[go: up one dir, main page]

TW200818204A - Mixed-use memory array with different data states and method for use therewith - Google Patents

Mixed-use memory array with different data states and method for use therewith Download PDF

Info

Publication number
TW200818204A
TW200818204A TW96123303A TW96123303A TW200818204A TW 200818204 A TW200818204 A TW 200818204A TW 96123303 A TW96123303 A TW 96123303A TW 96123303 A TW96123303 A TW 96123303A TW 200818204 A TW200818204 A TW 200818204A
Authority
TW
Taiwan
Prior art keywords
memory
state
data
memory cells
array
Prior art date
Application number
TW96123303A
Other languages
Chinese (zh)
Other versions
TWI483262B (en
Inventor
Roy E Scheuerlein
Christopher J Petti
Original Assignee
Sandisk 3D Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/496,870 external-priority patent/US20080025069A1/en
Priority claimed from US11/497,021 external-priority patent/US7486537B2/en
Application filed by Sandisk 3D Llc filed Critical Sandisk 3D Llc
Publication of TW200818204A publication Critical patent/TW200818204A/en
Application granted granted Critical
Publication of TWI483262B publication Critical patent/TWI483262B/en

Links

Classifications

    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C17/00Read-only memories programmable only once; Semi-permanent stores, e.g. manually-replaceable information cards
    • G11C17/14Read-only memories programmable only once; Semi-permanent stores, e.g. manually-replaceable information cards in which contents are determined by selectively establishing, breaking or modifying connecting links by permanently altering the state of coupling elements, e.g. PROM
    • G11C17/16Read-only memories programmable only once; Semi-permanent stores, e.g. manually-replaceable information cards in which contents are determined by selectively establishing, breaking or modifying connecting links by permanently altering the state of coupling elements, e.g. PROM using electrically-fusible links
    • G11C17/165Memory cells which are electrically programmed to cause a change in resistance, e.g. to permit multiple resistance steps to be programmed rather than conduct to or from non-conduct change of fuses and antifuses
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/56Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using storage elements with more than two stable states represented by steps, e.g. of voltage, current, phase, frequency
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/56Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using storage elements with more than two stable states represented by steps, e.g. of voltage, current, phase, frequency
    • G11C11/5692Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using storage elements with more than two stable states represented by steps, e.g. of voltage, current, phase, frequency read-only digital stores using storage elements with more than two stable states
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C13/00Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
    • G11C13/0002Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C17/00Read-only memories programmable only once; Semi-permanent stores, e.g. manually-replaceable information cards
    • G11C17/14Read-only memories programmable only once; Semi-permanent stores, e.g. manually-replaceable information cards in which contents are determined by selectively establishing, breaking or modifying connecting links by permanently altering the state of coupling elements, e.g. PROM
    • G11C17/16Read-only memories programmable only once; Semi-permanent stores, e.g. manually-replaceable information cards in which contents are determined by selectively establishing, breaking or modifying connecting links by permanently altering the state of coupling elements, e.g. PROM using electrically-fusible links
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C29/00Checking stores for correct operation ; Subsequent repair; Testing stores during standby or offline operation
    • G11C29/70Masking faults in memories by using spares or by reconfiguring
    • G11C29/76Masking faults in memories by using spares or by reconfiguring using address translation or modifications
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C2211/00Indexing scheme relating to digital stores characterized by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C2211/56Indexing scheme relating to G11C11/56 and sub-groups for features not covered by these groups
    • G11C2211/564Miscellaneous aspects
    • G11C2211/5641Multilevel memory having cells with different number of storage levels
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C2211/00Indexing scheme relating to digital stores characterized by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C2211/56Indexing scheme relating to G11C11/56 and sub-groups for features not covered by these groups
    • G11C2211/564Miscellaneous aspects
    • G11C2211/5646Multilevel memory with flag bits, e.g. for showing that a "first page" of a word line is programmed but not a "second page"
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C2213/00Indexing scheme relating to G11C13/00 for features not covered by this group
    • G11C2213/70Resistive array aspects
    • G11C2213/72Array wherein the access device being a diode

Landscapes

  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Semiconductor Memories (AREA)
  • Read Only Memory (AREA)

Abstract

A mixed-use memory array with different data states and a method for use therewith are disclosed. In one preferred embodiment, a memory array is provided comprising a plurality of memory cells, each memory cell comprising a memory element comprising a switchable resistance material configurable to one of at least three resistivity states. A first set of memory cells uses X resistivity states to represent X respective data states, and a second set of memory cells uses Y resistivity states to represent Y respective data states, wherein X ≠ Y.

Description

200818204 九、發明說明: 【先前技術】 時仍維持其資 憶體單元經形 以轉換成一經 記憶體單元係 元係可擦除並 達成之若干資 元的某特性來 或該記憶體單 憶體單元的電 ,諸如一資料 非揮發性記憶體陣列甚至當關閉裝置電源 料。在可單次程式化記憶體陣列中,每一記 成為處於一初始未經程式化狀態,並且可予 程式化狀恶。此項變更係永久性,並且此等 不可擦除。在其它類型記憶體中,記憶體單 且可重寫多次。 δ己fe體單元亦可變化於每一記憶體單元可 料狀I、中。可藉由改變可偵測到之記憶體單 儲存一資料狀態,諸如在一既定施加之電壓 元内一電晶體之臨限電壓之下流動通過該記 流。一資料狀態係記憶體單元之一相異值 π 〇π或一資料” 1,,。 一些:於達成可擦除或多狀態記憶體單元之方案複雜。 舉例而& ’洋動間極與SQ記憶體單元藉由健存電荷來 運作其中μ儲存之電荷存在、不存在或電荷量改變一電 晶體臨限電壓。彼等記憶體單元係三端子式裝置,在對於 現代積體電路巾餘 f力所系的非常小型尺寸下,彼等記憶 體早70相對難以製造與運作。 其它記憶體單元藉由改變相對奇特的材料(如硫屬)之電 率來運作。在大多數半導體生產㈣中,硫屬難以配 使用且可具挑戰性。 糟由具有以易於縮放至小尺寸之結構使用f知半導體材 121890.doc 200818204 料形成的可擦除或多狀態記憶體 二 列來提供實質上優點。 、揮毛性記憶體陣 【發明内容】 本發明係藉由下文請求項予以 、, / ^ ^ bh rfe 疋義,並且在此段落中的 ㈣内谷皆不應視為對請求項之限制。 藉由簡介,下文描述之較佳 ^ ^ 1具體實施例提供一種且右不 同 > 料狀態之混合用途記_ ^ w 用迮^己隐體陣列及其使用方法。在一項200818204 IX. Description of the invention: [Prior Art] When the memory unit is still shaped to be converted into a certain characteristic of a memory element system that can be erased and achieved, or the memory memory The unit's electricity, such as a data non-volatile memory array, even when the device power is turned off. In a single-programmable memory array, each record is in an initial unprogrammed state and can be stylized. This change is permanent and cannot be erased. In other types of memory, the memory is single and can be rewritten multiple times. The δ-hexene unit can also be changed in the memory form I and medium of each memory unit. The data state can be stored by changing the detectable memory bank, such as flowing through the current under a threshold voltage of a transistor within a predetermined applied voltage. A data state is one of the memory cells with a different value of π 〇 π or a data "1." Some: The scheme for achieving an erasable or multi-state memory cell is complicated. For example, & The SQ memory cell operates by storing a charge in which the stored charge of the μ is present, does not exist, or the amount of charge changes by a threshold voltage of the transistor. The memory cells are three-terminal devices, in the case of a modern integrated circuit Under the very small size of f force, their memory is relatively difficult to manufacture and operate. Other memory cells operate by changing the electrical potential of relatively exotic materials (such as chalcogen). In most semiconductor production (4) Among them, chalcogen is difficult to use and can be challenging. The depletion is provided by a two-column erasable or multi-state memory formed by a structure that is easy to scale to a small size using a semiconductor material 121890.doc 200818204. Advantages. Swinging memory array [Invention] The present invention is made by the following claims, / ^ ^ bh rfe ,, and (4) in this paragraph should not be regarded as Limitation of the claim. By way of introduction, the preferred embodiment described below provides a mixed use of the right and different states of the material, and a method of using the same. item

車父it具體實施例中,提供 、 纪㈣嚴_ — 己憶體陣列,其包括複數個 ^ ^ ^ , 平兀匕括一纪憶體元件,該記憶 體兀件包括可組態至黾小二猫+ ^ 至少二種電阻率狀態中之一者的一可 切換式電阻材料。一第一組 — … 一 、°己匕體早兀使用X種電阻率狀 怨來表示X種各自資料狀態;及一第二組記憶體單元使用 :種電阻率狀態來表示Y種各自資料狀態,其中X…揭 示其它具體實施例,並且每一且奋 ^ 母/、體只轭例可予以單獨或組 合運用。 現在將參考附圖來說明較佳具體實施例。 【實施方式】 已知,藉由施加電脈衝,由經摻雜複晶矽形成之電阻器 的電阻可^以修整,在穩定電阻狀態之間進行調整。已使 用此等可修整式電阻器作為積體電路中的元件。 但疋,在非揮發性記憶體單元中使用可修整式複晶矽電 阻器可來儲存資料狀態不是習知做法。製作複晶矽電阻器 之圯憶體陣列存在困難。如果在大交叉點(cross-point)記 憶體陣列中使用電阻器作為記憶體單元,則當施加電壓至 121890.doc 200818204 一所選記憶體單元時,則在整個記憶體陣列將有非所要洩 漏牙過半所選與非所選記憶體單元。舉例而言,請參考圖 1 ’假定施加一電壓於位元線B與字線A之間以設定、重設 或感測所擇記憶體單元S。電流意欲流動通過所擇記憶體 單元S。但是,某洩漏電流可在替代路徑(舉例而言,介於 位元線B與字線A之間)上流動通過非所擇記憶體單元υι、 U2與U3。有許多此類替代路徑可存在。 藉由形成母一記憶體單元作為一包括一個二極體的兩端 子式裝置,可大幅減小洩漏電流。二極體具有非線性p V(電流電壓)特性,允許低於開通電壓的極少量電流流動 及面於開通電壓的較高電流流動。一般而言,二極體亦作 為單向閥,以使電流往一方向行進比往另一方向行進更容 易。因此,只要所擇擇的加偏壓方案確保僅所擇記憶體單 元經受到高於開通電壓的正向電流,則可大幅減小沿非預 定路控(諸如圖1之U1-U2-U3非正常路徑)的洩漏電流。 Hemer等人於2004年9月29日申請之美國專利申請案第 10/955,549 號 ’’Nonvolatile Memory Cell Without aIn the specific embodiment of the car master, the invention provides a plurality of arrays, including a plurality of ^^^, which includes a component, the memory component including configurable to small Two cats + ^ A switchable resistive material of at least two of the resistivity states. A first group - ... a ° ° 匕 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 兀 电阻 电阻 电阻 电阻Wherein X ... reveals other specific embodiments, and each of the conjugates can be used alone or in combination. Preferred embodiments will now be described with reference to the drawings. [Embodiment] It is known that by applying an electric pulse, the resistance of a resistor formed by doped polysilicon can be trimmed and adjusted between stable resistance states. These trimmable resistors have been used as components in an integrated circuit. However, it is not customary to use a trimtable polysilicon resistor in a non-volatile memory cell to store data. It is difficult to fabricate a memory array of a polysilicon resistor. If a resistor is used as a memory cell in a large cross-point memory array, then when a voltage is applied to 121890.doc 200818204 a selected memory cell, there will be an unwanted leakage across the memory array. More than half of the selected and unselected memory units. For example, please refer to FIG. 1 ' assuming that a voltage is applied between the bit line B and the word line A to set, reset or sense the selected memory cell S. The current is intended to flow through the selected memory unit S. However, a leakage current can flow through the alternate memory cells υι, U2, and U3 over an alternate path (for example, between bit line B and word line A). There are many such alternative paths that can exist. By forming the mother-memory unit as a two-terminal device including a diode, the leakage current can be greatly reduced. The diode has a nonlinear p V (current-voltage) characteristic that allows a very small amount of current flow below the turn-on voltage and a higher current flow to the turn-on voltage. In general, diodes are also used as check valves to make it easier to travel in one direction than in the other. Therefore, as long as the selected biasing scheme ensures that only the selected memory cell is subjected to a forward current higher than the turn-on voltage, the non-predetermined routing can be greatly reduced (such as U1-U2-U3 in Figure 1 Leakage current for normal path). U.S. Patent Application Serial No. 10/955,549, filed on Sep. 29, 2004, to s.

Dielectric Antifuse Having High- and Low-Impedance States"(下文稱為’549申請案並且特此以引用方式併入本 文中)描述一種單片三維記憶體陣列,其中以半導體接面 一極體之衩晶半導體材料的電阻率狀態來儲存記憶體單元 之資料狀悲。此記憶體單元係一種具有兩種資料狀雜之可 單次程式化記憶體單元。二極體經形成為處於高電阻率狀 態;施加程式化電壓使二極體永久變換成低電阻率狀雖。 121890.doc 200818204 在本發明具體實施例中,藉由施加適當的電脈衝,由經 掺雜半導體材料所形成之記憶體元件(諸如,5辩請案之半 :體二極體)可達成三種、四種或四種以上穩定電阻率狀 °在本發明其它具體實施例巾’可使半導體材料從初始 高電阻率狀態轉換成較低電阻率狀態;接著,在施加適當 的電脈衝下,可返回至較高電阻率狀態。可個別地或組合 地才木用彼等具體實施例,以形成可具有兩種或兩種以上資 料狀態並且可以係可單次程式化或可重寫之記憶體單元。、 如所述’在記憶體單元之導體之間包含_個二極體允許 开> 成於问雄、集交叉點記憶體陣列中。在本發明較佳具體 實&例中’接著’複晶、非晶系或微晶半導體記憶體元件 經形成以串聯於二極體,或更佳方式為,形成為二極體本 身。 %在此論述中,自較高電阻率狀態至較低電阻率狀態之轉 义將稱為设定”轉變,其係受到設定電流、設定電壓或設 定T衝所影響;自較低電阻率狀態至較高電阻率狀態之逆 轉變將稱為"重設"轉變,其係受到重設電流、重設電壓或 重設脈衝所影響。 在較佳可單次程式化具體實施例中,一複晶半導體二極 體盘—八帝 /、 電破裂反熔絲配對,然而,在其它具體實施例 中’可省略反熔絲。 圖2綠不根據本發明較佳具體實施例形成之記憶體單 ^ —底導體12係由傳導材料(例如,鎢)所形成並且往一 第 _ 向延伸。在底部導體12中可包含障壁層與黏著層。 121890.doc 200818204Dielectric Antifuse Having High-and Low-Impedance States" (hereinafter referred to as the '549 application and incorporated herein by reference) describes a single-chip three-dimensional memory array in which a semiconductor junction-polar crystal semiconductor The resistivity state of the material stores the data of the memory cell. This memory unit is a single-programmed memory unit with two types of data. The diode is formed in a high resistivity state; the application of a stylized voltage causes the diode to be permanently transformed into a low resistivity. 121890.doc 200818204 In a particular embodiment of the invention, three types of memory elements (such as the fifth half of the pleading: body diode) formed by the doped semiconductor material can be achieved by applying appropriate electrical pulses. Four or more stable resistivity values. In other embodiments of the present invention, the semiconductor material can be converted from an initial high resistivity state to a lower resistivity state; then, under application of an appropriate electrical pulse, Return to the higher resistivity state. The specific embodiments may be used individually or in combination to form a memory unit that can have two or more states and can be single-programmed or rewritable. As described above, the inclusion of _ diodes between the conductors of the memory unit allows for > in the array of intersections and memory. In the preferred embodiment of the present invention, the 'subsequent' polycrystalline, amorphous or microcrystalline semiconductor memory device is formed to be connected in series to the diode, or more preferably, to form the diode itself. % In this discussion, the escaping from the higher resistivity state to the lower resistivity state will be referred to as the set "transition, which is affected by the set current, the set voltage, or the set T-shoot; from the lower resistivity state The inverse of the higher resistivity state will be referred to as a "reset" transition, which is affected by reset current, reset voltage, or reset pulses. In a preferred single-programmed embodiment, A polycrystalline semiconductor diode disk - octagonal /, electrical rupture anti-fuse pairing, however, in other embodiments 'an anti-fuse can be omitted. Figure 2 Green does not form a memory according to a preferred embodiment of the present invention The bottom conductor 12 is formed of a conductive material (for example, tungsten) and extends toward a first direction. The barrier layer and the adhesive layer may be included in the bottom conductor 12. 121890.doc 200818204

