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TW200811300A - A treatment method of metalization of metal or ceramic substrate - Google Patents

A treatment method of metalization of metal or ceramic substrate Download PDF

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Publication number
TW200811300A
TW200811300A TW95130377A TW95130377A TW200811300A TW 200811300 A TW200811300 A TW 200811300A TW 95130377 A TW95130377 A TW 95130377A TW 95130377 A TW95130377 A TW 95130377A TW 200811300 A TW200811300 A TW 200811300A
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Taiwan
Prior art keywords
layer
metal
conductive layer
substrate
plating
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TW95130377A
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Chinese (zh)
Inventor
Wen-Jun Zhou
Original Assignee
Wen-Jun Zhou
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Publication date
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Priority to TW95130377A priority Critical patent/TW200811300A/en
Publication of TW200811300A publication Critical patent/TW200811300A/en

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Abstract

A treatment method of metalization of metal or ceramic substrate is disclosed. The step are as follows: metal or ceramic substrate surface is plated with a heat conductive insulation layer by a batchwise continuous surface treatment physical vapor deposition (PVD) technique. The heat conductive insulation layer is then plated with an electric conductive layer through a batchwise continuous surface treatment PVD technique. The electric conductive layer includes using chromium (Cr), aluminum (Al), titanium (Ti), copper (Cu) to carry out metalization treatment. Electroplating is applied on the surface of the electric conductive layer to integrate the electroplating layer onto the electric conductive layer resulting in increasing the thickness of the electric conductive layer. This technique uses batchwise continuous surface treatment PVD technique to consecutively form a homogeneous heat conductive insulation layer and a homogeneously electric conductive layer on the metal or ceramic substrate. The electric conductive layer is then electroplated onto the electric conductive layer till to the required thickness.

