SU97161A1 - The method of obtaining yellow stains from indigo and orange stains from tetrabromindigo - Google Patents

The method of obtaining yellow stains from indigo and orange stains from tetrabromindigo

Info

Publication number: SU97161A1
Authority: SU; USSR - Soviet Union
Prior art keywords: stains; indigo; tetrabromindigo; orange; obtaining yellow
Prior art date: 1952-04-10

Application number

SU448846A

Other languages

Russian (ru)

Inventor

А.И. Батьков

И.Б. Мигачева

Н.Е. Федорова

Original Assignee

А.И. Батьков

И.Б. Мигачева

Н.Е. Федорова

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1952-04-10

Filing date

1952-04-10

Publication date

1953-11-30

1952-04-10 Application filed by А.И. Батьков, И.Б. Мигачева, Н.Е. Федорова filed Critical А.И. Батьков

1952-04-10 Priority to SU448846A priority Critical patent/SU97161A1/en

1953-11-30 Application granted granted Critical

1953-11-30 Publication of SU97161A1 publication Critical patent/SU97161A1/en

Links

COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 title description 8
235000000177 Indigofera tinctoria Nutrition 0.000 title description 6
229940097275 indigo Drugs 0.000 title description 6
238000000034 method Methods 0.000 title description 4
QLRKASHXFNIPLZ-UHFFFAOYSA-M benzyl-dimethyl-phenylazanium;chloride Chemical compound [Cl-].C=1C=CC=CC=1[N+](C)(C)CC1=CC=CC=C1 QLRKASHXFNIPLZ-UHFFFAOYSA-M 0.000 description 5
239000000975 dye Substances 0.000 description 5
239000001043 yellow dye Substances 0.000 description 4
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
229920001353 Dextrin Polymers 0.000 description 2
239000004375 Dextrin Substances 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
235000019425 dextrin Nutrition 0.000 description 2
239000002270 dispersing agent Substances 0.000 description 2
239000004744 fabric Substances 0.000 description 2
AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 2
230000003472 neutralizing effect Effects 0.000 description 2
239000001048 orange dye Substances 0.000 description 2
239000003973 paint Substances 0.000 description 2
159000000000 sodium salts Chemical class 0.000 description 2
238000010025 steaming Methods 0.000 description 2
239000002562 thickening agent Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
239000003086 colorant Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 1
235000019441 ethanol Nutrition 0.000 description 1
239000000835 fiber Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
230000002028 premature Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000000344 soap Substances 0.000 description 1
235000011121 sodium hydroxide Nutrition 0.000 description 1
239000002904 solvent Chemical class 0.000 description 1
238000003756 stirring Methods 0.000 description 1
WGPCGCOKHWGKJJ-UHFFFAOYSA-N sulfanylidenezinc Chemical compound [Zn]=S WGPCGCOKHWGKJJ-UHFFFAOYSA-N 0.000 description 1
WQSRXNAKUYIVET-UHFFFAOYSA-N sulfuric acid;zinc Chemical compound [Zn].OS(O)(=O)=O WQSRXNAKUYIVET-UHFFFAOYSA-N 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000011282 treatment Methods 0.000 description 1
210000004291 uterus Anatomy 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
229960001763 zinc sulfate Drugs 0.000 description 1
229910000368 zinc sulfate Inorganic materials 0.000 description 1

Landscapes

Inks, Pencil-Leads, Or Crayons (AREA)
Coloring (AREA)

Description

Известно образование желтого красител на ткани при печати лейкотропом О в смеси с ренгалитом и окисью цинка по ткан м, окрашенным индигоидными красител ми. Однако при смешении в печатной краске ронгалита, красител и лейкотропа О возможно преждевременное образование осадка соединени лейкотропа О и красител .The formation of a yellow dye on fabric is known when printing with leukotrope O mixed with renhalite and zinc oxide on fabrics dyed with indigoid dyes. However, when mixed in the printing ink of rongalite, dye, and leukotrope O, premature formation of a precipitate of a compound of leukotrope O and dye is possible.

Предлагаемый способ получени желтых окрасок из индиго и оранжевых окрасок из тетраброминдиго, образующихс на волокне при запаривании , свободен от этого недостатка и отличаетс от известных способов тем, что печатную краску готов т из лейкокислоты красител , получаемой нейтрализацией натриевой соли лейкосоединени сернистым цинком, и лейкотропа О. При этом дл получени более тонкой суспензии в краску добавл ют диспергаторы (триэтаноламин, солюционна соль).,The proposed method of obtaining yellow dyes from indigo and orange dyes from tetrabromindigo, formed on the fiber during steaming, is free from this drawback and differs from the known methods in that the printing ink is prepared from the leucoacid dye obtained by neutralizing the sodium salt of the leuco-compound with zinc sulfur, and leucotrope At the same time, to obtain a thinner suspension, dispersants (triethanolamine, solvent salt) are added to the paint,

ПримерыExamples

Получение желтого красител Getting yellow dye

Матка из индиго500 гIndigo uterus 500 g

Триэтаноламин40 Triethanolamine40

Загустка декстринова ....50 Добавить при размешивании:Dextrin thickener .... 50 Add when stirring:

Сернокислого цинка 50%-ного .200 50% zinc sulfate .200

Ронгалита 52%-ного110 52% Rongalitis 110

Лейкотропа О100 Leukotrope O100

1000 г1000 g

Получение матки дл индигоGetting a womb for indigo

Индиго 100%-ногоIndigo 100%

Спирта этилового Ethyl alcohol

ГлицеринаGlycerol

Едкого натра 24, 4%-ного . Caustic soda 24, 4%.

