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TW200818501A - Metal layer inducing strain in silicon - Google Patents

Metal layer inducing strain in silicon Download PDF

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Publication number
TW200818501A
TW200818501A TW096123859A TW96123859A TW200818501A TW 200818501 A TW200818501 A TW 200818501A TW 096123859 A TW096123859 A TW 096123859A TW 96123859 A TW96123859 A TW 96123859A TW 200818501 A TW200818501 A TW 200818501A
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Taiwan
Prior art keywords
strain
channel region
transistor
substrate
layer
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TW096123859A
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Chinese (zh)
Inventor
Reza Arghavani
Jianming Fu
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Applied Materials Inc
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Priority claimed from US11/490,884 external-priority patent/US20080061285A1/en
Application filed by Applied Materials Inc filed Critical Applied Materials Inc
Publication of TW200818501A publication Critical patent/TW200818501A/en

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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D64/00Electrodes of devices having potential barriers
    • H10D64/01Manufacture or treatment
    • H10D64/021Manufacture or treatment using multiple gate spacer layers, e.g. bilayered sidewall spacers
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/0641Nitrides
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/01Manufacture or treatment
    • H10D30/021Manufacture or treatment of FETs having insulated gates [IGFET]
    • H10D30/0223Manufacture or treatment of FETs having insulated gates [IGFET] having source and drain regions or source and drain extensions self-aligned to sides of the gate
    • H10D30/0227Manufacture or treatment of FETs having insulated gates [IGFET] having source and drain regions or source and drain extensions self-aligned to sides of the gate having both lightly-doped source and drain extensions and source and drain regions self-aligned to the sides of the gate, e.g. lightly-doped drain [LDD] MOSFET or double-diffused drain [DDD] MOSFET
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/60Insulated-gate field-effect transistors [IGFET]
    • H10D30/601Insulated-gate field-effect transistors [IGFET] having lightly-doped drain or source extensions, e.g. LDD IGFETs or DDD IGFETs 
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/60Insulated-gate field-effect transistors [IGFET]
    • H10D30/791Arrangements for exerting mechanical stress on the crystal lattice of the channel regions
    • H10D30/792Arrangements for exerting mechanical stress on the crystal lattice of the channel regions comprising applied insulating layers, e.g. stress liners
    • H10P14/44
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/60Insulated-gate field-effect transistors [IGFET]
    • H10D30/69IGFETs having charge trapping gate insulators, e.g. MNOS transistors
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D64/00Electrodes of devices having potential barriers
    • H10D64/01Manufacture or treatment
    • H10D64/017Manufacture or treatment using dummy gates in processes wherein at least parts of the final gates are self-aligned to the dummy gates, i.e. replacement gate processes

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Insulated Gate Type Field-Effect Transistor (AREA)
  • Electrodes Of Semiconductors (AREA)
  • Physical Vapour Deposition (AREA)
  • Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)

Abstract

A metal layer (62), especially a metal compound, induces strain into a gate channel (16) of a MOS transistor (60). Compressive strain of over 4GPa is available from sputter deposited TiN. The amount of strain can be controlled at least up to 11GPa, for example, by wafer biasing. The compressive strain may induce compressive strain in a PMOS channel when deposited around the channel and induce tensile strain in an NMOS channel when deposited over the channel.

Description

200818501 九、發明說明: 【發明所屬之技術領域】 本發明係有關於半導體元件及其形成。更詳而言之, 本各明係有關於具有應變矽(strained silicon)之半導體元 件以及藉由濺鍍(sputter)沉積一金屬層以將矽予以應變之 【先前技術】 石夕積體電路之持續進展可由摩爾定律所描述,而摩爾 定律也指出了 ,於每十八個月,最先進之積體電路晶片中 之元件數目將倍增。現今,一個先進之積體電路包含數十 億個電晶體。 積體化之持續進展主要地係藉由使積體電路所具有之 各別主動元件之尺寸大小予以縮減而完成。光微影術 (photolithography )之進步係部分地促進了此進展,但其 他方面,例如,較淺與更高度地摻雜之接面,以及低介電 常數亦為所須。現今此時,65奈米(nm)元件已進入量產, 而45奈米元件則仍在發展中。尺寸大小之縮減的一優點 為’切換電晶體之操作速度隨尺寸大小之減少而增加。於 積體化中持續此種趨勢為所須的。然而,此些進展將愈行 困難,且可能需要更多基礎性之改變。 近期係引入使用具有應變矽的元件。該應變促使較快 電晶體之製造而無須於實際尺寸大小上做一等量之減少。 已知相較於未應變石夕’壓縮應變發(C()inpressively strained silicon)具有一較高之電洞遷移率(hole mobility)。另一方 面,相較於未應變處理之矽,拉伸應變矽(tensile strained 5 200818501200818501 IX. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to semiconductor elements and their formation. More specifically, the present invention relates to a semiconductor element having strained silicon and a metal layer deposited by sputtering to strain the crucible. [Prior Art] Continued progress can be described by Moore's Law, and Moore's Law also points out that the number of components in the most advanced integrated circuit chips will double every 18 months. Today, an advanced integrated circuit contains billions of transistors. The continued progress of the integration is mainly accomplished by reducing the size of the individual active components of the integrated circuit. Advances in photolithography have partially contributed to this progress, but other aspects, such as shallower and more highly doped junctions, and low dielectric constants are also required. At this time, 65 nanometer (nm) components have entered mass production, while 45 nanometer components are still in development. One advantage of the reduction in size is that the operating speed of the switching transistor increases as the size decreases. It is necessary to continue this trend in the integration. However, such progress will be increasingly difficult and may require more fundamental changes. Recently, the use of components with strain enthalpy has been introduced. This strain promotes the manufacture of faster transistors without the need to achieve an equivalent reduction in actual size. It is known to have a higher hole mobility than unstrained strained silicon (C(). On the other hand, the tensile strain 矽 (tensile strained 5 200818501) compared to the unstrained treatment

