TW200803909A - Oil-based liquid cleansing composition - Google Patents

Abstract

It is intended to provide an oil-based liquid cleansing composition which has a high cleansing ability, an excellent ability to blend with a makeup cosmetic, is easy to be washed out, and has an excellent ability to be used with wet hands. The oil-based liquid cleansing composition is characterized by containing a diester of a fatty acid having 6 to 10 carbon atoms and a dihydric alcohol, and a nonionic surfactant.

Description

200803909 • IX. Description of the Invention: [Technical Field of the Invention] The present invention relates to an oily liquid makeup remover composition. Recently, an oily liquid cleansing composition for the purpose of removing skin dirt or makeup cosmetics has been sold on the market. The oil-repellent liquid cleansing composition has a makeup remover effect superior to that of the smear-shaped or sulphate-like compound, or a water-repellent or gel-like makeup remover. At present, a technique for improving the viscosity of an oily liquid makeup remover has been developed (Patent Document 1 pp 2 GG3-267835, Patent Document 2, JP-A-5_2), and the use of a composition for improving oily liquid makeup remover. A technique that can be used even if the hand is wet (Patent Document 3). In the case of the above-mentioned technology, the company has been continually researching and applying for the above-mentioned technology (patent document No. 2, No. 2.252726, and Japanese Patent Laid-Open No. Hei-5,2691).幵 However, the market has developed (4) water-based, oil-rich and other long-lasting color cosmetics, so the development of New Zealand is better __The composition is subject to the period ^. [Patent Document 1] Japanese Patent Laid-Open Publication No. 2003-267835. [Patent Document 2] Japanese Laid-Open Patent Publication No. 2005-194249 (Patent Document 3) Japanese Laid-Open Patent Publication No. Hei. No. Hei. SUMMARY OF THE INVENTION The object of the present invention is to provide an oily liquid cleansing agent which has a high detergency, can sufficiently dissolve facial makeup, is easy to rinse, and can be used even if the hand is wet. combination. The main structure of the present invention is as follows. . 〇) - An oily liquid cleansing composition comprising a diester of a dihydric alcohol having a carbon number of 6 to 10, and a nonionic surfactant. (2) An oily liquid cleansing composition according to 〇), wherein the fatty acid is a branched fatty acid. (3) The oily liquid cleansing composition according to (1) or (2), wherein the diol is one or more selected from the group consisting of propylene glycol, and the like. , a group formed by 3-butanediol, dipropylene glycol, and the like. (4) The oily liquid cleansing composition according to any one of (1) to (3), wherein the nonionic surfactant is one or more selected from the group consisting of polyglycerin fatty acid vinegar polyoxyethylene glycerin fatty acid, polyoxygen Ethylene fat _ _, polyoxyethylene sorbitan fatty acid ester, sorbitan fatty acid ester, polyoxyethylene hydrogenated castor oil (polyoxyethylene hydrogenated castor οιΠ, ^; polyoxyethylene castor oil (polyoxyethylene castor oil) (5) The oily liquid cleansing composition according to any one of (1) to (4), wherein the fatty acid having a carbon number of 6 to 10 is a diester of a glycol Class, system type or two or more selected from the group consisting of Propylene glycol di-2-ethylhexanoate and di-2-ethylhexanoic acid 1,3-butylene glycol 3 61^丫16116 21乂(:〇1(1卜2-6也71116\8110&7-6), Dipropylene glycol di-2-ethylhexanoate, diisoindole Propylene glycol diisononanoate, 1,3-butanediol diisodecanoate (1,3 Butylene glycol dii (6) The composition of the oily liquid cleansing composition according to any one of (1) to (4), wherein the carbon number is 6 to 10 The diesters of the fatty acid and the diol are one or more selected from the group consisting of propylene glycol di-2-ethylhexanoate/diisononanoate. Di-2-ethylhexanoic acid/diiso. '.. 1,3-butylene glycol citrate (1,3 Butylene glycol di-2-ethylhexanoate/ # diisononanoate), di-2-ethylhexanoic acid/ A group formed by Dipropylene glycol di-2-e lylhexanoate/diisononanoate. By using the composition of the present invention, it can provide a high detergency and can fully dissolve facial makeup. An oily liquid cleansing composition which is excellent in performance, easy to rinse, and excellent in function even when wetted by hands. Further, the composition of the present invention is transparent and can maintain stability from a low temperature to a high temperature temperature range of 7 200803909. [Embodiment] In the case of Linfa Japanese, a vinegar composed of a fatty acid having 6 to 10 carbon atoms and a glycol is used. If you use a second series of fatty acids with a carbon number higher than u,