複6, 晶半導體二極體2具有一 其意圖未經摻雜;及一 底部重摻雜η型區4; 一本質區 頂部重摻雜區8,然而此二極體 之定向可顛倒。無論此二極體之定向,其將稱為—二極 體。在一些具體實施例中,包含介電破裂反熔絲14。頂部 導體16可用相同於底部導體12之方式及材料予以形成並且 <不同於該第一方向之一第二方向延伸。複晶半導體二極 體2被垂直佈置於底部導體12與頂部導體16之間。 丘複::半導體二極體2係形成為處於高電阻率狀態。此記 憶體單元可形成於—適合基板上方’舉例而言,—單結晶 矽晶圓上方 圖3繪示於父叉點記憶體陣列中形成此等裝 置的記憶體層級之一部分,其 體12與頂部導體16之間(在此圖 重記憶體層級堆疊於一基板上 維記憶體陣列。 中二極體2係佈置於底部導 中省略反炼絲14)。可將多 ’以形成一高度密度單片三 隹此确述中,一意圖未經摻雜之半導體材料區描述為_ 本質區。但是’熟悉此項技術者應明白,實際上,本質〇 可包括-低濃度p型或η型摻雜物。摻雜物可自相鄰區擴, 進入本質區’或可能於沉積期間歸因於來自早先沉積之; 染而存在於沉積室中。應進—步明白,經沉積之本質半无 體材料(諸如%可包括缺陷,而造成其猶如經輕微η摻雜, 使用用詞"本質”來描述矽、鍺、矽料金或某其它半導# 材料非意欲暗示此區未含任何摻雜物’亦非意欲暗示此: 係完全電中性。 可藉由施加適當的電脈衝 使經摻雜複晶或微晶半導體 121890.doc 200818204 材料(例如,矽)之電阻率於穩定狀態之間改變。經發現, 在較佳具體實施例中,有利地配合二極體在正向偏壓下來 只行没定轉變,而配合二極體在逆向偏壓下更易於達成及 控制重設轉變。但是,在一些狀況中,可配合二極體在逆 向偏壓下來達成設定轉變,而配合二極體在正向偏壓下來 達成重設轉變。 半導體切換行為複雜。對於二極體,配合二極體在正向 偏壓下已達成設定轉變與重設轉變兩者。一般而言,配合 一極體在正向偏壓下施加之重設脈衝(其足以使構成二極 體的複晶半導體材料自一既定電阻率狀態切換至一較高電 阻率狀態、)的振幅低於相對應之設定脈衝(其將相同複晶半 導體材料自相同電阻率狀態切換至一較低電阻率狀態)並 且具有較長之脈衝寬度。 在逆向偏壓下進行切換呈現出相異的行為。假定複晶 i-n二極體(像是圖2中所示之二極體)在逆向偏壓下經受到 相對長切換脈衝。在施加切換脈衝之後,施加較小之讀 取脈衝(例如,2伏),並且測量流動通過處於讀取電壓之電 流(稱為讀取電流)。隨著在逆向偏壓下之切換脈衝之電壓 在後績脈衝中增大,後續讀取電流以兩個伏特變更,如圖 4所示。將理解到,初始時隨著逆向電壓與切換脈衝的電 抓乓大,§在母一切換脈衝後施加讀取電壓時,讀取電流 增大,即,在設定方向中,半導體材料(在此情況中,半 導體材料係矽)的初始轉變係朝向較低電阻率。一旦切換 脈衝抵達一定逆向偏壓電壓(圖4中之尺點,在此實例中係 121890.doc 200818204 約-14.6伏),讀取電流突然開始下降,原因係達成重設且 石夕電阻率增大。當開始施加逆向偏壓切換脈衝,切換電壓 (在此切換電壓下,設定趨勢被逆轉並且二極體之石夕開始 重设)係取決於(例如)構成二極體的矽之電阻率狀態而變 化。接著,將理解到,藉由所擇適當之電壓,配合二極體 在逆向偏壓下可達成構成二極體的半導體材料之設定或重 - 設。 本發明之記憶體單元的相異資料狀態對應於構成二極體 •的複晶或微晶半導體材料的電阻率狀態,其係藉由當施加 讀取電壓時偵測流動通過記憶體單元(介於頂部導體16與 底部導體12之間)的電流予以辨別。較佳方式為,介於任 一相異資料狀態與任何不同相異資料狀態之間的流動之電 流係至少2之因數,以允許介於狀態之間的差異係易於可 傾測。 可使用記憶體單元作為可單次程式化記憶體單元或可重 _ 寫β己彳思體單元,並且可具有兩種、三種、四種或四種以上 相 料狀悲。在正向偏壓與逆向偏壓下,可使記憶體單 元依任何順序自任何其資料狀態轉換成任何其它其資料狀 . 態。 • 將提供數項較佳具體實施例實例。但是,應明白,彼等 灵例無限制意圖。熟悉此項技術者應明白,用以程式化兩 端子式裝置(包括一個二極體及複晶或微晶半導體材料)之 其它方法將屬於本發明範疇内。 可單次程式化多位準記憶體單元 121890.doc -12- 200818204 /本發明之—較佳具體實施例中…由複晶半導體材料 形成之二極體與—介電破裂反熔絲係以串聯方式排列且佈 置於頂部與底部導體之間。兩端子式裝置係用作為可單次 程式化多位準記憶體,在較佳具體實施财,其具有三種 或四種資料狀態。 圖2繪示一較佳記憶體單元。二極體2較佳係用複晶或微 2導體材料所形成,例如,石夕、錯、或_石夕及/或錯之 口至更佳方式為,二極體2係複晶矽。在此實例中,底 部重摻雜區4係11型,並且頂部重摻雜區8係^型,然而二極 體之極性可顛倒。記憶體單元包括頂部導體之—部分、底 邛V體之一部分及一個二極體,該二極體佈置於該等導體 之間。 當形成時,複晶矽之二極體2係處於高電阻率狀態,並 且’I電破裂反溶絲14原封不動。圖5繪示在各種狀態中的 記憶體單元之電流的機率標繪圖。請參考圖5,當施加讀 取電壓(例如,2伏)於頂部導體16與底部導體12之間(配合 一極體2在正向偏壓下)時,介於頂部導體〗6與底部導體i 2 之間流動的讀取電流較佳係在奈安培範圍内,例如,小於 約5奈安培。圖5之圖表上的區域v相對應於記憶體單元之 第一資料狀態。對於記憶體陣列中的一些記憶體單元, 此記憶體單元將未經受設定脈衝或重設脈衝,並且此狀態 將被項取作為該記憶體單元之一資料狀態。此第一資料狀 態將稱為V狀態。 施加一第一電脈衝(較佳配合二極體2在正向偏壓下)於 121890.doc 13 200818204 頂部導體16與底部導體丨2之間。此脈衝係(例如)介於約8伏 與約12伏之間,例如,約10伏。電流係(例如)介於約8〇微 安培與約200微安培之間。脈衝寬度較佳係介於約1〇〇奈秒 與約500奈秒之間。此第一電脈衝使介電破裂反熔絲丨斗破 裂且使二極體2之半導體材料自一第一電阻率狀態切換至 一第二電阻率狀態,第二電阻率狀態低於第一電阻率狀 態。此第二資料狀態將稱為P狀態,並且圖5中將此轉變標 示為"V—P"。在2伏讀取電壓下流動於頂部導體“與底部 導體12之間的電流係約10微安培或以上。構成二極體2之 半導體材料電阻率減少約1000至約2000之因數。在其它具 體實施例中,電阻率變化小,但是介於任一資料狀態與任 一其它資料狀態之間將係至少2之因數,較佳係至少3或5 之因數’並且更典型係100或以上之因數。記憶體陣列中 的一些記憶體單元將係以此資料狀態予以讀取,並且將未 經受額外設定脈衝或重設脈衝。此第二資料狀態將稱為p 狀態。 施加一第二電脈衝(較佳配合二極體2在逆向偏壓下)於 頂部導體16與底部導體12之間。此脈衝係(例如)介於約_8 伏與約_14伏之間,較佳介於約-1〇伏與約_12伏之間,較佳 係約-11伏。電流係(例如)介於約8〇微安培與約2〇〇微安培 之間。脈衝寬度係(例如)介於約100奈秒與約10微秒之間, 較佳係介於約100奈秒與約1微秒之間,更佳係介於約2〇〇 奈秒與約800奈秒之間。此第二電脈衝使二極體2之半導體 材料自第二電阻率狀態切換至一第三電阻率狀態,第三電 121890.doc -14- 200818204 態高於第二電阻率狀態。在2伏讀取電塵下流動於 么^體16與底部導體12之間的電流係介於約H)奈安培與 約5〇0奈安培之間’較佳介於約⑽奈安培與約5G0奈安培 之^記憶體陣列中的—些記憶體單元將係以此資料狀態予 以項取’亚且將未經受額外設定脈衝或重設脈衝。此第三資 料狀態將稱為R狀態,並且圖5中將此轉變標示為"p—R,「' 為了達第四資料狀態,施加一第三電脈衝(較佳配合二 極體2在正向偏遷下)於頂部導體16與底部導體η之間。此 ,衝係(例如)介於約8伏與約12伏之間(例如約叫犬),而電 流係介於約5微安培與約職安培之間。此第三電脈衝使二 極之半導體材料自第三電阻率狀態切換至—第四電阻率 狀態’第目電阻率狀態低於第2電阻率狀態,ϋ且較佳電 阻率同於第_電阻率狀態。纟2伏讀取電壓下流動於頂部導 體16與底部導體12之間的電流係約i 5微安培與約4.5微安培 之間。記憶體陣列中的一些記憶體單元將係以此資料狀態(其 將%為s狀態)予以讀取’並且圖5中將此轉變標示為”R4S”。 介於任何兩種相鄰資料狀態在讀取電壓(例如2伏)下之 電流差異較佳係至少2之因數。舉例而言,處於資料狀態厌 之任何圮憶體單元的讀取電流較佳至少兩倍於處於資料狀 態v之任何記憶體單元的讀取電流;處於資料狀態s之任何 記憶體單元的讀取電流較佳至少兩倍於處於資料狀態尺之 任何^憶體單元的讀取電流;以及處於資料狀態p之任何 記憶體單元的讀取電流較佳至少兩倍於處於資料狀態§之 任何記憶體單元的讀取電流。舉例而言,在資料狀態尺下 12I890.doc -15· 200818204 之讀取電流可係兩倍於在資料狀態v下之讀取電流;在資 料狀態S下之讀取電流可係兩倍於在資料狀態R下之讀取電 流;及在資料狀態P下之讀取電流可係兩倍於在資料狀態S 下之讀取電流。如果彼等範圍被定義為較小,則差異可能 相當大;舉例而言,如果最高電流V狀態之記憶體單元可 具有5奈安培之讀取電流,以及最低電流R狀態之記憶體單 元可具有1〇〇奈安培之讀取電流,則電流差異將係20之因 數。藉由選擇其它限制,可確保介於相鄰記憶體狀態之間 的讀取電流差異將係至少3之因數。 下文將予以描述。可應用反覆性讀取-驗證-寫入過程, 以確保在一設定脈衝或重設脈衝之後,記憶體單元係處於 經定義之資料狀態中之一者,並且非處於彼等資料狀態之 間。 到目前為止,已論述介於一資料狀態中最高電流與第二 最高相鄰資料狀態中最低電流之間的差異。處於相鄰資料 狀態之大多數記憶體單元的讀取電流之差異仍然較大;舉 例而言,處於V狀態之記憶體單元可具有1奈安培之讀取電 流;處於R狀態之記憶體單元可具有100奈安培之讀取電 流;處於S狀態之記憶體單元可具有2微安培(2000奈安培)之讀 取電流;及處於P狀態之記憶體單元可具有20微安培之讀取電 流。彼等每一相鄰狀態中之電流可相差10或以上之因數。 已描述具有四種相異資料狀態之記憶體單元。為了輔助 辨別資料狀態,選擇三種資料狀態(而非四種資料狀態)可 為較佳方式。舉例而言,一種三狀態式記憶體單元可係形 I2I890.doc -16- 200818204 成為處於資料狀態v、設定至資料狀態p,接著重設至資料 狀態R。此記憶體單元不具有第四資料狀態s。在此情況 中,介於相鄰資料狀態(例如,介於汉與卩資料狀態)之間的 差異可能顯著較大。 如所述程式化一種含如所述之記憶體單元的可單次程式 化記憶體陣列,每一記憶體單元被程式化至三種相異資料 狀怨中之一者(在一具體實施例中)或四種相異資料狀態中 之一者(在一替代具體實施例中)。這些僅係實例;顯然 地,可有三種或四種以上相同電阻率狀態及相對應之資料 狀態。 但疋,在含可單次程式化記憶體單元之記憶體陣列中, 可用各種方式來程式化該等記憶體單元。舉例而言,請參 考圖6,圖2之圮憶體單元可經形成為為處於一第一狀態(v 狀悲)。一第一電脈衝(較佳在正向偏壓下)使破裂反熔絲14 破放且使一極體之複晶矽自一第一電阻率狀態切換至一第 一電阻率狀態(第二電阻率狀態低於第一電阻率狀態);使 5己憶體單70處於p狀態,在此實例中,p狀態係最低電阻率 狀態。一第二電脈衝(較佳在逆向偏壓下)使二極體之複晶 矽自第二電阻率狀態切換至一第三電阻率狀態(第三電阻 率狀態高於第二電阻率狀態),使記憶體單元處於s狀態。 一第二電脈衝(較佳在逆向偏壓下)使二極體之複晶矽自第 二電阻率狀態切換至一第四電阻率狀態(第三電阻率狀態 鬲於第二電阻率狀態),使記憶體單元處於R狀態。對於任 可无疋"己憶體單元’任何資料狀態(V狀態、R狀態、S狀態 121890.doc -17- 200818204 及P狀怨)可被讀取作為該記憶體單元之一資料狀態。圖6 中標示每一轉變。圖中繪示四種相異狀態;視需要,可有 三種或三種以上狀態。 在其它具體實施例中,每一相繼電脈衝可使二極體之半 導體材料切換至一相繼較低電阻率狀態。如圖7中所示, 舉例而言,記憶體單元可自初始V狀態進展至R狀態、自R 狀癌進展至S狀態及自S狀態進展至p狀態,對於每一狀 態,讀取電流係至少兩倍於前一狀態之讀取電流,每者相 對應於一相異資料狀態。此方案可在記憶體單元不包含任 何反熔絲時更有利。在此實例中,在正向偏壓或逆向偏壓 下施加脈衝。在替代具體實施例中,可有三種資料狀態或 四種以上資料狀態。 在一項具體貫施例中,記憶體單元包括圖8所示之複晶 矽或微晶二極體2,該二極體包括底部重摻雜p型區4、中 間本質或輕摻雜區6及頂部重摻雜n型區8。如同先前之具 體實施例中,此二極體2可與一介電破裂反熔絲以串聯方 式排列且佈置於頂部與底部導體之間。底部重摻雜p型區4 可經原位摻雜,即,摻雜方式為,藉由於沉積複晶矽期間 使提供p型摻雜物的氣體(諸如硼)流動,使得摻雜物原子被 併入於隨之形成的薄膜中。 請參考圖9,經發現,此記憶體單元經形成為處於v狀 態,其中在2伏讀取電壓下,介於頂部導體16與底部導體 12之間的電流低於約8〇奈安培。一第一電脈衝(較佳在正 向偏壓下予以施加)使介電破裂反熔絲14 (若有存在)破 121890.doc 200818204The compound 6, the semiconductor diode 2 has an intended undoped; and a bottom heavily doped n-type region 4; an intrinsic region top heavily doped region 8, however the orientation of the diode can be reversed. Regardless of the orientation of the diode, it will be referred to as a diode. In some embodiments, a dielectric rupture antifuse 14 is included. The top conductor 16 can be formed in the same manner and material as the bottom conductor 12 and < different from the first direction in one of the second directions. The polycrystalline semiconductor diode 2 is vertically disposed between the bottom conductor 12 and the top conductor 16. Qiu Fu: The semiconductor diode 2 is formed to be in a high resistivity state. The memory cell can be formed on top of a suitable substrate. For example, a single crystal wafer is overlaid on the wafer. Figure 3 illustrates a portion of the memory level of the device formed in the parent fork memory array, the body 12 and Between the top conductors 16 (in this figure, the memory is stacked on a substrate and the memory array is stacked. The middle diode 2 is arranged in the bottom lead to omit the anti-refining wire 14). A plurality of layers can be formed to form a high density monolithic film. A region of the semiconductor material that is intended to be undoped is described as an _essential region. However, those skilled in the art will appreciate that, in practice, the essence may include - low concentration p-type or n-type dopants. The dopant may extend from adjacent regions into the intrinsic region' or may be due to deposition from earlier deposition during deposition; dyeing is present in the deposition chamber. It should be further understood that the deposited semi-inorganic material (such as % may include defects, causing it to be slightly η-doped, using the term "essence" to describe 矽, 锗, 矽 gold or some other half The ## material is not intended to imply that this region does not contain any dopants' and is not intended to imply this: it is completely electrically neutral. The doped polycrystalline or microcrystalline semiconductor can be made by applying appropriate electrical pulses. 121890.doc 200818204 Material The resistivity of (e.g., 矽) changes between steady states. It has been found that, in a preferred embodiment, it is advantageous to cooperate with the diode to bias forward only under a forward bias, while the diode is It is easier to achieve and control the reset transition under reverse bias. However, in some cases, the diode can be reverse biased to achieve a set transition, and the diode is forward biased to achieve a reset transition. The switching behavior of the semiconductor is complicated. For the diode, the diode has achieved both set transition and reset transition under forward bias. Generally, the reset pulse applied by the one body under forward bias is applied. (its foot The amplitude of the polycrystalline semiconductor material constituting the diode from a predetermined resistivity state to a higher resistivity state is lower than a corresponding set pulse (which switches the same polycrystalline semiconductor material from the same resistivity state) To a lower resistivity state) and have a longer pulse width. Switching under reverse bias exhibits a different behavior. Assume a polycrystalline indiode (like the diode shown in Figure 2) A relatively long switching pulse is applied under reverse bias. After the switching pulse is applied, a smaller read pulse (e.g., 2 volts) is applied, and the measurement flows through a current at the read voltage (referred to as a read current). As the voltage of the switching pulse under reverse bias increases in the post-signal, the subsequent read current is changed by two volts, as shown in Figure 4. It will be understood that initially with the reverse voltage and the switching pulse The electric grab is large, § the read current increases when the read voltage is applied after the mother-switching pulse, that is, the initial turn of the semiconductor material (in this case, the semiconductor material system) in the set direction The variable line is oriented towards a lower resistivity. Once the switching pulse reaches a certain reverse bias voltage (the point in Figure 4, in this example is 121890.doc 200818204 about -14.6 volts), the read current suddenly begins to drop, the reason is achieved Reset and increase the resistivity of the Shishi. When the reverse bias switching pulse is applied, the switching voltage (at this switching voltage, the set trend is reversed and the diode is reset) depends on (for example) The resistivity state of the bismuth of the diode changes. Next, it will be understood that by setting the appropriate voltage, the diode can be set to reverse the bias voltage to achieve the setting or resetting of the semiconductor material constituting the diode. The distinct data state of the memory cell of the present invention corresponds to the resistivity state of the polycrystalline or microcrystalline semiconductor material constituting the diode, which is detected by flowing through the memory cell when a read voltage is applied ( The current between the top conductor 16 and the bottom conductor 12 is discerned. Preferably, the current flowing between any of the distinct data states and any of the different data states is at least 2 factors to allow for differences between states to be easily detectable. The memory unit can be used as a single-programmable memory unit or a rewritable β-single unit, and can have two, three, four or more kinds of sorrows. Under forward bias and reverse bias, the memory cells can be converted from any data state to any other data state in any order. • Several examples of preferred embodiments will be provided. However, it should be understood that they have no limit intent. Those skilled in the art will appreciate that other methods for programming a two-terminal device, including a diode and a polycrystalline or microcrystalline semiconductor material, are within the scope of the present invention. A single-programmed multi-level memory cell 121890.doc -12-200818204 / In the preferred embodiment of the invention - a diode formed by a polycrystalline semiconductor material and a dielectric rupture anti-fuse Arranged in series and arranged between the top and bottom conductors. The two-terminal device is used as a single-programmable multi-bit memory, which is preferably implemented in three or four data states. Figure 2 illustrates a preferred memory unit. The diode 2 is preferably formed of a polycrystalline or micro-conductor material, for example, a stone, a wrong, or a stalk and/or a faulty port. More preferably, the diode 2 is a multi-layered germanium. In this example, the bottom heavily doped region 4 is of the type 11 and the top heavily doped region 8 is shaped, however the polarity of the diode can be reversed. The memory unit includes a portion of the top conductor, a portion of the bottom V body, and a diode disposed between the conductors. When formed, the double crystal body 2 of the polycrystalline silicon is in a high resistivity state, and the 'I electrical cracking reversely soluble filament 14 is intact. Figure 5 is a graph showing the probability of current flow in a memory cell in various states. Referring to FIG. 5, when a read voltage (for example, 2 volts) is applied between the top conductor 16 and the bottom conductor 12 (with the one body 2 under forward bias), the top conductor -6 and the bottom conductor The read current flowing between i 2 is preferably in the range of naamper, for example, less than about 5 nanoamperes. The area v on the graph of Fig. 5 corresponds to the first data state of the memory unit. For some memory cells in the memory array, this memory cell will not be pulsed or reset, and this state will be taken as a data state for one of the memory cells. This first data state will be referred to as the V state. A first electrical pulse is applied (preferably with diode 2 under forward bias) between 121890.doc 13 200818204 between top conductor 16 and bottom conductor 丨2. This pulse is, for example, between about 8 volts and about 12 volts, for example, about 10 volts. The current system is, for example, between about 8 〇 microamperes and about 200 microamperes. The pulse width is preferably between about 1 nanosecond and about 500 nanoseconds. The first electrical pulse causes the dielectric rupture anti-fuse bucket to rupture and switches the semiconductor material of the diode 2 from a first resistivity state to a second resistivity state, the second resistivity state being lower than the first resistance Rate status. This second data state will be referred to as the P state, and this transition is indicated in Figure 5 as "V-P". The current flowing between the top conductor "and the bottom conductor 12 at a read voltage of 2 volts is about 10 microamperes or more. The resistivity of the semiconductor material constituting the diode 2 is reduced by a factor of about 1000 to about 2000. In an embodiment, the change in resistivity is small, but will be at least 2 factor between any data state and any other data state, preferably a factor of at least 3 or 5' and more typically a factor of 100 or more. Some of the memory cells in the memory array will be read by this data state and will not be pulsed or reset by an additional set. This second data state will be referred to as the p state. A second electrical pulse is applied ( Preferably, the diode 2 is placed under reverse bias between the top conductor 16 and the bottom conductor 12. This pulse is, for example, between about _8 volts and about _14 volts, preferably between about -1 The stagnation is between about -12 volts, preferably about -11 volts. The current system is, for example, between about 8 angstroms microamperes and about 2 angstrom microamperes. The pulse width is, for example, between about 100 angstroms. Between nanoseconds and about 10 microseconds, preferably between about 100 nanoseconds and about 1 Between microseconds, more preferably between about 2 nanoseconds and about 800 nanoseconds. This second electrical pulse causes the semiconductor material of the diode 2 to switch from the second resistivity state to a third resistivity. State, third electric 121890.doc -14- 200818204 state is higher than the second resistivity state. The current flowing between the body 16 and the bottom conductor 12 under the 2 volt read electric dust is about H) Amperes and about 5.00 nanoamperes are preferably between about (10) nanoamperes and about 5G0 nanoamperes. The memory cells will be taken from this data state and will not be affected. Additional setting pulse or reset pulse. This third data state will be referred to as R state, and this transition is labeled as "p-R in Figure 5," 'In order to reach the fourth data state, a third electrical pulse is applied ( Preferably, the diode 2 is forward biased between the top conductor 16 and the bottom conductor η. The rush system is, for example, between about 8 volts and about 12 volts (e.g., about a dog). The current system is between about 5 microamperes and about amps. This third electrical pulse causes the bipolar semiconductor material to be from the third resistivity. State transition to - fourth resistivity state 'the first resistivity state is lower than the second resistivity state, and the preferred resistivity is the same as the _th resistivity state. 纟 2 volts read voltage flows to the top conductor 16 and The current between the bottom conductors 12 is between about 5 microamperes and about 4.5 microamps. Some of the memory cells in the memory array will be read by this data state (which will be % s state) and The transition is labeled "R4S" in 5. The difference in current between any two adjacent data states at the read voltage (eg, 2 volts) is preferably at least a factor of 2. For example, it is in the data state. The read current of any memory cell is preferably at least twice the read current of any memory cell in the data state v; the read current of any memory cell in the data state s is preferably at least twice as large as the data. The read current of any memory cell of the state ruler; and the read current of any memory cell in the data state p is preferably at least twice the read current of any memory cell in the data state §. For example, the read current of 12I890.doc -15· 200818204 in the data state ruler can be twice the read current in the data state v; the read current in the data state S can be twice as much as The read current in the data state R; and the read current in the data state P can be twice the read current in the data state S. If the ranges are defined as being small, the difference may be quite large; for example, if the memory cell of the highest current V state can have a read current of 5 nanoamperes, and the memory cell of the lowest current R state can have If the current is read by 1 ampere, the current difference will be a factor of 20. By selecting other limits, it is ensured that the difference in read current between adjacent memory states will be at least a factor of three. This will be described below. A repetitive read-verify-write process can be applied to ensure that the memory cells are in one of the defined data states after a set pulse or reset pulse and are not in the state of their data. So far, the difference between the highest current in a data state and the lowest current in the second highest adjacent data state has been discussed. The difference in read current of most memory cells in the adjacent data state is still large; for example, the memory cell in the V state can have a read current of 1 nanoamperes; the memory cell in the R state can be It has a read current of 100 nanoamperes; a memory cell in the S state can have a read current of 2 microamperes (2000 nanoamperes); and a memory cell in the P state can have a read current of 20 microamperes. The currents in each of their adjacent states may differ by a factor of 10 or more. Memory cells having four distinct data states have been described. In order to assist in identifying the status of the data, it is preferable to select three data states (instead of the four data states). For example, a three-state memory cell can be tied to I2I890.doc -16-200818204 to be in data state v, set to data state p, and then reset to data state R. This memory unit does not have a fourth data state s. In this case, the difference between adjacent data states (for example, between Han and 卩 data states) may be significantly larger. As programmed, a single stylized memory array containing memory cells as described, each memory unit being programmed to one of three distinct data replies (in a particular embodiment) Or one of four distinct data states (in an alternate embodiment). These are merely examples; obviously, there may be three or more identical resistivity states and corresponding data states. However, in a memory array containing a single-programmable memory cell, the memory cells can be programmed in a variety of ways. For example, referring to FIG. 6, the memory cell of FIG. 2 can be formed to be in a first state (v-shaped sadness). A first electrical pulse (preferably under forward bias) causes the rupture antifuse 14 to break and switch the monolayer of the polar body from a first resistivity state to a first resistivity state (second The resistivity state is lower than the first resistivity state; the 5th memory cell 70 is in the p state, in this example, the p state is the lowest resistivity state. A second electrical pulse (preferably under reverse bias) switches the polysilicon of the diode from a second resistivity state to a third resistivity state (the third resistivity state is higher than the second resistivity state) , so that the memory unit is in the s state. A second electrical pulse (preferably under reverse bias) switches the polysilicon of the diode from a second resistivity state to a fourth resistivity state (the third resistivity state is in a second resistivity state) , so that the memory unit is in the R state. Any data state (V state, R state, S state 121890.doc -17-200818204 and P-like complaints) can be read as one of the data states of the memory unit. Each transition is labeled in Figure 6. The four different states are shown in the figure; there may be three or more states as needed. In other embodiments, each successive electrical pulse can switch the semiconductor material of the diode to a successive lower resistivity state. As shown in FIG. 7, for example, the memory cell can progress from the initial V state to the R state, from the R-shaped cancer to the S state, and from the S state to the p state, for each state, the current system is read. At least twice the read current of the previous state, each corresponding to a different data state. This scheme is more advantageous when the memory unit does not contain any antifuse. In this example, a pulse is applied under forward bias or reverse bias. In alternative embodiments, there may be three data states or more than four data states. In a specific embodiment, the memory cell includes a polycrystalline germanium or microcrystalline diode 2 as shown in FIG. 8, and the diode includes a bottom heavily doped p-type region 4, an intermediate or lightly doped region. 6 and top heavily doped n-type region 8. As in the previous specific embodiment, the diode 2 can be arranged in series with a dielectric rupture antifuse and disposed between the top and bottom conductors. The bottom heavily doped p-type region 4 may be doped in situ, that is, by doping the dopant atoms by flowing a gas (such as boron) that supplies a p-type dopant during deposition of the germanium. Incorporate into the film that is formed. Referring to Figure 9, it has been found that the memory cell is formed in a v state wherein the current between the top conductor 16 and the bottom conductor 12 is less than about 8 nanoamperes at a read voltage of 2 volts. A first electrical pulse (preferably applied under a forward bias) causes the dielectric rupture antifuse 14 (if present) to break. 121890.doc 200818204

