TW200534050A - Mask for use in a microlithographic projection exposure system - Google Patents
Mask for use in a microlithographic projection exposure system Download PDFInfo
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- TW200534050A TW200534050A TW094101369A TW94101369A TW200534050A TW 200534050 A TW200534050 A TW 200534050A TW 094101369 A TW094101369 A TW 094101369A TW 94101369 A TW94101369 A TW 94101369A TW 200534050 A TW200534050 A TW 200534050A
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- 239000000463 material Substances 0.000 claims abstract description 30
- 239000003989 dielectric material Substances 0.000 claims abstract description 12
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 9
- 239000010703 silicon Substances 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000005530 etching Methods 0.000 claims description 5
- 238000010276 construction Methods 0.000 claims description 2
- 230000001678 irradiating effect Effects 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 239000000969 carrier Substances 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 230000005540 biological transmission Effects 0.000 abstract description 23
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- 230000000694 effects Effects 0.000 description 19
- 239000003973 paint Substances 0.000 description 12
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 9
- 229910052804 chromium Inorganic materials 0.000 description 7
- 239000011651 chromium Substances 0.000 description 7
- 238000009826 distribution Methods 0.000 description 7
- 230000003287 optical effect Effects 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 230000008859 change Effects 0.000 description 5
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- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 238000005286 illumination Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
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- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910001634 calcium fluoride Inorganic materials 0.000 description 1
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- 238000005516 engineering process Methods 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
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- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000010363 phase shift Effects 0.000 description 1
- 238000001259 photo etching Methods 0.000 description 1
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- 239000010453 quartz Substances 0.000 description 1
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Classifications
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/50—Mask blanks not covered by G03F1/20 - G03F1/34; Preparation thereof
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F1/00—Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof
- G03F1/54—Absorbers, e.g. of opaque materials
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
- Preparing Plates And Mask In Photomechanical Process (AREA)
Abstract
Description
200534050 九、發明說明: 【發明所屬之技術領域】 本發明關於一種用於微|虫印(mikrolithographisch )的 才又景々曝光設備中的光罩,如在製造高度整合之積體電路或 其他微構造化的構件所用者。本發明特別關於具有一載體 的所謂的「波幅光罩」(Amplitudenmask ),有一個由不 透光的構造構成的圖案施覆到該載體上。200534050 IX. Description of the invention: [Technical field to which the invention belongs] The present invention relates to a photomask used in a mikrolithographisch exposure device, such as in the manufacture of highly integrated integrated circuits or other microchips. Used by structured components. The present invention is particularly concerned with a so-called "Amplitudenmask" having a carrier, to which a pattern consisting of a light-tight structure is applied.
【先前技術】 積體電路與其他微構造化的構件一般的製法中,係將 數個構造化的施覆到一適當基質(例如一種矽晶圓)上。 要將這些層作構造化,首先將它們覆以一種感光漆 (Photolack ),該感光漆對於一特定波長範圍的光〔例如 在低頻紫外光譜範圍(DUV,deep ultravi〇let)的光敏感, 然後將如此施覆過的晶圓在一投影曝光設備中照射(曝 光)’在此將一種由折射構造構成的圖案(它包含在一光 罩中)利用一投影物鏡(Pr〇jekti〇ns_〇bjektiv )成像到該 光敏漆上。由於成像的比例一般小於1,故這投影物鏡往 在也稱細小物鏡(Redukti〇nsobjektiv )。 在感光漆顯影(Entwickeln,英:develop )後,將該 曰曰圓作蝕刻程序,其中,最上一個層對應於光罩上的圖案 構造化。此程序一直重覆,直到所有層部施到晶圓上為止。 在微#印投影曝光設備顯影時,其主要目的之一係在 方、要月b將尺寸日盈變小的構造在晶圓上產生,俾用此方式 將所要製造的構件的整合密度提高。目前藉著使用大不相 200534050 同的措施,在晶片上所能產生的構造的尺寸小於所用之投 影光波長。 這些措施之一係將一種浸入液() 放入投影物鏡與晶圓之間的中間空間中。這呵使得具有特 尚數字的口孔(Apertur )(甚至可大於1 ·0)的投影物鏡 能使用。 然而在晶圓上利用浸入所能達成的小的構造寬度也使 ^ 得光罩上的構造也日益變小。固然相當的效果也可將投影 物鏡的成像比例變小而達成。但如此在投影物鏡的設計上 的深入的技術改善使得這種另外的方案由於成本的理由而 不予考慮,如果光罩中所含的圖案的構造寬度係在所用之 投影的波長的大小或甚至遠小於其波長,則特別是在波幅 光罩的場合會發生一些不良效應,使光學成像受到投影物 鏡的不良影響。稱為「波幅光罩」的光罩中,與在「相位 光罩」的情形不同,並非透過的光線的相位受影響,而係 ^其波幅受影響。因此,在一波幅光罩中所含的構造一般為 不透光者,且一般由構造化的鉻層構成。 波幅光罩中發生的不良作用之一(這種波幅光罩的構 造之間的中間空間大小在投影光波長的大小範圍中)在 於··該光罩對於穿透的投影光線有極化作用。因此在前景 (V〇rdergrund,英:f〇regr〇und )中有一種效應,即某些 投影光(其極化方向平行於構造的縱延伸方向對準)透過 光罩的程度比起另一些投影光(其極化方向垂直於構造縱 延伸方向)更士子。這種穿透性與極化的關係在於:在光罩 6 200534050 上,同種類但不同朝向的構造係以不同的光強度成像在光 敏漆(感光漆)上。由於光敏漆的曝光門楹很明確,因此 每單位面積上入射的光能量有些變動,就對於用光姓印方 式在晶圓上產生的構造的寬度有直接影響,一般上不希望 有這種構造寬度受到光罩中所含構造的朝向的影響的情 事。 但在構造之間小小的中間空間的極化作用的原因也可 m在於:當投射光的極化方向係平行於構造的縱延伸方向 時,光在構造之間傳播的速度係和極化方向垂直於構造的 投射光的傳播速度不同者。這點會導致互相垂直的極化分 置之間的相位差’就像在延遲小板 (Verziigeruiigsplattchen )中所發生的相位延遲的情形。 但在光罩中,這種相位差一般是不希望有的,因為晶圓上 的構造寬度會叉到光罩中所含構造的方向性的影響。其理 由在於:在投影物鏡中的某些光學元件,例如對極化有選 ^擇性的分光片層,本身具有與極化作用有關的穿透能力或 反射能力。因此,舉例而言,從直線式極化的光轉變成橢 圓式極化的光的轉變作用。在光罩中對於光強度以及對於 晶圓上的構造寬度有影響。 為了避免光透過能力受到極化的影響,故在美專利us 6,522,483 B2中提到:利用一個設在光罩前方的四分之一 波長小板將最初為線型方式極化的光轉變成圓形方式極化 的光如此,在光罩後方的投影光的強度就不受到光罩中 之不透光構造的方向性的影響,利用另一個設在光罩後面 7 200534050 的四刀之波長小板可再造成線型的極化作用。 习习 ic 白D做法的困難在於,投影光在通過光罩後, 由於透過能六你k y /、極化有關,因此並非很準確的圓形極化, 而係王各種不 勺擴圓形極化,各依構造的方向性而定, 但在光罩後方另 口少 另一個延遲小板只能將某種特定偏心率的橢 D /極化作用變成線型極化作用,但無法將各種不同偏心 率的橢圓形極化作用變線型。如A,在隨後的光學元件中 、二。乍用的衫響一般在這種習知做法也會使得晶圓上的 構k寬度依光罩中所含的構造的方向性而定而變動。 在相位光罩的場合,固然構造之間小小的中間空間的 極化作用要小得多,但相减罩在製造上比起波幅光罩要 繁複且昂貴得多。 【發明内容】 因此本發明的目在於將波幅光罩改善,使晶圓上的構 造寬度受到光罩中所含的構造的方向性的不良影響減小。 主依本發明’這種目的達成之道在於:並非如先前技術 的情形:使投影光在通過光罩之前及之後影響其極化作 用,而係直接地將光罩的極化作用,而且特別是透過能力 與極化的關係減少。 依本發明一要點,這點係可利用一種光罩達成,該光 罩有載體,有-種由不透光構造構成的圖案施覆在該載 體上,其達成方式’係使該構造含有一種材料,其折射指 數的虛數部分(Imaglnarteil)對於100奈米〜奈米的 波長係大於1.8且宜大於2.2。 200534050 依此第一特點,本發明係基於一種認知,即:當投影 光垂直於光罩中的構造的縱延伸方向被極化時,其在構: 間的中間空間被吸收的程度較大,因為它可較深地進入該 構造中。反之’當投影光通過構造間的中間空間時,則連 續地在構造的邊緣區域被吸收。因此極化作用的影響隨構 造高度增加而變大。 但如果該構造含有一種材料,其折射指數的虛數部分 ηι在此處所觀察的波長的場合比起一般所用特(鉻的場 合’對於193 4米的波長’其折射指數的虛數部分的值為 1.65 ) A tH T it ( Spurbar > ^ : traceable ) ^ 程度,則當光垂直於構造的縱延伸方向極化時,在該構造 中被吸收的程度就較大’因此用這種方式不會深入該構造 中。固然在這種材料的場合,在構造表面的電子被吸收的 程度比起例如在鉻的情形較多,但整體上被這些電子帶走 的肊里邠#乂少’廷種進入構造的深度隨著折射指數的虛數 部分增加而變小’ 0此使這種折射分量比起鉻來,有較大 的透過能力。 在進入該材料(其折射指數具有較大的虛數部分)的 過渡區,對於平行於構造之縱延伸方向極化的光幾乎沒有 〜曰此外’ &種極化分對於夠小構造係以習知方式受到 所謂的「金屬絲格柵效應」(wire_gnd_efffekt)〔一如在 傳統的金屬絲極化琴的梏犯Ί丄 的60 形〕由於電磁邊緣條件使其強度 減弱。 