For example, 2-Ethylhexanoic Acid, isodecanoic acid, capric acid, octanoic acid, Wei, and the like. Among the fatty acids having 6 to 10 carbon atoms, the detergency of the branched-chain fatty acid is preferred, and even if the hand is contaminated, it is excellent. The binary _ has, for example, ethylene glycol, propylene glycol, 1,3-butanediol, dipropylene glycol, neodecanediol, L 2 -pentanediol or the like. In order to obtain a high detergency in monohydric alcohols, it is preferred to use propylene glycol, 1,3-butanediol, and -propylene. a diester of a fatty acid having 6 to 10 carbon atoms and a diol, specifically, for example, Ethylene glycol di-2-ethylhexanoate, di-2-ethylhexanoate Propylene glycol di-2-ethylhexanoate, 1,3 Butylene glycol di-2-ethylhexanoate, di-2-ethyl Dipropylene glycol di-2-ethylhexanoate, neopentyl glycol di-2-ethylhexanoate, di-2-ethylhexanoic acid 1,2- Pentyl glycol ester (l, 2-Pentanediol di-2-e lylhexanoate), ethylene diisophthalate 8 200803909 (Ethylene glycol diisononanoate), Propylene glycol diisononanoate, diisoindole 1,3 Butylene glycol diisononanoate, Dipropylene glycol diisononanoate, XReopentyl glycol diisononanoate, diisodecanoic acid lv2 -Pentanediol diisononanoate, Ethylene glycol dicapro Ate), Propylene glycol dicaproate, 1,3 Butylene glycol dicaproate, Dipropylene glycol dicaproate, dihexanoic acid Neopentyl glycol dicaproate, 1,2-Pentanediol dicaproate, Ethylene glycol dicaprylate, Propylene glycol dicaprylate ), 1,3 Butylene glycol dicaprylate, Dipropylene glycol dicaprylate, Neopentyl glycol dicaprylate, dioctanoic acid 1,2 -1,2-Pentanediol dicaprylate, Ethylene glycol dicaprate, Propylene glycol dicaprate, 1,3-butylene glycol dicaprate (1,3 Butylene glycol dicaprate), Dipropylene glycol dicaprate, neopentyl glycol dioctanate (Neopentyl 9 200803909 - glycol dicaprate), dinonanoic acid i, 2-pentanediol (1,2-Pentanediol dicaprate) and the like. Among the above diesters, in order to obtain a high detergency, it is preferred to use ethylene glycol di-2-hexanoate, propylene glycol di-2-ethylhexanoate, di-2-ethylhexanoic acid. 1,3-butylene glycol ester, di-2-ethylhexanoic acid dipropylene glycol ester, di-2-ethylhexanoic acid neopentyl glycol ester, di-2-ethylhexanoic acid 1,2-pentanediol Ester, ethylene glycol diisophthalate, propylene glycol diisodecanoate, 1,3-butylene glycol diisodecanoate, dipropylene glycol diisophthalate, neopentyl glycol diisophthalate, 1,2-pentanediol diisodecanoate, and in order to obtain excellent detergency, easy rinsing properties, and functions that can be used even if the hands are wet, use propylene glycol di-hexyl hexanoate, di- 1,3-butylene glycol 2-ethylhexanoate, dipropylene glycol di-2-ethylhexanoate, propylene glycol diisophthalate, bismuth diisophthalate, 3-butanediol ester, diisoindole Dipropylene glycol acid ester is particularly desirable. Similarly, a mixed ester of 2-Ethylhexanoic acid with Isononanoic acid, such as di-2-ethylhexanoic acid/diisobutyl phthalate (Propylene glycol) Di-2-ethylhexanoate/ diisononanoate), di-2-ethylhexanoic acid / bismuth diisophthalate, 3-butanediol ester (1,3