!:並且使二極體2之複晶石夕自-第-電阻率狀態切換至 弟-電阻率狀態(第二電阻率狀態低於第一電阻率狀 態);使記憶體單元處於資料狀態P。在資料狀態?中,在 項取電壓下介於頂部導體16與底部導體12之間的電流係約 1微安培與約4微安培之間。—第二電脈衝(較佳在逆向偏 壓下予以施加)使二極體2之複晶石夕自第二電阻率狀態切換 =三電阻率狀態,第三電阻率狀態低於第一電阻率狀 悲。第三電阻率狀態對應於資料狀態M。在資料狀態Μ 卜在讀取電壓下介於頂部導體16與底部導體以間的電 流係約10微安培。如同先前之具體實施例中,介於相鄰資 料狀恶之任何記憶體單元之間(介於V狀態之最高電流記憶 體單元與Ρ狀態之最低電流記憶體單元之間,或介於?狀態 之最高電流記憶體單元與Μ狀態之最低電流記憶體單元之 間)的電流差異較佳係至少2之因數,較佳係3或以上之因 數。任何資料狀態(V、Ρ或Μ)皆可被偵測為該記憶體單元 之一資料狀態。 圖4展現出當半導體二極體經受逆向偏壓時,一般而 言’半導體材料初始時歷經至較低電阻率之設定轉變,接 著,隨著電壓增大,歷經至較高電阻率之重設轉變。對於 此特定二極體,運用頂部重摻雜η型區8,並且較佳運用藉 由用Ρ型摻雜物原位摻雜所形成之底部重摻雜區4,隨著增 大中之逆向偏壓而自設定轉變切換至重設轉變不會如同其 它具體實施例之二極體一樣突然或急劇地發生。此意謂著 運用此二極體較易於控制在逆向偏壓下之設定轉變。 121890.doc -19- 200818204 可重寫記憶體單元 在二具體實施例中,記憶體單元作用為可重寫記憶體 70 ,、可重複切換於兩種或三種資料狀態之間。 圖10繪示可作為可重寫記憶體單元之記憶體單元。 憶體單元相同於圖2所干之士障f置 ^、體早兀,惟不包含介電破 衣、、、除外。A多數可重寫具體實施例在記憶體單元不 包:反熔絲、然而若需要,可包含一個反熔絲。 :::圖u,在第一較佳具體實施例中,記憶體單元係 為處於兩電阻率狀態V’而在2伏下之電流約5奈安培 二,下肖於大多數可重寫具體實施例,初始V狀態不用 作為記憶體單元之-資料狀態。施加—第_電脈衝(較佳 配合一極體2在正向偏壓下)於頂部導體16與底部導體η之 間。此脈衝係(例如)介於約8伏與約12伏之間,較佳⑽ 伏。此第-電脈衝使二極體2之半導體材料自一第一電阻 率狀態切換至一第二電阻率狀態,第二電阻率狀態低於第 :電阻率狀態。在較佳具體實施例中,ρ狀態亦不用作為 5己k'體早兀之一資料狀態。在其它具體實施例中,ρ狀態 將用作為記憶體單元之一資料狀態。 ^ 施加一第二電脈衝(較佳配合二極體2在逆向偏壓下)於 頂部導㈣與底部導體12之間。此脈衝係(例如)介於約_8 伙與約-14伏之間,較佳介於約_9伏與約_13伏之間,更佳 係約或]0伏七伏。所要求之電壓將隨本質區之厚度而二 化。此第二電脈衝使二極體2之半導體材料自第二電阻率 狀態切換至-第三電阻率狀態R,第三電阻率狀態高於第 121890.doc -20- 200818204 一電阻率狀態。在較佳且濟每 隹罕乂仏,、體“也例中,R狀態對應於記憶 體早元之一資料狀態。 ▲可施加-第三電脈衝於頂部導體16與底部導體12之間, 較佳在正向偏壓下。此脈衝係(例如)介於約Μ伏與約9伏 =間仏約6·5伏’而電流係介於約職安培與約彻微 :坨之間,較佳係約5〇微安培與約ι〇〇微安培之間。此第 三電:衝使二極體2之半導體.材料自第三電阻率狀態㈣換 至一弟四電阻率狀態S,第四電阻率狀態低於第三電阻率 狀態。在較佳具體實施例中,s狀態對㈣記憶體單元之 一資料狀態。 在此可重寫、兩狀態具體實施例中,感測或讀取r狀態 與S狀態以作為資料狀態。記憶體單元可重複切換於該兩 種狀態之間。舉例而士, 银 _ ^ 牛例而θ,一弟四電脈衝(較佳配合二極體2 在逆向偏壓下)使二極體之半導體材料自第四電阻率狀態s ㈣至第五電阻率狀態R(其實質上相同於第三電阻鄉 第五電脈衝(較佳配合二極體2在正向偏壓下)使二極體之 半導體材料自第五電阻率狀態R切換至第六電阻率狀態 S(其實質上相同於第四電阻率8),以此類推。可能更難以 使記憶體單元返回初始V狀態與第二P狀態;因此,在可重 寫記憶體單元中,姑望业能1 + τ彼4狀悲可能未用作為資料狀態。可能 較佳方式為,在記憶體陣列到達使用者之前(例如,在製 造廢或測試設施中),實行第-電脈衝(其使記憶體單元自 初始他V狀怨切換至?狀態)及第二電脈衝(其使記憶體單元自 Ρ狀I、切換至R狀態)兩者。在其它具體實施例中,可能較 121890.doc -21- 200818204 么方式為’在記憶體陣列到達使用者之前,僅實行第一電 脈衝(其使圯憶體單元自初始v狀態切換至p狀態)。 如圖11所示,在提供的實例中,介於處於一資料狀態中!: and switch the helium-first-resistivity state of the diode 2 to the dipole-resistivity state (the second resistivity state is lower than the first resistivity state); leaving the memory cell in the data state P . In the status of the data? The current between the top conductor 16 and the bottom conductor 12 at a voltage is between about 1 microamperes and about 4 microamperes. - a second electrical pulse (preferably applied under reverse bias) causes the double crystal of the diode 2 to switch from the second resistivity state = a three resistivity state, the third resistivity state being lower than the first resistivity Sad. The third resistivity state corresponds to the data state M. In the data state, the current between the top conductor 16 and the bottom conductor is about 10 microamperes at the read voltage. As in the previous embodiment, between any memory cells of adjacent data (between the highest current memory cell in the V state and the lowest current memory cell in the Ρ state, or between? The difference in current between the highest current memory cell and the lowest current memory cell in the erbium state is preferably at least 2, preferably 3 or more. Any data status (V, Ρ or Μ) can be detected as one of the data status of the memory unit. Figure 4 shows that when the semiconductor diode is subjected to a reverse bias, generally the 'semiconductor material initially undergoes a set transition to a lower resistivity, and then, as the voltage increases, the reset to a higher resistivity is experienced. change. For this particular diode, the top heavily doped n-type region 8 is used, and the bottom heavily doped region 4 formed by in-situ doping with a germanium dopant is preferably used, with an increase in the reverse direction. Switching from a set transition to a reset transition with a bias voltage does not occur suddenly or abruptly like the diodes of other embodiments. This means that it is easier to control the set transition under reverse bias using this diode. 121890.doc -19- 200818204 Rewritable Memory Unit In a second embodiment, the memory unit acts as a rewritable memory 70, and can be repeatedly switched between two or three data states. FIG. 10 illustrates a memory unit that can function as a rewritable memory unit. The memory unit is the same as the one shown in Figure 2, and the body is early, except for dielectric breaks. A majority of the rewritable embodiments do not include in the memory unit: an anti-fuse, but if desired, an anti-fuse. ::: Figure u, in the first preferred embodiment, the memory cell is in the two resistivity state V' and the current at 2 volts is about 5 nanoamperes. In the embodiment, the initial V state is not used as the data state of the memory unit. An -first electrical pulse (preferably with a body 2 under forward bias) is applied between the top conductor 16 and the bottom conductor η. This pulse is, for example, between about 8 volts and about 12 volts, preferably (10) volts. The first electrical pulse causes the semiconductor material of the diode 2 to switch from a first resistivity state to a second resistivity state, the second resistivity state being lower than the first: resistivity state. In a preferred embodiment, the ρ state is also not used as one of the data states of the 5' k' body. In other embodiments, the ρ state will be used as a data state for one of the memory cells. ^ A second electrical pulse is applied (preferably with the diode 2 under reverse bias) between the top conductor (four) and the bottom conductor 12. The pulse is, for example, between about _8 gangs and about -14 volts, preferably between about _9 volts and about _13 volts, more preferably about 0 volts. The required voltage will be diversified with the thickness of the intrinsic zone. The second electrical pulse causes the semiconductor material of the diode 2 to switch from the second resistivity state to the third resistivity state R, the third resistivity state being higher than the resistivity state of the 121890.doc -20-200818204. In a preferred embodiment, the R state corresponds to a data state of the memory early element. ▲ A third electrical pulse can be applied between the top conductor 16 and the bottom conductor 12, Preferably, under forward bias, the pulse is, for example, between about 90 volts and about 9 volts = about 6.5 volts and the current is between about ampere and about ruthenium: Preferably, it is between about 5 〇 micro ampere and about ι 〇〇 micro ampere. The third electricity: the semiconductor of the diode 2 is switched from the third resistivity state (4) to the fourth resistivity state S, The fourth resistivity state is lower than the third resistivity state. In a preferred embodiment, the s state pairs (4) one of the memory cells is in a data state. In this rewritable, two-state embodiment, sensing or reading The r state and the S state are taken as the data state. The memory cell can be repeatedly switched between the two states. For example, Shih, silver _ ^ bovine case and θ, one brother four electric pulse (better with diode 2 Under reverse bias, the semiconductor material of the diode is from a fourth resistivity state s (four) to a fifth resistivity state R (its substantially phase Same as the fifth electric pulse of the third resistor town (preferably with the diode 2 under forward bias), the semiconductor material of the diode is switched from the fifth resistivity state R to the sixth resistivity state S (the essence thereof) The same as the fourth resistivity 8), and so on. It may be more difficult to return the memory cell to the initial V state and the second P state; therefore, in the rewritable memory cell, the hopeful industry can 1 + τ 4 sorrow may not be used as a data state. It may be preferable to perform a first-electric pulse (which causes the memory unit to self-initial before the memory array reaches the user (for example, in a manufacturing waste or test facility) V-response switches to the "state" and the second electrical pulse (which causes the memory cell to switch from the I state to the R state). In other embodiments, it may be more than 121890.doc -21-200818204 To perform only the first electrical pulse (which causes the memory cell to switch from the initial v state to the p state) before the memory array reaches the user. As shown in Figure 11, in the example provided, Data status

之任何5己憶體單元與處於相鄰資料狀態(在此情況中,係R 貢料狀態(介於約10奈安培與500奈安培之間)與R資料狀態 (介於約1 ·5微安培與4·5微安培之間))之任何記憶體單元之 • 間的介於頂部導體16與底部導體12之間在讀取電壓(例如2 伏)下机動的電流之間的差異係至少3之因數。取決於對於 所一資料狀態所選擇之範圍,該差異可能係2、3、5或以 上之因數。 在替代具體實施例中,一種可重寫記憶體單元可依任何 順序切換於三種或三種以上資料狀態之間。可配合二極體 在正向偏壓或逆向偏壓下來實行設定轉變或重設轉變。 在所描述之單火可程式化具體實施例與可重寫具體實施 例兩者中,指明資料狀態對應於構成二極體之複晶或微晶 _ 半導體材料的電阻率狀態。資料狀態不對應於電阻率切換 金屬氧化物或氮化物之電阻率狀態,如同Herner等人於 6年3月31日巾δ月之美國專利申請案第號 - nN_〇latile Memorym C〇mprising a Di〇de and aAny of the 5 memory cells are in a state of adjacent data (in this case, the R tributary state (between about 10 nanoamperes and 500 nanoamperes) and the R data state (between about 1 · 5 micro The difference between the current between the top conductor 16 and the bottom conductor 12 between the readout voltage (eg, 2 volts) between any of the memory cells between amps and 4.5 microamperes)) is at least The factor of 3. Depending on the range selected for the state of the data, the difference may be a factor of 2, 3, 5 or more. In an alternate embodiment, a rewritable memory unit can be switched between three or more data states in any order. The set transition or reset transition can be implemented with the diode in forward bias or reverse bias. In both the single fire programmable embodiment and the rewritable embodiment described, the data state is indicated to correspond to the resistivity state of the polycrystalline or microcrystalline semiconductor material constituting the diode. The data state does not correspond to the resistivity switching metal oxide or nitride resistivity state, as described in Herner et al., US Patent Application No. - nN_〇latile Memorym C〇mprising a Di〇de and a

ReSiStanCe-Switching M攸rial”中之描述,該案由本發明受 讓人所擁有並且特此以引用方式併入本文中。 逆向偏壓設定與重設 在到目前為止描述之根據具體實施例形成及程式化之記 憶體單元陣列中,記憶體單元在逆向偏壓中經受到大電麼 121890.doc -22- 200818204 的任何步驟已相較於逆向偏壓步驟使洩漏電流減小。 請參考圖12,假設跨所擇記憶體單元8施加正向偏壓之 10伏。(待使用之實際電壓將取決於許多因素,其包括記 憶體單元之構造、摻雜物量、本質區高度等等;丨〇伏僅僅 係實例)。位元線B0被設定至1〇伏’並且字線被設定至 接地。為了確保半所擇記憶體單元1?(其與.所擇記憶體單元 , S共用位元線B0)維持低於二極體之開通電壓,字線冒丨被 5又疋至低於但相當接近位元線B〇之電壓;舉例而言,字線 ⑩ W1可被設定至9·3伏,使得跨記憶體單元F施加〇·7伏(圖中 僅繪示一個記憶體單元F,但可有數百、數千或以上卜同 樣地,為了確保半所擇記憶體單元H(其與所擇記憶體單元 S共用字線W0)維持低於二極體之開通電壓,位元線扪被 σ又疋至同於但相當接近字線w〇之電壓;舉例而言,位元 線Β1可被設定至〇·7伏,使得跨記憶體單施加伏(再 火可有數千個七憶體單元Η)。非所擇記憶體單元U(其不 • 與所擇記憶體單元8共用纟線W0,Φ +共同位元線Β0)經 受到-8.6伏。由於可有數百萬個非所擇記憶體單元口,而 導致§己憶體陣列内顯著的线漏電流。 ‘ 圖13繪示跨記憶體單元施加大逆向偏壓(例如,作為重 ㈣衝)之有利加偏壓方案。位元線B0被設定至_5伏,並 且字線W0被設定至5伏’使得跨所擇記憶體單元s施加, 伏,二極體係處於逆向偏壓中。以不足以使非刻意設定或 重設半所擇記憶體單元的低逆向偏壓,設定字線们 與位元線B1至接地,使半所擇記憶體單元經受_5伏。 121890.doc -23- 200818204 一般而言’以逆向偏壓進行設定或重設似乎發生在或接近 使二極體轉變成逆向擊穿之電壓(其一般高於_5伏)。 運用此方案,使無跨非所擇記憶體單元u之電壓,導致 …、逆向洩漏。結果,如(舉例而言)SAeueriein等人連同本 案同曰申請且早先以引用方式併入本文中之美國專利申請 案第 11/461,352 號 ”Dual Data-Dependent Busses for Coupling Read/Write Circuits to a Memory Array”(代理人 檔案號碼第023-0051號)中之進一步描述,可顯著增大頻 寬。 圖13之加偏壓方案僅僅係實例;顯然地,可使用許多其 匕方案。舉例而言,位元線B0可被設定至〇伏,字線|〇可 被設定至-10伏,以及位元線B1與字線W1可被設定至 伏。在圖13之方案中,跨所擇記憶體單元s、半所擇記憶 體單το Η與F以及非所擇記憶體單元u之電壓將相同。在另 一項實例中,位元線Β〇可被設定至接地,字線w〇可被設 定至10伏,以及位元線B1與字線W1可被設定至5伏。 反覆式設定與重設 到目如為止,此論述已描述施加一適當電脈衝,以使二 極體之半導體材料自一電阻率狀態切換至一不同電阻率狀 態’因此使記憶體單元切換於兩種相異資料狀態之間。實 務上’彼等設定步驟與重設步驟可係反覆式處理程序。 如所述,介於在相鄰資料狀態中於讀取期間流動之電流 之間的差異較佳係至少2之因數;在許多具體實施例中, 可能較佳方式為,建置每一資料狀態之電流範圍,並且相 12I890.doc -24- 200818204 隔3、5、1〇或以上之因數。 請參考圖14,如所述,以2伏讀取電壓,資料狀態V可被 定義為5奈安培或以下之讀取電流,資料狀態R可被定義為 約1〇奈安培與約500奈安培之間,資料狀態S可被定義為約 1.5微安培與約4.5微安培之間,及資料狀態P可被定義為高 於約10微安培。熟悉此項技術者應明白彼等僅係實例。在 另一具體實施例中,舉例而言,資料狀態V可被定義於較 小範圍内,其中以2伏讀取電壓,讀取電流為5奈安培或以 下。實際讀取電流將隨記憶體單元之特性、記憶體陣列之 構造、所擇讀取電壓及許多其它因素而變化。 假定可單次程式化記憶體單元係處於資料狀態P。施加 逆向偏壓之電脈衝至記憶體單元,使記憶體單元切換至資 料狀態S。但是,在一些案例中,可能在施加電脈衝之後 讀取電流非處於所要範圍中;即,二極體之半導體材料之 電阻率狀態高於或低於所要狀態。舉例而言,假定在施加 電脈衝之後,記憶體單元之讀取電流係處於圖表上所示之 Q點,介於S狀態與P狀態電流範圍之間中。 施加電脈衝以使記憶體單元切換至所要資料狀態之後, 可讀取記憶體單元以判定是否抵達所要資料狀態。如果抵 達所要資料狀態,則施加額外脈衝。舉例而言,當感測到 電流Q時,施加額外重設脈衝以增大半導體材料之電阻 率、減小讀取電流進入相對應於s資料狀態之範圍中。如 上文所述’可在正向偏壓或逆向偏壓下施加此設定脈衝。 額外脈衝的振幅(電壓或電流)之脈衝寬度可長於或短於原 I21890.doc -25- 200818204 始脈衝。在額外設定脈衝後,再次讀取記憶體單元,接著 適當地施加設定脈衝或重設脈衝,直到讀取電流係處於所 要範圍中。 在兩端子式裝置(諸如包括所描述之二極體的記憶體單 元)中,這將特別有利於進行讀取以驗證設定或重設及進 行調整(若需要)。跨二極體施加大逆向偏壓可使二極體受 損;因此,當配合二極體在逆向偏壓下來實行設定或重設 時,最小化逆向偏壓電壓係有利的做法。 製造考量The description of ReSiStanCe-Switching M攸rial, which is owned by the assignee of the present invention and incorporated herein by reference in its entirety herein. In the memory cell array, the memory cell is subjected to a large voltage in the reverse bias voltage. 121890.doc -22-200818204 has reduced the leakage current compared to the reverse bias step. Referring to FIG. It is assumed that 10 volts of forward bias is applied across the selected memory cell 8. (The actual voltage to be used will depend on a number of factors, including the configuration of the memory cell, the amount of dopant, the height of the nature region, etc.; Just an example). Bit line B0 is set to 1 〇' and the word line is set to ground. To ensure half-selected memory unit 1 (which is the same as the selected memory unit, S shares bit line B0) Maintaining a lower turn-on voltage than the diode, the word line is further reduced to 5 but below the voltage of the bit line B〇; for example, the word line 10 W1 can be set to 9·3 volts. Applying cross-memory unit F to 7 volts (only one memory cell F is shown in the figure, but there may be hundreds, thousands or more. Similarly, in order to ensure a half-selected memory cell H (which shares the word line W0 with the selected memory cell S) Maintaining a turn-on voltage lower than the diode, the bit line 扪 is again σ to the same voltage but quite close to the word line w〇; for example, the bit line Β1 can be set to 〇·7 volts, so that Applying volts across the memory (reciprocal fire can have thousands of seven memory elements Η). Unselected memory unit U (which does not share the 纟 line W0, Φ + common bit line with the selected memory unit 8 Β0) is subjected to -8.6 volts. Since there are millions of unselected memory cell ports, significant line leakage currents in the § memory array are caused. ' Figure 13 shows a large reverse bias across the memory cells. A favorable biasing scheme for voltage (for example, as a heavy (four) rush). Bit line B0 is set to _5 volts, and word line W0 is set to 5 volts' such that it is applied across the selected memory cell s, volts, two The pole system is in reverse bias, so as not to deliberately set or reset the low reverse bias of the selected memory cell. The word lines and bit line B1 are grounded to subject the half-selected memory cell to _5 volts. 121890.doc -23- 200818204 Generally speaking, setting or resetting with reverse bias seems to occur at or near two The polar body transforms into a reverse breakdown voltage (which is generally higher than _5 volts). Using this scheme, the voltage across the unselected memory cell u is caused, causing ..., reverse leakage. The result, for example, for example U.S. Patent Application Serial No. 11/461,352, entitled "Dual Data-Dependent Busses for Coupling Read/Write Circuits to a Memory Array", filed by the same application in the present application. Further description in the number No. 023-0051 can significantly increase the bandwidth. The biasing scheme of Figure 13 is merely an example; obviously, many of its schemes can be used. For example, bit line B0 can be set to ramp, word line |〇 can be set to -10 volts, and bit line B1 and word line W1 can be set to volts. In the scheme of Fig. 13, the voltage across the selected memory cell s, the half-selected memory cells το Η and F, and the unselected memory cell u will be the same. In another example, the bit line Β〇 can be set to ground, the word line w 〇 can be set to 10 volts, and the bit line B1 and the word line W1 can be set to 5 volts. Repetitive setting and resetting to the point, this discussion has described the application of an appropriate electrical pulse to switch the semiconductor material of the diode from a resistivity state to a different resistivity state ' thus switching the memory cell to two Between different data states. In practice, the setting steps and resetting steps can be repeated procedures. As mentioned, the difference between the currents flowing during the reading in the adjacent data state is preferably a factor of at least 2; in many embodiments, it may be preferred to set each data state. The current range, and the phase 12I890.doc -24- 200818204 is a factor of 3, 5, 1 or more. Referring to FIG. 14, as described, the voltage is read at 2 volts, and the data state V can be defined as a read current of 5 nanoamperes or less. The data state R can be defined as about 1 nanoamperes and about 500 nanoamperes. Between the data states S can be defined as between about 1.5 microamperes and about 4.5 microamps, and the data state P can be defined as greater than about 10 microamperes. Those skilled in the art should understand that they are merely examples. In another embodiment, for example, the data state V can be defined in a smaller range, wherein the voltage is read at 2 volts and the read current is 5 nanoamperes or less. The actual read current will vary with the characteristics of the memory cell, the configuration of the memory array, the selected read voltage, and many other factors. It is assumed that the single-programmed memory cell is in the data state P. A reverse biased electrical pulse is applied to the memory cell to switch the memory cell to the data state S. However, in some cases, the read current may not be in the desired range after the application of the electrical pulse; that is, the resistivity state of the semiconductor material of the diode is above or below the desired state. For example, assume that after applying an electrical pulse, the read current of the memory cell is at the Q point shown on the graph, between the S state and the P state current range. After an electrical pulse is applied to switch the memory cell to the desired data state, the memory cell can be read to determine if the desired data state is reached. If the desired data status is reached, an additional pulse is applied. For example, when current Q is sensed, an additional reset pulse is applied to increase the resistivity of the semiconductor material, reducing the read current into a range corresponding to the s data state. This set pulse can be applied under forward or reverse bias as described above. The pulse width of the amplitude (voltage or current) of the extra pulse can be longer or shorter than the original I21890.doc -25- 200818204 start pulse. After the additional set pulse, the memory cell is read again, and then the set pulse or reset pulse is applied as appropriate until the read current is in the desired range. In a two-terminal device, such as a memory unit including the described diodes, this would be particularly advantageous for reading to verify settings or resets and adjustments if needed. Applying a large reverse bias across the diode can damage the diode; therefore, it is advantageous to minimize the reverse bias voltage when the mating diode is set or reset in reverse bias. Manufacturing considerations