人們要求透過能力不 要受化影響,這表示,對於垂直 9[Prior art] In the general manufacturing method of integrated circuits and other micro-structured components, several structures are applied to an appropriate substrate (such as a silicon wafer). To construct these layers, they are first covered with a photosensitive lacquer (Photolack), which is sensitive to light in a specific wavelength range (such as light in the low-frequency ultraviolet range (DUV)), and then The thus-coated wafer is irradiated (exposed) in a projection exposure apparatus. 'Here, a pattern composed of a refractive structure (which is contained in a mask) is used with a projection objective (Prójekti〇ns_〇). bjektiv) onto the photosensitive paint. Because the imaging ratio is generally less than 1, this projection objective is also called a small objective lens (Reduktionsobjektiv). After the photosensitive paint is developed (Entwickeln, English), the circle is used as an etching process, wherein the uppermost layer corresponds to the pattern on the photomask. This process is repeated until all layers are applied to the wafer. When the micro # print projection exposure device is developed, one of its main purposes is to produce a structure with a smaller and smaller size on the wafer in the month and month b. In this way, the integration density of the components to be manufactured is increased. At present, by using substantially different measures, the size of the structure that can be produced on the wafer is smaller than the wavelength of the projection light used. One of these measures is to place an immersion liquid () in the intermediate space between the projection objective and the wafer. This allows projection lenses with special digital apertures (even greater than 1.0) to be used. However, the small structure width that can be achieved by immersion on the wafer also makes the structure on the photomask increasingly smaller. Although the equivalent effect can be achieved by reducing the imaging ratio of the projection objective lens. However, such in-depth technical improvements in the design of the projection objective make this alternative solution not to be considered due to cost reasons. If the structural width of the pattern contained in the mask is the size of the wavelength of the projection used or even Far less than its wavelength, some adverse effects will occur especially in the case of the wave-amplitude reticle, and the optical imaging will be adversely affected by the projection objective. In the mask called "amplitude mask", unlike the "phase mask", the phase of the transmitted light is not affected, but its amplitude is affected. Therefore, the structure contained in an amplitude mask is generally opaque, and is generally composed of a structured chromium layer. One of the adverse effects that occur in an amplitude mask (the size of the intermediate space between the structures of such an amplitude mask is in the range of the wavelength of the projection light) is that the mask has a polarizing effect on the transmitted projection light. Therefore, there is an effect in the foreground (Vordergrund, English: f0regrund) that some projection light (its polarization direction is aligned parallel to the longitudinal extension direction of the structure) passes through the photomask more than others. Projection light (its polarization direction is perpendicular to the longitudinal extension direction of the structure). The relationship between this penetrability and polarization is that on the photomask 6 200534050, structures of the same kind but different orientations are imaged on the photosensitive paint (photosensitive paint) with different light intensities. Since the exposure threshold of the photosensitive paint is very clear, there is some change in the incident light energy per unit area, which directly affects the width of the structure produced on the wafer by the light surname method. Generally, such a structure is not desired. The width is affected by the orientation of the structure contained in the mask. However, the reason for the polarization in the small intermediate space between the structures can also be that when the polarization direction of the projected light is parallel to the longitudinal extension of the structure, the velocity system and polarization of the light traveling between the structures The projected light whose direction is perpendicular to the structure has a different propagation speed. This will cause a phase difference 'between the mutually orthogonal polarization components, as in the case of a phase delay that occurs in a delay plate (Verziigeruiigsplattchen). However, in a reticle, such a phase difference is generally undesirable because the width of the structure on the wafer can be influenced by the directivity of the structure contained in the reticle. The reason is that certain optical elements in the projection objective, such as a spectroscopic layer that is selective for polarization, itself has a penetrating or reflecting ability related to polarization. Therefore, for example, the conversion effect from linearly polarized light to elliptically polarized light. It has an effect on the light intensity in the photomask and on the width of the structure on the wafer. In order to prevent the light transmission ability from being affected by polarization, it is mentioned in US patent US 6,522,483 B2: a quarter-wavelength small plate located in front of the photomask is used to convert the originally linearly polarized light into a circle In this way, the intensity of the projected light behind the mask is not affected by the directionality of the opaque structure in the mask. Another four-blade wavelength plate is used behind the mask. Can again cause linear polarization. The difficulty of practicing the white D method is that after the projection light passes through the mask, because the transmission energy is related to the polarization, it is not a very accurate circular polarization. , Each depends on the directionality of the structure, but there is another delay plate behind the mask, which can only change the ellipsoidal D / polarization of a certain eccentricity into a linear polarization, but it cannot change the various eccentricities. The rate of elliptical polarization becomes linear. Such as A, in the subsequent optical elements, two. At first, the commonly used shirt sound will also make the structure k width on the wafer change according to the directionality of the structure contained in the mask. In the case of a phase mask, although the small intermediate space between the structures has a much smaller polarization effect, the subtractive