TW200421917A - Organic EL panel and method for manufacturing the same - Google Patents
Organic EL panel and method for manufacturing the same Download PDFInfo
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- TW200421917A TW200421917A TW093108695A TW93108695A TW200421917A TW 200421917 A TW200421917 A TW 200421917A TW 093108695 A TW093108695 A TW 093108695A TW 93108695 A TW93108695 A TW 93108695A TW 200421917 A TW200421917 A TW 200421917A
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/87—Passivation; Containers; Encapsulations
- H10K59/874—Passivation; Containers; Encapsulations including getter material or desiccant
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/805—Electrodes
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/8791—Arrangements for improving contrast, e.g. preventing reflection of ambient light
- H10K59/8792—Arrangements for improving contrast, e.g. preventing reflection of ambient light comprising light absorbing layers, e.g. black layers
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K77/00—Constructional details of devices covered by this subclass and not covered by groups H10K10/80, H10K30/80, H10K50/80 or H10K59/80
- H10K77/10—Substrates, e.g. flexible substrates
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Abstract
Description
200421917 玫、發明說明: 【發明所屬之技術領域】 本發明涉及一種有機EL(Electroluminescence)面板及其 製造方法。 【先前技術】 有機EL面板疋以有機EL元件為基本結構,把該有機el元 件作為單位面發光部件排列在平面基板上而形成的,該有 機EL元件是通過在支撐基板上形成第一電極,在其上形成 包含由有機化合物構成的發光層的有機層,再在其上形成 第二電極而構成的。 已知在所述有機層和電極曝露於外部空氣狀態下時有機 EL面板的特性會劣化。這是由於水分浸入有機層與電極間 的交界面,妨礙了電子注入,進而產生作為非發光區域的 暗點,或因電極腐蝕現象而造成,為了提高有機£1元件的 穩定性和耐久性,使有機EL元件與外部空氣隔絕的密封技 術是必不可缺的。關於該密封技術,一般採用在形成有電 極和有機層的支撐基板上,通過粘接劑將覆蓋該電極和有 機層的密封部件進行粘合的方法。 圖1表示該有機EL面板的習知技術(參照下述專利文獻 1)。有機EL面板(有機EL元件M由成為支撐基板的玻璃基板 2、ITO電極3和有機發光材料層4和陰極5構成的疊層體6、 成為密封部件的玻璃密封罐7、乾燥部件8以及㈣材料9 構成。 乾燥部件8是為了在通過玻璃密封罐7密封后,吸收除去200421917 Description of the invention: [Technical field to which the invention belongs] The present invention relates to an organic EL (Electroluminescence) panel and a manufacturing method thereof. [Prior art] An organic EL panel is formed by using an organic EL element as a basic structure and arranging the organic EL element as a unit-plane light-emitting component on a flat substrate. The organic EL element is formed by forming a first electrode on a supporting substrate. An organic layer including a light-emitting layer made of an organic compound is formed thereon, and a second electrode is formed thereon. It is known that the characteristics of the organic EL panel are deteriorated when the organic layer and the electrode are exposed to the outside air. This is due to the penetration of moisture into the interface between the organic layer and the electrode, which prevents electron injection, thereby creating dark spots as non-light-emitting areas, or caused by electrode corrosion. In order to improve the stability and durability of organic components, A sealing technology that insulates the organic EL element from the outside air is indispensable. This sealing technique generally employs a method of bonding a sealing member covering the electrode and the organic layer with an adhesive on a support substrate on which the electrode and the organic layer are formed. Fig. 1 shows a conventional technique of the organic EL panel (see Patent Document 1 below). Organic EL panel (Organic EL element M is a laminated body 6 composed of a glass substrate 2 serving as a supporting substrate, an ITO electrode 3, an organic light emitting material layer 4 and a cathode 5, a glass sealed can 7 serving as a sealing member, a drying member 8 and ㈣ The material 9 is formed. The drying member 8 is designed to be absorbed and removed after being sealed by the glass sealing pot 7
O:\92\92316.DOC 200421917 子在於其中的初期水分以及隨時間釋放出的或浸入的水分 而設置的。特別是由於形成有機虹元件的有機層抗熱能力 弱’不能在密封前通過加熱處理除去水分,所以不能完全 排出這樣的初期水分。因此,在使用現有的有機el材料的 面板中不侍不在密封部件内設置這種乾燥部件8。在下述 專利文獻1中有以下記載,作為乾燥部件8,使用可以通過 化學方式吸附水分並且即使吸濕也能維持固體狀態的化合 物,使用枯接材料把該乾燥部件8安裝在玻璃密封罐7的内 面(與玻璃基板對置的面)。 專利文獻1 特開平9-148066號公報 在這種現有的有機EL面板中,採用把有機EL元件的支撐 基板(玻璃基板·作成透明基板,從該支撐基板側發光的 方式(底面射出方式)。在這種情況下會產生下述現象,即, 外部光從支撐基板等入射到面板内部(由支撐基板和密封 部件(玻璃密封罐7)包圍而成的密封空間),然後,入射光在 密封部件的内面(與支撐基板相對的面)或被設置在該内面 上的乾燥部件的表面反射,從支撐基板的顯示面射出。另 外,雖然由有機EL元件發出的光的大部分被設定成從支撐 基板的發光面射出,但有時其中一部分光在面板内成為散 射光’和上述的外部光相同,該散射光在密封部件的内面 或安裝在該内面上的乾燥部件的表面反射,從支撐基板的 顯示面射出。 這樣,如果入射到面板内的外部光和來自有機EL元件的 散射光在密封部件的内面或乾燥部件的表面反射,併從顯O: \ 92 \ 92316.DOC 200421917 is set by the initial moisture content and the moisture released or immersed with time. In particular, since the organic layer forming the organic rainbow element has a low heat resistance, it is impossible to remove moisture by heat treatment before sealing, so that such initial moisture cannot be completely discharged. Therefore, such a drying member 8 is not provided in a sealing member in a panel using a conventional organic el material. In the following Patent Document 1, the following is described. As the drying member 8, a compound that can absorb moisture chemically and maintain a solid state even if it absorbs moisture is used. Inner surface (surface opposite to glass substrate). Patent Document 1 Japanese Patent Application Laid-Open No. 9-148066 discloses a conventional organic EL panel in which a supporting substrate (a glass substrate and a transparent substrate made of an organic