover, when region 30 is not comprised of the entire body volume of tool 18, member 20 can have another region 32 that differs from region 3〇 in one or more of the microstructure characteristics, and thus, above The nature of the description is different. In one embodiment, by referring again to FIG. 2A, member 20 is elongated and outer surface 22 defines a barrel or handle 34 that is disposed at one end of handle 34 and has a nose end or body 38 disposed at tip end 40. At the end of the handle 34 opposite the head 36. The working surface 26 carried on the tip 40 engages the side wall 42 of the tip 40 along the cutting edge 44. The cutting edge 44 defines a corner along which the side wall 42 and the working surface 26 meet. The cutting edge 44 and the working surface 26 collectively define a portion of the tool 18 that contacts the surface of the workpiece 28. The workpiece 28 can comprise materials that will be processed by the tool 18 in metal forming or metal cutting applications. When viewed along the longitudinal or centerline 50 of the tool 18, the shank 34 138621.doc 21 · 200944596 has an appropriate cross-sectional profile, such as a circular, rectangular, square cross-sectional wheel temple. The shank 34 and the body 38 can have a cross-sectional profile of the same region, or the body 38 can have a smaller cross-sectional area to provide an undulating region 52 between the shank 34 and the body 38. In certain embodiments, the shank 34 and the body 38 Regarding the midline 5 〇 symmetrical, and in detail 'can have a circular or circular cross-sectional profile centered on the midline 50.

工具之頭部36具㈣合於藉由與類似於機械卫具或壓 機(未展不)之金屬加工機器一起使用之工具固定器件來固 持的構造。在例示性實施例中,頭部%為具有大於柄Μ之 直徑的直徑的凸緣。然而,替代頭部36,工具18可替代地 ,括球鎖、楔鎖、轉塔或用於將工具18之柄34與工具固持 器件耦接之另一類型之固持結構。 工具18(其在代表性實施例中具有衝頭之構造)通常形成 模組54之組件。模組54進一步包括衝模56,衝模56含有收 納工具18之尖端4G之-部分的開σ58。衝模%及工具⑽ 作(當壓在一起時)以在工件28中形成成形洞或以某一所要The head 36 of the tool (4) is constructed to be held by a tool holding device for use with a metalworking machine similar to a mechanical or a mechanical machine (not shown). In an exemplary embodiment, the head % is a flange having a diameter greater than the diameter of the shank. However, instead of the head 36, the tool 18 can alternatively include a ball lock, a wedge lock, a turret, or another type of retaining structure for coupling the handle 34 of the tool 18 to the tool holding device. Tool 18, which has a configuration of a punch in a representative embodiment, typically forms a component of module 54. The module 54 further includes a die 56 that contains an opening σ 58 of the portion of the tip end 4G of the receiving tool 18. The die % and the tool (10) are made (when pressed together) to form a shaped hole in the workpiece 28 or at a desired