silicon)具有一較高之電子遷移率。部分用於導入應變之習 知技術係包含了一矽層以及一矽鍺(SiGe)層之磊晶生長 (epitaxial growth)。由於二種材料之不同的晶格常數,因 此之後所生長之層只要其厚度並非太大,則其會生長而具 有内建之應力。於一技術中,矽鍺會在凹設於矽之源極以 及汲極區域重新生長,並將應變傳至中間的矽閘極通道。 最近發展之一些技術,包含介電層(例如氮化矽或二氧化矽) 之化學氣相沉積(CVD; chemical vapor deposition),其係 在氮化物或氧化物為經應變之條件下而沉積在矽上方。於 該介電層中之應力可至少部分地轉移至矽,藉以影響石夕中 之遷移率。 第1圖所示為一剖面視圖,其為一金氧半導體(M〇§; metal-oxide-semiconductor)電晶體1 〇之一例,亦可稱之為 金氧半場效電晶體(M0SFET ; MOS field effect transistor)。由於本發明之第一實施例係實施於一 p型金 氧半導體(PM0S)電晶體,適於pm〇S之摻雜種類將予以 描述。然而,此描述亦可適用於η型金氧半導體(nm〇s) 電晶體,只要將其摻雜種類做一簡當相反轉變即可。一 PM0S電晶體10形成於一石夕基材12之表面上,石夕基材u 在其表面具有藉由離子佈植而形成之一輕摻雜η型井 (lightly doped «-type well)。PM0S 電晶體 10 係由一淺溝 槽隔離(STI ; shallow trench isolation) 14 所包圍,該淺黃 槽隔離1 4係由 >儿積於石夕基材1 2之一溝槽中的氧化石夕所形 成。淺溝槽隔離1 4圍繞一或一特定數量之電晶體,以使其 與其他之電晶體電氣隔離。電晶體閘極藉由一問極通、首 (G) 1 6形成,該閘極通道(G) 1 6形成於矽基材1? I Z ·Ν 型井 200818501 的表面内。一薄閘極氧化物1 8係沉積於通道1 6之上,或 是自通道1 6之矽被氧化後所形成,而一重摻雜之多晶矽閘 極電極2 0則沉積並界定於閘極氧化物丨8之上方。多晶矽 閘極電極20之侧邊可被氧化而形成一襯墊(liner)22。一氮 化物間隙物(spacer)24及其延伸腳係圍繞閘極電極2〇而形 成。此結構可調整成一快閃記憶體,其係藉由在閘極電極 20中包含一氧化物-氮化物·氧化物(〇N〇)穿隧式之儲存胞 而形成。 f' 在襯塾22及間隙物24形成之前,該閘極電極可作 用為一佈植遮罩,其係以一中間角度(medium angular)將p 型摻質予以摻雜佈植至較深之源極與汲極(s與D)34、36 的淺延伸部分3 0、3 2,其中係利用閘極間隙物2 4作為一 遮罩,並藉由一較高劑量之P型摻質的離子佈植而於稍後 形成較冰之源極與沒極。鎳化碎歐姆接觸(〇hmic contact)40、42、44係形成於多晶矽閘極電極2〇以及矽源 極與汲極34、36之上,其係藉由沉積一鎳層以及退火該鎳 層以形成一矽化物(下方為矽),而用以提供介於石夕與稍後 , 所形成之垂直金屬化(metallizations)之間的歐姆接觸。 I 一蝕刻終止層50以及一前金屬介質層52為保角地 (conformally)予以沉積(一般是以化學氣相沉積法)而形 成於閘極電極20以及基材1 2之平坦區域之上。一般地, 餘刻終止層係由組成成分為SisN4之氮化矽所組成,而前 金屬介質層52則是由二氧化矽(Si〇2,通常稱之為氧化石夕) 所組成’或於先進之元件中,一低介電常數之介電質係由 摻雜之氧化矽所形成。於形成孔洞之蝕刻時,先穿過前金 屬介質層52,接著,再穿過蝕刻終止層50,繼而,以一金 7Silicon) has a higher electron mobility. Part of the conventional technique for introducing strain involves a layer of germanium and an epitaxial growth of a layer of germanium (SiGe). Due to the different lattice constants of the two materials, the layer grown thereafter will grow with built-in stress as long as its thickness is not too large. In one technique, the crucible re-grows in the source and the drain region of the recess, and transmits the strain to the middle gate channel. Recently developed technologies include chemical vapor deposition (CVD) of a dielectric layer (such as tantalum nitride or hafnium oxide) deposited under conditions in which nitrides or oxides are strained.矽 Above. The stress in the dielectric layer can be at least partially transferred to the crucible to affect the mobility of the Shi Xizhong. Figure 1 is a cross-sectional view showing an example of a metal-oxide-semiconductor transistor, which may also be called a metal oxide half field effect transistor (M0SFET; MOS field). Effect transistor). Since the first embodiment of the present invention is implemented in a p-type metal oxide semiconductor (PMOS) transistor, the doping type suitable for pm 〇 S will be described. However, this description can also be applied to an n-type MOS transistor, as long as the doping type is simply reversed. A PM0S transistor 10 is formed on the surface of a stone substrate 12 having a lightly doped «-type well formed by ion implantation on its surface. The PM0S transistor 10 is surrounded by a shallow trench isolation (STI) 14 which is an oxide stone accumulated in a trench of the stone substrate 1 2 by the light yellow trench isolation. Formed in the evening. Shallow trench isolation 14 surrounds one or a particular number of transistors to electrically isolate them from other transistors. The gate of the transistor is formed by a gate, a first (G) 16 formed in the surface of the substrate 1? I Z · well 200818501. A thin gate oxide 18 is deposited on the channel 16 or formed after the channel 16 is oxidized, and a heavily doped polysilicon gate electrode 20 is deposited and defined in the gate oxide. Above the object 8. The sides of the polysilicon gate electrode 20 can be oxidized to form a liner 22. A nitride spacer 24 and its extension legs are formed around the gate electrode 2''. The structure can be adjusted to a flash memory formed by including an oxide-nitride oxide (〇N〇) tunneling memory cell in the gate electrode 20. f' Before the lining 22 and the spacer 24 are formed, the gate electrode can function as an implant mask, which is doped and implanted at a mid-degree angle to the deeper The shallow extensions 30, 3 2 of the source and drain electrodes (s and D) 34, 36, wherein the gate spacers 24 are used as a mask, and by a higher dose of P-type dopant Ion implantation and later forming a source of ice and no pole. Nickel ohmic contacts 40, 42, 44 are formed on the polysilicon gate electrode 2 and the germanium source and drain electrodes 34, 36 by depositing a nickel layer and annealing the nickel layer. To form a germanide (underneath), to provide an ohmic contact between the stone and the later formed metallizations. An etch stop layer 50 and a front metal dielectric layer 52 are deposited conformally (typically by chemical vapor deposition) over the gate electrode 20 and the planar region of the substrate 12. Generally, the residual termination layer is composed of tantalum nitride having a composition of SisN4, and the front metal dielectric layer 52 is composed of cerium oxide (Si〇2, commonly referred to as oxidized oxide eve). In advanced components, a dielectric of low dielectric constant is formed by doped yttrium oxide. During the etching of the holes, the front metal dielectric layer 52 is first passed through, and then through the etch stop layer 50, and then, a gold 7

