TW200826968A - Hair reformer, hair cosmetic, and hair reforming method - Google Patents

Abstract

It is intended to provide a hair modifier which essentially modifies damaged hair, improves hair manageability, moistness, and elasticity, and exhibits excellent sustainability effect, a hair care product containing the hair modifier, and a method for modifying hair using the hair care product. The hair modifier contains an ester compound of an unsaturated dicarboxylic acid having 4 to 6 carbon atoms and a linear or branched, saturated or unsaturated alcohol having 12 to 24 carbon atoms. The hair care product contains the hair modifier. The method for modifying hair includes the step of applying the hair care product to hair.

Description

200826968 IX. Description of the Invention: [Technical Field] The present invention relates to a hair modifying agent, a hair cosmetic, and a method for modifying the hair surface to reduce or repair the damage on the surface of the hair. [Prior Art] b In recent years, 'hair dyeing agents, bleaching agents, hair styling agents for hair styling, hair styling, etc.; excessive combing, human wind, etc. Sexual treatment; or affected by ultraviolet rays, etc. 'The hair, especially the surface of the hair, tends to be vulnerable. If the surface is damaged, the loss of the lipid layer, which functions as a protective layer for the hair surface, causes such a problem that the hair is dry, the touch and the gloss are deteriorated. Further, there is a state in which the interstitial substance located inside the hair flows out from the hair, the elasticity of the hair (i.e., the tension and dynamics of the hair), the decrease in productivity, and the branching are caused. In order to reduce or repair the damage on the surface of the hair, or to achieve the purpose of protecting the surface of the hair, Lu has used hair modifiers. In the past, the hair-reinforcing agent is mainly composed of a polymer compound having an oily month and a film shape, or a fourth-grade ammonium salt such as stearyltrimethylammonium chloride (STAC) temporarily attached to the hair. Table φ H changes the state of the hair. For example, the surface of the hair that is hydrolyzed and ionized by injury may be hydrophobized by the electrostatic interaction of the STAC key or the like and the physical phenomenon such as adsorption. As a result, the frictional resistance of the surface of the hair is reduced as compared with the case of 200826968, and the surface repair of the hair is achieved: the use of the 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 疋 毛 毛 毛 毛 发表 发表 发表 毛 毛 毛 发表 STA STA STA STA STA STA STA STA STA STA STA STA , Mu 1 uses a double-glucosyl gallate (DGA) hair modifier (see the non-patent literature for leather: =, also known as containing protein hydrolysate and amino acid as a hair injury The repair component, ^ ^ the hair damage of the injury site ... and not only for the purpose of hair modification, the purpose of keratin modification. ... keratin protein to achieve the use of Si as described above by the use of ionic bonds, hydrogen bonds and other electrostatic Interaction = transcript 'Although temporary effect can be obtained, but with the capacity = first: π - such as the hair modifier on the surface of the hair is easy to be washed off. 1 gentleman wants, $ Yushi + mountain /, , °, the hydrophilic part of the hair surface and the ionic part will go out again, the dryness of the hair, the finishing and the deterioration of the touch will regenerate. Because of the use of the above t hair modifier, not only the modification of the hair surface No solution to the problem In addition, there is a problem that the hair styling effect is low in persistence. The hydrolyzate of the word peptone and the amino acid are used as the hair cosmetic on the hair of the hair = force, although the tension of the hair can be obtained to have an effect of early effects. The persistence is not satisfactory. In the literature 2, the fiber treatment method of the keratin fiber which forms a covalent bond by the deuteration reaction of the acid hydrazide has specifically revealed the acid halide aqueous solution used for the usual hair. From the standpoint of safety in terms of stability, human susceptibility, and mutationality, acid halides are not easy to use. 200826968 Based on these problems, the development of hair that has been damaged in nature has been developed to enhance hair. A hair modifying agent which is excellent in finishing, moisturizing, and elastic, and has excellent sustained effects is desirable. Non-Patent Document 1: Yuichi NISHIDA et a丨 "ρ ·. Λ et al.5 Repairing Effect of Diglucosyl Gallic Acid 〇n Coinrinrr

Coloring-Damaged Hair59 JOURNAL OF OLEO SCIENCE V〇] ^ xr ^ .. ' u, Voi·53, N〇6, 295_304 (2004) Patent Document 1: Japanese Patent Laid-Open No. 11-13994 No. Patent Document 2: Special Open 2000 SUMMARY OF THE INVENTION An object of the present invention is to provide a hair modifying agent which substantially modifies damaged hair, enhances the finishing property, moisturizing property, and elasticity of hair, and has excellent sustained effect. A hair cosmetic having the hair modifying agent and a method of modifying the hair using the hair cosmetic. As a result of an effort by the present inventors, it has been found that an esterified product of an unsaturated dicarboxylic acid and a linear or branched saturated or unsaturated alcohol can overcome the shortcomings of the prior hair modifying agent and has the convenience of use. The present invention has been completed in terms of sex and safety to the living body, and at the same time, has a more remarkable and excellent modification effect on the damaged hair. In order to solve the above problems, according to a first aspect of the present invention, a hair modifying agent comprising a linear dicarboxylic acid having 4 to 6 carbon atoms and a linear chain having 12 to 24 carbon numbers or An esterified product of a branched saturated or unsaturated alcohol. The above esterified product is a diacetate, and the above-mentioned unsaturated dicarboxylic acid has at least one carboxyl group in the two carboxyl groups and the above-mentioned unsaturated hydrocarbons form an ester bond if the above unsaturated alcohol forms an ester bond. It is better. It is preferred that both of the bases of a few acids are saturated or unsaturated as described above. Further, the above unsaturated dicarboxylic acid is preferably maleic acid. It is preferred that the above saturated or unsaturated alcohol has a saturated alcohol having 18 to 22 carbon atoms and having a linear or branched form. It is preferred that the above-mentioned saturated or unsaturated alcohols have 18 to 22 carbon atoms and have a linear or branched unsaturated alcohol. It is preferred if the above unsaturated alcohol is stearyl alcohol. & If the above esterified product is dioctadecenyl maleate, it is preferably. Soil According to a second aspect of the present invention, a hair cosmetic containing the above hair styling agent is provided. According to a third aspect of the present invention, there is provided a method for modifying a text, comprising the step of applying the hair cosmetic to the hair.

L I YUAN WAN J is described in detail with respect to the present invention in terms of a hair modifying agent, a hair styling, a +, a sputum, and a hair styling. In the present application, "毛•傅剂" refers to a preparation which can reduce or repair hair. 2: Cage 4 hair surface -11 This enhances the finishing and moisturizing properties of the hair: ::Special. Further, the term "hair cosmetic" as used in the present application refers to a cosmetic material which is formed by the contact of keratin substances present in the human body such as contact hair. For this hair cosmetic, for example: she w agent. With hair conditioner, t, for example, shampoo, moisturizing /, month and hair cream. In the case of hair styling, for example, there are hair gel, lotion, curtain 8 200826968 " jin and border soil. In the case of the hair cosmetic, in addition to the hair conditioner and the hair styling agent described above, there are, for example, a hair dye, a hair coloring agent, a manicure, a perm agent, a curl correcting agent, etc., for dyeing hair or A topical cosmetic composition prepared by adding an additive component to a drug in a straightening/straight purpose. The hair modifying agent according to the present embodiment contains an unsaturated dicarboxylic acid having 4 to 6 carbon atoms and a saturated or unsaturated alcohol having 2 to 24 carbon atoms and being linear or branched. Esterified product. In the esterified product, at least one of the two carboxyl groups of the above unsaturated dicarboxylic acid forms an ester bond with the above-mentioned saturated or unsaturated alcohol. The hair cosmetic of the present embodiment contains the above-mentioned hair modifying agent, that is, the above-mentioned esterified product. In the case of the above-mentioned esterified product, for example, the two carboxyl groups of the above-mentioned unsaturated dicarboxylic acid form a diesterified product of the aceton bond with the above saturated or unsaturated alcohol. In addition to the diesterate, in the case of the above esterified product, for example, only one of the two carboxyl groups of the above-mentioned unsaturated dicarboxylic acid is opposite to the above-mentioned saturated or unsaturated alcohol, and an S曰 bond should be formed, and the other A carboxyl group and an alcohol other than the above-mentioned saturated or unsaturated alcohol form a diester of an ester bond. In addition to these diesters, in the above-mentioned esterified product, for example, only one of the two carboxyl groups of the above-mentioned unsaturated dicarboxylic acid forms an ester bond with the above-mentioned saturated or unsaturated alcohol, and the other carboxyl group is not formed. a monoester of an ester bond. Among the specific examples of these esterified materials, the above respective diester compounds are preferred. The hair modifying agent and the hair cosmetic of the present embodiment are not particularly limited as to the type of the acetate, and the above-mentioned ester bond is prepared as long as it is a saturated dicarboxylic acid corresponding to an acetate and a saturated or unsaturated alcohol. 9 200826968 Ester can be used. The two carboxyl groups of the above-mentioned unsaturated dicarboxylic acid and the above-mentioned saturated or non-existing yeast form a g-bond of the g-bond, which can be obtained by the following method, that is, the diester compound can be unsaturated An acid anhydride of an carboxylic acid or an unsaturated diacid and a long-chain alcohol compound are obtained by dehydrating a solvent which can be azeotropically dehydrated by adding a catalyst, and then removing the solvent. Regarding the production of the second cooling compound, for example, the solvent which can be azeotropically dehydrated is, for example, toluene. In the two carboxyl groups of the above unsaturated dicarboxylic acid, only one of the carboxyl groups reacts with the above saturated or unsaturated alcohol to form an ester bond, and the other carboxyl group has an ester bond other than the above-mentioned saturated or unsaturated alcohol. The diester can be obtained, for example, by the following method. That is, the second brewing compound; the acid needle which is not saturated with di-m or acid, and the alcohol compound which is not used alone, may be mixed with the catalyst, and the melting of μ-# After the dehydration and esterification of the medium, the steamed crane or the appropriate use of the exhibition ρ 、, 6%, the field is used to separate the guanidine column of each agent and the fine clothing. Regarding the production of the diesterified compound, Izak, Ik, is a solvent which can be azeotropically dehydrated, for example, toluene. Acid, cis-butenedioic acid, enedionic acid. In the case of the above unsaturated dicarboxylic acid, there are, for example, fumarenedioic acid, acetylene dicarboxylic acid, butyl succinic acid, cis methyl glutaconic acid, trans, transhexadiene, and cis. Among them, maleic acid is preferred. Alcohol, 1-octaol, and the above saturated or unsaturated alcohols, for example, tridecyl alcohol, tetradecanol, hydrazine-pentadecanol, ten丄19, Ethyl alcohol, 丨_20-alcohol, II. ^11-alcohol, 丨_22 _, tetradecanol, 2·dodecanol, 4 butyl-drunk 1- Undecyl alcohol, 4·methyltetradecyl alcohol, butyl alcohol, 1-1-heptadecanol, 10 200826968 2-pentadecanol, 2-hexadecanol, 7-methylhexadecanol, 4-heptadecanol, Isostearyl alcohol, 2-octadecyl alcohol, 2-nonadecanol, 9-methyl-1-nonanol, 2-dodecene-1 alcohol 8,10-11-ethylidene-1-fermentation, 7 ·12-fast-1·alcohol, 2-diluted alcohol, 9-tetradecenol, 9,12-tetradecyl vinyl alcohol, stearyl alcohol, stearyl alcohol, octadecyl alcohol, 11-twen En-1-ol, 5,8,π,14-t-buten-1-ol, 13-eicodiene-ol, 2,6,10-trimethyl_5,9_11 Vinyl alcohol, 3,7,11,15_tetramethyl_2_10 Enol, 3,7,u,i5_tetramethyl-2,6,l,l4-hexadecene-indole-alcohol, wherein it has a carbon number of 18 to 22 and is saturated with a straight bond or a branch Further, it is preferred that the alcohols are unsaturated. The alcohols may be used singly or in combination of two or more. The alcohols other than the above saturated or unsaturated alcohols may have, for example, a carbon number of from 1 to 11. The alcohol is preferably an alcohol having an i8 carbon number, particularly preferably methanol, ethanol, isopropanol or octanol. For example, the