方式變形:Μ牛28。X具18及衝模56可自金屬加工機器移 除,其中藉由使用工具固持機構而將工具18暫時附接至撞 鐘(未展示)之末端。 工具18通常以方向61朝向工件28移動且具有垂直於工作 表面26與工件28之間的接觸點的負載。可機械地、液壓 地、氣動地或電性地驅動金屬加工機器以施加迫使工具上8 進入工件28中之負載。工具18之尖端40在由金屬加工機器 所賦予之高負載下被迫穿過(或進入)工件28之厚度且進入 138621.doc -22- 200944596 衝模開口 58。工件28被變形及/或在工具18之工作表面% 與工件2 8之間的接觸帶處或在接觸帶周圍被切割。 工具1 8可具有與代表性實施例之構造不同的其他衝頭構 造。舉例而言,工具18可經組態為刀片、跟式衝頭、台式 衝頭、圓衝頭等。儘管工具1 8經描繪為具有與代表性實施 例中之衝頭一致的構造,一般熟習此項技術者將理解,工 具18可具有其他構造,諸如衝模,例如衝模56(圖2a&2B) 或剝離器。詳言之,衝頭、衝模或剝離器形式之工具18可 應用於諸如穿孔及打孔、精密下料加工、成形,及擠壓或 模壓之金屬衝壓及成形操作中。 工具18亦可具有切割工具之構造’諸如旋轉式拉刀、非 旋轉式拉刀、分接頭、鉸刀、鑽頭、銑刀、修整工具等。 工具18可用於鑄造及模製應用,諸如習知模鑄、高壓模鎊 及射出成形。工具18亦可利用在藥物製程、保健食品製 程、電池製造、化妝品、糖果及食品及飲料工業中所使用 之粉末壓製應用中,及家用產品及核燃料、壓片、炸藥、 彈藥、陶瓷及其他產品之製造中。工具18亦可用於自動化 及零件夾具應用中’諸如定位或零件接觸元件。 參看圖2B,工具18之區域30、衝模56之區域62或工具18 之區域30及衝模56之區域62兩者由經熱機械加工之預成形 达(未展示)之區域形成或機械加工製得,如以上所闡述。 舉例而言’區域30通常定位於接近工作表面26或包括工作 表面26,使得在工具1 8之操作期間區域3〇接近工件28或與 工件28直接接觸。類似地,衝模56之區域62在工具18及衝 138621.doc -23· 200944596 模56被使用時接近工件28或與工件28直接接觸。區域30自 外表面22(例如,工作表面26)延伸至大於〇_039吋(1 mm)之 深度<1!。類似地,在衝模56中,區域62可為不規則形狀 的,但亦自外表面63延伸至大於0.039吋(1 mm)之深度dy 然而,當區域30或62形成於工具鋼預成形坯内之其他位 置中時’可觀測到有益效能。此等位置可由隨著以下操作 而來之因素來判定:其中使用工具18或使用成本考慮以平 . 衡工具18之使用與其製造成本。在任何方面,熱機械加工 區域30之特徵在於高差排密度、精細晶粒結構、晶粒之較 ❹ 佳定向或其組合,如上文所提供。在一項實施例中,高差 排费度、精細晶粒結構、晶粒之較佳定向或其組合可與熱 機械加工期間之主要變形方向相關。 工具18可具有多個高差排密度之區域、精細晶粒結構之 區域、晶粒之較佳定向之區域,或其組合之區域。在具有 兩個或兩個以上區域之實施例中,每一區域可鄰接至工具 鋼預成形坯内之緊鄰區域。應瞭解,一個區域中晶粒之定 向可或不可與其他區域中之任一者或工具18之軸大體上對 ◎ 準。在另-實施例中,高差排密度之區域、精細晶粒結構 之區域、晶粒之較佳定向之區域或其組合之區域大體上遍 . 及工具18延伸而非限於其一或多個部分。換言之,工具18 可自根據本文中之實施例先前經熱機械加工之工具鋼預成 形述機械加工製得或形成。 參看圖3A及3B,儘管本文中關於大體上完全由工具鋼 所組成之預成形坯描述及說明本發明之實施例,但在其他 138621.doc -24- 200944596 實施例’預成形培64可為由具有由相異鋼所製得之核心μ 之工具鋼所製得之殼層66之組態。如圖3Α所示,連同其他 變數,視工具(未展示)經製造以用於之應用而;t,核心68 可填充殼層66内之全部空隙或僅其一部分。儘管殼層66中 〗具鋼之體積與相異鋼之體積相比可能較小,但殼層66大 於〇.039忖0叫之厚度使得變形區域為至少0.039时(1麵) ’ 厚度。殼層66經設計以形成工具之工作表面26(參看圖 1A)核〜6 8可形成工具之剩餘部分且可經設計以對工具 _ 提供優良機械性質。僅藉由實例,殼層66可為卫具鋼管了 如圖3A所示。核心68可為由更經濟之另一種鋼(諸如,低 碳或冷加工鋼,例如D2)製得之圓筒。在圓柱形核心68插 入管狀殼層66後,預成形坯64經加熱且至少殼層%藉由在 上述溫度範圍中型鍛或徑向鍛造而變形。舉例而言,徑向 鍛造殼層66及核心68後所得之變形預成形坯69展示於圖3β 中。由經變形或鍛造之預成形坯69形成或機械加工製得之 ❹工具18a可用於(例如)需要橫向強度以改良工具之使用壽命 之應用(其可包括齒輪(如圖3C所示)或齒輪滾動或螺紋滚動 衝模)中’儘管工具之材料成本顯著降低。 將關於以下實例來描述本發明之其他細節。 實例1 根據本文中所揭示之方法之一項實施例製備具有丨5〇〇 忖(3.81厘米)之直徑及48吋(1219厘米)之長度的且在此項 技術中已知名為AISI M2、D2及M4之呈軋製條棒之組態的 八個工具鋼預成形坯。 138621.doc -25· 200944596 為此,將條棒在氣動爐中加熱高於ACi至21〇(rF〇M9t) 之溫度。使用在操作範圍中經校準之紅外線高溫計來記錄 ▲度量測°咸信此溫度τ條棒中之每-者中之微結構包含 沃斯田體。-旦條棒達到目標溫度,其被個別地轉移(以 避免零件轉移期間之溫度損失)至喉4_鐘徑向锻造機之 進口輕⑽以r°U)。藉由四個縮減過程(re—Uon)將! 5〇〇 付⑽厘米)直徑x4时〇21.9厘米)長度之條棒各自徑向锻 造:具有0.875时(2.222厘米)之直徑的條棒。每一縮減過 程化費大致15秒至大致20秒之間(每一條棒總共為最多肋 秒)。所計算之有效縮減比為66%。經加工之條棒經強制對 流、空氣冷卻至室溫。 在熱機械加工期間’已知歸因於由對流及輻射造成之損 失’熱金屬將損失熱量。因此’為將每一條棒之溫度維 在接近21崎⑴49。〇之目標溫度的狹窄溫度範圍内,來 自變形過程之外部熱量及内部熱量用以補償任何熱量損 失。因此,鍛造在接近等溫條件下執行。此外,監視沒户 以確保任何溫度變化為可忽略的。 八 在中間縮減過程期間自每一條棒切割小剖面以用於分 析。無任何樣本被觀察到呈現任何再結晶。此外,判定^ -樣本中所存在之相’量測晶粒之間的錯誤定向且開發I 氏體之[001]平關於橫向(TD)及徑向(RD)之極象圖。在 變形及後繼回火後,於條棒之橫剖面之半徑的二分之— 置處或自M2工具鋼條棒之中心約〇22时處獲得二二 Philips X,Pert X射線繞射儀上進行相鑑定。實例1之一個 138621.doc -26- 200944596 M2條棒之相分析展示於圖4A中。圖4A中,每一相之數字 分數為0.771473鐵馬氏體、0.00419837鉻-釩碳化物 (658741) ' 0.219877鐵-鎢碳化物(892579)及 0.00445168 VdC3。在具有EBSD偵測器之場發射環境掃描電子顯微鏡 (ESEM)- FEI/Philips XL30 ESEM-FEG上執行EBSD掃描。 使用疋向成像顯微術TM(〇rientation Imaging Microscopy™, 0IMTM)資料收集軟體收集資料且與XRD資料一起映射。由 0IMTM分析軟體產生錯誤定向圖表。圖4B中展示關於實例 1之M2工具鋼條棒中之一者之馬氏體晶粒而量測的錯誤定 向角的代表性分佈。圖4C中展示關於此M2條棒開發之極 象圖。 實例2 來自實例1之0.875吋(2.222厘米)直徑條棒中之幾者經再 加熱至尚於八(:1至2100卞(1149。(:)之溫度。在條棒經加熱 南於AC!後’咸信微結構包含沃斯田體。一旦條棒達到目 標溫度,其被個別地轉移至2〇〇噸4-錘徑向鍛造機之進口 輥。每一條棒在處於2100卞(1149。〇之溫度下時經徑向鍛 造。在四個縮減過程中,條棒直徑自〇 875吋(2·222厘米) 減小至0.640吋(1.626厘米除來自實例!之首次四次縮減 過程的66%縮減外,橫剖面區域之此縮減達到47%有效縮 減比。經加工之條棒經強制對流、空氣冷卻至室溫。於中 間縮減過程處自一個條棒切割若干樣本以記錄應變之影 響。與來自實例1之樣本相同,未在樣本中之任一者中觀 測到再結晶。 138621.doc •27- 200944596 如前所述’平衡對環境之熱量損失與自變形產生之熱量 以試圖在熱機械加工期間將條棒維持在恆溫。在加工期間 且在縮減過程之間監視溫度以確保溫度變化為可忽略的。 因此咸信所有外部能量轉移至預成形坯以增加差排密度且 降低沃斯田體晶粒大小。 接著將條棒在氣動爐中於14〇〇〇F(76(rc )下消除應力歷 時四小時且經由條棒矯直器成功地加工以最小化變形。 實例3 製備具有1.500叫*(3.81厘米)之直徑及48叶(121.9厘米)之 長度的且此項技術中已知名為入181 M2、D2&M42呈軋製 條棒之組態的八個工具鋼預成形坯。 在氣動爐中將條棒加熱至2〇5〇卞(1121。(:)之溫度。咸信Mode deformation: Yak 28. The X-piece 18 and die 56 can be removed from the metalworking machine by temporarily attaching the tool 18 to the end of a bumper (not shown) by using a tool holding mechanism. The tool 18 typically moves in a direction 61 toward the workpiece 28 and has a load that is perpendicular to the point of contact between the working surface 26 and the workpiece 28. The metalworking machine can be driven mechanically, hydraulically, pneumatically or electrically to apply a load that forces the tool 8 into the workpiece 28. The tip 40 of the tool 18 is forced through (or into) the thickness of the workpiece 28 under high loads imparted by the metal working machine and into the die opening 58 of 138621.doc -22-200944596. The workpiece 28 is deformed and/or cut at or around the contact strip between the working surface % of the tool 18 and the workpiece 28. Tool 18 can have other punch configurations than those of the representative embodiment. For example, tool 18 can be configured as a blade, a heel punch, a table punch, a round punch, and the like. Although tool 18 is depicted as having a configuration consistent with a punch in a representative embodiment, those skilled in the art will appreciate that tool 18 can have other configurations, such as a die, such as die 56 (Fig. 2a & 2B) or Stripper. In particular, the tool 18 in the form of a punch, die or stripper can be used in metal stamping and forming operations such as perforation and perforation, precision blanking, forming, and extrusion or molding. The tool 18 can also have the construction of a cutting tool such as a rotary broach, a non-rotating broach, a tap, a reamer, a drill bit, a milling cutter, a dressing tool, and the like. Tool 18 can be used in casting and molding applications such as conventional die casting, high pressure die and injection molding. Tool 18 can also be utilized in powder compaction applications used in pharmaceutical manufacturing, health food processing, battery manufacturing, cosmetics, confectionery, and food and beverage industries, as well as household products and nuclear fuels, tablets, explosives, ammunition, ceramics, and other products. In the manufacture. Tool 18 can also be used in automation and part fixture applications such as positioning or part contact elements. Referring to Fig. 2B, region 30 of tool 18, region 62 of die 56 or region 30 of tool 18 and region 62 of die 56 are formed or machined from a thermoformed preformed (not shown) region. As explained above. For example, the 'area 30 is generally located proximate to or includes the working surface 26 such that the region 3〇 approaches or is in direct contact with the workpiece 28 during operation of the tool 18. Similarly, the region 62 of the die 56 approaches the workpiece 28 or is in direct contact with the workpiece 28 when the tool 18 and the die 138621.doc -23. 200944596 die 56 are used. Zone 30 extends from outer surface 22 (e.g., working surface 26) to a depth <1! greater than 〇 039 吋 (1 mm). Similarly, in the die 56, the region 62 may be irregularly shaped, but also extends from the outer surface 63 to a depth greater than 0.039 吋 (1 mm). However, when the region 30 or 62 is formed in the tool steel preform In other locations, 'beneficial performance can be observed. Such locations may be determined by factors such as the use of tool 18 or the use of cost considerations to balance the use of tool 18 with its manufacturing cost. In any aspect, the thermomechanical processing region 30 is characterized by a high differential density, a fine grain structure, a preferred orientation of the grains, or a combination thereof, as provided above. In one embodiment, the high differential charge, fine grain structure, preferred orientation of the grains, or a combination thereof may be associated with the primary direction of deformation during thermo-machining. The tool 18 can have a plurality of regions of high differential density, regions of fine grain structure, regions of preferred orientation of the grains, or regions of combinations thereof. In embodiments having two or more zones, each zone may abut the immediate vicinity of the tool steel preform. It should be understood that the orientation of the grains in a region may or may not be substantially aligned with any of the other regions or the axis of the tool 18. In another embodiment, the region of the high-difference density, the region of the fine grain structure, the region of the preferred orientation of the die, or a combination thereof is substantially throughout and the tool 18 extends rather than being limited to one or more thereof. section. In other words, the tool 18 can be made or formed from preformed mechanical machining of previously thermoformed tool steel in accordance with embodiments herein. Referring to Figures 3A and 3B, although embodiments of the present invention are described and illustrated herein with respect to preforms that are substantially entirely comprised of tool steel, in other embodiments 138621.doc -24- 200944596, the 'preformed culture 64 can be The configuration of the shell 66 made of tool steel having a core μ made of dissimilar steel. As shown in FIG. 3A, along with other variables, a tool (not shown) is fabricated for use; t, the core 68 can fill all or only a portion of the void within the shell 66. Although the volume of the steel in the shell 66 may be smaller than the volume of the dissimilar steel, the shell 66 is greater than the thickness of the 忖.039忖0 such that the deformed region is at least 0.039 (1 sided) thick. The shell 66 is designed to form the working surface 26 of the tool (see Figure 1A). The cores -6 can form the remainder of the tool and can be designed to provide excellent mechanical properties to the tool. By way of example only, the shell 66 can be a harness tube as shown in Figure 3A. Core 68 may be a cylinder made from another steel that is more economical, such as low carbon or cold worked steel, such as D2. After the cylindrical core 68 is inserted into the tubular shell 66, the preform 64 is heated and at least the shell layer % is deformed by swaging or radial forging in the above temperature range. For example, the deformed preform 69 obtained after radially forging the shell 66 and the core 68 is shown in Figure 3β. The boring tool 18a formed or machined from the deformed or forged preform 69 can be used, for example, in applications requiring lateral strength to improve the useful life of the tool (which can include gears (as shown in Figure 3C) or gears Rolling or thread rolling die) 'Although the material cost of the tool is significantly reduced. Further details of the invention will be described in relation to the following examples. Example 1 A diameter having a diameter of 丨5〇〇忖 (3.81 cm) and a length of 48 吋 (1219 cm) was prepared according to an embodiment of the method disclosed herein and is known in the art as AISI M2, D2 And eight tool steel preforms of M4 in the form of rolled bars. 138621.doc -25· 200944596 To this end, the bar is heated in a pneumatic furnace at a temperature above ACi to 21 〇 (rF 〇 M9t). Recorded using a calibrated infrared pyrometer in the operating range. ▲Metrics The microstructure of each of the temperature τ bars contains a Worth field. Once the bar reaches the target temperature, it is individually transferred (to avoid temperature loss during part transfer) to the throat of the throat 4* radial forging machine (10) at r°U). With four reduction processes (re-Uon) will! 5 付 (10) cm) 直径 21.9 cm in diameter x 4) length bars are each radially forged: bars with a diameter of 0.875 (2.222 cm). Each reduction in process cost is between approximately 15 seconds and approximately 20 seconds (each bar totals a maximum of rib seconds). The calculated effective reduction ratio is 66%. The processed bars are forced to convection and air cooled to room temperature. Hot metal will lose heat during thermomechanical processing known to be attributed to losses caused by convection and radiation. Therefore, the temperature of each bar is close to 21 (1) 49. The external heat and internal heat from the deformation process are used to compensate for any heat loss in the narrow temperature range of the target temperature. Therefore, forging is performed under nearly isothermal conditions. In addition, monitoring is done to ensure that any temperature changes are negligible. Eight Cut a small section from each bar during the intermediate reduction process for analysis. No samples were observed to exhibit any recrystallization. In addition, it is determined that the phase present in the sample measures the misorientation between the grains and develops the [001] plane of the I's body with respect to the polar (TD) and radial (RD) polar images. After deformation and subsequent tempering, the two-half Philips X, Pert X-ray diffractometer is obtained at a half of the radius of the cross section of the bar or at about 22 o'clock from the center of the M2 tool steel bar. Phase identification. One of Example 1 138621.doc -26- 200944596 The phase analysis of the M2 bar is shown in Figure 4A. In Figure 4A, the digital fraction for each phase is 0.771473 iron martensite, 0.00419837 chromium-vanadium carbide (658741) '0.219877 iron-tungsten carbide (892579) and 0.00445168 VdC3. The EBSD scan was performed on a field emission environment scanning electron microscope (ESEM)-FEI/Philips XL30 ESEM-FEG with an EBSD detector. The software collection data was collected using the 〇rientation Imaging MicroscopyTM (OMIMM) data and mapped with the XRD data. The error orientation chart is generated by the 0IMTM analysis software. A representative distribution of the wrong directional angles measured for the martensite grains of one of the M2 tool steel bars of Example 1 is shown in Figure 4B. An image of the development of this M2 bar is shown in Figure 4C. Example 2 Several of the 0.875 吋 (2.222 cm) diameter bars from Example 1 were reheated to a temperature of still eight (: 1 to 2100 卞 (1149. (:). The bars were heated to the south by AC! After the 'salt microstructure contains the Worth field. Once the bar reaches the target temperature, it is individually transferred to the inlet roller of the 2 ton 4-hammer radial forging machine. Each bar is at 2100 卞 (1149). Radial forging at the temperature of the crucible. During the four reductions, the diameter of the rod was reduced from 〇875吋 (2·222 cm) to 0.640吋 (1.626 cm except for the first four reductions from the example! In addition to the % reduction, the cross-sectional area is reduced by a 47% effective reduction ratio. The processed bars are forced to convection and air cooled to room temperature. Several samples are cut from a bar at the intermediate reduction process to record the effect of strain. As with the sample from Example 1, recrystallization was not observed in either of the samples. 138621.doc •27- 200944596 As described above, 'balance the heat loss from the environment and the heat generated by self-deformation in an attempt to be hot Maintain the bar at constant during machining Temperature. The temperature is monitored during processing and during the reduction process to ensure that the temperature change is negligible. Therefore all external energy is transferred to the preform to increase the differential density and reduce the grain size of the Worth field. The stress was relieved in a pneumatic furnace at 14 〇〇〇F (76(rc) for four hours and successfully processed by a bar straightener to minimize distortion. Example 3 was prepared with a diameter of 1.500**(3.81 cm) and Eight tool steel preforms of 48 leaf (121.9 cm) length and known in the art as 181 M2, D2 & M42 in the form of rolled bars. The bars are heated in a pneumatic furnace to 2〇5〇卞(1121.(:)The temperature.