EL element) is used to emit light from the supporting substrate (a bottom surface emitting method). In this case, a phenomenon occurs in which external light enters the inside of the panel from a support substrate or the like (a sealed space surrounded by the support substrate and a sealing member (glass sealing pot 7)), and then the incident light is sealed. The inner surface of the component (the surface opposite to the support substrate) or the surface of the dry component provided on the inner surface is reflected from the display surface of the support substrate. In addition, most of the light emitted by the organic EL element is set to be from The light-emitting surface of the support substrate is emitted, but a part of the light becomes scattered light in the panel, which is the same as the above-mentioned external light. The scattered light is reflected on the inner surface of the sealing member or the surface of the drying member mounted on the inner surface, and is reflected from the support. The display surface of the substrate is emitted. In this way, if external light incident into the panel and scattered light from the organic EL element enter the sealing member, Surface reflection or inner surface drying member, and the sensible
O:\92\92316.DOC 200421917 的射出光形成的顯 不面側射出,會產生來自有機EL元件 示對比度降低的問題。 :且:如果在密封部件的内面或乾燥部件的表面反射的 一側射出’那麼在從顯示面直接或 :基=況下等:有時會看到配置在面板内部的乾燥部 ^生對外觀造成不利的影響的問題。因此,如果 把這種外觀的缺陷視為次品,則需要針對外部光的人射和 散射光的防止進行高精度地設計,並且還必須提高乾燥部 件的配置位置等的精度’所以存在著產品的成品率降低, 產品成本增高的問題。 【發明内容】 本I月疋以解决上述問題為課題而提出的。即,本發明 :目的在於,提供„種有機EL面板及其製造方法,以此來 提高顯示面的對比《,消除從顯示面—側可看到面板内部 的乾燥部件的外觀缺陷,提高產品的成品率,降低產品成 本等0 為了達到上述目的,本發明的有機EL面板及其製造方法 至少具有以下各獨立技術方案。 [技術方案1] 一種有機£乙面板,在支撐基板上,形成在 一對電極間夾著至少含有發光層的有機層的有機el元件, 併粘合有使該有機EL元件與外部空氣隔絕的密封部件,其 特徵在於’在所述密封部件的與所述支撐基板相對的面上 設置已著色的乾燥部件。 [技術方案6] —種有機EL面板的製造方法,具有在支撐O: \ 92 \ 92316.DOC 200421917 The display side formed by the emitted light is emitted, which causes a problem that the contrast of the organic EL element is reduced. : And: If it is projected on the inner side of the sealing member or on the reflecting side of the dry member, then directly from the display surface or: base = case, etc .: sometimes the dry part placed inside the panel may be seen to the appearance Causing adverse effects. Therefore, if this defect in appearance is regarded as a defective product, it is necessary to design with high precision for the prevention of human light and scattered light from external light, and it is also necessary to improve the accuracy of the placement position of the drying parts, etc. The problem of lower yields and higher product costs. [Summary of the Invention] This month, I propose to solve the above problems. That is, the present invention aims to provide "an organic EL panel and a method for manufacturing the same, so as to improve the contrast of the display surface", eliminate the appearance defects of the dry parts that can see the interior of the panel from the display surface to the side, and improve the In order to achieve the above-mentioned object, the organic EL panel and the manufacturing method thereof of the present invention have at least the following independent technical solutions. [Technical solution 1] An organic panel is formed on a supporting substrate in a An organic el element having an organic layer containing at least a light-emitting layer is sandwiched between the counter electrodes, and a sealing member that isolates the organic EL element from the outside air is bonded, characterized in that 'the sealing member is opposed to the support substrate. [Colored dry part] is provided on the surface. [Technical solution 6] A method for manufacturing an organic EL panel
O:\92\92316.DOC 200421917 基板上形成在-對電極間夾著至少含有發光層的有機層的 有機EL元件的元件形成工序,和將使該有機肛元件盘夕^ 空氣隔絕的密封部件枯合在所述支撐基板上的密封工序, 其特徵在於,在所述密封工序之前,在所述密封部件的與 所述支撐基板相對的面上安褒已著色的乾燥部件。 【實施方式】 以下,芩照附圖說明本發明的實施方式。圖2〜4是本發 明的—實施方式的有飢面板的說明圖。該有機肛面板 10、20、3G在支撐基板u上形成有在一對電極間夾著至少 含有發光層的有機層的有機EL元件12。而且,通過钻接劑 15把密封料13、21、31料在支撐基板11上,從而㈣ 由^標基板U和密封部件13、21、31包圍而成的密封空間 復孤有機ELtc件12,使其與外部空氣隔絕。在該密封部件 内在與支撐基板11相對的面上與有機EL·元件 12分離開設置乾燥部件14。 此處’在圖2所示的實施方式的有機虹面板附,使用平 板的么封部件13,通過在枯接劑15内混入間隔團以來形成 所述的:、封空間。在圖3所示的實施方式的有機此面板汕 T在山封部件21的支撐基板11側形成密封凹部21A,在支 樓基㈣和㈣凹部21A之間形成所述的㈣空間。在圖4 厂、、只知方式的有機EL面板3 〇令,在密封部件3 1的支撐 基板u側形成密封凹部31A,在切基板η和密封凹部Μ —士 "成所述的搶封空間,並且在密封凹部3 1A内形成用於 一 燥°卩件14的安裝凹部3 1B。該安裝凹部3 1B被用透濕O: \ 92 \ 92316.DOC 200421917 An element forming process for forming an organic EL element having an organic layer containing at least a light-emitting layer between a counter electrode and a substrate, and a sealing member that isolates the organic anal element from the air ^ The sealing step superimposed on the support substrate is characterized in that, before the sealing step, a colored dry member is mounted on a surface of the sealing member opposite to the support substrate. [Embodiment] Hereinafter, an embodiment of the present invention will be described with reference to the drawings. 