Hemer等人於2006年6月8曰申請之美國專利申請案第 11/148,530號’’Nonvolatile Memory Cell Operating by Increasing Order in Polycrystalline Semiconductor Material·1 ;及 Herner於 2004年9月29日申請之美國專利申請案第10/954,5 10號 "Memory Cell Comprising a Semiconductor Junction Diode Crystallized Adjacent to a Silicide”(彼等案皆由本發明受 讓人所擁有並且特此皆以引用方式併入本文中),描述相 鄰於適當矽化物之複晶矽之結晶化影響複晶矽之屬性。某 些金屬矽化物(諸如矽化鈷與矽化鈦)之晶格結構非常接近 矽之晶格結構。當非晶系或微晶矽經結晶化成接觸於彼等 矽化物中之一者時,在結晶化期間,矽化物之晶格結構為 矽提供模版。所得複晶矽將經高度定序,並且缺陷相當 低。當用導電率增強摻雜物予以摻雜時,此高品質複晶矽 在形成時具相當高傳導性。 相比之下,當非晶系或微晶矽材料經結晶化成未接觸於 121890.doc -26- 200818204 具有矽化物(此矽化物之晶格良好匹配於矽)之矽時,舉例 而言’僅接觸於諸如二氧化矽與氮化鈦(二氧化矽與:化 鈦之晶格顯著不匹配於矽),則所得複晶矽將具有許多更 大程度之缺陷,並且以J;卜方:έ士曰/μ λ- 卫1以此方式結日日化之經摻雜複晶矽在形 成時將非常低之傳導性。。 在本發明態樣中,形成二極體之半導體材料切換於兩種 或兩種以上電阻率狀態之間’在既定讀取電壓下改變流動U.S. Patent Application Serial No. 11/148,530, the entire disclosure of which is hereby incorporated by reference in its entirety, the entire entire entire entire entire entire entire entire entire entire content Application Nos. 10/954, 5 10 "Memory Cell Comprising a Semiconductor Junction Diode Crystallized Adjacent to a Silicide" (all of which are owned by the assignee of the present invention and are hereby incorporated by reference) The crystallization of the polycrystalline germanium adjacent to the appropriate telluride affects the properties of the polycrystalline germanium. The lattice structure of certain metal halides (such as cobalt telluride and titanium telluride) is very close to the lattice structure of germanium. When the microcrystalline germanium is crystallized to contact one of the tellurides, during the crystallization, the lattice structure of the telluride provides a template for the germanium. The resulting germanium will be highly ordered and the defects are rather low. When doped with a conductivity-enhancing dopant, the high-quality polysilicon is relatively highly conductive when formed. In contrast, when amorphous or microcrystalline The material is crystallized to be in contact with 121890.doc -26- 200818204 with a telluride (the crystal lattice of this telluride is well matched to ruthenium), for example, 'only in contact with such as ruthenium dioxide and titanium nitride (two The yttrium oxide and the crystal lattice of titanium do not significantly match 矽), then the resulting ruthenium ruthenium will have many defects of a greater degree, and J; B: έ士曰/μ λ- 卫1 The doped polysilicon in the daytime will have very low conductivity when formed. In the aspect of the invention, the semiconductor material forming the diode is switched between two or more resistivity states. Change flow at a given reading voltage

通過二極體之電流’不同的電流(與電阻率狀態)相對應於 相異之資料狀態。經發現,由相鄰於%化物或提供結晶化 杈板之類似材料而尚未結晶化的高度缺陷矽(或其它適當 的半導體材料,諸如鍺切·鍺合金)所形成的二極體展現 出更有利的切換行為。 不希望受約束於任何特定理論,據信,支持所觀察電阻 率文變的項可旎機制在於,高於臨限振幅的設定脈衝致 使払雜物原子移出晶界(此處摻雜物原子為非活性)進入晶 體主體(此處摻雜物原子將增大傳導率且降低半導體材料 之電阻)。相比之下,重設脈衝可致使摻雜物原子移回晶 界降低傳導率且增大電阻。但是,可能亦有其它機制運 作或作為替代,諸如複晶材料定序程度增大或減小。 經發現,相鄰於適當矽化物之經結晶化極低缺陷矽的電 阻率狀態無法如同當半導體材料具有較高程度缺陷時一樣 易於切換。缺陷存在或大量晶界存在可能允許較易於切 Γ。在較佳具體實施<列中H,形成二極體之複晶或微 曰曰材料未經結晶化而相鄰於與其具有小晶格不匹配的材 121890.doc -27 - 200818204 料。小晶袼不匹配係(舉例而言)約百分之3或以下之晶袼不 匹配。 證據已建議切換行為可集中於本質區中之改變。已在電 阻器與p-i-n二極體中觀察切換行為,並且非限於p_i_n二極 冑’但是使用卜卜11二極體可能特別有利。@目前為止描述 之具體實施例包括p_i_n二極體。但是,在其它具體實施例 • 巾’二極體可代替地係P-n二極體,並且具有微不足道或 無本質區。 籲 冑提供描述製造本發明較佳具體實施例之詳細實例。The current through the diode 'different' (corresponding to the resistivity state) corresponds to a different data state. It has been found that a diode formed by a highly defective germanium (or other suitable semiconductor material such as a tantalum-bismuth alloy) that is not crystallized adjacent to a compound or a similar material that provides a crystallized tantalum plate exhibits a greater Favorable switching behavior. Without wishing to be bound by any particular theory, it is believed that the mechanism that supports the observed resistivity variability is that a set pulse above the threshold amplitude causes the dopant atoms to move out of the grain boundary (where the dopant atoms are Inactive) enters the crystal body (where dopant atoms will increase conductivity and reduce the resistance of the semiconductor material). In contrast, resetting the pulses can cause the dopant atoms to move back to the grain boundaries to reduce conductivity and increase electrical resistance. However, there may be other mechanisms to operate or as an alternative, such as increasing or decreasing the degree of sequencing of the polycrystalline material. It has been found that the state of resistivity of the crystallized very low defect 相邻 adjacent to the appropriate telluride is not as easy to switch as when the semiconductor material has a higher degree of defects. The presence of defects or the presence of a large number of grain boundaries may allow for easier cutting. In a preferred embodiment <column H, the polycrystalline or micro-ruthenium material forming the dipole is not crystallized adjacent to the material having a small lattice mismatch with it. 121890.doc -27 - 200818204. The twins do not match, for example, about 3 percent or less of the wafers do not match. Evidence has suggested that switching behavior can focus on changes in the essential area. The switching behavior has been observed in the resistor and the p-i-n diode, and is not limited to p_i_n diode 胄' but the use of the Bub 11 diode may be particularly advantageous. The specific embodiment described so far includes the p_i_n diode. However, in other embodiments, the 'diode' may alternatively be a P-n diode and have negligible or no intrinsic regions. The detailed description of the preferred embodiments of the invention is set forth.

Herner等人於2002年12月19曰申請之美國專利申請案第 10/320,470 ft "An Improved Method for Making High Density Nonvolatile Memory"(並且由於被放棄,此以引用 方式併入本文中)中&出的製造細節將有助於以來自,$衫申 請案之資訊來形成彼等具體實施例之二極體。亦可自 Hemer等人於2〇〇4年12月17曰申請之美國專利申請案第 φ 11/〇15,824 號"N〇nV〇latile Mem〇ry Cell Comprising a Reduced Height Vertical Diode"(該案由本發明受讓人所擁 有並且特此以引用方式併入本文中)導出有用的資訊。為 - 了避免混淆本發明,將不納含來自彼等申請案的所有細 節,但是應明白,未意圖排除來自彼等申請案的資訊。 範例 將詳細製造單-記憶體層級。可堆疊額外記憶體層級, 每一者以單片方式形成於在其下方之記憶體層級的上方。 在此具體實施例中,複晶半導體二極體將用作為可切換記 121890.doc -28 - 200818204 憶體元件。 e月參考圖l5a,記憶體之形成開始於基板⑽。此基板 100可係此項技術所% 4 ^ , 斤无、知之任何半導基板,諸如單結晶 石夕IV-IV化合物(如石广鍺或石夕务碳)、瓜乂化合物、& VII化合物、在此黧|, 寺基板上的磊晶層或任何其它半導材 料。基板可包括經製造於其中的積體電路。 在基板100上形成一絕緣層102。絕緣層102可係氧化 矽、I化石夕、高介電膜、Si-C-O-H膜或任何其它適合絕緣 材料。 在基板與絕緣體上古游> » _ ^ 上方形成弟一導體2〇〇。可在絕緣層1〇2 與傳導層106之間句杠一机# α ^ 括黏者層1〇4,以協助傳導層1〇6黏 著於絕緣層1 02。如要μ、皆β少 果上伙傳導層係鎢,則較佳係氮化鈦 作為黏著層104。 接下來待沉積之展在#措g • 、曰係傳V層106。傳導層106可包括此項 技術所^知之任何傳導層材料,諸㈣或其它材料,包括 鈕、鈦、銅、鈷或其任何合金。 -已/儿積將形成導體軌的所有層’將使用任何適合的 :“、與蝕刻製程來圖案化及蝕刻彼等層,以形成實質上平 行、:質上共面導體2〇〇,如圖…之剖面圖所示:在一項 具體實施例中,沉藉亦 、 積先阻,並且精由微影及彼等經蝕刻之 層來圖案化該光阻,并* 光阻。可❹。 接吏用標準製程技術來移除該 °曰代地糟由鑲嵌方法來形成導體200。 接下來,在導體軌2〇〇 介電材料⑽可伟任竹p4 L積—介電材料108。 係任何已知之電絕緣材料,例如,氧化 121890.doc -29- 200818204 矽氮化矽及/或氮氧化矽。在一較佳具體實施例中,可 使用一氧化矽作為介電材料1 。 取後’移除位於導體軌200最頂部上過量的介電材料 108 ’曝露出藉由介電材料108來分隔之導體軌200之最頂 部,並且留下實質上平坦表面109。圖15a繪示所得結構。 藉由此項技術所熟知之任何製程(諸如化學機械拋光(CMP) 或回蝕)來實行過填充(overfill)介電之移除,以形成平坦表 ⑩ 面109。可有利使用的回蝕的技術描述於Raghuram等人於 2004年6月30日提出之美國專利申請案第1〇/883417號 nNonselective Unpatterned Etchback to Expose Buried Pattemed Features”,並且特此以引用方式併入本文中。在 匕P白#又已在基板上以第一高度形成複數個實質上平 行之第一導體。 接下來,請參考圖15b,將在完成之導體執2〇〇上方形成 垂直柱。(為了節省空間,圖15b中未繪示出基板1〇〇;將 _ 認定有基板存在)。較佳方式為,沉積一障壁層110以作為 繼平坦化導體執之後的第一層。可在障壁層中使用任何適 合之材料,包括氮化鎢、氮化鈕、氮化鈦或彼等材料之組 • 合。在一較佳具體實施例中,使用氮化鈦作為障壁層。若 P早壁層係氮化鈦,則可依相同於上文所述之沉積黏著層的 方式來沉積障壁層。 接下來,沉積將被圖案化成為柱的半導體材料。該半導 體材料可係矽、鍺、矽-鍺合金或其它適合半導體或半導 體合金。為了簡單明瞭,本分說明書將半導體材料指稱為 121890.doc -30- 200818204 矽,但是熟悉此項技術者應明 材料以作為替代。 白可選擇任何彼等其它適合 在較佳具體實施射,柱包括半導體接面二極體。本文 中使用用㊅”接面二極體"來指稱具有非歐姆傳導屬性、具 有:端子式電極以及係由半導體材料(其一電極處係p型: 另-電極處係η型)所製成之半導體裝置。實例包括”二極 體及η-ρ二極體(其具有接觸的1)型半導體材料與η型半導體U.S. Patent Application Serial No. 10/320,470 ft "An Improved Method for Making High Density Nonvolatile Memory" (and is hereby incorporated by reference). The manufacturing details will help to form the diodes of their specific embodiments with information from the $shirt application. U.S. Patent Application No. φ 11/〇15,824, "N〇nV〇latile Mem〇ry Cell Comprising a Reduced Height Vertical Diode", filed by Hemer et al., December 17, 2004. The usefulness of the information is derived from the assignee of the present invention and is hereby incorporated by reference. In order to avoid obscuring the present invention, all details from their application are not included, but it should be understood that they are not intended to exclude information from their applications. Example The single-memory level will be fabricated in detail. Additional memory levels can be stacked, each formed in a monolithic manner above the memory level below it. In this embodiment, the polycrystalline semiconductor diode will be used as a switchable element. Referring to Figure 15a, the formation of the memory begins at the substrate (10). The substrate 100 can be any semi-conductive substrate known in the art, such as a single crystal stone IV-IV compound (such as Shiguangyu or Shishiwu carbon), a cucurbit compound, a & VII compound, Here, the epitaxial layer on the temple substrate or any other semiconductive material. The substrate may include an integrated circuit fabricated therein. An insulating layer 102 is formed on the substrate 100. The insulating layer 102 can be a ruthenium oxide, a I fossil, a high dielectric film, a Si-C-O-H film, or any other suitable insulating material. On the substrate and the insulator on the ancient tour > » _ ^ above the formation of a conductor 2 〇〇. A barrier layer 1〇4 may be interposed between the insulating layer 1〇2 and the conductive layer 106 to assist the conductive layer 1〇6 to adhere to the insulating layer 102. If it is desired that the conductive layer is tungsten, it is preferable to use titanium nitride as the adhesive layer 104. Next, the exhibition to be deposited is in the #措g•, 曰 system V layer 106. Conductive layer 106 can comprise any of the conductive layer materials known in the art, such as (4) or other materials, including buttons, titanium, copper, cobalt, or any alloy thereof. - All layers that will form conductor tracks will be used with any suitable: ", and etching processes to pattern and etch their layers to form substantially parallel: coplanar conductors 2", such as The cross-sectional view of the figure is shown: in one embodiment, the sinking, the first resistance, and the lithography and their etched layers are used to pattern the photoresist, and * photoresist. The standard process technology is used to remove the germanium. The conductor 200 is formed by a damascene method. Next, the dielectric material (10) on the conductor track 2 can be made of a p4 L-dielectric material 108. Any known electrically insulating material, for example, oxidized 121890.doc -29- 200818204 yttrium nitride and/or yttrium oxynitride. In a preferred embodiment, ruthenium oxide can be used as the dielectric material 1 . The subsequent 'removal of excess dielectric material 108' on the very top of the conductor track 200 exposes the topmost portion of the conductor track 200 separated by the dielectric material 108 and leaves a substantially flat surface 109. Figure 15a shows the result Structure. Any process known to the art (such as chemistry) Mechanical polishing (CMP) or etch back) to perform overfill dielectric removal to form a flat surface 10 109. An advantageous etchback technique is described by Raghuram et al. on June 30, 2004. U.S. Patent Application Serial No. 1/883,417, the disclosure of which is incorporated herein by reference. A plurality of substantially parallel first conductors are formed on the substrate at a first height. Next, referring to Figure 15b, a vertical column will be formed over the finished conductor. (In order to save space, the substrate 1 is not shown in Fig. 15b; _ is confirmed to have a substrate present). Preferably, a barrier layer 110 is deposited as the first layer following the planarization conductor. Any suitable material can be used in the barrier layer, including tungsten nitride, nitride buttons, titanium nitride, or a combination of these materials. In a preferred embodiment, titanium nitride is used as the barrier layer. If the P early layer is titanium nitride, the barrier layer can be deposited in the same manner as described above for depositing the adhesion layer. Next, a semiconductor material that will be patterned into a pillar is deposited. The semiconductor material can be a tantalum, niobium, tantalum-niobium alloy or other suitable semiconductor or semi-conducting alloy. For the sake of brevity, this sub-paragraph refers to the semiconductor material as 121890.doc -30- 200818204 矽, but those skilled in the art should clarify the material as an alternative. White may select any other suitable for the preferred embodiment, and the column includes a semiconductor junction diode. As used herein, a six-junction diode is used to refer to a non-ohmic conduction property having a terminal electrode and a semiconductor material (the p-type at one electrode: the n-type at the other electrode). Semiconductor device. Examples include "diode and η-ρ diode (which has contact 1) type semiconductor material and n-type semiconductor

材料,諸如齊納二極體)以及ρ]_η二極體(其中本質(未經換 雜)半導體材料被插入於p型半導體材料與11型半導體材料 之間。 可藉由此項技術所熟知的任何沉積摻雜方法來形成底部 重摻雜區112。可沉積且接著摻雜矽,但是較佳藉由於沉 積矽期間使提供n型摻雜物原子(例如,磷)的施體氣體流動 進行原位摻雜。重摻雜區112之厚度較佳係介於約1〇〇埃與 約800埃之間。 可藉由此項技術所熟知的任何方法來形成本質層〗14。 層114可係石夕、鍺或任何石夕或鍺之合金,並且厚度係介於 約1100埃與約3300埃之間,較佳係約2〇〇〇埃。 請重新參考圖15b,剛剛沉積的半導體層114與112將連 同下伏阻障層110—起被圖案化及蝕刻以形成柱3〇〇。柱 300應具有約相同於下方之導體200之間距與寬度,使得每 一柱300被形成於導體2〇〇之最頂部。可容許一些錯位。 可使用適合遮罩與蝕刻製程來形成柱300。舉例而言, 可沉積光阻、使用標準微影技術來圖案化並且蝕刻該光 121890.doc -31- 200818204 阻,接著移除該光阻。替代做法為,可在半導體層堆疊最 頂部上(在頂部上具有底部抗反射塗層(B ARC))形成某其它 材料(例如,二氧化矽)之硬遮罩,接著予以圖案化及蝕 刻。同樣地,可使用介電抗反射塗層(DARC)作為硬遮 罩。 ’ 於Chen於2003年12月5日申請之美國專利申請案第 一 10/728436號"Photomask Features with Interior NonprintingMaterials such as Zener diodes and ρ]_η diodes (wherein the intrinsic (unsubstituted) semiconductor material is interposed between the p-type semiconductor material and the type 11 semiconductor material. It is well known by the art. Any deposition doping method to form the bottom heavily doped region 112. The deposition can be followed by doping with germanium, but preferably by flowing a donor gas that provides n-type dopant atoms (eg, phosphorus) during deposition of germanium. In-situ doping. The thickness of heavily doped region 112 is preferably between about 1 Å and about 800 Å. The layer 14 can be formed by any method known in the art. An alloy of stone, enamel or any stone or enamel, and having a thickness of between about 1100 angstroms and about 3300 angstroms, preferably about 2 angstroms. Please refer back to Figure 15b, the just deposited semiconductor layer. 114 and 112 will be patterned and etched along with the underlying barrier layer 110 to form pillars 3. The pillars 300 should have approximately the same distance and width from the conductors 200 below, such that each pillar 300 is formed on the conductor 2〇〇 The top of the line. Some misplaced positions can be tolerated. The mask and etch process are combined to form pillars 300. For example, photoresist can be deposited, patterned using standard lithography techniques, and etched with the light 121890.doc -31 - 200818204, followed by removal of the photoresist. To form a hard mask of some other material (eg, cerium oxide) on the top of the semiconductor layer stack (with a bottom anti-reflective coating (B ARC) on top), followed by patterning and etching. A dielectric anti-reflective coating (DARC) can be used as a hard mask. 'US Patent Application No. 10/728436, "Photomask Features with Interior Nonprinting, filed on December 5, 2003