Butylene glycol di-2-ethylhexanoate/diisononanoate), di-2-ethylhexanoic acid/dipropylene glycol monoisopropionate (]) ipr〇pylene glyC〇l di - 2-ethy lhexanoate/di isononanoate) is also particularly desirable. The diesters of the fatty acids and glycols having a carbon number of 6 to 10 can be purchased from commercially available products. 200803909 • It is also possible to combine fatty acids with 6 to 10 carbon atoms in combination with glycols to form esters. For example, the alcohol (lm〇le) and the fatty acid (2.2 m〇le) are heated to 200 C ' with a catalyst and the generated water is removed. After sufficient reaction, the excess fatty acid and the catalyst are removed, and purified by distillation under reduced pressure (about 150 to 2 ° C, about 〇 · iT rr) to obtain the desired ester. As the catalyst, a general esterification catalyst (e.g., acid catalyst, an organic catalyst, a metal catalyst, etc.) can be used. In the oily liquid cleansing composition of the present invention, in addition to the above-mentioned diesters of a fatty acid having a carbon number of 6 to 1 Torr and a glycol, it may contain, for example, a hydrocarbon oil, a natural oil, or an ester. Oil, oyster sauce, higher fatty acids, higher alcohols, etc. Carbide eucalyptus oil has mobile paraffin, aragonine, etc., natural oils are eucalyptus oil, jojoba/specialized, known oil, isooctyl isodecanoate, isodecyl isononanoate (Is〇n〇nyl isononanoate) , isodecyl isodecanoate (is〇deCyi is〇n〇nan〇ate), Octyl palmitate, cetyl 2 ethylhexanoate, caprylic acid/capric acid triacid Glycerin (Capryiic/Capric • Thdycehde), tris-ethylhexanoic acid glyceride (2 to ^; ^11 tri-2-ethylhexanoate), etc., eucalyptus oil is phenyl phenyl polyoxaxane (Methylphenyl polysil 〇 xane), Phenyl diterpenoid

Dimethicone) and the like, the tertiary fatty acids are isostearic acid, oleic acid, etc., and the higher alcohols are octyldodecanol, oleyl alcohol and the like. In the entire composition of the oily liquid cleansing composition of the present invention, the diesters of the fatty acid having 6 to 10 carbon atoms and the diols used in the present invention and the other oil phase 200803909 (10) are all oily agents. The amount of addition is preferably (4) 5% by mass. Less than the time can not fully transfer the woven fabrics to do secret (four) secret accompaniment (10) very reasonable °:. When it is more than 95%, it is not easy to rinse with water. In the entire composition of the oily liquid cleansing composition of the present invention, the amount of the diacetate formed by the fatty acid having a carbon number of 6 to 10 and the diol used in the present invention is preferably 5 to 95. 40 to 95% by mass is more desirable. Less than Shi and the makeup-like eradication of the slaves to wash the county will be green though. The secret 4 〇〇 ^ % or more 'the compatibility effect with the _ _ _ _ excellent. The interface activity of the present invention is _ non-ionic interface activity (four), ionic surfactant, cationic boundary agent, amphoteric interface activity (four) == Γ; "__ composition. In the case of not falling _ two fruits, a combination of face-to-face women and anionic, surfactant, cationic surfactant, and amphoteric surfactant can be used. Take = earn (four) decomposing agent silk, her fat, acid, brewing, milk, glycerin, glycerin, oxy-ester Fine II 16 sesame oil, polyoxygenated ramie oil, alcoholic oil _, glycerol __, Chi __, glucosides, alkyl polyglucosides, fatty acid glucosamine _. From the phase with the oil agent = New Zealand and hemp. The concept of the secret _ words, the use of the non-surface active agent of this hair ride, the peak of the gana, the end of the 13 more ideal child turn to 200803909. It has an oily liquid with excellent function of Anding County, secret irrigation and even the use of hands However, the makeup composition is a polyglycerol fatty acid vinegar, a polyoxyethylene glycerin fatty acid ester, a polyoxyethylene fatty acid ester, a polyoxyethylene sorbitan fatty acid ester, a sorbitan fat. The acid ester, polyoxyethylene hydrogenated castor oil, and polyoxyethylene castor oil are particularly suitable. The above polyglycerin fatty acid ester is, for example, decaglyceryl diisostearate, hexaglyceryl octyl octoate, polyglyceryl isostearate, polyglyceryl diisostearate, triiso-stearate Purpose, four different hard condensed sweet, yoghurt polyglycerin, polyglycerol dilaurate, polyglycerol trilaurate, polyglycerol tetralaurate, octanoic acid polyglycol / yttrium, octanoic acid polyglycol Fats and oils, tricaprylic polyglycerol, tetraoctanoic acid polyglyceride, palm syrup glycerin, glyceryl dipalmitate, polyglyceryl tripalmitate, tetraglyceride polyglyceride, and the like. The above polyoxyethylene glycerin fatty acid esters are polyoxyethylene triisostearic acid glyceride (20E·0·), polyoxyethylene glycerol monococoate (p〇1 y〇xyethy 1 ene g 1 ycery丄_monococoate> (7E·0·), Polyoxye1:hylene Glyceryl Monostearate (5Ε·0·), Polyoxyethylene Glycerol Monooleate (P〇lyoXyethyiene Glyceryl M〇n〇〇leate (Equivalent to the above-mentioned polyoxyethylene fatty acid esters such as Polyethylene Glycol Monoisostearate. The above polyoxyethylene sorbitan fatty acid esters are exemplified by polyoxyethylene Coconut oil 13 sorbitan _, polyoxyethylene oil