卻至室溫。 儘可能將條棒保 與實例1及2中所描述之溫度控制類似 持在银溫。在加工 狩在位A。在加工期間且力始士 门立在縮減過程之間監視條棒中之每 一者之溫度以確保溫度變化為可忽略的。 138621.doc -28- 200944596 在中間縮減過程期間自每一條棒切割小剖面以用於分 析。沒有樣本呈現動態再結晶之微結構特性。判定相,獲 取晶粒之間錯誤定向之量測,且在條棒之橫剖面之半徑的 二分之一或自條棒中心約0.25吋的位置處開發馬氏體之 [001]平面之極象圖。實例3之一個M2條棒之相分析展示於 圖5A中。圖5A中相之數字分數為0.737644鐵馬氏體、 0.0111572鉻-釩碳化物(658741)、〇 24〇541鐵-鎢碳化物 (892579)及 0.0106579 V4C3。圖 5B中展示實例3iM2 工具 鋼條棒中之一者之馬氏體晶粒之間的錯誤定向角的代表性 分佈。圖5C中展示關於此M2條棒開發之極象圖。 比較實例1 藉由以下步驟而在2巴(bar)真空爐中使用標準熱處理循 環來熱處理軋製AISI M2棒料:將條棒加熱至高於 2250°F (約1232°C ),接著三個加熱至約1〇〇〇卞且保持約45 分鐘至1小時及冷卻之標準回火循環以達成與實例丨及3相 同之硬度,亦即HRC 61〜63。接著將經熱處理之條棒研磨 至與實例3之條棒相同之外部尺寸。 圖6A、6B及6C中展示比較條棒之相之量測、錯誤定向 角及極象圖。圖6A中指示之相之數字分數為〇·66〇257鐵馬 氏體、0.00451285絡-飢碳化物(658741)、〇33〇886鐵鶴碳 化物(892W9)及0.00434446 VW3。條棒中之每一者中所存 在之相與由圖4Α、5Α及6Α之比較分析所提供之相大體上 相同。 然而,實例1及3之條棒中之每一者的差排密度顯著高於 138621.doc •29· 200944596 比較實例1之條棒的差排密度。特定地,藉由將圖犯及化 與圖6B進行比較,實例丨及3之厘2條棒中之每一者的錯誤 定向角顯著高於圖6B中所展示之比較⑽條棒的錯誤^向 角。實&lt;歹U(圖4B)之條棒之錯誤定向角之分佈的平均值為 約36度’實例3⑽B)之條棒之錯誤定向角之分佈的平均 值為約42度’且比較實#u(圖6B)之條棒之錯誤定向角之 分佈的平均值為約34度。實例⑷之㈣工具鋼條棒相對 於比較熱處理M2條棒之高平均錯誤定向角指示較高差排 密度及應變。咸信在低於ACl之溫度下的變形與在高溫下 之變形相比可使晶粒之錯誤定向角增加,因為晶粒:較 少熱能且以減慢速率自變形恢復。 當與圖6C中所展示之比較實例κΜ2條棒之極象圖相比 時,實例!及3之M2條棒之改良之差排密度亦分別由圖4c 及5C中所展示之極象圖證實。極象圖指示實例⑴之條棒 的差排後度或差排數顯著高於僅經熱處理之比較實例^之 條棒的差排密度。相對差排密度由圖表中之每一者中之點 的密度來指示。因此,實例i(圖4C)具有最高差排數,接 著為實例3(圖5C),且比較實例1(圖6C)具有最小差排數。 實例4 來自實例3之過程的ι·〇〇〇吋(2·54厘米)直徑條棒中之幾 者經再加熱至2050 F(112TC )(高於AC〗但低於AC3)。將條 棒自爐子移除且使其空氣冷卻至約丨丨〇〇卞(約5%艺)與約 1200 F (約649 C )之間的加工溫度。一旦達到加工溫度,條 棒被各自於七個縮減過程中徑向锻造為具有〇 7〇〇忖(1 138621.doc -30· 200944596 厘米)之直㈣條棒。所計算之縮減比為m 自ΓΓ二條棒空氣冷卻至室溫。於中間縮減過程處 棒呈現動態再結晶之微結構特性。 沒有條 如前所述,在加工如pq ^ Α 期間且在縮減過程之間監視溫度以確 保溫度變化為可忽略的。 接著將條棒回火三次··在真空爐中於約9獅(約5But to room temperature. As much as possible, the bar is held at the same temperature as the temperature control described in Examples 1 and 2. In processing, hunting is in place A. The temperature of each of the bars is monitored during processing and during the reduction process to ensure that the temperature change is negligible. 138621.doc -28- 200944596 Cut a small section from each bar during the intermediate reduction process for analysis. None of the samples exhibited microstructural properties of dynamic recrystallization. Determining the phase, obtaining a measure of the misorientation between the grains, and developing the pole of the [001] plane of martensite at a distance of one-half of the radius of the cross-section of the bar or about 0.25 inch from the center of the bar Like a picture. A phase analysis of an M2 rod of Example 3 is shown in Figure 5A. The numerical fraction of the phase in Fig. 5A is 0.737644 iron martensite, 0.0111572 chromium-vanadium carbide (658741), 〇24〇541 iron-tungsten carbide (892579) and 0.0106579 V4C3. A representative distribution of misorientation angles between the martensite grains of one of the example 3iM2 tool steel bars is shown in Figure 5B. A pole figure for the development of this M2 bar is shown in Figure 5C. Comparative Example 1 A rolled AISI M2 bar was heat treated in a 2 bar vacuum furnace using a standard heat treatment cycle by heating the bar to above 2250 °F (about 1232 °C) followed by three heatings. A standard tempering cycle of about 1 Torr and holding for about 45 minutes to 1 hour and cooling is achieved to achieve the same hardness as Examples 丨 and 3, i.e., HRC 61-63. The heat treated bars were then ground to the same outer dimensions as the bars of Example 3. The measurement of the phase of the bar, the misorientation angle and the polar image are shown in Figures 6A, 6B and 6C. The numerical fractions indicated in Figure 6A are 〇·66〇257 iron martensite, 0.00451285 collateral-starved carbide (658741), 〇33〇886 iron crane carbide (892W9) and 0.00434446 VW3. The phase present in each of the bars is substantially the same as that provided by the comparative analysis of Figures 4, 5 and 6 . However, the difference in density of each of the bars of Examples 1 and 3 was significantly higher than that of 138621.doc •29·200944596. Specifically, by comparing the figure and the comparison with FIG. 6B, the error orientation angle of each of the example bars and the 3 bars of 3 is significantly higher than the error of the comparison (10) bar shown in FIG. 6B. To the corner. The average value of the distribution of the misorientation angles of the bars of the real < 歹 U (Fig. 4B) is about 36 degrees. The average value of the distribution of the misalignment angles of the bars of the example 3 (10) B) is about 42 degrees 'and the comparison # The average of the distribution of the misorientation angles of the bars of u (Fig. 6B) is about 34 degrees. The high average misalignment angle of the (4) tool steel bar of the example (4) relative to the comparative heat treated M2 bar indicates a higher difference in density and strain. The deformation of the salt at temperatures below ACl can increase the misorientation angle of the grains compared to the deformation at high temperatures because the grains: less thermal energy and recover from deformation at a slower rate. The improved differential density of the M2 bars of Examples! and 3 is also confirmed by the polar image shown in Figures 4c and 5C, respectively, when compared to the polar image of the comparative example κΜ2 bars shown in Figure 6C. . The pole image indicates that the difference in the post-displacement or the difference in the number of bars of the example (1) is significantly higher than that of the bars of the comparatively heat-treated comparative example. The relative difference in density is indicated by the density of points in each of the graphs. Therefore, the instance i (Fig. 4C) has the highest difference row number, followed by the example 3 (Fig. 5C), and the comparative example 1 (Fig. 6C) has the smallest difference row number. Example 4 Several of the ι·〇〇〇吋(2·54 cm) diameter bars from the procedure of Example 3 were reheated to 2050 F (112 TC) (above AC but below AC3). The rod is removed from the furnace and allowed to air cool to a processing temperature between about 5% (about 5% art) and about 1200 F (about 649 C). Once the processing temperature is reached, the bars are forged radially into seven straight bars with a diameter of 〇〇忖 7〇〇忖 (1 138621.doc -30· 200944596 cm). The calculated reduction ratio is m from two bar air cooling to room temperature. At the intermediate reduction process, the rod exhibits the microstructural properties of dynamic recrystallization. No bars As previously mentioned, the temperature is monitored during processing such as pq ^ 且 and during the reduction process to ensure that the temperature change is negligible. Then temper the bar three times. · About 9 lions in the vacuum furnace (about 5