mask is more complicated and more expensive to manufacture than an amplitude mask. SUMMARY OF THE INVENTION Therefore, an object of the present invention is to improve an amplitude mask so that the width of a structure on a wafer is less affected by the directivity of the structure included in the mask. This purpose is achieved according to the present invention: it is not the case in the prior art: the projection light affects its polarization before and after passing through the mask, but directly polarizes the mask, and in particular It is the decrease in the relationship between transmission capacity and polarization. According to an important point of the present invention, this can be achieved by using a photomask having a carrier, and having a pattern composed of an opaque structure applied on the carrier. The method for achieving this is to make the structure contain a For materials, the imaginary part of the refractive index (Imaglnarteil) is greater than 1.8 and preferably greater than 2.2 for a wavelength range of 100 nm to nanometers. 200534050 According to this first feature, the present invention is based on the recognition that when the projection light is polarized perpendicular to the longitudinal extension direction of the structure in the photomask, its intermediate space in the structure is absorbed to a greater degree. Because it can penetrate deeper into the structure. Conversely, when the projected light passes through the intermediate space between the structures, it is continuously absorbed in the edge regions of the structures. Therefore, the effect of polarization becomes larger as the structure height increases. However, if the structure contains a material, the imaginary part of the refractive index at the wavelength observed here is more special than that commonly used (in the case of chromium 'for a wavelength of 1934 meters', the imaginary part of its refractive index is 1.65 ) A tH T it (Spurbar > ^: traceable) ^ degree, when the light is polarized perpendicular to the longitudinal extension of the structure, the degree of absorption in the structure is greater ', so it will not go deep in this way In the construct. Although in the case of this material, more electrons are absorbed on the structure surface than in the case of chromium, for example, the overall depth of the 肊 里 邠 # 乂 少 'species that is carried away by these electrons varies with the structure. As the imaginary part of the refractive index increases, it becomes smaller. This makes this refractive component have a larger transmission capacity than chromium. In the transition zone into which the material (its refractive index has a larger imaginary number part), there is almost no light polarized parallel to the longitudinal extension of the structure. The known method suffers from the so-called "wire_gnd_efffekt" (like the 60 shape of a traditional wire-polarized piano), which weakens its strength due to electromagnetic edge conditions. People demand that transmittance should not be affected by chemical, which means that for vertical 9
200534050 於構造的縱延伸方向極化的光,其透過能力係與平行於搆 造縱延伸方向極化的光一樣強。當用鉻造構造時,對於粢 直的極化分量的透過能力比起對於平行的極化分量的透過 能力低。然而,如不用鉻,也找不到一種材料來做構造, 對於金直極化分篁的透過能力遠比對於平行極化分量 的透過能力大得多。最佳的方》’是找一種材料,它具有 這種折射指數的虛數部分,其中對於垂直的極化分量的透 過此力係要儘量接近其對於平行的極化分量的透過能力。 牛例而σ ,這種最佳材料的此值可利用模擬計算 (Smulationstrechnung)或利用實驗求出。 在選擇材料時可考慮的另一特點,係為相對相位延遲, 這種相位延遲係該二個不同的極化分在通過光罩時所發生 者’:般無法找到—種理想材料,它一方面其透過能力能 夠不叉極化影響’另方面相位延遲又逼近零。因此一般需 找出一個折衷的妥協之道,其中極化作用在整體上(換古 之’即透過能力受極化的影響,以及相對的相位延遲)總 ^而言為最小。這兩種作用孰輕孰重的權衡,係依個案而 疋看在才又衫物豸中所含的光學元件對於極化的影響大小 而決疋。 做構造的材料係用各# 合禋不同的金屬(如鋁)及半導體, 但特別適合者為矽,囡幺甘 ^ 為/、折射指數的虛數部分在1 93各 米波長時為2.78,因此# 士处丄 ,w 不 匕遂比鉻大。此外,在先前技術已 研究试驗過微構造化的秒> ^ ’禮的製造,因此要開發一種適各 的程序技術的成本很少。 田 10 200534050 基本上,如果該構造僅在沿其縱側翼的範圍由上述材 料構成,m已足夠。由於在許多考慮到的耗合,對紫外線 的侵入深度只在幾奈米到約10》米的大小範圍,因此該 構造的側表面只要用幾個厚子層的厚度的上述材料蓋住。 然而’如果這種總是很細微的構造完全由具有上述性質的 材料構成,則在造技術上特別簡單。200534050 Light polarized in the longitudinal direction of the structure has the same transmission ability as light polarized in parallel to the longitudinal direction of the structure. When constructed with chrome, the transmission capability for a straight polarization component is lower than the transmission capability for a parallel polarization component. However, if chromium is not used, no material can be found to make the structure. The transmission capacity for gold polarized tillers is much greater than the parallel polarization component. "The best formula" is to find a material that has the imaginary part of this refractive index, in which the transmission of the vertical polarization component is as close as possible to its transmission capacity for the parallel polarization component. For example, σ, this value of this optimal material can be obtained by simulation calculation (Smulationstrechnung) or experimentally. Another feature that can be considered when selecting materials is relative phase delay. This phase delay is caused by the two different polarization components when passing through the photomask: generally cannot be found-an ideal material. On the one hand, its transmission ability can not cross-polarize, and on the other hand, the phase delay is close to zero. Therefore, it is generally necessary to find a compromise. The polarization effect (in other words, the transmission capacity is affected by polarization, and the relative phase delay) is the smallest. The weighting of these two roles depends on the individual case, depending on the magnitude of the influence of the optical components contained in the talents on polarization. The material used for the structure is a combination of different metals (such as aluminum) and semiconductors, but it is particularly suitable for silicon, and the imaginary part of the refractive index is 2.78 at a wavelength of 193 meters, so # 士 处 丄, w is not larger than chrome. In addition, in the prior art, the fabrication of micro-structured seconds has been studied and tested, so the cost of developing a suitable programming technique is small. Tian 10 200534050 Basically, if the structure consists of the above materials only in the area along its longitudinal flanks, m is sufficient. Due to many considerations, the penetration depth of ultraviolet rays is only in the range of a few nanometers to about 10 ″ meters, so the side surface of the structure need only be covered with the thickness of the above-mentioned materials with a few thick sublayers. However, 'if this always very fine structure consists entirely of materials with the above properties, it is particularly simple in terms of manufacturing technology.