200818501 屬化法(例如,鎢)來填充此些孔洞,以形成無 (uη 1 an d e d)之源極與沒極接觸5 4、5 6、以及一閘極接觸 近來,藉由一些技術而將應變引入如第1圖中所 結構。於一技術中,源極3 4與汲極3 6可形成於矽鍺 之區域,其中矽鍺合金係磊晶地重新生長於矽基材1 2 刻區域。由矽鍺所引入之壓縮應變可傳至通道1 6,因 道1 6亦產生應變,其中矽鍺與具較小晶格間隔之矽為 (pseudomorphic)。於描述於Arghavani等人之美國專 開號2005/025 5 667的另一技術中,於淺溝槽隔離14 氧化物以拉伸應變型式生長,而將拉伸應變傳入MO S 體10中。 於Arghavani等人在20〇5年1月15號申請之y 利申請案號11/〇37,684並公開為美國專利公 2006/0 1 603 1 4中所描述之另一技術中,於化學氣相 件下,氮化物蝕刻終止層5 〇係生長而產生出應變。; 氧化物襯墊22或自前金屬介質層52來誘導出應變 石夕化物歐姆接觸層4〇、42、44可生長而誘導出應變 雖J這二用於誘導出應變的技術可有效地增加] 遷移率,並提切積體電路之速度,但是現今之技4 製造一最大約為3GPa應力炉六, χ ^ 應力之此力,然而,當應力1 一相鄰之矽層時,蜂旛七 傳送至下方…力:二層級通常會大幅度地減: 積、以及該結構:幾付里:„該應力誘導, 苒之4何。對於先進之 閘極間距離之減少,备几此t ^ 、體電路而θ 夠。未來之氧化物誘導應變層變) 夠未來之積體電路世代係 尺巧之應力與應變 著點 5 8 〇 示之 合金 之餘 而通 假晶 利公 中之 電晶 國專 開號 積條 可自 且, 子之 具有 送至 0 之面 隨著 不足 |級。 8 200818501 【發明内容】 藉由鄰近該電晶體所沉積之一金屬化合物的一金屬 層,則應變可誘導入一矽Μ 0 S電晶體或其他之矽元件中。 金屬化合物可為一金屬氮化物。藉由電漿反應性濺鍍 而使生長之氮化鈦具有4GPa且更大之壓縮應變。 例如為氮化鈦之壓縮應變金屬層當其沉積於該通道周 圍而非沉積於該通道上方時,其可誘導壓縮應變至一 MOS 閘極通道中,而此對於一 PMOS電晶體而言係為有利的。 f、 可選擇地,當氮化鈦沉積於通道上時,其會誘導拉伸應變 至一 MOS閘極中,而此對於一 NMOS電晶體係為有利的。 【實施方式】 根據本發明之一實施態樣,金屬層係沉積而鄰近一矽 通道,藉以傳送一高並可控制層級之應變至該通道。該應 變可經選擇以增加於半導體通道中之載子遷移率。金屬層 之一實例可為氮化鈦(TiN),該氮化鈦藉由亦可稱為物理氣 相沉積(P V D)之反應性藏鍵而沉積。錢鐘條件可經控制以 傳送一所需之應變層級至該通道。高達-12GPa之應變層級 可於反應性濺鍍氮化鈦中而重複地被察覺,而此應變層級 係遠超過藉由化學氣相沉積所生成之氧化矽及氮化矽之應 變誘導層的目前可得之-3 GP a。 根據一應變MOS電晶體60之一實施例,如第2圖中 之剖面視圖所示,一金屬壓縮層6 2係形成於閘極電極2 0 周圍以提供壓縮應變。藉由此幾何配置,金屬壓縮層 62 之壓縮應變將致使下面之矽產生拉伸應變,此將繼而推動 抵靠閘極通道16之周圍的矽,因而誘導出通道中所期望之 9 200818501 壓縮應變。壓縮應變將增加於半導體矽通道l6中之電洞之 遷移率,且因而增加p型金氧半導艘(pM〇s)電晶體之速 度。 壓縮層62係例如由氮化鈦形成,而氮化鈦可反應性地 濺鍍而具有所期望之壓縮應t。最初之結果顯示氮化鈦可 生長而具有高達lOGPa之應力’其遠超過目前可得自氧化 石夕及氣化石夕之應變誘導層@ 3GPa。^化欽為一熟知之村 料’其另可用在形成貫穿孔中之阻障層( — Η”,而 該貫穿孔穿過積體電路中之上方金屬層的層間介質層 (inteMevei dielectric layers)。當藉由反應性进鍍予以形 成時,該氮化鈦具應變特性係為已知#,且通常該應變被 視為一負面效應,此乃因為其降低了可靠性。200818501 The genus method (for example, tungsten) is used to fill the holes to form a source of no (uη 1 an ded) contact with the immersive contact 5 4, 5 6 , and a gate contact, with some techniques The strain is introduced as shown in Figure 1. In one technique, the source 34 and the drain 3 6 may be formed in the region of the crucible, wherein the niobium alloy is epitaxially re-grown in the engraved region of the crucible substrate. The compressive strain introduced by the crucible can be transmitted to the channel 16, and the strain is also generated by the channel 16, wherein the crucible is separated from the smaller lattice spacing (pseudomorphic). In another technique described in U.S. Patent No. 2005/025 5 667 to Arghavani et al., the shallow trench isolation 14 oxide is grown in a tensile strain pattern and the tensile strain is introduced into the MO S body 10. In another technique described in U.S. Patent Publication No. 2006/0 1 603 1 4, the disclosure of which is incorporated herein by reference. Under the condition, the nitride etch stop layer 5 grows and generates strain. The oxide liner 22 or the precursor metal dielectric layer 52 induces the strained oxime ohmic contact layer 4〇, 42, 44 to grow to induce strain, although the technique for inducing strain can be effectively increased] Mobility, and the speed of the integrated circuit is cut, but today's technology 4 produces a maximum of about 3GPa stress furnace, χ ^ stress of this force, however, when stress 1 is adjacent to the layer, bee sting Transfer to the bottom... Force: The second level will usually be greatly reduced: the product, and the structure: a few payments: „This stress induces, what is the 4th. For the reduction of the distance between the advanced gates, prepare a few t ^ The body circuit and θ are sufficient. The future oxide-induced strain layer change) is enough for the future generation of the circuit generation system to be the stress and strain point 5 8 〇 shows the alloy and passes the pseudo-crystal Li Gongzhong The special opening strip can be self-contained, and the sub-segment has a surface that is sent to 0 with a shortage of |. 8 200818501 [Invention] The strain can be induced by a metal layer of a metal compound deposited adjacent to the transistor. Into a 0 S transistor or other The metal compound may be a metal nitride. The titanium nitride grown by plasma reactive sputtering has a compressive strain of 4 GPa and greater. For example, a compressive strain metal layer of titanium nitride is When deposited around the channel rather than deposited over the channel, it induces compressive strain into a MOS gate channel, which is advantageous for a PMOS transistor. f. Alternatively, when nitriding When titanium is deposited on the channel, it induces tensile strain into a MOS gate, which is advantageous for an NMOS electro-crystalline system. [Embodiment] According to an embodiment of the present invention, the metal layer is deposited. Adjacent to a channel, a high and controllable level of strain is transmitted to the channel. The strain can be selected to increase carrier mobility in the semiconductor channel. An example of a metal layer can be titanium nitride (TiN), The titanium nitride is deposited by reactive bonds, also known as physical vapor deposition (PVD). The clock conditions can be controlled to deliver a desired strain level to the channel. The strain level can be up to -12 GPa. Reactive It is repeatedly observed in the sputtered titanium nitride, and the strain level is far beyond the currently available -3 GP a of the strain-inducing layer of yttrium oxide and tantalum nitride formed by chemical vapor deposition. An embodiment of the strained MOS transistor 60, as shown in the cross-sectional view of Fig. 2, a metal compression layer 62 is formed around the gate electrode 20 to provide compressive strain. By virtue of this geometric configuration, the metal compression layer The compressive strain of 62 will cause the underlying helium to produce tensile strain, which in turn will push against the imperfections around the gate channel 16, thereby inducing the desired 9 200818501 compressive strain in the channel. The compressive strain will increase in the semiconductor channel. The mobility of the holes in l6, and thus the speed of the p-type MOS transistor. The compression layer 62 is formed, for example, of titanium nitride, and the titanium nitride is reactively sputtered to have a desired compression ratio t. The initial results show that titanium nitride can grow and have a stress of up to 10 GPa, which far exceeds the strain-inducing layer @ 3GPa currently available from oxidized stone and gasification. ^化钦 is a well-known village material. It can also be used to form a barrier layer (-Η) in the through-hole, and the through-hole passes through the inteMevei dielectric layers of the upper metal layer in the integrated circuit. When formed by reactive plating, the titanium nitride has a strain characteristic of known #, and usually the strain is regarded as a negative effect because it lowers reliability.