2 to 4 are explanatory diagrams of a hungry panel according to an embodiment of the present invention. In the organic anal panel 10, 20, and 3G, an organic EL element 12 having an organic layer including at least a light-emitting layer between a pair of electrodes is formed on a support substrate u. In addition, the sealing materials 13, 21, and 31 are deposited on the support substrate 11 by the drilling agent 15, so that the sealed space is composed of the organic ELtc element 12 enclosed by the standard substrate U and the sealing members 13, 21, 31 Keep it away from the outside air. Inside the sealing member, a drying member 14 is provided separately from the organic EL element 12 on a surface facing the support substrate 11. Here, in the organic rainbow panel of the embodiment shown in FIG. 2, the flat sealing member 13 is used, and the above-mentioned sealing space is formed by mixing the spacers into the deadening agent 15. In the organic panel according to the embodiment shown in FIG. 3, a sealing recess 21A is formed on the support substrate 11 side of the mountain sealing member 21, and the above-mentioned ridge space is formed between the support base ridge and the ridge recess 21A. In the organic EL panel 300 of FIG. 4 in a known manner, a sealing recess 31A is formed on the supporting substrate u side of the sealing member 31, and the cutting substrate η and the sealing recess M are formed as described above. Space, and a mounting recess 3 1B for a drying member 14 is formed in the sealing recess 31A. The mounting recess 3 1B is permeable to moisture
O:\92\92316.DOC 200421917 性薄膜32堵塞著’用於防止乾燥部件14的脫落。 Χ且在本發明的實施方式的有機EL面板10、20、30中, 作為乾件14使用已著色為光吸收性顏色的部件。光吸 收性顏色只要是能夠吸收可見光區域的波長的顏色即可, 優遠黑色、灰色、、菜欠& 衣木色寺此夠均勻吸收可見光的所有波 長的顏色。作為一彳垂·#十 们貝^方式,使用被著色成大致黑多或 灰色的乾燥部件。 / 该乾燥部件14是在粘接密封部件Η、η、Η後安裝設置 的守用於吸收除去存在於其中的初期水分以及隨時間放出 或/又入的水刀’只要具有這種功能即可,沒有特別限定。 :為-個實施方式,使用下述的吸濕性模塑體,通過向該 模塑體内为散顏料來進行所述著色。 卜作為么封部件13、21、31,只要能夠保持氣密性 P可可以利用金屬或樹脂等形成,但作為一個實施方式, 優選利用破璃制基板來形成。 根據這種實施方式的有機EL面板10、20、3〇,利用來自 支撐基板11側的射出光進行顯示,在支撐基板U上形成顯 二且由於把已著色的乾燥部件14設在密封部件13、 、31中的與支撐基板11相對的表面上,所以已著色的乾 秌:件14吸收入射到面板内的外部光或來自有機队元件η 的政射光’可以防止這些光被反射後從顯示面一側射出。 由此’可以提高利用有機EL元件12的射出光而進行顯示的 Γ匕度1時可以肖除從支㈣板11側可相設在面板内 邛的乾爍部件14的外觀不良。O: \ 92 \ 92316.DOC 200421917 The blocking film 32 is used to prevent the drying member 14 from falling off. X. In the organic EL panels 10, 20, and 30 according to the embodiment of the present invention, a member that has been colored in a light-absorptive color is used as the dry material 14. The light-absorptive color is only required to be a color capable of absorbing wavelengths in the visible light region. Youyuan black, gray, and vegetable & Yimu color temple can absorb all wavelengths of visible light uniformly. As a one-touch method, ten parts are used, and dry parts colored approximately black or gray are used. / The drying member 14 is a water knife that is installed and installed after bonding the sealing members Η, η, and 用于 to absorb and remove the initial moisture present therein and to release or / re-enter the water knife over time as long as it has this function. It is not particularly limited. : As one embodiment, the coloring is performed by using a hygroscopic molding body described below and dispersing pigment into the molding body. As the seal members 13, 21, and 31, as long as the airtightness can be maintained, P may be formed of a metal, a resin, or the like, but as an embodiment, it is preferably formed of a glass-breaking substrate. According to the organic EL panels 10, 20, and 30 of this embodiment, display is performed by using the light emitted from the support substrate 11 side, and the second substrate is formed on the support substrate U, and the colored drying member 14 is provided on the sealing member 13 , 31, on the surface opposite to the support substrate 11, so the color has dried up: The piece 14 absorbs external light incident into the panel or political light from the organic element η can prevent these lights from being reflected from the display. Shoot from one side. As a result, when the display degree Γ of the organic EL element 12 is used for display 1, the defective appearance of the dry flashing member 14 which can be placed in the panel from the support plate 11 side can be eliminated.
O:\92\92316.DOC 200421917 為了防止在密封部件13、21、31内面的反射,也可以考 慮在密封部件内面塗覆光吸收性塗料,但根據這種方法, 頭外:要塗覆密封部件内面的工序,同時由於所塗覆的塗 :封:間内產生有機EL元件12的劣化因素(水分或有 、料)導致降低有機EL元件12壽命的不良情況。如果根 據本發明的實施方式,通過將乾燥部件14著色,不會影響 製造工序的工·康叙η, ' 數目,也不會在密封空間内產生有機EL元 件12的劣化因素。 ^且’特別是通過把乾燥部件14的顏色作成高可見光吸 色或灰色’可以均句吸收上述的外部光或散射光 、二光區域的所有波長’能夠更可靠地發揮上述作用。 、樣’导寸別是在進行彩色顯示的有機EL面板中,可以有效 改菩該顯示面㈣比度及外觀不良。 並且’在利用吸濕性模塑體形成乾燥部件14, ==來進行所述著色的實施方式卜不論乾燥部件14的 旦;=材料’均可著色成所需要的顏色。這樣,可以在不 如知部件14的吸濕功能的情況下確保上述作用。 方4纟把4封部件13、21、31作成破璃制基板的實施 第1 ’在上述作用的基礎上,可以獲得以下作用。即, ::由於利用和支撐基板u一般使用的玻璃制 的材料形成密封部件13、 封部件13、21、。7 斤以’支撐基板11和密 4 $熱膨脹係數相同,從而可以提高面板 性二溫度變化的機械強度。第二,破璃制基板的表面平 向於金屬制等的密封部件,所以在與枯接劑Η的交界 O:\92\92316.doc -11 - 200421917 面處難以形成間隙,從^ ^ ^ ^ ^ ^ 難以從外部浸人,^可接力。因此,水分等 用金屬制密封部件:‘=τ性。第三’由於與採 密封部件13、2 3 ;通過利用玻璃制基板形成 1仵3 21 31,可以使面板薄壁化和輕量化。 下面,說明本發明的實施方式涉及的有機虹面板的製造 法。圖5是表示其概略流程的說明圖。首先,作為元件开) 成工序WA,在支撐基板u±形成疊層了第—電極、有機 層i第二電極的有機此元件12,形成在—對電極㈣著至 少含有發光層的有機層的有機EL元件12。此處,有機£匕元 件的形成採用一般使用的眾所週知的成膜工序和圖案形成 工序 ° 另一方面,作為乾燥部件安裝工序S1B,把乾燥部件Μ 安裝到密封部件13、2卜31上。在該乾燥部件安裝工序MB, 準備好預先經顏料的分散等已著色的乾燥部件14,與通常 的乾燥部件安裝工序相同地將其安裝在密封部件丨3、2 i、 31的内面(與支撐基板11相對的面)。 作為密封工序S2,通過在支撐基板11的周邊或密封部件 13、21、31的粘接面上塗覆粘接劑15,在支撐基板n上粘 合密封部件13、21、31,對有機EL元件12進行密封。然後, 根據需要經過適當的檢查工序S3,獲得實施方式的有機eL 面板 10、20、30。 根據這種實施方式的製造方法,對以往的面板製造方法 不做任何變更,按照前面所述,就可以獲得高對比度且沒 有外觀不良的有機EL面板10、20、30。 O:\92\92316.DOC -12- 200421917 面把本發明的實施方式涉及的有機EL面板及其製造 方法的特徵總結如下。 … 種有機EL面板,在支撐基板上,形成在一對電 和門夾著至 > 含有發光層的有機層的有機元件,併粘合 有使/有機EL元件與外部空氣隔絕的密封部件,其特徵在 ]在所述么封部件的與所述支撐基板相對的面上設置已 著色的乾燥部件。