與約庸F(約538t)之間的溫度下歷時約3小時。確認為) 回火過程將任何殘留沃斯㈣轉換為馬氏體。應注意在以 上實例1·4中’經加工之條棒含有經伸長且沿條棒之縱轴 較佳定向的晶粒》 儘管實例1至4利用徑向鍛造,可使用此項技術中已知的 ”他鍛;^技術來熱機械加工預成形坯’如以上所闞述。因 此’在下述實例中’在水平熱桿端鍛粗機(upswing machine)上重複近平面應變锻造過程^開發預成形堪65, 其在藉由此機器經鍛造時將產生圓柱形條棒(參看圖7及8八 及8B)。圓柱形條棒可接著被用作預成形坯以用於機械加 工或形成金屬切割及金屬成形工具。 參看圖7、8A及8B,在近平面應變鍛造過程中,完全由 工具鋼組成之預成形坯65幾何形狀包括長方形段7〇及圓柱 形段72。圓柱形段72不經受任何變形且主要用於在鍛造期 間將預成形坯65定位及固持於機器中。長方形段7〇或區域 在加工期間經加熱且經受變形使得工具由此形成。在變形 後’經變形之預成形坯75具有變形之長方形段73或區域, I38621.doc 31 200944596 如圖8B中最佳展示。 現參看圖9,在近平面應變鍛造過程中,工具模槽”及 撞錘76各自經設計以形成半圓形模槽。共同地,所得之由 工具模槽74及撞錘76之閉合形成的圓形形狀經設計以在一 個方向上阻止長方形段7〇中工具鋼之移動同時允許工具鋼 在徑向及圓周方向上流動。 · 實例5 自軋製研磨棒料機械加工製得圖7及8A中所說明之幾何 形狀的AISI M2工具鋼預成形坯。習知研磨棒料中之軋製 〇 方向或主要碳化物方向始終與圓柱形段之軸同心,如圖4 中之箭頭所指示。在加工之前碳化物條帶之方向可判定熱 機械加工後碳化物之定向。隨後,在真空爐令= 1400 F(76〇C)下將預成形述初始退火歷時45分鐘及分鐘 之間以消除任何殘餘應力且獲得近等軸晶粒結構。 j火後,使用感應線圈將每一預成形迷之長方形段加熱 至高於ACi至約1850卞(約1〇1(rc)之溫度。在此加工溫度 下’咸信微結構包含沃斯田體。使用内建於用以模擬近+ Q 面應變鍛造㈣之5(H頁水平桿端鍛粗機中的紅外線高溫計 來監視溫度。一旦預成形坯之長方形段達到 185(TF(lGlGt) ’每-預成形堪被個別地鍛造為近半圓形 橫剖面(例如參圖8B)。 · 锻造後,藉由對流空氣冷卻將每—條棒淬火至室溫。鍛 造後之微結構包含精細晶粒沃斯田體。淬火後,沃斯田體 轉變為馬氏趙且碳化物沈殿。認為此微結構為不穩定的, 138621.doc 32- 200944596 且將其在真空爐申於約950〇F(約51(rc)與約1〇〇〇下(約 538 C )之間的溫度下及約2巴之壓力下消除應力。在消除 應力後,於約1200卞(約649t)與1400卞(760。〇之間的溫 度下歷時45至60分鐘每循環而經由三個回火循環加工預成 形坯以將殘留沃斯田體轉換至馬氏體,接著爐内冷卻以將 微結構中之殘留沃斯田體轉換至馬氏體。It takes about 3 hours with the temperature between Jochen F (about 538 t). Confirmed as) The tempering process converts any residual Voss (4) to martensite. It should be noted that in the above example 1-4, 'the processed bars contain grains which are elongated and preferably oriented along the longitudinal axis of the bar." Although Examples 1 through 4 utilize radial forging, it is known in the art. "He forging; ^ technology to thermomechanically process preforms" is described above. Therefore, in the following example, the near-plane strain forging process is repeated on the horizontal hot rod end upswing machine. Forming 65, which will produce cylindrical bars when forged by this machine (see Figures 7 and 8 8 and 8B). Cylindrical bars can then be used as preforms for machining or forming metals Cutting and metal forming tools. Referring to Figures 7, 8A and 8B, in a near-plane strain forging process, the preform 65 geometry consisting entirely of tool steel includes a rectangular section 7〇 and a cylindrical section 72. The cylindrical section 72 does not Subject to any deformation and primarily used to position and hold the preform 65 in the machine during forging. The rectangular section 7 or region is heated and subjected to deformation during processing such that the tool is thereby formed. Molding blank 75 A deformed rectangular section 73 or region, I38621.doc 31 200944596 is best shown in Figure 8B. Referring now to Figure 9, in the near-plane strain forging process, the tool cavity" and the ram 76 are each designed to form a semicircle Mold groove. Collectively, the resulting circular shape formed by the closure of the tool cavity 74 and the ram 76 is designed to prevent the movement of the tool steel in the rectangular section 7 in one direction while allowing the tool steel to flow in the radial and circumferential directions. . • Example 5 A AISI M2 tool steel preform of the geometry illustrated in Figures 7 and 8A was machined from a rolled abrasive bar. The rolling in the conventional abrasive bar 〇 direction or main carbide direction is always concentric with the axis of the cylindrical section, as indicated by the arrows in Figure 4. The orientation of the carbide strip prior to processing determines the orientation of the carbide after thermomechanical processing. Subsequently, the preform was initially annealed at vacuum furnace order = 1400 F (76 ° C) for between 45 minutes and minutes to eliminate any residual stress and obtain a near equiaxed grain structure. After the fire, the rectangular section of each pre-formed fan is heated to a temperature higher than ACi to about 1850 卞 (about 1 〇 1 (rc) using an induction coil. At this processing temperature, the salty microstructure contains the Worth field. Use the infrared pyrometer built into the 5th horizontal bar end forging machine to simulate the near + Q surface strain forging (4) to monitor the temperature. Once the rectangular segment of the preform reaches 185 (TF(lGlGt) ' Each pre-form is individually forged into a nearly semi-circular cross section (see, for example, Figure 8B). After forging, each bar is quenched to room temperature by convection air cooling. The forged microstructure contains fine crystals. After the quenching, the Worth field is transformed into Markov and the carbide sink. It is considered that the microstructure is unstable, 138621.doc 32- 200944596 and it is applied in a vacuum furnace at about 950〇F (Reducing stress at a temperature between about 51 (rc) and about 1 〇〇〇 (about 538 C) and at a pressure of about 2 bar. After stress relief, at about 1200 卞 (about 649 t) and 1400 卞 ( 760. The temperature between the crucibles is 45 to 60 minutes per cycle and the preforms are processed through three tempering cycles. Residual austenite-converted to martensite, followed by furnace cooling to the microstructure of the residual austenite to martensite-converted.

自近平面應變鍛造獲得之衝擊強度增加歸因於差排密度 之增加及沃斯田體晶粒大小之減小。然而,與徑向鍛造過 程不同,在近平面應變鍛造中,對環境之熱量損失為可忽 略的因為變形沿長方形段之全部長度幾乎瞬間發生。 實例6 自軋製研磨棒料機械加工製得圖8At所說明之幾何形狀 的AISI M2工具鋼預成形述且接著經加工。與先前預成形 链相同,在加工之前的碳化物札製方向以習知方向來定向 (參看圖7)。加熱及變形之前,預成形述在真空爐中於 1400 F(76〇C)下經退火歷時45分鐘與6〇分鐘之間以消除預 成形述中之任何殘餘應力且獲得近等軸晶粒結構。 使用感應線圈將預成形坯中之每一者加熱至 2050 F(1121 C )之溫度。此溫度高於ACi但低於a。使用 紅外線高溫計監視溫度。線圈及高溫計兩者均内建於 ACMA 50嘴水平桿端鍛粗機中。 的微結構包含沃斯田體。在加熱至·eF(u2rc)後允 許將長方形段空氣冷卻至約ιι〇〇卞(約59代)與約 1200 F (約649C)之間的溫度。降溫發生約i分鐘。微結構 138621.doc •33- 200944596 包含亞穩沃斯田體。長方形段接著被鍛造為圓形橫剖面組 態同時保持在1100卞(593。〇與1200卞(649。(:)之間的加工 溫度下。 接著允許經鍛造之預成形坯冷卻至室溫。冷卻後,所發 生之馬氏體轉變及碳化物沈澱產生預成形坯之長方形段中 的均質、精細晶粒微結構β然而,歸因於存在殘留沃斯田 體’認為微結構對於大部分應用為不穩定的。預成形坯隨 後在950卞(510。〇與1000卞(538。〇之間的溫度下歷時45分 鐘與60分鐘之間回火三次。 在變形之長方形段中之每一者中觀測到衝擊強度增加。 衝擊強度增加係歸因於差排密度之增加、沃斯田體晶粒大 小之減小及碳化物沈澱之起始。又,與在徑向鍛造試驗期 間所觀測之結果類似,在低於Aq之溫度下經鍛造之預成 形坯之機械性質與彼等在高於ACi之溫度下經鍛造之預成 形坯之機械性質相比為經改良的。咸信在較低溫度下經鍛 造之預成形坯中的差排密度顯著高於藉由在較高溫度下經 鍛造而產生的差排密度。 參看圖10A及10B,儘管先前例示性實施例中之熱機械 加工改良衝擊強度’歸因於近平面應變锻造過程之固有性 質,每一長方形段中存在相對高強度之區域及相對低強度 之區域。最大變形區域及最小變形區域經定向為大體上彼 此垂直。為達成清楚之目的,藉由圖1〇B中之曲線指示鍛 造後晶粒之較佳定向。相對低衝擊強度區域通常為彼等接 觸工具模槽及撞錘或位於工具模槽及撞錘附近的區域。相 138621.doc •34- 200944596 對焉衝擊強度區域係關於最大變形區域。圖l〇A中所展示 之橫剖面之尺寸為約13.11 mm高及約11.03 mm寬,其中寬 度為自預成形坯之末端(左邊)至變形之長方形段73之表面 轉變為圓柱形段72(右邊)的位置所量測。 • 在需要最大改良及近均一材料強度之預成形坯中,可使 用夕步驟平面應變锻造過程以連續地改良相對低衝擊強度 區域之強度。舉例而言,為獲得用於金屬成形及金屬切割 /、之;熱機械處理之圓柱形條棒,可使用近平面應變鍛 ^«•將’、有矩形或正方形之橫剖面幾何形狀之條棒之組態的 預成形坯熱機械處理為具有橢圓形橫剖面之條棒。用以形 成/、有圓I橫剖面之條棒的糖圓形橫剖面之後繼熱機械加 工可提供變形之更均一分佈。 特定地,參看圖1〇8,作為使用平面應變鍛造之第一次 熱機械處理之結果,相對低強度區域將沿最小變形區域對 準或接近於最小變形區域對準,且相對高強度區域將相對 φ 於相對兩變形區域對準。因此,經鍛造為橢圓形橫剖面之 矩形或正方形條棒可用作用於後繼近平面應變鍛造過程之 預成形坯。在後繼加工中,相對低強度區域可沿最高變形 • 之方向對準。此定向可(例如)垂直於初始變形方向。因 此’相對低強度區域將被增強(作為彼區域中變形之結 果)。相反,由第一次鍛造操作獲得之相對高強度區域將 觀測到最小變形強度且因此最小之改良。 實例7 自丁15工具鋼之粉末金屬預成形坯製備兩個工具。自經 138621.doc •35- 200944596 退火之熱等靜麼τ15粉末金屬機械加工製得預成形㈣ 注意,板之微結構由於其製備方法而為幾乎各向同性的。 預成形链具有如圖11Α十所展示之組態。如所展示,預成 形坯76之一個末端具有方錐形之形狀。所量測之預成形坯 之整體長度為5.75# (14.6厘米),其中方錐形段占總長度 之1.75吋(4.445厘米)。 藉由感應加熱器將預成形坯76於約4分鐘内加熱至 20崎(1〇93。〇與2050Τ⑴21。〇之間的加王溫度(A與 AG之間)。藉由具有5〇〇噸衝模夾持力之丨,〇〇〇噸水平機械 AJAX桿端鍛粗機將熱預成形坯在一個週期中鍛造為近淨 形。經鍛造之預成形坯78展示於圖UB中。詳言之,i 75 吋(4.445厘米)方錐形末端經鍛造為i吋(2 54厘米)矩形末 端80,如所展示。 鍛造後,將經鍛造之78在爐中於140&lt;rF(76(rc)下歷時 45分鐘與60分鐘之間消除應力。接著允許經鍛造之預成形 極78於爐中冷卻至室溫。 將經應力消除之預成形坯回火三次以將殘留沃斯田體轉 換為馬氏體。所量測之最終硬度為在63 1^11(:與66 hrC2 間。機械加工經三次回火之零件以移除鏽皮、脫碳 (decarb)且提供最終工具形狀。藉由將所展示之預成形坯 切割一半而自圖UB中所展示之預成形坯組態製得一組兩 個工具18b、18c。 工 兩個工具1 8b、18c相對於彼此操作(如圖丨丨c中之箭頭所 指示),亦即,一上部工具及一下部工具,以切割鋼片 138621.doc -36- 200944596 件(未展示)。工具之間的間隙為0 006吋(〇 〇1524厘米”工 件為具有以商標USIBOR® 1500P出售之八⑻塗層之 22MnB5鋼。工件鋼經壓力硬化至UTS 1500 MPa(50HRC)。鋼片經量測為J 85 mm(〇 〇7283吋)厚。在大 致68 F(大致20°C)下進行測試。於四個位置處監視切割邊 緣處之磨損。每5,000次衝擊或循環進行切割邊緣輪廓之 量測。 圖12A、13A、14A及15A中展示上部及下部T15工具中 ® 之每一者之邊緣輪廓量測,其亦提供參考材料及CPM® Μ4粕末金屬之工具的邊緣輪廓。(由CPM® M4粉末金屬製 得之工具充分描述於以下實例8中。)儘管進行上部及下部 工具兩者上四個位置處之磨損量測,圖式中僅提供上部及 下邛工具上之兩個最高磨損位置。分別於圖、BE、 14B及MB中所指示之位置進行輪廓量測。 更明確地說,圖12A及13A分別為上部工具於圖12B(位 φ S υ及圖13B(位置4)中所指^之位置處之切割邊緣的邊緣 輪廓的圖形。且,圖14A及15A分別為下部工具於圖 (位置1)及圖15B(位置4)中所指定之位置處之邊緣輪廓 . 的圖形。如圖式中所指示之位置1及4處之邊緣輪廓說明剩 餘兩個未報告位置處之磨損量測。 參看圖12A、13A、14A及15A,標有”開始邊緣幾何形狀” 之線表示在任何使用之前的邊緣幾何形狀。標有”參考&quot;之 線表示在由根據工業標準加工之參考材料製得之工具上進 行之量測。 138621.doc 200944596 10,000次及20,000次碰撞處之T15工具之位置處之邊 緣輪廓分別標有&quot;Τ15... 10000次衝擊,,及&quot;Τ15 2〇〇〇〇次衝 擊”。如圖形所說明,在每一位置處,與上部及下部工具 上之10,000次衝擊處之參考材料相比,根據上述程序 製得之Τ15工具之邊緣在1〇,〇〇〇次衝擊處具有較少磨損。 在20,000次衝擊處,Τ15工具具有可與參考材料工具於 1〇,〇〇〇次衝擊處之磨損量相當的磨損量。因此,根據本發 明之一項實施例之T15工具提供幾乎為參考材料之耐磨性 及抗衝擊性兩倍的耐磨性及抗衝擊性。 實例8 自CPM® M4工具鋼之粉末金屬預成形坯製備兩個工 具。(CPM® 為 Crucible Materials Corp.,New York之商 標。)自經退火之CPM® M4粉末金屬散裝材料機械加工製 得預成形坯。應注意,作為用以製備主體cpM(g) M4材料 之軋製方向之結果,CPM® M4板之微結構具有主要碳化 物條帶。預成形坯具有如圖11A中所展示之組態。如所展 不,預成形坯之一個末端具有方錐形之形狀。所量測之預 成形坯之整體長度為5.75吋(146厘米),其中方錐形段占 5.75吋(14.6厘米)中之1.75吋(4,445厘米)。 藉由感應加熱器將預成形述在大致4分鐘内加熱至 2000°F(1093。C)與2050。F(1121。C)之間的溫度(ACl與AC3之 間)。藉由具有500嘲衝模夾持力之ι,〇〇〇π頓水平機械ajAX 桿端鍛粗機將熱預成形坯在一個循環中锻造為近淨形。經 鍛造之預成形坯展示於圖11B中。詳言之,ι·75忖(4 445厘 138621.doc -38- 200944596 米)方錐形末端(展示於圖11A中)經鍛造為丨吋^,“厘米)矩 形末端’如所展示。 鍛造後,將預成形坯在爐中於1400=F下歷時45分鐘與6〇 分鐘之間進行應力消除。接著允許預成形坯於爐中冷卻至 室溫。 將經應力消除之預成形坯回火三次以將任何殘留沃斯田 體轉換為馬氏體。所量測之最終硬度為在62 料 HRC之間。 圖11B之經鍛造之預成形坯之切割邊緣之區域中的較佳 晶粒定向與圖16A中所展示之類似。圖16A中所展示之樣 本之尺寸為自上而下17.98 mm及自一側至另一側1382 mm。根據圖12A、nA、14A及1SA中所展示之邊緣剖面圖 量測’在10,000次衝擊處,CPM® M4鍛造工具與參考材料 相比具有較少磨損。又,觀測到工具壽命之顯著改良。 儘^已藉由對各種實施例之描述而說明本發明,且儘管 已相當詳細地描述此等實施例,但是申請者之意圖並非將 附加申請專利範圍之範疇限定於此細節或以任何方式將附 加申請專利範圍之範疇限制於此細節。熟習此項技術者將 容易地發現額外優點及修改。因此,在本發明之寬泛實施 例中,本發明因此不限於所展示及描述之特定細節、代表 性裝置及方法及說明性實例。因此,在不脫離申請者之通 用發明性概念之範疇的情況下,可自此等細節進行偏離。 【圖式簡單說明】 圖1為根據本發明之實施例之熱機械加工M2 AISI工具鋼 138621.doc -39- 200944596 之例示性時間-溫度關係的圖示。 圖1A為根據本發明之實施例之熱機械加工工具鋼之其他 例示性時間-溫度關係的圖示。 圖2 A為根據本發明之代表性實施例之工具之侧面正視圖 及相應衝模之橫剖面圖。 圖2B描繪圖2A之工具及衝模之放大橫剖面圖。 圖3 A及圖3B分別為在變形之前及之後的包含殼層及核 心之預成形坯之一項實施例的透視圖。 圖3C為由圖3C之經變形之預成形坯所製得之工具之— 項實施例的透視圖。 圖4A、4B及4C分別為由M2工具鋼所製得之本發明之一 項例示性實施例之所存在相之量測、晶粒之錯誤定向角之 分佈及極象圖的圖示。 圖5A、5B及5C分別為由M2工具鋼所製得之本發明之另 一例示性實施例之所存在相之量測、晶粒之錯誤定向角之 分佈及極象圖的圖示。 圖6A、6B及6C分別為根據先前技術熱處理之M2工具鋼 棒之所存在相、晶粒之錯誤定向角之分佈及極象圖的圖 示〇 圖7為說明根據本發明之一項實施例之用於熱機械加工 工具鋼之例示性預成形坯組態的透視圖。 圖8A為根據本發明之一項實施例之在加工之前的囷7之 例示性預成形坯的平面圖。 圖8B為圖8A之例示性預成形坯在變形之後且沿圖7之剖 138621.doc -40- 200944596 面線8B-8B所得之部分橫剖面圖。 圖9為用於熱機械加工圖4及圖5八中所描繪之預成形坯組 態之例示性衝模及撞錘的圖解橫剖面表示。 圖10A為沿如圖8B中所展示而組態之預成形坯之圖之 • 長方形剖面所獲得之橫剖面的13X放大處獲得之顯微照 相。 圖10B為圖10A之顯微照相之圖示,其描繪繪製為曲線 之較佳晶粒定向。 圖11A及圖11B分別為描繪在變形之前及在變形及機械 加工之後預成形坯之一項組態的透視圖。 圖11C為由圖11B中所展示之預成形坯製得之一組工具的 透視圖,其相對於彼此位於可操作之位置以提供用於鋼材 料之切割片的剪切或修整運動。 圖12A、13A、14A及15A為說明本發明之例示性工具之 切割邊緣與由各自具有圖11C中所描繪之組態之參考材料 φ 所製得之工具之切割邊緣的輪廓之磨損量測之比較的圖解 視圖。 圖12B、13B、14B及15B為圖11C之工具之平面圖,其分 •別說明圖12A、13A、14A及15A之圖表中所提供之磨損輪 廟之量測位置。 圖16A為自圖11B中所展示之圍繞一個工具之切割邊緣 之區域之1 7X放大處橫剖面所獲得之顯微照相,其說明圍 繞切割邊緣之區域中之較佳晶粒定向。 圖16B為圖16A之顯微照相之圖示,其具有經描繪以說 138621.doc 41 200944596 明較佳晶粒定向之線。 【主要元件符號說明】 10 面於A C 1之加工溫度 11 高於MS之加工溫度 12 八^與八匕之間的加工溫度 13 Ms與八匕之間的加工溫度 14 碳化物鼻端 16 貝氏體鼻端 18 工具 18a 工具 18b 工具 18c 工具 20 構件 22 外表面 24 第一部分 26 工作表面 28 工件 30 區域 32 區域 34 柄 36 頭部 38 本體 40 尖端 42 側壁 138621.doc -42- 200944596The increase in impact strength obtained from near-plane strain forging is attributed to an increase in the difference in density and a decrease in the grain size of the Worth field. However, unlike the radial forging process, in near-plane strain forging, the heat loss to the environment is negligible because the deformation occurs almost instantaneously along the entire length of the rectangular segment. Example 6 The AISI M2 tool steel of the geometry illustrated in Figure 8At was machined from a rolled abrasive bar to be preformed and then machined. As with the previous preformed chain, the carbide casting direction prior to processing is oriented in a conventional direction (see Figure 7). Prior to heating and deformation, the preform is described as being annealed at 1400 F (76 ° C) in a vacuum oven for between 45 minutes and 6 minutes to eliminate any residual stress in the preform and to obtain a near equiaxed grain structure. . Each of the preforms was heated to a temperature of 2050 F (1121 C) using an induction coil. This temperature is higher than ACi but lower than a. Use an infrared pyrometer to monitor the temperature. Both the coil and the pyrometer are built into the ACMA 50 nozzle horizontal rod end forging machine. The microstructure consists of a Worth field. After heating to eF(u2rc), the rectangular section air is allowed to cool to a temperature between about ι 〇〇卞 (about 59 passages) and about 1200 F (about 649 ° C). The cooling takes place for about i minutes. Microstructure 138621.doc •33- 200944596 Contains a metastable Worth field. The rectangular section is then forged into a circular cross-sectional configuration while maintaining a processing temperature of 1100 卞 (593. 〇 and 1200 卞 (649. (:).) The forged preform is then allowed to cool to room temperature. After cooling, the martensite transformation and carbide precipitation that occurs will result in a homogeneous, fine grain microstructure in the rectangular section of the preform. However, due to the presence of residual Worthfield, the microstructure is considered for most applications. It is unstable. The preform is then tempered three times between 950 卞 (510 〇 and 1000 卞 (538 ° 历 历 45 45 minutes and 60 minutes. Each of the deformed rectangular segments) The increase in impact strength was observed. The increase in impact strength was attributed to the increase in differential discharge density, the decrease in grain size of the Worth field and the initiation of carbide precipitation. Again, similar to the results observed during the radial forging test. The mechanical properties of the forged preforms at temperatures below Aq are improved compared to the mechanical properties of the preforms that are forged at temperatures above ACi. Forging The differential discharge density in the preform is significantly higher than the differential discharge density produced by forging at a higher temperature. Referring to Figures 10A and 10B, although the thermomechanical improved impact strength in the previous exemplary embodiment Due to the intrinsic properties of the near-plane strain forging process, there are relatively high-strength regions and relatively low-strength regions in each rectangular segment. The maximum deformation region and the minimum deformation region are oriented substantially perpendicular to each other. For the purpose of clarity, The preferred orientation of the forged grains is indicated by the curves in Figures 1 and B. The relatively low impact strength regions are typically the areas where they contact the tool cavity and the ram or are located near the tool cavity and the ram. Doc •34- 200944596 The 焉 impact strength zone is about the maximum deformation zone. The cross section shown in Figure 〇A is about 13.11 mm high and about 11.03 mm wide, where the width is from the end of the preform (left The measurement is made to the position where the surface of the deformed rectangular section 73 is transformed into the cylindrical section 72 (right side). • The preform is required to have maximum improvement and near uniform material strength. The planar step strain forging process can be used to continuously improve the strength of the relatively low impact strength region. For example, to obtain a cylindrical rod for metal forming and metal cutting, or thermomechanical treatment, a near bar can be used. Planar strain forging ^••The preforms of the configuration of bars with rectangular or square cross-sectional geometry are thermomechanically treated as bars with elliptical cross-sections to form /, with a circle I The sugar circular cross section of the profile bar followed by thermomechanical processing provides a more uniform distribution of deformation. Specifically, see Figure 1-8, as a result of the first thermomechanical treatment using planar strain forging, relatively low strength The regions will be aligned along or near the smallest deformed region, and the relatively high intensity regions will be aligned relative to the two deformed regions. Therefore, a rectangular or square bar that is forged into an elliptical cross section can be used as a preform for a subsequent near-plane strain forging process. In subsequent processing, the relatively low-strength regions can be aligned in the direction of the highest deformation •. This orientation can be, for example, perpendicular to the initial deformation direction. Therefore, the relatively low-intensity region will be enhanced (as a result of deformation in the region). In contrast, the relatively high strength regions obtained from the first forging operation will observe a minimum deformation strength and thus a minimal improvement. Example 7 Two tools were prepared from a powder metal preform of Ding 15 tool steel. From 138621.doc •35- 200944596 Annealing of thermal turbidity τ15 powder metal machining to obtain preforms (4) Note that the microstructure of the plate is almost isotropic due to its preparation method. The preformed chain has the configuration shown in Figures 11-10. As shown, one end of the preform 76 has a square tapered shape. The measured preform has an overall length of 5.75# (14.6 cm), wherein the square tapered section accounts for 1.75 inch (4.445 cm) of the total length. The preform 76 is heated by an induction heater to a temperature of 20 s (1 〇 93. 〇 and 2050 Τ (1) 21 〇 的 between the A and the AG in about 4 minutes. By having 5 〇〇 tons After the die clamping force, the 预 ton horizontal mechanical AJAX rod end forging machine forges the hot preform into a near net shape in one cycle. The forged preform 78 is shown in Figure UB. , i 75 吋 (4.445 cm) square tapered end forged into i吋 (2 54 cm) rectangular end 80, as shown. After forging, forged 78 in the furnace at 140 ° rF (76 (rc) The stress is relieved between 45 minutes and 60 minutes. The forged preform 78 is then allowed to cool to room temperature in the furnace. The stress-relieved preform is tempered three times to convert the residual Worth field into a horse. The final hardness measured is between 63 1^11 (: and 66 hrC2. The three tempered parts are machined to remove scale, decarb and provide the final tool shape. The preforms shown are cut in half and a set of two tools 18b are produced from the preform configuration shown in Figure UB. 18c. The two tools 1 8b, 18c are operated relative to each other (as indicated by the arrows in Figure 丨丨c), that is, an upper tool and a lower tool to cut the steel sheet 138621.doc -36- 200944596 pieces (not shown). The gap between the tools is 0 006 吋 (〇〇1524 cm). The workpiece is 22MnB5 steel with the eight (8) coating sold under the trademark USIBOR® 1500P. The workpiece steel is pressure hardened to UTS 1500 MPa (50HRC) The steel sheet was measured to be J 85 mm (〇〇7283吋) thick. Tested at approximately 68 F (approximately 20 ° C). The wear at the cutting edge was monitored at four locations. Every 5,000 impacts or cycles Performing the measurement of the cutting edge profile. The edge profile measurements for each of the upper and lower T15 tools are shown in Figures 12A, 13A, 14A and 15A, which also provide reference materials and tools for the CPM® 粕4 end metal. Edge profile. (Tools made of CPM® M4 powdered metal are fully described in Example 8 below.) Although the wear measurements at the four locations on both the upper and lower tools are performed, only the upper and lower jaws are provided in the drawing. The two highest wear positions on the tool Contour measurements are made at the locations indicated in Figures, BE, 14B, and MB. More specifically, Figures 12A and 13A show the upper tool in Figure 12B (bit φ S υ and Figure 13B (position 4), respectively. The pattern of the edge contour of the cutting edge at the position of ^. Further, Figs. 14A and 15A are graphs of the edge contours of the lower tool at the positions specified in the figure (position 1) and Fig. 15B (position 4), respectively. The edge profiles at positions 1 and 4 indicated in the figure illustrate the wear measurements at the remaining two unreported locations. Referring to Figures 12A, 13A, 14A and 15A, the line labeled "Start Edge Geometry" indicates the edge geometry prior to any use. The line labeled "References" indicates the measurement on a tool made from reference materials processed according to industry standards. 138621.doc 200944596 The edge contours at the position of the T15 tool at 10,000 and 20,000 collisions are marked separately. There are &quot;Τ15... 10,000 impacts, and &quot;Τ15 2 times impact.” As shown in the figure, at each position, compared with the reference material of 10,000 impacts on the upper and lower tools, the edge of the Τ15 tool made according to the above procedure is at 1 〇, and the impact at the impact is higher. Less wear and tear. At 20,000 impacts, the Τ15 tool has a wear amount comparable to the amount of wear of the reference material tool at 1 〇. Therefore, the T15 tool according to an embodiment of the present invention provides wear resistance and impact resistance which are almost twice the abrasion resistance and impact resistance of the reference material. Example 8 Two tools were prepared from a powder metal preform of CPM® M4 tool steel. (CPM® is a trademark of Crucible Materials Corp., New York.) Preforms are machined from annealed CPM® M4 powder metal bulk materials. It should be noted that as a result of the rolling direction used to prepare the bulk cpM(g) M4 material, the microstructure of the CPM® M4 board has a predominantly carbonized strip. The preform has a configuration as shown in Figure 11A. As shown, one end of the preform has a square tapered shape. The measured preform has an overall length of 5.75 吋 (146 cm), wherein the square tapered section accounts for 1.75 吋 (4,445 cm) of 5.75 吋 (14.6 cm). The preform was heated to 2000 °F (1093 ° C) and 2050 by means of an induction heater for approximately 4 minutes. The temperature between F (1121.C) (between ACl and AC3). The hot preform was forged into a near net shape in one cycle by a 135, horizontal mechanical ajAX rod end forging machine having a clamping force of 500 stencils. The forged preform is shown in Figure 11B. In particular, ι·75忖 (4 445 138 138621.doc -38- 200944596 m) square tapered ends (shown in Figure 11A) are forged into 丨吋^, "cm" rectangular ends as shown. Thereafter, the preform was subjected to stress relief in a furnace at 1400 = F for 45 minutes and 6 minutes. The preform was then allowed to cool to room temperature in a furnace. The stress-reduced preform was tempered Three times to convert any residual Worth field into martensite. The final hardness measured is between the HRC of 62. The preferred grain orientation in the region of the cut edge of the forged preform of Figure 11B Similar to that shown in Figure 16A, the dimensions of the sample shown in Figure 16A are from top to bottom 17.98 mm and from side to side 1382 mm. According to the edges shown in Figures 12A, nA, 14A and 1SA Profile measurement 'At 10,000 impacts, the CPM® M4 forging tool has less wear than the reference material. Also, significant improvements in tool life have been observed. The description has been made by describing various embodiments. Invention, and although these embodiments have been described in considerable detail, It is the intention of the applicant not to limit the scope of the appended claims to the details or to limit the scope of the appended claims to the details in any way. Those skilled in the art will readily find additional advantages and modifications. The present invention is not limited to the specific details, the representative apparatus and methods, and the illustrative examples shown and described, and thus, without departing from the scope of the general inventive concept of the applicant. Deviation from this detail. BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a graphical representation of an exemplary time-temperature relationship for thermomechanically processed M2 AISI tool steel 138621.doc-39-200944596, in accordance with an embodiment of the present invention. 2 is a schematic illustration of other exemplary time-temperature relationships of thermomechanical tool steels in accordance with an embodiment of the present invention. FIG. 2A is a side elevational view of a tool and a cross-sectional view of a corresponding die in accordance with a representative embodiment of the present invention. Figure 2B depicts an enlarged cross-sectional view of the tool and die of Figure 2A. Figure 3A and Figure 3B show the shell and core, respectively, before and after deformation. Figure 3C is a perspective view of an embodiment of the tool made from the deformed preform of Figure 3C. Figures 4A, 4B and 4C are respectively by M2 The measurement of the presence of the phase, the distribution of the misorientation angle of the die, and the diagram of the polar image of an exemplary embodiment of the present invention made by tool steel. Figures 5A, 5B, and 5C are respectively used by the M2 tool. A measurement of the presence of a phase, a distribution of misorientation angles of the grains, and a diagram of a pole image of another exemplary embodiment of the invention made by steel. Figures 6A, 6B and 6C are heat treatments according to prior art, respectively. FIG. 7 is a diagram illustrating an exemplary pre-preparation of a tool for thermomechanical machining of a tool steel according to an embodiment of the present invention. Perspective view of the configuration of the preform. Figure 8A is a plan view of an exemplary preform of crucible 7 prior to processing, in accordance with an embodiment of the present invention. Figure 8B is a partial cross-sectional view of the exemplary preform of Figure 8A after deformation and along section 138621.doc -40-200944596, face line 8B-8B of Figure 7. Figure 9 is a diagrammatic cross-sectional representation of an exemplary die and ram for thermomechanical processing of the preform configurations depicted in Figures 4 and 58. Figure 10A is a photomicrograph taken at a 13X magnification of a cross section obtained from a rectangular cross section of the preform configured as shown in Figure 8B. Figure 10B is an illustration of the photomicrograph of Figure 10A depicting a preferred grain orientation plotted as a curve. 11A and 11B are perspective views, respectively, depicting a configuration of a preform prior to deformation and after deformation and machining. Figure 11C is a perspective view of a set of tools made from the preforms shown in Figure 11B, operatively positioned relative to each other to provide shear or trimming motion for the cutting sheets of the steel material. Figures 12A, 13A, 14A and 15A are wear measurements for illustrating the contours of the cutting edges of the exemplary tool of the present invention and the cutting edges of the tool made of the reference material φ each having the configuration depicted in Figure 11C. A graphical view of the comparison. Figures 12B, 13B, 14B and 15B are plan views of the tool of Figure 11C, which illustrate the measurement positions of the wear wheel temples provided in the charts of Figures 12A, 13A, 14A and 15A. Figure 16A is a photomicrograph taken at a 1X magnified cross-section of the region of the cutting edge of a tool shown in Figure 11B, illustrating preferred grain orientation in the region surrounding the cutting edge. Figure 16B is a photomicrograph of Figure 16A with lines drawn to illustrate preferred grain orientation for 138621.doc 41 200944596. [Major component symbol description] 10 surface processing temperature of AC 1 is higher than MS processing temperature 12 八 与 and gossip processing temperature 13 Ms and processing temperature between gossip 14 carbide nose 16 Bayesian Body nose 18 Tool 18a Tool 18b Tool 18c Tool 20 Member 22 Outer surface 24 First part 26 Working surface 28 Workpiece 30 Area 32 Area 34 Handle 36 Head 38 Body 40 Tip 42 Side wall 138621.doc -42- 200944596