f Kf K

於所述之實施例中,金屬壓縮層62係沉積於氮化物蚀 刻終止層50之上方。其他之結構亦為可能。舉例而 化物姓刻終止層50可由氧化石夕層所取代,而該氧…: 有少許或並無任何應變,但可對下方之導電特徵結構:: -絕緣層。然而’ ®中之實施例具有之優點為:供 生長而具有-適當量之拉伸應變,並延伸而鄰近可 電晶體之二側’以提供所期望之拉伸應變i J 體。金屬壓縮層62繼而生長於氮化物層5〇之上晶 PMOS電晶體之區域),而此生長係在產生—較大 在 以過度補償於PM0S電晶體上之氮化物的拉伸應力之:力 下進行。因而’如期望的,PM〇s電晶體處於壓縮應變: 下,而NMOS電晶體則處於拉伸應變之下。可選擇茭之 ^方之則金屬”質層52可沉積而具一適當量之 變,而此拉伸應變可藉由金屬魔縮層62之高壓縮廡 應 、I而過 10 200818501 度補償。 不同於氧化矽或氮化矽,氮化鈦具有一適當高之導電 性’因而被視為一金屬而不視為一介電質。因此,氮化鈦 壓縮層62須被圖樣化以避開金屬接觸54、56、58而不會 使填充金屬之接觸被短路。習知技術之矽化物接觸的應變 誘導層避免了此短路問題,此乃由於其位於預計之導電路 徑上’且已與其他接觸隔離。氮化鈦之圖樣化蝕刻可藉由 為銘姓刻所發展之技術來進行,舉例而言,係利用一基於 氯之電漿。於美國專利公開號2004/0074869中,Wang等 人描述了 一個積體化之銘餘刻程序。 本發明之另一實施例係繪示於第3圖之剖面視圖中, 其係基於Li等人之美國專利公開號2005/0282329以及 Kudo等人之美國專利公開號2004/0 1 42546中所描述之替 代性閘極(replacement gate)之形態。幾何效應使得壓縮之 氮化鈦在下方之閘極通道中誘導出拉伸應變,此對於 NM0S電晶體是特別地有價值的,而NM0S電晶體可與先 前所述廣為應用於先進之邏輯電路的傳統CMOS積體電路 中之PMOS電晶體配對。 一替代性閘極Μ Ο S電晶體可以類似於應用在第1圖中 之多晶矽閘極電晶體之初期步驟而製造。然而,多晶矽閘 極電極20為將會被移除之一犧牲電極(sacrificial electrode)。如第3圖中所示之替代性閘極電晶體7〇的剖 面視圖’在間隙物2 4形成於多晶石夕閘極電極周圍、已進行 源極與汲極之佈植、以及源極與汲極歐姆接觸4 2、4 4被矽 化之後,一介質層7 2係沉積於表面之上,並且例如藉由化 學機械研磨法而將該間隙物24以及犧牲之多晶石夕閘極電 11 200818501 極的頂端予以平坦化。該介質層7 2可包含蝕刻終止層,但 主要地由一低介電常數介電質所組成,以作為前金屬介電 質。多晶矽繼而自間隙物24之間予以移除。於形成該犧牲 閘極電極之前或是在其移除之後,一薄之高介電常數的閘 極介質層74則形成於孔之底面。示範性之高介電常數介電 質可為氧化铪(HfO)、氧化锆(ZrO)、以及三氧化二鋁 (Al203)。閘極電極層76沉積於閘極介質層74之上。而閘 極電極層76可以由一金屬或金屬合金形成,其係經選取以 ζ-, 對於閘極通道1 6之摻雜型式而言具有適當之功函數,舉例 而言,對NM0S電晶體而言為矽化鈦(TiSi),或對PM0S 電晶體而言為鋁化鈦(TiAl)。 根據本發明之此實施例,一壓縮應變金屬層7 8係形成 於閘極電極層76之上。如上所述,氮化鈦為壓縮誘導金屬 層78之較佳材料。層74、76、78之一或多者可保角地沉 積於孔洞之側壁、以及可能位於間隙物24外側之上,其係 取決於沉積程序以及此程序之進行時點。例如為鋁之金屬 化金屬,其係經由物理氣相沉積法(PVD)來沉積,以填充 以及過填充(overfill)該孔洞之剩餘部分。化學機械研磨法 i (CMP)去除孔洞外側之金屬化金屬,而留下一閘極接觸金 屬8 0。進一步之處理程序將形成於第2圖中之源極以及汲 極接觸54、56。然而,於其他之程序中,介質層72將予 以移除且以另外一者來取代之。 氮化鈦之壓縮應變層7 8位於矽閘極通道1 6之上,且 導致閘極通道1 6於反應中而具有拉伸應變,此係為NM0S 電晶體所期望者。因此,相同組成之應變誘導層以及具有 相同型式之應變,其係取決於與應變誘導層和通道具關聯 12 200818501 性之幾何形態而於矽通道中誘導出拉伸Λ 丄 刀或壓縮力。 第2圖與第3圖中之電晶體60、7〇π、 J分別應用於積體 電路之PMOS與NMOS電晶體,或替々 、 Λ ^ η性閘極電晶體70 可用於NMOS電晶體,以及其他方式可目,丨In the illustrated embodiment, a metal compression layer 62 is deposited over the nitride etch stop layer 50. Other structures are also possible. For example, the etch stop layer 50 may be replaced by a oxidized stone layer, and the oxygen... has little or no strain, but may have a conductive feature underneath: - an insulating layer. However, the embodiment of ' has the advantage of having a suitable amount of tensile strain for growth and extending adjacent to the two sides of the electromagnet to provide the desired tensile strain iJ body. The metal compression layer 62 is then grown in the region of the nitride layer 5 on the nitride PMOS transistor, and this growth is produced by the tensile stress that is greater than the nitride that is overcompensated on the PMOS transistor: force Go on. Thus, as desired, the PM〇s transistor is under compressive strain: and the NMOS transistor is under tensile strain. Alternatively, the metal layer 52 can be deposited with a suitable amount of variation, and the tensile strain can be compensated by the high compression of the metal magic layer 62, and by 10 200818501 degrees. Unlike tantalum oxide or tantalum nitride, titanium nitride has a suitably high conductivity' and is therefore considered a metal and is not considered a dielectric. Therefore, the titanium nitride compression layer 62 must be patterned to avoid The metal contacts 54, 56, 58 do not short the contact of the filler metal. The strain-inducing layer of the germanide contact of the prior art avoids this short circuit problem because it is located on the expected conductive path' and has been Contact isolation. Patterned etching of titanium nitride can be performed by techniques developed for the name of the name, for example, using a chlorine-based plasma. In US Patent Publication No. 2004/0074869, Wang et al. A further embodiment of the present invention is described