SU581862A3 - Способ получени -этилгексагидро1н-азепин-1-карботиоата - Google Patents
Способ получени -этилгексагидро1н-азепин-1-карботиоатаInfo
- Publication number
- SU581862A3 SU581862A3 SU7201835460A SU1835460A SU581862A3 SU 581862 A3 SU581862 A3 SU 581862A3 SU 7201835460 A SU7201835460 A SU 7201835460A SU 1835460 A SU1835460 A SU 1835460A SU 581862 A3 SU581862 A3 SU 581862A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- organic
- ethyl
- gmi
- carbothioate
- mixture
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 12
- 239000000203 mixture Substances 0.000 claims 11
- ZSIQJIWKELUFRJ-UHFFFAOYSA-N azepane Chemical compound C1CCCNCC1 ZSIQJIWKELUFRJ-UHFFFAOYSA-N 0.000 claims 10
- 150000001875 compounds Chemical class 0.000 claims 10
- 239000012074 organic phase Substances 0.000 claims 9
- 238000009835 boiling Methods 0.000 claims 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 6
- 239000008346 aqueous phase Substances 0.000 claims 4
- WBJINCZRORDGAQ-UHFFFAOYSA-N ethyl formate Chemical compound CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 claims 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims 3
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 claims 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims 3
- 238000001816 cooling Methods 0.000 claims 3
- 125000004494 ethyl ester group Chemical group 0.000 claims 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 3
- 235000019253 formic acid Nutrition 0.000 claims 3
- 239000000463 material Substances 0.000 claims 3
- 229910052757 nitrogen Inorganic materials 0.000 claims 3
- 239000012044 organic layer Substances 0.000 claims 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 2
- 238000004817 gas chromatography Methods 0.000 claims 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims 2
- 230000003993 interaction Effects 0.000 claims 2
- 239000005416 organic matter Substances 0.000 claims 2
- -1 polyethylene Polymers 0.000 claims 2
- QCMHWZUFWLOOGI-UHFFFAOYSA-N s-ethyl chloromethanethioate Chemical compound CCSC(Cl)=O QCMHWZUFWLOOGI-UHFFFAOYSA-N 0.000 claims 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 150000003868 ammonium compounds Chemical class 0.000 claims 1
- LDOPKOBZIPJHTP-UHFFFAOYSA-N azepine-1-carbothioic s-acid Chemical compound OC(=S)N1C=CC=CC=C1 LDOPKOBZIPJHTP-UHFFFAOYSA-N 0.000 claims 1
- 230000004071 biological effect Effects 0.000 claims 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 claims 1
- 238000010924 continuous production Methods 0.000 claims 1
- 229960003750 ethyl chloride Drugs 0.000 claims 1
- MIHRVCSSMAGKNH-UHFFFAOYSA-N ethylcarbamodithioic acid Chemical compound CCNC(S)=S MIHRVCSSMAGKNH-UHFFFAOYSA-N 0.000 claims 1
- 239000012535 impurity Substances 0.000 claims 1
- 238000002955 isolation Methods 0.000 claims 1
- 239000010410 layer Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- JGZZEAPGGFAOAY-UHFFFAOYSA-N o-ethyl ethylsulfanylmethanethioate Chemical compound CCOC(=S)SCC JGZZEAPGGFAOAY-UHFFFAOYSA-N 0.000 claims 1
- 239000012071 phase Substances 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims 1
- 235000011181 potassium carbonates Nutrition 0.000 claims 1
- 235000011118 potassium hydroxide Nutrition 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 238000000746 purification Methods 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