里从、座、止^ 丨1干 另外逖涉及一種有機EL面板的製造方 〃有在支撐基板上开》成在一對電極間夾著至少含有發 光層的有機層的有機以件的元件形成卫序,和將使該有 機元件舁外邛空氣隔絕的密封部件粘合在所述支撐基板 上的密封工序,其特徵在於,在所述密封工序之前,在所 述密封部件的與所述支撐基板相對的面上安裝已著色的乾 燥部件。 這樣,色的乾燥部件吸收入射到面板内的外部光或 來自有機EL元件的散射光,可以防止這些光被反射後從顯 不面-側射出,可以提高利用來自有機虹元件的射出光而 進行顯示的對比度,同時可以消除從支撐基板側能看到設 在面板内部的乾燥部件的外觀不良。並且,可以不影響製 造精度而獲得這種優點,所以能夠簡單地減少低對比度或 外觀不良的次品’提高產品的成品率’降低產品成本。另 外,本發明的製造方法無須對以往的製造方法做任何變 更,就可以獲得上述的具有本發明的效果的有機EL面板。 第二’在上述的有機EL面板及其製造方法中,其特徵在 於,上述乾燥部件被著色成光吸收性顏色,特別是被著色 O:\92\92316.DOC -13- 200421917 成大致黑色或大致灰色。這樣,在上述特徵的基礎上,可 以均勻地吸收上述的外部光或散射光的可見光區域的所有 波長’能夠更可靠地實施上述作用。並且,特別是在進行 彩色顯示的有機EL面板中,可以有效改善該顯示面的對比 度及外觀不良。 第二,在上述的有機EL面板及其製造方法中,其特徵在 於,所述乾燥部件是吸濕性模塑體,通過向該吸濕性模塑 體内分散顏料來進行所述著色。這樣,在上述特徵的基礎 上,不論乾燥部件的種類或材料,均可著色成所需要的顏 色,可以在不影響乾燥部件的吸濕功能的情況下獲得上述 的效果。 第四,在上述的有機EL面板及其製造方法中,其特徵在 於所述在封;件是玻璃制基板。這樣,在上述特徵的基 礎上’可以獲得相對溫度變化的機械強 好的薄壁化和輕量化的有航面板。 [實施例] 成部件相關的具體示例 [摩dp件14]作為乾燥部件14,可以使用物理乾燥劑⑺ =:、碳、碳納米管等)、後述的化學吸濕劑、把有拍 至屬絡合物溶解到石油- 溶劑等)的乾燥料單體、/„7: 有摘 塑體。 早體,也可以使用以下所示的吸濕性損 所說的吸濕性模 塑體是向樹脂成分(枯合劑)中 分散了吸O: \ 92 \ 92316.DOC 200421917 In order to prevent reflection on the inner surface of the sealing members 13, 21, 31, it is also possible to consider applying a light absorbing coating to the inner surface of the sealing member, but according to this method, outside the head: the seal is applied In the process of the inner surface of the component, the degradation factors (moisture, presence, or absence) of the organic EL element 12 are generated due to the applied coating: sealing: and the like, which leads to a problem that the life of the organic EL element 12 is reduced. If the drying member 14 is colored according to the embodiment of the present invention, the number of processes in the manufacturing process will not be affected, and no degradation factor of the organic EL element 12 will be generated in the sealed space. ^ "Especially by making the color of the drying member 14 into a high visible light absorption or gray", the above-mentioned effect can be more reliably exerted by uniformly absorbing the above-mentioned external light or scattered light and all wavelengths in the two-light region. In the organic EL panel for color display, the display can effectively change the display ratio and appearance of the display. In the embodiment where the drying member 14 is formed using a hygroscopic molded body, == the coloring can be performed regardless of the drying member 14; the material can be colored to a desired color. Thus, the above-mentioned effect can be ensured without knowing the moisture absorption function of the member 14. Fang 4 Implementation of the four sealing members 13, 21, and 31 as a glass-breaking substrate. First, based on the above-mentioned effects, the following effects can be obtained. That is, :: the sealing members 13, the sealing members 13, 21, are formed by using and using a glass material generally used for and supporting the substrate u. The 7 kg ′ support substrate 11 and the dense 4 $ have the same thermal expansion coefficient, which can improve the mechanical strength of the panel due to temperature changes. Second, the surface of the broken glass substrate is flat to a sealing member made of metal, etc., so it is difficult to form a gap at the interface O: \ 92 \ 92316.doc -11-200421917 with the dead joint Η, from ^ ^ ^ ^ ^ ^ Difficult to immerse people from the outside, ^ relay. Therefore, a metal sealing member for moisture and the like: ‘= τ property. Thirdly, since the sealing members 13, 2 and 3 are used, by forming a glass substrate 1 仵 3 21 31, the panel can be made thinner and lighter. Next, a method for manufacturing an organic rainbow panel according to an embodiment of the present invention will be described. FIG. 5 is an explanatory diagram showing a schematic flow thereof. First, as an element forming step WA, an organic element 12 in which a first electrode and an organic layer i and a second electrode are laminated is formed on a supporting substrate u ±, and an organic layer including at least a light-emitting layer is formed on an opposite electrode. Organic EL element 12. Here, the organic components are formed using a well-known film-forming step and a pattern forming step generally used. On the other hand, as the drying member mounting step S1B, the drying member M is mounted on the sealing members 13, 2 and 31. In this drying member mounting step MB, a colored drying member 14 that has been colored in advance, such as pigment dispersion, is prepared, and it is mounted on the inner surface of the sealing member 3, 2 i, 31 (and supporting Opposite surface of the substrate 11). As the sealing step S2, the organic EL element is bonded to the support substrate 11 by applying an adhesive 15 to the periphery of the support substrate 11 or the bonding surfaces of the sealing members 13, 21, and 31, and then bonding the sealing members 13, 21, and 31 to the support substrate n. 12 Seal. Then, the organic eL panels 10, 20, and 30 according to the embodiment are obtained through an appropriate inspection step S3 as necessary. According to the manufacturing method of this embodiment, the conventional panel manufacturing method is not changed, and the organic EL panels 10, 20, and 30 having high contrast and no defective appearance can be obtained as described