依本發明另-特色,可用以下方式達到對極化更中性 (更不受極化影響)的遮罩的效果;在二個構造之間的一 個中間空間中有-種介電材料,它與該:構造不接觸。 用此方式,光主要在介電材料中傳播(舉例而令,該 介電材料可為石英玻璃在介電材料與不透光構造之間 留的縫隙(舉例而t,它可充以空氣或一種保護性氣體) 中,場強度很小。因此光侵入深度也對應地小,且該構成 不透光構的材料所吸收的光也對應地小。在此,該縫隙的 寬度對光罩的極化性質有重大的影響’藉著模擬或-種最 佳化=序’可以得知:在—種由不透光材料構成之所予圖 案的場合’究竟那-種縫隙寬度的透過能力的受極与 響最小。 ^ /在T間空間中的介電材料對於該極化分量(其極化方 向係为別平行及垂直於該構造的縱延伸方向延伸)的相對 :相位延遲作用也有很有利的影響。在此處,&可藉著研 九或杈擬找出「設計參數」,它們可使整體極化作用最小, 換吕之’即透過能力受極化的影響以及相對相位延遲為最 /J、〇 11 200534050 在二個構造間的中間空間中的材料宜構成一種核心構 造,該核心構造大致平行於該不透光的構造的縱方向延 伸。在此’這種核心構造的橫截面舉例而言,至少為近似 長方形。 依本發明的第三特點,可用以下方式使遮罩更不受極 化作用影響:至少有一構造有一個由介電材料構成的層。 這種介電層,舉例而言,可為由石英構成的一單獨的 φ層或者由數個薄的個別層構成的層設罩,例如習知的抗反 射層。此介電層在近接場(Nahfeld)中造成電磁場分佈的 改變,且可針對所要之極化中性的性質而且係對於透過能 力及相位延遲的方面)作最佳化。 顯然地,上述的措施也可互相組合。因此,舉例而言 可用核心構造包圍住矽構成的不透光構造〔在此構造上用 後氧化作用(Nachoxidation )時產生一個由石英玻璃構成 的薄層〕,該核心構造同樣地由石英玻璃構成。藉著將這 •些措施組合,可以使透過能力受極化的影響和在相位光罩 的場合一樣小。 本發明的其他特點與優點在以下配合圖式的一實施例 作說明。 【實施方式】 第1圖顯示一個依先前技術之光蝕印的投影曝光設備 的側視圖,此圖係咼度簡化且非呈正確比例者,該設備整 體用(10)表示,該投影曝光設備(10)有一照射裝置(11),它 用於產生投影光(12),為此目的,該照射裝置(1丨)包含一光 12 200534050 由光源(13)產生的投影 ’係為193奈米,且 源(1 3),舉例而言,可為雷射裝置。 光(12)的波長,在此所示之實施例中 因此在低頻紫外線光譜範圍。 光學元件,用(14)表示, 各種不同方式改變,例 麦其角度的分佈,由於 雷射裝置,因此所發出According to another feature of the present invention, the effect of a mask that is more neutral to polarization (less affected by polarization) can be achieved in the following ways; there is a dielectric material in an intermediate space between two structures, which No contact with this: structure. In this way, light mainly propagates in the dielectric material (for example, the dielectric material may be the gap left between the dielectric material and the opaque structure by quartz glass (for example, t may be filled with air or A protective gas), the field strength is small. Therefore, the depth of light penetration is correspondingly small, and the light absorbed by the material that forms the opaque structure is correspondingly small. Here, the width of the gap is The polarization property has a significant impact 'by simulation or-optimization = sequence' can be known: in the case of a predetermined pattern composed of opaque materials', exactly what is the transmission capacity of the gap width Receptivity and response are minimal. ^ / The relative of the dielectric material in the space between T to the polarization component (its polarization direction is parallel and extending perpendicular to the longitudinal extension of the structure): the phase delay effect is also very Beneficial effects. Here, & can be used to find "design parameters" by researching or designing, which can minimize the overall polarization effect. In other words, the transmission capacity is affected by polarization and the relative phase delay. For most / J, 〇11 200534050 in The material in the intermediate space between the structures should preferably constitute a core structure that extends substantially parallel to the longitudinal direction of the opaque structure. Here, the cross-section of this core structure is, for example, at least approximately rectangular According to the third feature of the present invention, the mask can be made less affected by polarization in the following manner: at least one layer is constructed with a layer made of a dielectric material. Such a dielectric layer, for example, can be made of quartz A single φ layer is formed or a layer composed of several thin individual layers is provided with a cover, such as a conventional anti-reflection layer. This dielectric layer causes a change in the electromagnetic field distribution in the near-field (Nahfeld), and can be tailored to the desired The polarization-neutral nature is also optimized for transmission capability and phase delay. Obviously, the above measures can also be combined with each other. Therefore, for example, an opaque structure made of silicon can be surrounded by a core structure [a thin layer of quartz glass is generated when Nachoxidation is used on this structure], and the core structure is also composed of quartz glass . By combining these measures, the transmission capacity can be affected by polarization as little as in the case of a phase mask. Other features and advantages of the present invention are described below in conjunction with an embodiment of the drawings. [Embodiment] FIG. 1 shows a side view of a projection exposure apparatus according to the prior art photoetching. This figure is simplified and not in the correct ratio. The apparatus is represented by (10) as a whole. The projection exposure apparatus (10) An illumination device (11) is used for generating projection light (12). For this purpose, the illumination device (1 丨) contains a light 12 200534050 The projection generated by the light source (13) is 193 nm And the source (1 3), for example, may be a laser device. The wavelength of light (12), in the embodiment shown here, is therefore in the low-frequency ultraviolet spectral range. The optical element, represented by (14), is changed in various ways. For example, the distribution of its angle is emitted by the laser device.