200803909 Fatty acid sorbitol Xuan (10) 〇.), (20 Ε. 0.), narrow _ ene early stearate sorbitan, ten, / Κ Fengfei ice early oleic acid sorbitol Xuan (10).0.) Wait. Monool ______ • Morning sorbitan sorbate. Examples of the above-mentioned polyoxyethylene women's scented bases include polyoxymethylene laurel _, polyoxyethylene ethoxylate stearyl _ and the like. The traits of the genitals are arbitrarily small, and the total amount of the invention is 4Q%. It is particularly desirable that when the temperature is 1%, the detergency and washability of the composition will be insufficient. ^二_°8^" There is a problem that "the liquidity is low and the oily liquid cannot be maintained", and the "name is used to irritate the skin and the like" can be caused by the invention. (4) The water is added to the secret compound village. Adding too much silk will result in water not completely covering the oil phase. Therefore, the amount of water added is less than 50% by mass, and less than 2% by mass is particularly desirable. In the oily liquid cleansing composition of the present invention, a multivalent _, a polyweidi diol (10) can be added, a saccharide, a lower alcohol, or the like, in a range which does not lower the effect of the present invention. Functional components such as polymers, organic and inorganic powders, preservatives, and oxidation inhibitors. (Embodiment) Hereinafter, the present invention will be specifically described with reference to the embodiments, but the present invention is not limited to the embodiments such as 200803909. According to the following manufacturing method _ as shown in Tables 1 to 4, the composition of the fine oily (four) make-up remover is evaluated in the following order, and the transparency, low-temperature stability, high-temperature stability, makeup dissolution effect, ease of rinsing, and even The function can also be used when the hand is wet. The results are shown in Tables 1 to 4. (Manufacturing method) The oil agent and the surfactant are heated to 8 Torr, mixed, and cooled at room temperature. (Transparency) The appearance of the oily liquid cleansing composition was observed and evaluated according to the following criteria. 〇: Transparent △: Translucent X: Insoluble (low temperature stability, 5 ° C) The oily liquid cleansing composition was stored in a thermostat at 5 ° C for 24 hours, and evaluated according to the following criteria. 〇: Transparent △: Translucent X: White turbidity or separation state 200803909 (High temperature stability, 40°c) The oily liquid cleansing composition was stored in a 40 C thermostat for 24 hours, and evaluated according to the following criteria. 〇:transparent △: translucent x·has white turbidity or separation state (makeup dissolution effect) The effect of makeup dissolution on the diameter of 5αη_ BIGSKIN side T (white) <Beaulax Co., Ltd. system> on fingertips The average sentence is smeared about lg __ face contact. Will be cultured back and forth to move back and forth 2.5, the paper rubbing, and only on the color difference to measure the macro oblique 斟 private # will be cultivated cover simple charm oblique, so that the county of Na Na read s bribe

Blow dry with the team fan, so that it does not mix paper, and the secret gas will not be stained when it is peeled off. Then, in the culture dish of Chen 8·, put 16 oily liquid secret-consistency, then the simple thief wiped the part down in the 'Puxian Petri dish' (4) makeup remover to make it Liquid 200703909 • Set the L*a*b氺 value of BIOSKIN SHEET before applying the liquid foundation to Eb (A), a氺(A), and b氺(A). The L%a*b* value of BIOSKIN SHEET after application of the liquid foundation is L*(B), a氺(B), b*(B). After evenly applying the composition for oily liquid exfoliation, repeat the L*a*b of the BIOSKIN SHEET after peeling off with the tissue paper and the n-meter value is (c), a氺(C), b* ( C). According to the formula 1, the color difference ΔΕ (0) before and after the application of the liquid foundation is obtained. • Equation 1 △ E (〇) = [(L* (Β) - L 氺 (A)) 2+ (a* (B) ~ a * (A)) 2+ (b* (Β) - b* (Α)) 2) 1/2 According to the formula 2, after applying the liquid foundation, evenly apply the oily liquid makeup remover composition, and then remove the BIOSKIN SHEET after peeling off with the tissue paper and the color difference ΔΕ of the BIOSKIN SHEET before the application of the liquid foundation. (1). Equation 2 ΔΕ (1) = ((L* (C)-L* (A)) 2+ (a* (〇- a * (A)) 2+ (b* (C) —b* (A)) 2) 1/2 Determine the residual ratio of the liquid foundation according to Equation 3. 17 200803909 Formula 3 Residual rate of liquid foundation = △ Ε (1) / ΔΕ (〇) χ 1〇〇 The estimated standards are as follows. 〇: The residual rate of liquid foundation is not Up to 5〇% △: The residual rate of the liquid foundation is above 50%, less than 80% X: The residual rate of the liquid foundation is above 8〇%, or because the oil-repellent interface agent cannot be given, it is a wealth and cannot be measured. In the case of the rinsing (in the case of rinsing), inject a 9 〇g of water into a 100 ml beaker, add 〇. 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油 油The rinse-off oily liquid makeup composition will be dispersed, so the glutinous rice is evaluated.

〇 Δ X Equally dispersed slightly oiled oil, or floating in the water. The state may also be due to the incompatibility of the oil agent and the surfactant, which may be uneven and cannot be measured. (Functions that can be used when the hands are wet) 18 200803909 The amount of water in the composition of the liquid cleansing composition of 3. 5g is reduced by visual evaluation of the transparency. The material is transparent, which means that the water is dissolved: ^ The pro-coffee composition can play the makeup remover function. It is only a slightly turbid process and it also functions as a makeup remover. However, when it is in a white turbid state, the composition for oily liquid cleansing cannot dissolve water, and forms a dispersed state, which means that the makeup remover function cannot be exerted. Therefore, the evaluation is based on the following criteria. Ο : Transparent • △: Slightly turbid X: White turbidity or because the oil agent and the surfactant are incompatible, showing an unequal state and cannot be measured. Table 1

Table 1 Example 1 Example 2 Example 3 Comparative Example 1 Comparative Example 2 a Butylene glycol di-2-ethylhexanoate (1,3 Butylene glycol di -2-ethy1hexanoate) 80 80 80 Oil b Propylene glycol diisononanoate 80 80 c Flowing paraffin cetyl 2-ethylhexanoate e Glycerin tr i 2-ethyIhexanoate interface Polyoxyethylene glyceryl triisostearate (20E. 0.) 20 19 200803909

Sex agent g sorbitan monostearate polyoxyethylene (20E. 15 T polyglycans ^Decaglyceryl diisostearate) 13.3

Sodium stearoyl glutamate 20 Potassium myristate

High temperature stability 40 °C Fruit XXXX 彳匕 makeup agent residual rate (- represents the sample can not be measured due to separation) Easy to wash the function even if the hands are wet 〇 〇 〇 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 40. 6% 48. 3% 〇Δ △ 〇36.9% 〇〇