above. O: \ 92 \ 92316.DOC -12- 200421917 The features of the organic EL panel and the manufacturing method thereof according to the embodiments of the present invention are summarized as follows. … An organic EL panel formed on a supporting substrate, an organic element sandwiched between a pair of electric and gates and an organic layer containing a light-emitting layer, and a sealing member that isolates the / organic EL element from outside air, It is characterized in that a colored drying member is provided on the face of the sealing member opposite to the support substrate. In the following, it is related to the manufacture of an organic EL panel, which is formed on a supporting substrate, and is formed by a pair of electrodes with an organic layer containing at least an organic layer containing a light-emitting layer. Wei Xu, and a sealing step of bonding a sealing member that isolates the organic element from the outer air to the support substrate, wherein, before the sealing step, the sealing member and the support are sealed. The colored dry parts are mounted on the opposite surface of the substrate. In this way, the colored drying member absorbs the external light incident into the panel or the scattered light from the organic EL element, which can prevent the light from being reflected from the display surface-side after being reflected, and can improve the use of the emitted light from the organic rainbow element. The contrast of the display can also eliminate the appearance of the dry parts that can be seen inside the panel from the support substrate side. In addition, such an advantage can be obtained without affecting the manufacturing accuracy, so it is possible to simply reduce the defective product with low contrast or poor appearance, 'improve the yield of the product,' and reduce the product cost. In addition, the manufacturing method of the present invention can obtain the above-mentioned organic EL panel having the effects of the present invention without any change to the conventional manufacturing method. Secondly, in the above-mentioned organic EL panel and its manufacturing method, the above-mentioned dry member is colored with a light-absorptive color, in particular, it is colored O: \ 92 \ 92316.DOC -13- 200421917 into a substantially black or Roughly gray. In this way, on the basis of the above-mentioned features, all the wavelengths in the visible light region of the above-mentioned external light or scattered light can be absorbed uniformly, and the above-mentioned effect can be performed more reliably. In addition, particularly in an organic EL panel that performs color display, the contrast of the display surface and the appearance defect can be effectively improved. Secondly, in the above-mentioned organic EL panel and its manufacturing method, the drying member is a hygroscopic molded body, and the coloring is performed by dispersing a pigment into the hygroscopic molded body. In this way, on the basis of the above characteristics, regardless of the type or material of the drying member, it can be colored to a desired color, and the above-mentioned effect can be obtained without affecting the moisture absorption function of the drying member. Fourth, in the above-mentioned organic EL panel and its manufacturing method, it is characterized in that the under-sealing; the element is a glass substrate. In this way, on the basis of the above characteristics, it is possible to obtain an aeronautical panel that is thinner and lighter in mechanical strength with respect to temperature changes. [Examples] Specific examples of components [Mdp parts 14] As the drying member 14, a physical desiccant (=, carbon, carbon nanotubes, etc.), a chemical hygroscopic agent described below, and The complex is dissolved in petroleum-solvent, etc.), the dry monomer, / „7: There is a plastic body. For early bodies, the hygroscopicity loss shown below can also be used. Resin is dispersed in the resin component (depleting agent)
O:\92\92316.DOC -14- 200421917O: \ 92 \ 92316.DOC -14- 200421917
濕劑的模塑體。作為哄、、H 作為及屬劑’只要是具有至少可以吸附水 分=能的物質即可,但特別優選可以通過化學方式吸附 ^1五且即使吸濕也能維持固體狀態的化合物。作為這種 勿例如可以列舉金屬氧化物、金屬的無機酸鹽和有 機酸鹽等,作拉g γ真;登太 小 仁4寸別k璉使用鹼土類金屬氧化物和硫酸鹽的 種作為鹼土類金屬氧化物,例如可以列舉氧化鈣 口 )氧化鋇(Ba0)、氧化鎂(MgO)等。作為硫酸鹽,例如 可以列舉硫酸鋰(Li2S〇4)、硫酸鈉(N^SCU)、硫酸鈣 (CaS〇4)、硫酸鎂(MgS〇4)、硫酸鈷(C〇S04)、硫酸鎵 :Ga2(S04)3)、琉酸欽(Ti(s〇4)2)、石荒酸錄(Nis〇^等。其它也 可X使用具有吸濕性的有機材料作為吸濕劑。 =方面,作為樹脂成分(粘合劑),只要不妨礙吸濕劑的 … 、作用,就不做特別限定,優選使用透氣性高的材 料(即屏蔽性低的材料,特別是透氣性樹脂)。作為這種材 ;】女可以列舉聚烯烴類、聚丙烯酸類、聚丙烯廬^類、 :齡類、聚s旨類、環氧類、聚碳酸g旨類等高分子材料。 其中,在本發明中優選聚烯烴類。具體而言,可以列舉聚 乙烯、聚丙烯、聚丁二烯、聚異戊間二烯等,卩及牠們的 共聚物等。 吸濕剑和樹脂成分的含有量根據牠們的種類等可以適當 〇 士 、吊把及濕劑和樹脂成分的合計含量設為1 〇 〇重量 ,吸濕劑約30重量%〜85重量%,樹脂成分約70重量 %〜15重量叱π 里/〇即可。