Window Using Alternating Phase Shifting” ;或 Chen於 2004 _ 年4月1曰申請之美國專利申請案第10/815312號"PhotomaskUS Patent Application No. 10/815312 "Photomask, filed by Chen, Alternating Phase Shifting; or Chen, April 1, 2004

Features with Chromeless Nonprinting Phase Shifting Window’’(彼等案皆由本發明受讓人所擁有並且皆特此以 引用方式併入本文中)中描述之微影技術有利於用於實行 在形成根據本發明之記憶體陣列中使用的任何微影步驟。 在半導體柱300上方及之間沉積介電材料108 ’以填滿柱 之間的間隙。介電材料108可係任何已知之電絕緣材料’ _ 例如,氧化矽、氮化矽及/或氮氧化矽。在一較佳具體實 施例中,使用二氧化矽作為絕緣材料。 接下來,移除位於柱300最頂部上的介電材料’曝露出 , 藉由介電材料108分隔之柱300之最頂部,並且留下實質上 平坦表面。藉由此項技術所熟知之任何製程(諸如CMP或 回蝕)來實行過填充介電之移除。在CMP或回蝕之後’實 行離子植入,形成頂部重摻雜p型區116。p塑摻雜物較佳 係棚或BC13。此植入步驟完成二極體111之形成。圖15b繪 示所得結構。在剛剛形成的二極體中,底部重摻雜區112 121890.doc -32 - 200818204 係η型,並且頂部重摻雜區116係p型;顯然地,極性可顛 倒。 請參考圖15c,接下來,在每一重摻雜p型區ι16之頂部 上形成介電破裂反熔絲層11 8。反熔絲11 8較佳係藉由在迅 速熱退火(例如,約600度)中氧化下伏矽所形成的二氧化矽 層。反溶絲118之厚度可約20埃。替代做法為,可沉積反 熔絲11 8。The lithography techniques described in the Features of Chromeless Nonprinting Phase Shifting Window's (both of which are owned by the assignee of the present invention and incorporated herein by reference) are herein Any lithography step used in the volume array. A dielectric material 108' is deposited over and between the semiconductor pillars 300 to fill the gaps between the pillars. Dielectric material 108 can be any known electrically insulating material ' _ for example, hafnium oxide, tantalum nitride, and/or hafnium oxynitride. In a preferred embodiment, cerium oxide is used as the insulating material. Next, the dielectric material removed on the topmost portion of the pillar 300 is exposed, the topmost portion of the pillar 300 separated by the dielectric material 108, and leaving a substantially flat surface. Overfill dielectric removal is performed by any process well known in the art, such as CMP or etch back. Ion implantation is performed after CMP or etch back to form a top heavily doped p-type region 116. The p-plastic dopant is preferably a shed or BC13. This implantation step completes the formation of the diode 111. Figure 15b shows the resulting structure. In the diode just formed, the bottom heavily doped region 112 121890.doc -32 - 200818204 is n-type, and the top heavily doped region 116 is p-type; obviously, the polarity can be reversed. Referring to Figure 15c, next, a dielectric rupture antifuse layer 11 8 is formed on top of each heavily doped p-type region ι16. The antifuse 11 8 is preferably a layer of ruthenium dioxide formed by oxidizing underlying ruthenium in a rapid thermal annealing (e.g., about 600 degrees). The counter-solvent 118 can have a thickness of about 20 angstroms. Alternatively, an anti-fuse 117 can be deposited.

可用相同於底部導體200之方式來形成頂部導體4〇〇,舉 例而言,藉由沉積黏著層12〇(較佳由氮化鈦所製成)及傳導 層122(較佳由鎢所製成)。接著,使用任何適合的遮罩與蝕 刻製程來圖案化及蝕刻傳導層122及黏著層12〇,以形成實 質上平行、實質上共面導體彻,如圖15e之左至右跨頁延 伸所示。在-較佳具體實施例中,沉積光阻,並且藉由微 影及彼等㈣^層來_案㈣纽,並且接著使用標準 製程技術來移除該光阻。 接下來,在導體軌400上方及之間沉積一介電材料(圖中 綺示)。介電材料可係㈣已知之電絕緣材料,例如, 氧化矽、氮化矽及/吱f童仆也 上 ^ 1 切。在-較佳具體實施例 中,可使用二氧化石夕作為此介電材料。 已描述形成一第一記憶體層 ,,^ t j在此弟一記憶體層級 上形成額外記憶體層級,以形 仏成早片二維記憶體陣列。 在一些具體實施例中,可在 牡^ fe體層級之間共用導體 即,頂部導體400將作為下一 〇己L、體層級之底部導體。在 …匕/、體實施例中,在圖15〇 ^ 弟一 C憶體層級上方形成 121890.doc -33- 200818204 一層間介電(圖中未繪示),其表面經平坦化,並且一第一 記憶體層級之構造開始於此經平坦化層間介電上,而且無 共用之導體。 單片二維記憶體陣列係在其中在一單一基板(諸如一晶 圓)上方形成多重記憶體層級而且無中介基板的記憶體陣 列。形成一記憶體層級的彼等層係直接沉積或生長於一現 有層級或多重層級的彼等層上方。相比之下,已藉由在翠 獨的基板上形成記憶體層級並且使彼等記憶體層級彼此在 頂部上黏著建構堆疊式記憶體,如同Leedy之美國專利案 第 5,915,167 號"Three dimensional structure memory” 中所提 出。彼等基板可在接合之前予以薄化或自彼等記憶體層級 移除,但是當在單獨基板上初始形成彼等記憶體層時,此 等記憶體不是真正的單片三維記憶體陣列。 在基板上方形成之單片三維記憶體陣列包括至少一第一 記憶體層級(其係以高於基板之第一高度予以形成)及一第 一記憶體層級(其係以不同於第一高度之第二高度予以形 成)。在此多層級記憶體陣列中,可在基板上方形成三、 四、八或甚至任何數量之記憶體層級。 在Radigan等人於2006年5月31曰申請之美國專利申請案 第 11/444,936號"Conductive Hard Mask to Protect PatternedThe top conductor 4 can be formed in the same manner as the bottom conductor 200, for example, by depositing an adhesive layer 12 (preferably made of titanium nitride) and a conductive layer 122 (preferably made of tungsten). ). Next, the conductive layer 122 and the adhesion layer 12A are patterned and etched using any suitable masking and etching process to form substantially parallel, substantially coplanar conductors, as shown in the left to right spread of FIG. 15e. . In a preferred embodiment, the photoresist is deposited and removed by lithography and their layers, and then the photoresist is removed using standard process techniques. Next, a dielectric material (shown in the figure) is deposited over and between the conductor tracks 400. The dielectric material may be (iv) known as an electrically insulating material, for example, yttrium oxide, tantalum nitride, and/or 童f servants are also cut. In a preferred embodiment, silica dioxide can be used as the dielectric material. It has been described that a first memory layer is formed, and an additional memory level is formed on this memory level to form an early two-dimensional memory array. In some embodiments, the conductor may be shared between the levels of the body, i.e., the top conductor 400 will serve as the bottom conductor of the next level, body level. In the 匕/, body embodiment, a layer of dielectric (not shown) is formed above the layer of the layer of FIG. 15 〇 C C C , , , , , , , , , , , , , , 121 121 121 121 121 121 121 121 121 121 121 121 121 121 121 121 121 121 121 The configuration of the first memory level begins with this planarized interlayer dielectric and has no shared conductor. A monolithic two-dimensional memory array is a memory array in which multiple memory levels are formed over a single substrate (such as a wafer) and there is no interposer. The layers forming a memory level are deposited or grown directly over an existing layer or layers of multiple levels. In contrast, stacked memory has been constructed by forming memory levels on a substrate that is unique and bonding the memory levels to each other on top, as in Leedy's U.S. Patent No. 5,915,167 "Three As proposed in the "dimensional structure memory", the substrates can be thinned or removed from the memory levels before bonding, but when the memory layers are initially formed on separate substrates, the memories are not truly single. a three-dimensional memory array. The monolithic three-dimensional memory array formed over the substrate includes at least a first memory level (which is formed at a higher level than the first height of the substrate) and a first memory level (which is A second height different from the first height is formed. In this multi-level memory array, three, four, eight or even any number of memory levels can be formed above the substrate. In Radigan et al., May 2006 US Patent Application Serial No. 11/444,936 "Conductive Hard Mask to Protect Patterned

Features During Trench Etch&quot;中描述一種用於形成類似記 憶體陣列之替代方法,其中使用鑲嵌構造來形成導體,該 案由本發明受讓人所擁有並且特此以引用方式併入本文 中。可代替地使用Radigan等人之方法來形成根據本發明 121890.doc 34· 200818204 之兄憶體陣列。 替代具體實施例 除了已描述之彼等具體實施例以外,以複晶或微晶半導 體材料之電阻率狀態來儲存其資料狀態之記憶體單元的許 多替代具體實施例亦可行並且屬於本發明範疇内。將提及 少數其它可行具體實施例,但此清單不可且非意圖詳盡 列舉。 圖16繪示以串聯於二極體U1方式形成之可切換式記憶 體兀件117。可切換式記憶體元件117係由如所述使用電脈 衝切換於電阻率狀態之間的半導體材料所形成。如上文所 述’一極體較佳係相鄰於石夕化物(諸如石夕化始,其提供晶 化模板)予以結晶化,致使二極體之半導體材料缺陷極低 並且展現出微不足道或無切換行為。較佳方式為,可切換 式圯憶體元件117經摻雜,並且應摻雜至相同於頂部重摻 雜區116的傳導類型。’167申請案中描述此裝置之製造方 法。 本文中已描述詳細製造方法,但是可使用形成相同結構 的任何其它方法,同時結果屬於本發明範疇内。 示範性應用 前文之具體實施例描述如何可使用記憶體單元作為兩種 資料狀態式€憶體單元、兩種以上資料狀態式記憶體單 元、可單次程式化記憶體單元或可重寫記憶體單元。此多 用途允許使用共同記憶體單元架構來提供多重類型之記憶 體產品。下文論述記憶體單元之多用途性質及其提供多用 121890.doc -35- 200818204 途記憶體陣列之潛力。 上文所述之記憶體單元复古 干几具有包含可切換式電阻材料(諸 如可組態至至少三種電阻率壯 丰狀L中之一者的半導體材料) 之記憶體元件。可於形成記憶體元件期間將記憶體元件 ’’組態’,至一電阻率狀態(例如, 土 π立 初始、未經程式化狀態之記 憶體元件具有初始電阻率狀態)’或藉由後續使記憶體元 件經受設定脈衝或重設脈衝來將記憶體元件&quot;μ”至一電 阻率狀態。因為此特性,所以單一 1 A平尤丨思體早兀可依兩種不 ,方式j行動作:料可單次程式化記憶體單元或可重寫 5己憶體單元。再者’因為此特性, 抑 ^ 符生所以早一記憶體單元可 使用兩種資料狀態或兩種以上資料狀態。據此,任何既定 製造的記憶體單元皆具有運作為具有兩種或兩種以上資料 狀態之可單次程式化記憶體單元或可重寫記憶體單元的潛 力。 如圖所示並且如上文所述,當記憶體單元運作為可單次 程式化記憶體單元時,使用—電阻率狀態來表示記憶體單 元的一資料狀態;但是當記憶體單元運作為可重寫記憶體 早病,不使用該電阻率狀態來表示記憶體單元的一資料 狀^換言之’當記憶體單⑼用作為可單次程式化記憶 體單元時,在記情體覃元中可此古 匕u體早兀中可月b有_,,額外&quot;狀態。舉例而 言,關於上文所述且配合圖5與圖u所描述之記憶體單 几,,己憶體單元被製造成處於初始電阻率㈣(V狀態), 並且當記憶體單元運作為可單次程式化記憶體單元時,使 用此初始電”狀態;但是當記憶體單元運作為 121890.doc -36· 200818204 憶體單元時’則不使用此初始電阻率狀態。當記憶體單元 運作為可重寫記憶體單元時,使用兩種其它資料狀態(R狀 態及S狀態)來表示記憶體單元之資料狀態。(如下文所 述’亦可在可單次程式化記憶體單元中使用彼等資料狀 態)。藉由改變可切換武雷日1 L企、, 、Λ電阻材枓之電阻來達成彼等資料 狀L再久,彼等其它育料狀態不包括僅當記憶體單元運 作為可單.人权式化讀體單元時才用於表示資料狀態的資 料狀L可使用額外貧料狀態(例如,介於r狀態與§狀態 之間的R2狀悲)以允許可重寫記憶體單元達成三種或達 成三種以上各別資料狀態。 應注意,在-項較佳具體實施例中,記憶體元件包括串 聯於反熔絲的切換式電阻材料(例如,半導體材料),並且 V狀態係僅當域料元運料可單切式化記憶體單元 時才使用的電阻率狀態。原因係,一旦反熔絲被燒斷,則 記憶體元件無法回Μ狀態。但是,甚至當不使用反溶絲 日守可豸電阻率狀態指定作為僅當記憶體單元運作為可 單次程式化記憶體單元時才使用的狀態。亦應注意,Ρ狀 態亦可係當記憶體單元運作為可單次程式化記憶體單元時 予以使用但疋當《憶體單元運作為可重寫記憶體單元時不 予以使用的電阻率狀態。但是,在-些具體實施例中,替 代Ρ狀悲或除了 Ρ狀態以外,使用R狀態與S狀態中之一者 或兩者來表不可單次程式化記憶體單元的一資料狀態,諸 如田可單久权式化記憶體單元儲存三種或四種資料狀態 時。在此-情況中,記憶體單元之可單次程式化與可重寫 121890.doc -37- 200818204 用途將共同具有一電阻率狀態。舉例而言,代替具有獨特 狀態狀態之可單次程式化記憶體單元及可重寫記憶體單元 (例如,V狀態及P狀態係用於可單次程式化記憶體單元, 及R狀態及S狀態係用於可重寫記憶體單元),可單次程式 化記憶體單元及可重寫記憶體單元可共同具有一狀態(例 如,S狀態與P狀態之間無任何差別)。然而,當記憶體單 元運作為可單次程式化記憶體單元時,仍然將使用至少一 電阻率狀態(例如,V狀態)來表示記憶體單元的一資料狀 態;但是當記憶體單元運作為可重寫記憶體單元時,則非 如此。 此多用途的一項優點在於,具有此等記憶體單元的單一 積體電路可被指定作為可單次程式化記憶體陣列或作為可 重寫記憶體陣列。此提供製造靈活性及良率提升。為了判 定記憶體陣列是否應用作為可單次程式化記憶體陣列或作 為可重寫記憶體陣列,可於製造期間(或之後)測試記憶體 陣列中的一組測試記憶體單元。舉例而言,可藉由重複程 式化、重設及設定彼等測試記憶體單元來運用彼等測試記 憶體單元。美®專難第6,4G7,953號巾描述—種適合的測 試技術’彼專㈣經讓渡給本發明受讓人並且特此以引用 方式整份併人本文。依據測試結果,可預測記憶體陣列是 否將正轉程式化以作為可重寫記憶體陣列。舉例而言,如 果測試展現出難以辨取狀態及S狀態(彼等狀態係用於當 記憶體陣列運作為可重寫記㈣㈣時),㈣部件將很 可能未正確程式化以作為可重寫記憶體陣列^但是,因為 121890.doc -38- 200818204 記憶體陣列中的記憶體單元可 陣列或作為可重寫記憶體陣列 所預期可重寫結果而予以丢棄 程式化記憶體陣列。據此,共 製造靈活性及良率提升。 運作為可單次程式化記憶體 ,所以代替因該部件未提供 ,可指定該部件作為可單次 同骨幹記憶體單元架構提供An alternative method for forming a similar array of memory elements is described in the Feature During Trench Etch&quot;, wherein a mosaic is used to form the conductor, which is owned by the assignee of the present invention and is hereby incorporated by reference. The method of Radigan et al. may alternatively be used to form the sequel array according to the invention 121890.doc 34. 200818204. Alternative Embodiments In addition to the specific embodiments that have been described, many alternative embodiments of memory cells that store their data states in the resistivity state of a polycrystalline or microcrystalline semiconductor material are also possible and within the scope of the present invention. . A few other possible specific embodiments will be mentioned, but this list is not intended to be exhaustive. Figure 16 illustrates a switchable memory element 117 formed in series with a diode U1. Switchable memory component 117 is formed from a semiconductor material that is switched between resistive states using electrical pulses as described. As described above, a monopolar body is preferably crystallized adjacent to a lithiated compound (such as a crystallization template provided by Shi Xihua), resulting in a semiconductor material defect of the diode being extremely low and exhibiting negligible or absent. Switch behavior. Preferably, the switchable memory element 117 is doped and should be doped to the same conductivity type as the top heavily doped region 116. The method of manufacture of this device is described in the '167 application. Detailed manufacturing methods have been described herein, but any other method of forming the same structure may be used, with the results falling within the scope of the present invention. Exemplary Applications The foregoing specific embodiments describe how memory cells can be used as two data state type memory cells, two or more data state memory cells, a single stylized memory cell, or a rewritable memory. unit. This versatility allows the use of a common memory cell architecture to provide multiple types of memory products. The versatile nature of memory cells and their potential to provide versatile memory arrays are discussed below. The memory cell retrofit described above has a memory component that includes a switchable resistive material, such as a semiconductor material configurable to one of at least three resistive densities L. The memory element can be 'configured' during the formation of the memory element to a resistivity state (eg, the initial, unprogrammed state of the memory element has an initial resistivity state) or by subsequent The memory element is subjected to a set pulse or a reset pulse to &quot;μ" the memory element to a resistivity state. Because of this characteristic, a single 1 A flat can be used as a two-way method. Action: It is possible to program a single memory unit or a rewritable 5 unit. In addition, because of this characteristic, the memory unit can use two data states or two or more data states. Accordingly, any predetermined memory cell has the potential to operate as a single-programmed memory cell or rewritable memory cell having two or more data states. As shown and as above Said that when the memory unit operates as a single-programmable memory unit, the resistivity state is used to represent a data state of the memory unit; but when the memory unit operates as a rewritable Memory early disease, do not use the resistivity state to represent a data structure of the memory unit. In other words, when the memory single (9) is used as a single-programmed memory unit, it can be used in the memory unit. In the early morning, there may be a _, extra &quot; state. For example, regarding the memory described above and in conjunction with FIG. 5 and FIG. u, the memory unit is manufactured to be in the initial state. Resistivity (4) (V state), and when the memory unit operates as a single-programmed memory unit, this initial power state is used; but when the memory unit operates as 121890.doc -36·200818204 'The initial resistivity state is not used. When the memory unit operates as a rewritable memory unit, two other data states (R state and S state) are used to represent the data state of the memory cell. (As described below, they can also be used in a single-programmed memory unit). By changing the resistance of the switchable Wu Leiri 1 L, and Λ resistance materials to achieve their data for a long time, their other state of education does not include only when the memory unit operates as a single. The material L used to represent the data state can use an extra lean state (for example, R2 sorrow between the r state and the § state) to allow the rewritable memory cell to achieve three or achieve Three or more different data states. It should be noted that in the preferred embodiment, the memory element comprises a switched resistive material (eg, a semiconductor material) connected in series with the antifuse, and the V state is only singularly tangible when the domain material transports The resistivity state used when the memory cell is used. The reason is that once the antifuse is blown, the memory component cannot be returned. However, even when the anti-solvent wire is not used, the state of the resistivity state is specified as the state that is used only when the memory cell operates as a single-programmable memory cell. It should also be noted that the Ρ state can also be used when the memory unit operates as a single-programmable memory unit, but it is a resistivity state that is not used when the memory unit operates as a rewritable memory unit. However, in some embodiments, instead of or in addition to the Ρ state, one or both of the R state and the S state are used to represent a data state of the memory cell that cannot be monolithically programmed, such as A single-time weighted memory unit stores three or four data states. In this case, the single-programmable and rewritable memory units of the memory unit will have a resistivity state in common. For example, instead of a single-programmed memory cell and a rewritable memory cell having a unique state state (eg, V-state and P-state are used for a single-programmed memory cell, and R-state and S The state is for a rewritable memory unit), and the single-programmed memory unit and the rewritable memory unit can have a state together (for example, there is no difference between the S state and the P state). However, when the memory unit operates as a single-programmable memory unit, at least one resistivity state (eg, V-state) will still be used to represent a data state of the memory cell; however, when the memory cell operates as This is not the case when overwriting the memory unit. An advantage of this versatility is that a single integrated circuit having such memory cells can be designated as a single-programmable memory array or as a rewritable memory array. This provides manufacturing flexibility and yield improvement. To determine if a memory array is to be used as a single-programmable memory array or as a rewritable memory array, a set of test memory cells in the memory array can be tested during (or after) manufacturing. For example, the test memory cells can be utilized by reprogramming, resetting, and setting their test memory cells. </ RTI> </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; Based on the test results, it is predicted whether the memory array will be normalized as a rewritable memory array. For example, if the test exhibits an indistinct state and an S state (these states are used when the memory array operates as a rewritable note (4) (4)), the (4) component will most likely not be properly programmed to be rewritable. Memory Array ^ However, the stylized memory array is discarded because the memory cells in the memory array of 121890.doc -38 - 200818204 can be arrayed or as a rewritable result expected by the rewritable memory array. As a result, co-manufacturing flexibility and yield improvement. Operates as a single-programmed memory, so instead of providing this component, you can specify that the component is available as a single-associated memory unit architecture.