diesterified product of the above-mentioned saturated or unsaturated alcohol to form an ester bond, for example, the above-mentioned unsaturated dicarboxylic acid compound, and the above-mentioned saturated or unsaturated alcohol The diesterified compound in the specific example. The diester compound and a, specifically, for example, di-dodecyl maleate, ditetradecyl maleate, and cis-butane Dihexadecyl phthalate, di-octadecyl maleate, di-docosyl maleate, di-octadecene maleate, cis Di-octadecyl enedomate, di-octadecyl methacrylate, bis(11-eidecyl) maleate, di-isooctadecane maleate曰Sandic acid bis 3,7,11,15-tetramethyl·2-hexadecenyl ester, hexadecane octadecyl methacrylate, octadecyl maleate Ester ester, cis-butyl 11 200826968 octadecyl octadecyl octadecyl ester, eicosanyl octadecyl maleate, octadecyl hexadecyl maleate, maleic acid Octadecyl alcohol octadecyl ester, di-dodecyl fumarate, di-tetradecyl fumarate, di-hexadecyl fumarate, antibutene Di-octadecyl acid ester, di-taucan ester of fumaric acid, di-isostearyl fumarate, di-octadecyl fumarate, anti-butene Di-octadecadienyl acid ester, di-octadecyl propylene fumarate, di-11-eicosyl fumarate, fumaric acid di-3,7,11, 15-tetramethyl-2-hexadecenyl ester, cetyl octadecyl fumarate, octadecyl octadecyl fumarate, anti-butene Octadecylethylene octadecyl ester, fumaric acid eicosyl octadecene vinegar, octadeca hexadecane octadecenyl ester, fumaric acid octadecyl octadecyl ester, Dioctadecylate of acetylene dicarboxylate, di-octadecyl acetylene dicarboxylate, di-octadecyl methylene succinate, decyl succinic acid Di-octadecyl decyl succinate, di-octadecyl cis methyl succinate, di-octadecyl glutaconate, di-octadecyl glutaconate , anti-, di-octadecyl dihexadienoate, anti-hexadienyl-octadecyl ester, cis, cis-dihexadiene di-octadecyl ester, and cis, cis Hexamethylene mono-octadecyl ester. Among them, in terms of the affinity with the damaged surface of the hair and the excellent effect of the finishing property and the persistence of the hair, the fried fe-e-element, the maleic acid di-tetradecene is used. , di-hexadecyl maleate, di-octadecyl maleate, di-undecyl maleate, di-isooctadecane maleate Ester, octadecyl maleate, di-octadecyl maleate, octadecyl methacrylate, bis-pentadecene maleate Ester, di-3,7,U 15 12 200826968 tetramethyl-2-hexadecene cis-butene „, 一一_3,7, Η,1 tetramethyl-2-decene, 十Hexadecane octadecene, octadecyl octadecyl ester, cis, field, butyric acid, eicosyl octadecyl octadecene Butene octadecyl octadecyl octadecene cis butyl octanoic acid octadecyl ethene sulphur octadecyl octadecyl octadecyl octadecyl octadecyl ester And maleic acid II _ excellent. In addition, in the former sincere correction * r olefin, slow acid and before The θ ' obtained from a saturated alcohol is preferably a saturated monocarboxylic acid and a = sensation of the hair, specifically, a finishing residue of the hair, a sense of smoothness, and a softness. - From the unsaturated and unsaturated alcohols, only one of the two slow bases of the above-mentioned unsaturated diteric acid is: a saturated or unsaturated alcohol forms a vinegar bond' and another carboxyl group and a non-saturated alcohol The material of the (4) type of core bond is _---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- Ethyl maleic acid, hexadecyl vinegar, octyl octadecyl maleate, octyl octadecyl sulfonate, octylisostearyl maleate. The compound may be used alone or in combination with a hair cosmetic or a hair cosmetic. The amount of the cooling compound in the hair modifying agent or the hair cosmetic may be based on the moisturizing feeling and the tactile sensation of the hair. In terms of efficiency improvement, and it is possible to give a hair a better touch, it is preferably 1 to 20% by mass in 〇·〇, 〇〇5~1〇% by mass is more preferable, and 〇1 to 5% by mass is particularly preferable. The hair modifying agent and the hair cosmetic material may be selected from the group consisting of the above-mentioned ester compound as a component other than 13 200826968. The formation of at least one of the polymer compound and the polymer compound: a surfactant, for example, a cationic polymer, an anionic polymer compound, and a nonionic polymer. "The substance, the amphoteric polymer, the above-mentioned oil component" For the oily component to be imparted to the hair, for example, there is a grease:::: the touch of the hair. Acid, base (4), and high-grade fat. For the above-mentioned fats and oils, for example, there is eucalyptus oil. ♦ Milk, wood oil, rape oil, tea oil, mountain oil wide: lha six oils, big oil, cotton oil, sesame oil, oil, peanuts, cockroaches, cockroaches, corn wheat germ oil, Hawaii Volcanic beans and printed butter. Brown exfoliation, jojoflitol, hexadecane / plucking oil, rice bran oil, rice germ oil oat oil, grape seed oil, avocado tree oil, carrot oil lotus seed oil, linseed oil, raisin oil For example, there are beeswax, candidone wax/yellow, and linoleic acid g. ^ In the case of the above higher alcohols, 'for example, dodecanol, stearyl alcohol, eicosyl alcohol, behenyl alcohol, octyldodecanol, decyltetradecyl alcohol, ten": isostearyl alcohol, 2-Alcohol, sheep, octadecyl alcohol, octadecyl alcohol, octadecyl acid, and broad. For the above higher fatty acids, for example, dodecanoic acid, hexaic acid, octadecanoic acid, behenic acid, and iso-decene Octaic acid, the base of the ten to ^ (four), eighteen ethyl acetate, ten people of acrylic acid, wool fatty acid. In the case of the oil core two r 'for example, the alcohol (single eight " kegan ether,,, know ( Early hexadecane glyceryl ether), oleyl alcohol (monooctadecyl glycerol, and iso-octadecanyl glycerin scale. 