優選吸濕劑約40重量%〜8〇重 樹脂成分約6 〇 *曰η/ ^㈧重〜20重量%,最優選吸濕劑約5〇重量Moisturizer molding. As the co-agent, H as the accessory agent, it is sufficient that it has at least a substance capable of adsorbing water = energy, but it is particularly preferably a compound that can adsorb chemically and maintain a solid state even if it absorbs moisture. Examples of such examples include metal oxides, inorganic and organic acid salts of metals, etc., as g γ; Deng Tai Xiaoren 4 inch Bek 琏 uses alkaline earth metal oxides and sulfates as alkaline earth Examples of the metalloid oxide include calcium oxide, barium oxide (Ba0), and magnesium oxide (MgO). Examples of the sulfate include lithium sulfate (Li2S04), sodium sulfate (N ^ SCU), calcium sulfate (CaS04), magnesium sulfate (MgS04), cobalt sulfate (C04), and gallium sulfate: Ga2 (S04) 3), Sulfuric acid (Ti (s〇4) 2), Ishihara acid record (Nis〇 ^, etc.) Others can also use organic materials with hygroscopicity as hygroscopic agent. = Aspect, The resin component (binder) is not particularly limited as long as it does not interfere with the function of the hygroscopic agent, and it is preferable to use a material having high air permeability (i.e., a material with low barrier properties, especially a gas permeable resin). Seed material;] females may include polymer materials such as polyolefins, polyacrylics, polypropylenes, ages, polystyrenes, epoxys, polycarbonates, etc. Among them, in the present invention Polyolefins are preferred. Specific examples include polyethylene, polypropylene, polybutadiene, polyisoprene, and the like, and copolymers thereof. The content of the moisture absorption sword and the resin component depends on their The type and the like can be appropriately set to 100, the total content of the moisturizer, the aerosol, and the resin component to be 1,000 weight, and the hygroscopic agent is about 30 It is sufficient that the resin content is about 70% by weight to 15% by weight 叱 π 叱 / 〇. It is preferable that the moisture absorbent is about 40% by weight to 80% by weight of the resin component is about 60%. % By weight, most preferably about 50% by weight
O:\92\92316.DOC -15- 200421917 7〇重1 %,樹脂成分約50重量%〜3〇重量%。 +吸濕性模塑體可以通過均勻混合所述各成分,模塑成所 需形狀而得到。該情況時,優選吸濕劑、氣體吸附劑等預 先充分乾燥後再混合。另外,在與樹脂成分混合時,可以 根據需要加熱形成熔融狀態。 7為本發明的實施例,吸濕性模塑體優選是把由吸濕劑 矛树知成分構成的混合物進行模塑而得到的物質。即,使 G έ /容劑專第二成分的材料製造吸濕性模塑體,由此 可以避免因這些第三成分殘存在模塑體中而帶來的弊端 (例如,所殘存的溶劑被吸濕劑吸附,降低吸附劑的性能, 或由於所殘存的溶劑在密封部件内隨時間而揮發所造 弊端)。 土在向㈣部件13、21、31上進行安裝時,只要是能夠可 罪地固疋在密封部件内的方法就不做特別限定,例如,可 2列舉利用公知的粘合劑、粘接劑(優選無溶劑型粘接劑) 等钻合吸濕性模塑體和㈣部件的方法,把吸濕性模塑體 熱熔覆在㈣部件上的方法,湘螺㈣目定部件把模塑 體固定在密封部件上的方法等。 、 雖然用於著色而分散的顏料與無機類及有機類的類屬無 關’但適宜選擇不會排出使有機EL元件劣化的因素的材料。 [密封部件]㈣部件13、2卜31優選用玻璃(納玻璃或非 鹼1玻螭)制基板來形成。所述的密封凹部2 1A、3 1A,例如 通過貫施加壓成形、蝕刻、噴砂處理等加工而形成。 [粘接劑]粘接劑丨5使用熱固化型、化學固化型(二液混O: \ 92 \ 92316.DOC -15- 200421917 70% 1% by weight, the resin content is about 50% to 30% by weight. + A hygroscopic molded body can be obtained by uniformly mixing the respective components and molding into a desired shape. In this case, it is preferable to mix the hygroscopic agent, the gas adsorbent, and the like sufficiently in advance. In addition, when mixed with a resin component, it may be heated to form a molten state as necessary. 7 is an example of the present invention, and the hygroscopic molded body is preferably a material obtained by molding a mixture of hygroscopic agents, known ingredients. That is, the second component of G / capsule is used to produce a hygroscopic molded body, thereby avoiding the disadvantages caused by these third components remaining in the molded body (for example, the remaining solvent is Absorption of hygroscopic agent, degrading the performance of the adsorbent, or the disadvantage caused by the residual solvent volatilizing in the sealing member over time). When the soil is mounted on the concrete members 13, 21, and 31, the method is not particularly limited as long as it can be guilty of being fixed in the seal member. For example, a publicly known adhesive or adhesive can be used (Preferred solvent-free adhesive) A method of drilling a hygroscopic molded body and a concrete member, a method of thermally cladding a hygroscopic molded body on a concrete member, A method of fixing the body to the sealing member, and the like. Although the pigment used for coloring and dispersing has nothing to do with the category of inorganic and organic materials, it is appropriate to select a material that does not emit factors that degrade organic EL elements. [Seal member] The cymbals 13 and 31 are preferably formed of a substrate made of glass (sodium glass or non-alkali glass). The sealing recesses 21A and 31A are formed by, for example, continuous application of press forming, etching, and sandblasting. [Adhesive] Adhesive 丨 5 uses heat curing type, chemical curing type (two-liquid mixed
O:\92\92316.DOC -16- 200421917 合)、光(紫外線)固化型等粘接劑,其材料可以使用丙烯酸 樹脂、環氧樹脂、聚酯、聚烯烴等。特別優選使用紫外線 固化型環氧樹脂。向這種粘接劑中,混合適量(約0.丨重量% 〜0.5重量%)的粒徑為1〜100 # m的隔離物(優選玻璃或塑 料隔離物),使然後用配合器等進行塗覆。 [有機EL元件]形成在支撐基板丨丨上,在一對電極間夾著 至少含有發光層的有機層的有機EL元件12的具體結搆和材 料的示例如下所述。 (a) 支撐基板: 作為支撐基板11,優選為具有透明性的平板狀或薄片 狀,其材質可以使用玻璃或塑料等。 (b) 電極 以從支撐基板11側射出光的方式(底面射出方式)為前提 的情況下,把支撐基板11側的電極設為由透明電極構成的 陽極,把另一方電極設為由金屬電極構成的陰極。作為可 以適用的陽極材料,可以使用IT〇、Zn〇等,通過蒸鍍、濺 射等成膜方法形成。作為陰極,使用功函數小的金屬、金 屬氧化物、金屬氟化物、合金等,具體講可以使用O: \ 92 \ 92316.DOC -16- 200421917), light (ultraviolet) curing type adhesives, the material can be acrylic resin, epoxy resin, polyester, polyolefin, etc. It is particularly preferable to use an ultraviolet curable epoxy resin. To this adhesive, an appropriate amount (approximately 0.1 to 0.5% by weight) of a spacer (preferably glass or plastic spacer) having a particle size of 1 to 100 # m is mixed, and then it is performed with a dispenser or the like Coated. [Organic EL element] An example of a specific structure and material of the organic EL element 12 formed on a support substrate with an organic layer including at least a light-emitting layer between a pair of electrodes is described below. (a) Support substrate: The support substrate 11 is preferably a flat plate or sheet having transparency, and the material can be glass, plastic, or the like. (b) When it is assumed that the electrode emits light from the support substrate 11 side (bottom surface emission method), the electrode on the support substrate 11 side is an anode made of a transparent electrode, and the other electrode is a metal electrode. Composition of the cathode. As an applicable anode material, it can be formed by a film-forming method such as IT0, ZnO, or the like. As the cathode, a metal, metal oxide, metal fluoride, alloy, or the like having a small work function is used, and specifically, it can be used