X 氺 oil a, b is carbon number 6 ~ medium chain grease * surfactant f ~; i is a non-ionic surfactant, and interface active paper,! Ionic surfactant

X

X Table 2 T2 _ -- Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Comparative Example 7 Oil agent a di-2-ethylhexanoic acid butanediol vinegar--- b diisodecanoic acid propylene glycol c flow Paraffin 80 80 80 d Hexadecyl 2-ethylhexanoate 80 80 e Tri-2-ethylhexanoic acid glyceride surfactant f Polyoxyethylene triisostearic acid glyceride (20E 〇·) 20 20 g Oxyethylene sorbitan monostearate (20E·0·) 15 15 h Decaglyceryl diisostearate 13.3 i Hexaglyceryl hexacylic acid 6.67 — j Monostearic acid sorbitan ester 5 5 k Sodium Stearoyl Glutamate 20 200803909

Residue rate of cosmetic agent (-%% ease of rinsing XX 〇XXX 〇XXX 〇X __X XXXX ---- one 86.3% - __X XX Δ X __X XX 〇X and the surfactants k and 1 are anionic Surfactant can be used even if the hands are wet _ #J a - b 4^ 6-10 _ * Surfactant H is a non-ionic interface, live vinegar is f, Table 3 -2-ethylhexanoate Glycol ester interface agent

--2-ethylhexanoic acid glycerin

Poly(ethylene triisostearate) (2〇E 〇_) _ polyoxyethylene monostearate (20E·0·) decaglyceryl diisostearate hexacylic acid glycerin Ester^isostearic acid sorbitan 酉ΐ _ Sodium Stearoyl Glutamate Transparent characterization 5$ 21 200803909 • * Oil a, carbon number 6~10~^^^^ and binary Alcohol diesters? - a * The surfactants f to j are nonionic surfactants, and the surfactants k and 1 are anionic surfactants. Table 4

