200845907 ‘九、發明說明： 、【發明所屬之技術領域】 本發明係有關殺蟲性氣膠組成物。 【先前技術】 已知含有3♦氰基小丙縣）_2,2_二甲基環丙燒缓酸 4·甲氧基甲基-2,3,5,6-四氟苯甲酯、二氯甲垸、已除#之煤 油及推進劑之殺蟲性氣膠組成物具有殺蟲活性（參2例如 美國專利第6908945號）。 _【發明内容】 本發明之目的為提供具有絕佳的殺蟲活性之氣膠組成 物。 為了找到具有絕佳殺蟲活性之氣膠組成物，本發明人 =行深人研紐發現含有3♦氰基小丙縣）_2,2i甲基 酸Γ氧…，3,5,㈣苯甲醋、有機溶劑 ^之殺蟲性氣膠組成物具有絕佳的殺蟲活性，其 _中該有機溶劑為飽和烴溶劑，因此創造本發明。 本發明提供： ._種殺蟲性氣膠組成物，包含3_(2_氰基小丙烯基戌2_ t甲基環丙烷羧酸4-甲氧基曱基_2,3,5,6·四氟苯曱 有機溶劑及推進劑’其中，該有機溶劑為飽和煙溶 =1項描述之殺蟲性氣膠組成物，其中，該組成物包 二相對於每重量份該飽和烴溶劑為〇·⑽⑽W至〇 1重 量份的量之3·(2·氰基七丙稀基）_2,2_二甲基環丙錢 320090 5 200845907 • 酸4-曱氧基甲基-2,3,5,6_四氟苯甲酯； * 3.第2項描述之殺蟲性氣膠組成物，其中，該組成物包含 相對於每重量份該飽和烴溶劑為0.25至8重量份的量 之該推進劑； 4·第1至3項中任一項描述之殺蟲性氣膠組成物，其中， 該組成物包含〇·〇〇1至1重量％的量之3气2_氰基丙 烯基）-2,2-二甲基環丙烷羧酸4_甲氧基甲基_2,3,5,6_四 氟本甲Ss 1 〇至79重置％的量之該餘和烴溶劑、以及 20至80重量％的量之該推進劑； 5·第1至4項中任一項描述之殺蟲性氣膠組成物，其中， 該乾和 谷剤係初沸點b〇iHng p〇int)g 或更南及95 A条餘溫度（95%-(^也1此〇11 teniperature) 為300 C或更低之飽和烴溶劑； 6·第1至5項中任一項描述之殺蟲性氣膠組成物，其中， 該組成物是用於防治蜚蠊目（Blattada)昆蟲； _ 7·第1至5項中任一項插述之殺蟲性氣膠組成物，其中， 該組成物是用於防治膜翅目（Hymen〇ptera)昆蟲； 第1至5項中任一項描述之殺蟲性氣膠組成物，其中， 該組成物是用於防治胡蜂科(Vespidae)昆蟲； 9· 一種防治有害f匕蟲之方法，包含將有效量之殺蟲性氣膠 組成物喷灑於該有害昆4或該昆蟲的棲地，該殺蟲性氣 膠組成物包含3_(2_氰基-1·丙烯基）-2,2-二甲基環丙烷 竣酉夂4-甲氧基甲基·2,3,5,6-四氣苯甲酯、有機溶劑以及 推進劍，立4?，, /、τ 该有機溶劑為飽和烴溶劑； 6 320090 200845907 • 10·第9項描述之方、土 4# 去’其中，該組成物包含相對於每重量 * 伤該飽和煙沒添|| 4 / 4為0.000001至0.1重量份的量之3-(2- 浠基>2,2-二曱基環丙烷羧酸‘甲氧基曱基 -2,3,5,6-四氟笨甲酯； •:1、〇項& 4之方法’其中’該組成物包含相對於每重 12 ΓΓ餘和烴溶劑為G·25至8重量份的量之該推進劑； .:。項f述之方法，其中，該組成物包含0.001至i重 的^之3_(2_氰基]丙烯基）Ί二甲基環丙烧緩 -文田-曱氧基曱基_2,3,5,6-四氟苯甲酯、1〇至79重量0/〇 的量之該飽和煙溶劑、以及2〇至80重量％的量之該推 進劑； 13.= 9至12項中任—項描述之方法，其中，該飽和烴溶 劍具有15Gt或更高的初沸點及3⑽1或更低的95%基 餾溫度； ^ 該方法是用 •第9至13項中任一項描述之方法，其中 於防治蜚蠊目昆蟲； 該方法是用 •第9至13項中任一項描述之方法，其中 於防治膜翅目昆蟲； 該方法是用 16·第9至13項中任一項描述之方法，其中 於防治胡蜂科昆蟲；以及 一種殺蟲性氣膠，包含第1至8項中任一項描述之殺蟲 性氣膠組成物。 很據本發明之殺蟲性氣膠組成物具有絕佳殺蟲活性。 【實施方式】 320090 7 .200845907 丙嫌^據么發明之殺蟲性氣膠組成物係包含3_(2-氰基 4 土·，甲基環丙駿酸4·甲氧基甲基-2,3,5,6_四氟 ^^=_為化合物Α)、有機溶劑及推進劑之殺 米 >、、且成物，其中，該有機溶劑為飽和烴溶劑。 化合物Α為如美國專利第69〇8945號所描述之化合 物，並能以該文獻中描述之方法製備。 雖然根據壤丙烧環中的兩個不對稱碳原子及雙鍵，化 合物A擁有異構物，但本發明可使用任何異構物或以任意 比例混合之異構物混合物。 根據本發明之殺蟲性氣膠組成物中的化合物A的含量 通常在0.001至50重量％之間，較佳在0.01至1重量％之 間。 根據本發明之殺蟲性氣膠組成物包含作為有機溶劑之 飽和烴溶劑。本發明使用之飽和烴溶劑通常為，例如:初 沸點為15(TC或更高及95%蒸餾溫度為30(rc或更低的溶 參劑/但當然也可使用初沸點為15(rc或更高及乾點…巧 point)為300°C或更低的溶劑。飽和烴溶劑的例子包括異鏈 文元挺G (Isopar G)(埃克森美孚公司（Exxon Mobil Corp.)製 造，初沸點：16(TC，乾點·· 176〇C)，異鏈烷烴L (埃克森 美孚公司製造，初沸點·· 189t，乾點·· 207它），異鏈烧烴 Η (埃克森美孚公司製造，初沸點·· i78〇c，乾點·· 188。〇， 兴鏈燒fe Μ (埃克森美孚公司製造，初沸點：223，乾點： 254 C)，正構烷烴13 (Norpar 13)(埃克森美孚公司製造， 初沸點：2221，乾點：242。〇，正構烷烴15 (埃克森美孚 320090 8 200845907 • 公司製造，初沸點：249°C，乾點：274°C )，脫芳香烴脂肪 . 族溶劑D40 (Exxsol D40)(埃克森美孚公司製造，初沸點： 164°C，乾點·· 192°C)，脫芳香烴脂肪族溶劑D60 (埃克森 美孚公司製造，初沸點：187°C，乾點：209°C)，脫芳香烴 脂肪族溶劑D80 (埃克森美孚公司製造，初沸點：208°C， 乾點：243°C )，尼奥奇佐（Neochiozol)(中央化成股份有限 公司（Chuokasei Co·，Ltd·)製造，初沸點：225°C，乾點： 247°C)，IP 溶劑 2028 (IP Solvent 2028)(出光股份有限公 •司（Idemitsu Kosan Co.，Ltd·)製造，初沸點：213°C，95% 蒸餾溫度：250°C)以及煤油。 根據本發明之殺蟲性氣膠組成物中的飽和烴溶劑的含 量通常在10至79重量％之間，較佳在20至70重量％之 根據本發明之殺蟲性氣膠組成物中含有之推進劑為具 有-50°C至沸點之液化氣體，推進劑之例子包括液化石 ⑩油氣（LPG)、二曱醚、丙烷、正丁烷以及異丁烷。根據本 發明之殺蟲性氣膠組成物中的推進劑的含量通常在20至 80重量％之間，較佳在25至75重量％之間。 根據本發明之殺蟲性氣膠組成物包含之酯類化合物及 飽和烴溶劑的比例通常落在下列範圍··相對於每重量份飽 和烴溶劑，酯類化合物係介於0.000001至0.1重量份之 間，較佳係介於0.000005至0.05重量份之間。該組成物 包含之飽和烴溶劑及推進劑的比例通常落在下列範圍：相 對於每重量份飽和烴溶劑，推進劑係介於0.25至8重量份 9 320090 200845907 • 之間，較佳係介於〇·3至4重量份之間。 更詳細地說，根據本發明之殺蟲性氣膠組成物通常包 含相對於每重量份飽和烴溶劑，0.000001至0.1重量份比 例之酯類化合物及0.25至8重量份比例之推進劑；較佳包 含相對於每重量份飽和烴溶劑，0.000Ό05至0.05重量份比 例之酯類化合物及0.3至4重量份比例之推進劑。 根據本發明之殺蟲性氣膠組成物在需要時可包含一或 多種額外添加劑，例如其他殺蟲成分、拒避劑（repellent)、 _增效劑以及芳香劑。 其他殺蟲成分的例子包含有機鱗酸鹽類，如二氯松 (dichlorvos)、撲滅松（fenitrothion)、殺蟲畏 (tetrachlorvinphos)、倍硫磷（fenthion)、陶斯松（chlorpyrifos) 及大利松（diazinon);胺基甲酸鹽類化合物，如安丹 (propoxur)、加保（carbaryl)、惡蟲酮（metoxadiazone)以及丁 基滅必蝨（fenobucarb);幾丁質合成抑制劑，如祿芬隆 • (lufenuron)、克福隆（chlorfluazuron)、六伏隆 (hexaflumuron)、二福隆（diflubenzuron)、赛滅淨（cyromazine) 以及1-(2,6-二氟苯甲醯基）-3-[2-氟-4-(l，l，2,3,3,3_六氟丙 氧基）苯基]尿素；青春激素(juvenile hormone)類似物，如 百利普芬(pyriproxyfen)、美賜年（methoprene)、烯蟲乙酯 (hydroprene)以及芬諾克（fen0Xycarb);新類尼古丁化合物 (neonicotinoids);以及 苯基吡唑。 拒避劑包括，例如，N，N-二乙基-間曱苯醯胺、檸檬油 精（limonene)、沈香醇（iinai〇〇i)、香茅酸（citronellal)、薄荷 10 320090 200845907 • 腦（menthol)、薄荷酮（menthone)、扁柏驗（hinokitiol)、香 ,葉醇（geraniol)、桉油醇（eucalyptol)、因得克（indoxacarb)、 長松針烷-3,4·二醇（carane-3,4，diol)、MGK-R-326、 MGK-R-874 以及 BAY-KBR-3023。 增效劑的例子包括5-[2-(2-丁氧乙氧基）乙氧甲基]-6-丙基-1,3-苯并二氧雜環戊烯、N-(2-乙基己基）-雙環[2.2.1] 庚-5-細-2,3 -二曱酿亞胺、八氯二丙謎、硫氯乙酸異获酯、 以及N - (2 -乙基己基）-1·異丙基-4 -曱基雙壤[2 · 2 * 2 ]辛-5 -稀 ⑩-2,3-二曱酸亞胺。 安定劑的例子包括盼類抗氧化劑，如2,6-二-第三丁基 -4-曱紛。 含有根據本發明之殺蟲性氣膠組成物的殺蟲性氣膠可 依例如下列步驟製備：將本發明之含有化合物A、有機溶 劑以及因需要加入的其他添加物（如殺蟲成分、拒避劑、增 效劑以及安定劑）裝入喷霧容器中後，將噴霧閥門裝到容器 0上，使推進劑經過閥桿填入容器中，搖動容器，再加裝致 動器。致動器的例子包括按鈕式以及觸發式致動器。 根據本發明之殺蟲性氣膠組成物係藉由例如喷灑含有 有效量的根據本發明之殺蟲性氣膠組成物的殺蟲性氣膠於 有害昆蟲或其移動路徑及/或棲地上而使用。