in the cross-sectional view of Fig. 3, which is based on U.S. Patent Publication No. 2005/0282329 to Li et al. and Kudo et al. U.S. Patent Publication No. 2004/0 1 42546 The shape of the alternative replacement gate is described. The geometric effect causes the compressed titanium nitride to induce tensile strain in the underlying gate channel, which is particularly valuable for NM0S transistors, while NM0S transistors It can be paired with a PMOS transistor in a conventional CMOS integrated circuit that is widely used in advanced logic circuits as described above. An alternative gate Μ 电 S transistor can be similar to the polysilicon gate electrode used in FIG. The initial step of the crystal is fabricated. However, the polysilicon gate electrode 20 is one of the sacrificial electrodes to be removed. A cross-sectional view of the alternative gate transistor 7A as shown in Fig. 3 The spacers 24 are formed around the polycrystalline silicon gate electrode, the source and drain electrodes have been implanted, and the source and drain ohmic contacts 4, 4 4 are deuterated, and a dielectric layer 7 2 is deposited. Above the surface, and planarizing the spacer 24 and the top end of the sacrificial polycrystalline silicon gate 11 200818501 pole, for example by chemical mechanical polishing. The dielectric layer 72 may comprise an etch stop layer, but main Consisting of a low dielectric constant dielectric as a front metal dielectric. The polysilicon is then removed from between the spacers 24. Before the formation of the sacrificial gate electrode or after its removal, a thin A high dielectric constant gate dielectric layer 74 is formed on the bottom surface of the hole. Exemplary high dielectric constant dielectrics may be hafnium oxide (HfO), zirconium oxide (ZrO), and aluminum oxide (Al203). The gate electrode layer 76 is deposited over the gate dielectric layer 74. The gate electrode layer 76 can be formed of a metal or metal alloy selected to be ζ-, for the doping pattern of the gate channel 16. It has an appropriate work function, for example, titanium hydride (TiSi) for NMOS transistors or titanium aluminide (TiAl) for PMOS transistors. In accordance with this embodiment of the invention, a compressively strained metal layer 78 is formed over the gate electrode layer 76. As described above, titanium nitride is a preferred material for the compression inducing metal layer 78. One or more of the layers 74, 76, 78 may be preserved in a conformal manner on the sidewall of the aperture and possibly on the outside of the spacer 24, depending on the deposition procedure and the point in time at which the procedure is performed. For example, a metallized metal of aluminum is deposited via physical vapor deposition (PVD) to fill and overfill the remainder of the hole. The chemical mechanical polishing method i (CMP) removes the metallized metal outside the hole leaving a gate contact with the metal 80. Further processing procedures will be formed in the source and anode contacts 54, 56 in Figure 2. However, in other procedures, the dielectric layer 72 will be removed and replaced by another one. The compressive strain layer 78 of titanium nitride is located above the gate channel 16 and causes the gate channel 16 to have tensile strain in the reaction, which is desirable for NM0S transistors. Thus, the strain-inducing layer of the same composition and the strain of the same type are dependent on the geometry of the strain-inducing layer and the channel to induce a tensile 丄 或 knife or compressive force in the 矽 channel. The transistors 60, 7 〇 π, and J in FIGS. 2 and 3 are respectively applied to the PMOS and NMOS transistors of the integrated circuit, or the NMOS and NMOS gate transistors 70 can be used for the NMOS transistor. And other ways to see, 丨