此外,5亥知射裝置(11)包含數個 它們將從光源(13)出來的投影光用 如將光束形狀改變,或混合,或改 圖示之實施例中的光源(1 3)為一種 的投影光最先係呈線型極化。 此外,該照射裝置⑽包含—投影物鏡(16),其物平面 (18)中設—光罩(20),設成可以移行的方式。在投影物鏡⑽ 的像平面(22)中,有一個光敏漆(24)構成的光敏層。光敏漆 (24)係直地施覆在-載體(26)或者間接地經由已構造化的層 細覆在其_L ’該載體(26)設計成矽晶圓的形式。由於投影 曝光設備⑽在先前技術中已為習知,故其進—步細節不 予贅述。 第2圖以高度示意的圖示顯示該光罩(2〇),舉例而言, 它包含-簡單的圖t,由水平與垂直的圖案(28)或(3〇)構 成。在此各長方形表示在圍繞的構造間的一個中間空間。 為了簡明起見,此處假設這些水平與垂直的構造(28)或(3〇) 只有方向性不同,但其寬度或互相的間隔並無不同。構造 (28)(30)由鉻構成,因此投影光(12)不能透過去。 如箭頭(32)所示的平行於水平構造(28)極化的投影光 (12),可無阻礙地穿透水平構造(28)之間的中間空間。然而 對於穿透過垂直延伸的構造(30)之間的中間空間的投影光 13 200534050 線(12)則其透過能力受限。這些垂直的構造(30)之間的中間 空間對於垂直於其縱方向極化的投影光(12)而言,其穿透 月b力比起在水平構造(28)之間的中間空間更小。 第2圖右邊顯示一個由水平與垂直構造(28,)(3〇,)構成 的圖案,它被投影物鏡(16)投影到光敏漆(24)上。為了簡明 起見,成像比例選設為1 ··丨,因此在光敏漆(24)上產生的 圖案大致相當於光罩(20)上的圖案。在第2圖所示之實施 φ 例中可看出:在光罩(20)上的垂直構造(30)並非以與水平延 伸的構造(28)間的中間空間相同的構造寬度成像到像平面 (22)上〔光敏漆(24)在該像平面上延伸〕。其起因在於··在 垂直的延伸的構造(3 0)之間的中間空間對於投影光(12)的穿 透能力比起在水平延伸的構造(28)之間的中間空間小。因 此在光敏漆(24)上的投影光(12)的強度就不同,其強度各依 該投影構造(28)(30)的朝向是平行式垂直於投影光(12)的極 化方向(32)而定。由於光敏漆(24)的照射臨限範圍很窄,因 胃| 此這種光強度的不同使得產生的構造(28,)(30,)的寬度也不 當地不同。 在第3圖所示之視圖中係假設光罩(2〇)被圓形極化的 投影光(12’)穿過。由於與不透光構造(28)(3〇)呈垂直與平 行地極化的投衫光(1 2 )的極化分量的透過能力不同’因此 該投影光(12’)在通過光罩(2〇)後,受到不同之橢圓形的極 化。這種橢圓形極化作用描述出的橢圓形(34)(36)係互相垂 直。如果此時該橢圓形極化作用要被一「延遲小板」(3 8) 轉變成一種線型的極化作用,則這點只能對一很確定的圓 14 200534050 形極化作用達成。因此投影光(12,)的極化作用各不相同。 各依它是穿過水平或垂直的構造(28)或(3〇)之間的中間空間 而定。如果該投影物鏡(16)含有與極化有關的光學元件, 例如一種對極化有選擇性的分光層或雙折射的元件,則這 種極化的影響一般同樣地會使得產生的構造(28,)(3〇,)有; 同的寬度。 對此本發明提出對策,使用一種光罩,它在整體上具有 φ較小的極化的作用,且特別是透過能力受極化的影響較小。 第4圖中顯示本發明第一實施例的一光罩(2〇a)的立體 圖,藉之可將透過能力受極化的影響減少。光罩(2〇^有一 載體(40)’其構成之材料對於波長193奈米的投影光(ua) 係透明者。在此波長,載體(4〇)所用的材料舉例而言可考 慮石英玻璃。 在載體(4G)之背向照射裝置(11)的_表面(42)上施覆一 圖案’該圖案不透光的構造(44)構成,它在此處只作例示。 讓在第4圖所示之實施例巾’該不透光構造(44)包含較粗縫 之大面積構造(441)與較細緻的框條狀構造(442),其橫截面 大致呈長方形,這些構造(44)係在一道光姓印方式所定的 蚀刻程序的過程由-個層(46)產生,該層(46)由一導電材料 構成,其折射指數的虛數部分大力1.8。在圖式的實施例 中,此材料為矽,其折射指數的虛數部岀在波長193奈米 時大約為2.78。 在該不透光構造(44)之間留有中間空間(48),它用一種 包圍的氣體(例如空氣或特別的保護氣體)充滿,在所示 15 200534050 之圖示之實施例中’框條狀構造(442)的間隔p為4〇〇奈米, 而層(46)的高度d為100奈米。 由於構造(44)的折射指數的虛數部分m很大,故垂直 於框條式構造(442)的縱方向極化且穿過中間空間(48)的投 影光(12a)只侵入該構造(44)中大約幾個原子層的深度。因 此在這些中間空間(48)中的電場只受到這些構造微不足道 地減弱。而平行於框條構造(442)的縱方向極化的極化光則 φ由於所謂的「金屬絲袼柵效應」而減弱。 如此,該與構造(442)的縱方向平行及垂直極化的投影 光(12a)的分量減弱程度大約相同,因此光罩(2〇a)透過能力 /、叉该穿過之投影光的極化方向有很小的影響。 第4圖中係假設該照到光罩(2〇a)上的投影光(i2a)係非 極化者。因此該投影光(12a)在穿過光罩(2〇a)之前,在所有 垂直於投影光(1 2a)的一傳播方向的所有方向,其極化方向 有一種呈統計學方式變化的分佈,如第4圖用極化分佈 g所示者。被構造(44)繞射的投影光(12a,,),固然由於被構造 (44)吸收,而整體上有較小的強度,然而投影光(i2a)的極 化作用則保持不受影響。利用光罩(2〇a)造成在互相垂直的 極化方向之間的相位延遲作用,在未極化光的場合,對於 極化狀態不會有影響。由此,被構造(44)繞射的投影光(12a,) 仍未極化,如中用極化分佈(50,)所示者。 弟5圖中顯示依本發明弟二實施例之與第*圖相似的 一光罩(20b)的視圖。與第4圖所示之第一實施例相同的部 件用相同的圖號表示。 16 200534050 光罩(20b)與第4圖b所示的光罩(2〇a)不同處在於:第 -、層(46)不一定要由該種材料構成(該材料折射指數且 有特別大的虛數部分)。因此該層(46)舉例而言,也可由 鉻構成。但重要的是在光罩(2〇b)的場合,在框條形構造042) 之間的中間空間(48)中有核心構造(54)施覆到載體(4〇)上, 該載體(40)由一種介電材料(例如石英玻璃構造)。核心 構造(54)同樣地具有至少近乎長方形的橫截面,且平行於 該不透光的構造延伸,但不與該構造接觸。用此方式,在 核心構造(54)與不透光的構造(44)之間留有狹窄的縫隙 (5 6),其寬度a在所示實施例中為丨5奈米。 投景》光(126)〔它在不透光構造(44)之間侵入中間空間 (48)中〕大致在核心構造(54)中導進。反之,在縫隙(56)中, 投影光(12b)的電場強度則很小。用此方式,可使該投影光 (12b)以及特別是其垂直於構造(442)的縱方向延伸的極化分 量只有很小的一部分在構造(44)的垂直邊緣區域中被吸 收。因此,該光罩(20b)的透過能力在此實施例中也只在很 小的範圍中受入射之投影光的極化方向影響。 此外’该光罩在二個互相垂直的極化分量之間只會產 生很小的相位移動。 第5圖中顯示在通過光罩(20b)之前及之後,投影光(12b) 的極化作用的分佈(50b)與(50b,)。此處假設為極化光(12b) 的一種圓形極化作用。通過光罩(2〇b)的投影光(12b,)仍呈 圓形極化或者在所有情形中略呈橢圓形極化。在此對於互 相垂直的極化分量而言,透過能力以及有效折射指數差別 17 200534050 越大,則所造成之極化狀態的橢圓偏心率越大。 在第6圖中顯不本發明的第三實施例的光罩(⑽之與 第4及第5圖相似的立體圖。與第4圖中所示第一實施例 相同的部件用相同的圖號表示。 光罩(20c)“第4圖所示光罩(術)不同處在於··該構造 晴有,介電材料(例如石英玻璃)構成的覆層_。 士果士在第4圖所不的光罩(20a)的情形,該構造(44)由 • 冓力貝j舉例而g ’這種覆層⑽)可藉著將構造(4句的表 面作後續的氧化作用而產生。但該覆層(60)(在所示實施 例中’其厚度h為90奈米)也可做成多層系统,例如呈 抗反射層的種類。 事見顯不,藉著將一覆層(6〇)施到構造(44)上,可使透 過能力受極化的影響減少。這點示於帛6圖中,利用投影 光(12c)(12c’)在穿過光罩(2〇c)之前或之後的極化分佈In addition, the radiating device (11) includes several projection light from the light source (13), such as changing the shape of the beam, or mixing, or changing the light source (13) in the illustrated embodiment. The first projection light was linearly polarized. In addition, the irradiating device ⑽ includes a projection objective lens (16), and an object plane (18) is provided with a photomask (20) so as to be movable. In the image plane (22) of the projection objective ⑽, there is a photosensitive layer composed of a photosensitive paint (24). The photosensitive lacquer (24) is applied directly on the carrier (26) or indirectly via a structured layer, and the carrier (26) is designed in the form of a silicon wafer. Since projection exposure equipment is already known in the prior art, its further details will not be described in detail. Figure 2 shows the reticle (20) in a highly schematic illustration. For example, it contains-a simple graph t consisting of horizontal and vertical patterns (28) or (30). The rectangles represent an intermediate space between the surrounding structures. For the sake of brevity, it is assumed here that these horizontal and vertical structures (28) or (30) are only different in directionality, but their widths or intervals are not different. Structures (28) and (30) are made of chromium, so the projection light (12) cannot pass through. As shown by the arrow (32), the projection light (12) polarized parallel to the horizontal structures (28) can penetrate the intermediate space between the horizontal structures (28) unhindered. However, for the projected light penetrating through the intermediate space between the vertically extending structures (30) 13 200534050 line (12) has limited transmission ability. The intermediate space between these vertical structures (30) is smaller than the intermediate space between horizontal structures (28) for the projected light (12) polarized perpendicular to its longitudinal direction. . Figure 2 on the right shows a pattern consisting of