SU692536A3 - Fungicidal composition - Google Patents
Fungicidal compositionInfo
- Publication number
- SU692536A3 SU692536A3 SU711691054A SU1691054A SU692536A3 SU 692536 A3 SU692536 A3 SU 692536A3 SU 711691054 A SU711691054 A SU 711691054A SU 1691054 A SU1691054 A SU 1691054A SU 692536 A3 SU692536 A3 SU 692536A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- fungicidal composition
- composition
- fungicidal
- fungus
- experiment
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title description 8
- 230000000855 fungicidal effect Effects 0.000 title description 5
- 241000233866 Fungi Species 0.000 description 5
- 150000001469 hydantoins Chemical class 0.000 description 5
- 229940053195 antiepileptics hydantoin derivative Drugs 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000013543 active substance Substances 0.000 description 2
- JFMOAIVHTYQOKA-UHFFFAOYSA-N 3-(3,5-dichlorophenyl)-1-methylimidazolidine-2,4-dione Chemical compound O=C1N(C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 JFMOAIVHTYQOKA-UHFFFAOYSA-N 0.000 description 1
- 241000223600 Alternaria Species 0.000 description 1
- 241000123650 Botrytis cinerea Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 229940091173 hydantoin Drugs 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003090 pesticide formulation Substances 0.000 description 1
- 239000004476 plant protection product Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/86—Oxygen and sulfur atoms, e.g. thiohydantoin
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/72—Two oxygen atoms, e.g. hydantoin
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/72—Two oxygen atoms, e.g. hydantoin
- C07D233/74—Two oxygen atoms, e.g. hydantoin with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to other ring members
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/72—Two oxygen atoms, e.g. hydantoin
- C07D233/80—Two oxygen atoms, e.g. hydantoin with hetero atoms or acyl radicals directly attached to ring nitrogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
Description
(54) ФУНГИЦИДНАЯ КОМПОЗИЦИЯ(54) FUNGICIDE COMPOSITION
1one
Изобретение относитс к химическим средствам защиты растений, конкретно к фунгицидной композиции на основе производных гидантоина.This invention relates to chemical plant protection products, specifically to a fungicidal composition based on hydantoin derivatives.
Известно использование производных гидантоина , например 3-(3,5-дихлорфеиил)-1-метилимидазолидин-2 ,4-диона 1, а также 3-(3,5-дихлорфеиил ) - 1-ацетш1имидазопидин-2,4-диона 2 в качестве активнодействующих веществ в фунгицидных композици х. Однако известные композиции про вл ют недостаточную актиЛюсть при низких дозах расхода.The use of hydantoin derivatives is known, for example, 3- (3,5-dichlorophenyl) -1-methylimidazolidin-2, 4-dione 1, and 3- (3,5-dichlorfeiyl) -1-acetylimidazopidin-2,4-dione 2 in as active substances in fungicidal compositions. However, known compositions exhibit insufficient activity at low dosage rates.
Целью изобретени вл етс изыскание новых композиций на основе производных гидантоина , обладающих усиленной биологической активностью.The aim of the invention is to find new compositions based on hydantoin derivatives with enhanced biological activity.
Указанна цель достигаетс использованием композиции, содержащей как активное вещество производные гидантоина общей формулы IThis goal is achieved using a composition containing as active substance hydantoin derivatives of general formula I
dO-Ei i. ,dO-Ei i. ,
С1C1
NN
(ir(ir
в которой RJ обозначает NHRj, где R Cj-Сз-алкил , в количестве 0,05-80 вес;% и добавку, выбранную из группы разбавитель, поверхностно-активное вещество.in which RJ denotes NHRj, where R Cj-Cz-alkyl, in an amount of 0.05-80 weight;% and an additive selected from the group of diluent, surfactant.