在此點,可有製造分歧。通過測試的記憶體陣列可_ 用以進—步格式化(例如,將所有記憶體單元自V狀態程式 化^狀態’接著於驗態與s狀態之間予以運用以作為最 、、貝格測4) ’亚且接著作為可重寫記憶體陣列(例如,用 讀位攝影機的記憶卡)運送至倉庫或使用者。未通過測 試的記憶料列可Μ封裝且送至製造廠之*同部分以程 式化可單次程式化内容。替代做法為,該部件可送至倉 庫由层庫員工或使用者現場程式化可單次程式化内容 (例如,使用kiosk) »未經程式化部件亦可銷售給使用者以 用作為存檔用記憶體。 較佳方式為,使用一旗標來發訊號給讀取及寫入至記憶 體陣列的裝置(例如,在主機裝置中包括記憶體陣列或硬 體/軟體的記憶體裝置上的控制器)以告知記憶體陣列係可 單次程式化記憶體陣列或可重寫記憶體陣列。”旗標”可係 儲存於記憶體陣列中的一或多個位元。舉例而言,可在記 十思體陣列中的一特殊位址位置(例如,位址〇〇〇〇)中設定旗 標。當主機裝置偵測到旗標時,其可藉由不嘗試重新程式 化記憶體陣列來調適至記憶體陣列的可單次程式化性質。 代替使用整個記憶體陣列作為可單次程式化記憶體陣列 121890.doc -39- 200818204 或作為可重寫記憶體陣列, °己隐體陣列可係&quot;多用途”却忤 體陣列。在此具體實施例中,由心憶體陣列中的所有Γ :記憶體單元皆可用作為可單次程式化記憶體單元或用: 為可重寫記憶體單元,所以一第一 — 示、、且5己丨思體單疋運作為可 單次程式化記憶體單元,及一第_ 弟一組圮憶體早兀運作為可 重寫記憶體單元。在此方式中,w — 八甲可在相同積體電路上可單 次程式化記憶體單元及可重寫纪愔 里馬忑體早兀。如上文所述,At this point, there may be manufacturing differences. The tested memory array can be used for further formatting (for example, staging all memory cells from the V state ^ state) and then applying between the verification state and the s state as the most, and the Berg test 4) 'Affinity is a rewritable memory array (for example, a memory card with a reading camera) that is shipped to a warehouse or user. Memory samples that fail the test can be packaged and sent to the same part of the manufacturer to program a single stylized content. Alternatively, the part can be sent to the warehouse by the library staff or the user to programmatically program the content in a single program (for example, using kiosk) » Unprogrammed parts can also be sold to the user for use as an archive memory body. Preferably, a flag is used to send a signal to a device for reading and writing to the memory array (for example, a controller on a memory device including a memory array or a hardware/software in the host device). The memory array is told to be a single-programmed memory array or a rewritable memory array. A "flag" may be one or more bits stored in a memory array. For example, a flag can be set in a special address location (e.g., address 〇〇〇〇) in the imaginary array. When the host device detects the flag, it can be adapted to the single-programmable nature of the memory array by not attempting to reprogram the memory array. Instead of using the entire memory array as a single-programmable memory array 121890.doc -39- 200818204 or as a rewritable memory array, the °-hidden array can be a "multi-purpose" but body array. In a specific embodiment, all of the memory cells in the memory cell array can be used as a single-programmable memory cell or as: a rewritable memory cell, so a first-display, and 5 The single-single-single-single unit operates as a single-programmed memory unit, and a group of _ _ 圮 兀 兀 兀 兀 兀 兀 兀 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 A single-programmed memory unit and a rewritable memory can be programmed on the integrated circuit. As mentioned above,

可^亍測試以判定-既定組記憶體單元是否應被指定作為 可單-人私式化记憶體單元或可重寫記憶體單元。 、 圖17繪示較佳具體實施例之混合用途記憶體陣列200之 圖解。一第一組記憶體單元210運作為可單次程式化記憶 體單元,以及一第二組記憶體單元220運作為可重寫記憶 體單元。在此具體實施例中,該兩組210、220中的記憶體 單元皆包含相同數量之每記憶體單元資料狀態,然而記憶 體單元資料狀態之數量變化係可行,如下文所述。在一項 具體實施例中,第一組記憶體單元儲存被視為永久性且可 相關於記憶體陣列運作的資料。此資訊之實例包括(但不 限於)下列項目中之一或多項:内容管理位元、修整位 元、製造商資料及格式化資料。 ’’内容管理位元&quot;指稱相關於經程式化内容之管理的資 訊。”修整位元”係設定晶片上電路中各種選項的自訂資 訊。運作中,晶片上電路讀取第一組記憶體單元210中的 修整位元,並且經讀取之修整位元控制電路的進一步運 作。舉例而言,修整位元可包含用於記憶體裝置之寫入/ 121890.doc -40- 200818204 貝:電路的車“圭寫入&quot;讀取似電流或電壓)的言免$。&quot;製造 商貝料可包括製造商名稱與序號。”格式化資料”指示出 記憶體陣列的不自部八.a μ &amp; ^ 艮邛刀,具體而s,記憶體陣列中之一特 疋列及/或行不良及冗餘列及/或行位置。如需關於冗餘的 、v資汛印參閱美國專利申請案第10/402,385號及第 ’646號,彼等專利申請案均已讓渡給本發明受讓人 並且特此以5丨用方式併人本文。當然,彼等資訊僅係實 例,並且可在可單次程式化記憶體單元210中儲存其它形The test can be performed to determine whether a given set of memory cells should be designated as a single-person private memory cell or a rewritable memory cell. FIG. 17 is a diagram showing a hybrid memory array 200 of a preferred embodiment. A first set of memory cells 210 operates as a single-programmable memory cell, and a second set of memory cells 220 operates as a rewritable memory cell. In this embodiment, the memory cells in the two sets 210, 220 all contain the same number of memory cell data states, however, the number of memory cell data states is feasible, as described below. In a specific embodiment, the first set of memory cells stores data that is considered permanent and can be related to the operation of the memory array. Examples of this information include, but are not limited to, one or more of the following: content management bits, trim bits, manufacturer data, and formatted material. ‘’Content Management Bit&quot; refers to information related to the management of stylized content. The "trimming bit" is a custom message that sets various options in the circuit on the wafer. In operation, the on-wafer circuit reads the trim bits in the first set of memory cells 210 and the read trim bit control circuitry further operates. For example, the trim bit can include a write for the memory device / 121890.doc -40- 200818204 B: the circuit of the car "guy write &quot; read like current or voltage) exemption $.&quot; The manufacturer's bedding material may include the manufacturer's name and serial number. "Formatted data" indicates that the memory array is not self-contained. a μ &amp; ^ file, specifically s, one of the memory arrays And/or poor and redundant columns and/or row locations. For more information on redundancy, see U.S. Patent Application Nos. 10/402,385 and '646, and their patent applications have been It is to be noted that the assignee of the present invention is hereby incorporated by reference.

式之資afl。舉例而言,帛—組記憶體單元2工〇可包含遊戲 内谷資料(即遊戲的電腦程式碼),以及第二組記憶體單 兀220可包含遊戲狀態資料(即,當使用者要求保存遊戲 時,在遊戲中之使用者位置的指示)。再者,可在製造廠 處或由後續使用者來程式化第一組記憶體單元2丨〇或第二 組記憶體單元220中的資料。 在圖17中,有可單次程式化記憶體單元的僅一個區段以 及可重寫s己憶體單元的僅一個區段。在另一具體實施例 中,有至少一額外組記憶體單元運作為可單次程式化記憶 體單元或可重寫記憶體單元。圖18繪示此一具體實施例, 其中使兩個可早次程式化區段230、250與兩個可重寫區段 240、260交錯(即,兩相鄰組記憶體單元非皆是可單次程 式化或皆是可重寫)。如上文所述,可將任何資料儲存於 任何區段中。舉例而言,遊戲内容資料可儲存於可單次程 式化區段230、250中,遊戲狀態資料可儲存於可重寫區段 240、260 中 〇 121890.doc -41 - 200818204 應注意,雖然圖17及圖18繪示依水平方式來定向該等組 記憶體單元,但是在替代具體實施例中,可依垂直方式來 定向一或多組記憶體單元。舉例而言,代替在水平列記憶 體單元中具有格式化資料(如圖17所示),格式化資料可以 係在垂直列記憶體單元中。在此方式中,冗餘資料將跨越 許多頁。亦可使用混合用途水平定向及垂直定向資訊。舉 例而言,製造資料可予以水平定向,而格式化資料可予以 垂直定向。 如圖18所示,每頁資料可包括一或多個旗標位元”❹, 其指示出一頁是否係可單次程式化或可重寫。在圖18中, πι”旗標指示出可單次程式化,以及”0”旗標指示出可重 寫。較佳方式為,旗標係儲存於可單次程式化記憶體單元 中(即使記憶體單元係處於可重寫區段中)。再者,較佳方 式為,對於可單次程式化資料使預設讀取條件最佳化(所 以可成功讀取可單次程式化區段中儲存的可單次程式化旗 標位元與修整位元、製造資料等等),並且如果旗標指示 出可重寫貧料,則修改彼等讀取條件。使用旗標位元之一 項優點在於,實際上不可能使用可單次程式化記憶體單元 作為可重寫記憶體單元,反之亦然,原因係藉由晶片上寫 電路來解譯旗標,該晶片上寫電路經程式化用以如果旗標 ,元指示出一記憶體單元係可單次程式化,則防止超過二 次寫入至該記憶體單元。 作為使用旗標位元的替代方案,位址空間計算與寫控制 可被移至晶片夕卜,例如’移至主機裝置中的硬體/軟體。 121890.doc -42- 200818204 舉例而言,如果使用記憶體裝置作為遊戲匣,則主機裝置 中的軟體可使用用於儲存遊戲狀態資料的預先指定之位址 空間(主機裝置已知該位址空間,但記憶體未得知位址空 間)。替代做法為’可藉由儲存於記憶體陣列中之遊戲内 容資料中、記憶體陣列之另一可單次程式化部分(例如, 記憶體陣列中的一特殊位址位置(例如,位址〇〇〇〇))或記憶 體裝置中與記憶體陣列分開的裝置控制器中的資訊來向主 機裝置告知用於遊戲狀態資料的位址空間。 在圖17及圖18所示之具體實施例中,就一些記憶體單元 係可單次程式化記憶體單元並且其它者係可重寫記憶體單 元之意義而言,記憶體陣列係,,混合用途&quot;。在其它具體實 施例中,代替或除了可單次程式化/可重寫特徵,,,混合用 途&quot;記憶體陣列包含其它&quot;混合”特徵。如上文所述,可使 用旗榣位元或其它機制來判定一既定組記憶體單元的性 質。舉例而言,在相同記憶體陣列中的第一組記憶體單元 可比第二組記憶體單元更加可靠並且溫度與電壓範圍更 寬。 作為另一項實例,運用上文所述之較佳記憶體單元結 構,一既定記憶體單元可係··⑴用正向偏壓予以程式化 (例如,如同一可單次程式化記憶體單元或可重寫記憶體 單元);或(ii)用逆向偏壓予以程式化(例如,如同一可重 寫記憶體單元,但不同於兩狀態式可單次程式化記憶體單 元)。換言之,可單次程式化記憶體單元僅可接受正向偏 壓程式化,而可重寫記憶體單元可接受正向偏壓程式化及 121890.doc -43- 200818204 逆向偏壓程式化兩者。此繪示於圖19及圖20之電路圖中。 如需正向偏壓寫入之詳細描述,請參閱美國專利案第 6,618,295號;以及如需逆向偏壓寫入之詳細描述,請參閱 美國專利申請案第11/461,339號(代理人檔案號碼第023-0048號)題為’’Passive Element Memory Array Incorporating Reversible Polarity Word Line and Bit Line Decoders”及美 國專利申請案第11/461,364號(代理人檔案號碼第023-0054 號)題為 ’’Method for Using a Passive Element Memory Array Incorporating Reversible Polarity Word Line and Bit Line Decoders”,彼等案均已讓渡給本發明受讓人並且特此以引 用方式併入本文。據此,”混合用途n記憶體陣列可包含: 一第一組記憶體單元,其係用正向偏壓予以程式化;及一 第二組記憶體單元,其係用逆向偏壓予以程式化。用逆向 偏壓予以程式化的記憶體單元亦可用正向偏壓予以擦除。 在擦除操作(相較於寫入操作)中,一頁中的個別資料位元 不是變數,原因係在擦除操作中擦除了所有位元。如需擦 除操作之詳細描述,請參閱美國專利申請案第11/461,339 號(代理人檔案號碼第023-0048號)題為”Passive Element Memory Array Incorporating Reversible Polarity Word Line and Bit Line Decoders&quot;及美國專利申請案第11/461,364號 (代理人檔案號碼第023-0054號)題為&quot;Method for Using a Passive Element Memory Array Incorporating Reversible Polarity Word Line and Bit Line Decoders”,彼等案均已讓 渡給本發明受讓人並且特此以引用方式併入本文。 121890.doc -44- 200818204 、到目則為止之論述係關於使用記憶體單元作為可單次程 式化石己憶體單元或作為可重寫記憶體單元,並且記憶體陣 =具有可早次程式化記憶體單元與可重寫記憶體單元之混 &quot;仁疋,如上文所述,另一多用途態樣之較佳記憶體單 • 兀在於,該記憶體單元(無論係可單次程式化記憶體單元 或係可重寫記憶體單元)可儲存兩種資料狀態或兩種以上 資料狀心可對於每_可能的資料狀態來測試多重測試記 _ 體單7〇 ’以與J定在一記憶體陣列可儲存多少、資料狀態。 牛彳〗而。可在v、p、s與R資料狀態下來對測試記憶體 t元進行測試,以推斷記憶體單元是否合意地運作為四狀 態式可單次程式化記憶體單元。如果記憶體陣列未通過測 试’則可將其用作為兩狀態式記憶體陣列,在該記憶體陣 列中儲存有適當的旗標。 此口用逆c憶體陣列可連同使用x種電阻率狀態的一組 記憶體單元-起使用來表示X種資料狀態,以及連同使用 • Y種電阻率狀態的—第二組記憶體單元-起使用來表示Y 種貝料狀悲,其中X矣γ。在此方式中,記憶體陣列中的一 記憶體單元中儲存的資料狀態數量可在各組記憶體單元之 , 間變化。可組合上文所述之各種多用途與混合多用途。舉 . 例而S,記憶體陣列中的第一組記憶體單元與第二組記憶 體單元可使用不同數量之資料狀態,並且兩者皆係可單次 程式化、兩者皆可重寫,或係可單次程式化與可重寫之混 合。換言之,記憶體陣列的多個部分可係可單次程式化記 憶體單元與可重寫記憶體單元之任何組合,其中一部分儲 I21890.doc -45- 200818204 存χ種資料狀態(例如,+描次,、 兩種負料狀態)並且另一部分儲存γ 種資料狀態(例如,兩德丨v u _ 兩種以上貢料狀態)。舉例而言,記憶 體陣列可具有··一第 、/ 弟組兄憶體單元,其係可單次程式化 並且具有兩種以上眘 ^ 貝科狀恶(例如,用於程式化資料);及 一f二組記憶體單元,其係可重寫並且具有兩種以上資料 ΌΗ用於作為焉速暫存(scratch pad)記憶體)。可有 兩個以上部分。Af. For example, the 记忆-group memory unit 2 process may include in-game valley data (ie, the computer code of the game), and the second group of memory units 220 may include game state data (ie, when the user requests to save An indication of the position of the user in the game during the game). Further, the data in the first set of memory cells 2 or the second set of memory cells 220 can be programmed at the manufacturing facility or by subsequent users. In Fig. 17, there is only one section of a single-programmed memory unit and only one section of a rewritable s-resonance unit. In another embodiment, at least one additional set of memory cells operates as a single-programmable memory cell or a rewritable memory cell. Figure 18 illustrates this embodiment in which two pre-programmed sections 230, 250 are interleaved with two rewritable sections 240, 260 (i.e., two adjacent sets of memory cells are not available) Single stylized or both are rewritable). As described above, any data can be stored in any section. For example, the game content data may be stored in the single-programmable sections 230, 250, and the game state data may be stored in the rewritable sections 240, 260. 121890.doc -41 - 200818204 It should be noted that although 17 and 18 illustrate that the sets of memory cells are oriented in a horizontal manner, but in an alternative embodiment, one or more sets of memory cells can be oriented in a vertical manner. For example, instead of having formatted data in a horizontal column of memory cells (as shown in Figure 17), the formatted material can be tied to a vertical column of memory cells. In this way, redundant data will span many pages. Mixed horizontal orientation and vertical orientation information can also be used. For example, manufacturing materials can be oriented horizontally, while formatted data can be oriented vertically. As shown in FIG. 18, each page of data may include one or more flag bits "❹" indicating whether a page is single-programmable or rewritable. In Figure 18, the πι" flag indicates It can be single-programmed, and the "0" flag indicates rewritable. Preferably, the flag is stored in a single-programmable memory unit (even if the memory unit is in a rewritable section). Furthermore, a preferred method is to optimize the preset read conditions for the single-programmed data (so that the single-programizable flag bits stored in the single-programizable section can be successfully read and Trimming the bits, manufacturing materials, etc.), and modifying the reading conditions if the flag indicates a rewritable lean. One advantage of using flag bits is that it is virtually impossible to use a single-programmed memory cell as a rewritable memory cell, and vice versa, because the on-wafer write circuit interprets the flag. The write-once circuit on the wafer is programmed to prevent more than a second write to the memory cell if the flag indicates that a memory cell is single-programmable. As an alternative to using a flag bit, the address space calculation and write control can be moved to the chip, e.g., to the hardware/software in the host device. 121890.doc -42- 200818204 For example, if a memory device is used as the game device, the software in the host device can use a pre-specified address space for storing game state data (the host device knows the address space) , but the memory does not know the address space). An alternative would be to use a single stylized portion of the memory array that can be stored in the game content data in the memory array (eg, a special address location in the memory array (eg, address 〇) 〇〇〇)) or information in the device controller in the memory device that is separate from the memory array to inform the host device of the address space for the game state data. In the specific embodiment shown in FIG. 17 and FIG. 18, in the sense that some memory cells can be single-programmed memory cells and others are rewritable memory cells, the memory array is mixed. Use &quot;. In other embodiments, instead of or in addition to a single stylized/rewritable feature, the mixed-use &quot;memory array includes other &quot;hybrid&quot; features. As described above, flag cells or Other mechanisms are used to determine the properties of a given set of memory cells. For example, a first set of memory cells in the same memory array can be more reliable than a second set of memory cells and have a wider temperature and voltage range. For example, using the preferred memory cell structure described above, a given memory cell can be programmed (1) with a forward bias (eg, the same single-programmed memory cell or can be heavy) Write memory unit); or (ii) program with reverse bias (for example, the same rewritable memory unit, but different from the two-state single-programmed memory unit). In other words, it can be single The stylized memory unit can only accept forward bias programming, while the rewritable memory unit can accept forward bias programming and 121890.doc -43-200818204 reverse bias programming. See the circuit diagrams of Figures 19 and 20. For a detailed description of forward bias writes, see U.S. Patent No. 6,618,295; and for a detailed description of reverse bias writes, see U.S. Patent Application No. 11/461,339 (Attorney Docket No. 023-0048) entitled "'Passive Element Memory Array Incorporating Reversible Polarity Word Line and Bit Line Decoders" and US Patent Application No. 11/461,364 (Attorney Archives) No. 023-0054) entitled "'Method for Using a Passive Element Memory Array Incorporating Reversible Polarity Word Line and Bit Line Decoders", each of which has been assigned to the assignee of the present invention and is hereby incorporated by reference. Accordingly, "a hybrid n memory array can include: a first set of memory cells that are programmed with forward bias; and a second set of memory cells that are reverse biased Stylized. A memory cell that is programmed with a reverse bias can also be erased with a forward bias. In an erase operation (compared to a write operation), individual data bits in a page are not variables because all bits are erased during the erase operation. For a detailed description of the erasing operation, see U.S. Patent Application Serial No. 11/461,339 (Attorney Docket No. 023-0048) entitled "Passive Element Memory Array Incorporating Reversible Polarity Word Line and Bit Line Decoders&quot; And U.S. Patent Application Serial No. 11/461,364 (Attorney Docket No. 023-0054) entitled &quot;Method for Using a Passive Element Memory Array Incorporating Reversible Polarity Word Line and Bit Line Decoders&quot; It has been assigned to the assignee of the present invention and is hereby incorporated by reference. 121890.doc -44- 200818204, until the end of the discussion about the use of memory cells as a single-program fossil memory unit or as a rewritable memory unit, and memory array = with early stylization A combination of a memory unit and a rewritable memory unit, as described above, another preferred form of memory is that the memory unit (whether it can be single-programmed) The memory unit or the rewritable memory unit can store two data states or two or more data states. The test can be tested for each _ possible data state. How much data can be stored in the memory array. The burdock is 〗. The test memory t-element can be tested in the v, p, s, and R data states to infer whether the memory cell desirably operates as a four-state, single-programmed memory cell. If the memory array fails the test, it can be used as a two-state memory array in which the appropriate flags are stored. This port uses an inverse c memory array that can be used in conjunction with a set of memory cells using x resistivity states to represent the X data states, and together with the Y resistivity states - a second set of memory cells - It is used to represent Y species of beriberi, where X矣γ. In this manner, the number of data states stored in a memory cell in the memory array can vary between groups of memory cells. The various versatile and mixed versatility described above can be combined. For example, S, the first set of memory cells and the second set of memory cells in the memory array can use different numbers of data states, and both can be single-programmed and both can be rewritten. Or a single stylized and rewritable mix. In other words, portions of the memory array can be any combination of a single-programmed memory unit and a rewritable memory unit, some of which store I2890.doc -45-200818204 data status (eg, + description) The second, the two negative states) and the other part stores the gamma data state (for example, two Germans vu _ two or more tributary states). For example, the memory array can have a first or a group of brothers, which can be single-programmed and have more than two types of caution (for example, for stylized data); And a set of two memory cells, which are rewritable and have two or more kinds of data for use as scratch pad memory. There can be more than two parts.