~用於提供PMOS 電晶體中所期望之壓縮應變。再者,應轡 又誘導金屬層可與 其他提供相同或相反之應變的方法以及站 、Q構結合,例如於 習知技術部分所提及者。 習知技術之應變誘導氮化物及氧化鉍a 物層,其典型地係~ Used to provide the desired compressive strain in a PMOS transistor. Furthermore, the inducing metal layer can be combined with other methods of providing the same or opposite strain as well as station, Q, such as those mentioned in the prior art section. Strain-induced nitride and yttrium oxide layer of conventional techniques, typically

藉由化學氣相沉積法來沉積。本發明之 ^ ^愿變誘導金屬層則 藉由自一金屬靶材之濺鍍而經濟地並有 巧双率地予以沉積。 一電漿濺鍍反應室90係概要繪示於第4 —圖之剖面視圖中。Deposited by chemical vapor deposition. The inductive metal layer of the present invention is deposited economically and ingeniously by sputtering from a metal target. A plasma sputtering reaction chamber 90 is schematically illustrated in the cross-sectional view of Fig. 4.

真空反應:t 92包含-基座電極94 α支樓一晶ffl %,而使 相對於晶圓96之一靶材98的材質濺鍍到晶圓%上。對於 藏鑛氮化欽而言,至少乾材98之前表面係由鈦所組成。真 空反應室92係典型地為電氣接地,並經由一隔離體1〇〇 而支撐乾材98。一直"il電源供應器1〇2於約6〇〇〜8〇〇VDC 之下而電氣地偏壓靶材98至一負電壓,藉以於真空反應室 92中支援一電漿。 一真空抽氣系統1 04係抽吸真空反應室至介於微托 (microTorr)範圍或更低之一基礎壓力(base pressure)。一氬 氣氣體源106經由質流控制器108而將氬氣供應至真空反 應室92以作為一濺鍍工作氣體。當真空反應室92中之氬 氣壓力處於低毫托(milliT〇rr)範圍時,施加一負電壓至相 對於該接地反應室或未圖示出之接地反應室屏蔽(chamber shields)的靶材98可將氬氣激發成為電漿。帶正電荷之氬 氣離子被吸引至被負偏壓之靶材9 8並將鈦原子自靶材9 8 13 200818501 濺射出來,所被濺射出來的一些鈦原子會撞擊晶圓並鍍 該晶圓。磁控言110設置於靶材98之背面並典型地包含 磁極性的一内磁極1 12以及一相對極性之周圍的較強外 極114,藉以產生鄰近靶材98之濺射面的一磁場,以增 電漿之雄、度,且藉以增加了濺鍍速率。相對較小之磁控 1 1 0會沿著反應室之中心軸旋轉,藉以提供更均一之靶 侵蝕以及晶圓之鍍覆。對於一高靶材功率以及一小又強 磁控管而言,一實質數量之濺鍍原子將被離子化。一射 電源11 6經由一電容耦合電路丨丨8而將基座電極94予以 氣地偏壓’藉以在晶圓9 6上產生出一負直流自給偏 (self-bias),以加速氬氣及靶材離子朝向晶圓96移動。 氮化欽之濺鍵塗覆可藉由一氮氣氣體源12〇來達成 其係經由另一質流控制器1 2 2而將氮氣氣體提供至真空 應室92。於一稱之為反應性錢鍍之程序中,氮氣將與藏 之鈦原子反應’以於晶圓9 6之表面上形成一氮化鈦層。 藉由使用如第4圖中所示之一濺鍍反應室,一系列 氮化鈦薄膜在六種不同組之濺鍍條件下生長。接著量測 些薄膜的應力以及其片電阻rs。描繪於第5圖之結果係 示出可藉由濺鍍條件之適當控制而將氮化鈦中所產生出 應力調整在- lGPa〜-12GPa之間。因此,對照於3GPa之 般限制,4PGa且更大或甚至為7GPa或更大的應力與 變之大小可輕易地且可控制地達成。氮化鈦薄膜之阻抗 愈大愈好。然而’實驗指出有一重大之例外,片電阻於 18〜75歐姆每平方(〇hms per square)之範圍間係與壓縮 力呈相反地變化。 更多系統化之實驗之進行係藉由於一裸石夕晶圓上, 覆 磁 加 管 材 之 頻 電 壓 反 鍍 之 這 顯 之 應 為 約 應 或 14 200818501 =矽晶圓上經熱氧化處理之300奈米厚之氧化矽上,生長 高應變之氮化鈦薄膜。如於第6圖所示之圖表中,在厚度 介於20〜100奈米之間’於二種組成之基材上,係具有二 著厚度而小但可量測之壓縮應力改變以及兩者相當之應 力》較薄之薄琪對於未來10世代所預期之緊密幾何佈局而 言係具有優勢。薄膜亦可生長於以不同之射頻偏壓功率施 加到基座電極的二個基材之上。>第7圖所示,壓縮應力 ΟVacuum reaction: t 92 contains a pedestal electrode 94 a fulcrum of a crystal, and a material relative to the target 98 of the wafer 96 is sputtered onto the wafer %. For the Tibetan mineralized nitrite, at least the surface of the dry material 98 is composed of titanium. The vacuum reaction chamber 92 is typically electrically grounded and supports the dry material 98 via a separator. The <il power supply 1 2 is electrically biased under the target of 98 to a negative voltage at about 6 Torr to 8 VDC to support a plasma in the vacuum reaction chamber 92. A vacuum pumping system 104 draws the vacuum reaction chamber to a base pressure in the microTorr range or lower. An argon gas source 106 supplies argon gas to the vacuum reaction chamber 92 via the mass flow controller 108 to act as a sputtering working gas. When the argon pressure in the vacuum reaction chamber 92 is in the low milliTorr range, a negative voltage is applied to the target relative to the grounded reaction chamber or the shielded shield chambers (not shown). 98 can excite argon gas into a plasma. The positively charged argon ions are attracted to the negatively biased target 9 8 and the titanium atoms are sputtered from the target 9 8 13 200818501. Some of the titanium atoms sputtered will strike the wafer and plate the Wafer. The magnetic control 110 is disposed on the back surface of the target 98 and typically includes an inner magnetic pole 1 12 of magnetic polarity and a strong outer pole 114 around a relative polarity to generate a magnetic field adjacent to the sputtering surface of the target 98. In order to increase the male and the degree of the plasma, and thereby increase the sputtering rate. A relatively small magnetron 110 will rotate along the central axis of the reaction chamber to provide more uniform target erosion and wafer plating. For a high target power and a small, strong magnetron, a substantial amount of sputtered atoms will be ionized. A primary power source 161 aurically biases the pedestal electrode 94 via a capacitive coupling circuit 丨丨8 to generate a negative direct current self-bias on the wafer 96 to accelerate argon gas and The target ions move toward the wafer 96. The nitriding of the nitriding can be achieved by a nitrogen gas source 12 其 which supplies nitrogen gas to the vacuum chamber 92 via another mass flow controller 1 2 2 . In a process known as reactive money plating, nitrogen will react with the trapped titanium atoms to form a titanium nitride layer on the surface of the wafer 96. A series of titanium nitride films were grown under six different sets of sputtering conditions by sputtering the reaction chamber as shown in Figure 4. The stress of the films and their sheet resistance rs are then measured. The results depicted in Figure 5 show that the stress generated in the titanium nitride can be adjusted between -1 GPa and -12 GPa by appropriate control of the sputtering conditions. Therefore, the stress and the magnitude of 4PGa and more or even 7 GPa or more can be easily and controllably determined in comparison with the limitation of 3 GPa. The impedance of the titanium nitride film is as large as possible. However, the experiment pointed out that there is a major exception. The sheet resistance varies inversely with the compressive force between the range of 18 to 75 ohms per square. More systematic experiments were carried out by means of a bare-metal wafer, and the voltage-voltage plating of the magnetically-coated tube was supposed to be approximately or 14 200818501 = 300 thermally oxidized on the wafer. On the nanometer thick yttrium oxide, a high strain titanium nitride film is grown. As shown in the graph shown in Fig. 6, on a substrate having a thickness of between 20 and 100 nm, the substrate has two thicknesses but small but measurable compressive stress changes and both The equivalent stress is thinner than the thin geometric layout expected for the next 10 generations. The film can also be grown on two substrates applied to the pedestal electrode at different RF bias powers. > Figure 7, compressive stress Ο

之最大值產生☆沒有晶圓·壓功率之條件T,且壓縮應力 隨著偏壓功率之增加而降低。基材材料之間所觀察到的差 異為非常微小。 本發明之氮化鈦無須為一純化學計量(st〇ichi〇metric) 之氣化鈦化合物,然,其可具有改變量之鈦與氮,只要最 終之材=為電氣地導電以及可被視為一金屬。氮化鈦可包 S較少里之其他元素,只要鈦與氮為二個最大之原子組成 部分。特別的是,一些氧可取代氮。K,本發明並非侷 限於氮化鈦。亦可使用其他含有應變誘導金屬之層,例如 為一金屬氮化物,例如:氮化钽或氮化鎢。其他金屬之實 例係包含其他耐火金屬,例如,鳃(Sr)、铪(Hf)、釩(V)、 鈮(Nb)、鈕(Ta)、鉻(Cr)以及鉬(Μ〇)。對於本發明之目的而 "’石夕並不視為在應變誘導層中的一金屬成分,此乃因為 氮化矽與氧化矽皆非為導電性。 雖然應變誘導金屬層係具有優勢地應用於一 MO S電 曰曰體以增加於通道中的遷移率,但其亦可應用於獲利於 ,變之半導體矽元件上。可瞭解的是,矽可以為經摻雜或 是為合金化,舉例言之,加入鍺,只要最終材料展現出純 矽之能帶結構以及一般遷移率特性。 15 200818501 本發明之應變層可於其他之濺鍍反應室中沉積,例如 包含用於電漿源區域之射頻線圈的濺鍍反應室。CVD生長 薄膜亦可能在適當之生長條件下可提供所需之應變。 本發明因而可利用一習知且可自一較經濟之來源予以 沉積之材料而使較大與可控制量之應變進入石夕中。 以上所述僅為本發明之較佳實施例而已,並非用以限 定本發明之範圍;凡其它未脫離本發明所揭示之精神下所 完成之等效改變或修飾,均應包含在下述之專利範圍内。 Γ 【圖式簡單說明】 第1圖為習知之金氧半導體(MOS)電晶體之剖面視圖; 第2圖為本發明之MOS電晶體之第一實施例之剖面視 圖,其具有圍繞閘極通道之一金屬應變誘導層; 第3圖為本發明之MOS電晶體之第二實施例,其具有 一金屬應變誘導層於閘極通道之上; 第4圖為一濺鍍反應室之概要剖面視圖,其可與本發 明並用; 第5圖為壓縮應力與片電阻之關係圖,用以顯示於不 K 同濺鍍條件下之氮化鈦薄膜的壓縮應力與片電阻之關係; 第6圖為壓縮應力與厚度之關係圖,用以顯示於不同 基材所濺鍍沉積之不同厚度的氮化鈦薄膜所產生之壓縮應 力與厚度之關係;以及 第7圖為壓縮應力與不同晶圓偏壓功率之關係圖,用 以顯示於不同基材所濺鍍沉積之氮化鈦薄膜所產生之壓縮 應力與不同晶圓偏壓功率之關係。 16 200818501The maximum value is generated ☆ without the condition T of wafer/pressure power, and the compressive stress decreases as the bias power increases. The difference observed between the substrate materials is very small. The titanium nitride of the present invention does not need to be a purely stoichiometric titanium oxide compound, however, it may have varying amounts of titanium and nitrogen as long as the final material = electrically conductive and can be viewed For a metal. Titanium nitride can contain other elements in S as long as titanium and nitrogen are the two largest atomic components. In particular, some oxygen can replace nitrogen. K, the invention is not limited to titanium nitride. Other layers containing strain-inducing metals may also be used, such as a metal nitride such as tantalum nitride or tungsten nitride. Other examples of metals include other refractory metals such as strontium (Sr), hafnium (Hf), vanadium (V), niobium (Nb), button (Ta), chromium (Cr), and molybdenum (ruthenium). For the purposes of the present invention, "Shi Xi is not considered to be a metal component in the strain inducing layer because neither tantalum nitride nor ruthenium oxide is electrically conductive. Although the strain inducing metal layer is advantageously applied to a MO S electric body to increase the mobility in the channel, it can also be applied to a semiconductor device that is advantageous for variation. It will be appreciated that niobium may be doped or alloyed, for example, by adding niobium as long as the final material exhibits a pure tantalum band structure and general mobility characteristics. 15 200818501 The strained layer of the present invention can be deposited in other sputtering reaction chambers, such as a sputtering reaction chamber containing a radio frequency coil for the plasma source region. CVD grown films may also provide the required strain under suitable growth conditions. The present invention thus makes it possible to utilize a material that is conventionally deposited and can be deposited from a more economical source to allow a greater and controllable amount of strain to enter the day. The above are only the preferred embodiments of the present invention, and are not intended to limit the scope of the present invention; all other equivalent changes or modifications which are not departing from the spirit of the present invention should be included in the following patents. Within the scope. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a cross-sectional view of a conventional metal oxide semiconductor (MOS) transistor; FIG. 2 is a cross-sectional view of a first embodiment of the MOS transistor of the present invention having a surrounding gate channel a metal strain inducing layer; Fig. 3 is a second embodiment of the MOS transistor of the present invention having a metal strain inducing layer over the gate channel; and Fig. 4 is a schematic cross-sectional view of a sputtering reaction chamber It can be used in combination with the present invention; Fig. 5 is a graph showing the relationship between the compressive stress and the sheet resistance for showing the relationship between the compressive stress and the sheet resistance of the titanium nitride film under the sputtering condition; The relationship between compressive stress and thickness is used to show the relationship between compressive stress and thickness produced by different thicknesses of titanium nitride film deposited on different substrates; and Figure 7 is the compressive stress and different wafer bias The power relationship diagram is used to show the relationship between the compressive stress generated by the titanium nitride film deposited on different substrates and the different wafer bias powers. 16 200818501

【主要元件符號說明】 10 電晶體 12 砍基材 14 淺溝槽隔離 16 通道 18 閘極氧化物 20 閘極電極 22 襯墊 24 間隙物 30,32 延伸部分 34 源極 36 汲極 40,42,44歐姆接觸(層) 50 蝕刻終止層/氮化物 52 前金屬介質層 層 54 (源極)接觸 56 (汲極)接觸 58 (閘極)接觸 60 電晶體 62 壓縮層 70 電晶體 72 介質層 74 閘極介質層 76 閘極電極層 78 金屬層/應變層 80 接觸金屬 90 反應室 92 真空反應室 94 基座電極 96 晶圓 98 靶材 100 隔離體 102 電源供應器 104 真空抽氣系統 106 氬氣氣體源 108 質流控制器 110 磁控管 112 内磁極 114 外磁極 116 射頻功率 118 電容耦合電路 120 氮氣氣體源 122 質流控制器 17[Main component symbol description] 10 transistor 12 chopping substrate 14 shallow trench isolation 16 channel 18 gate oxide 20 gate electrode 22 pad 24 spacer 30, 32 extension portion 34 source 36 drain 40, 42, 44 ohm contact (layer) 50 etch stop layer/nitride 52 front metal dielectric layer 54 (source) contact 56 (drain) contact 58 (gate) contact 60 transistor 62 compression layer 70 transistor 72 dielectric layer 74 Gate dielectric layer 76 Gate electrode layer 78 Metal layer/strain layer 80 Contact metal 90 Reaction chamber 92 Vacuum reaction chamber 94 Base electrode 96 Wafer 98 Target 100 Isolation body 102 Power supply 104 Vacuum extraction system 106 Argon Gas source 108 mass flow controller 110 magnetron 112 inner magnetic pole 114 outer magnetic pole 116 RF power 118 capacitive coupling circuit 120 nitrogen gas source 122 mass flow controller 17

Claims (1)