Формы применени композиции обычные; растворы, порощки, эмульсии, дисперсии. Их готов т обычными способами, общими при изготовлении препаративных форм пестицидов. Спосо.б получени соединени формулы I основан на взаимодействии соответствуюишм образом замещенного гидантоина с производными изоцианата в присутствии триэнтланина.The form of application of the composition is normal; solutions, powders, emulsions, dispersions. They are prepared by conventional methods common to the manufacture of pesticide formulations. The method of preparing a compound of formula I is based on the interaction of a suitably substituted hydantoin with isocyanate derivatives in the presence of trientlanin.
Пример 1. Фунгицидную активность изучают в лабораторных услови х на грибках:Example 1. Fungicidal activity is studied in laboratory conditions on fungi:
ВС - Botrytis cinerea;Sun - Botrytis cinerea;
SS - Sclerotina scterat;SS - Sclerotina scterat;
AM - Alternaria;AM - Alternaria;
PS - Pellicularia. Опыт проводилс на искусственной питательной среде в пробирке; Дл грибка Colletotricum Zinolemutham (Cd) опыт проводилс на растени х фасоли возрастом 12 дней. Эти растени сначала обрабатыва1й активным соединением, а затем заражали грибками. . - - - , .,-. Пол)Ч1енные результаты обобщены в таблице . Дл каждой группы грибка/культуры CA9S-100 в мг/мл дана минимальна доза, предотвращающа рост грибка. В опыте участвуют соединени формулы / с-н а)известные №1 R-H, R-H, №2 R-СНз, R-H, №3 R-H, R-СНз, R-СОСНз, R-H; №5 R-СОСНз, R-СНз; б)согласно изобретению №6 R-CONHCH3, R-H, NO 7 R-CONH(CH2)jpH3, R-H, № 8 (CH/CH3)2, R-H.PS - Pellicularia. The experiment was conducted on an artificial culture medium in a test tube; For the fungus Colletotricum Zinolemutham (Cd), the experiment was carried out on 12 day bean plants. These plants are first treated with the active compound and then infected with fungi. . - - -,., -. Gender) The overall results are summarized in the table. For each group of fungus / CA9S-100 culture in mg / ml, a minimum dose is given to prevent the growth of the fungus. Compounds of the formula / c-n a) known in the experiment are No. 1 R-H, R-H, No. 2 R-CH3, R-H, No. 3 R-H, R-CH3, R-COCH3, R-H; No. 5 R-COCH3, R-CH3; b) according to the invention No. 6 R-CONHCH3, R-H, NO 7 R-CONH (CH2) jpH3, R-H, No. 8 (CH / CH3) 2, R-H.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7036084A FR2120222A5 (en) | 1970-10-06 | 1970-10-06 | N-acyl-hydantoin derivs - with fungicidal activity |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU692536A3 true SU692536A3 (en) | 1979-10-15 |
Family
ID=9062356
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU711691054A SU692536A3 (en) | 1970-10-06 | 1971-09-03 | Fungicidal composition |
Country Status (17)
| Country | Link |
|---|---|
| AT (1) | AT311722B (en) |
| BE (1) | BE773529A (en) |
| BG (1) | BG22367A3 (en) |
| BR (1) | BR7106553D0 (en) |
| CH (1) | CH531307A (en) |
| CS (1) | CS158567B2 (en) |
| DK (1) | DK129287B (en) |
| ES (2) | ES395768A1 (en) |
| FR (1) | FR2120222A5 (en) |
| HU (1) | HU163151B (en) |