Description

200811300 九、發明說明: 【發明所屬之技術領域】 一 本發明為有關於一種金屬或陶瓷基材金屬化處理方法,特別 •是指基板經金屬化鍍膜處理後,品質穩定,可提升高功率LED模組 散熱需求與使用效率。 【先前技術】 按,以現行既有基板的製造技術,主要係於一金屬基板(通常 •為鋁板)上施以一層具有導熱功能之絕緣膠,於絕緣膠上黏貼附有 -層厚約15條義屬,_高溫高壓環境下將鋪金屬壓合 於至屬基板上結合。由於銅金屬必須藉助絕緣膠與金屬基板, 在金屬基板的邊緣因應力集中的關係,會使得銅箔金屬層無法完 王!口合’甚至其間含有氣泡,也會使得結合性變差,導致鍾曲現 象,若是絕緣膠塗佈不均勻,亦會造成銅箔金屬層壓合後難以控 制其平坦度問題。 • a現階段—種高功率的LED為未來發展方向,目此現行的金屬基 板是所使用之導熱絕緣膠再經高功率LED模組運作時所產生的數 ,付(w)高溫狀態下’該導舰轉即無法騎產生的高溫,因此 膠體遇高溫即形成軟化,這時便會使得所結合之_金屬產生剝 離現象’魏於_製簡侧、定辦雜會大大影響。 【發明内容】 本發社要課題在_決上述高功率⑽基板目導熱絕緣效 率不佳所引起的相關問題’同時可以提高高功率led之效率與使用 5 200811300 壽命,進而使得基板品質、生產效率、成本及品質穩定度均高於 習知壓合技術。 r 本發明之主要目的,即表於提供一種具有鍍膜層之金屬或陶 #瓷基材’運用卿(Physical Vapor Deposition)批次級連續表 面處理技術,於金屬或陶瓷基材上依序形成一均勻之導熱絕緣層 及一均勻之導電層,後續再以電鍍技術於導電層上電鍍以達導電 層所需應用之增厚。 _ 本發明之次一目的,即在於提供一種一貫化製程作業,針對 '孟屬或陶瓷基材金屬化處理方式,將基材藉由PVD處理技術能使導 '…、、、巴緣層構成之成分以原子級狀態呈現均勻且確實的附著於基材 上’後績亚以PVD方式鍍覆導電層於導熱絕緣層上,最後一道續製 程以電鍍金屬方式增厚導電層輯需厚度;由於導熱絕緣層與導 電層均MPVD方式鍍覆技術處理,故基材、導熱絕緣層、導電層 之間得以達到具有穩定的結合效果。 ’ 【實施方式】 *有關於本發明為達上述目的、特__的技術手段及其功 技例舉較佳實施例並配合圖式說明如下: -請參閱第_圖至第三圖所示,本發明為—種金屬或陶絲材 二,_方法’其主要係於_上結合有導熱絕緣層2及 ¥包層3,其處理步驟為: 步驟―、基材1為金屬或陶兗基材,基材1可為銘⑻、銅 6 200811300 (Cu)、氧化鋁(Al2〇3)、氧化锆(Zr〇2)等材質; 步驟二、將基材1表面鍍覆一層導熱絕緣層2,該導熱絕緣層2 r 主要成分為氧化鋁(AI2O2)、氮化鋁(A1N)、氧化砍(Si〇D、氧化铪 • ⑽⑹及氧化鎢(W〇2)、氮化鉻((^)、氮化鈦(1^)、氮化鎳釩 (NiVN)等成分,由這些成分每種均可實施成為導熱絕緣層2,每種 成分均可由PVD批次級連續表面處理技術將其鍍覆於基材1表面, 達到具有高導熱效率與絕緣效果; • 步驟三、於導熱絕緣層2上以PVD批次級連續表面處理技術鍍 -覆導電層3,該導電層3包含以鉻(Cr)、鋁(41)、鈦(1^)、鎳(1^)、 銅(Cu),每種金屬成分均可實施成為導電層3,達到具有導電效果 之金屬鍍層。 步驟四、將具有導電功能之導電層3利用電鍍技術方式處理, 該電鍍層4為銅(Cu)電鍍層或其他金屬電鍍層,該電鍍層4結合於 V電層3上,依設計需求增後至所需厚度,以達到最佳傳導功率。 • 另外’在步驟三中,導熱絕緣層2所包含的成分,包含可以PVD 方式鍍著之導熱絕緣氧化物、氮化物、碳化物等均可以複合於導 .熱絕緣層2中。_含有這魏化物、氮錄、碳化物的導°熱絕緣 —鍍層2 ’可以與喊或是金屬材質之基财良好而穩定的結合。 【圖示簡單說明】 第一圖所示係本發明金屬基材結構剖面示意圖。 第二圖所示係本發明分層結構示意圖。 7 200811300 第三圖所示係本發明製造步驟流程圖。 【主要元件符號說明】 1. ···.····..··基材 2. · ....... · · · ·導熱絕緣層 3.............鍍膜層 4.. · .........電鍛層200811300 IX. Description of the invention: [Technical field of invention] A invention relates to a metallization treatment method for a metal or ceramic substrate, in particular, the method is characterized in that the substrate is subjected to metallization coating treatment, the quality is stable, and the high-power LED can be improved. Module cooling requirements and efficiency. [Prior Art] According to the current manufacturing technology of existing substrates, mainly on a metal substrate (usually • aluminum plate), a layer of insulating adhesive with thermal conductivity is applied, and a layer of about 15 is attached to the insulating adhesive. Article genus, _ high temperature and high pressure environment, the metal is laminated to the substrate. Since copper metal must rely on insulating glue and metal substrate, the copper foil metal layer cannot be finished due to stress concentration at the edge of the metal substrate! The mouth' even contains bubbles, which may cause the bonding to deteriorate, resulting in a bell-curve phenomenon. If the insulating coating is unevenly applied, it may cause difficulty in controlling the flatness of the copper foil after lamination. • a current stage – a kind of high-power LED is the future development direction. The current metal substrate is the number of heat-conductive insulating rubber used and then operated by high-power LED module, pay (w) high temperature state' The guide ship can not ride the high temperature generated, so the gel will soften when it encounters high temperature. At this time, the metal-debonding phenomenon of the combined metal will be greatly affected. SUMMARY OF THE INVENTION The subject of the present invention is to solve the related problems caused by the poor thermal conductivity of the high-power (10) substrate, and to improve the efficiency of the high-power LED and the life of the use of 5 200811300, thereby making the substrate quality and production efficiency. The cost and quality stability are higher than the conventional press-fit technology. r The main purpose of the present