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TR201908177T4 - Bir co(ıı) veya ce(ııı) katalizörü, bir bromür tuzu ve bir solvent varlığında 5-(alkiloksimetil)furfuralin (AMF) oksijen ile oksidasyonu aracılığıyla 2,5-furandikarboksilik asidin (FDCA) hazırlanışına yönelik proses. - Google Patents

Bir co(ıı) veya ce(ııı) katalizörü, bir bromür tuzu ve bir solvent varlığında 5-(alkiloksimetil)furfuralin (AMF) oksijen ile oksidasyonu aracılığıyla 2,5-furandikarboksilik asidin (FDCA) hazırlanışına yönelik proses. Download PDF

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Publication number
TR201908177T4
TR201908177T4 TR2019/08177T TR201908177T TR201908177T4 TR 201908177 T4 TR201908177 T4 TR 201908177T4 TR 2019/08177 T TR2019/08177 T TR 2019/08177T TR 201908177 T TR201908177 T TR 201908177T TR 201908177 T4 TR201908177 T4 TR 201908177T4
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TR
Turkey
Prior art keywords
fdca
amf
furfural
solvent
alkyloxymethyl
Prior art date
Application number
TR2019/08177T
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English (en)
Inventor
Sanborn Alexandra
Original Assignee
Archer Daniels Midland Co
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Publication date
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Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of TR201908177T4 publication Critical patent/TR201908177T4/tr

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)

Abstract

Bir Co(II) veya Ce(III) katalizörü, bir bromür tuzu ve bir solvent varlığında oksijen ile 5-(hidroksimetil)furfural (HMF) veya 5-(alkiloksimetil)furfuralın (AMF) oksidasyonu aracılığıyla 2,5-furandikarboksilik asit (FDCA) hazırlanışına yönelik bir prosestir. AMF, akabinde FDCA'ya hidrolizlenen ara ürün bileşiği 5-(alkoksikarbonil)furankarboksilik aside (AcMFA) oksitlenir. Proses tercihen T=80-130°C ve 800-1000 psi?de gerçekleştirilir. Asetik asit tercih edilen solventtir.
TR2019/08177T 2009-05-14 2010-05-14 Bir co(ıı) veya ce(ııı) katalizörü, bir bromür tuzu ve bir solvent varlığında 5-(alkiloksimetil)furfuralin (AMF) oksijen ile oksidasyonu aracılığıyla 2,5-furandikarboksilik asidin (FDCA) hazırlanışına yönelik proses. TR201908177T4 (tr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US17830109P 2009-05-14 2009-05-14

Publications (1)

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TR201908177T4 true TR201908177T4 (tr) 2019-06-21

Family

ID=43085592

Family Applications (1)

Application Number Title Priority Date Filing Date
TR2019/08177T TR201908177T4 (tr) 2009-05-14 2010-05-14 Bir co(ıı) veya ce(ııı) katalizörü, bir bromür tuzu ve bir solvent varlığında 5-(alkiloksimetil)furfuralin (AMF) oksijen ile oksidasyonu aracılığıyla 2,5-furandikarboksilik asidin (FDCA) hazırlanışına yönelik proses.

Country Status (8)

Country Link
US (1) US8558018B2 (tr)
EP (5) EP3257845A1 (tr)
CN (2) CN104744414B (tr)
BR (2) BRPI1007729A2 (tr)
ES (2) ES2730100T3 (tr)
PL (1) PL2430010T3 (tr)
TR (1) TR201908177T4 (tr)
WO (1) WO2010132740A2 (tr)

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