horizontal and vertical structures (28,) (30,), which is projected onto the photosensitive paint (24) by a projection objective (16). For the sake of brevity, the imaging ratio is selected as 1 ·· 丨, so the pattern produced on the photosensitive paint (24) is roughly equivalent to the pattern on the photomask (20). It can be seen in the implementation φ example shown in FIG. 2 that the vertical structure (30) on the mask (20) is not imaged on the image plane with the same structural width as the intermediate space between the horizontally extending structures (28). (22) [Photosensitive paint (24) extends on the image plane]. The reason is that the intermediate space between the vertically extending structures (30) penetrates the projection light (12) less than the intermediate space between the horizontally extending structures (28). Therefore, the intensity of the projection light (12) on the photosensitive paint (24) is different, and its intensity depends on the direction of the projection structure (28) (30) is parallel to the polarization direction (32) of the projection light (12). ). Because the exposure threshold of the photosensitive paint (24) is very narrow, the difference in light intensity makes the width of the structure (28,) (30,) different. In the view shown in Fig. 3, it is assumed that the mask (20) is passed by the circularly polarized projection light (12 '). Since the polarized components of the cast light (1 2) polarized vertically and parallel to the opaque structure (28) (30) have different transmission capabilities, the projection light (12 ') passes through the photomask ( After 20), it is subjected to different elliptical polarizations. The elliptical (34) (36) described by this elliptical polarization is perpendicular to each other. If the elliptical polarization is to be transformed into a linear polarization by a "delay plate" (38) at this time, this can only be achieved for a well-defined circular polarization effect. Therefore, the polarization of the projection light (12,) varies. Depending on whether it passes through the intermediate space between horizontal or vertical structures (28) or (30). If the projection objective (16) contains polarization-dependent optical elements, such as a polarization-selective beam splitter or birefringent element, the effect of this polarization will generally also result in the resulting structure (28 () (3〇,) has; the same width. The present invention proposes a countermeasure to this, using a photomask that has a polarization effect of smaller φ as a whole, and in particular, the transmission capacity is less affected by the polarization. Fig. 4 shows a perspective view of a photomask (20a) according to the first embodiment of the present invention, thereby reducing the influence of polarization on the transmission capability. The photomask (2〇 ^ has a carrier (40) 'whose material is transparent to the projection light (ua) with a wavelength of 193 nm. At this wavelength, the material used for the carrier (40) can be considered as an example of quartz glass A pattern is formed on the surface (42) of the carrier (4G) facing away from the irradiation device (11). The pattern is an opaque structure (44), which is only illustrated here. In the embodiment shown in the figure, the opaque structure (44) includes a large-area structure (441) with a thick seam and a finer frame-like structure (442). The cross section is generally rectangular. These structures (44 ) The process of an etching procedure defined by a light-printing method is produced by a layer (46) composed of a conductive material, and the imaginary part of its refractive index is strongly 1.8. In the illustrated embodiment, This material is silicon and its imaginary part of the refractive index is approximately 2.78 at a wavelength of 193 nm. There is an intermediate space (48) between the opaque structure (44), which uses a surrounding gas (for example Air or special protective gas) filled example shown in 15 200534050 'The interval p of the frame strip structure (442) is 400 nm, and the height d of the layer (46) is 100 nm. Since the imaginary part m of the refractive index of the structure (44) is large, it is perpendicular to the frame The stripe structures (442) are vertically polarized and projected light (12a) passing through the intermediate space (48) only penetrates into the depth of the structure (44) by a few atomic layers. Therefore, in these intermediate spaces (48) The electric field of is only weakly weakened by these structures. The polarized light polarized in the longitudinal direction parallel to the frame structure (442) is weakened by the so-called "wire grid effect". Thus, the AND structure (442) The longitudinally parallel and vertically polarized projection light (12a) has approximately the same degree of attenuation, so the transmission capacity of the mask (20a) and the polarization direction of the projected light passing through it have little effect. In Fig. 4, it is assumed that the projection light (i2a) hitting the mask (20a) is a non-polarized person. Therefore, the projection light (12a) passes through the mask (20a) at all In all directions perpendicular to a propagation direction of the projection light (1 2a), the polarization direction changes in a statistical manner. , As shown in Figure 4 by the polarization distribution g. The projected light (12a ,,) diffracted by the structure (44), although absorbed by the structure (44), has a small overall intensity, However, the polarization of the projection light (i2a) remains unaffected. The use of the mask (20a) causes a phase delay between the mutually orthogonal polarization directions. In the case of unpolarized light, the polarization The state will have no effect. Therefore, the projected light (12a,) diffracted by the structure (44) is still unpolarized, as shown by the polarization distribution (50,) used in the figure. A second embodiment of the second embodiment is similar to the figure * view of a mask (20b). The same components as those of the first embodiment shown in Fig. 4 are designated by the same reference numerals. 16 200534050 The photomask (20b) is different from the photomask (20a) shown in Fig. 4 in that the-and layer (46) do not have to be composed of this material (the refractive index of this material is particularly large) Imaginary part). This layer (46) can also be made of chromium, for example. However, it is important that in the case of the photomask (20b), a core structure (54) is applied to the carrier (40) in the intermediate space (48) between the frame-strip structure 042), and the carrier (40) 40) Constructed from a dielectric material (such as quartz glass). The core structure (54) likewise has at least a nearly rectangular cross-section and extends parallel to the opaque structure but does not contact the structure. In this way, a narrow gap (56) is left between the core structure (54) and the opaque structure (44), the width a of which is 5 nm in the embodiment shown. The "casting scene" light (126) [which penetrates the intermediate space (48) between the opaque structures (44)] is roughly guided in the core structure (54). In contrast, in the gap (56), the electric field intensity of the projection light (12b) is small. In this way, only a small part of the projection light (12b) and especially its polarization component extending perpendicular to the longitudinal direction of the structure (442) can be absorbed in the vertical edge region of the structure (44). Therefore, the transmittance of the mask (20b) is also affected by the polarization direction of the incident projected light in a small range in this embodiment. In addition, the mask will produce only a small phase shift between two mutually polarized components. Figure 5 shows the distributions (50b) and (50b,) of the polarization of the projected light (12b) before and after passing through the mask (20b). This assumes a circular polarization of polarized light (12b). The projection light (12b,) passing through the mask (20b) is still circularly polarized or slightly elliptical in all cases. For the polarization components that are perpendicular to each other, the larger the difference in transmittance and effective refractive index 17 200534050, the greater the ellipse eccentricity of the polarization state caused. The photomask of the third embodiment of the present invention is shown in Fig. 6 (a perspective view similar to Figs. 4 and 5). The same components as those of the first embodiment shown in Fig. 4 are given the same reference numerals. Photomask (20c) "The photomask (operation) shown in Figure 4 differs in that ... the structure is clear, and the coating is made of a dielectric material (such as quartz glass). In the case of a non-mask (20a), the structure (44) is illustrated by • 冓 Libei j and g 'this kind of coating ⑽) can be generated by the structure (the surface of 4 sentences is subjected to subsequent oxidation. The coating (60) (in the illustrated embodiment, 'its thickness h is 90 nanometers) can also be made into a multilayer system, such as a type of anti-reflection layer. As it turns out, by coating a coating (6 〇) Applied to the structure (44), the transmittance can be reduced by the influence of polarization. This is shown in Figure 6 and the projection light (12c) (12c ') is used to pass through the photomask (20c). Before or after polarization distribution
(5〇C)(5Ge,)表示。此處該投影光(12e)與帛4圖中相似,係 未極化者。由於有覆層(6G),故該極化狀態即使在通過光 罩(20C)後仍保持不變。 么八著將上述的措鈀作任意組合,或將所有三個實施例 組口,還可將透過能力受極化的影響進_步減少。因此, 2例而3,由石夕構成的不透光的構造(44)〔在後氧化過程 #,有-薄石英玻璃層_在其上產生〕彳包圍同樣由石 英玻璃構成的核心構造(54)。 顯然地 奈米更短時 ’上述實施例可用多種方式變更 ’例如在157奈米的波長時, 。當波長比1 9 3 則該載體(40)、 18 200534050 核心構造(54)及層(60)的材料宜為螢石(Fluj3spat)( CaF2), 因為石奂玻璃對此波長的光吸收性太強。此外,可將該構 造(44)及核心構造(54)不直接用載體(4〇)承載,而係間接地 由施在載體上的一層或數層中間層所承載。 【圖式簡單說明】 第1圖係依先前技術的一微光蝕印投影曝光設備的高 度簡化的側視圖,(50 ° C) (5Ge,). Here, the projection light (12e) is similar to that in Fig. 4 and is unpolarized. Due to the coating (6G), this polarization state remains unchanged even after passing through the mask (20C). The combination of the above-mentioned measures of palladium in any combination, or the combination of all three embodiments, can further reduce the influence of the transmission capacity by polarization. Therefore, in 2 cases and 3, the opaque structure made of Shi Xi (44) [in the post-oxidation process #, there is-thin quartz glass layer _ generated on it] 彳 surrounds the core structure also made of quartz glass ( 54). Obviously, when the nanometer is shorter, the above embodiment can be changed in various ways, for example, at a wavelength of 157 nanometers. When the wavelength ratio is 1 9 3, the material of the carrier (40), 18 200534050 core structure (54) and layer (60) should be fluorite (Fluj3spat) (CaF2), because the light absorption of this wavelength is too low. Strong. In addition, the structure (44) and the core structure (54) may not be directly carried by the carrier (40), but indirectly by one or several intermediate layers applied on the carrier. [Brief description of the figure] FIG. 1 is a highly simplified side view of a low-light etching projection exposure apparatus according to the prior art.