Mg%的單層結構、LiOVAl等的疊層結構,通過蒸鍍、濺 等成膜方法來形成。 、 (0有機層 有機層在以支撐基板11側的電極為陽極、以另一方♦ 為陰極的情況下’―般是空穴輸送層/發光層/電子輸送2 金層結構,也可以設置各自不只—層的多層疊層的發光The Mg% single-layer structure and the stacked structure such as LiOVAl are formed by a film formation method such as evaporation or sputtering. (0) Organic layer: The organic layer uses the electrode on the support substrate 11 side as the anode and the other side as the cathode. It is generally a hole transport layer / light-emitting layer / electron transport 2 gold layer structure. More than just-light emitting from multiple layers
O:\92\92316.DOC -17- 200421917 層、空穴輸送層、電子輸送層,還可以省略空穴輸送層和 電子輸送層任何一層,也可以兩層均省略只剩下發光層。 作為有機層,可以根據用途插入空穴注入層、電子注入層、 空穴屏蔽層、電子屏蔽層等的有機功能層。 有機層的材料可以根據有機EL元件12的用途適當選擇。 以下列舉出示例,但不限於此。 作為空穴輸送層,只要具有高空穴遷移率的功能即可, 其材料可以選擇使用以往公知的化合物中的任意物質。作 為具體示例,可以使用銅酞菁藍等血卟啉化合物、4,4,—雙 [N— (1 —炎基)一N—苯氨基]—聯苯(NPB)等芳香族叔胺、4 一(二對甲苯氨基)一4’一 [4 一(二對甲苯氨基)苯乙烯基]二 苯乙烯等二苯乙烯化合物、三唑衍生物或苯乙烯基胺化合 物等有機材料。另外,也可以使用聚碳酸酯等高分子中分 散有低分子的空穴輸送用有機材料的高分子分散類材料。 毛光層可以使用公知的發光材料,作為具體示例,可以 使用4,4’ 一雙(2,2,一聯苯基乙烯基卜聯苯(DpvBi)等 芳香族二次甲基化合物、1,4一雙(2 —甲基苯乙烯基)苯等 苯乙烯苯化合物、3—(4—聯笨基)一 4一苯基_5 一叔丁苯基 1,2,4 —二唑(TAZ)等三唑衍生物、蒽醌衍生物、芴酮 衍生物等的熒光性有機材料、(8 一羥基喹啉)鋁絡合物(Aiq3) 等熒光性有機金屬化合物、聚對苯乙炔(ppv)類、聚芴類、 聚乙烯咔唑(PVK)類等的高分子材料、白金絡合物或銥絡合 物等三重激子中可以利用熒光發光的有機材料(特表2〇〇1 — 520450)。發光材料可以是僅用上述的發光材料構成的物 O:\92\92316.DOC -18 - 200421917 貝,也可以含有空穴輸送材料、電子輸送材料、添加劑(供 體、受體等)或發光性摻雜物等。另外,這些物質也可以分 散到高分子材料或無機材料中。 电子輸送層只要具有把陰極注入的電子傳遞到發光層的 力月b即可,其材料可以選擇使用以往公知的化合物中的任 思物質。作為具體示例,可以使用硝,基取代㈣_衍生物、 i金雞納甲㈣生物等的有機材料、卜㈣㈣衍生物的 金屬絡合物、金屬i太菁藍等。 上述的空穴輸送層、發光層、電子輸送層可以用旋轉塗 覆法、次潰法等塗覆法、喷射法、絲網印刷&等濕式工藝、 或蒸鍍法、激光轉印法等干式工藝形成。 w [有機EL面板的各種方式]有機EL元件12可以是單一結 構的有機EL元件,也可以是具有所需的圖案結構,構成多 個像素的元件。 、=果是後者的情況’其顯示方式可以是單色發光,也可 以是2色或2色以上的多色發光’特別是為了實現多色發光 的有機EL面板,可以用以下方式來構成,形成包含用於形 成對應RGB的3種發光功能層的方式的2色或2色以上的發 光功能層的方式(分塗方式)、白色或藍色等單色發光功能層 組合渡色器或由焚光材料形成的色變換層的方式⑽方 式CCM方式)、通過向單色發光功能層的發光區域照射電 磁波等實現多色發光的方式(光致褪色方式)等。另外,有機 此元件的驅動方式可以是無源驅動方式或有源驅動方式中 的任^種。O: \ 92 \ 92316.DOC -17- 200421917 layer, hole transporting layer, electron transporting layer, either the hole transporting layer or the electron transporting layer can be omitted, or both layers can be omitted to leave only the light emitting layer. As the organic layer, an organic functional layer such as a hole injection layer, an electron injection layer, a hole shielding layer, and an electron shielding layer can be inserted depending on the application. The material of the organic layer can be appropriately selected according to the application of the organic EL element 12. Examples are given below, but are not limited thereto. The hole transporting layer may be any material as long as it has a function of high hole mobility, and any of the materials may be selected from conventionally known compounds. As a specific example, a hematoporphyrin compound such as copper phthalocyanine blue, 4,4, -bis [N— (1—inflammatory group) -N-phenylamino] -biphenyl (NPB), such as aromatic tertiary amines, 4 Organic materials such as stilbene compounds such as mono (di-p-toluylamino) -4 '-[4 ((p-toluylamino) styryl] stilbene), triazole derivatives, or styrylamine compounds. Alternatively, a polymer-dispersed material in which a low-molecular organic material for hole transport is dispersed in a polymer such as polycarbonate may be used. A known light-emitting material can be used as the matte layer. As a specific example, an aromatic secondary methyl compound such as 4,4′-bis (2,2, -biphenylvinylbiphenyl (DpvBi)), 1, 4-bis (2-methylstyryl) benzene and other styrene-benzene compounds, 3- (4-bibenzyl) -4-phenyl-5, and tert-butylphenyl1,2,4-diazole (TAZ ), And other fluorescent organic materials such as triazole derivatives, anthraquinone derivatives, and fluorenone derivatives; (8-hydroxyquinoline) aluminum complexes (Aiq3); and other fluorescent organic metal compounds, poly-p-phenylacetylene (ppv ), Polyfluorene-based, polyvinyl carbazole (PVK) -based polymer materials, organic materials such as platinum complexes or iridium complexes that can utilize fluorescent light emission (Special Table 2001 — 520450). The light-emitting material may be an object consisting of only the above-mentioned light-emitting materials O: \ 92 \ 92316.DOC -18-200421917, and may also contain hole-transporting materials, electron-transporting materials, additives (donors, acceptors, etc. ) Or luminescent dopants, etc. In addition, these substances may be dispersed in a polymer material or an inorganic material. The sub-transport layer only needs to have a force b that transfers electrons injected from the cathode to the light-emitting layer, and the material can be selected from