如上文所述,可藉由測試來判定對於任何組記憶體單元 中使用多少資料狀態之選擇。舉例而t,如果因為讀取電 路,涂辨別V、?與R狀態而使四狀態式可單次程式化記憶 體早70未通過測試。則包含彼等測試記憶體單元的記憶體 陣列邛分可用作為兩狀態式可重寫部分。在此情況中,寫 電路可使用反覆式寫程式化(如上文所述)來驗證並且接著 再人重新私式化,以將R狀態&quot;推&quot;向v狀態及將$狀態&quot;推” 向Y狀悲。換言之,反覆式回饋機制,,開放”介於R狀態與S 狀態之間的”空間,,。 具有不同肓料狀態之多用途記憶體陣列認定:事實上, 雖^每圮憶體單元具有儲存兩種以上資料狀態之潛力, 仁疋最具效率使用記憶體陣列中的記憶體單元發生於記憶 體陣列並非所有記憶體單元皆儲存兩種以上狀態時。舉例 而言,在一項較佳具體實施例中,一第一組記憶體單元係 為了單-人秋式化記憶體單元,並且一第二組記憶體單元 二作為可重寫記憶體單元。圖2 1繪示此項具體實施例。在 此具體實施例中,用於讀取四狀態式記憶體單元之最佳電 121890.doc -46 - 200818204 路組態設定被儲存於中兩狀態式記憶體單元。舉例而言, 如圖,頁〇中的組態位元指示出用每記憶體單元兩 狀態式讀取電路操作相對於每記憶體單元四狀態式讀取電 路操作進行讀取的頁。態位元亦判定每記憶體單元 兩狀悲式頁中之可用位元的限制。當寫入頁〇時,組態晶 片中用於兩狀態式資料與四狀態式資料的部分。對於可單 次程式化記憶體單元使用方式,頁〇可被寫入數次以加入 指示出用於兩狀態式資料之額外部分的額外組態位元,因 為組態位元皆設定至邏輯”&quot;,所以指示出除頁。以外,所 有頁皆被讀取為四狀態式資料(即,預設組態係僅讀取頁〇 為兩狀恶式資料留As described above, the choice of how many data states to use in any group of memory cells can be determined by testing. For example, if the circuit is read, what is the difference between V and ? With the R state, the four-state single-programmed memory failed the test 70 times earlier. The memory array segment containing their test memory cells can then be used as a two-state rewritable portion. In this case, the write circuit can be verified using a repetitive write stylization (as described above) and then re-privatized to push the R state &quot;push&quot; to the v state and the $state&quot; "Y-sorrowful. In other words, the repeated feedback mechanism, open" space between the R state and the S state, the multi-purpose memory array with different data states is determined: in fact, although ^ The memory unit has the potential to store more than two data states. The most efficient use of the memory cells in the memory array occurs in the memory array. Not all memory cells store more than two states. For example, In a preferred embodiment, a first set of memory cells is for a single-human autumn memory cell, and a second set of memory cells 2 is a rewritable memory cell. This embodiment is shown. In this embodiment, the optimal configuration for reading the four-state memory unit is stored in the two state memory cells. For example As shown in the figure, the configuration bit in the page indicates the page read by the two-state read circuit operation per memory unit with respect to the operation of the four-state read circuit per memory unit. The state bit also determines that each The limitation of the available bits in the two-bit sad page of the memory unit. When writing to the page, the part of the wafer for the two-state data and the four-state data is configured. For the single-programmed memory unit In this way, the page can be written several times to include additional configuration bits indicating the extra portion for the two-state data, since the configuration bits are all set to logic "&quot;, indicating the page division. In addition, all pages are read as four-state data (ie, the default configuration is only read page 〇 for two-dimensional data retention)

)原生了早=人私式化纪憶體單元狀態(V 狀悲)係邏輯1&quot;。組態位元之預設組態與解譯係藉由記憶 體晶片上的邏輯編碼予以進行。列數與頁數非必然相等, 但較佳係簡單的倍數(例如,四頁對一列)。 田然’其它組態係可行的。舉例而言,另一應用可具有 亦作為每„己^體單%兩狀態式資料之第三部分,其係基於 製,測試指W記憶輯狀第三部分中的次於最佳記憶 體單兀⑽在還有另一應用中,記憶體陣列具有在第一部分 中的可單人&amp;式化記憶體單元以及兩種以上狀態式可重 記憶體單元(例如,你η μ 、』如使用R、S與R1狀態)。最佳電路組態較 仏係儲存於兩狀態式可單次程式化記憶體單元中。另外, 記憶體陣列可且右/络 /、百在弟一部分中的兩狀態式可重寫記憒 單元以及在第二都八丄 &quot; 刀中的兩種以上狀態式可重寫記憶體單 元。 干 121890.doc •47- 200818204 請再次附圖,圖22繪示較佳具體實施 圖解,其巾藉由每—實體i 。.¾體陣列之 田母貫體頁上的旗標位元來指 體單元兩狀態之部分及每記憶體單元四狀旗: 位元較佳係每記憶體單元兩狀態式資料。偶數數 關聯於每一列。經讀取為&quot;「 示出該頁不可用。不可用夕…頁之旗標位元指 不了用之頁亦被儲存在 控制邏輯或軟體中,並且可蕤由匕體日日片外的 制予以重靳户r 了猎由已知之冗餘/不良區塊機 制予以重新扣派。選擇性地,可 其中旗標相關聯於多重頁並 、用旗標位兀’ 單元狀態數量以及二出用於該列之每記憶體 列偶數數可用。較佳方式為,使用每 =二Γ於若干相鄰列,對於不良區塊表使用 的&amp;塊較佳被定義為列的二分之—。 圖23繪示較佳具體實施例之記憶體陣列之 由記憶體陣列中儲存的轉 /、T糟 能夕#八》轉#表朿私不出母記憶體單元兩狀 =^刀及母記憶體單元四狀態之部分。該轉譯表具有記 fe、體陣列中介於邏輯頁 /、 只體列之間的對應。該轉譯 、=L1—實體列處儲存之位元數量的旗標位元。 二該轉譯表亦具有指示出某些頁係可單次程式化 =糸二重寫資料的旗標。旗標位元較佳對於用於指示之資 料類型的最佳設定來控制讀取與寫入電路。 圖,示較佳具體實施例之記憶體陣列之圖解,其中藉 :^體頁上的旗標位元來指示出每記憶體單元兩狀態 °早人私式化αΡ分、每記憶體單元兩狀態可重每 記憶體單元时態可單切式化料。在此具體實施例 121890.doc -48- 200818204 中’旗標位元被儲存為每記憶體單元兩狀態式資料。偶數 數量之頁相關聯於每一列。晶片外控制器掃描旗標資訊以 建立不良區塊表。用於一些頁之旗標位元指示出該頁不可 用。旗標位元亦較佳控制晶片上讀取與寫入電路,以提供 用於每記憶體單元兩狀態式操作及可重寫相對於可單欠程 式化操作的最佳組態。在此情況中,圖24中指示出的旗標 位元至少包含一用以指示出每記憶體單元狀態數量的位元 及一用以指示出可單次程式化或可重寫的位元在一些具體 實施例中,可使用兩個以上位元。 記憶體單元兩狀態之預設設定來讀取位於該初步實體位址 的旗標位元(步驟320)。如要玆百在—) Native early = person privateized memory unit state (V-shaped sadness) is logic 1 &quot;. The default configuration and interpretation of the configuration bits is performed by logic coding on the memory chip. The number of columns is not necessarily equal to the number of pages, but is preferably a simple multiple (for example, four pages to one column). Tian Ran's other configuration systems are feasible. For example, another application may have the third part of the data as a single-state and two-state data, which is based on the system, and the test refers to the second-order best memory in the third part of the memory.兀 (10) In yet another application, the memory array has a single-person &-memory memory unit in the first portion and two or more state-of-the-art re-memory units (eg, you η μ, 』 R, S and R1 states). The optimal circuit configuration is stored in a two-state single-programmed memory unit. In addition, the memory array can be two of the right/network/partial part. The state-of-the-art rewritable memory unit and the two or more state-of-the-art rewritable memory units in the second omnibus &quot; knife. Dry 121890.doc •47- 200818204 Please refer to the figure again, Figure 22 shows A specific implementation diagram, the towel is represented by the flag bit on the field of the body matrix of each entity i.. 3⁄4 body array refers to the two states of the body unit and the four-character flag of each memory unit: Good system two state data per memory unit. Even number is associated with each column Read as &quot;" shows that the page is not available. It is not available. The page flag of the page can not be used. It is also stored in the control logic or software, and can be used by the body outside the day. The system is re-delegated by known redundant/bad block mechanisms. Alternatively, the flag can be associated with multiple pages, with the flag number 兀 'unit status number and two The number of even columns per memory column for the column is available. Preferably, each square is used for a number of adjacent columns, and the &amp; block used for the bad block table is preferably defined as a binary of the column. FIG. 23 is a diagram showing the memory array of the preferred embodiment of the memory array stored in the memory array, and the T memory can be stored in the memory array. The portion of the four-state of the body unit. The translation table has a correspondence between the logical page/the body column in the body array, and the translation, =L1—the flag bit of the number of bits stored in the entity column. 2. The translation table also has instructions indicating that certain pages can be single-programmed = 糸 two rewritten materials. The flag, the flag bit, preferably controls the read and write circuits for the optimal setting of the type of data used for the indication. Figure is a diagram showing a memory array of a preferred embodiment, wherein: The upper flag bit indicates the two states of each memory unit. The early humanized αΡ points, the two states of each memory unit can be weighted, and the memory unit states can be single-cut material. 121890.doc -48- 200818204 The 'flag bit is stored as two state data per memory unit. An even number of pages are associated with each column. The off-chip controller scans the flag information to create a bad block table. A flag bit for some pages indicates that the page is not available. The flag bit also preferably controls the read and write circuits on the wafer to provide two state operations and rewritable relative to each memory cell. The best configuration for single-programming operations. In this case, the flag bit indicated in FIG. 24 includes at least one bit for indicating the number of states per memory unit and a bit for indicating that it can be single-programmed or rewritable. In some embodiments, more than two bits can be used. A preset setting of the two states of the memory unit reads the flag bit located at the preliminary physical address (step 320). If you want to be in the company -

或寫入頁資料(步驟35〇:)。 圖25繪使用晶片旗標與晶片外不良區塊機制之較佳具體 實施例的流程圖。提供一邏輯頁位址(步驟3〇〇)。記憶-裝 置之控制器晶片中的一不良區塊表與轉譯邏輯判定一相關 聯於該邏輯頁位址的初步實體位址(步驟31〇)。接著,用每Or write the page data (step 35〇:). Figure 25 depicts a flow diagram of a preferred embodiment using a wafer flag and an off-chip bad block mechanism. Provide a logical page address (step 3〇〇). A bad block table in the controller-memory controller wafer is associated with the translation logic to determine a preliminary physical address associated with the logical page address (step 31). Then, with each

一 TLlDlnary)金屬氧化物、 其它可切換式電阻材料包括(但不限於) ^化物、相變材料(如美國專利案第 I21890.doc -49- 200818204 5,751,012號及美國專利案第4,646,266號所示)及有機材料 電阻器’舉例而言’包括若干有機材料層之記憶體單元, 其包括具有似二極體特性傳導之至少一層及施.加電場來變 更傳導率的至少一有機材料。美國專利案第0,055,180號描 述有機被動το件陣列。另一可變電阻材料係摻雜有v、 Co Ni、Pd、Fe或Μη之非晶系矽,舉例而言,如美國專 利案第5,541,869號中更充分描述所述。美國專利案第 6,473,332號巾講授另-類別材料。彼等材料係_鈦礦材料, 諸如 PmCaxMn〇3 (PCM0)、Lai xCaxMn〇3 (LCM〇)、A TL1Dlnary) metal oxide, other switchable resistive material includes, but is not limited to, a compound, a phase change material (e.g., U.S. Patent No. I21890.doc-49-200818204 5,751,012 and U.S. Patent No. 4,646,266 And an organic material resistor 'for example' includes a plurality of memory cells of an organic material layer comprising at least one layer having a conductivity-like conductivity and at least one organic material applying an electric field to change the conductivity. U.S. Patent No. 0,055,180 describes an array of organic passive τ. Another varistor material is an amorphous ruthenium doped with v, Co Ni, Pd, Fe or Mn, as described more fully in U.S. Patent No. 5,541,869. U.S. Patent No. 6,473,332 teaches another-category material. These materials are _ titanium ore materials, such as PmCaxMn〇3 (PCM0), Lai xCaxMn〇3 (LCM〇),

LaSrMn03 (LSMO)或 GdBaCox〇Y (GBCO)。此可變電阻材 料之另一選項係碳聚合物膜,其包含(舉例而言)混合於塑 料聚合物中之碳黑微粒或石墨,如美國專利案第 號之講授。美國專利申請案第〇9/943,190號中及美國專利 申請案第09/941,544號中講授另一可切換式電阻材料。此 材料係經摻雜分子式AXBY之硫族玻璃,其中A包含週期表 之下列至少一元素:第⑴八族(B、A卜Ga、In、Ti)、第 IVA族(C、Si、Ge、Sn、Pb)、第 VA族(N、P、As、Sb、 Bi)或第VIIA族(F、Cl、Br、I、At);其中B係選自s、以與 Te及其混合物。摻雜物係選自貴金屬(n〇Me met卟及過渡 金屬,包括 Ag、An、Pt、Cu、Cd、Ir、Ru、c〇、Cr、Mn 或Ni。此硫族玻璃(非晶系硫族,而非結晶狀態)較佳係形 成於相鄰於移動金屬離子儲藏器之記憶體單元中。可用某 其它固體電解質材料來取代硫族玻璃。 在一項較佳具體實施例中,元件包括串聯於半導體材料 121890.doc •50- 200818204 之反熔絲。在另—項較佳具體實施例中,記憶體元件包括 反熔絲、二元金屬氧化物及複晶矽二極體隔離裝置。另 外,雖然記憶體單元可係二維記憶體陣列之部件,但是較 仏方式為,圯憶體單元係單片三維記憶體陣列之部件,其 中記憶體單元經排列於複數層記憶體層級中,每一記憶體 層級經形成在-單一基板上方並且無任何中介基板。 目前較佳方式為,記憶體元件係非揮發性。但是,在一 項替代具體實施例中,在記憶體元件運作為可重寫記憶體 單元時使用的資料狀態中,記憶體元件可係揮發性。舉例 而言’記憶體元件可允許乂狀態與p狀態成為永久性,但是 可允許R狀態與s狀態緩慢衰落。運用此—記憶體元件,R 狀態與S狀態將隨時間重新刷新。 如文詳細說明僅描述本發明可援用 、 今私π J休用之許多形式中的少數 心式。基於此原因’詳細說明孫音办ά 汗況明係思欲精由闡釋說明,而不 是限制本發明。僅下列請求頊f句技 月承項(包括所有同等項)係旨在定 義本發明的範疇。 【圖式簡單說明】 ‘ 圖1綠示在記憶體陣列中介於記怜 J &quot;方…ώ II體皁元之間的電隔離 所需的電路圖。 圖2纟會示根據本發明較佳且濟眚 1主篮貝苑例形成之多狀態或可 重寫記憶體單元之剖視圖。 圖3、纟會不包括圖2所示之記情辦置_ 己U體早兀的記憶體層級之一部 分的剖視圖。 圖4繪示本發明之記憶體覃矣 早兀的靖取電流隨著跨二極體 121890.doc -51- 200818204 之逆向偏壓電壓增大而改變的圖表。 圖5緣示記憶體單元自v狀態變換至p狀態、自p狀態變 換至R狀態及自R狀態變換至S狀態的機率標緣圖。 圖6繪示記憶體單元自V狀態變換至P狀態、自P狀態變 換至S狀態及自S狀態變換至R狀態的機率標繪圖。 圖7繪示記憶體單元自V狀態變換至r狀態、自r狀態變 換至S狀態及自s狀態變換至p狀態的機率標繪圖。 圖8繪示可在本發明具體實施例中使用之垂直定向p-i_n 二極體的剖視圖。 圖9繪示記憶體單元自v狀態變換至p狀態及自p狀態變 換至Μ狀態的機率標繪圖。 圖10繪示根據本發明較佳具體實施例形成之多狀態或可 重寫記憶體單元之剖視圖。 圖11繪示記憶體單元自ν狀態變換至Ρ狀態、自Ρ狀態變 換至R狀態及自R狀態變換至s狀態、接著可重複於8狀態 與R狀態之間的機率標繪圖。 圖12繪不以正向偏壓加偏壓於8記憶體單元之加偏壓方 案的電路圖。 圖13繪示以逆向偏壓加偏壓於3記憶體單元之加偏壓方 案的電路圖。 圖14繪不反覆性讀取_驗證_寫入循環以使記憶體單元移 動進入資料狀態。 圖15a至15c繪示根據本發明具體實施例形成之記憶體層 級形成中階段的剖面圖。 121890.doc -52- 200818204 圖16繪示可在本發明替代具體實施例中使用之二極體與 電阻式切換元件的剖面圖。 圖17綠示較佳具體貪施例之混合用途記憶體陣列之圖 解’其中一第一組記憶體單元運作為可單次程式化記憶體 單兀’及一第二組記憶體單元運作為可重寫記憶體單元。 圖18缘示較佳具體實施例之混合用途記憶體陣列之圖 解’其中交錯多組可單次程式化記憶體單元與可重寫記憶 體單元。 圖19、、會示較佳具體實施例之電路之圖解,其展示用正向 偏壓予以程式化之一組記憶體單元。 圖20緣示較佳具體實施例之電路之圖解,其展示用逆向 偏壓予以程式化之一組記憶體單元。 圖21緣示較佳具體實施例之記憶體陣列之圖解,其中該 A fe體陣列之一第一部分儲存每記憶體單元兩種資料狀態 及該記憶體P車列之―第—部分儲存每記憶體單元四種資料 狀態。 圖22繪不較佳具體實施例之記憶體陣列之圖解,其中藉 由每貝體頁上的旗標位元來指示出每記憶體單元兩狀態 之部分及每記憶體單元四狀態之部分。 圖23 '、、日tf #又&gt;[土具體實施例之記憶體陣列之圖解,其中藉 由記憶體陣列中儲存的鐘士罢主也 仔的轉泽表來指示出每記憶體單元兩狀 悲、之部分及每記憶體單元四狀態之部分。 圖24緣示較佳具體實施例之記憶體陣狀圖解,其中藉 由每實體頁上的旗標位元來指示出每記憶體單元兩狀態 121890.doc -53- 200818204 可單次程式化部分、每記憶體單元兩狀態可重寫部分及每 記憶體單元四狀態可單次程式化部分。 圖25繪使用晶片旗標與晶片外不良區塊機制之較佳具體 實施例的流程圖。 【主要元件符號說明】LaSrMn03 (LSMO) or GdBaCox〇Y (GBCO). Another option for this variable resistance material is a carbon polymer film comprising, for example, carbon black particles or graphite mixed in a plastic polymer, as taught in U.S. Patent No.. Another switchable resistive material is taught in U.S. Patent Application Serial No. 9/943, 190, and U.S. Patent Application Serial No. 09/941,544. This material is a chalcogenide glass doped with the molecular formula AXBY, wherein A contains at least one of the following elements of the periodic table: Group (1) Group 8 (B, A, Ga, In, Ti), Group IVA (C, Si, Ge, Sn, Pb), Group VA (N, P, As, Sb, Bi) or Group VIIA (F, Cl, Br, I, At); wherein the B is selected from the group consisting of s, with Te and mixtures thereof. The dopant is selected from the group consisting of noble metals (n〇Me met卟 and transition metals, including Ag, An, Pt, Cu, Cd, Ir, Ru, c〇, Cr, Mn or Ni. This chalcogenide glass (amorphous sulfur) The family, rather than the crystalline state, is preferably formed in a memory cell adjacent to the mobile metal ion reservoir. Some other solid electrolyte material may be substituted for the chalcogenide glass. In a preferred embodiment, the component comprises The antifuse is connected in series to the semiconductor material 121890.doc • 50-200818204. In another preferred embodiment, the memory component comprises an antifuse, a binary metal oxide, and a polysilicon germanium isolation device. In addition, although the memory unit can be a component of the two-dimensional memory array, in a more conventional manner, the memory unit is a component of a single-chip three-dimensional memory array, wherein the memory unit is arranged in a plurality of layers of memory, Each memory level is formed over a single substrate and without any interposer. It is presently preferred that the memory elements are non-volatile. However, in an alternate embodiment, the memory elements operate. In the data state used when the memory cell can be rewritten, the memory component can be volatile. For example, the 'memory component can allow the chirp state and the p state to be permanent, but can allow the R state and the s state to slowly fade. Using this-memory component, the R state and the S state will be refreshed over time. As described in detail, only a few of the many forms of the present invention can be used, and for many reasons, for this reason, The syllabus of the syllabus is to explain the invention, not to limit the invention. Only the following requests (including all equivalents) are intended to define the scope of the invention. Description] Figure 1 shows the circuit diagram required for electrical isolation between the memory cells in the memory array. Figure 2纟 shows a better and better mode according to the present invention. A cross-sectional view of a multi-state or rewritable memory cell formed by the example of a basket. Figure 3 is a cross-sectional view of a portion of the memory level of the memory device shown in Figure 2. 4 depicts the record of the present invention Recall that the current of the body is changed as the reverse bias voltage across the diodes 121890.doc -51- 200818204 increases. Figure 5 shows that the memory cell changes from the v state to the p state, Figure 6 shows the memory cell transition from V state to P state, P state to S state, and S state transition to R. Figure 7 illustrates the probability plot of the memory unit transitioning from the V state to the r state, the transition from the r state to the S state, and the transition from the s state to the p state. Figure 8 illustrates that the present invention can be embodied in the present invention. A cross-sectional view of a vertically oriented p-i_n diode used in the embodiment. Figure 9 illustrates a probability plot of a memory cell transitioning from a v state to a p state and from a p state to a chirp state. 10 is a cross-sectional view of a multi-state or rewritable memory cell formed in accordance with a preferred embodiment of the present invention. Fig. 11 is a diagram showing the probability of the memory cell changing from the ν state to the Ρ state, the self-turning state to the R state, and the transition from the R state to the s state, and then repeatable between the 8 state and the R state. Figure 12 depicts a circuit diagram of a biasing scheme that does not bias the 8 memory cells with a forward bias. Figure 13 is a circuit diagram showing the biasing scheme for biasing the three memory cells with a reverse bias. Figure 14 depicts a non-repetitive read_verify_write cycle to move the memory cells into the data state. 15a through 15c are cross-sectional views showing stages in the formation of a memory level formed in accordance with an embodiment of the present invention. 121890.doc -52- 200818204 Figure 16 is a cross-sectional view of a diode and a resistive switching element that can be used in an alternative embodiment of the present invention. Figure 17 is a diagram showing a preferred embodiment of a mixed-use memory array in which a first group of memory cells operate as a single-programmed memory cell and a second group of memory cells operate as Overwrite the memory unit. Figure 18 is a schematic illustration of a mixed-use memory array of the preferred embodiment in which a plurality of sets of single-programmable memory cells and rewritable memory cells are interleaved. Figure 19 is a diagram showing a circuit of a preferred embodiment showing a group of memory cells programmed with forward bias. Figure 20 is a schematic illustration of a circuit of a preferred embodiment showing the programming of a set of memory cells with a reverse bias. Figure 21 is a diagram showing a memory array of a preferred embodiment, wherein the first portion of the A fe body array stores two data states per memory cell and the first portion of the memory P train stores each memory Four data states of the body unit. Figure 22 depicts an illustration of a memory array in a non-better embodiment in which portions of each state of each memory cell and portions of four states of each memory cell are indicated by flag bits on each bay page. Figure 23 ',, day tf #又&gt; [Illustration of the memory array of the concrete embodiment, wherein each memory unit is indicated by a clock table stored in the memory array. The sorrow, the part, and the four states of each memory unit. Figure 24 is a block diagram of a memory array of a preferred embodiment, wherein the two states of each memory unit are indicated by a flag bit on each physical page. 121890.doc -53 - 200818204 can be a single stylized portion The two-state rewritable portion of each memory unit and the four-state single-programmed portion of each memory unit. Figure 25 depicts a flow diagram of a preferred embodiment using a wafer flag and an off-chip bad block mechanism. [Main component symbol description]

