TW200902644A - Ink-jet ink - Google Patents

Abstract

An ink-jet ink for forming thicker polyimide film (no less then 1 μm) by inkjetting one time is provided. This invention is related to an ink-jet ink including: selecting from a silicon compound (A) obtained by a compound (a1) having no less than 2 acid anhydride groups and a monoamine (a2), and a silicon compound (A') obtained by a compound (a1') having an acid anhydride group and a diamine (a2')

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an inkjet ink, relating to a bismuth compound (A) and/or a stone eve for forming an insulating film layer in, for example, electronic component fabrication. An inkjet ink of the compound (A), a polyimide film formed using the inkjet ink, a film substrate on which the polyimide film is formed, and an electronic component including the film substrate. <Prior Art> Polyimine is excellent in heat resistance and electrical insulation, and is therefore widely used in the field of electronic communication [for example, see Japanese Patent Laid-Open Publication No. 2000-039714, Japanese Patent Laid-Open No. 2003-238683 Japanese Patent Laid-Open Publication No. 2004-094118. In the case where polyimine is used as a desired pattern film, it is conventionally to use etching or photosensitive polyimide to form a pattern, and in recent years, a need for formation by inkjet is being studied. The method of patterning a film. A person skilled in the art has proposed various types of inkjet inks, for example, when preparing a polyimide inkjet ink, for example, Japanese Patent Laid-Open Publication No. 2003-213165, Japanese Patent Laid-Open No. Hei. No. 2006-131730 Since the polyimide ink is a relatively high-molecular ink, in order to prepare an ink of the most suitable viscosity, it is necessary to increase the ratio of the solvent and reduce the polyamine content in the ink. As a result, there is a problem that the thickness of the film obtained by the ink jetting is reduced. On the other hand, it is known that if a proline compound (an oxime coupling agent) is used in combination with a cycloolefin resin or a ruthenium resin, it may react with a metal or open a compound of 200902644, so that the film has a close resistance. Improve [for example, the next day, the resistance to weld cracking (soIder crack bulletin.) According to the above-mentioned conditions under the Japanese Patent Special Open No. 2003-105059, it is possible to form a thicker polythene (spray) 1 reading. In the inkjet ink, the inkjet ink of the octagonal octagonal compound (B) containing at least a rich ink and further containing a fermented product (A') is found. Further, (C^^ Congratulations to the inkjet ink and the inkjet ink containing the solvent (D). The present invention k provides an inkjet ink or the like as described below. The inkjet ink of the inkjet ink contains: Obtaining the compound (A) obtained by using the compound (al) having an acid anhydride group equal to or more than the monoamine (a2), and using the compound (ar) having an anthracene acid group and the diamine (a2'). At least one of the hydrazine compounds (A,). /, a [2] as in the above item [1] In the inkjet ink, the compound (al) having two or more acid anhydride groups is represented by the following formula (1), tetracarboxylic dianhydride, and the monoamine (a2) is as follows. a compound represented by the formula (2), [Chem. 16]

(1) R1 H2N—Y—Si—r2

I R3 (2) 200902644 27225pif (In the formula (1), X is a tetravalent organic group having a carbon number of 2 to 100, and in the formula (2), R1, R2 and R3 are hydrogen, a halogen or a monovalent organic group. These may be the same or different, and Y is an organic group having 1 to 20 carbon atoms. [3] The inkjet ink according to [2] above, wherein the tetracarboxylic dianhydride is selected from the group consisting of pyromellitic dianhydride and 3,3',4,4'-diphenyl ketone Carboxylic dianhydride, 2,2',3,3'-diphenyl ketone tetracarboxylic dianhydride, 2,3,3',4'-diphenyl ketone tetracarboxylic dianhydride, 3,3', 4,4'-diphenylphosphonium tetracarboxylic dianhydride, 2,2',3,3'-diphenylsulfone tetracarboxylic dianhydride, 2,3,3',4'-diphenylfluorene Carboxylic dianhydride, 3,3',4,4'-diphenyl ether tetracarboxylic dianhydride, 2,2',3,3|-diphenyl ether tetracarboxylic dianhydride, 2,3,3 ',4'-diphenyl ether tetracarboxylic dianhydride, 2,2-[bis(3,4-dicarboxyphenyl)]hexafluoropropane dianhydride, ethylene glycol bis(trimellitic anhydride), Cyclobutane tetracarboxylic dianhydride, decylcyclobutane tetracarboxylic dianhydride, cyclopentane tetracarboxylic dianhydride, 1,2,4,5-cyclohexanetetracarboxylic dianhydride, ethane tetracarboxylic acid One or more of the group consisting of acid dianhydride and butane tetracarboxylic dianhydride selected from the group consisting of p-aminophenyltrimethoxydecane and p-aminophenyltriethoxydecane , m-aminophenyl trimethoxy decane, m-aminophenyl triethoxy stone shed, One or more of the group consisting of aminopropyltrimethoxysilane and aminopropyltriethoxylate. [4] The inkjet ink according to [1], wherein the ruthenium compound (4) is a phthalic acid (a) represented by the following formula (3), [Chem. 17] (3) 200902644 〇〇R1 H〇_

H R2—Si—Y—NI R3 —NH—Y—R 2 R 3 ΌΗ 〇〇 (In the formula (3), X is a tetravalent organic group having a carbon number of 2 to 100, and R 1 , R 2 and R 3 are hydrogen, Halogen or a monovalent organic group, which may be the same or different, and Y is an organic group having 1 to 20 carbon atoms. [5] The ink for inkjet according to the above [4], wherein the proline is a hydrazine represented by the following formula (4-1), (4-2) or (4-3) Proline, [Chem. 18] 〇〇

3 I R3 R1 (4-1) R2-Si—(H2C)— I R3

H〇〇C

Ri NH-(CH2)-Si-R2

, COOH R3 (4-2) -Si—^ R3

R2-Si-(H2C)-HN

R1 I NH-(CH2)-Si-R2

HOOC

C〇〇H R3 (4-3) 200902644 (In the formula (4-1), (4-2) or (4-3), at least one of R], R2 and R contains a carbon number of 1 to 2 〇 The alkoxy group, a is 1 to an integer). [6] The inkjet ink according to any one of [1] to [5] wherein the compound (al) having two or more acid anhydride groups and the above monoamine (a2) The ratio is 1 mole: 0.5 mole to 8.0 mole. [7] The inkjet ink according to any one of the above [1], wherein the compound (al) having one acid anhydride group is represented by the following formula (1'). The carboxylic anhydride represented by the above diamine (a2') is a diamine represented by the following formula (2,), [Chem. 19] 〇

(In the formula (Γ), R1, R2 and R3 are hydrogen, halogen or a monovalent organic group, which may be the same or different, Y1 is an organic group having a carbon number of 1 to 20, and in the formula (2'), X · A divalent organic group having a carbon number of 2 to 100). [8] The inkjet ink according to the above [7] wherein the above phthalic anhydride is selected from the group consisting of p-(trimethoxydecyl)phenyl succinic anhydride and p-(triethoxy oxalate)phenyl Succinic anhydride, m-(tridecyloxyalkyl)phenylsuccinic acid, m-(triethoxydecyl)phenyl succinic anhydride, trimethoxydecyl propyl succinic anhydride, and triethoxy decyl propyl One or more of the oxime groups composed of succinic anhydride, 200902644 The above diamine is selected from the group consisting of p-diamine, m-diamine, p-diphenylammonium, 4.4-monoaminodiphenylcarbene; 4,4'-diamino-1,2-diphenylethane, 4,4'-diamino-1,3-diphenylpropane, 2,2-bis(4-aminophenyl) Propane, bis(4-amino-3-methylphenyl)methane, 1,2-bis-(4-amino-3-methylphenyl)ethane, bis(4-amino-2-indenyl) Phenyl)methane, iota, 2-bis(4-amino-2-methylphenyl) ethidium, 4,4'-diaminodiphenyl ether, 3,3'-diaminodiphenyl Ether, 4,4 fluorene-amine-based stone, 4,4f-diaminodiphenylthioate, 4,4·-diaminodiphenyl ketone, 4,4-aminodiphenyl _2,2'_丙烧, ι,4·diaminocyclohexane, 4.4-diaminodicyclohexylmethane, iota, 4-bis[(4-aminophenyl)methyl]benzene, 1,4-bis(4-amine Phenyloxy)benzene, iota, bis(4-aminophenoxy) stupid, 2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2_double [4_(4_Aminophenyloxy)phenyl] fluoropropane, bis[4-(4-aminophenoxy)phenyl]diphenyl]biphenyl, U-bis(tetra)·amine-based Na, aminobenzyl) phenyl] hexane, 5-phenylindole 4,3. diamino stupid, 5-[4-(4-alkylcyclohexyl)phenyl]indolyl-1,3-diamine Benzene, 5-[4-(4-(4-alkylcyclohexyl)phenyl]indenyl-U-diaminobenzene, 5-[((alkylcyclohexyl, hexyl)phenyl]fluorenyl) Diaminobenzene, ^^4♦aminophenoxy)phenyl]cyclohexane, 1,1-bis[4-(4-aminophenoxy)phenyl]_4-alkylcyclohexene 1 , 1-bis[4-(4-aminobenzyl)phenyl]cyclohexene, I, bis['(A•aminobenzyl)phenyl]_4-alkylcyclohexane, 1, One or more of the groups consisting of 3-bis(3-aminopropyl)-tetramethyldioxane. [9] Any of the above items [1] to [6] The ink for the nozzle ink, wherein The above hydrazine compound (A,) is a proline (A,) represented by the following formula (3,), 10 200902644 27225pif [20] Q Η H 〇 R2-., a Y<~C-N —X,一N—C—- r3 COOH / H〇〇c -Si—R2 I R3 (3,) Halogen or an organic group of 20 valence,

(In the formula (3), R, R2 and R3 are hydrogen, and these may be the same or different, and γ is an organic group having a carbon number of X 2 to 1 Å). The inkjet ink according to the above [9], wherein the valine acid (A,) is a glycine represented by the following formula or (4'-5) (eight, ), [Chem. 21] 11 200902644

R

R

(4'-4) (CH2); early i-R: 0 D (4,-5) (4.-3) R1 R2-Si-(H2C) R3

R3 H〇y ^ (in the formula (4'-l), (4'-2), (4'-3), (4,_4) or (4,_5', at least R1, R2 and R3 An alkyl group having a carbon number, R_ of the formula (4'-3) is an organic group having a carbon number of 2 to 30, and the formula (4,_4 of R is oxygen or the number of rabbits is 1 j^·20) The ink jet ink according to any one of the above items [1] to [1], wherein the compound having one acid anhydride group (al, And the ratio of the above-mentioned two 12 200902644 27225pif amine (a2') is 0.5 mol to 8. 〇 Moule: 1 mol. [12] As described in any one of the above items [1] to [11] The inkjet ink according to the above [12], wherein the polymer compound (Β) is selected from the group consisting of the inkjet ink. [14] The inkjet ink according to the above [12] or [13], wherein the south molecular compound (B) of f' The weight average molecular weight is 1,000 to 5,000 〇 [15] as described in any one of the above [n item to [14] Inkjet ink, wherein the inkjet ink further contains an alkenyl group, the inkjet ink according to the above [15], wherein the alkenyl group is substituted. Nadick acid imide (C) is an alkenyl-substituted nadic acid bismuth formed by reacting a monoamine, diamine, triamine or tetraamine with an alkenyl-substituted nadic anhydride represented by the following formula (5'). Imine, 1 [22]

In the formula (5), R1 and R2 are each independently hydrogen, an alkyl group having a carbon number of j to 12, an alkenyl group having 3 to 6 carbon atoms, a cycloalkyl group having 5 to 8 carbon atoms, and an aryl group having 6 to 12 carbon atoms. Or any of the benzyl groups. [17] The inkjet ink according to [15] or [16] above, wherein the dilute-substituted nadic acid st imine (c) in the above-mentioned formula 2009- s. Compound, [Chem. 23]

In the formula (5), R) and R2 are each independently hydrogen, an alkyl group having a carbon number, an alkenyl group having a carbon number of 3 to fluorene, a cycloalkyl group having 5 to 8 carbon atoms, an aryl group having 6 to 12 carbon atoms or benzyl group. Any one of the groups, η is an integer of 1 to 4, * when η = 1, R3 in the formula (5) is hydrogen, an alkyl group having 1 to 12 carbon atoms, a hydroxyalkyl group having 1 to 12 carbon atoms, carbon a 5 to 8 cycloalkyl group, an aryl group having a carbon number of 6 to 12, a benzyl group, _{(CqH2q)〇t(CrH2rO)uCsH2sX} (wherein q, Γ, s are independently selected from 2 to 6) An integer, 丨 is an integer of 〇 or 丨, an integer of u ^ 1 3〇, X is hydrogen or hydroxy), represented by polyoxyalkylene alkane = -(R)a-C6H4-R4 (its towel, a represents 〇 or An integer of J, R represents = an alkylene group of 1 to 4, R4 represents hydrogen or an alkyl group having 1 to 4 carbon atoms, and a group of t groups, C6H4-T-C6H5 {where T is -〇^ _, _C(CH3)2, a group represented by aromatic s or s〇2-l, or one to three hydrogen permeans bonded to a straight line on the square of the groups Substituted group, alkyl Hi, formula, r3 in (5) is an alkylene group having a carbon number of 2 to 20 {sub-substitution, arpeggio mutual = any methylene group adjacent to or may be -CH=CH_ 5 ^ 8 Select 2~6|九马_ (where q, r, S are the independent choices of 't is 〇 or an integer of 1, u is 1~3〇 of the whole 14 200902644 number) a polyoxyalkylene, an arylene group having a carbon number of 6 to 12, _(R)a-C6H4-R5- (where a is an integer of 0 or 1, and r and R5 are each independently a carbon number of 1 to 4; a group represented by a sub-alkyl group, consisting of -C6H4-T-C6H4-, -C6H4_T-C6H4-T-C6H4- or -C6H4-T'-C6H4-T-C6H4-T'-C6H4- {where T Is a single bond, an alkylene group having 1 to 6 carbon atoms, -C(CH3)2-, -C(CF3)2-, -CO-, _〇_, -OC6H4C(CH3)2C6H40-, -S- or -S02-, Τ' is -CH2- or a group represented by the group, or a group of -3 hydrogen-substituted groups which are directly bonded to the aromatic ring of the groups, the following formula (diwax) The group represented by the group represented by the following formula (6-2), in the formula (6_1;), χ is independently an integer of j 6 , and y is an integer of 1 to 7 ,, [Chem. 24]

When n==3, R3 in the formula (5) is a group represented by the group (7_1) represented by the following formula or two oxime) 15 200902644

(7-2) In the formula (7-1), 'R is hydrogen, fluorine, chlorine,_0H, _〇CF3, _〇Cf2H, -CF3, -CF2H, -CFH2, -OCF2CF2H, -OCF2CFHCF3, or carbon number 1. In the alkyl group of ～10, / in the formula (7-1) and the formula (7-2), R4, R5 and R6 are each independently a single bond, a trans-1,4-cyclohexylene group, and a 1,3-dioxin. _2,5-diyl, 1,4-phenylene, fluorene-substituted 1,4-phenylene or a carbon number 1 to a sub-alkyl group, any sub-substrate in the sub-alkyl group The methyl group may be substituted by _〇_ or _CH=CH_, and any hydrazine may be substituted by fluorine. When n=4, R3 in the formula (5) is a group represented by the following formula (8), [Chem. 26] R\ /R4

In the formula (8), R4, R5, r6 and sizing 7 are each independently a single bond, a trans-y-hexyl group, a 1,3-dioxane-2,5-diyl group, a 1,4-phenylene group, a hydrogen group. a 1,4-phenylene group substituted by fluorine or an alkylene group having a carbon number of 丨~., any methylene group in the alkylene group which is not adjacent to each other may be substituted by -0- or -CH=CH-, any Hydrogen can be replaced by fluorine. [18] The ink for inkjet according to [17] above, wherein n is 2. [19] The ink for inkjet according to [π] above, wherein ^ is 2, and R in the formula (5) is an alkylene group having 2 to 15 carbon atoms; mutual phase in the alkylene group 16 200902644 27225pif Any methylene group not adjacent may be substituted by 〇· or _CH=CH-, and any hydrogen may be taken by fluorine /&lt;}, _(R)a_C6H4_R5吖, and &amp; is an integer of 〇 or i, The group represented by R and R are each independently an alkylene group having a carbon number of 〜4, and is composed of -QH4-T-C6H4_, -c6h4-t-c6h4-t-c6h4- or -C6H4-T'-C6H4- T-C6H4-T'-C6H4- {wherein, butyl is a single bond, _ch2_, -C(CH3)2- &gt; -C(CF3)2-^-CO-^-o-. -0C6H4C(CH3)2C6H40 - &gt; _s- or -SCV, T, is the group represented by _CH2_ or _0_}. [2] The ink for inkjet according to the above [17], wherein R and r2 in the formula (5) are each independently hydrogen or an alkyl group having a carbon number of 1 to 6 η is 2, 5) R3 is an alkylene group having 2 to 15 carbon atoms. Any methylene group in the alkylene group which is not adjacent to each other may be substituted by _〇_ or _CH=CH-'any hydrogen may be substituted. (6)) a group represented by the formula, a group represented by the formula (6-2), a group represented by the formula (6-3), a group represented by the formula (6-4), or a group represented by the formula (6-5). [化27] 200902644

(6-1)

Me I Si-O Me Me I Si- I Me

(6-2)

(64) (6-5) In the formula (6-1), X is independently an integer of 1 to 6, and y is an integer formula (6-3) of i to 7〇 and (6-5), and R is An organic group comprising -CH2-, -CH2CH2-, -Ο-, -C(CH3)2-, -C(CF3)2-, -S02_, wherein 'X is -CH2- in the formula (6-5) , -〇 - the organic base. [21] The ink for inkjet according to [17] above, wherein R1 and R2 in the formula (5) are each independently hydrogen or; ε is a burning group of 1 to 6 carbon; and η is 3' ( 5) R3 is expressed by the formula (7^), the formula or the formula (7-2-2), 18 200902644 27225pif [28]

(7-1-1)

, r5wr4

/N , R6 (7-2-2) ^ , /-丄-1 y τ '丄, 尽, v The last formula (7-2-2) 'R4, R5, R6 are independent of 1, 2 - ethylene 1,4-butylene. [R] [22] The inkjet ink according to the above [I7], wherein the furnace (5) and R2 are independently hydrogen or η, and η is 4, and the rule 3 in the formula (5) is: 6 alkyl, [Chemical 29] Formula (8-1), 19 200902644

[23] The ink for inkjet according to the above [17], wherein the ink for inkjet contains an alkenyl group selected from the group consisting of n-substituted nadic acid yttrium imide (c) and η of 2 Replacing at least two of Nadick's yttrium imine (C), η of 3 alkenyl substituted nano-gram acid-imine (C), and 4 4 alkenyl-substituted nadic acid-based imine (c) Alkenyl substituted nadic acid ylide (c). [24] The inkjet ink according to the above [17], wherein the inkjet ink contains at least two kinds of alkenyl groups substituted with nadic acid ylide (c): R1 in the formula (5) And R2 is independently hydrogen or an alkyl group having a carbon number of 66, and R3 in the formula (5) is an alkyl group having 1 to 12 carbon atoms (n=1) and an aryl group having 6 to 12 carbon atoms (n=r 1), _(CH2) pair (n = 2, p is an integer of 6 to 12), a group represented by the formula (6-1-1), a group represented by the formula (6-2), and a formula (6- 3-1) the group represented by the formula, the group represented by the formula (6-4), the group represented by the formula (6J-D, the group represented by the formula (74-2), and the group represented by the formula a group represented by a group, &lt; (7-2_1), a group represented by the formula (7_2_3), and a group represented by the formula (8-1), 20 200902644 27225pif [Chem. 30]

Me

Me -CH. -S i-〇—Si—(cH2'

Me

Me

H3C\ /CH2—H3C>J^CH3(6-2) n=2

21 200902644 Further, the ink for inkjet of the present invention may be the following ink. The inkjet ink according to the above [17], wherein the inkjet ink contains at least one of the following alkenyl-substituted nadic acid ylides (c): η is 1' in the formula (5) a cyclyl group having a carbon number i to l2, a cycloalkyl group having 5 to 8 carbon atoms, an aryl group having 6 to 12 carbon atoms, a benzyl group, :{(CqH2q)〇t(CrH2r〇)ucsH2s+1} (the towel thereof) , q, r, s are independent integers of 2 to 6 integers, t is an integer of 〇 or }, u is 】 】 】 】 】 】 】 】 ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ ～ Wherein, a represents an integer of 0 or 1, R represents a group represented by a sub-alkyl group of Wei 1 to 4, an alkyl group having hydrogen or a carbon number of 1 to 4, or -C6H4-T-C6H5 (the towel thereof, τ is a group represented by the term, _Cd〇, _s_ or S〇2·); and a rare group in which the n is 2 is substituted for the nadic acid ylide (c). Further, the ink for inkjet of the present invention may be the following ink. A. The ink for inkjet according to the above item [17], wherein the inkjet ink 3, "to the following thin base is substituted for Nadick-imine (C): R and R of Formula 5, respectively Independently hydrogen or an alkyl group having a carbon number of 6~6, n in the formula (5), RJ is a fluorenyl group having 1 to 12 carbon atoms, a carbonic acid group having 5 to 8 carbon atoms, an aryl group having 6 to 12 carbon atoms, Or a thiol group in which η is 2 is substituted for the nadic acid-based imine (6). Further, the ink for inkjet according to the present invention is the ink described below. Ink, wherein the inkjet ink 3 has the following alkenyl-substituted N-acrylic acid-imine (6): wherein R and R2 are independently hydrogen or carbon number 1 to 6 respectively. The alkyl group in the formula (5) wherein R is a carbon number of 1 to 12 or an aryl group having 6 to 12 carbon atoms; and at least one of the following alkenyl substituted nadic acid ylides (c) R1 and R2 in the formula (5) are each independently hydrogen or an alkyl group having a carbon number of i to 6, 2, and R3 in the formula (5) is -(CH2)6-, and the above formula (6-3) -1 ) a group represented by the group represented by the above formula (6-4). [25] The inkjet ink according to any one of [1], wherein the inkjet ink further contains a solvent (D). [26] The inkjet according to the above [25] Ink, wherein the solvent is selected from the group consisting of lactic acid ethyl acetate, ethanol, ethylene glycol, propylene glycol, glycerin, diethylene glycol dioxime ether, diethylene glycol diethylene glycol, diethylene glycol decyl ethyl ether, diethyl Glycol monoethylidene (tetra), ethylene glycol monotop, ethylene diether acetate vinegar, propylene glycol monoterpene (tetra) _, 3 methoxy propionic acid, gt, ethoxy propionate, cyclohexanone and r - Ding vinegar, one kind

= Ink inks as in the above items _ to _], wherein the above-mentioned zebra chemical (A) and the above ruthenium compound (A,) are 99 parts by weight relative to the ink of the ink. The total content is 1 part by weight to [28] as in the above [nth item to [26] ^ ink rf in the mouth ink relative to TM: two things (A) and the above dream compound (A,) &lt; parts by weight ~ 80 parts by weight. The ink for inkjet according to any one of the items [1] to [26], wherein the above-mentioned stone is combined with 100 parts by weight of the ink for nozzle ink, and The total content of the above-mentioned Wei compound (A,) is from 22 parts by weight to 70% by weight. (4) an imine film or a patterned faceted amine film, and the polycondensation or the light absorption is obtained by the following method: by the inkjet f cloth method, coating the above items (1) to [29] After forming a coating film with the ink for ink, the coating film is cured to form a polyimide film. [31], the method of forming the side of the material or the surface of the pattern is as follows: by the inkjet coating method, coating the inkjet as described in the item [2 9] The ink forms a coating, a coating, and a process for curing the coating. , * [32 kinds of film substrate, which has a poly-amine film or a pattern, a film, which is formed by the method described in the above [31]. On the substrate. The substrate of the electronic component having the film as described in the above item [Effect of the Invention] The inkjet ink of the preferred embodiment of the present invention can be used right to form a polyimide film having a thick film thickness. . X, a poly-light amine film formed by the ink-based ink of W-shaped and % ink on the first day, for example, has high electrical insulation, thereby improving the reliability and yield of the electronic component. The above and other objects, features, and advantages of the present invention will become more apparent and understood. The invention provides an inkjet ink containing a ruthenium compound (A) and/or a ruthenium compound j A'), a method for forming a polyimide film using the ink, etc. Further, the ink for inkjet of the present invention may be colorless. The ink for ink jets is an inkjet ink containing at least one cerium compound (A) and/or at least one cerium compound (Αι), and further contains a high score.

The inkjet ink of the sub-compound (B), the inkjet ink containing an alkenyl group substituted with nadicimide (C), and the inkjet ink of (D). The compound (4) can be obtained by using at least a compound (4) having an acid anhydride group or more and a monoamine (a2), for example, a product obtained by reacting (al) with (a2). ^ For example, a compound which can form a salt with (F2) and (a2), a compound (ai) having an acid anhydride group of 2 or more and a compound which can be obtained by using (4), is not comparable to the upper axis. a Further, in the ruthenium compound (A), the acid anhydride group compound (al), π / has A equal to 2 initial U1), may be derived from the monoamine (a2), derived from (al) Both with (8). In the following detailed description, the compound (8) which is obtained by the dream derived from the caramine U2) and which is equal to two of the linings (8) has the case of Shi Xi = the Japanese patent special opening 61 fun 285 The compound disclosed in Japanese Laid-Open Patent Publication No. Hei No. Hei-5-271245, or Japanese Patent Laid-Open No. Hei. Further, the oxime compound (A1) can be obtained by using at least the compound ir) of i + and the diamine (4): a product obtained by reacting an acid anhydride group with (a2·) (proline) (8), such that (a1') may be a compound in which (al') forms a salt with (a2'), as long as, for example, an acid anhydride group-containing compound (al') and a diamine (a2i) are available for use in the stone. The case of having one is not limited to the above examples. The compound of Shixi compound, and the compound of Shishi compound (A'), may be derived from a compound (al), which may be derived from a diamine (a2,). , in the following detailed description, in the detailed description below, the use of two or two "1," one anhydride group of the compound (1), the stone eve to obtain the stone 化 化 ^ ^ U2) has an example of a diarrhea, and examples thereof include a oxane-based diamine represented by the following. Formula (XV) 1_„Montmoral &amp; Aminate = Day = Astaxantine (A) contained in inkjet ink Amine it: Compound (al) equal to 2 acid anhydride groups:

However, it is not limited to the compound of A (3), and (4) the above-mentioned shape (4)), (4-2) of the chemical represented by the formula (4), and the spray of the present invention. The field can be obtained by using at least a phthalic acid (A) which is contained in the ink for P, and can be obtained by using the following formula (H) and diamine &lt; clothing method, but is not limited thereto. The proline acid obtained by the method of 200902644. The proline acid (A') may, for example, be a compound represented by the above formula (3'), preferably a compound of the above formula (4, -1), (4, -2), (4-3) or ( 4'-4) The compound represented. The valeric acid (A) which can be used in the present invention to obtain the lysine (A) and the valine (A') is preferably 2 or more with respect to 1 mol. The acid anhydride group-containing compound (al) is obtained by reacting with 〇5 mol to 8.0 mol of monoamine (a2). Further, it is further preferably obtained by reacting a compound (al)' having an acid anhydride group of 2 mol or more with 1 mol of monoamine (a2). More preferably, ruthenium is obtained by reacting with a compound of U1) having 1 or more acid needle groups of 1 mol, and L5 mol to 2.5 mol of monoamine (a2). Further, the proline (A,) which can be used in the present invention is preferably a compound having an acid anhydride group with respect to 1 mol of the diamine (a2')' and 0.5 mol to 8 mol%. (al,) obtained by reaction. Again, the better is relative

Used to obtain (4) New (A) and (4) Amino acids of the present invention

And valine acid (A,) are not limited, for example, ''ethylene glycol methyl ethyl scale, 200902644 diethylene glycol monoethyl ether acetate, ethylene glycol acetaminoacetate, 3- Methoxypropionate, 3, propylene glycol monohexyl ruthenium, r-butyrolactone, N-m-based acid, guanidine, and the like. And Ν, Ν-dimethyl ethane in the above solvent, if _ 0-methyl propionic acid methyl vinegar, ring (10), diacetic acid vinegar ' 3-methoxymethyl ether and 7 ^ butyrolactone, then It can be dreamed of ^ earth ether, diethylene glycol dihydrate, so it is better. The clothes are made of ink which is less damaged to the ink jet head. The reaction solvents may be a mixed solvent of #. Further, in addition to the above, two or more solvents are used. In addition to the net training, it is also possible to mix and use the combined weight fraction of the acid anhydride group of two or more substances, or the threat: ten Γ 0 parts by weight 'to use 100 parts by weight or more, use 100 parts by weight or more' Since it is carried out smoothly, it is preferable that the order of the addition of the reaction raw material to the reaction system is not particularly limited, that is, in the case of 石10 in the case of the ceramide (A), any of the following methods may be used. 4 * a method of simultaneously adding a compound (al ) having two or more acid anhydride groups to a reaction solvent with a monoamine (10); and dissolving the monoamine (a2) in a reaction solvent, and adding an acid needle having a ratio of equal to or greater than: The method of adding a monoamine (a2) to a compound (al) having an acid anhydride group of two or more is used. - Further, for the proline (A1), a method of the following method can be used: a compound having one acid anhydride group (al,) and a diamine (a2,), =^ to a reaction solvent The method of adding a diamine (f), a compound having an acid anhydride group (al,), and a method of adding a diamine (a2,) to a compound (10) having an acid liver group; If you know that (4) aminic acid (Α) is used together with epoxy and _lipid, then == agent, react with metal or form a mismatch to improve the film's performance and improve weld resistance. In addition, for Shi Xi, J predicts that if it is used together with epoxy wax and turning fat, ^ acts as a bismuth coupling agent, and an anti-rock material is formed with the metal, so that the adhesion of the film is improved and the welding resistance is improved. Forming '.曰 Further, the present invention has been studied with difficulty = (A) is a solid product (polyimide) which can be hydrolyzed by heating and dehydrated to make an amine imine bond; Γ (tetra) Amine acid "') is also available by heating: = = = = = solid product (polyimide) "solid poly = 4 =: combined with the previous linear heat, the pores Or ii 29 200902644 or a matrix resin of a laminate material with excellent properties. 1.3 for the long-term composition of the succinic acid (A) and the scorpion scorpion fA1), the compound having the acid needle group of 2 or more acids which can be used to obtain the valine acid (A) (al) is explained with the monoamine (a2). Further, a compound (al') having one anhydride group and a diamine (a2') which can be used to obtain valeric acid (A') will be described. (1) The compound (al) having an acid anhydride group of 2 or more, which is used in the present invention, may be exemplified by the above-mentioned compound (1). Acid dianhydride. Specific examples of the compound U1) having two or more acid anhydride groups used in the present invention include styrene-maleic anhydride copolymer, methacrylic acid, and cis-tau A copolymer of a radically polymerizable monomer having an acid anhydride group and another free-filable monomer, or a tetracarboxylic dianhydride or the like. Examples of the tetracarboxylic dianhydride include: 2,2,3,3,-di-p-stylene-tetracarboxylic acid-anhydride, 2,3,3',4'-di-p-propyl ketone, and 2,2 ,,3,3,-diphenyl-tetrakis(tetra) dianhydride, 2,3,3',4,•diphenylphosphonium sulphate, 2,2',3,3'-diphenyl ether Four rebel acid two Xuan, 2,3,3,,4,_diphenyl bond tetracarboxylic dianhydride, ethylene glycol double (p-benzoic acid Xuan vinegar), E-burning four-wet acid two needles, 4_( 2,5_ dihydrotetrahydrofuran-3-yl)-1,2,3,4-tetrahydronaphthalene], 2_di-acid acid needle, 5_(2,5-dioxotetrahydrotetrahydrocarbyl)_3_ The thiol_3_cyclohexene# thief anhydride is specifically a tetracarboxylic dianhydride such as a compound represented by the following formula (M·) to (bU73). 30 200902644 [Chem. 31]

[化32] 31 200902644 b1-15 b1-14 b1-16

B1-17

B1-18 b1-19 f

B1-21 o o

B1-20

B1-24 b1-23

B1-25

32 200902644 [Chem. 33]

B1-27 b1-28 b1-29

B1-34 〇 〇

[化34] 33 200902644 b1-35 Ο 〇

B1-36o 〇 li Ύ 久Ύ 八v丫丫/' J 〇 L. ^ P Γ 〇 〇

B1-43 b1-44 c

B1-42

B1-45 〇 l &gt; b 〇

Ω η Ο O

B1-50

34 200902644 27225pif [化 35] b1-51 b1-52 b1-53

B1-54 b1-55

B1-56 〇

B1-60 b1-61 b1-62

B1-63 b1-64 〇 /P °^IX X^° 〇 0 35 200902644 [Chem. 36]

B1-72

In the above specific order of the compound having two or more acid anhydrides, the styrene-maleic anhydride copolymer, from the formula (bl_i), (bl_5) (bl-6Hbl-7Hbl-8) Kbl-9) ^(bl-14)&gt;(The compound represented by bM8Hbl.20 has high solubility in a solvent, and water is preferred. Further, 'transparency according to inkjet ink is particularly good in this case. The reverse is sometimes required Η 疋 using styrene-cis-butyl bismuth 36 200902644 27225pif 轩 copolymer, from the formula (bl-6), (bl-7), (bl_8), (bl outside (Μ_14) (bl-18), etc. The compound represented by π and 'the above-mentioned job' has the acid anhydride group of the two cut-offs, and can be used alone or in combination of two or more. L3 (2) Monoamine The monoamine (a2) used in the above-mentioned general formula (2) is exemplified by the above formula (2). (' The monoamine (a2) used in the present invention is not particularly limited, and specific examples thereof For example, 3-aminopropyltrimethoxydecane, 3-aminopropyltriethoxysulfate, 3-aminopropylmethyldimethoxycarbazide, 3-aminopropylmethyl Diethoxy矽, 4-aminobutyltrimethoxy decane, 4-aminobutyl triethoxy decane, 4-aminobutyl dimethyl diethoxy decane, p-aminophenyl trimethoxy decane, Aminophenyl triethoxy decane, p-aminophenylmethyl monomethoxy decane, p-aminophenyl methyl diethoxy oxime, m-aminophenyl methoxy decane, m-amino group Phenyltriethoxydecane, m-aminophenylmethyldiethoxydecane, etc. / v Among the above monoamines, in terms of excellent durability of the obtained film, p-aminobenzene is preferred. Trimethoxy decane, p-aminophenyl triethoxy sylvestre, m-aminophenyl trimethoxy decane, m-aminophenyl triethoxy oxime, 3-aminopropyl tridecyloxy The decane and the 3-aminopropyltriethoxysulfonate are particularly preferably 3-aminopropyltriethoxydecane. These monoamines may be used alone or in combination of two or more. ^1X3) A compound having one phthalic anhydride group (an 37 200902644 The compound (al) having one acid anhydride group used in the present invention, and the above formula (1') can be cited. The carboxylic anhydride represented by the present invention is not particularly limited as long as the compound (al) having one acid anhydride group used, and specific examples thereof include trimethoxydecylpropyl succinic anhydride and triethoxy decylpropyl group. Succinic anhydride, methyl dimethoxydecyl succinic anhydride, decyl diethoxy decyl propyl succinic anhydride, trimethoxy decyl butyl succinic anhydride, triethoxy decyl butyl succinic anhydride, Methyldiethoxydecyl butyl succinic anhydride, p-(trimethoxydecyl)phenyl succinic anhydride, p-(triethoxydecyl)phenyl succinic anhydride, p-(methyl-methoxy oxalate) Phenylboroic anhydride, p-(methyldiethoxycarbenyl)phenylsuccinic anhydride, m-(trimethoxydecyl)succinic succinic anhydride, m-(diethoxy-stone) Base glass station anhydride, m-(methyldiethoxy oxalate) phenyl succinic anhydride, and the like. Among the above compounds, in terms of excellent durability of the obtained film, p-(trimethoxydecylalkyl)phenylsuccinic anhydride, p-(triethoxydecyl)phenylsuccinic anhydride, and (trimethoxydecyl)phenyl succinic anhydride, m-(triethoxydecyl)phenyl succinic anhydride, tridecyloxy decyl succinic anhydride, and triethoxy decyl propyl succinic anhydride: especially Preferred is triethoxydecyl propyl succinic anhydride. These compounds having one acid anhydride group may be used singly or in combination of two or more kinds. L3 (4) Diamine The "fee ( a2 ) ' used in the present invention may, for example, be a diamine represented by the above formula (^,). 38 200902644 The diamine (a2') used in the present invention is not particularly limited as long as it has two amine groups, and examples thereof include p-phenylenediamine, m-diphenylamine, p-diphenylammonium diamine, and 4, 4'-Diaminodiphenylnonane, 4,4匕diamino-1,2-diphenylethene, 4,4'-diamino-1,3-diphenylpropane, 2 , 2-bis(4-aminophenyl)propane, bis(4-amino-3-methylphenyl)decane, 1,2-bis-(4-amino-3-methylphenyl)乙院, bis(4-amino-2-methylphenyl) oxime, 1,2-bis-(4-amino-2-mercaptophenyl) ethene, 4,4'-diamine Diphenyl ether, 3,3'-diaminodiphenyl ether, 4,4'-diaminodiphenyl sulfonium, 4,4'-diaminodiphenyl sulfide, 4,4,-di Amino-based, benzyl, 4,4'-diaminodiphenyl-2,2'-propan, 1,4-diaminocyclohexane, 4,4'-diaminodicyclohexyl Burned, i, 4_bis[(4-aminophenyl)indolyl] benzene, 1,4-bis(4-aminophenoxy)benzene, iota, 3-bis(4-aminophenyloxy) Stupid, 2,2-bis[4-(4-aminophenoxy)phenyl]propane, 2,2-bis[4-(4-aminophenoxy)phenyl]fluoropropane, double [4] -(4_Aminophenoxy)phenyl]indole, bis[4_(4-aminobenzene) Base)]biphenyl, 1,3-bis[4-(4-aminobenzyl)phenyl]propane, bis[4-(4-aminobenzyl)phenyl]hexane, 5-benzene Base 丨, 3, 3-diaminobenzene, 5-[4-(4-carbocyclohexyl)phenyl]fluorenyl-153-diaminobenzene, 5-[4_(4_(4-alkylcyclohexyl)) Cyclohexyl)phenyl]decyldiamine-based, 5-[((alkylcyclohexyl)ethylcyclohexyl)phenyl]indenyl 4,3·diaminobenzene,-bis[4_(4-amino) Benzene) Cyclohexane, U-bis[4-(4-aminophenyloxy)phenyl]_4_alkylcyclohexane, hydrazine, 1·bis[4-(4-aminobenzyl) Phenyl]cyclohexane, 1, 丨_bis[4_(4-aminophenyl)phenyl]-4-alkylcyclohexane, 1,3-bis(3-aminopropyl)_ Tetramethyl bismuth is calcined, and examples thereof include compounds represented by the following formulas (^) to (f). [化37] 39 200902644

H2N - A1 - NH2

(IV)

(V) (VI)

(VII) H2N nh2 (In the formula (Π), A1 is -(CH2)m-, wherein m is an integer of 1 to 6, in the formula (IV) and (VI) to (Μ), Α1 is a single bond , -0-, -S-, -S-S_, -S02-, -CO-, -CONH-, -NHCO-, -C(CH3)2-, -C(CF3)2-, -(CH2) M-, -0-(CH2)m-0-, -S-(CH2)mS-, wherein m is an integer from 1 to 6, and A2 is a single bond, -Ο-, -S-, -CO-, - C(CH3)2-, -C(CF3)2- or a calcined group having a carbon number of 1 to 3, and a hydrogen bonded to a cyclohexane ring or a benzene ring may be substituted by -F and -CH3.) 40 200902644 27225pif The diamine represented by the formula (Π) may, for example, be a diamine represented by the following formula (Π-1) to (Π-3). 11-3 H-1 11-2 η2νγ η2ν/χ^ΝΗ2 η2ν&quot; The diamine represented by the formula (ΠΙ) is, for example, represented by the following formulas (ΠΙ-1) and (II-2) Diamine. [化39] 111-1 II1-2 h2n-

-NH 2 H2N-f 7-NH2 The diamine represented by the formula (IV) is, for example, a diamine represented by the following formulas (1Y-1) to (IV-3). [IV 40] IV-1 IV-2 IV-3

The diamine represented by the formula (V) is, for example, a diamine represented by the following formulas (V-1) to (V-5). [41] 41 200902644 V-1 V-2 V-3

V-4 V-5 h2n-^^-nh2 h2n-^^-nh2

The diamine represented by the formula (VI) is, for example, a diamine represented by the following formulas (VI-1) to (VI-30). k [化42]

V I - 1 0 V I - 1 1 h2N-NH2 VI-12

42 200902644 27225pif [化44] VI - 1 6 VI - 1 7 h2n-^^〇^〇'-{^-nh2 h2n-^&gt;-0-^0^^nh2 VI-18 VI-19 v I - 2 Ο VI - 2 1 H2N-x〇^S^G^NH2 h2n-&lt;Q&gt;^%^^-nh2 f ' [Chem. 45] VI -2 2 VI -2 3 h2n-^Ks^s^j&gt ;-nh2 h2n-^^s-^\s^j&gt;-nh2 V I-2 4 VI -2 5 Noisy - called H2N-^3kSn'/&quot;&quot;'&quot;n^x^s'n&lt; (^-call

The diamine represented by the formula (w) is, for example, a diamine represented by the following formula (νπ-ι) to (W-6). [Chem. 46] 43 200902644 VII- 1 VII- 2

VII-5 VII-6 The diamine represented by the formula (M) is, for example, a diamine represented by the following formula (M-Ι) to (VE-11). 44 200902644 27225pif VIII-1 VIII-2 VIII-3 VIII-4

VIII-5 VIII-6 VIII-7 VIII-8

VIII-9

In the above specific examples of the diamine (a2') represented by the formula (Π) to (M), the formula (V-1) to (V-5) and the formula (VI-1) are more preferable. (VI-12), Formula (VI-26), Formula (YI-27), Formula (YH-1), Formula (ΥΠ 45 200902644 -2), Formula (VH-6), Formula (M-Ι)~ Further, the diamine represented by the formula (V-5), preferably a diamine represented by the formula (V-6), the formula (V-7), or the formula (VI-1) to (VI-12). The diamine (a2〇 used in the present invention may furthermore be a diamine represented by the following formula (IX).

(In the formula (IX), A3 is a single bond, -0-, -COO-, -OCO-, -CO-, -CONH- or -(CH2)m- (wherein m is an integer of 1 to 6) And R6 is a group having a steroid skeleton, a group represented by the following formula (X) or a positional relationship of two amine groups bonded to a benzene ring, which is a carbon number of 1 to 30 in the para position. The base or the positional relationship is an alkyl group having a carbon number of 1 to 30 or a phenyl group, and any of the -CH2- may be -CF2-, -CHF-, -0-, -CH= in the alkyl group. CH- or -C tri-C-substitution, -CH3 may be substituted by -CH2F, -CHF2 or -CF3, and the hydrogen bonded to the ring-forming carbon of the stupid group may be via -F, -CH3, -OCH3, -OCH2F , -OCHF2 or -OCF3 is substituted.) [Chem. 49] 46 (X ) 200902644 27225pif

(In the general formula (X), A4 and A5 are each independently a single bond, -〇-, -COO-, -OCO-, -CONH-, -CH=CH- or an alkylene group having 1 to 12 carbon atoms, R7 And R8 is independently -F or _Ch3,

Ring S is 1,4-phenylene, 1,4-cyclohexylene, 1,3-two chewing compound _2,5-diyl, pyrimidine-2,5-diyl, pyridine-2,5-di Base, naphthalene_1,5-diyl, naphthalene_2,7-diyl or fluoren-9,10-diyl, R9 is -H, -F, alkyl having 1 to 30 carbon atoms, carbon number 1 to 3氟 氟 氟 院 院 院 院 取代 取代 取代 取代 取代 取代 取代 取代 取代 取代 取代 取代 取代 取代 取代 取代 取代 取代 氟 取代 取代 取代 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟 氟Individually representing an integer of 〇~3, e is 2 or 3 柃, multiple rings S may be the same group, or different groups, f and g respectively represent integers of 0~2, and c+d+ e^i0) In the general formula (K), two amine groups are bonded to the stupid ring carbon, and the two bonding positions are preferably the meta or para position. The diamine which is represented by the following general formula (IX) [only - n) is exemplified as the "diamine which is preferably bonded to the two amine groups at the three positions". , [50] 47 200902644 ί

I Χ-6

[化 51] I Χ_7 h2n

I X-8

R 19 19

R is preferably an organic group having a hydrazine or a carbon number of 1 to 30 in the above formula (IX-1), aX-2), (IX-7), and (IX-8) 48 200902644 R]8. The alkyl group having a carbon number of 3 to 12 or an alkoxy group having a carbon number of 3 to 12 is preferably an alkoxy group having a carbon number of 5 to 12 or an inverse number of 5 to 12. Further, in the above formula (Han-3) to (K-6) and (K-9) to (IX-11), R]9 is an organic group having a carbon number of from 1 to 30, and Preferably, it is an alkyl group having a carbon number of 〇1〇 or an alkoxy group having a carbon number of 1 to 10, and further preferably an alkane having a carbon number of 3 to 1 Å or an alkoxy group having a carbon number of 3 to 10.

Further, examples of the diamine represented by the formula (IX) include diamines represented by the following formulae (IX-12) to (K-17).

[化52]

々, 丄心必八, _12) ~ (κ·15), two of which have a number of 6~16. In the formula (Κ-16) and the formula (which is an organic group having 2 to 30 carbon atoms, preferably (Κ-17), it is preferably an alkyl group having a carbon number of 8 to 2 Å. The alkyl group represented by the formula (IX) may, for example, be a diamine represented by the following 49 49 49 200902644 (K-18) to (K-38).

50 200902644

51 200902644

H2N is in the above formula (K-18), (IX-19), (K-22), (ix_24), (ix -25), 2 (2 Han-28), (Κ-30), (K_3! , (κ_36) and (Han·), wherein R is hydrogen or an organic group having 1 to 30 carbon atoms, preferably an alkyl group having 12 carbon atoms and an alkoxy group having a carbon number of 1-4, and further preferably It is an alkyl group having 3 to 12 carbon atoms or an alkoxy group having 3 to 12 carbon atoms. Further, in the above formula (Han-20)^(]Χ-21)&gt;(ιχ.23)&gt;(]Χ -26)&gt;(ΙΧ-27)&gt;(Ιχ.29)^(ΙΧ -32)~(Κ-35) and (κ·38), R23 is _H, -F, carbon number 1 to 12 The alkyl group, the oxy group having 1 to 12 carbon atoms, _cn, _〇ch2F, -〇CHF2 or -OCF3' are further preferably a decyl group having a carbon number of 3 to 12 or a methoxy group having a carbon number of 3 to 12. In the above formula (!χ_33) and (κ_34), A9 is an alkylene group of carbon 52 200902644 number 1 to 12.

Further, the diamine represented by the formula (IX) may, for example, be a diamine represented by the following formulas (IX-39) to (IX-48). [化56]

[化57] 53 200902644

Among the diamines (a2') represented by the formula (IX), preferred are the diamines represented by the formulae (IX-1) to (IX-11), and further preferably by the formula (IX). 2), a diamine represented by (1X-4), (IX-5), and (IX-6). The diamine (a2〇 used in the present invention may furthermore be a compound represented by the following formula (XI) and (XU). [Chem. 58] 54

(XI)200902644 M/ZZ^pU d11 R11 η2ν

(XII) (In the formulas (3⁄4) and (XE), ΰΐο^ρΐΐ ν 6 is an alkyl group or an alkenyl group which is independently -Η or a carbon number of 1 to 20, A. independently a single bond, _c ( =〇)_ or _CH2_, ^ and R14 are independently _H, carbon number 1~2〇 alkyl or benzene\.

R1 R14 is preferably in the formula (XI). Two are preferably "cis-Qin, 〇-" C, and Ph is a phenylene group. The - bit in the other is tied to 6 bits. Also, 'the buccal nucleus 3' is better than the yoke in the W reading ^ key in the benzene ring breaking formula (w represented by the diamine, standing or para position. ~ (XI-4) represented by the diamine. Formula (XI 1) [Chem. 59] 55 200902644

H〇f

Ph represents a phenylene group. ) are respectively bonded to the benzene ring carbon, preferably bonded to the carbon which is meta or para to the carbon bonded to the steroid nucleus. Further, the two amine groups are bonded to the benzene ring carbon, respectively, and it is preferably bonded to the meta or para position with respect to A6. The diamine represented by the formula (XE) is, for example, a diamine represented by the following formula (XH-1) to (M-8). [化60] 56 200902644 27225pif

57 200902644

Z / ZZDpiI The diamine (a2') used in the present invention may, for example, be a compound represented by the following formula (ΧΠΙ) and (XIV). [化 62]

R15 is -H or an alkyl group having 1 to 20 carbon atoms, and any -CH2- of the alkyl group having 2 to 20 carbon atoms in the alkyl group may be substituted by -0-, -CH=CH- or -CeC-, A7 Each is independently -0- or an alkylene group having 1 to 6 carbon atoms, and A8 is a single bond or an alkylene group having 1 to 3 carbon atoms.

Ring T is 1,4-phenylene or 1,4-cyclohexylene, and h is 0 or 1. ) [Chem. 63] 〇16 d17

(XIV) R16 is an alkyl group having 6 to 22 carbon atoms, R17 is -H or an alkyl group having 1 to 22 carbon atoms, and 58 200902644 27225pif A7 is independently an alkylene group having _〇_ or a carbon number of 1 to 6. In the above formula (xm), the two amine groups are bonded to the benzene ring carbon, respectively, and it is preferably bonded to the meta or para position with respect to A7. The diamine represented by the formula (xm) may, for example, be a diamine represented by the following formula (yttrium-ι) to (xm-9). [化 64]

[Chem. 65] 59 200902644 ζ/ζζ^ρπ

R, 25

Ί, an alkyl group having a carbon number of 1 to 2 Å, in (xm-4) to (xm-9), and further preferably R2S is an alkyl group having 1 to 10 carbon atoms. f In the above formula (XIV), the two amine groups are bonded to the stupid ring carbon, respectively, and it is preferably bonded to the meta or para position with respect to Α7. The formula (X IV ) is represented by - Cong; a丨 / expressed by ~1) ~ (XIV-3) '[66]

The amine may, for example, be exemplified by the following formula (X-amine 0 60 200902644 27225pif XI V-1 R26 R27 03⁄4 XIV-2 r V R26 R27 \ /, ^03⁄4 XIV-3 Γ=·~~\ R In the general formula (Χΐν·ι)~, θ~ΝΗ2 (XIV-3), r26 R27 1 —, Ding into the mouth, J is the carbon number ό~20

It is an organic group having 2 to 30 carbon atoms, and further wherein these are further a group and an alkyl group of R 10 to 10. Seven or carbon number As described above, the diamine represented by the general formulae (8) to (XIV) used in the present invention may be, for example, a diamine other than an amine. For example, it is possible to use a diamine which has a structure in which these two structures can be used, or a methane, a diamine, an early use alone or a dioxane-based diamine such as a diamine. The amine is not particularly limited, and the product represented by the following formula (XV) can preferably be a compound of the formula. (XV) (Upper 逑 (XV), r3 and R are independently a carbon group i~3 61 200902644 or a phenyl group, and R5 is independently a sub-W, a silk group or a pyridyl substituted phenylene group. X is independently an integer of ～6, and more preferably y is an integer of 152.) The positive number is further preferably, the diamine (a2,) used in the present invention can be represented by the following formula (XVI). -1 ) The diamine represented by ~(XV!_8). [68]

XVI-2 XVi'3

Further, the diamine (a2) which can be used in the present invention is not limited to the diamine of the present specification, and a diamine in a pot form can be used within the range in which the object of the present invention is achieved. Further, the diamine (a2,) which can be used in the present invention may be used singly or in combination of two or more kinds. #, A combination of two or more kinds of diamines may be used: a combination of the above diamines, a combination of the above diamines and a diamine other than the above diamines. In this case, the ink is used, and the tree is "transparent" in the formula (xv);: - is a diamine diphenyl stone wind and the above-mentioned diamine of an integer of from -15. ^-^±dt±4^ (B) (B) The polymer compound imine, poly: amine acid polyimine, polyamine, polyamine, or the like in the ink for ink of the present invention. The compound is polymerized with polyvinyl alcohol, a acrylate polymer, and acrylic acid. Privately condensed ethylene ortho-molecule compound, but not limited to 醯imino-based ancient father, poly-phthalic acid or soluble polyimine, etc. I hope that the material of the arsenic of the arsenic is not limited to the compound. The odor can be obtained by at least making the acid field having two or more acid fields and not limited to (10) _, but the material is (4) having a combination of two or more acid secrets. Acid (Α) substance /. , ' : the same compound of the two acid anhydride group compounds (al) 63

200902644 Z/ZZDpiT The compound (b1) having two or more acid anhydride groups may be the same as or different from the compound (al) having two or more acid anhydride groups. Further, the above-mentioned compounds having an acid anhydride group may be used singly or in combination of two or more kinds. As a specific example of the diamine (b2) used in the present invention, the same diamine as the above-mentioned diamine (a2) which can be used for obtaining valine acid (A,) can be used. The diamine (b2) and the diamine (a2') may be the same or different. Further, the above diamines may be used singly or in combination of two or more kinds. Monoamine (5)) As a specific example of the monoamine (b3) used in the present invention, the same monoamine as the above-mentioned monoamine (a2) which can be used for obtaining valine acid (A) can be used. The single fee (b3) may be the same as or different from the monoamine (a2). Further, the monoamines disclosed above may be used singly or in combination of two or more kinds. 2A Polyproline and oxime fraction The polyglycine which can be used in the present invention is preferably a compound (bl) having an acid anhydride group of 2 or more with respect to 1 mole, and 〇〇5, Mo It is obtained by reacting ~0.8 mol of diamine (b2) and 0.4 mol to 19 mol of monoamine (b3). Further, further preferably, it is a compound (b1) with respect to two acid anhydride groups, and a diamine (b2) such as 〇1 mol//〇·6 mol, 0.8 mol to 1.8 mol. The monoamine (b3) reaction is more preferably obtained by reacting with 1 mole of a compound having more than 2 gorges, 200902644 27225 pif - 〇 · 35 mol of diamine (b2), 1.3 mol. . Compound (bl), reacted with 0.15 moles to 1.7 moles of monoamine (b3), in the invention, can be used to obtain the amine surface, and can be used to obtain the acid. A) or 8 lysine (A') / 1:1! The same ridge. The reaction solution is used singly or as a solvent of two or two kinds of /tti 5 . Moreover, in addition to the above reaction solvent, it may be mixed

Use other solvents together. When the reaction solvent is used in an amount of 100 parts by weight or more based on the total of 1 part by weight of the compound (M), the monoamine (b2) and the monoamine (b3) having two or more acid needle groups, the reaction proceeds smoothly. Therefore, it is better. Preferably, the reaction is carried out at o ° c ~ loot (preferably 8 t to 7 (rc) for 0.2 hours to 20 hours (preferably 2 hours to hours). 2.4 ( 2 ) added to the reaction system In addition, the order in which the reaction raw material is added to the reaction system is not particularly limited. That is, any one of the following methods may be used: a compound (bl) having an acid anhydride group of 2 or more and a diamine ( B2) is added to the reaction simultaneously with the monoamine (乜3); * in the method of the granule, the diamine (b2) and the monoamine (b3) are dissolved in the reaction solvent, and then the acid liver group having two or more is added. a method of compound (bl); a method of adding a diamine (b2) by reacting a compound (b1) having an acid anhydride group of 2 or more with a monoamine (b3); and first having an acid anhydride group of 2 or more A method in which a compound (b1) and a diamine (b2) are reacted to synthesize a copolymer, and a monoamine (b3) is added to the copolymer. 65 200902644 '.ι^Δορη The weight average molecular weight is a macromolecule of coffee = paste Q In particular, it is excellent in solubility in solvents, and it is better as a kind of ink. The molecular compound (8) is solvent-solving, and it is preferred that the weight average of the polymer compound (8) is =, 000, 0 to 0, more preferably (10) to 7, 5GG, and further preferably = 5,000 ' It is ι, 〇〇〇~3,5〇〇. The reason is that a polymer compound (8) having a weight average molecular size of 1,000 or more does not evaporate, is chemically stable, has a mechanical stability, and has an average weight of eight or less. The polymer compound (8) can improve the solubility in a solvent, and the film thickness of the obtained coating film can be preferably used as an ink for inkjet.重量 The weight average molecular weight of the polymer compound (8) is determined by a gel permeation chromatography (GPC) method. Specifically, it can be obtained by diluting the concentration of the obtained polymer compound (8) with a weight percentage (wt%) of the obtained polymer compound (8) by tetrahydroanthracene (THF) or the like, and _ Columns G4000HXL, G3〇〇〇hxl, g25〇〇hxl, and θ are determined by gel permeation chromatography (GPC) and converted to polystyrene using THF as a developing solvent. Substituted Nadick acid yttrium ytterbium compound also m The dilute-substituted nadic ylide ylide imine compound (6) contained in the inkjet ink of the present invention has at least one olefinic nadidonic acid yttrium imine in the molecule a compound of a structure, preferably a monoamine, a diamine, a triamine or a tetraamine, which is reacted with an upper (5') silk olefinic sinic acid anhydride. 66 200902644 27225pif obtained an alkenyl substituted nadic acid yttrium The amine is more preferably an alkenyl-substituted nadic acid ruthenium imide compound represented by the above formula (5), but is not limited to the compound. The alkenyl-substituted nadic acid ruthenium imide compound (c) is present. : η is an alkenyl group substituted with a nadic acid-based imine compound (cl: below, When it is only referred to as "alkenyl-substituted nadic acid ylide"), and η is 2 alkenyl-substituted nadic acid ylidene imine compound (C2: hereinafter, sometimes only referred to as "double-dilute substituted nadic acid"醯imino"), n is an alkenyl group substituted with a nadic acid ylide compound (c3: hereinafter, sometimes referred to simply as "trienyl substituted nadic ylide"), and n is an alkenyl group of 4 Substituting Nadick's yttrium imine compound (c4: hereinafter, sometimes referred to simply as "tetraalkenyl substituted nadic acid yttrium imine"). Terpene is substituted for J. Didi. Acid 醯 眩 眩 k/n The present invention Specific examples of the alkenyl-substituted nadic acid ruthenium imine compound having a η of 1 used include, for example, the following compounds: Allylbicyclo[2.2.1]hept-5-ene-2,3- Dicarboxy quinone imine, allyl fluorenyl bicyclo [2.2.1] hept-5-ene · 2,3-dicarboxy quinone imine, methallyl bicyclo [2.2.1] hept-5-ene - 2,3-dicarboxy quinone imine, fluorenyl propyl fluorenylbicyclo[2.2.1]hept-5-ene-2,3-di-trans-acid imine, fluorenyl-p-propyl-bromopropyl bicyclo [ m]g_5_diluted _2,3_dicarboxy quinone imine, N-hydroxy-allylmethylbicyclic hydrazine. 21]g _ 5-ene-2,3-dicarboxyarsenine, N-hydroxy-mercaptopropylbicyclo[2·21]hept-5-ene-2,3·dicarboxyarmine, 67 200902644 Ν-hydroxyl -methylallylmethylbicyclo[2.2.1]hept-5-ene-2,3.dicarboxyindolimine, Ν-methyl-allylbicyclo[2.2.1]hept-5-ene- 2,3-Dicarboxy quinone imine, fluorenyl-fluorenyl-allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, fluorenyl-fluorenyl-methylene Propylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine, fluorenyl-mercapto-methylallylhydrazinobicyclo[2.2.1]hept-5-ene-2, 3-dicarboxy quinone imine, Ν-(2-ethylhexyl)-allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, and oligomers thereof Wait. Further, Ν-(2-ethylhexyl)-allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarminemine, Ν-allyl-allyl Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine, Ν-allyl-allylmethylbicyclo[2.2.1]hept-5-ene-2,3-di Carboxylimine, Ν-allyl-mercaptopropylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, Ν-isopropenyl-allyl bicyclo [2.2 .1]hept-5-ene-2,3-dicarboxy quinone imine, Ν-isopropenyl-allylhydrylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy fluorene Amine, 68 200902644 27225pif N-isopropenyl-mercaptopropyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine, N-cyclohexyl-allyl bicyclo [2.2. 1]hept-5-ene-2,3-dicarboxyindenine, N-cyclohexyl-allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyanimine, N-cyclohexyl-methylallylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid imine, N-phenyl-allylbicyclo[2.2.1]hept-5- Alkene-2,3-dicarboxy quinone imine, and oligomers thereof and the like. Further, N-phenyl-allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarminemine, N-benzyl-allylbicyclo[2.2.1] Hg-5-ene-2,3-dicarboxy quinone imine, N-benzyl-allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, N- Benzyl-mercaptopropylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine, N-(2'-hydroxyethyl)-allylbicyclo[2.2.1] Hg-5-ene-2,3-dicarboxyanimine, N-(2'-hydroxyethyl)-allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyl Yttrium imine, 1(2'-hydroxyethyl)-methylallylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarmine, and oligomers thereof. 69 200902644 Also exemplified: N-(2',2'-dimercapto_3'-hydroxypropyl)-allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyfluorene Amine, N-(2',2'-dimethyl-3'-hydroxypropyl)-allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, Ν-(2^-dihydroxypropyl)-allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, Ν-(2\3'-dihydroxypropyl) Allyl-mercaptobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarminemine, Ν-(3^hydroxy-purin-propenyl)-allylbicyclo[2.2.1] Hg-5-ene-2,3-dicarboxyindolimine, N-(4'-hydroxy-cyclohexyl)-allylmethylbicyclo[2.2.1]hept-5-ene-2,3-di Carboxylimine, and oligomers thereof. Further, N-(4'-hydroxyphenyl)-allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarminemine, N-(4'-hydroxyphenyl) _Allylmercaptobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenine, N-(indolylphenyl)-methylallylbicyclo[2.2.1]heptane- 5-ene-2,3-dicarboxy quinone imine, Ν-(4'-hydroxyphenyl)-mercaptopropyl hydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyl Yttrium imine, Ν-(3'-hydroxyphenyl)-allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, Ν-(3'-hydroxyphenyl) -allylmethylbicyclo[2.2.1]hept-5-ene-2,3-di70 200902644 27225pif Carboxylimine, N-(p-hydroxybenzyl)-allylbicyclo[2.2.1]g -5-ene-2,3-dicarboxylic acid imine, N-{2'-(2'-hydroxyethoxy)ethylbuallylbicyclo[2.2.1]hept-5-ene-2, 3-dicarboxy quinone imine, and oligomers thereof and the like. Further, N-{2'-(2'-hydroxyethoxy)ethyl}-allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarlimine, N-{2'-(2'-hydroxyethoxy)ethyl}-methylallylbicyclo[2.2.1]hept-5-fried-2,3-di-rebasic imine, Ν-Ρ '-β-Hydroxyethoxy)ethyl}-mercaptopropylidenebicyclo[2.2.1]hept-5-fine-2,3-diindenyl iodide, Ν-[2'-{ 2'-(2"-Hydroxyethoxy)ethoxy}ethyl]-allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenine, Ν-[2' -{2'-(2"-hydroxyethoxy)ethoxy}ethyl]-allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarminemine, hydrazine -[2'-{2'-(2"-hydroxyethoxy)ethoxy}ethyl]-mercaptopropylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindole Imine, Ν-{4'-(4'-hydroxyphenyl isopropylidene)phenyl}-allylbicyclo[2.2.1]hept-5-^-2,3-di-biotinimidate , N-{4'-(4'-hydroxyphenyl isopropylidene)phenyl}-allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, N-{4'-(4'-hydroxyphenyl-isopropylidene)phenyl}-mercaptopropylbicyclo[2.2.1] hept-5-fried-2,3-disulfonyl The imine, 71 200902644 z/iz^pu, and the like, etc. Further, the alkenyl-substituted nadic acid imide (cl) can be used as a mixture of these alkenos. The above alkenyl group is substituted with nadic acid ylidene imine (c N-methyl, propyl bicyclo [2.2. Pro 5 ^ Ning is preferably fluorenyl, propylmethyl bicyclo [2.2.1] g) : bis-imine, imine, 5-diuretic-2,3-dicarboxyindole N-fluorenyl-mercaptopropylbicyclo[221] imine, sub-5-ene-2,3-diweil醯N-fluorenyl-hydrazinopropyl hydrazinobicyclo[2. acid imide, ]hept-5-rare-2,3-dioxime N-(2-ethylhexylallylbicyclo[2.2醢iamine, etc. Geng 5 - dilute-2,3-dibolycyl group can also be exemplified by N-(2-ethylhexyl), internal group of 5-5-ene-2,3-dicarboxy quinone imine, Earth and clothing [2.2.] heptyl decyl propyl keyl double ring [2.2.1] gen, do: green 醯 Ν 烯 ally-allyl-allyl fluorenyl double ring [2.2. 醯 imine, g ~ 5 -ene-2,3-dicarboxy-branched = aryl-allyl bis-bis-iminoimine Ν 异 异 郝 郝 郝 双 双 双 · · · · · 异丙 异丙 异丙 异丙 · · · · · 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.2 2.2 G, 5_稀_2,3_二竣72 200902644 27225pif Basic imine, N-isopropenyl-methylallyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine, N-cyclohexyl-allyl bicyclo [2.2. 1]hept-5-ene-2,3-dicarboxy quinone imine, N-cyclohexyl-allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, N-cyclohexyl-mercaptopropylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyl with imine, N-phenyl-allylbicyclo[2.2.1]hept-5- Alkene-2,3-dicarboxy quinone imine, and the like. Further, N-phenyl-allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarminemine, N-benzyl-allylbicyclo[2.2.1] Hg-5-ene-2,3-dicarboxy quinone imine, N-benzyl-allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, N- Benzyl-methylallyl bicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarminemine, and the like. More preferably, the alkenyl-substituted nadic acid ylide (cl) is: N-methyl-allyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine, N- Mercapto-allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine, N-mercapto-mercaptopropylbicyclo[2.2.1]hept-5- Ace-2,3-dicarboxy quinone imine, 73 200902644 N-fluorenyl-methylallylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, &gt; ^-(2-Ethylhexyl)-allylbicyclic guanidine .2.1]hept-5-ene-2,3-dicarboxy quinone imine, and the like. Also exemplified is: N-(2-ethylhexyl)-allylhydrazinobicyclo[2.2.1]hept-5- fine-2,3-diweiryimine, N-allyl-allyl Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine, N-allyl-allylmethylbicyclo[2.2.1]hept-5-ene-2,3- Dicarboxy quinone imine, N-allyl-methylallyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine, N-isopropenyl-allyl bicyclo [ 2.2.1]hept-5-ene-2,3-dicarboxyindolimine' N-isopropenyl-allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindole Imine, N-isopropenyl mercaptopropyl bicyclic P.2.1] hept-5-ene-2,3-dicarboxy quinone imine, and the like. 3.2 Dikenyl-substituted nadic acid ylide (c2) Further, specific examples of the alkenyl-substituted nadic acid ylide compound of η used in the present invention include, for example, the following compounds. Illustratively: Ν, Ν '-ethylene-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine), NW-ethylene-bis(allyl Methylbicyclo[2.2.1]hept-5-ene-2,3-di 74 200902644 27225pif carboxy quinone imine), hydrazine, Ν'-ethylene-bis(mercaptopropyl bicyclo [2.2.1 ]hept-5-ene-2,3-dicarboxyindenine), N,N'-triindolyl-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyl醯imino), N,N'-hexamethylene-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarmine), N,N'-hexa Mercapto-bis(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenine), N,N'-dodedecyl-bis(allylbicyclo) [2.2.1]hept-5-ene-2,3-dicarboxyindenine), hydrazine, Ν'-dodedecyl-bis(allylmethylbicyclo[2.2.1]hept-5- Alkene-2,3-dicarboxy quinone imine), hydrazine, Ν'-cyclohexylene-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinazoline), Ν, Ν'-cyclohexylene-bis(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine), and oligomers thereof. Also exemplified are: 1,2-bis{34-allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolide)propoxy}ethane, 1.2-double {3'- (Allyl fluorenylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine)propoxy}ethane, 1.2-bis{3'-(nonylallylbicyclo[ 2.2.1]hept-5-ene-2,3-dicarboxyindolimine)propoxy}ethane, 75 200902644 bis [2'·{3'_(allylbicyclo[2.2.1]heptane- 5-ene·2,3·dicarboxyindolimine)propoxy}ethyl]ether, bis[2'-{3'-(allylmethylbicyclo[2.2.1]hept-5-ene- 2,3-Dicarboxyindolimine)propoxy}ethyl]ether, 1,4-double {3'-(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyl Yttrium imine) propoxy}butane, fluorene-bis{3'-(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)propoxy} Butane, and oligomers thereof and the like. Also exemplified by: Ν, Ν'-p-phenylene-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine), Ν, Ν'-pair Base-bis(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine), fluorene, Ν'-m-phenylene-bis(allylbicyclo[2.2 .1]hept-5-ene-2,3-dicarboxy quinone imine), hydrazine, Ν'-m-phenylene-bis(allylmethylbicyclo[2.2.1]hept-5-ene-2 , 3-dicarboxy quinone imine), hydrazine, hydrazine, -{(1-indolyl)-2,4-phenylene}-bis(allylbicyclo[2.2.1]hept-5-ene-2 ,3-dicarboxy quinone imine), hydrazine, Ν'-p-phenylenediyl-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine), hydrazine ,Ν'-p-Oxyl-bis(allyl-decylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenine), anthracene, Ν'-m-phenylenedifluoryl - bis (allylbicyclo[2.2.1]hept-5-ene-2,3-di 76 200902644 27225pif carboxy quinone imine), hydrazine, Ν'-m-phenylenedifluoryl-bis(allyl fluorenyl) Bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine), and oligomers thereof and the like. Further, exemplified by 2,2-bis[4'-{4'-(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarmineimine)phenoxy}phenyl] Propane, 2.2-bis[[{4'-(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)phenoxy}phenyl]propane, 2.2- Bis[4'-{4'-(methylallylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)phenoxy}phenyl]propane, double {4- (allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyinlimine)phenyl}decane, bis{4-(allylhydrazinobicyclo[2.2.1]heptane- 5-ene-2,3-dicarboxy quinone imine) phenyl} decane, and oligomers thereof and the like. Further, exemplified by: bis{4-(methylallylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarmineimine)phenyl}methane, double {4-(decyl allyl Base bisbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinazoline)phenyl}decane, bis{4-(allylbicyclo[2.2.1]hept-5-ene -2,3-dicarboxy quinone imine) phenyl} bond, bis{4-(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine) phenyl }ether, bis{4-(methylallylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyfluorene 77 200902644 amine)phenyl}ether, double {4-(allyl Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)phenyl}stone, bis{4-(allylmethylbicyclo[2.2.1]hept-5-ene- 2,3-dicarboxy quinone imine) phenyl} fluorene, and oligomers thereof and the like. Further, exemplified by: bis{4-(decylallylbiscyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolide)phenyl}anthracene, 1,6-bis(allyl) Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)-3-3⁄4yl-hexyl, 1,12-bis(nonylallylbicyclo[2.2.1]heptane- 5-ene-2,3-dicarboxy quinoid imine)-3,6-di-light-d-dodecyl, 1,3-bis(allylbicyclo[2.2.1]hept-5-ene-2, 3-Dicarboxy quinone imine)-5-3⁄4 base - 哀 己 己, 1,5-bis{3'-(allylbicycloindole.2.1)hept-5-ene-2,3-dicarboxyanthracene Imine)propoxy}_3_light-e-butyl, 1,4-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)-2-hydroxyl - benzene, and oligomers thereof and the like. Further, 1,4-bis(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-diindenyl iodide)_2,5-di-di-phenyl, N, N'-p-(2-hydroxy)benzenedimethyl-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolide), N,N'-pair (2 -hydroxy)benzoyl-bis(allylmethylcyclo[2.2.1]hepta 78 200902644 27225pif -5-female-2,3-di-rebelletic imine), Ν, Ν·-between (2 -hydroxy)phenylenediyl-bis(allylbicyclo[2.21]hept-5-dilute-2,3-di-supplemental-i-imine), NW-m-(2-hydroxy)benzodiazepine-bis(曱Allylbicyclo[2·2.1]hept-5-rare-2,3-dicarbenylimine), hydrazine, Ν'-p-(2,3-dihydroxy)benzenedimethyl-bis(ene) Propylbicyclo[Hi]hept-5-rare-2,3-diyl-bromoimine), and oligomers thereof and the like. Further, 2,2-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)-2'-hydroxy-phenoxy}phenyl]propane, Double {4-(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)-2-hydroxy-phenyl}decane, double {3-(allyl Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)-4-hydroxy-phenyl}ether, bis{3-(decylallylbicyclo[2.2.1]g -5-ene-2,3-dicarboxy quinone imine)-5-hydroxy-phenyl}sulfone, 1,1,1-tris{4'·(allylhydrylbicyclo[2.2.1]heptane- 5-ene-2,3-dicarboxy quinone imine)}phenoxymethylpropane, N,N',N"-tris(ethylene decylallylbicyclo[2.2.1]hept-5- Alkene-2,3. dicarboxy quinone imine) trimeric isocyanate, and oligomers thereof, etc. Further, it may be the following compound containing an asymmetric alkylene group. [Chem. 69] 79 200902644

Further, it is mentioned that the dienyl substituted nadic acid imide (c2) may be used singly or as a mixture of these. The above dienyl substituted nadic acid ylide (c2) is preferably Ν, Ν1-ethylene-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-di Carboxylimine), hydrazine, Ν'-ethylidene-bis(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarmine), hydrazine, Ν'_ Ethylene-bis(methylallylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine), fluorene, fluorene 1-trientylene-bis(allylbicyclo[2.2 .1]hept-5-ene-2,3-dicarboxyindenine), 80 200902644 27225pif N,Ν'-hexamethylene-bis(allylbicyclo[2.2.1]hept-5-ene- 2,3-dicarboxy quinone imine), N, NL hexamethylene-bis(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine), N , N'-docamethylene-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarmine), hydrazine, fluorene 1-dodecyl-di- Allyl fluorenylbicyclo[2.2.1]hept-5-ene #-2,3-dicarboxy quinone imine), hydrazine, Ν'-cyclohexylene-bis(allylbicyclo[2.2.1]g -5-ene-2,3-dicarboxy quinone imine), hydrazine, Ν'-cyclohexylene-bis(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyl醯imine) and so on. Also exemplified by: Ν, Ν'-p-phenylene bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine), hydrazine, Ν'-p-phenylene Base-bis(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenine), I Ν, Ν'-m-phenylene-bis(allylbicyclo[ 2.2.1] hept-5-ene-2,3-dicarboxy quinone imine), hydrazine, Ν'-m-phenylene-bis(allylhydrazinobicyclo[2.2.1]hept-5-ene- 2,3-Dicarboxy quinone imine), hydrazine, Ν'-{(1-indolyl)-2,4-phenylene}-bis(allylbicyclo[2.2.1]hept-5-ene- 2,3-dicarboxy quinone imine), air enthalpy-p-xylylene-bis(allyl bicyclo[2.2.1; |hept-5-ene-2,3-dicarboxy quinone imine), 81 200902644 N,N'-p-Oxime-bis(allyl-decylbicyclo[2.2.1]hept-5-ene-2,3-di-rebasic imine), hydrazine, Ν'-m-phenylene Dimercapto-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenine), hydrazine, Ν'-m-phenylenedifluoryl-bis(allylmethyl) Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine), 2.2-bis[4'-{4'-(allylbicyclo[2.2.1]hept-5-ene- 2,3-Dicarboxy quinone imine) phenoxy} phenyl] propyl, 2.2- bis [4'-{4'-( Propylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)phenoxy}phenyl]propane, 2.2-bis[4'-{4|-(decylene) Propylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarsenazo)phenoxy}phenyl]propane, bis{4-(allylbicyclo[2.2.1]hept-5 -ene-2,3-dicarboxy quinone imine) phenyl}methane, bis{4-(allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine) Phenyl}methane, etc. Also exemplified by: bis{4-(decylallylbiscyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolide)phenyl}methane, double {4-(decyl allyl Base bisbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinazomine)phenyl}methane, bis{4-(allylbicyclo[2.2.1]hept-5-ene- 2,3-dicarboxy quinone imine)phenyl} bond, bis{4-(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinazoline)phenyl} Ether, 82 200902644 27225pif a succinic acid sub-bis(methylallyl bicyclo [2.2.1] hept-5-oxime 23_amine) phenyl}_, carboxy quinone imine) benzene double {4_ (propyl Bicyclo[2.2,1]hept-5-ene-2,3-bis{4-(allylmethylbicyclo[^^heptene-2-enylamine)phenyl} can be exemplified. 4_(mercaptopropylidene bicyclo [2 dicarboxy quinone imine) phenyl] sulfone, etc. 『nekenene·2&gt; Dialkyl substituted nadic acid ylide (C2) is more preferable. N, N '-Ethylene-bis(allylbicyclopurine.21)hept-5-ene-2-2+3-diimineimine), first-order 丞N,N'-ethylene-bis(dilylpropyl) Methyl bicyclo [^ ^heptazepine-^-dicarbenyl imine), n, n'-ethylidene-bis(methylallylbicyclo[2.2· :^g^^^_2,3_ Carboxylimine), N,N'-triindolyl-bis(allylbicyclo[m]hept-5-ene-2,3_bis-supplemental imine), N,N'-hexamethylene Base-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine), AN1-hexamethylene-bis(l-propyl fluorenylbicyclo ρ.2·1 ]hept-5-ene-2,3-dicarboxy quinone imine), hydrazine, Ν'-docamethylene-bis(allylbicyclo[2.2.1]hept-5-ene_2,3_ Dicarboxy quinone imine), hydrazine, Ν'-dodecyl bis(allylmethylbicyclo[2.2.1]hept-5-ene 83 200902644 -2,3-dicarboxy quinone imine), hydrazine ,Ν'-cyclohexylene·bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarmine), hydrazine, Ν'-cyclohexylene-bis(allyl Indenylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenine), etc. Also exemplified by Ν,Ν'-p-phenylene-bis(allylbicyclo[2.2.1 ]hept-5-ene-2,3-dicarboxy quinone imine), fluorene, fluorene-p-phenylene-bis(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3- Dicarboxy quinone imine), hydrazine, Ν'-m-phenylene-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine), hydrazine, Ν'- M-phenylene-bis(allylmethylbicyclo[ 2.2.1]hept-5-ene-2,3-dicarboxyindolimine), hydrazine, Ν'-{(1-indolyl)-2,4-phenylene}-bis(allylbicyclo[ 2.2.1] hept-5-fine-2,3-diindenyl iodide), hydrazine, Ν'-p-xylylene-bis(allylbicyclo[2.2.1]hept-5-ene- 2,3-Dicarboxy quinone imine), hydrazine, Ν'-p-phenylenediyl-bis(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarmine ), Ν, Ν·-m-xylylene-bis(allylbicyclo[2.2_1]hept-5-ene-2,3-dicarboxy quinone imine), ruthenium, Ν'-m-phenylene fluorenyl - bis(allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyinlimine) and the like. Also exemplified is: 2,2-bis[4'-{44allylbicyclo[2.2.1]hept-5-ene 84 200902644 27225pif-2,3-dicarboxyindenine)phenoxy}phenyl] Propane, 2.2-bis[4'-{4'_(allyl-decylbicyclo[2.2.1]hept-5-diuretic-2,3-di-reoxypyridinium)phenoxy}phenyl]propane , 2.2-bis[4|-{4'-(decylallylbiscyclo[2.2.1]hept-5-ene-2,3_bis-decenary imine)phenoxy}phenyl]propane, Double {4-(allylbicyclo[2.2.1]hept-5-ene-2,3-dioxaliminium)phenyl}decane, bis{4·(Ltypropyl fluorenylbicyclo[2.2 .1] hept-5-diluted _2,3-dicarboxyarenimine)phenyl}decane, and the like. Further, exemplified by: bis{4_(methallylbicyclo[221]hept-5-ene-2,3-dicarboxyarenimine)phenyl}methane, double {4-(mercapto-l-propylmethylbicyclo) [2.2.im_5_m· quinone imine) phenyl}methane, etc. Two: 3⁄4-based substitution of Nadick acid acid sub-neck "1 ^In the invention, the synthesis of the 3rd alkenyl-substituted Nadick acid-imine compound in the invention can be carried out as follows: relative to the L0 moir 2:" 3.G Moer ~ 5 · ° Moer's alkenyl substituted nadic anhydride, in the case of diseases such as benzene, toluene, dimethyl strepto, mesitylene, methyl naphthalene, di-t-tralin, chloroform , dichloroethylene, tetrachloroethylene, chlorobenzene, dioxane, hexamethylene ether, benzamidine Unis, propionate, _: ketone: methyl isobutyl ketone, acetophenone, two Mercaptoamine, from a sirroin, or a mixture of two or more solvents. [Shouting fresh storage G. 5 hours ~ 3G hours ride reaction. The above solvent was obtained under reduced pressure at 20 to C to obtain proline. The above-mentioned 85 200902644 is immersed in the above solvent, and is refluxed for about 5 hours to 30 hours in the vicinity of the point of the solvent, or the compound itself is heated at I60t: 〜20 (TC) to cause dehydration ring closure. The solvent is dried under reduced pressure to obtain the target compound, which can be confirmed to be the target compound by nuclear magnetic resonance (Nmr) or infrared (IR). The n used in the present invention is a specific one of the 3rd trienyl substituted nadic acid ylide imine compound. For example, the following compounds can be exemplified. Two {4-(dilylbicyclo[2.2.1]hept-5-diluted-2,3-dicarboxyarenimine)triethyl}amine (TrisANITAEA), three {4 -(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimide)trisyltrimethane (TrisANITrisAM), tris{4-(dipropylbicyclo[2.2.1] The IR spectrum and the 1H-NMR spectrum (400 MHz) of hept-5-sweet-2,3-dicarboxyarsenazo)phenyl}hydroxymethane (TrisANIPARARO) and "TrisANITAEA" are shown in Fig. 1 and Fig. 2, respectively. In the spectrum, it is attributed to olefin CH stretching: 3070 cm·1, 2966 cm 1; attributed to aromatic CH stretching: 2966 cm-1; attributed to terpene hydrocarbon CH stretching: 2938 cm·1; attributable to quinone imine C=0 Stretch Shrinkage: 1762 cm], 1690 cm-1; attributed to C=C expansion: 1640 cm-1; attributed to -CH2-N-methylene scissor vibration: 1448 cm'1; attributed to quinone imine C-Ν Telescopic: 1382 cm·1, etc. [Chem. 70] 86 200902644 27225pif

2.50卩111~3.49卩111 peak; attributed to 』,]^, 111,11 proton (1 condition): 5.01??111~6.27??111 peak; belonging to 11 proton (611):1.251)1) 111 to 1.76 ppm peak and so on.

The IR spectrum and the iH_NMR spectrum (4 〇〇 MHz) of "TrisANITrisAM" are shown in Fig. 3 and Fig. 4, respectively. In the IR spectrum, it is attributed to olefin CH stretching: 3056 cm·1, 2970 cm·1; belonging to aromatic C-Η stretching: 2970 cm-1; belonging to burning hydrocarbon CH stretching: 2936 cm·1; Amine C=0 stretching: 1772 cm·1, 1706 cm-1; belonging to C=C stretching: 1638 cm·1; belonging to quinone imine CN stretching: 1402 (^1, etc. [Chem. 71] 87 200902644 Z/ ZZ3pil

5.14 ppm, 5.74 ppm to 6.34 ppm peak; attributed to 〇 proton (1H): ί 5.30 ppm to 5.60 ppm peak. The IR spectrum of "TnsANIPARARO" and the iH_NMR spectrum (I) 〇〇 MHz are shown in Fig. 5 and Fig. 6, respectively. In the IR spectrum, it is attributed to olefin CH stretching: 3056 cm-1, 2972 cm-1; attributed to aromatic CH stretching: four 72 cm"; attributed to burning hydrocarbon CH stretching: 2936 cm·1; attributable to yttrium imine 0 telescopic: 1776 cm-i, 1706 cm, fine belongs to CC telescopic. 1636 cm; attributed to yttrium imine: ^ telescopic: 1402 (; 111-1, etc. 88 200902644 27225pif [化72]

/N ]H-NMR spectrum, assigned to 3 protons ~d ppm~7·53 Ppm; attributed to e, f, g, Bu U2H): 6.98 2.27 ppm~3.60 ppm peak; attributed to hf (18H): ~(10) Jingzhifeng; belonging to j, k, m, n protons (gamma), :1·47 ah~6.24 ppm. The synthesis of the ppm amine compound can be carried out by substituting Nadickic acid yttrium tetramine, mixed with 4.0 mA~A method: at room temperature relative to 00 hr, dissolved in an alkenyl-substituted na Dick anhydride, in Shiyan - Ητ*·. tetrahydronaphthalene, chloroform, trichloroethylene, mesitylene, decylnaphthalene, hydrogen hydrazine, six" base, four gases, chlorobenzene, two Teriyaki, tetramethyl hydrazine, acetone, methyl ethyl ketone, methyl 89 200902644 f I ketone, stupid oxime, N, N-didecyl decylamine, dimethyl hydrazine, etc. Alternatively, a mixture of two or more kinds of solvents may be stirred as a solution for 5 hours to 30 hours. The reaction is carried out at 205⁄4 to 8 Torr. (The solvent is removed by drying under reduced pressure to obtain valine acid. The amine acid is refluxed in the above solvent at a boiling point of the solvent for 0.5 hours to 3 hours, or the compound itself is heated at 160°. (:~200° C., subjected to dehydration ring closure, and dried under reduced pressure. The target compound is obtained by a solvent, and can be confirmed as a target compound by NMr and IR. The η used in the present invention is 4 Specific examples of the alkenyl-substituted nadic acid ruthenium imine compound include the following compounds: ^Teb (dilylbicyclo[2.2.1]hept-5-ene-2,3-dimercaptoimine) IV The IR spectrum and 1H-NMR spectrum (400 MHz) of "Tetrakis ANITAM" "TetrakisANlTAM" are shown in Fig. 7 and Fig. 8. In the IR spectrum, 'attributed to olefin CH stretching: 3060 cm·1, 2972 cm, Attributable to the scented C-Η telescopic: 2972 cm"; attributed to hydrocarbon-burning CH stretching: 2936 cm·1; attributable to 醯imine 〇〇 stretching: 1776, 1706 cm 1 ; attributable to C=C expansion: 1638 cm_1 ; is attributed to 醯 imine CN stretching: 1404 cm_], etc. [Chem. 73] 90 200902644 27225pif

In the h-NMR spectrum, it belongs to a proton to d proton (16H): peak of 6.80 ppm to 7.59 ppm; attributed to e, f, g, i, l proton (24H): peak of 2.25 ppm~3·60 ppm ; belonging to j, k, m, n proton (16H): 5.04 ppm ~ 6.50 ppm peak; attributed to h proton (8H): 1.25 ppm ~ 1.75 ppm peak. The preferred alkenyl-substituted nadic acid ylidene imide compound (C) of the present invention is a low molecular weight quinone imine monomer having a bulky structure, and thus is soluble in most organic solvents even when stored in a solution state for a long period of time. It can be used stably without precipitation or gelation of crystals. Further, the polyimine which is formed into a three-dimensional crosslinked structure by heating exhibits good heat resistance, mechanical properties, electrical properties, and drug sealing properties. 4 Solvent (D) 200902644 Substituting Nadickic acid hydrazide 4f / ^ molecular compound (b), gynecyl lysine (4) with water containing secret - to dissolve molecular compound (8), thief take 2 thief (4), if necessary Highly soluble, there is no special ship system. X, Yi b compound (C), r At, 呎疋 early alone can not dissolve lysine (A), Shixi me acid U,), and if necessary, polymer compound) Replace Nadick The amine compound is mixed with the solvent of the olefinic solvent, and is used as a solvent for the black blister. It can also be exemplified by the specific example of N-methyl-2•scale and lf^(D): N-methyl propyl _ , L: _, N-methyl caprolactam, decyl decylamine, hydrazine, hydrazine, diethyl hydrazine, hydrazinyl hard, bi-ester, lactic acid, 3-methyl _3_甲4^, diethyl ethanoamine, hydrazine, butane glycol monotop, diethylene glycol monobutanol, tetrahydronaphthalene, isophora, diethylene glycol dioxime, two Ethylene glycol methoxide monoethyl acetate vinegar, propylene glycol monotop, propylene glycol monomethyl / ethyl _, triethylene glycol monoethyl _, 3-methoxy propionic acid methyl vinegar, 3 n ethyl, dipropylene glycol monomethyl Anthracene, ethanol, 2-propanol, dioxane, ethyl ethyl ester, diethyl malonate, monool, and the like. As described above, the ink jet of the present invention is not limited, and the solvent contained in the silk imprint is not particularly limited or the internal filter material may be corroded or swelled in the J gauge. Alternatively, the solvent of the type of dry &amp; the faster-growing solvent causes the ink jet head 92 200902644 27225pif to be generated, etc., so the choice of the solvent (D) is very important. As a result of intensive research, the inventors found that it is possible to improve the long-lasting effect of the black-spraying M or the nozzles, and to stop the +--------------------------------------------------------------------------------------- In terms of properties, lactic acid ethyl ester, diethylene glycol methyl ethyl (tetra): diethyl ether acetate, diethylene glycol dimethyl ether, hydrazine, y-butane, as solvent (D) it is good. The size of the latex C/large is due to the influence of the surface tension of the ink on the coating properties of the inkjet ink 45 mN/m, good: ί: the surface tension of the ink is adjusted to 20 〜, the ink ejection port H 5 The spray of mN/m ink is good _ face 0^ _ coffee) becomes stable, the solvent phase is in the range of “run ~ 45 — — Si wants. A surface tension of -45 (for example, _ t solvent' can be used, and if a solvent having a large surface tension is mixed (for example, two, ^^ (4) and a solvent having a small surface activity - alcohol methyl ethyl hydrazine: 24 mN / m or B-alcohol succinct r = / m), it can be better to form the surface tension tension, so it is better. Review ~ N methyl amide, N, N dimethyl carbamide, N,N-diethyl''amine, acetamide, N-methylacetamide, N,N-dimethylacetamide, bis-ethylidene, N-methylamine, hydrazine, hydrazine , Ν', Ν, _ tetramethylurea, 2 · —— soil -2-. Bismuth, ε _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Hypoamic acid (A), lysine (Α,) 93 200902644

Z/ZZDpiT or a polymer compound (B) or an alkenyl group is a good solvent for the nadic acid ylidene imide compound (C), so that it can be preferably used, but on the other hand, the solvent affects the durability of the ink jet head. So need to pay attention. Preferably, 70 of the solvent (D) contained in the inkjet ink of the present invention contains no guanamine-based solvent, or at most 20% by weight or less based on the total weight of the solvent (D). 3 Xuanqing> The granules can be used alone or in combination of two or more. Hydramine (A), 矽醯胗醅^ y/v. 7 /1 person ti / —_ 丄 and ene substituted turbid acid yttrium imide also gold material _ this 5 Ming towel, spray The lysine (A) and the stone stalk t of the money ink towel. The total concentration of /夂^ is not particularly limited, and is preferably from 1 wt% to 99 70 wt%. If it is a ship, it is better to use 22(10)~, and the ejection precision is high. The film thickness obtained by one inkjet is optimal. The ink is not fixed. The ink: the concentrated wt% of the polymer compound (B) in the ink ^25 wt〇/〇0 . ^ 〇Γ%^5° Wt% 5 gives good characteristics, and:::the range of agronomics' can be used as an insulating film to read and read the silky nucleus imine, limited by It is better to use it as a good feature, but the degree range is 94 200902644 27225pif. When used as an ink for inkjet, it is the case of A. sulphate (A.) and polymer compound (4) (A) and/or the yttrium ylide compound (C), the thicker the sulphate and the alkenyl substituted Nadi film, the better, but the 醯, the resulting polyimine 臈 臈, so sometimes There will be no problems: the results of the efforts of the people who have been working hard since the inkjet two became high. The present invention is preferably used as a formable thicker concentration range of water. An inkjet ink such as a quinone imine film or (d) an amino acid (A,), an amine acid (4), and a dilute-substituted nadic acid-imidized second substance are obtained by molecular compounds (8) and (D). And if necessary, the solvent is further mixed, and according to the desired characteristics, the following method is obtained: if necessary, the ink for inkjet can be selected by using, for example, a surfactant, an antistatic agent, a doll, an oxygen resin, an acrylic resin, Agent, amine ruthenium compound, ρΗ value adjustment, 1, epoxy curing agent such as stupid tricarboxylic acid, antioxidant, reduction inhibitor = travel anti-recording agent, preservative, mildew/gluten polymer, pigment, , χ promoter, chelating agent, water Yang,, (4) (4) dissolved. + The ink for inkjet according to the present invention is an epoxy resin contained in an ink for inkjet ink. In the present invention, the epoxy bismuth (_ane) II, the epoxy bismuth (Qxirane) has two or more epoxy oximes = particularly limited, preferably 95 200902644 in the present invention, the mouth black Preferably, it is preferred that the concentration of the epoxy resin in the crucible 1 is not particularly Wt%. If the weight is 〖~2G, which is better than 1 wt% to 10, heat resistance and chemical resistance, the epoxy resin of the coating film formed by the inkjet ink may be, for example, a type II ester. Epoxy resin, bismuth S-bisphenol quinone type oxy-oxygen resin, glycidyl polymer, and copolymer with bismuth: % oxy resin, monomer with epoxy ethidene and epoxy resin and other monomers Wait. Specific examples of acid methyl glycosphate Li, 4·epoxycyclohexan vinegar and (meth) propylene; column: n-fired single, one of the other monomers copolymerized) propylene (mercapto) acrylic acid, ( Methyl methacrylate, (曱二, (审^,·曰/(曱)) isopropyl acrylate, (曱) acrylic acid n-butyl: aceamic acid ΐ ΐ: dilute acid isobutyl 11: (fluorenyl) Acrylic acid tributyl, (fluorenyl) t: &lt; 1, (benzyl) benzyl acrylate, (mercapto) acrylic acid 2-hydroxyacetamidine,: base \ acrylic acid 2 _ propyl acetoacetate, phenyl Tethered, methyl styrene, chlorine: stupid ethylene, (meth)propionic acid (3 · ethyl-3-epoxypropyl) vinegar, N-cyclohexyl maleimide and N-phenyl maleimide, etc. Preferred examples of the copolymer of a monomer having ethylene oxide and a copolymer of a monomer having ethylene oxide and another monomer include poly Glycidyl methacrylate, decyl methacrylate-glycidyl glycerol conjugate, benzyl methacrylate _ methacrylate glycidyl methacrylate copolymer, n-butyl methacrylate - methacrylic acid glycidol ester Polymer, 2-hydroxyethyl methacrylate-glycidyl methacrylate copolymer, mercapto propylene 96 200902644 27225pif acid (3-ethyl-3-epoxypropyl) 曱g--methacrylic acid glycidol The ester copolymer and the styrene-glycidyl methacrylate copolymer. If the inkjet ink of the present invention contains the epoxy resin, the coating film formed of the inkjet ink has good heat resistance, so it is preferable. Specific examples of the epoxy resin which can be contained in the inkjet ink of the present invention include "Epikote 807", "Epikote 815", "Epikote 825", "Epikote 827", "Epikote 828", and "Epikote". 190P", "Epikote 191P" (above, manufactured by Yuka Shell Epoxy Co., Ltd.), trade name "Epikote 1004", "Epikote 1256" (above, manufactured by Nippon Epoxy Co., Ltd.), Trade name "Araldite CY177", trade name "Araldite CY184" (manufactured by Ciba-Geigy Co., Ltd.), trade name r Celloxide 2021P", "Celloxide 3000", "EHPE- 3150" (manufactured by Daicel Chemical Industry Co., Ltd.), trade name "Techmore VG3101L" (manufactured by Mitsui Chemicals, Inc.), ν, ν, ν', ν, -tetraglycidyl-m-xylylenediamine, 1, 3-Bis(Ν,Ν-diglycidylaminemethyl)cyclohexane, hydrazine, hydrazine, hydrazine\Ν|-tetraglycidyl-4,4'-diaminodiphenyl decane. In the above, when the trade name "Araldite CY184", the trade name "Celloxide 2021P", the trade name "Techmore VG3101L", and the trade name "Epikote 828" are used, the flatness of the obtained polyimide film is particularly good, so that it is good. The epoxy resin may be used singly or in combination of two or more. 6(2) Acrylic acid resin 97 200902644 The ink for inkjet may further contain an acrylic resin. The acrylic resin contained in the ink for nozzle ink is not particularly limited as long as it has an acrylonitrile group or a methyl propyl group. The concentration of the acrylic resin in the ink for inkjet is not particularly limited, and is preferably 0.1 Wt% to 20 wt%. ,even better is! Wt%~1〇 wt%. In the case of the concentration range, the heat resistance of the coating film formed of the inkjet ink is good, and the chemical property and flatness are good. Examples of the acrylic resin include a monofunctional poly-I form having a hydroxyl group, a monofunctional polymerizable monomer having no silk, a difunctional (fluorenyl) propyl group, and a trifunctional polyfunctional group (methyl group). Specific examples of the monofunctional polymerizable monomer having a acrylic acid group include 2-hydroxyethyl acrylate, (meth)acrylic acid 2 methacrylic acid acrylate 4-pyridinium, or 】, 4_cyclohexene dicarboxylic acid vinegar and the like. Among them, in terms of the flexibility of the formed film, eucalyptus 'θ acrylic acid 4-pyridylpyridine, li4•cyclohexene dimethanol monoacrylic acid vinegar. Specific examples of the monofunctional polymerizable monomer are exemplified by (meth) propyl-glycidyl ester, (meth) propyl _3. (meth)acrylic acid methyl glycidol vinegar, 3 _Methyl propyl, :, methyl epoxidized, 3-ethyl-3-rmethyl decyl propyl lactopyl, 3-methyl-3 彳 methyl propylene _ soil ~ oxymethyl Epoxy propyl acrylate ethyl epoxide, A propoxy erythr epoxy, propylene methyl group % &lt; oxypropyl-3-yl f ether, 2-phenyl _ 3 fluorene hydrazine, dioxin '2 -: qijiamei 3 π, "methyl) ene methoxymethyl epoxide propylene oxymethyl epoxide, 4 _ triphos) propylene oxymethyl epoxide, ( Exhaustion C ^ 98 200902644 27225pif base) _, the purpose, (曱基) (10) acid ethyl g |, (mercapto) acrylic acid butyl vinegar, :: base) propane acid cyclohexanol ' (methyl (3 曰Ethene 3, ethylene, hydrazine methyl styrene, (oxyalkyl) propyl acrylate, N, cyclohexyl cis-butyl bis-imide, hydrazine, butyl-di-imide, ethylene Stupid, (meth) acrylamide, (A ^ ^ ^ yang 癸 ^ (4) (four) acid: cyclopentyloxy mercapto acrylic acid, vinegar, (meth) acrylate phthalate, glycerol ( =: SV polystyrene giant monomer, polymethyl methacrylate A: giant: lauryl alcohol ring m, H) acrylic acid 5_tetrahydrofurfuryloxycarbonyl pentane vinegar, acid, butyl s Methyl)acrylic acid vinegar, (meth) acrylic acid, yidi, cinnamic acid, cis-butanic acid, anti-butene rebel rf cis-succinic acid, methyl-butyric acid, vinegar, ^ Butadiene-succinic acid mono [2-(methyl)acrylic oxyethyl], etc. hexadeced _3,4_dicarboxylic acid mono[2_(methyl)propoxy-oxyethyl oxime (A Specific examples of the acrylic acid vinegar include: bis-F ring ester, iso: ethene ethane-modified diacrylic acid dilute acid 酉: 'Ethylene-burning modified two (10) acid hydrazine, polyethylene glycol two Propyl propanol dipropionate, keto-pentaerythritol diacrylate, single hard drink, 14 pento-propyl ester, quarter 16-hexane®, butyl diol diacrylate, : Alcohol two dilute vinegar, 壬 二甲 二甲 二 二 骑 骑 骑 丁基 丁基 丁基 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 2009 Acid vinegar, etc. Specific examples of trifunctional polyfunctional (meth) acrylates, Listed: trimethylolpropane tris(mercapto) acrylate, ethylene oxide modified trishydroxypropyl propane tri (meth) acrylate, propylene oxide modified trihydroxy decyl propane tris(fluorenyl) acrylate Ester, epichlorohydrin modified trihydroxymercaptopropane tris(indenyl) acrylate, di-trihydroxydecylpropane tetra(indenyl) acrylate, glycerol tris(decyl) acrylate, epichlorohydrin modification Tris(meth)acrylate, diglyceryltetrakis(meth)acrylate, pentaerythritol tri(meth)acrylate, pentaerythritol tetra(meth)acrylate, dipentaerythritol penta(indenyl)acrylate, alkyl modification Dipentaerythritol penta(indenyl) acrylate, alkyl modified dipentaerythritol tetrakis(meth) acrylate, alkyl modified dipentaerythritol tri(meth) acrylate, dipentaerythritol hexakisyl acrylate , caprolactone modified dipentaerythritol hexa(indenyl) acrylate, ethylene oxide modified tris(mercapto) acrylate, trimeric isocyanate tris[(indenyl) propylene oxiranyl ethyl] Vinegar, caprolactone modified trimeric isocyanate tris[(indenyl)-propyl Acyl oxy ethyl] ester, or amine Yue ester (meth) acrylate vinegar. These acrylic resins may be used singly or in combination of two or more kinds. 6 (3) Interface active portion 界面 When it is desired to improve the coatability of the inkjet ink, a surfactant which achieves this purpose can be added. Specific examples of the surfactant to be added to the inkjet ink of the present invention include "Byk-300", "Byk-306", "Byk-335", "Byk-310", and "Byk-". 341", "Byk-344", "Byk-370" 100 200902644 27225pif (manufactured by BYK Chemie Co., Ltd.) and other hairline surfactants; trade names "Byk-354", "Byk-358", "Byk-361" (byk Chemie ^ Injury Co., Ltd.) 荨 ;; acid 糸 surfactant; trade name "DFX-18", "ftergent 250", "ftergent 251" (manufactured by Ne〇s Co., Ltd.) and other fluorine-based interfacial activity Agent. These surfactants may be used alone or in combination of two or more. The surfactant 疋 is used for the pan wetness, leveling property or coating property of the base substrate. It is preferably used in combination with the weight portion of the ink for inkjet printing. ^ K4) 名静雷剂 The anti-static agent added to the ink for ink of the present invention can be used without any particular limitation. Tin, tin oxide, oxidation, and oxidation can be exemplified.

V is a metal oxide such as a compound or a second-order recording! 1 锡 锡 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化 氧化Ink used &quot;J', plus 〇·〇〗 Weights ~] tongue and eight reset injury and use. In the mouth II of the present invention, the alkoxylated compound can be used. The coupling agent added in the prior art is not particularly limited to an alkane coupling agent. Specifically, the coupling agent of the second addition is preferably a brothel. The compound 箄--alkoxydecane compound or two can be exemplified: 7·vinyl propyl 101 200902644 272 ρ ί 曱 曱 曱 珍 、 、 、 、 、 、 、 、 、 、 、 、 、 、 基 基 基 基 基 基 基 基 _ _ Propyl decyl dimethoxy decane, 7-propylene decyl propyl tridecyl decane, propylene decyl propyl decyl diethoxy decane, 7-propylene decyl propyl triethoxy decane, Τ-mercaptopropenylpropyl decyl decyloxydecane, methacryl propyl propyl trimethoxy decane, r-mercapto propylene propyl propyl methyl diethoxy decane, r-fluorenyl Propylene decyl propyl triethoxy decane, r-glycidoxy propyl decyl dimethoxy decane, glycidoxy propyl trimethoxy oxycarbazide, τ-glycidoxy propyl methyl 2. Ethoxy decane, r-glycidoxypropyl triethoxy decane, r-aminopropyl decyl decyloxy calcined, 7-amino group曱 曱 珍 珍 **, 7&quot;-aminopropyl decyl dimethoxy decane, aminopropyl triethoxy decane, N-aminoethyl-r-iminopropyl fluorenyl Dimethoxydecane, N-Aminoethyl-7-aminopropyltrimethoxyxanthine&lt;,N-Aminoethyl-7-aminopropyldiethoxylate, N-Benzene Benzyl-7-aminopropyl decyloxylate, N-phenyl-T-aminopropyltriethoxy pulverization, N-phenyl-7-aminopropyl decyl decyloxy Crushed, N-phenyl-aminopropylmethyldiethoxyoxycene, (T-mercaptopropyl decyl decyloxydecane, aminopropyltrimethoxy decane, 7-mercaptopropyl Methyl diethoxy decane, r-mercaptopropyl triethoxy decane, T-isocyanate propyl decyl diethoxy decane, isocyanate propyl triethoxy decane, etc. Among these, ethylene is exemplified. Propyltrimethoxydecane, 7-propenylpropyltrimethoxydecane, methacryl propyltrimethoxydecane, T-isocyanatepropyltriethoxydecane, etc. The mixture may be used alone or in combination of two or more types. 102 200902644 27225p If the agent is used, it is preferable to add 0.01 weight loss to 3 parts by weight with respect to the inkjet ink i〇〇 part by weight. 6-ί 6 ) - Add to the ink pad of this U ink The epoxy curing agent is not particularly limited, and an epoxy curing agent known in the art can be used. Specific examples thereof include diterpene compounds of organic acids, derivatives of imidazoles and imidazoles, and dicyanamide and iamide. An aromatic amine, a polyvalent decanoic acid, a polybasic slow acid anhydride, etc. More specifically, dicyandiamides, such as dicyandiamide, adipic acid, and 1,3-bis(decyl-ethene)_5_ Isopropyl B inner gland (substance (4) such as carboethyl) 5 isopropyl hydantoin) and other organic acid diterpenes, 2 4_ j ethyl ethyl ethyl triazine, 2 phenyl ♦ sit, ^ benzoate 4, A ^米°坐,2·phenyl ice methyl·5 曱 曱 base materials, etc. &quot;米°坐衍二曱酸酸, trimellitic anhydride, U,4-cyclohexanetricarboxylic acid-1,2 - Anhydride anhydride or the like. It is a well-turned trimellitic acid with 4·cyclohexene di-oroxic acid-1,2-xuan. These epoxy curing agents may be used alone or in combination of two or more. The % oxygen curing agent is preferably used in an amount of from 0.2 part by weight to 5 parts by weight per part by weight of the ink for the nozzle ink. An amine sulfonium compound can be added to the inkjet ink of the present invention. Amine Shishi compound can county: axis silk base three? Oxyhetero, p-aminophenyl 103 200902644 triethoxy decane, m-aminophenyl trimethoxy decane, m-aminophenyl triethoxy decane, aminopropyl trimethoxy decane, amine propyl Base trioxane and the like. —虱i It is also possible to mix two or two of these amine-based ruthenium compounds, and it is possible to use only one type or more. The amine ruthenium compound is used to improve the adhesion to the substrate, preferably

To 5 parts by weight of the ink for inkjet, 5 parts by weight to 2 parts by weight of ruthenium was added and used. In the present invention, the viscosity of the ink for inkjet is not particularly limited, and in the case of spraying at a temperature, it is preferable to improve the spray precision by the inkjet coating method, preferably ImPa.s~ 50mpa.s (25r,) is better 5mPa.s~3QmPa.s (25t), and then 8 is her a's s~20mPa · s (25°C). At a heating temperature (矽醯~120 ° C), it is s~30 mPa · s, and when the ink jet head is sprayed, the temperature at which the amine acid does not solidify is preferably 4 〇 t: mPa. S~5GmPa·s, preferably 5mPa·better 8mPa·s~2〇mPa imine film=inkjet The inkjet ink of the present invention is applied to the surface of the substrate, and heated in a ΊίΊ oven or the like. The treatment can form a full-size or predetermined pattern, a large-sized imine film. Further, the polyimine film of the present invention is not limited to heat treatment, and may be treated by ultraviolet (UV) treatment or sub-beam, electron beam, gammamy or the like. 104 200902644 27225pif The first step is to form a pattern of (4) imine film lithography technology, and this technique is used in a variety of large quantities of chemicals, such as light stripping liquid, and is required and wrong. In the engraving, the pattern-forming film formed by using the inkjet ink of the present invention is characterized in that it can be mass-produced in a variety of varieties by only the desired f-amine by charm printing, and the number of processes required for manufacturing is required. Qi Jun, so according to the ink ejection method, inkjet coating: piezoelectric element type, bubble mouth ink (bubbiejet) f_ 2) type, continuous injection type, electrostatic induction Uatie_ ^ booklet = appropriate to the ink towel Ingredients, can be invented = l == line jet, so that the mouth ink can be coated with ink as _ element of 4 water for coating better piezoelectric method: the nozzle with multiple nozzles Piece ==: Circumference;: = The pressure of the material is generated. The ink filled around the y-y member is displaced by the application of voltage = force, so that the ink is small (four) ejected from the nozzle. The inkjet coating device is not limited to the device of the coating head and the ink containing portion, and the material can not be separated from each other. In a form in which the method is integrated with the head and mounted on the bracket, there is also a configuration in which 105 200902644 I rzz^pii is placed in a fixed portion of the device, and ink is supplied through the ink supply portion. For example, if the &amp; sub-coating is applied, the ink cartridge is provided with an ink-receiving ink accommodating bag which can be used for the coating head, and the spring portion of the urging force. The coating apparatus wood is arranged in the form of a serial printer in which the coating medium is arranged in the range of the entire width of the coating medium as described above. ^ΜΜΜΜ. The coating method of 'Bright' by removing the solvent (9) by vaporizing the heat generated on the substrate by the application of the heat of the solvent (9), etc., thereby forming a proline (Α) and/or a membrane of proline (Α,). When the ink for inkjet further contains a polymer compound (8) or a dilute-substituted nadic acid-based imine compound (C), it can form a dream acid (8) and a domain (4) Lai (Α), a polymer. A composite film of the compound (8) and a dilute group-substituted nadic acid ruthenium imide compound (C). The heating conditions vary depending on the type of each component and the blending ratio. It is preferred that the temperature at which valine and glutamic acid do not solidify is usually 7 〇t to i2 (rc, used). In the case of a box, a dry film is formed in 5 minutes to 15 minutes. When the heating plate is used, a dry mash is formed in minutes to 5 minutes. 8.3 Polyimine amine 106 200902644 27225pif Forms proline (A) and / or a membrane of proline (Ai), or a sylvestreic acid (A) and / or; a glutamic acid (A,), a polymer compound (B) and an alkenyl substituted nadic acid After the composite film of the amine compound (c), in order to imidize the lysine (A) and/or the valine acid (A), it is preferably 15 Å. ~35〇艽, more preferably 2GGC~3GGC for the addition of the secret, to obtain the polyimide film (in the case of using the oven for 3 minutes ~ 9 minutes, when using the heating plate) 5 minutes to 3 minutes). In addition, in the case of the polymer compound (8) silk-acid or w-amic acid, When the film is formed into a pattern, the patterned polyimine is formed in the form of a pattern, and if it is not particularly expensive, the film is included. The patterned polyimide film is obtained in the case where the inkjet ink which is excellent in the resistance to brewing and electrical insulation is contained in the case where the ink is contained in the ink, and the chemical resistance is flat. It is preferable to use an insulating film excellent in adhesion and excellent visibility. ^The film-based yoke sneeze is obtained by, for example, on a substrate such as a polyimide film, by 嗔 = Γ a predetermined pattern The present invention dries the substrate and further heats it to form a polyelectron electron. #107200902644 For example, on a film substrate such as a polyimide film having a wiring formed in advance, by inkjet Coating method The inkjet ink of the present invention is applied, and then the film substrate is dried and further heated to form a flexible electronic component covered with an insulating polyimide film. Hereinafter, description will be made by way of examples and comparative examples. The present invention is not limited to the examples. The compound (al)' monoamine (a2) having two or more acids, 'anhydride group, used in the examples and the comparative examples, has an acid anhydride. a compound (al'), a diamine (anthracene, a compound having two or more acid anhydride groups (bl), a diamine (b2), a monoamine (b3), a dilute-substituted nadic acid amine (◦, And the name of the solvent (9) is written as abbreviated. This no. is used in the description of α. Very straight too gl vine in 2 &lt; acid anhydride based defensive ODPA. 3,3',4,4'-di-phenyl bond four 2,3',4,4'-diphenyl ketone tetrahydro acid dianhydride. 6FDA : 4,4'_hexafluoropropylene bisphthalate dixyl jL^,, Xa2) &gt; Cb3) APSE: 3-aminopropyltriethoxydecane UUJ solid anhydride group compound fay) TESA: triethoxy oxalyl propyl succinic anhydride ^J£-Xa2')&gt;(b2) DDS : 3,3'-diaminodiphenyl fluorene pDA: p-phenylenediamine 108 200902644 27225pif 7ΗΗΡ· 5'[((n-heptylcyclohexyl)ethylcyclohexyl)phenyl]methyl-1,3-diaminobenzene 7HB 1'1 bis[4-(4-aminobenzyl)phenyl]_4 _N-Heptylcyclohexene BAPP : 2,2_bis[4-(4-Aminophenoxy)phenyl]propane &amp;

_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _咹(c2) BANIM: bis{4_(allylbicyclo[2.2.1]hept-5-ene-2,3-di-succinimide)phenyl}decane-trienyl substituted naphth Acid amide (c3)

TrisANITAEA: three {4-(allylbicyclo[2.2.1]hepta-5,_23_monodecyl iodide)diethyl}amine

TrisANITrisAM: tris{4-(allylbicyclo[2.2.1]glycoside_23_dicarboxyindolimide)triphenyl}decane ’

TrisANIPARARO: tris{4-(allylbicyclo[2.2.1]heptan-2,3-dicarboxyindolimide) phenyl hydroxy decane tetraalkenyl substituted nadi ruthenate (c4)

TetrakisANITAM: tetra{4-(allylbicyclo[2.2.1]hept-5-bond-2,3-dicarboxyindolimide)tetraphenyl}decane solvent (D) EDM: diethylene glycol fluorenyl Ethyl ether GBL: 7&quot; - Ding Nike NMP: N-mercapto-2-pyrrolidone 109 200902644 [Example 1] Inkjet ink (1) Widely equipped with a lion machine and a raw material supply port 'Supply' The raw materials as described below were stirred in a dry nitrogen stream at room temperature to obtain a transparent phthalic acid (Α) 30 wt% solution. This solution was directly made into ink (1). Money will be. The viscosity of the solution was 10.8 mPa·s (200 million), and the surface tension (25 〇 was 33 mN/m. The viscosity of the solution was measured by an E-type viscosity meter (VISC〇NICELD manufactured by Τ〇Κγ〇ΚΕΙΚΙ). The tension was measured by a hanging drop method using an interfacial tensiometer (Drop Master 500 manufactured by Kyowa Interface Science Co., Ltd.), ° al : 0 DPA 12.4 g a2: APSE 17.6 g D : EDM 35.0 g D : GBL 35.0 g [ Example 2] Inkjet ink (2)

In a 500 ml four-necked flask equipped with a thermometer, a mixer, a raw material supply port, and a nitrogen inlet, the following materials were supplied, and the mixture was stirred for 5 hr under a dry nitrogen stream at 40 C to obtain a pale yellow transparent. A 50 wt% solution of polylysine (B). The viscosity of the solution was 586 mPa·s. The weight average molecular weight measured by GPC was 2,100. The weight average molecular weight of the polyamic acid is determined by diluting the obtained poly-tanic acid with tetrahydrofuran (THF) in such a manner that the concentration of the polyamic acid is about 1 wt%, so that the 甩GPC apparatus: 曰本分光Manufactured by the company, JASCO GULLIVER 1500 (Intelligent 110 200902644 27225pif differential differential refractometer RI-1530), using the above dilution as a developing agent, measured by Gpc method's conversion with polystyrene . The column is connected by the four columns G4000HXL, G3000HXL, G2500HXL and G2000HXL manufactured by T〇s〇h Co., Ltd. in this order, at a column temperature of 40 C and a flow rate of 1.0 ml/min. The measurement was carried out under the conditions. Bl : ODPA 55.0 g b2 : DDS li.Og b3 : APSE 59.0 g D : (3BL 291.0 g The solution of the proline (A) solution of Example 1 and the solution of the poly (resource) (0) was stirred as follows. A solid concentration of 30 wt〇/() solution was obtained at 2 hr'. This solution was used as an inkjet ink (2). The viscosity of the solution was 12.9 mPa*s (25C)' Surface tension (25 c) was 31.7 mN. /m. Aspartic acid (A) solution 64.0 g Poly-amino acid (B) solution 32.0 g D : GBL 24.0 g D : BDM 40.0 g [Example 3] Inkjet ink (3) Supply as follows The solution of the proline (A) solution of Example 1 and the alkenyl group substituted nalacid. The imine (C) 'mixed until the solid component was completely dissolved to obtain the astaxantine acid (A) / fine base substituted Nadick A 40 wty solution of the acid-coated imine (C) was used as the ink for inkjet (3). The viscosity of the solution was 18.1 mPa·s (25 C) and the surface tension (25C) was 31.8 mN/m. 111 200902644 z/zzjpn Proline (Α) solution 50 g c2 : BANIM 15 g D : GBL 5 g D : EDM 5 g [Example 4] The inkjet ink (1) prepared in Example 1 was used as Inkjet ink,

The inkjet coating device DMP-2831 manufactured by FUJIFILM Dimatix Co., Ltd. was set on a 1·5 mm thick glass epoxy double-coated steel sheet with a dot width of 1 μm and a dot pitch of 40 μm. . The heater of the ink jet head was set to 30 ° C, the piezoelectric voltage was 16 V, and the driving frequency was 5 kHz. The substrate was dried on a hot plate at 80 ° C for 5 minutes, and then heated in an oven at 23 ° C for 30 minutes to obtain an insulating film of a polyimine formed into a linear shape. The line width of the obtained polyimide film and the uniformity of the line width were observed with an optical microscope, and the film thickness was measured. The film thickness was measured by using the stylus type film thickness meter α-step 200' manufactured by KLA-Tencor Japan Co., Ltd. as the film thickness of the average value of the three places. The results are shown in Table 1. The wire has sufficient thickness. [Example 5] Further, 唆^^^, ^ &lt; ink for inkjet (2) prepared in Example 2 was used as the inkjet ink'. The same conditions as in Example 4 were obtained. An insulating film of imine. In the same price as her example 4. The results are shown in Table 1. [Example 6] The obtained polyimine film was evaluated to have sufficient thickness for the green polyimide film of Example 3. Ink (3) was used as the inkjet ink. In the same manner as in Example 4, an insulating film of polyimine was obtained except that the dot pitch was set to 20 μm. The obtained polyimide film was evaluated under the same conditions as in Example 4. The results are shown in Table 1. The wire has sufficient thickness. [Comparative Example 1] Inkjet ink (4) A polyamine acid (B) 50% solution of Example 2 was supplied as follows, and stirred under a nitrogen stream at room temperature to obtain a pale yellow transparent polyamine. 25 wt% solution of acid (B). This solution was used as an ink for inkjet (4). The viscosity of the solution was 12.3 mPa · s, the surface tension (25 ° C) was 33.2 mN/m ° Polyproline (B) solution 40.0 g D : EDM 30.0 g D : GBL 10.0 g [Comparative Example 2] An ink film for inkjet (4) prepared in Example 1 was used as an inkjet ink, and an insulating film of polyimide was obtained under the same conditions as in Example 4. The obtained polyimide film was evaluated under the same conditions as in Example 4. The results are shown in Table 1. The wire does not have a thickness of more than 1 micron. 113 200902644 [Table 1] Line width (/zm) Film thickness (//m) Ink viscosity (mPa · s) Example 4 85.3 1.67 10.8 Example 5 77.4 2.13 12.9 Example 6 103.0 2.50 18.1 Comparative example 2 66.0 0.89 12.3 [Example 7] Preparation of ink for inkjet (5) and formation of polyimide film The raw material was supplied as follows, except that the inkjet ink was prepared in accordance with the method of Example 1, and the viscosity was measured. Al : BTDA 12.6 g a2 : APSE 17.4 g D : EDM 35.0 g D : GBL 35.0 g Further, a polyimide film was formed in accordance with the method of Example 4. [Example 8] Preparation of ink for inkjet (6) and formation of polyimide film The inkjet ink was prepared in the same manner as in Example 1 except that the raw material was supplied as follows, and the viscosity was measured. Al : 6FDA 15.0 g a2 : APSE 15.0 g D : EDM 35.0 g D : GBL 35.0 g Further, a polyimide film was formed in accordance with the method of Example 4. 114 200902644 27225pif [Example 9] Preparation of inkjet ink (7) and formation of polyimide film The raw material was supplied as follows, except that the inkjet ink was prepared in accordance with the method of Example 1, and the viscosity was measured. . Al' : TESA 21.3 g a2' : DDS 8.7 g D : EDM 35.0 g D : GBL 35.0 g Further, a polyimide film was formed in accordance with the method of Example 4. [Example 10] Preparation of Inkjet Ink (8) and Formation of Polyimine Insulating Film The ink was prepared by the method of Example 1 except that the raw material was supplied as follows, and the viscosity was measured. Al' : TESA 25.5 g a2' : PDA 4.5 g D : EDM 35.0 g D : GBL 35.0 g Further, a polyimide film was formed in accordance with the method of Example 4. [Example 11] Preparation of ink for inkjet (9) and formation of polyimide film of insulating film An inkjet ink was prepared by the method of Example 1 except that the raw material was supplied as follows, and the viscosity was measured. Al,: TESA 16.6 g a2' : 7HHP 13.4 g 115 200902644 2/J.2^pn D : EDM 35.0 g D : GBL 35.0 g Further, a polyimide film was formed in accordance with the method of Example 4. [Example 12] Preparation of inkjet ink (10) and formation of polyimide film of insulating film An inkjet ink was prepared by the method of Example 1 except that the raw material was supplied as follows, and the viscosity was measured. Al' : TESA 15.8 g a2' : 7HB 14.2 g D : EDM 35.0 g D : GBL 35.0 g Further, a polyimide film was formed in accordance with the method of Example 4. [Example 13] Preparation of ink for inkjet (11) and formation of polyimide film of insulating film An inkjet ink was prepared by the method of Example 1 except that the raw material was supplied as follows, and the viscosity was measured. Al' : TESA 17.9 g a2' : BAPP 12.1 g D : EDM 35.0 g D : GBL 35.0 g For the examples 7 to 13, the obtained polyimine film was evaluated under the same conditions as in the example 4. The results are shown in Table 2. The wire has sufficient thickness. 116 200902644 27225pif [Table 2] Example 7 Line width (//m) Q〇η Film thickness (/zm) Example 8 112.2 1.83 1.45 ^ - Example 9 76.4 1.55 - 3 · υ Ο Λ - Example 10 Example 11 80.3 ------ 95.2 —------- 1.67 ----~- 1.64 Example 12 Example 13 Stomach 83.5 1 1.73 ----- 2.12 Although the present invention has been exemplified As disclosed above, the invention of the present invention is intended to be modified and retouched in the spirit of the present invention. Therefore, the protection of the present invention is defined by the scope of the patent application. Prevail. [Industrial Applicability] The active film of the present invention may, for example, be an insulating film for a flexible wiring board or an electronic component using the insulating film. [Simple diagram of the figure] Figure 1 shows the IR spectrum of "TrisANITAEA". Figure 2 shows the 1H-NMR spectrum of "TrisANITAEA". Figure 3 shows the IR spectrum of "TrisANITrisAM". Figure 4 shows the 1H-NMR spectrum of "TrisANITrisAM". Figure 5 shows the IR spectrum of "TrisANIPARARO". Figure 6 shows the 1H-NMR spectrum of "TrisANIPARARO". Figure 7 shows the IR spectrum of "TetrakisANITAM". Figure 8 shows the 1H-NMR spectrum of "TetrakisANITAM". 117 200902644 z/zz^pir [Key component symbol description] None

Claims (1)

200902644 X. Patent Application Range: 1. An inkjet ink comprising: an anthracene compound (A) selected from the group consisting of a compound (al) having an acid anhydride group of 2 or more and a monoamine (a2), and At least one of the compound (A') obtained by using the compound (al') having one acid anhydride group and the diamine (a2') is used. 2. The ink for inkjet according to claim 1, wherein the compound (al) having two or more acid anhydride groups is a tetracarboxylic dianhydride represented by the following formula (1), a monoamine (a2) is an amine-based compound represented by the following formula (2), [Chemical Formula 1] 〇 〇 0 〇 (1) (In the formula (1), X is a tetravalent organic group having a carbon number of 2 to 100, and in the formula (2), R1, R2 and R3 are hydrogen, halogen or a monovalent organic group, and these may be the same or different. Y is an organic group having 1 to 20 carbon atoms). 3. The ink for inkjet according to Item 2, wherein the tetracarboxylic dianhydride is selected from the group consisting of pyromellitic dianhydride and 3,3',4,4'-diphenyl ketone. Carboxylic dianhydride, 2,2,3,3'-diphenyl ketone tetracarboxylic dianhydride, 2,3,3',4'-diphenyl ketone tetracarboxylic dianhydride, 3,3', 4,4'-diphenyl sulfone tetracarboxylic dianhydride, 2,2',3,3'-diphenyl sulfone tetracarboxylic dianhydride, 2,3,3',I-diphenylstilbene tetracarboxylate Acid dianhydride, 3,3\4,4'-diphenyl ether tetracarboxylic dianhydride, 2,2',3,3^diphenyl ether tetracarboxylic dianhydride, 2,3,3',4 '-Diphenyl ether tetracarboxylic dianhydride, 2,2-[bis(3,4-dicarboxyphenyl)]hexafluoropropane dianhydride, ethylene glycol bis(trimellitic anhydride), cyclobutyl Alkane tetracarboxyl 119 200902644 z acid monoanhydride, methylcyclobutane tetracarboxylic dianhydride, cyclopentane tetracarboxylic dianhydride, 1,2,4,5-cyclohexane tetracarboxylic dianhydride, ethane four One or more of a group consisting of a carboxylic acid dianhydride and a butane tetracarboxy sialic anhydride selected from the group consisting of p-aminophenyltrimethoxydecane and p-aminophenyloxyl Base decane, m-aminophenyl trimethoxy decane, m-amino The group consisting of residues triethoxysilane, aminopropyl group, (iv) and three Yue aminopropyl diethoxy rock embankment of the evening to a The ink for ink jet according to item 1 of the patent scope is as described in the following formula (3) &lt; (4) Aminic acid &amp; k逋only Λ R2 and R3 are hydrogen (3) The tetravalent organic group of the main group, Ri, halogen or monovalent organic group, which is different from the gentleman, Y is an organic group having a carbon number of 1 to 20). ^二一等或5. The inkjet as described in claim 4, wherein the proline acid is of the following formula (44) 444) or wherein the proline acid, (4-3) Means [化3] 120 200902644 ο R1 R3 (4-1) R1 R3 K, 'NH-(CH2)--Si-R2 α I (4-2) R1 NH-(CH2)—Si—r2 R3 COOH K (4-3) R2~Si—(H2C)—HN I 3 c4_3) f , ri'r2^ , 夕—Alkane with a carbon number of 1~2〇 Alkoxy, a is the number of 1 to 20). The ratio of the compound ear a of the above-mentioned monoamine (a2) to the above-mentioned single-amine (a2) having the acid anhydride group of two or more is as described in the above-mentioned. Moer: 〇·5莫耳~8 〇莫黑用^Applicable to the patent (4) 1 to 5th towel--the spray of 'soil' and water, wherein the above compound having one anhydride group ( Ar) is a carboxylic acid anhydride represented by the formula (1), and the diamine (a2,) is a diamine represented by the following formula: (Chemical Formula 4) 121 200902644 ο Si-R2 (r) η2ν—x′—νη2 (2·) R—and for the mouse, pixel or monovalent organic group, which may be the same or different, Υ, is an organic group having a number of 1 to 20, and the formula (2' In the formula, X is a divalent organic group having a carbon number of 2 to 100). 8. The ink for inkjet according to Item 7, wherein the carboxylic acid anhydride is selected from the group consisting of p-(trimethoxydecylalkyl) phenylsuccinic anhydride, and p-(triethoxy-stone) Alkyl anhydride, m-(trimethoxy oxalate) phenyl succinic anhydride, m-(triethoxysulfonyl) phenyl cyanoic anhydride, trimethoxydecyl propyl succinic anhydride, and triethoxy One or more selected from the group consisting of p-phenylenediamine, m-phenylenediamine, p-xylenediamine, 4,4'-diaminodiphenyl Decane, 4,4'-diamino-1,2.diphenylethane, 4,4'-diamino-1,3-diphenylpropane, 2,2-bis(4-amino group Phenyl)alkane, bis(4-amino-3-indolylphenyl)methane, anthracene, 2-bis-(4-amino-3-indolylphenyl)ethane, bis(4-amine -2-methylphenyl)methane, 12-bis&lt;4-amino-2-indolyl) ethane, 4,4'-diaminodiphenyl ether, 3,3,-diamine Diphenyl ether, 4,4,-diaminodiphenylanthracene, 4,4'-diaminodiphenyl sulfide, 4,4'-diaminodiphenyl ketone, 4,4'- Diaminodiphenyl-2,2 -propane, 1,4-diaminocyclohexane, 4,4'-diaminodicyclohexylmethane; [,4_bis[(4-aminophenyl)methyl]benzene, 1, 4-bis(4-aminophenoxy)benzene, 1,3-bis(4-aminophenoxy)benzene, 2,2-bis[4-(4-aminophenoxy)phenyl] Propane, 2,2_bis[4_(4-aminophenyloxy)phenyl] 122 200902644 27225ριί Fluoropropane, bis[4-(4-aminophenoxy)phenyl], double [4_(4 -aminophenyloxy)phenyl]biphenyl, U-bis[4-(4.aminobenzyl)phenyl]propane, 1,6-bis[4_(^-aminobenzyl)phenyl] Hexane, 5-phenylmethyl-^-diaminobenzene, 5-[4-(4-carbocyclohexyl)benyl]methyl-1,3-diaminobenzene, 5·[4_(4_(4) ·院基环己,) cyclohexyl)phenyl]methyldiaminobenzene, 5-[((alkylcyclohexyl)ethylf-hexyl)phenyl]decyl-1,3-diaminobenzene, amine Phenyloxy)phenyl]cyclohexane, 1,1-bis[4-(4-aminophenoxy)phenyl]_4-alkylcyclohexane, bis[4_(4-aminobenzyl) Phenyl]cyclohexane, 1,1-bis[4.(4-amino)phenyl]-4-alkylcyclohexane; 1,3_bis(3-aminopropyl) One or one of the groups consisting of tetramethyl dioxane on. 9. The ink for inkjet according to any one of the items of the present invention, wherein the above-mentioned compound (AI) is an oxime amine represented by the following formula (7). ), [Chemical 5] #4—, 〇Η Η 〇R1 Jl丨I II 〒 -C—N—X'-N—c—-r—Si—R2 (3-) r/3 C〇〇H HO 〇 / Right 媸 L L L (3) towel 'R, R and R. The hydrogen, halogen or - may be the same or different, γ is an organic group having 1 to 20 carbon atoms, and Α is an organic group having an anisotropy of 2 to 100).喷墨 如 如 如 如 如 如 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨 喷墨Si-(H2C) R3 R1 〇 I IIH R2-Si—(Η2〇^-ρ~Ν- R3 γ-ΟΗ 〇 (In the general formula (4'-l), (bucket '·^), ^"), (4, -4) or (4, -5), at least one of R, R and R3 contains a carbon number 丨~ 2 is an alkoxy group, R of the formula (4'-3) is an organic group having 2 to 3 carbon atoms, and R of the formula (4,-4) is hydrogen or an alkyl group having 1 to 20 carbon atoms. a is an integer from 1 to 2). U. The spray according to any one of claims 1 to 5, 200902644 2. The ink for ink jetting according to any one of the items of the present invention, wherein the ink for ink jetting further comprises a polymer ink for ink, wherein the ink for ink jetting is used. Further, as described in claim 12, the above-mentioned molecular compound (B) is at least one selected from the group consisting of polyamic acid. The ink for inkjet according to Item 12, wherein (B) is selected from the group consisting of poly-proline and polyimine, such as the spray (four) ink of the application of the special fiber -12, and the above polymer compound ( The weight average molecular weight of B) is 丨'(4)~^(8). 15. The ink for spray according to any one of clauses 1-5 to 5, wherein the inkjet ink further comprises a rare-substituted alkenyl-substituted nadimide (C) ). 1. The inkjet ink according to Item 15, wherein the alkenyl-substituted nadic acid imide (C) is a monoamine, a _de/, a monoamine or a tetraamine and the following formula (7) The dilute base is expressed as follows:::Di 2: Alkenyl substituted nadic acid ylide imine, [Chem. 7] In the formula (5,), R1 and R2 are each independently hydrogen, an alkyl group having a carbon number, an alkenyl group having 3 to 6 carbon atoms, a cycloalkyl group having 5 to 8 carbon atoms, an aryl group having 6 to 12 carbon atoms or benzyl group. Any of the bases. The ink for inkjet according to claim 15, wherein the alkenyl-substituted nadic acid ylide (C) is a compound represented by the following formula (5), [Chem. 8] N-R3 (5) In the formula (5), R1 and R2 are each independently hydrogen, an alkyl group having a carbon number of 丨12, an alkenyl group having a number of 3 to 6 carbon atoms, a cycloalkyl group having a carbon number of 5 to 8, and a carbon number of 6 to 12; Or any one of the benzyl groups, wherein ^ is an integer of 1 to 4, wherein R3 in the formula (5) is hydrogen, an alkyl group having a carbon number of from 10 to 12, a hydroxyalkyl group having a carbon number of from 1 to 12, and a carbon number of 5 Cycloalkyl group of -8, aryl group of 6 to 12 carbon atoms, benzyl group, -{(CqH2q)Ot(CrH2r〇)uCsH2sX} (wherein q, r, s are independently selected as integers of 2 to 6, respectively t is an integer of 〇 or 丨, u is an integer from 1 to 30, X is hydrogen or a polyoxyalkylene group represented by a group, -(R)a-C6H4-R4 (where a represents 〇 or j An integer, R represents an alkylene group having 1 to 4 carbon atoms, R4 represents a hydrogen group or an alkyl group having a carbon number of 丨~4, and -C6H4-T-C6H5 {where T is -CH2-, - a group represented by C(CH3>-, 〇-/- or -S〇2-}, or a group of 1 to 3 hydrogen-substituted groups directly bonded to the aromatic ring of the group 3 , when n = 2, R3 in the formula (5) is an alkylene group having a carbon number of 2 to 2 Å. Any methylene group which is not adjacent to each other in the sub-system group may be _〇_ or _ch =ch is substituted, any hydrogen can be substituted by fluorine}, a cycloalkylene group having a carbon number of 5~8, -{(CqH2ciO)t(CrH2rO)uCsH2s}_ (where 'q, r, s are independently selected 126 200902644 Select an integer of 2 to 6 't is an integer of 0 or 1, u is an integer of 〜3〇), represented by a polyoxyalkylene group, a carbon number of 6 to 12, an arylene group, (where a is 〇 or an integer of the formula, R and R5 are each independently an alkylene group having 1 to 4 carbon atoms, represented by -c6h4-t-c6h4-, -c6h4-t-c6h4-t-c6h4- or - C6H4-r-C6H4-T-C6H4-r-C6H4- {where T is a single bond, an alkylene group having a carbon number of j 1-6, _C(Ch3)2_, _C(CF3)2_, _c〇..._〇· - 〇C6H4C(CH3)2C6H40-, -s- or -S02-, Γ is -CH2- or _〇_} groups represented by jin, or 1 directly bonded to the aromatic ring of the groups ～3 groups in which hydrogen is substituted by a hydroxyl group, a group represented by the following formula (64) or a group represented by the following formula (6-2), and in the formula (6_υ, χ is independently an integer of ～6) y An integer from 1 to 70, [Chem. 9] When n==3, R3 in the formula (5) is a group represented by the following formula (7-1): a group represented by the following formula (7-2), [Chem. 10] 127 200902644 .R6 R R4 R4 .N (7-1) R6 (7-2) 'R in the formula (7_1) is hydrogen, fluorine, chlorine, -OH, -OCF3, -〇CF2H, -cf3, -cf2h, -cfh2 , OCF2cF2H, _〇CF, CFHCF3, or an alkyl group having a carbon number of 1 to 10, in the formula (7-1) and the formula (7_2), r4, r5, and r6 are each independently a tree, an inverse _M_cyclohexylene group, U_n2,5-diyl, phenylene, hydrogen, difluoro-substituted 1,4-phenylene or "charo-b]; sub-alkyl, sub-alkyl, not __ methylene (4) or (Η·· Substituting 'arbitrary hydrogen may be substituted by fluorine, and when η = 4, the formula (5) in the evening|&gt;3仏 is a group represented by the following formula (8), [Chem. 11] R6 R5 , R4 (8) In class (8), R, R3, R6 and ruler 7 are each independently a single bond, anti-kappa hexyl, 1,3-di-wei-2,5-diyl, fluorene _ phenylene, hydrogen can be substituted by fluorine, 1,4-phenylene or carbon number ho, the sub-homogeneous non-adjacent of any fluorenyl group can be passed by (;) Cheng _CH= CH_ substituted, any gas can be substituted by fluorine. 18. The ink for inkjet according to claim 17, wherein n is 2 〇 19. The ink for inkjet according to the invention of claim 5, wherein 128 200902644 j /-υμιι n Is 2, R in the formula (5). Any fluorenylmethyl group which is not adjacent to each other in the alkylene sulfinyl group having 2 to i5 carbon atoms may be substituted by _CH=CH-, and any hydrogen may be substituted by fluorine}, -(RVQH^R5-( Wherein, a is an integer of 〇 or ], and R and R5 are each independently a carbon number of 1-4 alkylene groups, which are represented by -CHQH4-'-C6H4-T-C6H4-T-C6H4- or -C6H4-r-C6H4-T-C6H4-r-C6H4- {where τ is a single bond, -CH2-, -C(CH3)2-'-C(CF3)2-'-CO-^-0- -0C6H4C(CH3)2C6H40- 'f' _S_ or _s〇2_ 'r is a group represented by _CH2· or -〇-}. 20. For inkjet according to claim 17 In the ink, wherein R) and R2 in the formula (5) are each independently hydrogen or an alkyl group having a carbon number of 丨~6, and η is 2'. wherein R3 in the formula (5) is an alkylene group having 2 to 15 carbon atoms. Any of the alkylidene groups in the alkyl group which are not adjacent to each other may be substituted by -0- or -CH=CH-, and any hydrogen may be substituted by fluorine to the group represented by the formula (64), and the formula (6-2) a group represented by the formula, a group represented by the formula (6-3), a group represented by the formula (6-4), or a group represented by the formula (6-5), [Chemical 12] 129 200902644 e 2 c X o e y Μ——si——M e π2 c e X ώ /(\ (6-2) _ (6-3) (6~4) (6-5) In the equation (6-1), χ is an integer of i~6, and y is the whole formula of ～7〇(6- 3) and in the formula (6-5), R is an organic group containing _CH2...CH2cH2_, -Ο-, -C(CH3)2-, -C(CF3)2_, _s〇2_, formula (6- In 5), X is an organic group containing _CH2...七. 21. The ink for inkjet according to claim 17, wherein R1 and r2 in ^(5) are separated from hydrogen or Wei, and ^3' is (1) &amp; 7-M), Formula (1)·n 130 200902644 or Formula (7-2-2) means [Chem. 13] In the formula (7-1-1), r is a carbon number of 1 V.. /N, R6 (7^2-2) 10 or a group of _〇H ^ , n- -un 7 (7-2- In 2), r4, r5 and R6 are each independently an ethylene group and a 1,4-butylene group. '土 22. In the inkjet ink according to item n of the patent application, R) and R2 in the formula (5) are each independently hydrogen or a carbon number group, and a few η is 4' in the formula (5) V is the following [Chem. 14] 'U-1) Table is not '131 200902644 23. The ink for inkjet according to claim 1, wherein the ink for inkjet contains a base selected from the group consisting of an alkenyl-substituted nadic acid ylide (N) having a η of 1, and a η of 2. Replacing at least two of Nadick's acid imine (c), η of 3 alkenyl substituted nadic acid yttrium imide (c), and η of 4 alkenyl substituted nadic acid yttrium imine (C) Alkenyl substituted nadic acid ylide (C). 24. The ink for inkjet according to claim 17, wherein the ink for inkjet contains at least two kinds of alkenyl substituted nadic acid amide (C) as follows: &lt;R1 and R2 in (5) Each of which is independently hydrogen or a carbon number i 1-6, wherein R 3 is an alkyl group having a carbon number of 12 12 (n = 1), a carbon number of 6 2 (n-1), - ( CH2)P (n = 2, p is an integer of 6 to 12), a group represented by the formula (6-1-1), a group represented by the formula (6-2), and a formula (6-3-1) The group represented by the group represented by the formula (6-4), the group represented by the formula (7), the group represented by the formula (?), and the formula (7-2-1) a group, a group represented by the formula (7_2_3), a group represented by the formula (8-1), 132 200902644 27225pif [Chemical 15] -CH' Me Me 0 岭 h3c ch2 ie ^^CHs Me (6- 1-1) n=2 F3C CF (6-2) n = 2 (64) n=2 (6-5-1) n=2 'N (7-2-3) n=3 133 200902644 Ink ink for use in any of items 1 to 5 of the patent application, wherein the inkjet ink further contains a solvent (D).贺26. The inkjet ink according to claim 25, wherein the solvent (9) is selected from the group consisting of lactic acid ethyl acetate, ethanol, ethylene glycol, :, oil, diethylene glycol dimethyl ether, and diethylene glycol. Alcohol diethyl ether, diethylene glycol base, diethylene glycol monoacetic acid vinegar, ethylene glycol monobutyl, ethylene diethylene glycol: propylene glycol monomethyl acetic acid, 3-methoxypropionic acid A group of methyl ketone early cyclohexanone in the group consisting of TM 27. For example, in the ink of any one of the scope of claims 1 to 5, in which 1 part by weight of inkjet ink is used, : 述石^ The compound (A) and the total content of the above-mentioned compound (A,) are ～99 parts by weight. The inkjet ink according to any one of the preceding claims, wherein the above-mentioned bismuth compound (A) and the above-mentioned stone eve are used with respect to 100 parts by weight of the ink for inkjet. The total content of the compound (4) is from 1 part by weight to 80 parts by weight. 29. The ink for ink according to any one of the preceding claims, wherein the above-mentioned bismuth compound (4) and the above-mentioned stone compound U' are used with respect to 1 part by weight of the ink for inkjet. The total content is 22 parts by weight to 70 parts by weight. s 30. A t-imine film or a patterned polyimine film, the polyimide film or the patterned polyimide film is obtained by the following method: by inkjet 134 200902644 27225pit coating method, coating A coating film is formed by applying the ink for inkjet according to any one of the first to the twenty-ninth aspects of the invention, and the coating film is cured to form a polyimide film. 31. A method for forming a polyimine film or a patterned polyimide film, the method comprising the following steps: coating by the inkjet coating method, as in claim 1 to item 29 A process for forming a coating film by using the inkjet ink; and a process of curing the coating film to form a polyimide film. f 32. A film substrate having a polyimide film or a patterned polyimide film, the polyimide film or the patterned polyimide film being as described in claim 31 The method is formed on the substrate. 33. An electronic component having a film substrate as described in claim 32. 135