以化合物A 來說，當施用於平面面積時，噴灑量之範圍則通常約為每 平方公尺（m2) 0.001至1，000毫克（mg);以化合物A來說， 當施用於空間中時，喷灑量之範圍則通常約為每立方公尺 (m3) 0.001 至 1，000 毫克。 11 320090 200845907 • 根據本發明之殺蟲性氣膠組成物可防治的有害昆蟲之 、 例子包含節肢動物（如昆蟲和螺），典型例子包含下列各者： 鱗翅目（Lepidoptera):螟蛾科（pyraiidae)，如二化螟蟲 (Chilo suppressalis)、稻縱捲葉野螟蛾（cnaphalocrocis medinalis)、印度谷斑螟（？1〇(^11^1^1111(^11&);夜蛾科 (Noctuidae)，如斜紋夜蛾（Spodoptera litura)、粟夜蛾 (Pseudaletia separata)、甘藍夜蛾（Mamestra brassicae);粉 蝶科（Pieridae) ’ 如曰本紋白蝶（Pieris rapae crucivora);捲 鲁葉蛾科（Tortricidae)，如茶姬捲葉蛾（Adoxophyes orana); 果蛀蛾科（Carposinidae);莱氏蛾科（Lyonetiidae);毒蛾科 (Lymantriidae);苜蓿夜蛾（Autographa);地老虎屬（Agrotis spp·)，如蒸菁夜蛾（Agrotis segetum)及球菜夜蛾（Agrotis ipsilon);龄夜蛾屬（Helicoverpaspp·);實夜蛾屬（Heliothis spp·);小菜蛾（Plutella xylostella);單帶弄蝶（Parnara guttata guttata) ;負袋衣蛾（Tinea pellionella);衣蛾（Tineola • bisselliella)等。 雙翅目（Diptera):家蚊屬（Culex)，如淡色庫蚊（Culex pipiens pallens) - (Culex tritaeniorhynchus)^ ^ ψ 家蚊（Culex quinquefasciatus);伊蚊屬（Aedes)，如埃及斑 蚊（Aedes aegypti)及白線斑蚊（Aedes albopictus);癔蚊亞科 (Anophelinae)，如中華癔蚊（Anopheles sinensis)及甘比亞 瘧蚊（Anopheles gambiae);搖蚊科（Chironomidae);家绳科 (Muscidae)，如普通家繩（Musca domestica)、廄腐繩 (Muscina stabulans)及黃腹廁繩（Fannia canicularis);麗虫龜 12 320090 200845907 ^ 科（Calliphoridae);麻繩科（Sarcophagidae);花绳科 ，（Anthomyiidae)，如灰地種绳（Delia platura)和蔥地種蠅 (Delia antiqua);果實繩科（Tephritidae);果繩科 (Drosophilidae);蛾蚋科（Psychodidae);蚤繩科（Phoridae); it科（Tabanidae);納科（Simuliidae);庫蠓屬（Culicoides); 蠓科（Ceratopogonidae)等。 蜚蠊目（Blattaria):德國姬蠊（Blattella germanica)、黑 褐家蠊（Periplaneta fuliginosa)、美洲斐蠊(Periplaneta 肇 americana)、澳洲蜚蠊（Periplaneta australasiae)、掠色蜚蠊 (Periplaneta brunnea)、紅蠊（Lobopterella dimidiatipes)等。 膜翅目（Hymenoptera):蟻科（Formicidae);胡蜂科 (Vespidae)，如歐洲胡蜂（Vespa crabro)及擬大虎頭蜂（Vespa analis);蟻形蜂科(Bethylidae);葉蜂科（Tenthredinidae)， 如紅角菜葉蜂(Athalia rosae ruficornis)等。 蚤目（Siphonaptera):犬蚤（Ctenocephalides canis)、貓 鲁蚤（Ctenocephalides felis felis)、人蚤（Pulex irritans)等。 為目（Anoplura):體益（Pediculus humanus)、陰兹 (Pthirus pubis)、頭風（Pediculuscapitis)、體蟲（PediculιlS humanus)等。 等翅目（Isoptera)(白蟻類）：黃肢散白蟻（Reticulitermes speratus speratus)、臺灣家白蟻（Coptotermes formosanus) 等。. 半翅目（Hemiptera):飛蟲科（Delphacidae)，如斑飛兹 (Laodelphax stratella)、褐飛風(Nilaparvata lugens)及白背 13 320090 .200845907 •飛蟲（Sogatella furcifera);浮塵子科（Deltocephalidae)，如 ^ 黑尾葉蟬（Nephotettix cincticeps)及二點黑尾葉蟬 (Nephotettix virescens);虫牙科（Aphididae);椿科 (Pentatomidae)；粉蝨科（Aleyrodidae);軟介殼蟲科 (Coccoidae);軍配蟲科（Tingidae);木蝨科（Psyllidae);臭 蟲科（Cimicidae)等。 鞘翅目（Coleoptera) ··姬鰹節蟲（Attagenus japonicus)、 姬圓鰹節蟲（Anthrenus verbasci);玉米根蟲（corn 馨 rootworms)，如西方玉米根蟲（Western corn rootworm)以及 南方玉米根蟲（Southern corn rootworm);金龜子科 (Scarabaeidae)，如金銅金龜（Anomala cuprea)以及姬金龜 (Anomala rufocuprea);象鼻蟲科（Curculionidae)，如玉米 象（Sitophilus zeamais)、稻水象曱(Lissorhoptrus oryzophilus)、棉龄象鼻蟲（Anthonomus grandis grandis)以 及綠豆象（Callosobruchus chinensis);擬步行蟲科 • (Tenebrionidae)，如大黃粉蟲（Tenebrio molitor)以及擬穀盜 (Tribolium castanemn);金花蟲科（Chrysomelidae)，如負泥 蟲（Oulema oryzae)、黃條葉蚤（Phyllotreta striolata)以及黃 守瓜（八111&00卩110^£61110^113);竊蠢科（入11〇1^(1&6);瓢蟲屬 (Epilachna spp·)，如茄二十八星瓢蟲（Epilachna yigintioctopunctata)；粉蠹科（Lyctidae);長蠹蟲科 (Bostrychidae)；天牛科（Cerambycidae);紅胸隱翅轰 (Paederus fuscipes)等。 纓翅目（Thysanoptera)(薊馬科害蟲（thrips)):南黃薊馬 14 320090 .200845907 • (Thrips palmi)、西方花薊馬（Frankliniella occidentalis)、花 4 薊馬（Thrips hawaiiensis)等。 直翅目（Orthoptera):螻蛄科（Gryllotalpidae)、虫皇科 (Acrididae)等。 蜗（Acarines):塵蜗科（Pyroglyphidae)，如美洲塵蟎 (Dermatophagoides farinae)及歐洲塵螨（Dermatophagoides pteronyssinus);粉蜗科（Acaridae)，如兹粉蟎（Tyrophagus putrescentiae)及橢圓斑白蟎（Aleuroglyphus ovatus);食甜 Φ 蜗科（Glycyphagidae)，如食甜蜗（Glycyphagidae privatus)、 家食甜蜗（Glycyphagidae domesticus)、害食甜蜗 (Glycyphagus destructor);肉食蟎科（Cheyletidae)，如馬六 甲肉食蜗（Cheyletus malaccensis)及肉食蜗（Cheyletus fortis);細蜗科（Tarsonemidae);嗜渣科（〇1〇11:〇817|)111(1&6); 禽刺蜗科（Haplochthoniidae);葉蜗科（Tetranychidae)，如 二點葉螨（Tetranychus urticae)、神澤氏葉蜗（Tetranyclms ⑩kanzawai)、柑桔葉瞒（Panonychus citri)以及歐洲葉编 (Panonychus ulmi);硬蜱科（Ixodidae)，如長角血蜱 (Haemaphysalis longicornis)等。 實施例 以下將參照配方例及實施例詳細描述本發明，但本發 明並不僅侷限於此。 首先描述含有根據本發明之殺蟲性氣膠組成物之氣膠 的配方例。在以下實施例中，“份”代表“重量份”。 配方例1 15 320090 200845907 • 將 0.04 份的 1Κϋ(2-氰基-丙烯基（e/z=1/5))-2,2- ^二甲基環丙烷羧酸4·曱氧基甲基_2,3,5,6-四氟苯甲酯以及 39.96份之異鏈烷烴M (Isopar M)置於噴霧罐中。然後將閥 門裝到罐上，經由閥門將60份之推進劑（液化石油氣）填充 到罐裡後，產生含有100份的殺蟲性氣膠組成物的氣膠（以 下稱為本發明氣膠（1))。 配方例2 將0.04份的1心反-3-(2-氰基小丙烯基（e/z=1/5))-2,2-⑩一甲基環丙烧羧酸4-曱氧基.甲基_2,3,5,6-四氟苯甲酯以及 49·96份之異鏈烷烴μ置於喷霧罐中。然後將閥門裝到罐 上，經由閥門將50份之推進劑（液化石油氣）填充到罐裡 後產生含有100份的殺蟲性氣膠組成物的氣膠(以下稱為 本發明氣膠（2))。 配方例3 將0·2份的1R·反-3-(2-氰基小丙烯基（ε/ζ=1/5))-2,2-春二甲基環丙烷羧酸4-曱氧基曱基-253,5,6_四氟苯甲酯以及 49·8份之尼奥奇佐（Neochiozol)置於喷霧罐中。然後將閥門 裝到罐上，經由閥門將50份之推進劑（二甲基醚及液化石 油^之1:1混合物）填充到罐裡後，產生含有1〇〇份的殺蟲 ^生氣膠組成物的氣膠（以下稱為本發明氣膠（3))。 