invention is to provide a metal or ceramic substrate with a coating layer, a physical Vapor Deposition batch-level continuous surface treatment technology, sequentially forming a metal or ceramic substrate. A uniform thermal conductive layer and a uniform conductive layer are subsequently plated on the conductive layer by electroplating to increase the thickness of the conductive layer. _ The second objective of the present invention is to provide a consistent process operation for the metallization treatment of the genus or ceramic substrate, and the substrate can be formed by the PVD processing technology. The composition is uniformly and surely adhered to the substrate in an atomic state. After that, the conductive layer is plated on the thermally conductive insulating layer by PVD, and the final continuous process is to thicken the thickness of the conductive layer by electroplating. Both the thermal conductive insulating layer and the conductive layer are treated by the MPVD plating technology, so that a stable bonding effect can be achieved between the substrate, the thermal conductive insulating layer and the conductive layer. [Embodiment] * The present invention is directed to the above-described objects, the technical means and the technical means thereof, and the preferred embodiments are described as follows: - Please refer to the figures _ to 3 The invention is a metal or ceramic wire 2, the method is mainly based on the thermal conductive insulating layer 2 and the outer cladding layer 3, and the processing steps are as follows: Step ―, the substrate 1 is metal or ceramic enamel The substrate 1 may be made of materials such as Ming (8), copper 6 200811300 (Cu), alumina (Al 2 〇 3), and zirconia (Zr 〇 2); Step 2: plating a surface of the substrate 1 with a thermal conductive layer 2, the thermal conductive insulation layer 2 r main components are alumina (AI2O2), aluminum nitride (A1N), oxidized chopping (Si〇D, yttrium oxide • (10) (6) and tungsten oxide (W〇2), chromium nitride ((^ ), titanium nitride (1^), nickel nitride vanadium (NiVN) and other components, each of which can be implemented as a thermally conductive insulating layer 2, each of which can be plated by PVD batch-level continuous surface treatment technology Covering the surface of the substrate 1 to achieve high thermal conductivity and insulation effect; • Step 3, plating on the thermal conductive insulation layer 2 with PVD batch-level continuous surface treatment technology Layer 3, the conductive layer 3 comprises chromium (Cr), aluminum (41), titanium (1), nickel (1), copper (Cu), each of which can be implemented as a conductive layer 3, Step 4: The conductive layer 3 having a conductive function is treated by a plating technique, and the plating layer 4 is a copper (Cu) plating layer or another metal plating layer, and the plating layer 4 is bonded to the V electrical layer 3 Above, according to the design requirements, increase to the required thickness to achieve the best conduction power. • In addition, in step 3, the thermal insulation layer 2 contains components containing thermally conductive insulating oxides and nitrides that can be PVD-plated. , carbides, etc. can be composited in the thermal insulation layer 2. _ Containing this derivative, nitrogen recording, carbide thermal insulation - coating 2 'can be good and stable with shouting or metal material BRIEF DESCRIPTION OF THE DRAWINGS The first figure shows a schematic cross-sectional view of a metal substrate structure of the present invention. The second figure shows a schematic diagram of the layered structure of the present invention. 7 200811300 The third figure shows a flow chart of the manufacturing steps of the present invention. [Main component symbol description] 1. ···.·· ···················································· Electric forging layer