44 切割邊緣 50 中線 52 起伏區域 54 模組 56 衝模 58 開口 61 方向 62 區域 63 外表面 64 預成形坯 65 預成形坯 66 殼層 68 核心 69 預成形场 70 長方形段 72 圓柱形段 73 長方形段 74 工具模槽 75 預成形坯 76 撞錘 78 預成形坯 80 矩形末端 di 深度 d2 深度 138621.doc -4344 Cutting edge 50 Center line 52 Fluctuating area 54 Module 56 Die 58 Opening 61 Direction 62 Area 63 Outer surface 64 Preform 65 Preform 66 Shell 68 Core 69 Preformed field 70 Rectangular section 72 Cylindrical section 73 Rectangular section 74 Tool cavities 75 Preforms 76 Hammers 78 Preforms 80 Rectangular ends di Depth d2 Depth 138621.doc -43

Claims (1)

200944596 七、申請專利範圍: …種熱機械加I—包含具有—馬氏體開始溫度及一穩定 沃斯田體級度之卫具鋼之預成形达的方法該預成形述 、有3有沃斯田體之區域,該區域包括一外表面及用 於該外表面之複數個外部尺寸,該方法包含: 在Λ馬氏體開始溫度與該穩定沃斯田體溫度之間的一 加:溫度下建立至少該預成形坯之該區域; ❸ 萬/預成形坯之該區域處於該加工溫度下時,變形該 區域以改變該區域之該等外部尺寸中之至少-者及將該 區域之微結構自該外表面延伸之—深度改質為該外表面 之下的1毫米或超過1毫求之一深度;及 在ι區域經變形後,將該區域冷卻至室溫。 2. 如請求項]&gt; &gt; .1 法,其中在該區域變形後,該區域之該 等外部尺计+ Μ 大致等於一用於金屬成形或金屬切判應用中 之工具之一近淨形。 β, 3.200944596 VII. Scope of application for patents: ... a kind of thermomechanical plus I - a method comprising pre-forming of a steer steel with a martensite start temperature and a stable Worthian body grade. The region of the field body, the region including an outer surface and a plurality of outer dimensions for the outer surface, the method comprising: adding: a temperature between the start temperature of the martensite and the temperature of the stable wort field: temperature Establishing at least the region of the preform; when the region of the preform/the preform is at the processing temperature, deforming the region to change at least the outer dimensions of the region and the region The structure extends from the outer surface - the depth is modified to a depth of 1 mm or more than 1 millimeter below the outer surface; and after the ι region is deformed, the region is cooled to room temperature. 2. The claim item &gt;&gt; .1 method, wherein after the deformation of the region, the external gauge + Μ of the region is approximately equal to one of the tools used in metal forming or metal cutting applications shape. β, 3. 月求項1之方法,其中該區域具有一 深度跨越該橫剖面區延伸。 橫剖面區,且該 該 面 求項1之方法,其中該區域具有-橫剖面區 等外部只+ 寸中之該至少一者中之該改變減小該 區0 如請求項1之方法,其中 部尺 六丁6化辦丹勿―食度,且該等外 該長度。至少-者中之該改變增加或減小該區域之 6.如請求項b 士、丄 之方法,其中該藉由該變形改質之微結構包 138621.doc 200944596 錯誤定 ::有以大於約34。之一平均錯誤定向角為特徵的 向角之一分佈的馬氏體晶粒。 7. 8. 9. 如請求項1之方法, 度保持值溫。 如請求項1之方法, 沃斯田體開始溫度。 如請求項8之方法, 述包括加熱該區域至 度。 其中在該區域經變形時將該加工溫 其中該加工溫度大於該工具鋼之一 其中在該加工溫度下建立該預成形 不超過該穩定沃斯田體溫度的一溫 10·如請求項丨之方法,其進一步包含: 一在變形該區域之前,加熱該區域至一高於該工具鋼之 沃斯田體開始溫度的溫度且將該區域自該高於該沃斯 田體開始溫度之溫度冷卻至該加工溫度。 11 ·如叫求項1之方法,其中該加工溫度高於該工具鋼之一 沃斯田體開始溫度,且進一步包含: 田4區域經變形時,保持該加工溫度高於該沃斯田體 開始溫度。 12.如叫求項i之方法,其中該加工溫度在該馬氏體開始溫 度與该工具鋼之一沃斯田體開始溫度之間,且進一步包 含: 虽該區域經變形時,保持該加工溫度在該馬氏體開始 溫度與該沃斯田體開始溫度之間。 13.如叫求項i之方法’其中該區域之該微結構不會再結 晶0 138621.doc 200944596 14. 如請求項丨之方法,其進一步包含: Θ火該區域’其中回火包括加熱該區域至-不超過該 加工溫度之溫度。 15. 如請求項丨之方法,其進一步包含: • 在變形該區域之前,組合一由工具鋼製得之殼層與一 由相異鋼製得之核心,其t在該加工溫度下建立該區域 匕括在該加工溫度下建立至少該殼層,且,當該殼層處 於該加工溫度下時,變形該殼層之至少一部分。 16· -種用於在—機器中使用以改質—卫件之工具,該工具 包含: ' 一匕含一工具鋼之構件,該構件具有一外表面,該外 表面界定一經組態以與該機器耦接之第一部分及一適用 於接觸該工件之第二部分’且該構件包括—自該外表面 延伸至一大於1毫米之深度的第一區域及一藉由該第一 區域而與該外表面分離之第二區域,該第一區域包括具 〇 有以一大於約34。之平均錯誤定向角為特徵之錯誤定向 角之一分佈的複數個晶粒’具有一比該第二區域之平均 晶粒大小小至少1〇%的平均晶粒大小,且具有與該第二 • 區域中複數個晶粒不同的一晶粒定向。 17.如請求項16之工具,其中該平均錯誤定向角為至少約 40° 〇 18. 如請求項16之工具’其中該第—區域接近該外表面之該 第二部分。 19, 如請求項16之卫具,其中該第—區域之該微結構未經再 138621.doc 200944596 結晶。 20.如請求項16之工具,其中該構件包括一由工具鋼製得之 殼層及一由相異鋼製得之核心,該殼層具有該界定該第 一部分之外表面且該核心形成該第二區域之至少一部 分。 138621.doc -4-The method of claim 1, wherein the region has a depth extending across the cross-sectional area. a cross-sectional area, and the method of claim 1, wherein the area has a cross-sectional area or the like, and the change is reduced in the at least one of the at least one of the areas, such as the method of claim 1, wherein The ruler of the six-six-six-six-six-story--------------------------------------------- At least - the change in the region increases or decreases the region. 6. The method of requesting the term b, 丄, wherein the microstructure package 138621.doc 200944596 modified by the deformation is determined to be: 34. One of the average misorientation angles is a martensitic grain distributed in one of the characteristic directional angles. 7. 8. 9. As requested in item 1, the degree is kept constant. As in the method of claim 1, the Worth field begins to temperature. The method of claim 8 includes heating the area to a degree. Wherein the processing temperature is increased when the region is deformed, wherein the processing temperature is greater than one of the tool steels, wherein the preforming temperature at the processing temperature does not exceed a temperature of the stable Worth field temperature. The method further comprising: prior to deforming the region, heating the region to a temperature above a starting temperature of the Worth field of the tool steel and cooling the region from the temperature above the temperature at which the Worth field begins To the processing temperature. 11. The method of claim 1, wherein the processing temperature is higher than a starting temperature of a Worth field of the tool steel, and further comprising: maintaining a processing temperature higher than the Worth field when the field 4 is deformed Start temperature. 12. The method of claim i, wherein the processing temperature is between the martensite start temperature and a Worth field start temperature of the tool steel, and further comprising: maintaining the process while the region is deformed The temperature is between the martensite start temperature and the Worth field start temperature. 13. The method of claim i wherein the microstructure of the region does not recrystallize 0 138621.doc 200944596 14. The method of claim </ RTI> further comprising: bonfire the region wherein tempering comprises heating Zone to - does not exceed the temperature of the processing temperature. 15. The method of claim 1, further comprising: • combining a shell made of tool steel and a core made of dissimilar steel before deforming the region, t establishing the temperature at the processing temperature The region includes establishing at least the shell layer at the processing temperature and deforming at least a portion of the shell layer when the shell layer is at the processing temperature. 16. A tool for use in a machine to modify a defensive member, the tool comprising: 'a member comprising a tool steel, the member having an outer surface, the outer surface defining a configuration to The first portion of the coupling of the machine and a second portion adapted to contact the workpiece and the member includes a first region extending from the outer surface to a depth greater than 1 mm and a region by the first region The outer surface is separated by a second region, the first region comprising a plurality of greater than about 34. The plurality of dies having a mean misorientation angle that is one of the characteristic misorientation angles has an average grain size that is at least 1% less than the average grain size of the second region, and has the second A grain orientation with a plurality of different grains in the region. 17. The tool of claim 16, wherein the average misorientation angle is at least about 40°. 18. The tool of claim 16 wherein the first region is adjacent to the second portion of the outer surface. 19. The implement of claim 16, wherein the microstructure of the first region is not crystallized by further 138621.doc 200944596. 20. The tool of claim 16, wherein the member comprises a shell made of tool steel and a core made of dissimilar steel, the shell having the outer surface defining the first portion and the core forming the At least a portion of the second region. 138621.doc -4-
TW098104717A 2008-02-15 2009-02-13 Method for thermomechanically machining tool steel and tool made of thermo-machined tool steel TWI479025B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US2923608P 2008-02-15 2008-02-15