200818501 十、申請專利範圍: 1· 一種應變金氧半導體(metal-oxide-semiconductor ; M0S)電晶體,其包含: 一基材,包含半導體矽之一通道區;以及 一應變誘導層,該應變誘導層為一金屬化合物,該應 變誘導層係形成於該基材之上並位於該通道區之一區域 中,而在該通道區中具有應變與誘導應變。 C 2 ·如申請專利範圍第1項所述之電晶體,其中該金屬化合 物為氮化物。 3 .如申請專利範圍第2項所述之電晶體,其中該金屬化合 物包含氣化鈇。 4.如申請專利範圍第1項至第3項之任一項所述之電晶 體,其中該基材更包含: p型(p -1 y p e)源極與沒極區域,其係分別位於該通道 區之一側,其中該應變誘導層係形成於該通道區之側邊。 5 ·如申請專利範圍第1項至第3項之任一項所述之電晶 體,其中該基材更包含: η型(η -1 y p e)源極與汲極區域,其係分別位於該通道區 之一側,且其中該應變誘導層係直接形成於該通道區之一 中心之上。 6.如申請專利範圍第1項至第3項之任一項所述之電晶 18 200818501 體,其中該應變為具有強度值至少為4GPa (40億帕斯卡) 之一壓縮應變(compressive strain)。 7. 如申請專利範圍第6項所述之電晶體,其中該壓縮應變 之強度至少為7GPa。 8. 如申請專利範圍第1項至第3項之任一項所述之電晶 體,其中該基材更包含: fx η型源極與汲極區域,其係分別位於該通道區之一 側,其中該應變為壓縮應變,且其中該應變誘導層係直接 形成於該通道區之一中心之上。 9. 一種應變MOS電晶體,其包含: 一基材,包含半導體矽之一通道區;以及 一應變誘導層,該應變誘導層為氮化鈦,該應變誘導 層係形成於該基材之上而位於該通道區之一區域中’並在 該通道區中誘導應變。 ( V 1 0.如申請專利範圍第9項所述之電晶體,其更包含: p型源極與汲極區域,其係分別形成於該通道區之一 側,且其中該應變誘導層係形成於該通道區之側邊而不直 接位於一中心之上。 1 1.如申請專利範圍第9項或第1 0項所述之電晶體,其更 包含: η型源極與汲極區域,其係分別形成於該通道區之一 19 200818501 側,且其中該應變誘導層係直接形成於該通道區之一中心 之上。 12.—種於矽中誘導應變之方法,該方法包含: 濺鍍沉積一包含一金屬化合物的應變誘導層於一矽基 材上,藉以形成一區域,該區域鄰近形成於該矽基材中之 一 MOS電晶體的一通道區,並在其中誘導應變。 1 3 .如申請專利範圍第1 2項所述之方法,其中該金屬化合 物包含一金屬氮化物。 14.如申請專利範圍第13項所述之方法,其中該金屬氮化 物包含氮化鈦。 1 5 .如申請專利範圍第1 2項至第1 4項之任一項所述之方 法,其中該金屬化合物係於一電漿濺鍍室中沉積,該電漿 錢鑛室具有·基座電極以支撐該砍基材’而使該基材處於 一乾材之相對位置,該把材包含該金屬化合物之一金屬。 / 1 6.如申請專利範圍第1 5項所述之方法,其中該靶材包含 一鈦濺鍍表面,且額外地包含使氮氣進入該電漿濺鍍室内。 1 7.如申請專利範圍第1 5項所述之方法,其中施加至該基 座電極之一偏壓功率係經選擇而使該金屬化合物内的應變 達到一預定層級。 20 200818501 1 8 ·如申請專利範圍第1 5項所述之方法,其中該金屬化合 物包含氮化鈦,以及應變之該預定層級之強度至少為 4GPa 〇 19.如申請專利範圍第18項所述之方法,其中該MOS電晶 體為一 PMOS電晶體,且該應變誘導層係沉積於該通道區 之側邊,而非直接地位於其上方。 2 0.如申請專利範圍第18項所述之方法,其中該MOS電晶 體為一 NMOS電晶體,且該應變誘導層係直接沉積於該通 道區之上。 21.如申請專利範圍第12項至第14項之任一項所述之方 法,其中該應變為壓縮應變。 21200818501 X. Patent application scope: 1. A metal-oxide-semiconductor (MOS) transistor comprising: a substrate comprising a channel region of a semiconductor germanium; and a strain inducing layer, the strain induction The layer is a metal compound formed on the substrate and located in a region of the channel region with strain and induced strain in the channel region. C 2 The transistor of claim 1, wherein the metal compound is a nitride. 3. The transistor of claim 2, wherein the metal compound comprises gasified ruthenium. 4. The transistor according to any one of claims 1 to 3, wherein the substrate further comprises: a p-type (p -1 ype) source and a non-polar region, the One side of the channel region, wherein the strain inducing layer is formed on a side of the channel region. The transistor according to any one of claims 1 to 3, wherein the substrate further comprises: an n-type (η -1 ype) source and a drain region, respectively One side of the channel region, and wherein the strain inducing layer is formed directly on the center of one of the channel regions. 6. The electro-crystal 18 200818501 according to any one of claims 1 to 3, wherein the strain is one of compressive strain having an intensity value of at least 4 GPa (4 billion Pascals). 7. The transistor of claim 6, wherein the compressive strain has an intensity of at least 7 GPa. 8. The transistor of any one of claims 1 to 3, wherein the substrate further comprises: an fx η source source and a drain region, each of which is located on one side of the channel region Wherein the strain is a compressive strain, and wherein the strain inducing layer is formed directly on a center of the channel region. 9. A strained MOS transistor comprising: a substrate comprising a channel region of a semiconductor germanium; and a strain inducing layer, the strain inducing layer being titanium nitride, the strain inducing layer being formed on the substrate And located in a region of the channel region 'and induces strain in the channel region. (V1 0. The transistor of claim 9, further comprising: a p-type source and a drain region, respectively formed on one side of the channel region, and wherein the strain inducing layer is Formed on the side of the channel region and not directly on a center. 1 1. The transistor according to claim 9 or 10, further comprising: an n-type source and a drain region And the system is formed on one side of the channel region 19 200818501, and wherein the strain inducing layer is directly formed on the center of one of the channel regions. 12. A method for inducing strain in a crucible, the method comprising: Sputter deposition deposits a strain inducing layer comprising a metal compound on a substrate to form a region adjacent to a channel region of one of the MOS transistors formed in the germanium substrate and inducing strain therein. The method of claim 12, wherein the metal compound comprises a metal nitride. The method of claim 13, wherein the metal nitride comprises titanium nitride. 1 5 . If you apply for a patent The method of any one of clauses 1 to 4, wherein the metal compound is deposited in a plasma sputtering chamber having a pedestal electrode to support the chopping substrate And the substrate is in a relative position of a dry material, the material comprising a metal of the metal compound. The method of claim 15, wherein the target comprises a titanium sputtering a surface, and additionally comprising introducing nitrogen into the plasma sputtering chamber. The method of claim 15, wherein the bias power applied to the one of the susceptor electrodes is selected such that The strain in the metal compound reaches a predetermined level. 20 200818501 1 8 The method of claim 15, wherein the metal compound comprises titanium nitride, and the predetermined level of strain has a strength of at least 4 GPa 〇 19 The method of claim 18, wherein the MOS transistor is a PMOS transistor, and the strain inducing layer is deposited on a side of the channel region rather than directly above it. For example, the 18th item of patent application The method, wherein the MOS transistor is an NMOS transistor, and the strain inducing layer is directly deposited on the channel region. 21. The method according to any one of claims 12 to 14 The method wherein the strain is a compressive strain.
TW096123859A 2006-06-30 2007-06-29 Metal layer inducing strain in silicon TW200818501A (en)

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CN104183492A (en) * 2013-05-21 2014-12-03 中芯国际集成电路制造(上海)有限公司 Stress structure forming method

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US20060118892A1 (en) * 2004-12-02 2006-06-08 Taiwan Semiconductor Manufacturing Company, Ltd. Methods and Structures to Produce a Strain-Inducing Layer in a Semiconductor Device

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104183492A (en) * 2013-05-21 2014-12-03 中芯国际集成电路制造(上海)有限公司 Stress structure forming method

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