14 200826968 For the above vinegar, for example, dipropyl adipate, dibutyl adipate Purpose, dioctyl adipate S, adipic acid 2-hexyl fluorenyl S, adipic acid di-octadecane S, tetradecanoic acid isopropyl vinegar, octanoic acid hexahydrate S, isooctanoic acid Six burned vinegar, isodecyl isononanoate, isodecyl isononanoate, isotridecyl isononanoate, diisopropyl isopropyl sebacate, octyl octadecanoic acid, hexadecanoic acid isopropyl g, ten Butyl octaester, octadecyl octadecanoate Decyl hexyl hexanoate, tetradecyl octanoate, decyl decanoate, hexyl decyl dimethyl octanoate, triisoindole sulphate, isooctadecanyl myristate, sixteen 2-ethylhexyl acid ester, octyl dodecyl ricinoleate, fatty acid (C 10-30) (cholesterol ester / lanosterol ester), decyl lactate, hexadecyl lactate, tetradecyl lactic acid Ester, octyl dodecyl lactate, lanolin acetate, isohexadecane octadecyl ester, isohexadecanoate isodecanoate, cholesterol ester 12-hydroxyoctadecanoate, di-2-ethylhexanoic acid Ethylene glycol ester, dipentaerythritol fatty acid ester, mono-octadecanoic acid N-alkyl glycol ester, hexadecanoic acid citrate, glyceryl tricaprate, neopentyl glycol diacetate, malic acid In the case of the above hydrocarbons, for example, α-olefin low polymer, light isoparaffin, light liquid isoparaffin, liquid isoparaffin, liquid paraffin, three Decane, polybutene, paraffin, polyethylene, microcrystalline wax, and petrolatum. With the above fluorenone and t, for example, dimethyl fluorenone, methyl phenyl fluorenone, cyclic bis fluorene, (4) 'Methyl hydrogen sulfonate, amine-modified fluorenone, ammonium-modified fluorenone, dimethyl polyoxyalkylene whose terminal is hydroxyl-denatured, alcoholic (4) _, aliphatic alcohol denaturation (4), burnt-based hair loss Ketone, poly bond denatured second ketone, epoxy resin denatured 7 ketone, and fluorine denatured 7 ketone. Specifically, the above fluorenone is, for example, octamethylcyclotetraoxane, octamethyl 15 200826968 s Oxane, mercapto polyoxyalkylene (dimethyl fluorenone), dimercapto oxo-methyl stearyl oxyalkylene oxide copolymer, dimethyl methoxy oxane-mercapto hexa oxysulfide Anoxane copolymer, stearyloxytrimethyl decane, stearyloxymethyl polyoxyalkylene, decamethylcyclopentaoxane, decamethyltetraoxane, tetra-decamethylcyclo Hexacosane, tetradecyl hexaoxane, tetrahydroxytetramethylcyclotetraoxane, decylcyclohexaoxane, tris(tributyloxy)oxymethane, three Methyl hydroxamic acid, biphenyl dodecyl hexaoxane 'hexadecylcyclocyclooxane, hexamethylcyclotrioxane, hexamethyldioxane, poly(ethylene oxide _ Epoxy propylene) methyl a siloxane copolymer, a polyethylene oxide-methyl polyoxyalkylene copolymer, a polyepoxy propylene-methyl polyoxyalkylene copolymer, a polymethacrylic acid I methyl-methyl polyoxy siloxane Branch copolymer, fluorenyl cyclic polyoxane, decyl hydroxy polyoxy siloxane, benzyl polyoxy siloxane, methyl polyoxy siloxane - hexadecyl ketone oxygenation - poly (ring Oxyethylene-epoxy propylene) methyl polymeric oxy-oxygenated copolymer, and poly(ethylene oxide-epoxypropylene)-butene-methyl polyoxyalkylene copolymer. In the specific examples of the above-mentioned fluorenone, at least one of the oxime methyl ketone, the polyether fluorenone, and the amino fluorenone can be preferably used to improve the feel of the hair. These oily components may be contained alone in the hair modifying agent or the hair cosmetic, and may be used in combination of two or more kinds. The content of the oily component in the hair dressing agent or the hair styling cosmetic is based on the ability to improve the moist feeling and the tactile sensation of the hair, and to prevent the hair from sticking, 〇.〇1 to 30% by mass Good, 0. 05~2〇% by mass, 〇m% by mass. 16 200826968 » _ The above surfactants make hair modifiers or hair cosmetics stable. In the stabilization of the hair modifying agent or the hair cosmetic, for example, there are dissolution, ~ π, cloning of the μ, and improvement of the dispersibility of the component. The interface activity sword, f. . L # 丨王^ and s, for example, there are nonionic surfactants, cationic surfactants, anionic surfactants, and amphoteric surfactants. In the following description, polyethylene oxide is referred to as p〇E, and polyoxypropylene is referred to as POP. Examples of the non-ionic surfactants include alkyl ethers, POE alkyl phenyl ethers, P0E POP alkyl ethers, p〇E sorbitan sulphate sa, and P0E propylene glycol fat. Acid esters, and aliphatic alkanolamines. Examples of the above cationic surfactant include dodecyldimethylammonium chloride, gasified cetanetrimethylammonium chloride, octadecyltrimethylammonium chloride, and alkyltrimethylammonium chloride. , octadecane dimethyl ammonium chloride, hexadecane dimethyl ammonium bromide, octadecyl trimethyl ammonium bromide, ethyl sulphate fatty acid aminopropyl propyl dimethyl ammonium, ten Eight burned trimethylammonium saccharin, hexadeced trimethyl ammonium saccharin, and tetracosyltrimethylammonium methyl sulfate. In the above anionic surfactant, for example, a burnt-based sulfate, a poe-based sulfate, a burnt-based sulfate, a sodium methyl octadecanoate, a triethanolamine dodecylbenzenesulfonate, and ten Sodium tetraethene sulfonate, P0E lauryl ether phosphate and its salt, N-dodecan glutamate, N-dodecylmethyl acetonate, carboxymethyl dextrin, and carboxyl group Methyl chitin. In the case of alkyl sulfate, for example, sodium lauryl sulfate is used. In the case of POE alkyl sulfate, for example, there is P0E sodium lauryl ether sulfate. In the case of the alkyl sulfate salt 17 200826968, for example, there is a triethanolamine dodecyl sulfate. In the case of the above-mentioned amphoteric surfactant, for example, there are 2 to 11-yl-n-carboxymethyl-N-hydroxyethylimidazolium betaine, cocoamide propyl betaine, and dodecane II. Methylaminoacetic acid: Alkaloids. The above cationic polymer, anionic polymer, amphoteric polymer, and nonionic polymer are generally known in the form of a polymer. The above cationic polymer is a polymer containing an amine group or an ammonium group bonded to a polymer chain, or a water-soluble polymer containing at least a component of dimethyldipropylene ammonium. In the case of a cationic polymer, for example, a cationized cellulose derivative, a cationic starch, a cationized guar gum derivative, a dipropylene quaternary ammonium salt polymer, a dipropylene quaternary ammonium salt-acrylamide Copolymers, as well as 4-stage polyvinylpyrrolidone derivatives. In the case of the above-mentioned commercial products of the cationized cellulose derivative, for example, the products of the Lion King Co., Ltd., "Leo Gade G", "Leo Gade Gp", and the joint carbide company's polymer "claw" 125", "Top_4", "Claw_30M", "LR-400", and "LR-30M". As the cationized cellulose derivative other than the cationized cellulose derivative, for example, hydroxyethylcellulose-methyl-propyl fine-grain chloride is used. For the products of the benzyl hexamethyl methacrylate hydride, for example, the products of the International Starch Chemical