| IL (1) | IL37840A (en) |
| IT (1) | IT941470B (en) |
| LU (1) | LU64011A1 (en) |
| NL (1) | NL155542B (en) |
| RO (1) | RO61110A (en) |
| SU (1) | SU692536A3 (en) |
| ZA (1) | ZA716672B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| OA05041A (en) * | 1974-07-15 | 1980-12-31 | Rhone Poulenc Ind | New fungicidal compositions. |
| FR2320945A1 (en) * | 1975-08-13 | 1977-03-11 | Rhone Poulenc Ind | NEW PROCESS FOR THE PREPARATION OF (DICHLORO-3,5 PHENYL) -3 HYDANTOINE |
| FR2336397A1 (en) * | 1975-12-22 | 1977-07-22 | Philagro Sa | NEW PROCESS FOR THE PREPARATION OF CARBAMOYL-I (DICHLORO-3,5 PHENYL) -3 HYDANTOINS |
| EP0041465B1 (en) * | 1980-05-29 | 1984-07-25 | Rhone-Poulenc Agrochimie | Process for the preparation of 1-carbamoyl-3-(3,5-dichlorophenyl)-hydantoin, and 1-chlorocarbonyl-3-(3,5-dichlorophenyl) hydantoin as intermediate in this process |
| FR2483414A1 (en) * | 1980-05-29 | 1981-12-04 | Rhone Poulenc Agrochimie | Prepn. of 1-carbamoyl di:chlorophenyl hydantoin fungicide(s) - by reaction of a 1-unsubstituted hydantoin with phosgene and an amine |
| US5151524A (en) * | 1989-07-19 | 1992-09-29 | Otsuka Kagaku Kabushiki Kaisha | Process for preparing imidazolidine-2,5-dione derivative |
-
1970
- 1970-10-06 FR FR7036084A patent/FR2120222A5/en not_active Expired
-
1971
- 1971-09-03 SU SU711691054A patent/SU692536A3/en active
- 1971-09-28 NL NL7113311.A patent/NL155542B/en not_active IP Right Cessation
- 1971-10-01 CS CS696671A patent/CS158567B2/cs unknown
- 1971-10-04 BR BR6553/71A patent/BR7106553D0/en unknown
- 1971-10-05 BE BE773529A patent/BE773529A/en not_active IP Right Cessation
- 1971-10-05 LU LU64011D patent/LU64011A1/xx unknown
- 1971-10-05 CH CH1449671A patent/CH531307A/en not_active IP Right Cessation
- 1971-10-05 IL IL37840A patent/IL37840A/en unknown
- 1971-10-05 HU HURO630A patent/HU163151B/hu unknown
- 1971-10-05 DK DK484271AA patent/DK129287B/en unknown
- 1971-10-05 RO RO68368A patent/RO61110A/ro unknown
- 1971-10-05 ZA ZA716672A patent/ZA716672B/en unknown
- 1971-10-06 ES ES395768A patent/ES395768A1/en not_active Expired
- 1971-10-06 BG BG018713A patent/BG22367A3/en unknown
- 1971-10-06 IT IT29584/71A patent/IT941470B/en active
- 1971-10-06 ES ES395766A patent/ES395766A1/en not_active Expired
- 1971-10-06 AT AT864171A patent/AT311722B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DK129287C (en) | 1975-02-10 |
| BE773529A (en) | 1972-04-05 |
| BG22367A3 (en) | 1977-02-20 |
| FR2120222A5 (en) | 1972-08-18 |
| ES395768A1 (en) | 1973-12-01 |
| CH531307A (en) | 1972-12-15 |
| LU64011A1 (en) | 1972-06-28 |
| IL37840A0 (en) | 1971-12-29 |
| DK129287B (en) | 1974-09-23 |
| BR7106553D0 (en) | 1973-02-22 |
| ZA716672B (en) | 1972-06-28 |
| AT311722B (en) | 1973-11-26 |
| HU163151B (en) | 1973-06-28 |
| CS158567B2 (en) | 1974-11-25 |
| NL7113311A (en) | 1972-04-10 |
| IL37840A (en) | 1974-11-29 |
| RO61110A (en) | 1976-11-15 |
| NL155542B (en) | 1978-01-16 |
| IT941470B (en) | 1973-03-01 |
| ES395766A1 (en) | 1973-12-01 |
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