Publications (2)

Publication Number Publication Date
TW200944596A true TW200944596A (en) 2009-11-01
TWI479025B TWI479025B (en) 2015-04-01

Family

ID=40626593

Family Applications (1)

Application Number Title Priority Date Filing Date
TW098104717A TWI479025B (en) 2008-02-15 2009-02-13 Method for thermomechanically machining tool steel and tool made of thermo-machined tool steel

Country Status (8)

Country Link
EP (1) EP2090383B1 (en)
JP (2) JP6112752B2 (en)
CA (1) CA2654368C (en)
ES (1) ES2554608T3 (en)
MX (2) MX2009001768A (en)
PT (1) PT2090383E (en)
TW (1) TWI479025B (en)
WO (1) WO2009102848A1 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2483120C1 (en) * 2012-05-22 2013-05-27 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Тверской государственный технический университет" Method of hardening built-up high-speed steel
RU2627837C1 (en) * 2016-02-24 2017-08-11 Федеральное государственное бюджетное образовательное учреждение высшего образования "Тверской государственный технический университет" Method for manufacturing weld bimetallic cutting tool
KR101781816B1 (en) * 2017-01-12 2017-09-26 박명석 Composite surface treatment method for improving lifetime of die casting mold
US10682725B2 (en) * 2017-11-30 2020-06-16 The Boeing Company Microstructure refinement methods by mechanical work for additive manufactured materials
CN107952965B (en) * 2017-12-08 2020-09-29 有研工程技术研究院有限公司 Preparation method of plum blossom inner hexagonal punch needle and needle head
JP7185211B2 (en) * 2018-02-07 2022-12-07 住友重機械ハイマテックス株式会社 Tool material manufacturing method and tool material
WO2019180492A1 (en) * 2018-03-23 2019-09-26 Arcelormittal Forged part of bainitic steel and a method of manufacturing thereof
CN109632550B (en) * 2018-12-24 2022-01-14 长安大学 Abrasion performance contrast test device and test method
US11985781B2 (en) 2020-09-23 2024-05-14 Apple Inc. Surface treatment for metallic components
CN112705613B (en) * 2021-02-26 2023-03-31 惠州市诺利星电子科技有限公司 Punching device for electronic product production

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3340102A (en) * 1962-05-15 1967-09-05 Manlabs Inc Metal process and article
US3413166A (en) * 1965-10-15 1968-11-26 Atomic Energy Commission Usa Fine grained steel and process for preparation thereof
US3903761A (en) 1971-09-28 1975-09-09 Phillips Screw Co Process for the manufacture of driver bits
US4170497A (en) * 1977-08-24 1979-10-09 The Regents Of The University Of California High strength, tough alloy steel
US4318733A (en) * 1979-11-19 1982-03-09 Marko Materials, Inc. Tool steels which contain boron and have been processed using a rapid solidification process and method
SE452124B (en) * 1984-06-19 1987-11-16 Kloster Speedsteel Ab SUBJECT TO COMPLETE STATE TOOL MATERIAL AND WELL MANUFACTURED
GB8725668D0 (en) * 1987-11-03 1987-12-09 Reed Tool Co Manufacture of rotary drill bits
US6348752B1 (en) * 1992-04-06 2002-02-19 General Electric Company Integral motor and control
JP3716454B2 (en) * 1995-05-01 2005-11-16 大同特殊鋼株式会社 Manufacturing method of high strength and toughness mold by warm hobbing
JP3563587B2 (en) * 1998-03-10 2004-09-08 新日本製鐵株式会社 Hot width reduction press tool and manufacturing method thereof
JPH11254077A (en) * 1998-03-12 1999-09-21 Sanyo Special Steel Co Ltd Manufacturing method of high strength, high toughness mold
DE19921286A1 (en) * 1999-05-07 2000-11-09 Sms Demag Ag Heat treatment process for the production of surface-hardened long and flat products from unalloyed or low-alloy steels
JP2005314756A (en) * 2004-04-28 2005-11-10 Jfe Steel Kk Machine structural parts
SE0402760L (en) * 2004-11-10 2006-05-09 Sandvik Intellectual Property Cutting tools for metalworking and method of manufacturing cutting tools
PL1985390T3 (en) * 2007-03-23 2011-09-30 Dayton Progress Corp Tools with a thermo-mechanically modified working region and methods of forming such tools

Also Published As

Publication number Publication date
MX2009001768A (en) 2009-08-24
MX368493B (en) 2019-10-04
CA2654368C (en) 2017-10-03
EP2090383A8 (en) 2009-10-14
EP2090383A1 (en) 2009-08-19
CA2654368A1 (en) 2009-08-15
ES2554608T3 (en) 2015-12-22
JP6282545B2 (en) 2018-02-21
JP2014210979A (en) 2014-11-13
WO2009102848A1 (en) 2009-08-20
JP6112752B2 (en) 2017-04-12
JP2009191364A (en) 2009-08-27
PT2090383E (en) 2016-01-26
EP2090383B1 (en) 2015-11-04
TWI479025B (en) 2015-04-01

Similar Documents

Publication Publication Date Title
US9481023B2 (en) Methods of thermo-mechanically processing tool steel and tools made from thermo-mechanically processed tool steels
JP6282545B2 (en) Method for thermomechanical processing of tool steel and tools made from thermomechanically processed tool steel
JP5015050B2 (en) Tool with improved machining area by thermal processing and method for forming such tool
CN101629267B (en) Tool steel and preparation method thereof
CN114682728B (en) Method for making metal ring using beryllium copper alloy and metal ring
CA2403545C (en) Ni based alloy, method for producing the same, and forging die
KR100756077B1 (en) Process for forming ultrafine crystal layer, machine component having ultrafine crystal layer formed by the ultrafine crystal layer forming process, process for producing the machine component, process for forming nano-crystal layer, machine component having nano-crystal layer formed by nano-crystal layer forming process, and process of producing the machinecomponent
JP7766914B2 (en) Manufacturing method for forged heat-treated products
EP1985390B1 (en) Tools with a thermo-mechanically modified working region and methods of forming such tools
Jha et al. Process optimization for high fracture toughness of maraging steel rings formed by mandrel forging
WO2017147504A1 (en) High fluidity iron alloy forming process and articles therefrom
JPS62156203A (en) Production of tool
CN105274444A (en) Steel for cold working tool
Van Tyne Forging of carbon and alloy steels
WO2023129949A1 (en) Method of heat treating a metal part with optional forging
Mochnal Forging of stainless steels
HK1148791B (en) Steel, process for the manufacture of a steel blank and process for the manufacture of a component of the steel
HK1148791A1 (en) Steel, process for the manufacture of a steel blank and process for the manufacture of a component of the steel
PL116046B2 (en) Method of high-temperature thermal-mechanical treatmentof tools made of medium-and high-carbon,high-chromium alloy tool steels

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees