200928062 九、發明說明： 【發明所屬之技術領域】 本發明係提供一種塑膠地磚，尤指一種應用不含氯之塑 膠材質，而具有環保概念之塑膠地磚製造方法。 【先前技術】 按，一般傳統的地磚大多為磁碑，由於磁磚的施工不僅 費時、成本高，且非一般民眾能自行施工（DIY)，因此隨著 時代的進步，市面上便有一種消費者可自行施工之塑膠地碑。 由先前技術可知，一般塑膠地碑的材質大多係為聚氯乙 烯（PVC)，惟由於聚氯乙烯（PVC)含有氯成分，所以被世界 衛生組織（WHO)認定為第三類的致癌物質，並在動物實驗中 被證實可能導致肝、血管腫瘤等癌症發生；其次聚氯乙烯 (PVC)塑膠不易回收，加上燃燒可能產生戴奥辛，因此環保 界亦開始出現禁用聚氯乙烯（PVC)塑膠的聲浪。基於上述原 因，目前塑膠地碑業界亦致力於不含氯之塑膠地碑產品的開 發。 請參閱第一圖所示，其係公告第58〇〇36號『環保地碑』 專利案（以下簡稱習用案），該習用案係一種以不含氣材質所 製成之塑膠地磚，其包括了在上層的印刷層（丄）及下層的 5 200928062 塾底層，兩者互相貼合，其特徵在於：印刷層（工）又包括一 上透明層（1 1 )及-下透明層（丄2 )，彼此互相貼合，且 在下透明層（1 2 )的底面（i 3 )印刷有圖案。 Ο 上述習用案雖於專利範圍及創作說明書+主張：印刷層 及墊底層兩者互械合，叹上翻層及下翻層彼此互相 貼合等技細容，惟實際上目前產轉並無不含氯之瓣材 質之塑膠地碑產品問世。主要原因係非聚氯乙稀（p⑹之塑 膠材質，如聚㈣（PP)等轉其歸分子_於非極性， 且表面的毛細孔幾乎小到沒有，故無法以熱熔或膠黏方式穩 固結合。換言之’由於目前以所謂非聚氯⑽⑽）塑材製 ^之塑膠地磚普遍存在著上叙_層及下層之底部層間結 5之結構強度不佳之情形，形成品質上的-大缺點，而益法 :實大幅推廣，因此如何加強非㈣塑材製成之塑膠地碑其 ，構強度，便成為業者亟思改善之方向。 、 有鑑於此’本發明人乃針對前述習用創作問題深入探討 沐並藉由多年從事相業之研發與製造猶，積極尋求解 私之道’經懒努力州恤， Γ塑膠地磚及其表層之製造方法』，以改善習用二 200928062 【發明内容】 本發月之主要目的，在於解決上述的問題而提供—種『 .讎_及其表層之製造綠』，其齡林含減分之塑膠 材質製成之塑膠地碑，能具有耐用、穩固之結構強度，而能 確實達到健康之環保概念。 緣以達成上述之功效目的，本發明『塑膠地磚及其表層 〇之製造方法』，其係由不含氯成份之_材料製成—底部層、 p刷層’及耐磨層後，再分麟該印獨及耐磨層貼合，構 成j膠地磚具有硫、圖案之表層，而若再於具有耐磨層之 印刷層底面貼合該底部層，_成完整之讎地磚成品。本 發明主要係於該底部層、印刷層及耐磨層彼此相貼合之表面 ’㈣合前先辭-表鱗理辦’使無合面具有提昇附 〇 著度之毛細孔，*輯加該歸㈣貼合成型之結構強度。 上述之表面處理程序依實務上來說，可為一種電暈處理，其 係利用機n將高壓電打在該底部層、印_及耐磨層彼此欲 貼合之二面，而於其表面產生有別於光滑面之毛細孔，令該 底部層、_層及咖層彳纽貼合時能具錢目之結構強度 。再者該耐磨層表面亦可再塗佈一樹脂層，以增加其表面之 耐磨度。藉此可確實將不含氣成份之塑膠材質製成具有穩固 200928062 =質之塑膠地磚’令塑膠地磚能確實具有環保缝，而更能 符合新時代健親念之趨勢献，細提產錢爭性。 有關本發明所_之技術、手段及其功效，_一較佳 實施例並配合圖式詳細說明於後，姉本發明上述之目的、 構造及特徵，當可由此得一深入而具體的瞭解。 【實施方式】 茲為使其能進-步轉本發明之結槪計及技術，謹配 合圖式再予說明於後： 參閱第一〜八圖所示，本發明『塑膠地磚及其表層之製 w方法』其技術應用之標的包含由底部層（2 〇 )、印刷層 (3 0)及耐磨層（4 〇)貼合組成之塑膠地碑（2)，以及 由印刷層（3 〇)及耐磨層（4 〇)貼合構成之塑膠地碑 (2 )具有各式花紋、圖樣之表層。而不論係塑膠地碑（2 ) 或其表層’該底部層（2 0 )、印刷層（3 0 )，以及耐磨層 (4 0 )皆係由不含氣成份之塑膠材質製成，如聚丙烯（pp) ，而本發明實際應用實施例，即以聚丙烯（pp)作為塑膠地 磚（2)之材質，其中： 該底部層（2 〇 )’係位於塑膠地磚（2 )最下層，其背 面即係與欲黏貼之地面結合。 200928062 該印刷層（3 Q )可為透明或非翻，其上可依設計之 需求印刷有各式花紋或圖樣。 該耐磨層（4 ◦) ’係位於塑膠地碍（2 )最上層，且呈 現透明之態樣。 兹再進-步將本發明主要技術之内料述於后； 本發明錄丙烯（PP)歸材料製造成型娜地碑⑵ ❹ 時’係可先貼紋祕表層，即先賴物層（3 Q )及耐 磨層（4 0)貼合後，再與該底部層（2 Q)貼合。如第二 、二圖所示，其技術特徵為：該_層（3⑻及耐磨層 (4 0 )於貼合前，絲於其彼此相互貼合之貼合面（3工 、41)施予一表面處理程序，使其貼合面（3丄、41) 財提昇附著度之毛細孔（5 Q )，而後再於該二貼合面 0( 3 1、4 1)之間塗抹黏合之處理齊卜進而加強其貼合之 構強度。上述表面處理程序依實務上來說，可為一種電晕 處理’亦即利用機器將高壓電打在該印刷層（3 〇)及耐磨 層（4 0)之貼合面（3工、4玉），而於其表面產生有別於 光'月面之毛細孔（5 0 )，令印刷層（3 0 )及耐磨層（4 〇) 相貼合時能具有穩固之結構強度。· 其-欠，如第四、五圖所示，本發明該耐磨層（4 〇 )外 200928062 表面可㈣表©處理程相產生毛細孔（5⑹後，再塗佈 一樹脂層（6 0 )’進而能A幅增加其表面之耐磨度。 請再參閱第六〜七圖，係本發明該底部層（2〇)、印刷 層（3 0)及耐磨層（4〇)貼合之示意圖，當該印刷層 0)及耐磨層（4 Q)先貼合完成後，便可再將上層具 有耐磨層（40)之印刷層（3〇)與該底部層（2〇)貼 〇 合’惟貼合前亦先於該底部層（2 0)及印刷層（3 〇)其 彼此相貼合之貼合面（2 1、32)施予電暈之表面處理程 序使，、貼口面（2 1、3 2 )具有提昇附著度之毛細孔 (5 0 )❿增加其貼合之結構強度。如此便完成塑膠地碑 ⑵成品，此外’如第八圖所示，上述提及該耐磨層（4 〇 ) 表面塗佈讀崎（_，除了可聽顧於該耐4 〇) ◎ 卜亦可於歸地碑（2 )成品完成後再塗佈，而其塗佈 成型之程序，亦與上述相同，不再陳述。 承上述，進-步朗的是，本發明將絲部層（2 〇 )、 印刷層（3 0)及耐磨層（4 0)貼合之技術，除了於二相 貼°之貼合面（31、41)及（21、32)間塗抹黏著 之處理劑外，亦可利用熱溶之方式達成。 據此上述之製程說明，確實可將不含氣成份之塑膠材質 200928062 製成具有穩固品質之塑膠地磚，令歸地磚能確實具有環保 讀’而更能符合新時代健康概念之趨勢潮流，進而提昇其 產業競爭性。 綜上所述，本發明在同類產品中實有其極佳之進步實用 眭同時遍查國0外關於此類結構之技術資料、文獻中亦未 發見有相同的製造工法存在在先，是以，本發明實已具備發 ❹ 明翻要件，纽法提出申請。 上述實施例’僅用以舉例說明本發明’據以在不離本發 月精神之範圍’熟習此項技藝者憑此說明内容而作之各種變 I、修飾與朗，均應包括於本發明之範嘴者。 【圖式簡單說明】 第圖·係習用歸地磚成型之示意圖。 〇 第二圖：係本發明瓣地碑外層之分解示意圖。 第三圖：係本發明塑膠地碑外層之結合示意圖。 第四圖：係本發曰月塑膠地碑外層之另一應用實施例之分解示 意圖。 第五圖：係本發曰月塑膠地碑外層之另一應用實施例之結合示 意圖。 第六圖：係本發明塑膠地磚之分解示意圖。 200928062 第七圖：係本發明塑膠地磚之結合示意圖。 第八圖：係本發明塑膠地磚之另一實施例之結合示意圖。 【主要元件符號說明】 塑膠地磚：（2 ) 底部層（2 0 ) 貼合面（2 1 ) 印刷層：（3 0 ) 貼合面：（3 1、3 2 ) 耐磨層：（4 0 ) 〇 貼合面：（4 1 ) 毛細孔：（5 0 ) 樹脂層：（6 0 )200928062 IX. Description of the invention: [Technical field to which the invention pertains] The present invention provides a plastic floor tile, in particular, a method for manufacturing a plastic floor tile which uses a chlorine-free plastic material and has an environmental protection concept. [Prior Art] According to the general, most traditional floor tiles are magnetic monuments. Because the construction of tiles is not only time-consuming and costly, but also non-general people can build their own (DIY), so with the progress of the times, there is a kind of consumption in the market. Plastic monuments that can be constructed by themselves. According to the prior art, the material of the general plastic monument is mostly polyvinyl chloride (PVC). However, since polyvinyl chloride (PVC) contains chlorine, it is recognized as the third type of carcinogen by the World Health Organization (WHO). It has been confirmed in animal experiments that it may cause cancers such as liver and vascular tumors. Secondly, polyvinyl chloride (PVC) plastics are not easy to recycle, and burning may produce dioxin. Therefore, the environmental protection industry has also begun to ban PVC (PVC) plastics. Sound waves. For the above reasons, the plastic floor industry is also committed to the development of chlorine-free plastic monument products. Please refer to the first figure, which is the "Environmental Landmark" patent case (hereinafter referred to as the "Practical Case"), which is a plastic floor tile made of a gas-free material, including In the upper printing layer (丄) and the lower layer 5 200928062 塾 bottom layer, the two are attached to each other, characterized in that the printing layer (work) further comprises an upper transparent layer (1 1 ) and a lower transparent layer (丄2) ), they are bonded to each other, and a pattern is printed on the bottom surface (i 3 ) of the lower transparent layer (1 2 ). Ο Although the above-mentioned stipulations in the scope of patents and the creation instructions + claim that the printed layer and the underlying layer are mutually commensurate with each other, the sighs and the layers of the layers are attached to each other, but in fact, there is no current production. The plastic inscription product of chlorine-free flap material is available. The main reason is that non-polyvinyl chloride (p(6) plastic material, such as poly (four) (PP), etc., is converted to a molecule--non-polar, and the pores on the surface are almost small, so it cannot be stabilized by hot melt or adhesive. In other words, in view of the fact that the plastic floor tiles of the so-called non-polychlorine (10) (10) plastic material are generally inferior in the structural strength of the bottom layer of the upper layer and the lower layer, the quality of the structure is large, and Yifa: Really promoted greatly, so how to strengthen the plastic monument made of non- (four) plastic materials, its structural strength, has become the direction of the industry to improve. In view of this, the inventor has in-depth discussion on the above-mentioned customary creation issues and has been actively pursuing the idea of unraveling through the research and development and manufacturing of the industry for many years, the lazy hard-working state shirt, the plastic floor tiles and the surface thereof. Manufacturing method" to improve the use of the second two 200928062 [Invention content] The main purpose of this month is to solve the above problems and provide a kind of ". 雠 _ and its surface green manufacturing", the age of the forest with reduced plastic material The made plastic monument can have a durable and stable structural strength, and can truly achieve the concept of healthy environmental protection. In order to achieve the above-mentioned effects, the present invention "manufacturing method of plastic floor tiles and surface layers thereof" is made of a material containing no chlorine component - a bottom layer, a p brush layer and a wear layer, and then divided Lin's printing and wear layer are laminated to form a surface layer of sulfur and pattern, and if the bottom layer is adhered to the bottom of the printed layer with the wear layer, the finished floor tile is finished. The invention mainly relates to the surface of the bottom layer, the printing layer and the wear layer which are in contact with each other' (4) before the first word-table scales to make the non-combined surface have the pores which enhance the degree of the attachment, * The structural strength of the composite (4) composite. The surface treatment program described above may be a corona treatment in which the high voltage electricity is applied to the bottom layer, the printing layer and the wear layer to be bonded to each other on the surface thereof. Produces a capillary hole that is different from the smooth surface, so that the bottom layer, the _ layer and the coffee layer can be combined to have the structural strength of the money. Furthermore, the surface of the wear layer may be further coated with a resin layer to increase the wear resistance of the surface. In this way, the plastic material without gas content can be made into a plastic floor tile with a stable 200928062 = quality, so that the plastic floor tile can have a green seam, and it can better meet the trend of the new era of health and love. Sex. The above-described objects, configurations and features of the present invention will become more apparent from the detailed description of the invention. [Embodiment] In order to enable it to further advance the method and technology of the present invention, it will be further described with reference to the following figures: Referring to Figures 1 to 8, the present invention "plastic floor tile and its surface layer" The method of the "W method" includes a plastic monument (2) composed of a bottom layer (2 〇), a printed layer (30) and a wear layer (4 〇), and a printed layer (3 〇) ) and the wear-resistant layer (4 〇) are laminated to form a plastic monument (2) with various patterns and patterns. Regardless of whether the plastic monument (2) or its surface layer 'the bottom layer (20), the printed layer (30), and the wear layer (40) are made of a plastic material that does not contain gas, such as Polypropylene (pp), and the practical application example of the present invention, that is, polypropylene (pp) is used as the material of the plastic floor tile (2), wherein: the bottom layer (2 〇) is located at the lowermost layer of the plastic floor tile (2). The back side is combined with the ground to be pasted. 200928062 The printed layer (3 Q ) can be transparent or non-turned, and various patterns or patterns can be printed on the design. The wear layer (4 ◦) ′ is located on the uppermost layer of the plastic barrier (2) and is transparent. Further re-introduction of the main technology of the present invention is described later; the present invention records the production of propylene (PP) material into the shape of Nadi monument (2) ❹ when the system can first paste the surface layer, that is, the first layer (3) Q) After the wear layer (40) is bonded, it is bonded to the bottom layer (2Q). As shown in the second and second figures, the technical feature is that the _ layer (3 (8) and the wear-resistant layer (40) are attached to each other before the bonding, and the bonding surfaces (3, 41) Apply a surface treatment procedure to the bonding surface (3丄, 41) to increase the adhesion of the capillary (5 Q), and then apply the bonding between the two bonding surfaces 0 ( 3 1 , 4 1) The treatment process is further enhanced to enhance the bonding strength. The above surface treatment procedure can be a corona treatment in practice, that is, using a machine to apply high voltage electricity to the printing layer (3 〇) and the wear layer ( 4 0) The bonding surface (3 working, 4 jade), and the pores (5 0 ) on the surface which are different from the light 'moon surface, so that the printed layer (30) and the wear layer (4 〇) It can have a firm structural strength when it is attached. · Its - owing, as shown in the fourth and fifth figures, the wear layer (4 〇) of the present invention can be used on the surface of the surface of the surface of the wear layer (4). After that, a resin layer (60) is further coated to further increase the wear resistance of the surface by A. Please refer to the sixth to seventh figures, which are the bottom layer (2〇) and the printed layer (3 0) of the present invention. )and A schematic diagram of the bonding layer (4〇), when the printing layer 0) and the wear layer (4 Q) are first bonded together, the upper layer can be printed with the wear layer (40) (3〇) Applying to the bottom layer (2〇), but also applying the bonding surface (2 1 , 32) to which the bottom layer (20) and the printing layer (3 〇) are attached to each other before bonding. The corona surface treatment program makes the surface of the veneer (2 1 , 3 2 ) with increased adhesion (5 0 ), increasing the structural strength of the bonding. This completes the plastic monument (2) finished product, in addition As shown in the eighth figure, the above mentioned wear layer (4 〇) surface coated with Nagasaki (_, in addition to listening to the resistance of 4 〇) ◎ Bu can also be returned to the monument (2) finished product Recoating, and the procedure of coating and forming thereof is the same as above, and will not be stated. According to the above, in the present invention, the present invention will have a silk layer (2 〇), a printing layer (30) and resistance. The technique of bonding the layer (40) can be achieved by hot-dissolving in addition to the treatment agent applied between the two-phase bonding surface (31, 41) and (21, 32). The above process description It is true that the plastic material 200928062, which contains no gas content, can be made into a plastic tile with a stable quality, so that the floor tile can be truly environmentally friendly, and it can better conform to the trend trend of the new era health concept, thereby enhancing its industrial competitiveness. According to the invention, the invention has excellent progress and practicality in the same kind of products, and at the same time, the technical materials of such structures are not inspected in the country, and the same manufacturing method is not found in the literature. The present invention has been developed and claimed, and the above-mentioned embodiment is merely used to exemplify the present invention, so that it can be used by those skilled in the art without departing from the spirit of the present invention. The various changes I, modifications and langs should be included in the scope of the present invention. [Simple description of the diagram] The figure is a schematic diagram of the formation of the slab. 〇 Second figure: It is an exploded view of the outer layer of the petal monument of the present invention. The third figure is a schematic diagram of the combination of the outer layers of the plastic monument of the present invention. Figure 4: An exploded view of another application embodiment of the outer layer of the plastic monument. Fig. 5 is a schematic view showing another embodiment of the application of the outer layer of the plastic monument. Figure 6 is a schematic exploded view of the plastic floor tile of the present invention. 200928062 The seventh figure is a schematic diagram of the combination of the plastic floor tiles of the present invention. Figure 8 is a schematic view showing a combination of another embodiment of the plastic floor tile of the present invention. [Main component symbol description] Plastic floor tile: (2) Bottom layer (2 0 ) Fitting surface (2 1 ) Printing layer: (3 0 ) Fitting surface: (3 1 , 3 2 ) Wear layer: (4 0 ) 〇 fitting surface: (4 1 ) capillary: (5 0 ) resin layer: (6 0 )