Company, "Sherman H-100", and rL_2 〇〇". For example, PHONE-"Jack-C-14S", the cationized guar gum derivative described in the article 5 POULENC company's product "Jack_c]3S", 18 200826968 "Ji-C-17", "Additional pa" "Building block-C-210", "Ji-C-162", and HI_CARE-1000 i 〇,,, u, 7 are commercially available as the above-mentioned propylene 4-grade ammonium salt polymer. "For example, the right public, the mountain people 4 Ge have the goods of the Dior · Naco company "Ma Yude." In the case of the above-mentioned propylene 4-grade ammonium salt propylene amide copolymer, for example, the product "Ma 寇 2200" and "Ma 仔 550" of the Ondigo Naco 8 q μ ^ J Α division The molecular weight of the 4-stage polyvinylpyrrolidone derivative is GM, and the commercial product of the 4-stage polyethylene σ 洛 洛 _ _ derivative is 5 cases of Shikougu D 丄 有 ISP The products of Japan Co., Ltd. are "Jiafu Chad 734", "Jiafu Chad 755", and "Jiafu Chad 755". j, in the case of a useful cationic polymer other than the above specific examples of the cationic polymer, for example, a gasified methacrylate polymer, specifically, e, for example, 2-methylpropenyl oxyethylphosphonate An alkali polymer, a methacrylic acid oxyethylphosphocholine 2 -hydroxy_3_mercapto propylene oxypropyltrimethyl sulfonium chloride copolymer, and a chlorinated choline choline polymer. For the products containing the chlorinated methacrylate polymer, for example, "Salke SC95" by Chiba Special Chemicals Co., Ltd., and "Rijuju hm" by "Salke SC96 曰本油知有限公司" "Lippi Pmb and "Lippu C". The cationic polymer may be contained alone or in combination of two or more kinds. Examples of the anionic polymer include an acrylic acid-acrylamide-ethyl acrylate copolymer, an acrylic acid-acrylamide-ethyl acrylate copolymer chlorination solution, and an acrylic acid group-methyl methacrylate. G-diacetone acrylamide-methacrylic acid copolymer solution, acrylic acid-alkyl methacrylate copolymer, propylene resin alcohol amine solution, carboxyvinyl polymer, hydroxy acrylate 19 200826968 propyl acrylate, methacrylic acid Tetraethyl ester, copolymer of octylamine acrylate, vinyl acetate-crotonic acid copolymer, vinyl acetate-crotonic acid-ethylene neodecanoate copolymer, vinyl acetate-crotonic acid-vinyl propionate copolymer, and methyl ethylene Ether-maleic acid monobutyl ester copolymer. In the case of the aforementioned amphoteric polymer, for example, N-methyl propylene oxime ethyl N,N-dimethylammonium a-N-nonyl carboxybetaine·butyl methacrylate copolymer, hydroxypropyl acrylate- a butylaminoethyl methacrylate-octyl decylamine copolymer, a gasified dimethyldipropylene-acrylic acid copolymer, a dimethyldimethacrylate-propylene acrylamide-acrylic acid terpolymer, And propyl acrylate-acrylic acid methacrylate-methyl methacrylate with N-methyl propylene oxime ethyl n,N-dimethylammonium α-Ν-methyl carboxyl beet test · butyl methacrylate copolymer For the commercial product, for example, "Kafama AM-75" manufactured by Mitsubishi Chemical Corporation. For example, the propyl methacrylate-butyl butyl methacrylate-octyl decyl methacrylate copolymer has "Anno 4 28_491" manufactured by the International Palace Powder Company. For the commercial product of a dimercapto-dipropylene-acrylic acid copolymer, for example, "Malay 295" manufactured by Ondion Co., Ltd. is used. A commercially available product of a terpolymer of dinonyldipropylammonium chloride-acrylic acid-acrylic acid, for example, "Malaysia +333〇" and "Ma" by Ondo. Chad +333 1". For the commercial product of a acrylic acid-methyl acrylate-methyl propyl amide propyl methacrylate copolymer, for example, "Ma 寇 细 细" manufactured by Ondigo. The type of the above-mentioned nonionic polymer is not limited, and specific examples thereof include a natural nonionic polymer, a semiquinone nonionic polymer, and a synthetic nonionic polymer. 〇 Κ 〇 Μ Μ Μ 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 Examples of the above semi-synthetic system and nonionic polymer include methyl cellulose, ethyl cellulose, transethyl cellulose, propyl cellulose, and hydroxypropyl methyl cellulose. Examples of the above-mentioned synthetic nonionic polymer include polyacrylic acid, polyacrylamide, polyethylene glycol, polypropylene glycol, P0E. p〇p copolymer, p〇p. simple butyl ether, and poly Women, POE monostearate, and ρ〇Ε distearate. The hair dressing agent and the hair cosmetic according to the present invention may be appropriately contained in a usual hair cosmetic composition in addition to the above-described various known effects. In terms of such a component, there are, for example, a solvent, an anti-dandruff agent, a vitamin, a preservative, an anti-inflammatory sputum, a chelating agent, a coloring agent such as a dye, a pigment, a carboxyvinyl polymer, a huangyuan#, a clay mineral, or the like. Viscosity modifier, citric acid, 2-amino/2-methyl-propanol, sodium hydroxide, etc., hydrolyzed terpenoid or amino acid and its derivatives, reducing agent, oxidizing agent, self-plant Extracts, pearlescent agents, perfumes, pigments, UV absorbers, antioxidants, and propellants extracted from animals or microorganisms. In this component, for example, there are a cosmetic raw material standard, a cosmetic type, a component specification, a statutory coloring matter manual, a Japanese cosmetics industry commissary component name list, and an INCI dictionary (The Internati〇nal Commie)

Ingredient Dicti〇nary and Handb〇〇k), quasi-pharmaceutical raw material specifications, quasi-pharmaceutical raw material specifications 2006, Japanese Pharmacy prescriptions, pharmaceutical additive specifications, and ingredients included in food supplements. The pH value of a type of pH acid and its salt hair modifier and hair cosmetic is adjusted between pH 3 and 1 () with a conditioning agent or a buffer containing organic acid or inorganic 21 200826968 pH buffer. Preferably, the adjustment is better between p and 5 to 8 5 'adjustment between pH 6. 〇 ~ 8.0. Examples of the organic acid containing a pH buffer include citric acid, oxalic acid, succinic acid, tartaric acid, lactic acid, fumaric acid, malic acid, and acetamidine. As the inorganic acid containing a pH buffer, there are, for example, phosphonium, sulfur & L, and nitric acid. Further, in the case of such acid salts, there are basic metal salts and alkanolamine salts. As the basic metal salt, for example, there are a sodium salt and a potassium salt. In the case of an alkoxylated amine salt, for example, an ammonium salt and a diethanolamine salt are mentioned. In the form of a hair modifying agent and a hair cosmetic, for example, a liquid, an oil-based emulsion, an oil-in-water emulsion, a composite emulsion, a microemulsion/, a spray, a gel, a foam, a granule, an emulsion, Creamy. The hair; the cosmetic and the hair cosmetic can be directly used as a hair conditioner for shampoo, moisturizing lotion, hair conditioner, hair lotion, lotion, hair wax, and the like. The hair dressing agent and the hair cosmetic may be contained in the form of a drug, a hair coloring agent, or the like, a hair dye, a curl correcting agent, or the like as a roll/straight purpose. : Pharmacy, and a drug for the purpose of hair growth. μ Hair modifier and hair cosmetic are suitable for washing with water or warm water after hair, and can be maintained in the state of being attached to the hair without washing. Alternatively, the hair modifying agent and the hair cosmetic of the present embodiment can be heated by application to the hair to achieve a hair styling agent and hair growth: reactivity with the surface of the hair and penetration into the hair. The above heating may be performed by using a heating device to maintain a specific time. In the case of heating 22 200826968 appliances, for example, there are hair dryers, warmers, steam engines, high-temperature hair-filling utensils, and self-heating appliances. The time to maintain when warming is appropriate in 1 to 30 minutes. In the case of using a high-temperature hair-lifting jewel in warming, the contact time between the hair around the place and the high-temperature hair styling is about 2 seconds to 1 minute. The hair modifying agent and the hair cosmetic of the present embodiment are treated with a hair dye treatment agent such as a denture dyeing agent or an acid dyeing material, or a hair treatment agent such as a bleaching agent, a permanent wave agent, or a curling correcting agent. Even if the hair is affected by factors other than the hair treatment agent, for example, hair damaged by the influence of ultraviolet rays can exert its effect. In other words, the hair modifying agent and the hair cosmetic of the present embodiment can protect the surface of the hair by reducing or repairing damage to the surface of the hair, thereby improving the hair of the damaged hair, effectively improving the finishing property of the hair, moisturizing, and elastic knives. And the long-term persistence of excellent effects and the touch after the completion. The reaction mechanism and the binding state of the above-mentioned known compounds on the surface of the hair are not the same, the main agglomeration, β _ ..., 'Shaw edge, but it is presumed that the unsaturated bond due to the adjacent ester site is right-handed. , ^ The reactivity of the singularity makes the acetate and the surface of the hair easy and strong to produce Α ^. The seat has a total of mussel bonds, and the adsorption capacity of the ester on the surface of the hair becomes high. The present invention will be described below by way of examples and comparative examples, but the present invention is not limited to the examples. Examples 1 to 6, Comparative Examples, 1 to 2, and Reference Example 1 (hair conditioner) As Examples 1 to 6 and Comparative Examples, only columns 1 to 2 and Reference Example 1 were as follows. The method to modulate has a table like! Zhang _ z, various hair conditioners that are not composed. For each of the examples and the comparison, the content of 23 200826968 per 100 g of esterified body of the #J mussel conditioner was set to 3 x 10_3 mol. In Reference Example 1, no esterified product was contained. In the order of Table 1, the unit corresponding to the value of each component is mass 0/〇. In addition, regarding the hair conditioner, the "slipness" of the hair surface, the "elastic feeling" of the hair, the "finishing property", and the "feeling feeling (smoothness, moist feeling, soft feeling, oily feeling)" In addition, the "sustainability" and the "damage reduction effect" of the hair were tested. The results of the test are shown in Table 3. <Preparation method> (1) In a 300 ml beaker, pure water, a pH adjuster, and each component other than "Rituthrone SM8704C" were added, and the final production amount was 3:g after the final production amount was 2'. The components were uniformly dissolved by heating at 80 °C. (2) Pure water in a final amount of 200 g was added to a 200 ml beaker, and after heating at 80 ° C, it was added to the mixture obtained in the above step (丨) to be emulsified. Then, the emulsified mixture was stirred while cooling. (3) After cooling the emulsified mixture to below 4 °C, add pH adjuster, ketone SM87 (MC), and pure water to prepare the final amount of hair conditioner. 24 200826968 Reference Example - 1 1 1 1 1 1 1 1 Appropriate amount 〇ο (Ν' (Ν1—1 οο ο (Ν r—Η 〇rn cn o τ-Η ο residual l〇〇gq r> Comparative example (Ν 1 1 1 1 1 1 1 1.86 Appropriate amount 〇ο (Ν (Ν 1 1 ( οο ο (Ν ο cn (T) o fH d Residual l〇〇go Τ-Η 1 1 1 1 1 1 1.86 1 Appropriate amount I 〇ο (Ν ( τ τ-Η οο ο CN ο cn cn o in ο Residual l〇〇gp Example ν〇1 1 1 1 1 S rH 1 1 Appropriate amount 〇ο (Ν (Ν τ—Η οο ο (Ν ο rn mo ^ T) ο Residual amount 100g o 1 1 1 1 1.44 1 1 1 Appropriate amount 〇ο CN (Ν 00 ο (Ν rH ο rn md T~( 〇 · Residual lOOg o inch 1 1 1 1.18 1 1 1 1 ο ... ο <Ν CN οο ο <Ν ο cn md rH 〇Residual amount I lOOg o 卜^ m 1 1 1.35 1 1 1 1 1 Appropriate amount ο ο <Ν <Ν 'Γ-Η οο ο (Ν rH ο Cn mor—H 〇Residual amount I lOOg o (N 1 1.86 1 1 1 1 1 1 Appropriate amount ο wS ο (Ν (Ν 00 ο (Ν FH ο m 〇«T Io Residual amount lOOg o 1 < 1.85 1 1 1 1 1 1 1 1 Appropriate amount | ο Ό· ο (Ν (Ν 1—Η 00 ο (Ν r"H ο cn O yn rH 〇 residual amount lOOg o cis-butene Di-octadecyl dicarboxylate di-octadecyl maleate cis-butane dicarboxylic acid di-dodecyl vinegar maleic acid ethyl octadecyl ester maleic acid octyl ten Octenyl maleate maleate octadecyl ester succinate octadecyl succinate di-octadecyl ester pH adjuster (80% monoethanolamine or phosphoric acid) ※1 hexadecanol liquid stone butterfly ΡΟΕ(30)Cetyl ether oxime (5.5) cetyl ether gasification octadecyltrimethylammonium 1,3-butane diol Shelter Ceylon SM8704C*3 Perfume pure water total distillate鍩鮏Κ3 spider%0〇〇·· I※ (铋i?<<tl5.龟修螇螇)瘃佑蓉铋咪域碱 to ^砩鍩_ο蝶鸽:ε※ (铋t?<<斋^伞3⁄4逄®)荽^^竣<^爱¢u<^ &-M♦ 鳟 鳟 ^ ^ ^ : 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 2008 The hair of a Japanese woman, grows a hair bundle that grows 15cm and weighs 2.0g. After that, the hair bundle was subjected to two bleaching treatments using a pr〇master LT manufactured by Heyou Co., Ltd. to prepare a hair bundle for evaluation. (2) Treatment of the hair bundle for evaluation The hair bundle for evaluation was wiped with a towel after the hairdressing of the professional master color-protecting shampoo for the evaluation of the hairdressing system. Next, each of the hair conditioners of the examples, the comparative examples, or the reference examples was applied to the evaluation hair bundle uniformly, and placed in a thermostat at 50 ° C for 1 minute. Thereafter, the hair conditioner was thoroughly washed off. Then, the evaluation hair bundle was dried using a hair dryer. (3) Evaluation method The friction coefficient measuring device manufactured by Kartika Co., Ltd. was used to measure the dynamic friction coefficient of the hair surface on which the evaluation was applied, and the "slipness" was judged based on the measured Miu value and the MMD value. In the same evaluation, the hair bundle was used to measure the change in the surface of the hair before and after the treatment. The hair hair bundles treated by the hair conditioners of the examples and the comparative examples were compared with the hair hair bundles treated according to the reference hair conditioner, and were classified into very good and good in comparison with the reference examples. 〇〇), good (〇), equivalent (△), slightly bad (X), and bad (XX) five grades. "Essence of elasticity", "finishing", "feeling (smoothness, moistness, softness, oiliness)" and "sustainability" evaluation 26 200826968 (1) Evaluation of the use of hair bundles The hair of a Japanese woman who is chemically treated, such as dyeing hair, is made into a hair bundle that grows 25 cm in weight and l〇g. After that, the hair bundle was subjected to two bleaching treatments using a professional LT manufactured by Heyou Co., Ltd., and then subjected to perm treatment using a Feitmi wave 45 manufactured by Heyou Co., Ltd. to prepare a hair bundle for evaluation. (2) Treatment of the hair bundle for evaluation The hair bundle for evaluation evaluation was wiped with a towel after the hairdressing of the professional shampoo cleaning evaluation by the company. Next, each of the hair conditioners i.Og of the examples, the comparative examples, or the reference examples was uniformly applied to the evaluation hair bundles and placed in a 50 C thermostat for 10 minutes. Thereafter, the hair conditioner was thoroughly washed off. Then, the evaluation hair bundle was dried using a hair dryer. (3) Evaluation criteria The evaluation evaluation hair bundles were evaluated by #5, and the price was calculated based on the basis shown in Table 2, and the average value of the evaluation scores was calculated. (4) Sustainability evaluation. The evaluation of the ping price was carried out in the above-mentioned manner, and the hair was cleaned and evaluated by the hair dryer after the hairdressing of the professional master of the company. Then, after the treatment, the hair bundle for evaluation was evaluated by the above-mentioned five evaluations, and the sensory evaluation was performed based on the basis of the evaluation, and the effect was evaluated. The hair coloring bundles treated by the hair conditioning agents of the respective examples and the comparative examples are in accordance with the hair conditioning agent of the reference example: often good (〇〇), good micro-defective (x), and poor ( XX) Five levels. 27 200826968 Table 2 Elasticity finishing property 5: Obviously elastic feeling compared with Reference Example 1 4: slightly elastic feeling compared with Reference Example 1 3: Compared with Reference Example 1 with the same elastic feeling 2: and Reference Example 1 Compared with a slight lack of elastic feeling 1: Compared with Reference Example 1, there is a clear lack of elastic feeling 5: Compared with Reference Example 1, there is a clear finishing property 4: Compared with Reference Example 1, there is a slight finishing property 3: Compared with Reference Example 1 It has the same finishing property 2: a slight lack of finishing property compared with Reference Example 1: Compared with Reference Example 1, there is a clear lack of finishing smoothness and moist feeling 5: Compared with Reference Example 1, there is a noticeable smoothness 4: and reference Example 1 has a slight smoothness compared to Example 3: It has the same smoothness as Reference Example 1 2: A slight lack of smoothness compared with Reference Example 1 1: Significant lack of smoothness compared with Reference Example 1 5: Compared with Reference Example 1, there was a noticeable moist feeling 4: a slightly moist feeling compared to Reference Example 1 3: an equivalent moist feeling compared to Reference Example 2 2: a slight lack of moist feeling compared with Reference Example 1 : and reference Example 1 was significantly weaker than the soft feeling of the oily feeling (feeling) 5: Compared with Reference Example 1, it was noticeable softness 4: slightly softer than Reference Example 1. Sense 3: Compared with Reference Example 1, there was an equivalent soft feeling 2: a slight lack of soft feeling compared with Reference Example 1: Compared with Reference Example 1, there was a clear lack of soft feeling 5: Compared with Reference Example 1, there was a noticeable oily feeling 4 : Slightly oily compared with Reference Example 1 3: Compared with Reference Example 1, it has the same oiliness. 2: Compared with Reference Example 1, there is a slight lack of oilyness. 1: Compared with Reference Example 1, there is a clear lack of oiliness. Evaluation of the effect (1) Evaluation of the hair bundle The hair of a Japanese woman who has not been chemically treated with a perm or hair dye is used to grow a hair bundle having a length of 15 cm and a weight of 2.0 g. After that, the hair bundle was subjected to bleaching treatment twice using a professional LT manufactured by Heyou Co., Ltd. to prepare a hair bundle for evaluation. (2) Treatment of the hair bundle for evaluation The hair bundle for evaluation was wiped with a towel after the hairdressing of the professional master color-protecting shampoo for the evaluation of the hairdressing system. Next, each of the hair conditioners of the examples, the comparative examples, or the reference examples was uniformly coated on the evaluation hair bundle 28 200826968