- 235000011182 sodium carbonates Nutrition 0.000 claims 1
- 235000011121 sodium hydroxide Nutrition 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 150000003672 ureas Chemical class 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
- C07D295/023—Preparation; Separation; Stabilisation; Use of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US18319071A | 1971-09-23 | 1971-09-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU581862A3 true SU581862A3 (ru) | 1977-11-25 |
Family
ID=22671822
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU7201835460A SU581862A3 (ru) | 1971-09-23 | 1972-09-22 | Способ получени -этилгексагидро1н-азепин-1-карботиоата |
Country Status (19)
| Country | Link |
|---|---|
| JP (1) | JPS4911892A (es) |
| AR (1) | AR201089A1 (es) |
| BE (1) | BE789161A (es) |
| BR (1) | BR7206563D0 (es) |
| CA (1) | CA995215A (es) |
| CH (1) | CH588480A5 (es) |
| CS (1) | CS185204B2 (es) |
| DD (1) | DD100254A5 (es) |
| DE (1) | DE2245000A1 (es) |
| ES (1) | ES406987A1 (es) |
| FR (1) | FR2153368B1 (es) |
| GB (1) | GB1377266A (es) |
| HU (1) | HU169766B (es) |
| IL (1) | IL40287A (es) |
| IT (1) | IT965444B (es) |
| NL (1) | NL7212318A (es) |
| PH (1) | PH13275A (es) |
| RO (1) | RO60666A (es) |
| SU (1) | SU581862A3 (es) |
-
0
- BE BE789161D patent/BE789161A/xx unknown
-
1972
- 1972-09-04 IL IL40287A patent/IL40287A/xx unknown
- 1972-09-07 CA CA151,157A patent/CA995215A/en not_active Expired
- 1972-09-08 AR AR243989A patent/AR201089A1/es active
- 1972-09-11 NL NL7212318A patent/NL7212318A/xx not_active Application Discontinuation
- 1972-09-14 DE DE2245000A patent/DE2245000A1/de active Pending
- 1972-09-19 GB GB4327172A patent/GB1377266A/en not_active Expired
- 1972-09-20 CS CS7200006423A patent/CS185204B2/cs unknown
- 1972-09-20 JP JP47094046A patent/JPS4911892A/ja active Pending
- 1972-09-21 BR BR006563/72A patent/BR7206563D0/pt unknown
- 1972-09-21 FR FR7233446A patent/FR2153368B1/fr not_active Expired
- 1972-09-21 IT IT52879/72A patent/IT965444B/it active
- 1972-09-22 CH CH1387472A patent/CH588480A5/xx not_active IP Right Cessation
- 1972-09-22 HU HUSA2404A patent/HU169766B/hu unknown
- 1972-09-22 SU SU7201835460A patent/SU581862A3/ru active
- 1972-09-23 RO RO72314A patent/RO60666A/ro unknown
- 1972-09-23 ES ES406987A patent/ES406987A1/es not_active Expired
- 1972-09-25 PH PH13935A patent/PH13275A/en unknown
- 1972-09-25 DD DD165863A patent/DD100254A5/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IL40287A (en) | 1975-07-28 |
| DD100254A5 (es) | 1973-09-12 |
| IL40287A0 (en) | 1972-11-28 |
| DE2245000A1 (de) | 1973-03-29 |
| BE789161A (fr) | 1973-03-22 |
| NL7212318A (es) | 1973-03-27 |
| RO60666A (es) | 1976-09-15 |
| GB1377266A (en) | 1974-12-11 |
| PH13275A (en) | 1980-02-27 |
| AR201089A1 (es) | 1975-02-14 |
| CA995215A (en) | 1976-08-17 |
| JPS4911892A (es) | 1974-02-01 |
| FR2153368B1 (es) | 1977-12-30 |
| FR2153368A1 (es) | 1973-05-04 |
| AU4657572A (en) | 1974-03-21 |
| BR7206563D0 (pt) | 1973-08-21 |
| IT965444B (it) | 1974-01-31 |
| ES406987A1 (es) | 1975-12-01 |
| CS185204B2 (en) | 1978-09-15 |
| HU169766B (es) | 1977-02-28 |
| CH588480A5 (es) | 1977-06-15 |
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