Table 4 Comparative Example 13 Comparative Example 14 Comparative Example 15 Comparative Example 16 Comparative Example 17 Oil agent a-2-ethylhexanoic acid butanediol bb b-isopropanoic acid propylene glycol ester ^------ a c flow Paraffin'-80 d 2-hexyl 2-ethylhexanoate 80 80 e Di-2-ethylhexanoate 80 80 Surfactant f ^ Oxyethylene diiso-hard · 0 ·) * g Monostearic acid Sorbitol polyglycol ^ (20E· 0·) h Decaglyceryl diisostearate i hexacylic acid 20 glycerin vine j monoisostearic acid sorbitol 1# alcohol anhydride 酉i~~ k 1 stearin Sodium citrate (Sodilinr^^ y j Glutamate) 20 20 1 1" Potassium myristate-Γ-20 X 20 One X 20 X Low temperature security? Λ4- C °Γ^ ------- : Sex 5 CXXX 高温 ^ 彩 ϋ ϋ ϋ λ λ λ λ λ Γ XXX XXX XXX XXX XXX XXX XXX XXX 效果 效果 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆 化妆When 3 1 v / only ^ trial), six! ·》!· '---~~-- One~ - One 1 Valleyability XX *----- Even hand,; 1 Yong,: Occupy ll C L- ^'0 -A* J*h /4r rrj w _ i al. " --- XXXXV 匕 We can also use the function», k 甴 z 甴 cylinder β ΑΛ 士 士 --- XXX / 哭贝< Ε3δ Φθ ° —^— * interface The active agent j is a non-ionic interface _, while the interface activity _ k, Ί is an anionic interface----~~__ In the case of the embodiment 1~3, her _ 卩 makeup complex secret carbon number 6~ 10 fatty acids and binary _ _ 贞 贞 二 diisophthalic acid butanediol brewing, diisomeric propylene glycol vinegar and non-ionic interface _, its residual rate is less than India 22 200803909 % The makeup effect is exceptionally excellent. On the other hand, in the oil green body release composition of Comparative Examples 3 to n, it was added as a flow monument of hydrocarbon oil, and it was composed of 1 glycerol acid and a monovalent higher alcohol. The domain, the triglyceride triethylhexanoic acid glycerin vinegar and the nonionic surfactant, the cosmetic agent residual rate is above the Qing, or more than 80%, so the makeup dissolution effect is not good. In addition, there is also a case where the H surfactant cannot be uniformly dissolved and cannot be measured. The oily liquid makeup remover of the embodiment of the present invention is stable in transparency and low temperature. (2), ^ Stability (10). 〇, the secret of rinsing, even if the hands are wet, you can use the merits of the month. In the implementation of the addition of a surfactant such as polyoxyethylene monomer = acid sorbose _ (姗α) and monoisostearic acid sorbose 2, although weaving temperature stability 峨), high temperature stability (sail) The capacity of the rinsing:!, the function of the function that can be used even if the hand is wet, etc., the cleaning effect of the main purpose of the micro-disregard (the makeup dissolution effect axis ^: the same, in the comparative examples 4, 7, 1G) It also uses the interface to know when it is live, and adds the mobile sarcophagus, 2_ethylhexanoic acid 16 § and the triethylhexanoic acid lanthanum interface _ no material _ capacity. Therefore, the carbon number ion η yuan The second rotation and the other _, when compared with the non-comparative example 5, although the composition of the trr is better, the addition of the mobile sarcophagus is equally compatible, so the makeup removal function cannot be measured. Comparative Example 6, δ, although in the temperature of 10; 23 200803909 (5 C), south temperature stability (4 〇. 〇, easy to rinse, even if the hands can be used, etc. The measurement results are excellent, but as described above, the detergency (cosmetic dissolution effect) which is the main object of the present invention is not good. Comparative Example 9 and n to which triethylhexanoic acid glyceride and nonionic surfactant were added were excellent in transparency, low-temperature stability (5C), and high-temperature stability (4 (rc) 2 measurement, but dissolved in makeup The effect and the ease of rinsing the glutinous rice are not good, and even if the hand is wet, the function of the shape can be unsatisfactory. In addition, as shown in the comparative example 2, even if the carbon number 6~(7) is used, the participation in the second conversion type is achieved. The second embodiment is not capable of exhibiting the function of the makeup remover composition with the anion + surfactant phase/valley. (Embodiment) Hereinafter, the embodiment will be described in detail, but the present invention is not limited thereto. The same manufacturing method of the oily makeup remover of Table 4 was prepared by preparing the slit (four) makeup remover of the composition shown in Table 5, and evaluating it in the same order as the oil (10) body makeup remover of the above table. Permeability, low temperature stability ^, enthalpy temperature stability, color makeup dissolution effect, ice wet can also be Wei Wei. The measurement results are shown in Table 5 (four) and even hand / account 5

twenty four

In the oily liquid cleansing compositions of Examples 4 to 6, a fatty acid having a carbon number of 6 to 1 Å was added, and a binary bismuth diisophthalic acid butyl hydride was added as a nonionic surfactant. Its _ 朗料柯 _, the makeup removal effect is exceptionally excellent. The oily liquid cleansing compositions of Examples 4 to 6 of the present invention have high transparency and stability in transparency, low temperature, and high temperature stability (10). c), the tolerance during rinsing, even if the hand smear / Luo also use this function in all aspects have obtained excellent gentleman fruit 200803909 formula example 1 ingredient name 1 · di-2-ethylhexanoic acid butyl vinegar 2. Octyl palmitate 3 · Decaglycerol diisostearic acid 4·6 octyl octanoic acid glycerol ester added (% by mass) 6 0 2 0 10 9· 9 25 200803909 '5·Dextrin palmitate 0.1 Formulation Example 2 Adding amount (% by mass) 70 1 C 18 2 Ingredient name 1. Diisodecanoic acid propylene glycol 2. Triethylhexanoic acid glyceride 3. Polyoxyethylene triisostearic acid glyceride

4. (Behenic acid/telecacindioic acid) glyceride Formulation Example 3 Additive amount of component name (% by mass) 1. Butylene diisophthalate 7 0 2. Octyldodecanol 10 3. Ten Polyglyceryl diisostearate 1 5 _ 4. Hexaglyceryl hexacylic acid 4.5 5. (behenic acid/telecacindioic acid) glyceride 0.5 Formulation Example 4 Additive amount of component name (% by mass) 7 0 1 Di-2-ethylhexanoic acid propylene glycol 2. Meadowfoam Oil 1 〇26 200803909 - 3. Decaglyceryl diisostearate 4. Hexaglyceryl octadecyl acid 5. Dextrin 10 9.9 0· 1 Formulation Example 5