第2圖係依先前技術的一個用線型極化光照射曝光的 光罩以及一個在晶圓上如此所產生的構造的高度示意的立 體圖, 第3圖係依先前技術用圓形極化光照射曝光的光罩, 及一個四分之一波長小板以及一個在晶圓上如此所產生的 構造的高度示意立體圖, 第4圖係依本發明第一特點的一個具有矽成之構成的 光罩的放大立體圖(此圖並非成正確比例者), 第5圖係依本發明第二特點之具有介電核心構造的光 罩之類似第4圖之視圖, 第6圖係依本發明第三特點的一個光罩之類似於第4 圖的視圖,它具有帶介電質覆層的構造。 【主要元件符號說明】 (10) 投影曝光設備 (11) 照射裝置 (12) (12’)(12”)(12a)(l2b)投影光 (13) 光源 19 200534050 (14) 光學元件 (16) 投影物鏡 (18) 物平面 (20a)(20b)(20c) 光罩 (22) 像平面 (24) 光敏漆 (26) 載體 (28)(289) 水平構造 (30)(305) 垂直構造 (32) 箭頭 (34) 橢圓形 (36) 擴圓形 (38) 延遲小板 (40) 載體 (42) 表面 (44) 不光 (441) 粗链的大面積構造 (442) 細緻的框條狀構造 (46) 層 (48) 中間空間 (50b)(50b,)(50c)(50c,) 極化作用的分佈 (54) 核心構造 (56) (60)覆層 縫隙 20FIG. 2 is a highly schematic perspective view of a photomask irradiated with linearly polarized light and a structure so produced on a wafer according to the prior art, and FIG. 3 is a circularly polarized light according to the prior art. The exposed photomask, and a quarter-wave plate and a highly schematic perspective view of the structure thus produced on the wafer. FIG. 4 is a photomask made of silicon according to the first feature of the present invention. Figure 3 is an enlarged perspective view (this figure is not to scale), Figure 5 is a view similar to Figure 4 in a photomask with a dielectric core structure according to the second feature of the present invention, and Figure 6 is according to the third feature of the present invention A view of a photomask similar to that of Figure 4 has a construction with a dielectric coating. [Symbol description of main components] (10) Projection exposure equipment (11) Irradiation device (12) (12 ') (12 ") (12a) (l2b) Projection light (13) Light source 19 200534050 (14) Optical element (16) Projection objective (18) Object plane (20a) (20b) (20c) Mask (22) Image plane (24) Photosensitive paint (26) Carrier (28) (289) Horizontal structure (30) (305) Vertical structure (32 ) Arrow (34) Oval (36) Rounded (38) Delay plate (40) Carrier (42) Surface (44) Not only (441) Large area structure with thick chains (442) Fine frame-like structure ( 46) Layer (48) Intermediate space (50b) (50b,) (50c) (50c,) Distribution of polarization (54) Core structure (56) (60) Overlay gap 20
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004006227 | 2004-02-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW200534050A true TW200534050A (en) | 2005-10-16 |
Family
ID=34832564
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW094101369A TW200534050A (en) | 2004-02-09 | 2005-01-18 | Mask for use in a microlithographic projection exposure system |
Country Status (2)
| Country | Link |
|---|---|
| TW (1) | TW200534050A (en) |
| WO (1) | WO2005076078A2 (en) |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6084817A (en) * | 1983-10-15 | 1985-05-14 | Mitsubishi Electric Corp | Mask for sor light exposure |
| JPH0695363A (en) * | 1992-09-11 | 1994-04-08 | Toppan Printing Co Ltd | Photomask blank, manufacturing method thereof, and photomask |
| US6120942A (en) * | 1997-02-18 | 2000-09-19 | Micron Technology, Inc. | Method for making a photomask with multiple absorption levels |
| WO2000046643A1 (en) * | 1999-02-05 | 2000-08-10 | Rochester Institute Of Technology | Masks for use in optical lithography below 180 nm |
| DE19958201A1 (en) * | 1999-12-02 | 2001-06-21 | Infineon Technologies Ag | Lithographic process for structuring layers during the manufacture of integrated circuits comprises guiding radiation emitted by a radiation source and lying in the extreme UV range onto photosensitive layers via a mask |
| US6818357B2 (en) * | 2001-10-03 | 2004-11-16 | Intel Corporation | Photolithographic mask fabrication |
-
2005
- 2005-01-18 TW TW094101369A patent/TW200534050A/en unknown
- 2005-01-24 WO PCT/EP2005/000640 patent/WO2005076078A2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| WO2005076078A2 (en) | 2005-08-18 |
| WO2005076078A3 (en) | 2008-12-11 |
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