any conventionally known compounds. As a specific example, a nitrate group can be used instead of a fluorene derivative. , I.e., organic materials such as cinchona bio, biological complexes of metal derivatives, metal i-cyanine blue, etc. The above hole transporting layer, light emitting layer, and electron transporting layer can be spin-coated, It is formed by a wet process such as coating method, spray method, screen printing & etc., or a dry process such as vapor deposition method, laser transfer method, etc. [Various methods of organic EL panel] The organic EL element 12 may be The organic EL element with a single structure may also be an element having a desired pattern structure and constituting a plurality of pixels. If the latter is the case, the display mode may be monochromatic light emission, or two or more colors. The multi-color light-emitting organic EL panel, in particular, for achieving multi-color light emission, can be configured in the following manner to form two-color or more light-emitting devices including a method for forming three types of light-emitting functional layers corresponding to RGB. Optical function layer method (split coating method), white or blue monochromatic light-emitting function layer combined with color device or color conversion layer formed by fluorescent material (CCM method), through to monochromatic light-emitting functional layer The light-emitting area is irradiated with electromagnetic waves, etc. to achieve multi-color light emission (photofading method). In addition, the driving method of the organic device may be any of a passive driving method and an active driving method.
O:\92\92316.DOC -19- ι / 圖式簡單說明】 圖1是現有技術的說明圖。 圖2疋說明本發明的一實施方式 网 々有機EL面板的說明圖。 圖3是說明本發明的其它實施方κ 圖 K的有機EL面板的說明 〇 圖4疋表不本發明的其它實施方式的有機面板的說明 圖。 圖5是表示本發明的實施方式的有機el面板的製造方法 的概略流程的說明圖。 【圖式代表符號說明】 !〇、20、30 有機EL面板 11 支撐基板 12 13 、 21 、 31 14 15 有機EL元件 密封部件 乾燥部件 米占接劑O: \ 92 \ 92316.DOC -19- ι / Brief Description of Drawings] Fig. 1 is an explanatory drawing of the prior art. Fig. 2 is an explanatory diagram illustrating a network organic EL panel according to an embodiment of the present invention. Fig. 3 is a diagram illustrating an organic EL panel according to another embodiment of the present invention. Fig. K is an explanatory diagram illustrating an organic panel according to another embodiment of the present invention. Fig. 5 is an explanatory diagram showing a schematic flow of a method for manufacturing an organic el panel according to the embodiment of the present invention. [Illustration of Symbols in the Drawings]! 〇, 20, 30 Organic EL panel 11 Supporting substrate 12 13, 21, 31 14 15 Organic EL element Sealing part Drying part Metering agent
15A 16、21 間隔團3 1、41、5 1 密封部件15A 16, 21 Spacer 3 1, 41, 5 1 Sealing part
21A、31A21A, 31A
31B 密封凹部 安裝凹部 O:\92\92316.DOC -20 -31B Seal recess O: \ 92 \ 92316.DOC -20-
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| KR101222968B1 (en) * | 2006-04-25 | 2013-01-17 | 엘지디스플레이 주식회사 | Organic el display device and method for fabricating the same |
| KR102370715B1 (en) * | 2014-12-29 | 2022-03-07 | 엘지디스플레이 주식회사 | Organic Light Emitting Diode Display Having Quantum Dot |
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| CN107170906B (en) * | 2017-07-19 | 2020-03-24 | 京东方科技集团股份有限公司 | A frame sealing glue structure, a display panel and a display device |
| US11411198B2 (en) * | 2019-06-18 | 2022-08-09 | Innolux Corporation | Electronic device |
| CN110429206B (en) * | 2019-08-07 | 2021-11-23 | 京东方科技集团股份有限公司 | Packaging cover plate, display device, display panel and packaging method of display panel |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6196695A (en) * | 1984-10-18 | 1986-05-15 | 松下電器産業株式会社 | EL panel |
| JPS63105495A (en) * | 1986-10-22 | 1988-05-10 | アルプス電気株式会社 | Thin film el panel |
| JPH02197071A (en) * | 1989-01-26 | 1990-08-03 | Sharp Corp | Thin film el panel |
| JPH04267096A (en) * | 1991-02-21 | 1992-09-22 | Sharp Corp | Thin film electroluminescence panel |
| CN1385053A (en) * | 1999-09-03 | 2002-12-11 | 优尼爱克斯公司 | Encapsulation of organic electronic devices |
| DE19959957A1 (en) * | 1999-12-13 | 2001-06-21 | Sued Chemie Ag | Platelet-shaped compacts |
| JP3409764B2 (en) * | 1999-12-28 | 2003-05-26 | 日本電気株式会社 | Manufacturing method of organic EL display panel |
| JP2003017242A (en) * | 2001-07-03 | 2003-01-17 | Saes Getters Japan Co Ltd | Organic electroluminescence device |
-
2003
- 2003-04-08 JP JP2003104242A patent/JP2004311246A/en active Pending
-
2004
- 2004-03-30 TW TW093108695A patent/TWI249366B/en not_active IP Right Cessation
- 2004-04-02 CN CNB2004100306615A patent/CN100438120C/en not_active Expired - Lifetime
- 2004-04-08 KR KR1020040023955A patent/KR20040087937A/en not_active Ceased
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI575485B (en) * | 2011-01-04 | 2017-03-21 | 三星顯示器有限公司 | Flat panel display device and organic light emitting display device |
Also Published As
| Publication number | Publication date |
|---|---|
| TWI249366B (en) | 2006-02-11 |
| JP2004311246A (en) | 2004-11-04 |
| CN100438120C (en) | 2008-11-26 |
| KR20040087937A (en) | 2004-10-15 |
| CN1536939A (en) | 2004-10-13 |
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| MM4A | Annulment or lapse of patent due to non-payment of fees |