Ingredient name L di-2-ethylhexanoic acid propylene glycol 2. Diisobutyl phthalate 3. Tetraglyceryl diisostearate 4. Hexyl octyl citrate 5. (behenic acid / two Decrole diacid) glycerin hydrazine added amount (% by mass) 5 0 30 10 8. 5 Formulation Example 6 Ingredient name • 1. Butane-2-ethylhexanoate 2. 2-ethylhexanoic acid 6. The oxyethylene triisostearic acid glyceride 4. Polyoxyethylene hydrogenated linseed oil 5. Palmitic acid dextrin addition amount (% by mass) 40 4 0 15 4. 5 0. 5 Formulation example 7 27 200803909 Ingredient name 1. Butane diisophthalic acid ester 2. Octanoic acid / citric acid triglyceride 3 3. 3. Decaglyceryl diisostearate i.. hexacylic acid twenty glycerol S. 5. (behenic acid /20% succinic acid) Addition amount (% by mass) 44 4 0 10 5 1 Formulation Example 8 Ingredient name 1. Butylene diisophthalate 2. Squalane 3. Polyoxyethylene triisostearyl Acid glyceride 4. Polyoxyethylene hydrogenated castor oil addition amount (% by mass) 70 10 15 5 Formulation Example 9 Ingredient name 1. Diisodecanoic acid propylene glycol 2 2. Olive oil 3. Decaglycerol diisostearic acid Ester 4. Hexaglyceryl octadecanoate 5. The amount of acid odextrin added Quality %) 70 10 10 9. 5 0. 5 28 200803909 Formulation Example 10 Ingredient name 1. Di-2-ethylhexanoic acid propylene glycol 2. Charged oil 3. Polyoxyethylene triisostearic acid glyceride 4 . Addition amount of polyoxyethylene eucalyptus eucalyptus oil 5 · (behenic acid / decanoic acid) glyceride (% by mass) 101541 7 0 Formulation Example 11 Addition amount of component name (% by mass) 1. Propylene glycol dioctanoic acid S Purpose 4 0 2. Hexadecyl 2-ethylhexanoate 4 0 3. Decaglycerol diisostearic acid vinegar 10 Good 4. Hexaic acid twenty glycerin vinegar 9 5. (behenic acid / eicosanedioic acid )Glyceride 1 [Simple description of the diagram] [Explanation of main component symbols] 29

Claims (1)

200803909 - X. Application for Patent Park: 1. An oily liquid repellent composition characterized by containing a fatty acid of Wei 6, and a second of two, and a nonionic surfactant. 2. The oily liquid cleansing composition according to the patent application item i is a branched fatty acid. 3. The oily liquid cleansing composition according to the above, wherein the diol is one or more selected from the group consisting of propylene glycol, 1,3-butylene glycol, and dipropylene. a group formed by diols. The invention relates to an oily liquid cleansing composition according to any one of the items of the present invention, which is characterized in that: (4) Polyoxyethylene glycerin fat, polyoxyethylene fat, polyoxyethylene sorbitan fat, mountain __fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil Group class. 5: The invention relates to the oily liquid clock makeup composition according to any one of the items i to 4, and the fatty acid and the glycol which are 6 to 10 in the middle of the 17th stone. One or more esters selected from the group consisting of propylene glycol di-2-ethylhexanoate, butylene glycol di-2-ethylhexanoate, and dipropylene glycol di-2-ethylhexanoate A group formed by acid propylene glycol ester, diisodecyi-butanol, and dipropylene glycol diisophthalate. The oily liquid cleansing composition according to any one of the items of the present invention, wherein the fatty acid having a carbon number of 6 to 1 Å and the diester of the diol are formed. , one or more selected from the group consisting of di-2-ethylhexanoic acid/propylene diisophthalate, di-2- 30 200803909 • ethylhexanoic acid / butylene diisophthalate, di-2 a group formed by ethylhexanoic acid/dipropylene glycol diisophthalate. 31