Evaluation method Price method (moisture absorption rate of hair)

p judges that there is a hair damage reduction effect. The damage reduction effect of the hair bundle for hair treated by each of the hair styling agents of the examples and the comparative examples was compared with the reference example 1 by the hair bundle treated with the hair conditioner according to Reference Example 1 as a control. Very good (良好), good (〇), equivalent (△), slightly bad (X), and bad (XX) five grades. 29 200826968 Comparative example (NX (N oo < N 〇〇CN CN < N << si <] inch (N < N (N (N rN inch (N 〇 (N << Example < (N m 〇cn OO (N (N m 〇(N cn < 〇〇oo cn m 寸 m oo cn m 00 cn 1 〇〇_1 〇 inch 〇 oo cn inch m O m cn ( N cn o inch 〇〇 〇 CO oo cn inch cn 00 cn cn o inch 〇〇 (N [〇〇" o inch oo cn 〇 inch o inch <N m 00 cn 〇〇〇rH 1 〇〇—” &lt ; N inch (N inch o inch inch oo m inch cn oo 〇〇 smooth feeling (hair friction test) elastic feeling finishing touch (smooth feeling) N w touch (soft feeling) touch (oily sexy) effect Persistence ί ^ Μ Μ % Umbrella · 200826968 The results on the field can be confirmed, hair makeup » λ, the hair modifier and the hair = family, to reduce the damage of the hair surface and protect the hair from the hair Intrinsically modified to enhance the finishing, moisturizing, and elastic properties of the hair, and it has excellent..., sensation. Eight-leaf long-lasting J performance and after the end of the touch Example 7 (shampoo) 4

—~Home-based Sodium Sulfate Coconut Oil Ester Fatty Acid Aminopropyl Sweet Vegetable

Chlorinated 0-[2_hydroxy_3_(trimethylphenyl cellulose oxalic acid tetra-n-taurine flavor water

Lemon) Residual adjustment to pH5.5_ ------ m /______je» Two t-p 丄uj The shampoo prepared by mixing the ingredients shown in Table 4 in the usual way, with excellent rinse time Suppleness, smoothness after drying, and moisture retention. 31 200826968 Example 8 (non-rinsing hair conditioner) Table 5 (% by mass) Di-isooctadecyl maleate 4.0 Cetyl alcohol 0.8 Glycerol 1.0 Decylcyclopentaoxane 2.5 High polymerization Mercapto polyoxyalkylene 1.5 gasification alkyl trimethyl ammonium 0.5 isopropyl methyl phenol 0.3 hydrolyzed silk 0.2 perfume 0.05 water residue tartaric acid (pH adjuster) adjusted to pH 6.0 as shown in Table 5 The hair conditioner is prepared by mixing and mixing the hair conditioner to have an appropriate oily feel, suppressing a sticky feeling, and having excellent hair finishing properties and moisturizing properties. Example 9 (Hair conditioner) Table 6 (% by mass) di-octadecyl maleate 5.0 microcrystalline wax 3.5 tetradecanoic acid neopentyl tetraester 1.0 32 200826968 octadecanoic acid 2.0 highly polymerized methyl group Polyoxane 0.5 Di-propylene glycol 0.5 Retinoethylene polymer 0.1 Hydrolyzed oat protein 0.5 Perfume 0.05 Water residue Aminomethyl propanol (pH adjuster) Adjusted to pH 6.5 The ingredients shown in Table 6 are normalized The hair styling agent is prepared by mixing, has a moderate setting force at the time of completion, and has excellent hair finishing property and moisture retention property. Example 10 (dyeing agent) Table 7 (1st agent) (% by mass) Toluene-2,5-diamine 1.5-Aminophenol 1.0-M-aminophenol 0.3 Isophthalene 0.4 Amino-o-cresol 0.2 28 % ammonia water ascorbic acid 0.5 octadecyl alcohol 2.0 propylene glycol 4.0 benzyl alcohol 8.0 33 200826968 P〇E(25) behenyl ether - 12.0 POE (1 〇) octadecyl ether 8.0 octadecyl trimethyl chloride According to 1.0 amine-terminated dimethyl polyoxane 0.3 sodium sulfite - 0.1 EDTA disodium 0.1 water residue amount 8 (second dose) (mass ° / 〇) maleic acid di-isostearyl ester 1.5 Octadecyl alcohol 1.5 POE (2) hexadecyl group _ 0.3 POE (3 〇) hexadecyl group _ 0.3 octadecyltrimethylammonium chloride 0.3 glycerol 2.5 sodium stannate 0.1 35% hydrogen peroxide 16.6 water --- -- Residual phosphoric acid was adjusted to pH 4.5. The ingredients shown in Table 7 and Table 8 were mixed and prepared into the summer agent and the second agent was dyed with 5 liters of & The hair dye has an excellent ratio of 1 to 1 to prepare a hair dye and use 4. As a result, not only natural hair dyeing hair but also a moderate smoothness and glossiness can be obtained. In addition, the finishing of the hair. 34 200826968 [Simple description of the diagram] None [Key component symbol description] None 35

Claims (1)

200826968 X. Patent Application Range: 1 · A hair modifying agent' characterized by containing an unsaturated dicarboxylic acid having 4 to 6 carbon numbers and a linear or branched shape having 12 to 24 carbon numbers An acetate obtained from a saturated or unsaturated alcohol. 2. The hair modifying agent according to claim 1, wherein the ester compound is a diester compound, and at least one of the two carboxyl groups of the unsaturated dicarboxylic acid forms a vinegar bond with the saturated or unsaturated alcohol. 3. The hair modifying agent according to claim 2, wherein the unsaturated-Wei S(tetra) two carboxyl groups and the saturated or unsaturated alcohol form a vinegar bond. 4. The hair modifying agent according to claim 1, wherein the unsaturated dicarboxylic acid is maleic acid. 5. The hair modifying agent according to claim 1, wherein the saturated or residual alcohol is a linear saturated alcohol having a carbon number of 18 to 22. The hair styling agent is the hair modifying agent according to the item i of the patent application scope, wherein the or unsaturated alcohol has a polyunsaturated alcohol. There are 18~22 slaves in a linear or branched shape. The scope of the patent is 帛6, and the saturated alcohol is octadecyl alcohol. In the cookware, the 8: patent application scope " member's hair modifier is: butyric acid di- 18 vinegar. In the sputum, the vinegar is a hair cosmetic which is characterized by any one of the items 1 to 8. There is a scope of application. 1 0. A method for modifying the main county, which is characterized in that it has a step of applying the hair cosmetic of the ninth item of the application. Eleven, circle: no 37