配方例4 將 〇·〇2 份的 1R-反._3_(2_氰基丙烯基（e/z=1/5))_2,2_ f甲基環丙烧賴4-甲氧基曱基_2,3,5,6_四氟苯甲酯以及 .伤之兴鏈燒煙Μ置於噴霧罐中。然後將閥門裝到罐 320090 16 ,200845907 ♦上，經由閥門將40份之推進劑（液化石油氣）填充到罐裡 α後，產生含有100份的殺蟲性氣膠組成物的氣膠（以下稱為 本發明氣膠（4))。 配方例5 將 0·08 份的 1R-反-3-(2-氰基·ι_丙烯基（ε/ζ=1/5))_2,2_ 二曱基環丙烷羧酸4-曱氧基曱基_2,3,5,6_四氟苯曱酯以及 49.92份之尼奥奇佐置於喷霧罐中。然後將闕門裝到罐上， 經由閥門將50份之推進劑（液化石油氣）填充到罐裡後，產 _生含有100份的殺蟲性氣膠組成物的氣膠（以下稱為本發 明氣膠（5)) 〇 參考製備例1 將 0.04 份的 1R-反-3-(2•氰基-1-丙烯基(Ε/ζ=1/5)；μ2,2-二甲基環丙烷羧酸4-甲氧基曱基_2Λ5,6-四氟苯甲酯、5 份的二氯甲烷以及34.96份的異鏈烷烴Μ置於噴.霧罐中。 然後將閥門裝到罐上，經由閥門將6〇份之推進劑（液化石 籲油氣）填充到罐裡後，產生含有i⑽份的殺蟲性氣膠組成物 的氣膠（以下稱為比較性氣膠（1))。 參考製備例2 將 〇.04 份的 m-反-3-(2-氰基-1-丙烯基（E/Z=l/5))_2,2-二甲基環丙㈣酸4_甲氧基f基_2,3,5,6.四i苯f g旨、6.’4i 份的二氯甲烷以及43.55份的異鏈烷烴Ml於喷霧罐中。 然後將閥門裝到罐上，經由閥門將5〇份之推進劑（液化石 油填充到罐裡後’產生含有1〇〇份的殺蟲性氣膠組成物 的氣膠（以下稱為比較性氣膠（2))。 320090 17 200845907 ¥ 以下將會插述含有根據本發明之殺蟲性氣膠組成物的 i 氣膠之殺蟲功效。 測試例1及2 將1 〇隻家罐（Musca domesticas)的成蟲（五隻雄性及五 隻雌性）放在聚乙烯杯中（底部直徑：1〇·6公分，頂部 直徑.12公分，高度：7公分），接著以16網目尼龍網蓋 住杯子。另外再準備内無家繩的杯子。將内有家繩的杯子 放在70公分立方之箱室底板的中心，並將内無家蠅的杯子 響放在底板之最内部。 將300笔克（就氣膠組成物而言)的本發明氣膠（！）經由 内。然後在5分200845907 ‘9. Description of the invention: [Technical field to which the invention belongs] The present invention relates to an insecticidal gas gel composition. [Prior Art] It is known to contain 3 ♦ cyano-based Xiao propie) _2,2- dimethylcyclopropanone acid 4·methoxymethyl-2,3,5,6-tetrafluorobenzyl ester, two The chlorpyrifos, the chlorite-containing kerosene of the kerosene and the propellant have an insecticidal activity (see, for example, U.S. Patent No. 6,908,945). SUMMARY OF THE INVENTION An object of the present invention is to provide a gas gel composition having excellent insecticidal activity. In order to find a gas gel composition having excellent insecticidal activity, the inventors of the present invention found that 3 cyano-based Xiaobing County) 2,2i methyl acid oxime..., 3,5, (four) benzene The insecticidal gas gel composition of vinegar and organic solvent has excellent insecticidal activity, and the organic solvent is a saturated hydrocarbon solvent, thus creating the present invention. The invention provides: - an insecticidal gas gel composition comprising 3_(2-cyanopropenyl hydrazine 2_ t methylcyclopropanecarboxylic acid 4-methoxyindolyl 2,3,5,6· Tetrafluorophenyl hydrazine organic solvent and propellant 'wherein, the organic solvent is an insecticidal gas gel composition described in saturated smoke solution=1, wherein the composition package 2 is 〇 with respect to each part by weight of the saturated hydrocarbon solvent · (10) (10) W to 〇 1 part by weight of 3 · (2 · cyano heptapropyl) 2, 2 - dimethylcyclopropene 320090 5 200845907 • Acid 4-decyloxymethyl-2,3,5 , 6_tetrafluorobenzyl ester; * 3. The insecticidal gas gel composition described in item 2, wherein the composition comprises the amount of 0.25 to 8 parts by weight per part by weight of the saturated hydrocarbon solvent. The insecticidal gas gel composition described in any one of items 1 to 3, wherein the composition comprises 3 to 2% by weight of 3 2 2 - cyanopropenyl group of 〇·〇〇1 to 1% by weight 2,2-Dimethylcyclopropanecarboxylic acid 4_methoxymethyl-2,3,5,6-tetrafluorobenz Ss 1 〇 to 79% by weight of the remainder and the hydrocarbon solvent, And the amount of the propellant is from 20 to 80% by weight; 5. The one described in any one of items 1 to 4. An insecticidal gas gel composition, wherein the dry and glutenic initial boiling point b〇iHng p〇int)g or more and 95 A residual temperature (95%-(^also 1 this 11 11 11 11 11 11 11 The insecticidal gas gel composition described in any one of items 1 to 5, wherein the composition is for controlling a Blattada insect; _ 7· The insecticidal gas gel composition according to any one of items 1 to 5, wherein the composition is for controlling a Hymen〇ptera insect; any one of items 1 to 5 is described. An insecticidal gas gel composition, wherein the composition is for controlling a Vespidae insect; 9. A method for controlling harmful aphids, comprising spraying an effective amount of an insecticidal gas gel composition The harmful Kun 4 or the habitat of the insect, the insecticidal gas gel composition comprising 3_(2-cyano-1·propenyl)-2,2-dimethylcyclopropane竣酉夂4-methoxy Methyl 2,3,5,6-tetraqi benzyl ester, organic solvent and propellant sword, Li 4?,, /, τ The organic solvent is a saturated hydrocarbon solvent; 6 320090 200845907 • 10· Item 9 Fang, soil 4# go ' Wherein the composition comprises 3-(2-mercapto>2,2-dimercaptocyclopropanecarboxylate in an amount of 0.000001 to 0.1 part by weight relative to the weight of the saturated smoke per weight*; Acid 'methoxy fluorenyl-2,3,5,6-tetrafluoro benzyl ester; ·: 1, 〇 & 4 method 'where 'the composition contains 12 ΓΓ and hydrocarbon solvent per weight The propellant in an amount of from 25 to 8 parts by weight; The method of claim 1, wherein the composition comprises 0.001 to i by weight of 3_(2-cyano)propenyl) dimethyl dimethyl propyl ketone - Manda- oxime oxime 2, 3, 5,6-tetrafluorobenzyl ester, the saturated fuming solvent in an amount of from 1 to 79 wt%, and the propellant in an amount of from 2 to 80% by weight; The method of the present invention, wherein the saturated hydrocarbon solution has an initial boiling point of 15 Gt or higher and a 95% base distillation temperature of 3 (10) 1 or lower; ^ the method is the method described in any one of items 9 to 13 In the method of any one of the items 9 to 13, wherein the method is for controlling a Hymenoptera; the method is the use of any one of items 16 to 13 A method for controlling a vespidae insect; and an insecticidal gutta-percha, comprising the insecticidal gas gel composition described in any one of items 1 to 8. The insecticidal gas gel composition according to the present invention has excellent insecticidal activity. [Embodiment] 320090 7 .200845907 The insecticidal gas composition of the invention is composed of 3_(2-cyano-4,·methylcyclopropionate 4·methoxymethyl-2, 3,5,6_tetrafluoro^^=_ is a compound Α), an organic solvent and a propellant, and a mixture thereof, wherein the organic solvent is a saturated hydrocarbon solvent. The compound oxime is a compound as described in U.S. Patent No. 69,894, and can be prepared by the method described in the literature. Although Compound A possesses an isomer according to two asymmetric carbon atoms and a double bond in the silicide ring, the present invention may use any isomer or a mixture of isomers mixed in any ratio. The content of the compound A in the insecticidal gas-adhesive composition according to the present invention is usually from 0.001 to 50% by weight, preferably from 0.01 to 1% by weight. The insecticidal gas gel composition according to the present invention contains a saturated hydrocarbon solvent as an organic solvent. The saturated hydrocarbon solvent used in the present invention is usually, for example, an initial boiling point of 15 (TC or higher and 95% distillation temperature of 30 (rc or lower lysing agent / but of course, an initial boiling point of 15 (rc or Higher and dry points are solvents of 300 ° C or lower. Examples of saturated hydrocarbon solvents include Isopar G (manufactured by Exxon Mobil Corp.) Boiling point: 16 (TC, dry point · · 176 ° C), isoparaffin L (manufactured by ExxonMobil, initial boiling point · 189t, dry point · 207 it), isobaric hydrocarbon oxime (Exxon Made by Mobil, initial boiling point · i78〇c, dry point · 188. 〇, Xinglian burning fe Μ (made by Exxon Mobil, initial boiling point: 223, dry point: 254 C), normal paraffin 13 ( Norpar 13) (manufactured by ExxonMobil, initial boiling point: 2221, dry point: 242. 〇, normal paraffin 15 (ExxonMobil 320090 8 200845907 • Made by the company, initial boiling point: 249 ° C, dry point: 274 °C), dearomatized fat. Group solvent D40 (Exxsol D40) (manufactured by ExxonMobil, initial boiling point: 164 ° C, dry point · 192 ° C), dearomatized aliphatic D60 (manufactured by ExxonMobil, initial boiling point: 187 ° C, dry point: 209 ° C), dearomatized aliphatic solvent D80 (made by ExxonMobil, initial boiling point: 208 ° C, dry point: 243 ° C), Neochiozol (manufactured by Chuokasei Co., Ltd., initial boiling point: 225 ° C, dry point: 247 ° C), IP solvent 2028 (IP Solvent 2028) (Manufactured by Idemitsu Kosan Co., Ltd., initial boiling point: 213 ° C, 95% distillation temperature: 250 ° C) and kerosene. In the insecticidal gas gel composition according to the present invention The saturated hydrocarbon solvent is usually contained in an amount of from 10 to 79% by weight, preferably from 20 to 70% by weight, of the propellant contained in the insecticidal gas composition of the present invention having a boiling point of from -50 ° C to the boiling point Examples of the liquefied gas, the propellant include liquefied stone 10 oil and gas (LPG), diterpene ether, propane, n-butane, and isobutane. The propellant content of the insecticidal gas gel composition according to the present invention is usually 20 Between 80% by weight, preferably between 25 and 75% by weight. The insecticidal gas gel group according to the present invention The ratio of the ester compound and the saturated hydrocarbon solvent contained in the product generally falls within the following range: The ester compound is between 0.000001 and 0.1 parts by weight, preferably 0.000005 to 0.05, per part by weight of the saturated hydrocarbon solvent. Between parts by weight. The ratio of the saturated hydrocarbon solvent and the propellant contained in the composition generally falls within the following range: between 0.25 and 8 parts by weight of 9 320090 200845907 • per part by weight of the saturated hydrocarbon solvent, preferably between 〇·3 to 4 parts by weight. In more detail, the insecticidal gas gel composition according to the present invention usually comprises 0.000001 to 0.1 parts by weight of the ester compound and 0.25 to 8 parts by weight of the propellant per part by weight of the saturated hydrocarbon solvent; preferably. The ester compound is contained in a proportion of 0.000 Ό05 to 0.05 parts by weight per part by weight of the saturated hydrocarbon solvent, and a propellant is used in a proportion of 0.3 to 4 parts by weight. The insecticidal gas gel composition according to the present invention may contain one or more additional additives as needed, such as other insecticidal ingredients, repellents, synergists, and fragrances. Examples of other insecticidal ingredients include organic sulphates such as dichlorvos, fenitrothion, tetrachlorvinphos, fenthion, chlorpyrifos and diazinon Carbamates such as propoxur, carbaryl, metoxadiazone, and fenobucarb; chitin synthesis inhibitors such as Lucendon • (lufenuron), chlorfluazuron, hexaflumuron, diflubenzuron, cyromazine, and 1-(2,6-difluorobenzhydryl)-3-[ 2-fluoro-4-(l,l,2,3,3,3-hexafluoropropoxy)phenyl]urea; juvenile hormone analogues such as pyriproxyfen, beauty Methorene, hydroprene, and fen0Xycarb; neonicotinoids; and phenylpyrazole. Repellents include, for example, N,N-diethyl-m-benzoquinone, limonene, iinai〇〇i, citronellal, mint 10 320090 200845907 • Brain (menthol), menthone, hinokitiol, geraniol, eucalyptol, indoxacarb, long pine needle-3,4·diol (carane) -3,4,diol), MGK-R-326, MGK-R-874 and BAY-KBR-3023. Examples of synergists include 5-[2-(2-butoxyethoxy)ethoxymethyl]-6-propyl-1,3-benzodioxole, N-(2-B Hexyl)-bicyclo[2.2.1] hept-5-fine-2,3-di-branched imine, octachlorodipropylene, thiochloroacetic acid iso-ester, and N-(2-ethylhexyl)- 1. Isopropyl-4-mercapto-double soil [2 · 2 * 2 ] oct-5 - dilute 10-2,3-didecanoate. Examples of stabilizers include anti-oxidants such as 2,6-di-t-butyl-4-pyrene. The insecticidal gas gel containing the insecticidal gas gel composition according to the present invention can be prepared, for example, by the following steps: the compound A of the present invention, an organic solvent, and other additives (such as insecticidal ingredients, rejected) After the agent, the synergist and the stabilizer are placed in the spray container, the spray valve is placed on the container 0, the propellant is filled into the container through the valve stem, the container is shaken, and the actuator is further installed. Examples of actuators include push button type and trigger type actuators. The insecticidal gas gel composition according to the present invention is applied to a harmful insect or its moving path and/or habitat by, for example, spraying an insecticidal gas gel containing an effective amount of the insecticidal gas gel composition according to the present invention. And use. In the case of Compound A, when applied to a flat area, the amount of spray is usually about 0.001 to 1,000 mg (mg) per square meter (m2); in the case of Compound A, when applied to space The range of spray is usually about 0.001 to 1,000 mg per cubic meter (m3). 11 320090 200845907 • Examples of harmful insects which can be controlled by the insecticidal gas gel composition according to the present invention include arthropods (such as insects and snails), and typical examples include the following: Lepidoptera: Coleoptera ( Pyraiidae), such as Chilo suppressalis, Cnaphalocrocis medinalis, Indian variegata (?1〇(^11^1^1111(^11&); Noctuidae) ), such as Spodoptera litura, Pseudaletia separata, Mamestra brassicae, Pieridae 'Pieris rapae crucivora; Torricidae ), such as Adoxophyes orana; Carposinidae; Lyonetiidae; Lymantriidae; Autographa; Agrotis spp. Agrotis segetum and Agrotis ipsilon; Helicoverpaspp·; Heliothis spp.; Plutella xylostella; single-banded butterfly (Parnara) Guttata guttata) ; negative Tinea pellionella; Tineola • bisselliella, etc. Diptera: Culex, such as Culex pipiens pallens - (Culex tritaeniorhynchus) ^ ^ ψ Culex quinquefasciatus); Aedes, such as Aedes aegypti and Aedes albopictus; Anophelinae, such as Anopheles sinensis and Anopheles gambiae (Anopheles gambiae); Chironomidae; Muscidae, such as Musca domestica, Muscina stabulans, and Fannia canicularis; Lizard Turtle 12 320090 200845907^Calliphoridae; Sarcophagidae; Anthomyiidae, Delia platura and Delia antiqua; Tephritidae; fruit rope Drosophilidae; Psychodidae; Phoridae; Tabanidae; Simuliidae; Culicoides; Ceratopogonidae et al. Blattaria: Blattella germanica, Periplaneta fuliginosa, Periplaneta 肇americana, Periplaneta australasiae, Periplaneta brunnea, Red dragonfly (Lobopterella dimidiatipes) and so on. Hymenoptera: Formicidae; Vespidae, such as Vespa crabro and Vespa analis; Bethylidae; Tenthredinidae ), such as Athalia rosae ruficornis. Siphonaptera: Ctenocephalides canis, Ctenocephalides felis felis, Pulex irritans, etc. Anoplura: Pediculus humanus, Pthirus pubis, Pediculus capitis, Pediculιl S humanus, and the like. Isoptera (termites): Reticulitermes speratus speratus, Coptotermes formosanus, etc. Hemiptera: Delphacidae, such as Laodelphax stratella, Nilaparvata lugens, and white back 13 320090 .200845907 • Sogatella furcifera; Delphicephalidae ), such as: Nephotettix cincticeps and Nephotettix virescens; Aphididae; Pentatomidae; Aleyrodidae; Coccoidae ; Tingidae; Psyllidae; Cimicidae. Coleoptera · Attagenus japonicus, Anthrenus verbasci; corn rootworms, such as Western corn rootworm and southern corn rootworm (Southern) Corn rootworm); Scarabaeidae, such as Anomala cuprea and Anomala rufocuprea; Curculionidae, such as Sitophilus zeamais, Lisorhoptrus oryzophilus, Cotton-like weevil (Anthonomus grandis grandis) and mung bean (Callosobruchus chinensis); Tenebrionidae, such as Tenebrio molitor and Tribolium castanemn; Chrysomelidae), such as Oulema oryzae, Phyllotreta striolata, and Huang Shougua (8111 &00卩110^£61110^113); thief (into 11〇1^(1&6); Epilachna spp., such as Epilachna yigintioctopunctata; Lyctidae; Bostrychidae; Ceramby Cidae); Paederus fuscipes, etc. Thysanoptera (thrips): Southern Yellow Horse 14 320090 .200845907 • (Thrips palmi), Western flower hummer (Frankliniella Occidentalis), flower 4 Thrips hawaiiensis, etc. Orthoptera: Gryllotalpidae, Acrididae, etc. Acarines: Pyroglyphidae, such as the American dust mites (Dermatophagoides farinae) and European dust mites (Dermatophagoides pteronyssinus); Acaridae, such as Tyrophagus putrescentiae and Aleuroglyphus ovatus; Glycyphagidae, such as sweet worm (Glycyphagidae privatus), Glycyphagidae domesticus, Glycyphagus destructor; Cheyletidae, such as the genus Cheyletus malaccensis and Cheyletus fortis; Tarsonemidae); scorpion (〇1〇11:〇817|)111(1&6);Haplochthoniidae; Tetranychidae, such as Tetranyc Hus urticae), Tetranyclms 10kanzawai, Panonychus citri, and Panonychus ulmi; Ixodidae, such as Haemaphysalis longicornis. EXAMPLES Hereinafter, the present invention will be described in detail with reference to formulation examples and examples, but the present invention is not limited thereto. First, a formulation example of a gas gel containing the insecticidal gas gel composition according to the present invention will be described. In the following examples, "parts" means "parts by weight". Formulation Example 1 15 320090 200845907 • 0.04 parts of 1 Κϋ (2-cyano-propenyl (e/z=1/5))-2,2- ^dimethylcyclopropanecarboxylic acid 4·decyloxymethyl _2,3,5,6-tetrafluorobenzyl ester and 39.96 parts of isoparaffin M (Isopar M) were placed in a spray can. Then, the valve is placed on the tank, and 60 parts of the propellant (liquefied petroleum gas) is filled into the tank through the valve to produce a gas gel containing 100 parts of the insecticidal gas gel composition (hereinafter referred to as the gas gel of the present invention). (1)). Formulation Example 2 0.04 parts of 1-hearted reverse-3-(2-cyanopropenyl (e/z=1/5))-2,2-10-methylcyclopropanecarboxylic acid 4-decyloxy Methyl 2,3,5,6-tetrafluorobenzyl ester and 49.96 parts of isoparaffin μ were placed in a spray can. Then, the valve is placed on the tank, and 50 parts of the propellant (liquefied petroleum gas) is filled into the tank through the valve to produce a gas gel containing 100 parts of the insecticidal gas gel composition (hereinafter referred to as the gas gel of the present invention ( 2)). Formulation Example 3 0.2 parts of 1R·trans-3-(2-cyanopropenyl (ε/ζ=1/5))-2,2-chun dimethylcyclopropanecarboxylic acid 4-anthracene The thiol-253,5,6-tetrafluorobenzyl ester and 49.8 parts of Neochiozol were placed in a spray can. Then, the valve is placed on the tank, and 50 parts of the propellant (1:1 mixture of dimethyl ether and liquefied petroleum oil) is filled into the tank through the valve to produce a composition containing 1 part of insecticide A gas gel of the substance (hereinafter referred to as a gas gel (3) of the present invention). Formulation Example 4 〇·〇2 parts of 1R-anti._3_(2-cyanopropenyl (e/z=1/5))_2,2_fmethylcyclopropanone 4-methoxyindenyl group_ 2,3,5,6_tetrafluorobenzyl ester and the wounded chain-burning soot are placed in a spray can. Then, the valve is placed on the tank 320090 16 , 200845907 ♦, 40 parts of propellant (liquefied petroleum gas) is filled into the tank α through the valve, and then a gas gel containing 100 parts of the insecticidal gas gel composition is produced (below It is called the gas gel (4) of the present invention. Formulation Example 5 0. 08 parts of 1R-trans-3-(2-cyano·ι_propenyl (ε/ζ=1/5))_2,2-diisopropylcyclopropanecarboxylic acid 4-decyloxy Mercapto-2,3,5,6-tetrafluorobenzoate and 49.92 parts of nicotiz are placed in a spray can. Then, the trick is placed on the can, and 50 parts of the propellant (liquefied petroleum gas) is filled into the tank through the valve, and then the gas gel containing 100 parts of the insecticidal gas gel composition is produced (hereinafter referred to as the present). Inventive gas gel (5)) 〇 Reference Preparation Example 1 0.04 parts of 1R-trans-3-(2 cyano-1-propenyl (Ε/ζ=1/5); μ2,2-dimethyl ring Propanecarboxylic acid 4-methoxyindolyl 2Λ5,6-tetrafluorobenzyl ester, 5 parts of dichloromethane and 34.96 parts of isoparaffin were placed in a spray can. The valve was then placed on the can. After filling 6 parts of the propellant (liquefied petroleum gas) into the tank through a valve, a gas gel containing i (10) parts of the insecticidal gas gel composition (hereinafter referred to as comparative gas gel (1)) was produced. Reference Production Example 2 〇.04 parts of m-trans-3-(2-cyano-1-propenyl (E/Z=l/5))_2,2-dimethylcyclopropane (tetra) acid 4_A Oxy-f-group 2,3,5,6.tetra-benzene fg, 6.'4i part of dichloromethane and 43.55 parts of isoparaffin M1 in a spray can. Then the valve is placed on the can, 5 parts of propellant (filled into the tank after liquefied petroleum oil) through the valve to produce an insecticidal gas gel containing 1 part The gas gel of the substance (hereinafter referred to as comparative gas gel (2)). 320090 17 200845907 ¥ The insecticidal efficacy of the i gas gel containing the insecticidal gas gel composition according to the present invention will be inserted below. And 2 Adults (five males and five females) of a single can (Musca domesticas) were placed in a polyethylene cup (bottom diameter: 1 〇 · 6 cm, top diameter . 12 cm, height: 7 cm) Then, cover the cup with a 16 mesh nylon net. Also prepare a cup without a home rope. Place the cup with the rope inside the center of the bottom of the 70 cm cube chamber, and place the cup without the housefly inside. In the innermost part of the bottom plate. 300 grams (in terms of the gas composition) of the inventive gas gel (!) via the inside. Then at 5 points
形成於箱室前侧壁中心的窗戶喷灑到箱室内 鐘期間内監測被擊倒的昆蟲數目。 測試例2The number of insects that were knocked down was monitored during the spraying of the window formed in the center of the front side wall of the chamber to the chamber. Test example 2
參考測試例1及2Reference test examples 1 and 2
320090 18 200845907 * [表 i]320090 18 200845907 * [Table i]
測試例3 將二隻雌性大黃蜂（Vespa crabro)置於立方形不 龍（25公分X 25公分X 25公分，16網目金屬線網）中。鋼 金屬鍊將籠子懸掛在測試室（1·8公尺（m) X 1·8公尺χ △尺）之天花板，使籠子位於離該室地板120公分高的办 t °在離籠子侧邊igg公分處將4克⑻的本發明氣膠(Γ) =到龍子上。喷灑後三分鐘’將昆蟲由籠子中移到乾淨的 聚乙婦杯中（底部直徑：10.6公分，頂部直徑：12公分， 高度:7公分)。將以水稀釋的蜂蜜餵食這些昆蟲，並將杯 子靜置於室溫-整天。噴灑之後—天，計算死亡以及存活 的昆蟲數以決定死亡率（兩次測試的平均）。根據結果，死 亡率是100%。 測試例4 將五隻雌性大黃蜂置於立方开；μ 先不銹鋼籠（25公分X 25 公分X 25公分’ 16網目金屬線锢、 说上 蜀深、、、罔）中。以金屬鍊將籠子懸 掛在測試室（1·8公尺X 1.8公尺χ 。 7 X U公尺）之天花板，使籠 子位於離該室地板120公分高的处 刀回的空中。在離籠子侧邊100 320090 19 .200845907 •公分處將4克的本發明氣#(3)喷㈣子上。 蟲由蘢子中移到乾淨的聚乙婦杯中(底部直：》 Μ公分，頂部直徑：12公分，高度：7公分）。將蘇 釋的蜂蜜儀食這些昆蟲，並將杯子靜置於室溫—敫天稀 麗之後—天，計算死亡以及存活的昆蟲數以決定死亡率^ 次測試的平均）。根據結果，死亡率是1〇〇%。 （兩 測試例5 將直徑為8.2公分的濾紙放在乾淨聚乙埽杯内的底 (底部直控：8.2公分）。將滑石粉塗覆在杯子内面的上部^ 自然風乾以避免昆蟲逃逸。然後將十隻螞蟻（堅硬雔針蠕 pungens))放入杯中。將杯子放在内=為心 '刀’冋度為60公分之圓柱狀箱室内的底部。將綱 的本發明氣膠（3)由箱室頂部的開口噴入杯中。之後:益 時龍過，計算被擊倒的昆蟲直到五分鐘。由結果判^ 倒90%測試昆蟲所需的時間（ΚΤ9〇)(每次試 根據結果，分鐘。 稷一乂）。 測試例6 將十隻德國姬蠊（Blattella germanica)(五隻雄性及五 隻雌性）置於内壁塗有奶油的測試容器（直徑：8^75公分， 高度：7.5公分，底面：16網目金屬網)中。將此容二放 ==5公分’高度6。公分之圓柱狀箱室内的底部。 將4〇〇氅克的本發明氣膠（4)由箱室頂部的開口喷入杯中。 之後，隨著時間經過，計算被擊倒的昆蟲直到五分鐘。 由、、、。不判疋擊倒90%測試昆蟲所需的時間（κι。）（每 320090 20 200845907 • 次試驗重複二次）。根據結果，ΚΤ9()為1.7分鐘。 太 測試例7 將六隻澳洲蟑螂（Periplaneta australasiae)(三隻雄性 及三隻雌性）置於内壁塗有奶油的測試容器（直徑：12·5公 分，高度·· 10公分，底面：43網目金屬網）中。將此容器 置放於内徑16.5公分，高度6〇公分之圓柱狀箱室内的； 部。將1000毫克的本發明氣膠（5)由箱 杯中。之絲，Ρ左荽日士 ρ,, 貝4的開口贺入 :: 亀過，計算被擊倒的昆蟲直到20 刀知。由結果判定擊倒9_m昆蟲所需 次試驗錢三:欠）。根㈣果，KT4 3 8 町一（每 【圖式簡單說明】 ^ ° 【主要元件符號說明】 無Test Example 3 Two female bumblebees (Vespa crabro) were placed in a cubic dragon (25 cm x 25 cm x 25 cm, 16 mesh metal wire mesh). The steel metal chain hangs the cage in the ceiling of the test room (1·8 m (m) X 1·8 m χ △ ft), so that the cage is located 120 cm above the floor of the room, t ° on the side of the cage Ig centimeters will put 4 grams (8) of the gas gel (Γ) of the invention on the dragon. Three minutes after spraying, the insects were moved from the cage to a clean Polyethylene cup (bottom diameter: 10.6 cm, top diameter: 12 cm, height: 7 cm). These insects were fed with honey diluted in water and the cup was allowed to stand at room temperature - all day. After spraying - days, the number of dead and surviving insects was counted to determine mortality (average of two tests). According to the results, the death rate is 100%. Test Example 4 Five female bumblebees were placed in a cubic open; μ first stainless steel cage (25 cm X 25 cm X 25 cm '16 mesh metal wire 说, said 蜀 deep, 、, 罔). The cage was suspended by a metal chain in the test room (1·8 m x 1.8 m 7 7 X U m), so that the cage was located in the air at a height of 120 cm from the floor of the room. On the side of the cage 100 320090 19 .200845907 • 4 grams of the inventive gas #(3) spray (four). The worm was moved from the scorpion into a clean cup of tea (bottom straight: Μ centimeters, top diameter: 12 cm, height: 7 cm). The insects were immersed in the insects and the cups were allowed to stand at room temperature—after a rare day—the number of dead and surviving insects was counted to determine the average of the mortality test. According to the results, the mortality rate is 1%. (Two test cases 5) A filter paper having a diameter of 8.2 cm was placed in the bottom of a clean polyethylene cup (bottom control: 8.2 cm). The talcum powder was applied to the upper part of the inner surface of the cup and naturally dried to avoid insect escape. Put ten ants (hard 雔 pun pungens) into the cup. Place the cup inside = the bottom of the heart of the cylindrical box inside the heart of the 'knife'. The inventive gas gel (3) is sprayed into the cup from the opening at the top of the chamber. After that: Yi Shilong passed and counted the knocked insects until five minutes. From the results, judge the time required to test the insects by 90% (ΚΤ9〇) (each test according to the results, minutes. 稷一乂). Test Example 6 Ten German cockroaches (Blattella germanica) (five males and five females) were placed on a test container coated with cream on the inner wall (diameter: 8^75 cm, height: 7.5 cm, bottom surface: 16 mesh metal mesh) )in. Put this into two ==5 cm' height 6. The bottom of the cylinder box inside the centimeter. 4 grams of the inventive gas gel (4) was sprayed into the cup from the opening at the top of the chamber. After that, over time, the knocked insects were counted until five minutes. by,,,. Do not judge the time required to knock down 90% of the test insects (κι.) (per 320090 20 200845907 • Repeat the test twice). According to the results, ΚΤ9() was 1.7 minutes. Too Test Example 7 Six Australian cockroaches (Periplaneta australasiae) (three males and three females) were placed on the inner wall of the cream-coated test container (diameter: 12·5 cm, height··10 cm, bottom: 43 mesh metal) In the net). Place the container in a cylindrical box with an inner diameter of 16.5 cm and a height of 6 cm. 1000 mg of the inventive gas gel (5) was placed in a cup. The silk, Ρ left 荽 日 ρ,, Bei 4's opening congratulations :: 亀, calculate the knocked insects until 20 knives know. From the results, it was judged that the test of knocking down 9_m insects required the test three money: owed). Root (four) fruit, KT4 3 8 Town One (each [simplified description] ^ ° [Main component symbol description] None
320090 21320090 21