Claims (1)

200811300 十、申請專利範圍: 1、-種金屬或陶錄材金屬化處理方法,其處理步驟包含有: Γ 步驟一、金屬或陶瓷基材; • 步驟二、將基材表面以Ρ職次級連續表面處理,形成導熱絕 緣層; ' 步驟三、於導熱絕緣層上以批次級連續絲處理技術鍍覆 金屬導電層; ⑩ 步驟四、於導電層表面以電鍍方式,鍍著金屬電鑛層,該電 鏡層結合於導電層上,增厚導電層至所需厚度。 . 2、如申料觀賴述之基材金屬化鍍膜處理方法, 其中基材可為鋁(Α1)、銅(Cu)、氧化鋁(a12〇s)、氧化锆(Zr〇2)等材 質。 3、 如申請專利範圍第丨項所述之基材金屬化鍍膜處理方法, 其中$熱、%緣層2可為氧化铭(Αΐ2〇3)、氮化銘(Ain)、氧化梦 • (Si〇2)、氧化铪(削2)、氧化鶴⑽)、氧化锆(Zr02)、氮化錯(挪)、 氮化鉻(CrN)、氧化鈦(Ti〇2)、氮化鈦(彻)、氮化鎳飢⑽领)、及 ,其他可以PVD方式形成之導熱絕緣氮化物、氧化物、碳化物成分均 •可個別或兩種或兩種以上混合成為導熱絕緣層。 4、 如申請專利範圍第1項所述之基材金屬化鍍膜處理方法, 其中该導電層3可為絡(Cr)、銘(A1)、鈦(Ti)、銅(Cu)、錯(Zr)及 其他可以PVD方式形成之導電金屬成分,均可個別或兩種或兩種 以上混合成為導電層。 9 200811300 5、如申請專利範圍第1項所述之金屬基材金屬化鍍膜處理方 法,其中導電層與電鍍層結合厚度可依設計不同而靈活變動。 6、如申請專利範圍第1項所述之金屬基材金屬化鍍膜處理方 法,其中該電鍍層為銅(Cu)電鍍層或其他金屬電鍍層。200811300 X. Patent application scope: 1. Metallization treatment method for metal or ceramic materials, the processing steps include: Γ Step one, metal or ceramic substrate; • Step two, the surface of the substrate is used as a secondary continuous surface Processing, forming a thermally conductive insulating layer; 'Step 3, plating the metal conductive layer on the thermally conductive insulating layer by batch-level continuous wire processing technology; 10 Step 4, plating the metal electric ore layer on the surface of the conductive layer by electroplating, The electron mirror layer is bonded to the conductive layer to thicken the conductive layer to a desired thickness. 2. The substrate metallization coating treatment method according to the application of the material, wherein the substrate may be aluminum (Α1), copper (Cu), alumina (a12〇s), zirconia (Zr〇2) and the like. . 3. The method for processing a substrate metallization coating according to the scope of the patent application, wherein the heat and % layer 2 can be oxidized (Αΐ2〇3), nitrided (Ain), oxidized dream• (Si) 〇2), yttrium oxide (cut 2), oxidized crane (10)), zirconia (Zr02), nitriding (nothing), chromium nitride (CrN), titanium oxide (Ti〇2), titanium nitride (complete) , nickel nitride hunger (10) collar, and other thermally conductive insulating nitrides, oxides, and carbide components that can be formed by PVD. They can be mixed individually or in combination of two or more to form a thermally conductive insulating layer. 4. The substrate metallization coating treatment method according to claim 1, wherein the conductive layer 3 can be complex (Cr), Ming (A1), titanium (Ti), copper (Cu), and wrong (Zr). And other conductive metal components which can be formed by PVD, may be mixed individually or in two or more to form a conductive layer. 9 200811300 5. The metal substrate metallization coating method according to claim 1, wherein the thickness of the conductive layer and the plating layer can be flexibly changed according to the design. 6. The metal substrate metallization coating method according to claim 1, wherein the plating layer is a copper (Cu) plating layer or another metal plating layer.
TW95130377A 2006-08-18 2006-08-18 A treatment method of metalization of metal or ceramic substrate TW200811300A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110643939A (en) * 2018-06-27 2020-01-03 蒸汽技术公司 Copper-based antibacterial PVD coating
CN111819303A (en) * 2018-02-19 2020-10-23 应用材料公司 PVD titania formation using sputter etching to stop crystallization in thick films

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111819303A (en) * 2018-02-19 2020-10-23 应用材料公司 PVD titania formation using sputter etching to stop crystallization in thick films
US11008647B2 (en) 2018-02-19 2021-05-18 Applied Materials, Inc. PVD titanium dioxide formation using sputter etch to halt onset of crystalinity in thick films
TWI796438B (en) * 2018-02-19 2023-03-21 美商應用材料股份有限公司 Pvd titanium dioxide formation using sputter etch to halt onset of crystalinity in thick films
CN111819303B (en) * 2018-02-19 2023-12-08 应用材料公司 Using sputter etching to halt PVD titanium dioxide formation where crystallization occurs in thick films
TWI845907B (en) * 2018-02-19 2024-06-21 美商應用材料股份有限公司 Pvd titanium dioxide formation using sputter etch to halt onset of crystalinity in thick films
CN110643939A (en) * 2018-06-27 2020-01-03 蒸汽技术公司 Copper-based antibacterial PVD coating

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