Гидросульфита 85%-ного . Hydrosulfite 85%.

Загустки декстриновой Dextrin Thickeners

Восстанавливают при 40° и выдерживают в течение 24 час.Restore at 40 ° and incubated for 24 hours.

Оранжева краска получаетс при работе с тетраброминдиго.Orange paint is obtained when working with tetrabromindigo.

Проводка после печати: зрельник восстановительный при 104°в течение 3-5 мин., промывка в холодной воде, затем гор чей воде и мыле.Post-printing wiring: zelelnik recovery at 104 ° for 3-5 minutes, rinse in cold water, then hot water and soap.

Прочность получаемых окрасок к мокрым обработкам соответствует таковой дл синего индиго.The strength of the obtained colors for wet treatments corresponds to that of indigo blue.

Предмет изобретени Subject invention

Способ получени желтых окрасок из индиго и оранжевых окрасок из тетраброминдиго при запаривании, отличающийс тем, что печатную краску готов т из лейкокислоты красител , получаемой нейтрализацией натриевой соли лейкосоединени сернистым цинком, и лейкотропа О в присутствии диспергаторов.The method of obtaining yellow dyes from indigo and orange dyes from tetrabromindigo during steaming, characterized in that the printing ink is prepared from a leucoacid dye obtained by neutralizing the sodium salt of a leucosilane with zinc sulphuric acid and leukotrope O in the presence of dispersants.

500 г500 g

SU448846A 1952-04-10 1952-04-10 The method of obtaining yellow stains from indigo and orange stains from tetrabromindigo SU97161A1 (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
SU448846A SU97161A1 (en)	1952-04-10	1952-04-10	The method of obtaining yellow stains from indigo and orange stains from tetrabromindigo

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
SU448846A SU97161A1 (en)	1952-04-10	1952-04-10	The method of obtaining yellow stains from indigo and orange stains from tetrabromindigo

Publications (1)

Publication Number	Publication Date
SU97161A1 true SU97161A1 (en)	1953-11-30

Family

ID=48371831

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SU448846A SU97161A1 (en)	1952-04-10	1952-04-10	The method of obtaining yellow stains from indigo and orange stains from tetrabromindigo

Country Status (1)

Country	Link
SU (1)	SU97161A1 (en)

1952
- 1952-04-10 SU SU448846A patent/SU97161A1/en active

Publication	Publication Date	Title
GB428767A (en)	1935-05-13	Improvements in the dyeing of cellulose acetate artificial silk
SU97161A1 (en)	1953-11-30	The method of obtaining yellow stains from indigo and orange stains from tetrabromindigo
US2029351A (en)	1936-02-04	Dyeing process
US2298147A (en)	1942-10-06	Textile printing process
US2450773A (en)	1948-10-05	Dyeing of wool with indigo dyestuffs
US1106970A (en)	1914-08-11	Compounds of leuco vat dyes with aralkyl compounds and process of making same.
US2182140A (en)	1939-12-05	Process for producing reserves under dyeings of ester salts of leuco vat dyestuffs
US1951571A (en)	1934-03-20	Process of preparing dyeings and printings
DE870083C (en)	1953-03-09	Process for the production of prints on polyamide fibers with Kuepen dyes
US2548545A (en)	1951-04-10	Pyranthrone dye composition comprising an inorganic nitrite and process for dyeing
US2052716A (en)	1936-09-01	Compounds of basic dyestuffs with sulphuric acid ester salts
US1903175A (en)	1933-03-28	Dyeing animal fibers
DE1469722C3 (en)	1975-06-12	Process for printing textile materials made of native or regenerated cellulose with reactive dyes
SU15646A1 (en)	1930-06-30	Dyeing Acetate Silk
DE658364C (en)	1938-03-30	Process for the production of metal-containing azo dyes
GB145240A (en)	1920-07-02	Improvements in printing cotton fabrics and yarns
AT103622B (en)	1926-06-25	Procedure for reserving Prudhommes aniline black with vat dyes.
AT227349B (en)	1963-05-10	Process for the production of new dyes
DE562623C (en)	1932-10-27	Process for the production of prints and tints with insoluble azo dyes
DE1088460B (en)	1960-09-08	Process for dyeing or printing cellulosic textile fabrics
DE621758C (en)	1935-11-13	Process for the production of azo dyes on wool
US2085145A (en)	1937-06-29	Vat dye compositions
GB622676A (en)	1949-05-05	Improvements in or relating to the colouration of yarn or fabrics composed wholly orpartly of secondary or acetone-soluble cellulose acetate
SU4342A1 (en)	1924-09-15	The method of fixing the basic dyes in printing on cotton fabrics
SU106005A1 (en)	1956-11-30	Method for producing acid anthraquinone dyes