2 複晶半導體二極體 4 底部重摻雜n^}區(圖2) 4 底部重摻雜p型區(圖8) 6 本質區 8 頂部重摻雜區(圖2) 8 頂部重捧雜η型區(圖8) 12 底部導體 14 介電破裂反熔絲 16 頂部導體 100 基板 102 絕緣層 104 黏著層 106 傳導層 108 介電材料 109 平坦表面 110 阻障層 111 二極體 112 底部重摻雜區 114 本質層 12I890.doc -54- 2008182042 polycrystalline semiconductor diode 4 bottom heavily doped n^} region (Figure 2) 4 bottom heavily doped p-type region (Figure 8) 6 essential region 8 top heavily doped region (Figure 2) 8 top heavy miscellaneous N-type region (Fig. 8) 12 bottom conductor 14 dielectric rupture antifuse 16 top conductor 100 substrate 102 insulating layer 104 adhesive layer 106 conductive layer 108 dielectric material 109 flat surface 110 barrier layer 111 diode 112 bottom doping Miscellaneous Zone 114 Essential Layer 12I890.doc -54- 200818204

116 頂部重摻雜p型區 117 可切換式記憶體元件 118 介電破裂反熔絲層 120 黏著層 122 傳導層 200 導體(第一導體;導體執;底部導 體)(圖 15a-c) 200 記憶體陣列(圖17) 210 第一組記憶體單元 220 第二組記憶體單元 230, 250 可單次程式化區段 240, 260 可重寫區段 270 旗標位元 300 柱 400 導體(導體執;頂部導體) A,A0, A1 字線 B, BO, B1 位元線 F,H 半所擇記憶體單元 U 非所擇記憶體單元 M,P,R,S,V 記憶體單元之資料狀態 Ul,U2, U3 非所擇記憶體單元 121890.doc -55-116 top heavily doped p-type region 117 switchable memory element 118 dielectric rupture anti-fuse layer 120 adhesive layer 122 conductive layer 200 conductor (first conductor; conductor; bottom conductor) (Fig. 15a-c) 200 memory Body array (Fig. 17) 210 The first group of memory units 220 The second group of memory units 230, 250 can be a single programd section 240, 260 rewritable section 270 flag bit 300 column 400 conductor (conductor implementation ; top conductor) A, A0, A1 word line B, BO, B1 bit line F, H semi-selected memory unit U non-selected memory unit M, P, R, S, V memory unit data status Ul, U2, U3 Unselected memory unit 121890.doc -55-

Claims (1)

200818204 十、申請專利範圍: 1· 一種記憶體陣列,包括.· 複數個記憶體單元, ^ 母一記憶體單元包括一 ~ K立祕 件,該記憶體元件包括 匕括以思體元 J組恶至至少二插蕾 之-者的-可切換式電阻材料;-電阻率狀態中 其中該複數個記憶體單元包括: -第-組記憶體單元广其使 示X種各自資料狀態;及 D革狀恶來表 弟—組讀、體單元,其使用Y種電 不Y種各自資料狀態,其中χ^。 狀也來表 2·如請求項丨之記憶體 用雨鍤Φ七 ,、中該弟一組記憶體單元# 用兩種電阻率狀態來表 使 筮一, 不兩種各自育料狀態;及盆中兮 -、、“己憶體單元使用兩種以上電 :- 以上各自資料狀態。 υ表不兩種 3·如請求項丨之記憶體陣苴 用雨絲兩 八中該弟一組圮憶體單元使 〜 阻率狀態來表示兩種各自資料狀態,·及其中誃 :::1:憶體單元使用四種電阻率狀態來表示四種各: 4· ^求们之記憶體陣列’其中㈣二組記憶體單元儲 子全頁資料,並且其中該第'组記憶體單元 一全頁資料。 、 5.:請:項4之記憶體陣列’其中該第一組記憶體 ^ 一 +頁資料。 6·如研永項1之記憶體陣列’其中對於該第一組記憶體單 121890.doc 200818204 元中及該第二組記憶體單元中的既定數晉 - ▲ 里又§己憶體單 &quot;亥第一組§己憶體單元中的該等記憶體單元所儲存的 資料少於該第二組記憶體單元中的該等記憶體單元=儲 存的資料。 7.如請求項丨之記憶體陣列,其中該第一組記憶體單元儲 列項目中之一或多者:内容管理位元、修整位元、 ‘ 製造商資料或格式化資料。 8·如=求項i之記憶體陣列,其中該第一組記憶體單元及 該弟二組記憶體單元兩者皆運作為可單次程式化記憶體 皁元。 .:求項1之記憶體陣列’其中該第一組記憶體單元及 =^記憶體單元中之—者運作為可單切式化記憶 —:几’以及該第一組記憶體單元及該第二組記憶體單 70之另一者運作為可重寫記憶體單元 1。·::求項9之記憶體陣列’其中該第一組記億體單元運 • 體::可平次程式化記憶體單元,並且其中該第二組記憶 -早凡運作為可重寫記憶體單元。 11 ·如凊求項9之記憶體陣苴 作為π w T該弟一組記憶體單元運 , ^早次程式化記憶體單元,並且其中細々产 體罝;、宏&quot; /、τ邊第一組#己f思 , 運作為可重寫記憶體單元。 12.如請求们之記憶 該第-知a /、T以弟一組纪憶體單元及 Ί憶體單元兩者皆運作為 13·如請求項丨十』&amp; 里馬记fe體早兀。 、1之圮k體陣列,其中該第一組 括一列記恃I# I w 體早兀 匕體早凡,該列記憶體單元儲存第一數量之頁 121890.doc 200818204 ,並且其中該第二組記憶 記憶體單元,該相同大小之_體二二大小之列 数里的第一數量之頁資料。 乐 之記憶料列,其中該記 於該可切換式電阻材料之—反炼絲。 ^括串聯 15. 如請求们之記憶體陣列,其 含-半導體材料。 刀換式電阻材料包200818204 X. Patent application scope: 1. A memory array, including: a plurality of memory cells, ^ mother-memory unit includes a ~K secret member, the memory component includes a group of a switchable resistive material of at least two buds; wherein the plurality of memory cells in the resistivity state comprises: - a first set of memory cells that broadly indicate X respective data states; and D The leather-like evil cousin - group reading, body unit, which uses Y kinds of electricity and not Y kinds of data status, of which χ ^. The shape is also shown in Table 2. If the memory of the request item is 锸 七 VII, the middle memory group of the memory unit # uses two resistivity states to make the 筮 one, not the two respective brooding states; In the basin, 兮-,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, The body unit makes the ~ resistivity state to represent the two respective data states, and its middle:::1: the memory cell uses four resistivity states to represent each of the four: 4·^ (4) Two sets of memory cell storage full page data, and wherein the first 'group memory unit is a full page of data. 5.: Please: Item 4 of the memory array 'where the first set of memory ^ one + page data. 6. If the memory array of the research project 1 is in the first group of memory, 121890.doc 200818204 and the predetermined number in the second group of memory cells - ▲ 里 里 忆 体 体 quot ; the first group of §   memory cells stored in the memory unit Less than the memory cells in the second set of memory cells = stored data. 7. The memory array of the request, wherein the first set of memory cells stores one or more of the items : content management bit, trim bit, 'manufacturer data or formatted data. 8. If the memory array of the item i, the first group of memory cells and the two groups of memory cells are both The operation is a single-programmed memory soap element.: The memory array of claim 1 wherein the first group of memory cells and the memory cells of the memory device operate as a single-cut memory-: The other one of the first group of memory cells and the second group of memory cells 70 operates as a rewritable memory cell 1. In addition: the memory array of claim 9 wherein the first group of records Billion unit transport body:: can be a flat program memory unit, and the second group of memory - early operation as a rewritable memory unit. 11 · If the memory of the item 9 is π w T, a group of memory cells, ^ early stylized memory cells, and Among them, the fine body of the body;; macro &quot; /, τ side of the first group # own thinking, operating as a rewritable memory unit. 12. If the memory of the requester - know a /, T to a group Both the memory unit and the memory unit operate as 13 · as requested in the article 』 』 』 里 fe fe fe 体 兀 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 体 体 体 体 体 体 体# I w The body of the memory is stored earlier, the column of memory cells stores the first number of pages 121890.doc 200818204, and wherein the second group of memory cells, the same size of the body size The first number of pages in the database. The music memory column, which is recorded in the switchable resistive material - the anti-refining wire. ^ Include series. 15. As requested by the memory array, it contains - semiconductor material. Knife-changing resistor package 16. =求項15之記憶體陣列,其中該半導體材料包括—複 晶矽二極體。 稷 片二=^ 1之Z 11體陣列,其中該每憶體陣列包括一單 複二記憶體陣列,其中該複數個記憶體單元經排列於 曰a憶體層級中,每—記憶體層級經形成在—單一 基板上方並且無任何中介基板。 18.—種使用-記憶體陣列之方法,該方法包括: 二提供:記憶體陣列’該記憶體陣列包括複數個記 思一-早元,每一圮憶體單元包括一記憶體元件,該 體元件包括可組態至至少三種電阻率狀態中之_者的: 可切換式電阻材料; (b) 在一第一組記憶體單元中,使用x種電阻 來表示X種各自資料狀態;及 〜、 (c) 在一第二組記憶體單元中,使用γ種電阻率狀離 來表不Υ種各自資料狀態,其中X赛Υ 〇 19.如5月求項18之方法,其中X係2,Υ係;2以上。 2〇.如請求項18項之方法,進一步包括: 121890.doc 200818204 在该s t思體陣列中儲在百-欠』, τ僻存一頁貧料及一相關聯之至少一 組態位元,該至少一釦At, 恶位70指示出一第一或第二操作 模式。 21· 如請求項20之方法,其中該至少 同於該頁資料的實體列中。 組態位元被儲存在相 22.如請求項20之方沐 甘+ 、 套,、中用於複數個頁資料的組態位元 被健存在該記憶體陣列的一 _ ^ ? ^ κ體列中,該實體列不同於16. The memory array of claim 15, wherein the semiconductor material comprises a polycrystalline germanium diode. The Z 11 body array of the slice 2=^1, wherein the array of each memory includes a single complex memory array, wherein the plurality of memory cells are arranged in the level of the memory layer, each memory level Formed on top of a single substrate and without any interposer. 18. A method of using a memory array, the method comprising: providing: a memory array 'the memory array comprising a plurality of memory-early elements, each memory unit comprising a memory element, The body element includes configurable to at least three of the resistivity states: a switchable resistive material; (b) in a first set of memory cells, x types of resistors are used to represent the respective data states of the X species; ~, (c) In a second group of memory cells, using γ kinds of resistivity to distinguish the respective data states, where X races 〇 19. as in May, the method of claim 18, where X system 2, tethered; 2 or more. 2. The method of claim 18, further comprising: 121890.doc 200818204 storing in the st-shaped array in a hundred-negative, τ a page of poor materials and an associated at least one configuration bit, The at least one buckle At, the bad position 70 indicates a first or second mode of operation. 21. The method of claim 20, wherein the method is at least the same as the entity column of the page material. The configuration bit is stored in phase 22. As in the request item 20, the configuration bits for the plurality of page data are stored in a _ ^ ^ ^ κ body of the memory array. In the column, the entity column is different 儲存該相關聯之頁資料的該等實體列。 23·如請求項20之方法,進一步包括·· 讀取該至少一組態位元; 如果該至少-組態位元指示出該第一操作模式,則控 制讀取電路以辨別一記憶體單元中的兩種資料狀態;及 如果該至少-組態位元指示出該第二操作模式,則控 制讀取電路以辨別一記憶體單元中的至少三種資料狀 態。 、 24·如請求項2〇項之方法,進一步包括·· 讀取該至少一組態位元; 如果該至少一組態位元指示出該第一操作模式,則控 制寫電路以在一記憶體單元中程式化兩種資料狀態中之 一者;及 如果該至少一組態位元指示出該第二操作模式,則控 制寫電路以在一記憶體單元中程式化至少三種資料狀態 中之一者。 &quot; 25.如請求項20之方法,其中該至少一組態位元包括兩種資 121890.doc 200818204 料狀態’甚至對於台扭a I栝母记憶體單元兩種以上資料狀態 的資料頁。 26·如請求項18之方法, 進一步包括在(b)及(c)之前: 測试该§己憶體陣列由 J中的一組測試記憶體單元; 預測該記憶體陣列 J中的該弟一組記憶體單元將使用兩 種各自資料狀態而未 禾予以正確程式化;及 預測該記憶體陣列中的該第二組記憶體單元將使用兩 種各自貧料狀態而予以正確程式化。 27.如請求項18之方法 . ^ 進一步包括: 在該第一組記怜髀g — ^體早7L中程式化下列項目中之一或多 者:内容管理位元、欲針, 修I位TL、製造商資料或格式化資 料0The columns of entities that store the associated page data. 23. The method of claim 20, further comprising: reading the at least one configuration bit; if the at least - configuration bit indicates the first mode of operation, controlling the read circuit to identify a memory cell Two of the data states; and if the at least-configured bit indicates the second mode of operation, controlling the read circuit to identify at least three data states in a memory cell. The method of claim 2, further comprising: reading the at least one configuration bit; if the at least one configuration bit indicates the first operation mode, controlling the write circuit to be in a memory One of the two data states being programmed in the body unit; and if the at least one configuration bit indicates the second mode of operation, controlling the write circuit to program the at least three data states in a memory unit One. [25] The method of claim 20, wherein the at least one configuration bit comprises two materials 121890.doc 200818204 material status 'even for the data sheet of the two or more data states of the device . 26. The method of claim 18, further comprising before (b) and (c): testing the § memory array by a set of test memory cells in J; predicting the brother in the memory array J A set of memory cells will use two respective data states without proper programming; and predict that the second set of memory cells in the memory array will be properly programmed using two respective lean states. 27. The method of claim 18. ^ Further comprising: stylizing one or more of the following items in the first group of pity g - ^ body 7L: content management bit, pin, repair bit TL, manufacturer data or formatted data0 如請求項18之方法,甘士 八中該記憶體元件包括串聯於該可 切換式電阻材料之一反熔絲。 如叫求項18之方法,其中該可切換式電阻材料包含一半 導體材料。 3〇·如請求項29之方法,其中該半導體材料包括一複晶石夕二 極體。 31·如請求項18之方法,其中該記憶體陣列包括一單片三維 °己隐體陣列’其+該複數個記憶體單元經排列於複數層 。己k體層級中,每一記憶體層級經形成在一單一基板上 方並且無任何中介基板。 121890.docThe method of claim 18, wherein the memory component comprises an antifuse connected in series with the switchable resistive material. The method of claim 18, wherein the switchable resistive material comprises half of the conductor material. The method of claim 29, wherein the semiconductor material comprises a polycrystalline spine. 31. The method of claim 18, wherein the memory array comprises a monolithic three-dimensional hidden array&apos; + + the plurality of memory cells are arranged in a plurality of layers. In the k-level, each memory level is formed over a single substrate and without any interposer. 121890.doc
TW096123303A 2006-07-31 2007-06-27 Mixed-use memory array with different data states and method for use therewith TWI483262B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/496,870 US20080025069A1 (en) 2006-07-31 2006-07-31 Mixed-use memory array with different data states
US11/497,021 US7486537B2 (en) 2006-07-31 2006-07-31 Method for using a mixed-use memory array with different data states

Publications (2)

Publication Number Publication Date
TW200818204A true TW200818204A (en) 2008-04-16
TWI483262B TWI483262B (en) 2015-05-01

Family

ID=38997615

Family Applications (1)

Application Number Title Priority Date Filing Date
TW096123303A TWI483262B (en) 2006-07-31 2007-06-27 Mixed-use memory array with different data states and method for use therewith

Country Status (2)

Country Link
TW (1) TWI483262B (en)
WO (1) WO2008016421A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI409881B (en) * 2008-11-26 2013-09-21 國立大學法人東北大學 Semiconductor device manufacturing method

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0788113B1 (en) * 1996-01-31 2005-08-24 STMicroelectronics S.r.l. Multilevel memory circuits and corresponding reading and writing methods
US6034882A (en) * 1998-11-16 2000-03-07 Matrix Semiconductor, Inc. Vertically stacked field programmable nonvolatile memory and method of fabrication
US6420215B1 (en) * 2000-04-28 2002-07-16 Matrix Semiconductor, Inc. Three-dimensional memory array and method of fabrication
US6483734B1 (en) * 2001-11-26 2002-11-19 Hewlett Packard Company Memory device having memory cells capable of four states
US6768661B2 (en) * 2002-06-27 2004-07-27 Matrix Semiconductor, Inc. Multiple-mode memory and method for forming same
DE102004029939A1 (en) * 2004-06-21 2006-01-12 Infineon Technologies Ag Memory cell component with non-volatile memory (NVM) cells with cells distributed in memory sections so configured that cells of a memory section

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI409881B (en) * 2008-11-26 2013-09-21 國立大學法人東北大學 Semiconductor device manufacturing method

Also Published As

Publication number Publication date
TWI483262B (en) 2015-05-01
WO2008016421A2 (en) 2008-02-07
WO2008016421A3 (en) 2008-05-02

Similar Documents

Publication Publication Date Title
US7447056B2 (en) Method for using a multi-use memory cell and memory array
US7450414B2 (en) Method for using a mixed-use memory array
EP1929525B1 (en) Method for using a memory cell comprising switchable semiconductor memory element with trimmable resistance
US7660181B2 (en) Method of making non-volatile memory cell with embedded antifuse
KR101652826B1 (en) Semiconductor Devices and Method of Driving the Same
US7830697B2 (en) High forward current diodes for reverse write 3D cell
US7486537B2 (en) Method for using a mixed-use memory array with different data states
US8008700B2 (en) Non-volatile memory cell with embedded antifuse
US7800934B2 (en) Programming methods to increase window for reverse write 3D cell
US7684226B2 (en) Method of making high forward current diodes for reverse write 3D cell
JP2006510220A (en) Memory and access device
US20080023790A1 (en) Mixed-use memory array
US20080025069A1 (en) Mixed-use memory array with different data states
TWI508307B (en) Non-volatile memory containing carbon or nitrogen doped diode and manufacturing method thereof
TW200917255A (en) High forward current diodes for reverse write 3D cell and method of making thereof
US20250253004A1 (en) One-Time Programmable (OTP) Memory and Method of Operating the Same
TWI441182B (en) Multi-use memory cell and memory array and method for use therewith
TW200818204A (en) Mixed-use memory array with different data states and method for use therewith
TWI455130B (en) Mixed-use memory array and method for use therewith

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees